WO2008029765A1 - Support d'enregistrement optique d'hologramme volumique, composition pour fabriquer une couche d'enregistrement d'hologramme volumique, matériau d'enregistrement d'hologramme volumique et procédé d'enregistrement optique d'hologramme volumique - Google Patents
Support d'enregistrement optique d'hologramme volumique, composition pour fabriquer une couche d'enregistrement d'hologramme volumique, matériau d'enregistrement d'hologramme volumique et procédé d'enregistrement optique d'hologramme volumique Download PDFInfo
- Publication number
- WO2008029765A1 WO2008029765A1 PCT/JP2007/067139 JP2007067139W WO2008029765A1 WO 2008029765 A1 WO2008029765 A1 WO 2008029765A1 JP 2007067139 W JP2007067139 W JP 2007067139W WO 2008029765 A1 WO2008029765 A1 WO 2008029765A1
- Authority
- WO
- WIPO (PCT)
- Prior art keywords
- volume hologram
- recording layer
- resin matrix
- optical recording
- recording medium
- Prior art date
Links
- 230000003287 optical effect Effects 0.000 title claims abstract description 65
- 239000000463 material Substances 0.000 title claims description 39
- 239000000203 mixture Substances 0.000 title claims description 31
- 238000000034 method Methods 0.000 title claims description 29
- 150000001875 compounds Chemical class 0.000 claims abstract description 124
- 239000011159 matrix material Substances 0.000 claims abstract description 101
- 229920005989 resin Polymers 0.000 claims abstract description 77
- 239000011347 resin Substances 0.000 claims abstract description 77
- 150000003077 polyols Chemical class 0.000 claims abstract description 69
- 229920005862 polyol Polymers 0.000 claims abstract description 53
- 238000010521 absorption reaction Methods 0.000 claims abstract description 38
- 239000000758 substrate Substances 0.000 claims abstract description 37
- 239000005056 polyisocyanate Substances 0.000 claims abstract description 31
- 229920001228 polyisocyanate Polymers 0.000 claims abstract description 31
- 239000004593 Epoxy Substances 0.000 claims abstract description 30
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 125000003700 epoxy group Chemical group 0.000 claims abstract description 21
- 239000000178 monomer Substances 0.000 claims description 31
- 239000003505 polymerization initiator Substances 0.000 claims description 27
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 20
- 150000001412 amines Chemical class 0.000 claims description 12
- 125000002947 alkylene group Chemical group 0.000 claims description 11
- 150000008065 acid anhydrides Chemical class 0.000 claims description 8
- 238000010538 cationic polymerization reaction Methods 0.000 claims description 8
- 230000005284 excitation Effects 0.000 claims description 7
- 229920003002 synthetic resin Polymers 0.000 claims description 7
- 239000000057 synthetic resin Substances 0.000 claims description 7
- 230000001427 coherent effect Effects 0.000 claims description 6
- 150000003573 thiols Chemical class 0.000 claims description 5
- 125000004432 carbon atom Chemical group C* 0.000 claims description 4
- 239000010410 layer Substances 0.000 description 137
- -1 siloxane structure Chemical group 0.000 description 54
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical group OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 35
- 239000003999 initiator Substances 0.000 description 23
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical group CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 22
- 239000000654 additive Substances 0.000 description 21
- 125000000524 functional group Chemical group 0.000 description 16
- 239000011521 glass Substances 0.000 description 16
- 238000006116 polymerization reaction Methods 0.000 description 16
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 15
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 14
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 14
- 239000002904 solvent Substances 0.000 description 14
- 238000000576 coating method Methods 0.000 description 13
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 13
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 13
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 13
- WERYXYBDKMZEQL-UHFFFAOYSA-N butane-1,4-diol Chemical compound OCCCCO WERYXYBDKMZEQL-UHFFFAOYSA-N 0.000 description 12
- 238000003860 storage Methods 0.000 description 12
- 238000006243 chemical reaction Methods 0.000 description 11
- 230000002829 reductive effect Effects 0.000 description 11
- YIWUKEYIRIRTPP-UHFFFAOYSA-N 2-ethylhexan-1-ol Chemical compound CCCCC(CC)CO YIWUKEYIRIRTPP-UHFFFAOYSA-N 0.000 description 10
- 150000001450 anions Chemical class 0.000 description 10
- 125000002091 cationic group Chemical group 0.000 description 10
- 239000010408 film Substances 0.000 description 10
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 10
- 229920001296 polysiloxane Polymers 0.000 description 10
- 150000003254 radicals Chemical class 0.000 description 10
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 9
- 230000000996 additive effect Effects 0.000 description 9
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 9
- XQBCVRSTVUHIGH-UHFFFAOYSA-L [dodecanoyloxy(dioctyl)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCCCCCC)(CCCCCCCC)OC(=O)CCCCCCCCCCC XQBCVRSTVUHIGH-UHFFFAOYSA-L 0.000 description 8
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 8
- 229920000515 polycarbonate Polymers 0.000 description 8
- 239000004417 polycarbonate Substances 0.000 description 8
- 239000003054 catalyst Substances 0.000 description 7
- 230000006870 function Effects 0.000 description 7
- 229920000768 polyamine Polymers 0.000 description 7
- 238000002360 preparation method Methods 0.000 description 7
- 239000010936 titanium Substances 0.000 description 7
- 229940043375 1,5-pentanediol Drugs 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 6
- ALQSHHUCVQOPAS-UHFFFAOYSA-N Pentane-1,5-diol Chemical compound OCCCCCO ALQSHHUCVQOPAS-UHFFFAOYSA-N 0.000 description 6
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 6
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 6
- 230000008859 change Effects 0.000 description 6
- 238000006482 condensation reaction Methods 0.000 description 6
- 239000000975 dye Substances 0.000 description 6
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 6
- 230000002209 hydrophobic effect Effects 0.000 description 6
- 239000012948 isocyanate Substances 0.000 description 6
- 239000007788 liquid Substances 0.000 description 6
- 229920001223 polyethylene glycol Polymers 0.000 description 6
- 239000013638 trimer Substances 0.000 description 6
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 description 5
- 239000002202 Polyethylene glycol Substances 0.000 description 5
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 5
- YIMQCDZDWXUDCA-UHFFFAOYSA-N [4-(hydroxymethyl)cyclohexyl]methanol Chemical compound OCC1CCC(CO)CC1 YIMQCDZDWXUDCA-UHFFFAOYSA-N 0.000 description 5
- GUCYFKSBFREPBC-UHFFFAOYSA-N [phenyl-(2,4,6-trimethylbenzoyl)phosphoryl]-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C(=O)C1=C(C)C=C(C)C=C1C GUCYFKSBFREPBC-UHFFFAOYSA-N 0.000 description 5
- 125000003118 aryl group Chemical group 0.000 description 5
- 239000004202 carbamide Substances 0.000 description 5
- 229910052799 carbon Inorganic materials 0.000 description 5
- PMMYEEVYMWASQN-IMJSIDKUSA-N cis-4-Hydroxy-L-proline Chemical compound O[C@@H]1CN[C@H](C(O)=O)C1 PMMYEEVYMWASQN-IMJSIDKUSA-N 0.000 description 5
- 239000011248 coating agent Substances 0.000 description 5
- 238000010438 heat treatment Methods 0.000 description 5
- 150000002513 isocyanates Chemical class 0.000 description 5
- 125000003566 oxetanyl group Chemical group 0.000 description 5
- 230000035945 sensitivity Effects 0.000 description 5
- 239000000126 substance Substances 0.000 description 5
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 4
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 4
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 4
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 4
- 239000004809 Teflon Substances 0.000 description 4
- 229920006362 Teflon® Polymers 0.000 description 4
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- PESYEWKSBIWTAK-UHFFFAOYSA-N cyclopenta-1,3-diene;titanium(2+) Chemical class [Ti+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 PESYEWKSBIWTAK-UHFFFAOYSA-N 0.000 description 4
- FOTKYAAJKYLFFN-UHFFFAOYSA-N decane-1,10-diol Chemical compound OCCCCCCCCCCO FOTKYAAJKYLFFN-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 4
- 150000002430 hydrocarbons Chemical group 0.000 description 4
- 239000011254 layer-forming composition Substances 0.000 description 4
- 150000002790 naphthalenes Chemical class 0.000 description 4
- QBDSZLJBMIMQRS-UHFFFAOYSA-N p-Cumylphenol Chemical compound C=1C=C(O)C=CC=1C(C)(C)C1=CC=CC=C1 QBDSZLJBMIMQRS-UHFFFAOYSA-N 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 229920005906 polyester polyol Polymers 0.000 description 4
- 229920001451 polypropylene glycol Polymers 0.000 description 4
- 239000011241 protective layer Substances 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 125000006850 spacer group Chemical group 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- 238000004381 surface treatment Methods 0.000 description 4
- ARCGXLSVLAOJQL-UHFFFAOYSA-N trimellitic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C(C(O)=O)=C1 ARCGXLSVLAOJQL-UHFFFAOYSA-N 0.000 description 4
- QGKMIGUHVLGJBR-UHFFFAOYSA-M (4z)-1-(3-methylbutyl)-4-[[1-(3-methylbutyl)quinolin-1-ium-4-yl]methylidene]quinoline;iodide Chemical compound [I-].C12=CC=CC=C2N(CCC(C)C)C=CC1=CC1=CC=[N+](CCC(C)C)C2=CC=CC=C12 QGKMIGUHVLGJBR-UHFFFAOYSA-M 0.000 description 3
- DURPTKYDGMDSBL-UHFFFAOYSA-N 1-butoxybutane Chemical compound CCCCOCCCC DURPTKYDGMDSBL-UHFFFAOYSA-N 0.000 description 3
- UAJRSHJHFRVGMG-UHFFFAOYSA-N 1-ethenyl-4-methoxybenzene Chemical compound COC1=CC=C(C=C)C=C1 UAJRSHJHFRVGMG-UHFFFAOYSA-N 0.000 description 3
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- RNLHGQLZWXBQNY-UHFFFAOYSA-N 3-(aminomethyl)-3,5,5-trimethylcyclohexan-1-amine Chemical compound CC1(C)CC(N)CC(C)(CN)C1 RNLHGQLZWXBQNY-UHFFFAOYSA-N 0.000 description 3
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 3
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 3
- 229930185605 Bisphenol Natural products 0.000 description 3
- 239000004215 Carbon black (E152) Substances 0.000 description 3
- YMWUJEATGCHHMB-UHFFFAOYSA-N Dichloromethane Chemical compound ClCCl YMWUJEATGCHHMB-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 description 3
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 3
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 3
- 125000002723 alicyclic group Chemical group 0.000 description 3
- 125000001931 aliphatic group Chemical group 0.000 description 3
- 238000010539 anionic addition polymerization reaction Methods 0.000 description 3
- XSIFPSYPOVKYCO-UHFFFAOYSA-N benzoic acid butyl ester Natural products CCCCOC(=O)C1=CC=CC=C1 XSIFPSYPOVKYCO-UHFFFAOYSA-N 0.000 description 3
- 230000001588 bifunctional effect Effects 0.000 description 3
- 244000309464 bull Species 0.000 description 3
- 150000001768 cations Chemical class 0.000 description 3
- 150000002009 diols Chemical class 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- 150000002170 ethers Chemical class 0.000 description 3
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- 239000007789 gas Substances 0.000 description 3
- 230000009477 glass transition Effects 0.000 description 3
- 229930195733 hydrocarbon Natural products 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 230000001771 impaired effect Effects 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 3
- 150000002989 phenols Chemical class 0.000 description 3
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 description 3
- 229920000728 polyester Polymers 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical compound OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
- SZNYYWIUQFZLLT-UHFFFAOYSA-N 2-methyl-1-(2-methylpropoxy)propane Chemical compound CC(C)COCC(C)C SZNYYWIUQFZLLT-UHFFFAOYSA-N 0.000 description 2
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 2
- BNDRWEVUODOUDW-UHFFFAOYSA-N 3-Hydroxy-3-methylbutan-2-one Chemical compound CC(=O)C(C)(C)O BNDRWEVUODOUDW-UHFFFAOYSA-N 0.000 description 2
- ZGHFDIIVVIFNPS-UHFFFAOYSA-N 3-Methyl-3-buten-2-one Chemical compound CC(=C)C(C)=O ZGHFDIIVVIFNPS-UHFFFAOYSA-N 0.000 description 2
- SXFJDZNJHVPHPH-UHFFFAOYSA-N 3-methylpentane-1,5-diol Chemical compound OCCC(C)CCO SXFJDZNJHVPHPH-UHFFFAOYSA-N 0.000 description 2
- ULKLGIFJWFIQFF-UHFFFAOYSA-N 5K8XI641G3 Chemical compound CCC1=NC=C(C)N1 ULKLGIFJWFIQFF-UHFFFAOYSA-N 0.000 description 2
- UJOBWOGCFQCDNV-UHFFFAOYSA-N 9H-carbazole Chemical compound C1=CC=C2C3=CC=CC=C3NC2=C1 UJOBWOGCFQCDNV-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- GAWIXWVDTYZWAW-UHFFFAOYSA-N C[CH]O Chemical group C[CH]O GAWIXWVDTYZWAW-UHFFFAOYSA-N 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 description 2
- IAZDPXIOMUYVGZ-UHFFFAOYSA-N Dimethylsulphoxide Chemical compound CS(C)=O IAZDPXIOMUYVGZ-UHFFFAOYSA-N 0.000 description 2
- BRLQWZUYTZBJKN-UHFFFAOYSA-N Epichlorohydrin Chemical compound ClCC1CO1 BRLQWZUYTZBJKN-UHFFFAOYSA-N 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 2
- 229910001218 Gallium arsenide Inorganic materials 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 2
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 2
- BAPJBEWLBFYGME-UHFFFAOYSA-N Methyl acrylate Chemical compound COC(=O)C=C BAPJBEWLBFYGME-UHFFFAOYSA-N 0.000 description 2
- LGRFSURHDFAFJT-UHFFFAOYSA-N Phthalic anhydride Natural products C1=CC=C2C(=O)OC(=O)C2=C1 LGRFSURHDFAFJT-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- 150000003926 acrylamides Chemical class 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-L adipate(2-) Chemical compound [O-]C(=O)CCCCC([O-])=O WNLRTRBMVRJNCN-UHFFFAOYSA-L 0.000 description 2
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 2
- 229910052782 aluminium Inorganic materials 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 230000015572 biosynthetic process Effects 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 230000000740 bleeding effect Effects 0.000 description 2
- FUSUHKVFWTUUBE-UHFFFAOYSA-N buten-2-one Chemical compound CC(=O)C=C FUSUHKVFWTUUBE-UHFFFAOYSA-N 0.000 description 2
- JHIWVOJDXOSYLW-UHFFFAOYSA-N butyl 2,2-difluorocyclopropane-1-carboxylate Chemical compound CCCCOC(=O)C1CC1(F)F JHIWVOJDXOSYLW-UHFFFAOYSA-N 0.000 description 2
- XUPYJHCZDLZNFP-UHFFFAOYSA-N butyl butanoate Chemical compound CCCCOC(=O)CCC XUPYJHCZDLZNFP-UHFFFAOYSA-N 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 239000000460 chlorine Substances 0.000 description 2
- 229910052801 chlorine Inorganic materials 0.000 description 2
- 239000013078 crystal Substances 0.000 description 2
- 238000002425 crystallisation Methods 0.000 description 2
- 230000008025 crystallization Effects 0.000 description 2
- 125000004122 cyclic group Chemical group 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- SWXVUIWOUIDPGS-UHFFFAOYSA-N diacetone alcohol Chemical compound CC(=O)CC(C)(C)O SWXVUIWOUIDPGS-UHFFFAOYSA-N 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 239000000539 dimer Substances 0.000 description 2
- 239000002270 dispersing agent Substances 0.000 description 2
- 238000011156 evaluation Methods 0.000 description 2
- 150000002334 glycols Chemical class 0.000 description 2
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 2
- 229910052737 gold Inorganic materials 0.000 description 2
- 239000010931 gold Substances 0.000 description 2
- 125000005842 heteroatom Chemical group 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000004464 hydroxyphenyl group Chemical group 0.000 description 2
- 229910010272 inorganic material Inorganic materials 0.000 description 2
- 239000011147 inorganic material Substances 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 150000002576 ketones Chemical class 0.000 description 2
- ORUIBWPALBXDOA-UHFFFAOYSA-L magnesium fluoride Chemical compound [F-].[F-].[Mg+2] ORUIBWPALBXDOA-UHFFFAOYSA-L 0.000 description 2
- 229910001635 magnesium fluoride Inorganic materials 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- CKFGINPQOCXMAZ-UHFFFAOYSA-N methanediol Chemical compound OCO CKFGINPQOCXMAZ-UHFFFAOYSA-N 0.000 description 2
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
- PQIOSYKVBBWRRI-UHFFFAOYSA-N methylphosphonyl difluoride Chemical group CP(F)(F)=O PQIOSYKVBBWRRI-UHFFFAOYSA-N 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 2
- BDJRBEYXGGNYIS-UHFFFAOYSA-N nonanedioic acid Chemical compound OC(=O)CCCCCCCC(O)=O BDJRBEYXGGNYIS-UHFFFAOYSA-N 0.000 description 2
- 239000011368 organic material Substances 0.000 description 2
- RVTZCBVAJQQJTK-UHFFFAOYSA-N oxygen(2-);zirconium(4+) Chemical compound [O-2].[O-2].[Zr+4] RVTZCBVAJQQJTK-UHFFFAOYSA-N 0.000 description 2
- 230000035699 permeability Effects 0.000 description 2
- 239000005011 phenolic resin Substances 0.000 description 2
- 230000000704 physical effect Effects 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- 229920006295 polythiol Polymers 0.000 description 2
- 229920002635 polyurethane Polymers 0.000 description 2
- 238000012545 processing Methods 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000007142 ring opening reaction Methods 0.000 description 2
- 229920006395 saturated elastomer Polymers 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- 239000002356 single layer Substances 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 150000003440 styrenes Chemical class 0.000 description 2
- KZNICNPSHKQLFF-UHFFFAOYSA-N succinimide Chemical compound O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 2
- 150000003512 tertiary amines Chemical class 0.000 description 2
- 125000003944 tolyl group Chemical group 0.000 description 2
- 238000002834 transmittance Methods 0.000 description 2
- IMNIMPAHZVJRPE-UHFFFAOYSA-N triethylenediamine Chemical compound C1CN2CCN1CC2 IMNIMPAHZVJRPE-UHFFFAOYSA-N 0.000 description 2
- RIOQSEWOXXDEQQ-UHFFFAOYSA-N triphenylphosphine Chemical compound C1=CC=CC=C1P(C=1C=CC=CC=1)C1=CC=CC=C1 RIOQSEWOXXDEQQ-UHFFFAOYSA-N 0.000 description 2
- 229910001928 zirconium oxide Inorganic materials 0.000 description 2
- BUPRYTFTHBNSBD-UHFFFAOYSA-N (2,3,4-tribromophenyl) prop-2-enoate Chemical compound BrC1=CC=C(OC(=O)C=C)C(Br)=C1Br BUPRYTFTHBNSBD-UHFFFAOYSA-N 0.000 description 1
- SHMWGXIEPCHLGC-UHFFFAOYSA-N (4-ethenylphenyl)-phenylmethanone Chemical compound C1=CC(C=C)=CC=C1C(=O)C1=CC=CC=C1 SHMWGXIEPCHLGC-UHFFFAOYSA-N 0.000 description 1
- WNZGTRLARPEMIG-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10,11,11,12,12,12-hexacosafluorododecane Chemical compound FC(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F WNZGTRLARPEMIG-UHFFFAOYSA-N 0.000 description 1
- DSNMEFYRPYNWJJ-UHFFFAOYSA-N 1,1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,9,9,10,10-henicosafluorodecane Chemical compound FC(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)F DSNMEFYRPYNWJJ-UHFFFAOYSA-N 0.000 description 1
- OBAVAMUHCSFDSY-UHFFFAOYSA-N 1,1,1,2,3,3,4,4,5,5,6,6,7,8,8,8-hexadecafluoro-2,7-bis(trifluoromethyl)octane Chemical compound FC(F)(F)C(F)(C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)C(F)(C(F)(F)F)C(F)(F)F OBAVAMUHCSFDSY-UHFFFAOYSA-N 0.000 description 1
- CSUFEOXMCRPQBB-UHFFFAOYSA-N 1,1,2,2-tetrafluoropropan-1-ol Chemical compound CC(F)(F)C(O)(F)F CSUFEOXMCRPQBB-UHFFFAOYSA-N 0.000 description 1
- SCYULBFZEHDVBN-UHFFFAOYSA-N 1,1-Dichloroethane Chemical compound CC(Cl)Cl SCYULBFZEHDVBN-UHFFFAOYSA-N 0.000 description 1
- ZZXUZKXVROWEIF-UHFFFAOYSA-N 1,2-butylene carbonate Chemical compound CCC1COC(=O)O1 ZZXUZKXVROWEIF-UHFFFAOYSA-N 0.000 description 1
- VYMPLPIFKRHAAC-UHFFFAOYSA-N 1,2-ethanedithiol Chemical compound SCCS VYMPLPIFKRHAAC-UHFFFAOYSA-N 0.000 description 1
- XMEPRJBZFCWFKN-UHFFFAOYSA-N 1,3-Butanedithiol Chemical compound CC(S)CCS XMEPRJBZFCWFKN-UHFFFAOYSA-N 0.000 description 1
- VIESAWGOYVNHLV-UHFFFAOYSA-N 1,3-dihydropyrrol-2-one Chemical compound O=C1CC=CN1 VIESAWGOYVNHLV-UHFFFAOYSA-N 0.000 description 1
- PPMCFKAXXHZLMX-UHFFFAOYSA-N 1,3-dioxocan-2-one Chemical compound O=C1OCCCCCO1 PPMCFKAXXHZLMX-UHFFFAOYSA-N 0.000 description 1
- ANLVEXKNRYNLDH-UHFFFAOYSA-N 1,3-dioxonan-2-one Chemical compound O=C1OCCCCCCO1 ANLVEXKNRYNLDH-UHFFFAOYSA-N 0.000 description 1
- RYHBNJHYFVUHQT-UHFFFAOYSA-N 1,4-Dioxane Chemical compound C1COCCO1 RYHBNJHYFVUHQT-UHFFFAOYSA-N 0.000 description 1
- SRZXCOWFGPICGA-UHFFFAOYSA-N 1,6-Hexanedithiol Chemical compound SCCCCCCS SRZXCOWFGPICGA-UHFFFAOYSA-N 0.000 description 1
- GJRCLMJHPWCJEI-UHFFFAOYSA-N 1,9-Nonanedithiol Chemical compound SCCCCCCCCCS GJRCLMJHPWCJEI-UHFFFAOYSA-N 0.000 description 1
- GMYGJQQKISOIHH-UHFFFAOYSA-N 1-(2-methoxyphenyl)-2-phenylethane-1,2-dione Chemical compound COC1=CC=CC=C1C(=O)C(=O)C1=CC=CC=C1 GMYGJQQKISOIHH-UHFFFAOYSA-N 0.000 description 1
- HDXVSRDSYNPSAE-UHFFFAOYSA-N 1-(4-ethenylphenyl)ethanone Chemical compound CC(=O)C1=CC=C(C=C)C=C1 HDXVSRDSYNPSAE-UHFFFAOYSA-N 0.000 description 1
- PHPRWKJDGHSJMI-UHFFFAOYSA-N 1-adamantyl prop-2-enoate Chemical compound C1C(C2)CC3CC2CC1(OC(=O)C=C)C3 PHPRWKJDGHSJMI-UHFFFAOYSA-N 0.000 description 1
- BOVQCIDBZXNFEJ-UHFFFAOYSA-N 1-chloro-3-ethenylbenzene Chemical compound ClC1=CC=CC(C=C)=C1 BOVQCIDBZXNFEJ-UHFFFAOYSA-N 0.000 description 1
- KTZVZZJJVJQZHV-UHFFFAOYSA-N 1-chloro-4-ethenylbenzene Chemical compound ClC1=CC=C(C=C)C=C1 KTZVZZJJVJQZHV-UHFFFAOYSA-N 0.000 description 1
- VFWCMGCRMGJXDK-UHFFFAOYSA-N 1-chlorobutane Chemical compound CCCCCl VFWCMGCRMGJXDK-UHFFFAOYSA-N 0.000 description 1
- WXOZSJIRHYARIF-UHFFFAOYSA-N 1-cyclohexylprop-2-en-1-one Chemical compound C=CC(=O)C1CCCCC1 WXOZSJIRHYARIF-UHFFFAOYSA-N 0.000 description 1
- GJNDXPONYMDBFD-UHFFFAOYSA-N 1-ethenoxy-2,2-dimethylpropane Chemical compound CC(C)(C)COC=C GJNDXPONYMDBFD-UHFFFAOYSA-N 0.000 description 1
- OUSXYCTXXLYBGJ-UHFFFAOYSA-N 1-ethenyl-2,4-di(propan-2-yl)benzene Chemical compound CC(C)C1=CC=C(C=C)C(C(C)C)=C1 OUSXYCTXXLYBGJ-UHFFFAOYSA-N 0.000 description 1
- VTPNYMSKBPZSTF-UHFFFAOYSA-N 1-ethenyl-2-ethylbenzene Chemical compound CCC1=CC=CC=C1C=C VTPNYMSKBPZSTF-UHFFFAOYSA-N 0.000 description 1
- NVZWEEGUWXZOKI-UHFFFAOYSA-N 1-ethenyl-2-methylbenzene Chemical compound CC1=CC=CC=C1C=C NVZWEEGUWXZOKI-UHFFFAOYSA-N 0.000 description 1
- JZHGRUMIRATHIU-UHFFFAOYSA-N 1-ethenyl-3-methylbenzene Chemical compound CC1=CC=CC(C=C)=C1 JZHGRUMIRATHIU-UHFFFAOYSA-N 0.000 description 1
- OBRYRJYZWVLVLF-UHFFFAOYSA-N 1-ethenyl-4-ethoxybenzene Chemical compound CCOC1=CC=C(C=C)C=C1 OBRYRJYZWVLVLF-UHFFFAOYSA-N 0.000 description 1
- UULPGUKSBAXNJN-UHFFFAOYSA-N 1-ethenyl-4-phenoxybenzene Chemical compound C1=CC(C=C)=CC=C1OC1=CC=CC=C1 UULPGUKSBAXNJN-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- KUIZKZHDMPERHR-UHFFFAOYSA-N 1-phenylprop-2-en-1-one Chemical compound C=CC(=O)C1=CC=CC=C1 KUIZKZHDMPERHR-UHFFFAOYSA-N 0.000 description 1
- HECLRDQVFMWTQS-RGOKHQFPSA-N 1755-01-7 Chemical compound C1[C@H]2[C@@H]3CC=C[C@@H]3[C@@H]1C=C2 HECLRDQVFMWTQS-RGOKHQFPSA-N 0.000 description 1
- CDJYGEREXGLOSL-UHFFFAOYSA-N 2,11-dimethyldodecane Chemical compound CC(C)CCCCCCCCC(C)C CDJYGEREXGLOSL-UHFFFAOYSA-N 0.000 description 1
- KZUSAXRVIONPJU-UHFFFAOYSA-N 2,2,3,4,4,5,5,6,6,7,8,8,8-tridecafluoro-3,7-bis(trifluoromethyl)octanoic acid Chemical compound OC(=O)C(F)(F)C(F)(C(F)(F)F)C(F)(F)C(F)(F)C(F)(F)C(F)(C(F)(F)F)C(F)(F)F KZUSAXRVIONPJU-UHFFFAOYSA-N 0.000 description 1
- JCUZDQXWVYNXHD-UHFFFAOYSA-N 2,2,4-trimethylhexane-1,6-diamine Chemical compound NCCC(C)CC(C)(C)CN JCUZDQXWVYNXHD-UHFFFAOYSA-N 0.000 description 1
- CISIJYCKDJSTMX-UHFFFAOYSA-N 2,2-dichloroethenylbenzene Chemical compound ClC(Cl)=CC1=CC=CC=C1 CISIJYCKDJSTMX-UHFFFAOYSA-N 0.000 description 1
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 1
- BSWWXRFVMJHFBN-UHFFFAOYSA-N 2,4,6-tribromophenol Chemical compound OC1=C(Br)C=C(Br)C=C1Br BSWWXRFVMJHFBN-UHFFFAOYSA-N 0.000 description 1
- WQMWHMMJVJNCAL-UHFFFAOYSA-N 2,4-dimethylpenta-1,4-dien-3-one Chemical class CC(=C)C(=O)C(C)=C WQMWHMMJVJNCAL-UHFFFAOYSA-N 0.000 description 1
- AZUHIVLOSAPWDM-UHFFFAOYSA-N 2-(1h-imidazol-2-yl)-1h-imidazole Chemical class C1=CNC(C=2NC=CN=2)=N1 AZUHIVLOSAPWDM-UHFFFAOYSA-N 0.000 description 1
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 1
- NKBWMBRPILTCRD-UHFFFAOYSA-N 2-Methylheptanoic acid Chemical compound CCCCCC(C)C(O)=O NKBWMBRPILTCRD-UHFFFAOYSA-N 0.000 description 1
- FUIQBJHUESBZNU-UHFFFAOYSA-N 2-[(dimethylazaniumyl)methyl]phenolate Chemical compound CN(C)CC1=CC=CC=C1O FUIQBJHUESBZNU-UHFFFAOYSA-N 0.000 description 1
- NQXNYVAALXGLQT-UHFFFAOYSA-N 2-[4-[9-[4-(2-hydroxyethoxy)phenyl]fluoren-9-yl]phenoxy]ethanol Chemical compound C1=CC(OCCO)=CC=C1C1(C=2C=CC(OCCO)=CC=2)C2=CC=CC=C2C2=CC=CC=C21 NQXNYVAALXGLQT-UHFFFAOYSA-N 0.000 description 1
- ISRGONDNXBCDBM-UHFFFAOYSA-N 2-chlorostyrene Chemical compound ClC1=CC=CC=C1C=C ISRGONDNXBCDBM-UHFFFAOYSA-N 0.000 description 1
- 125000000954 2-hydroxyethyl group Chemical group [H]C([*])([H])C([H])([H])O[H] 0.000 description 1
- KJCFAQDTHMIAAN-UHFFFAOYSA-N 2-methyl-1-phenylprop-2-en-1-one Chemical compound CC(=C)C(=O)C1=CC=CC=C1 KJCFAQDTHMIAAN-UHFFFAOYSA-N 0.000 description 1
- FCYVWWWTHPPJII-UHFFFAOYSA-N 2-methylidenepropanedinitrile Chemical compound N#CC(=C)C#N FCYVWWWTHPPJII-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- BTOVVHWKPVSLBI-UHFFFAOYSA-N 2-methylprop-1-enylbenzene Chemical compound CC(C)=CC1=CC=CC=C1 BTOVVHWKPVSLBI-UHFFFAOYSA-N 0.000 description 1
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical compound OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 1
- DXIJHCSGLOHNES-UHFFFAOYSA-N 3,3-dimethylbut-1-enylbenzene Chemical compound CC(C)(C)C=CC1=CC=CC=C1 DXIJHCSGLOHNES-UHFFFAOYSA-N 0.000 description 1
- KOGSPLLRMRSADR-UHFFFAOYSA-N 4-(2-aminopropan-2-yl)-1-methylcyclohexan-1-amine Chemical compound CC(C)(N)C1CCC(C)(N)CC1 KOGSPLLRMRSADR-UHFFFAOYSA-N 0.000 description 1
- DZIHTWJGPDVSGE-UHFFFAOYSA-N 4-[(4-aminocyclohexyl)methyl]cyclohexan-1-amine Chemical compound C1CC(N)CCC1CC1CCC(N)CC1 DZIHTWJGPDVSGE-UHFFFAOYSA-N 0.000 description 1
- NNJMFJSKMRYHSR-UHFFFAOYSA-M 4-phenylbenzoate Chemical compound C1=CC(C(=O)[O-])=CC=C1C1=CC=CC=C1 NNJMFJSKMRYHSR-UHFFFAOYSA-M 0.000 description 1
- QWJWPDHACGGABF-UHFFFAOYSA-N 5,5-dimethylcyclopenta-1,3-diene Chemical compound CC1(C)C=CC=C1 QWJWPDHACGGABF-UHFFFAOYSA-N 0.000 description 1
- IZSHZLKNFQAAKX-UHFFFAOYSA-N 5-cyclopenta-2,4-dien-1-ylcyclopenta-1,3-diene Chemical group C1=CC=CC1C1C=CC=C1 IZSHZLKNFQAAKX-UHFFFAOYSA-N 0.000 description 1
- IVDFDARTBRUMQU-UHFFFAOYSA-N 6-nitro-1,5-dioxocane-2,4-dione Chemical compound C1(CC(=O)OC(CCO1)[N+](=O)[O-])=O IVDFDARTBRUMQU-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- QZCLKYGREBVARF-UHFFFAOYSA-N Acetyl tributyl citrate Chemical compound CCCCOC(=O)CC(C(=O)OCCCC)(OC(C)=O)CC(=O)OCCCC QZCLKYGREBVARF-UHFFFAOYSA-N 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- HMMJSYTURQVVBP-UHFFFAOYSA-N C(CCCCCCCCCS)S.C1(=CC=C(C=C1)S)S Chemical compound C(CCCCCCCCCS)S.C1(=CC=C(C=C1)S)S HMMJSYTURQVVBP-UHFFFAOYSA-N 0.000 description 1
- 229920001651 Cyanoacrylate Polymers 0.000 description 1
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
- MQIUGAXCHLFZKX-UHFFFAOYSA-N Di-n-octyl phthalate Natural products CCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC MQIUGAXCHLFZKX-UHFFFAOYSA-N 0.000 description 1
- PYGXAGIECVVIOZ-UHFFFAOYSA-N Dibutyl decanedioate Chemical compound CCCCOC(=O)CCCCCCCCC(=O)OCCCC PYGXAGIECVVIOZ-UHFFFAOYSA-N 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- ZVFDTKUVRCTHQE-UHFFFAOYSA-N Diisodecyl phthalate Chemical compound CC(C)CCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCC(C)C ZVFDTKUVRCTHQE-UHFFFAOYSA-N 0.000 description 1
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 1
- JIGUQPWFLRLWPJ-UHFFFAOYSA-N Ethyl acrylate Chemical compound CCOC(=O)C=C JIGUQPWFLRLWPJ-UHFFFAOYSA-N 0.000 description 1
- 239000005977 Ethylene Substances 0.000 description 1
- KMTRUDSVKNLOMY-UHFFFAOYSA-N Ethylene carbonate Chemical compound O=C1OCCO1 KMTRUDSVKNLOMY-UHFFFAOYSA-N 0.000 description 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 1
- 235000010469 Glycine max Nutrition 0.000 description 1
- 244000068988 Glycine max Species 0.000 description 1
- LSDPWZHWYPCBBB-UHFFFAOYSA-N Methanethiol Chemical compound SC LSDPWZHWYPCBBB-UHFFFAOYSA-N 0.000 description 1
- MWCLLHOVUTZFKS-UHFFFAOYSA-N Methyl cyanoacrylate Chemical compound COC(=O)C(=C)C#N MWCLLHOVUTZFKS-UHFFFAOYSA-N 0.000 description 1
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 1
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 1
- VVQNEPGJFQJSBK-UHFFFAOYSA-N Methyl methacrylate Chemical compound COC(=O)C(C)=C VVQNEPGJFQJSBK-UHFFFAOYSA-N 0.000 description 1
- FXHOOIRPVKKKFG-UHFFFAOYSA-N N,N-Dimethylacetamide Chemical compound CN(C)C(C)=O FXHOOIRPVKKKFG-UHFFFAOYSA-N 0.000 description 1
- SECXISVLQFMRJM-UHFFFAOYSA-N N-Methylpyrrolidone Chemical compound CN1CCCC1=O SECXISVLQFMRJM-UHFFFAOYSA-N 0.000 description 1
- FZERHIULMFGESH-UHFFFAOYSA-N N-phenylacetamide Chemical compound CC(=O)NC1=CC=CC=C1 FZERHIULMFGESH-UHFFFAOYSA-N 0.000 description 1
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 1
- 229910019142 PO4 Inorganic materials 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- LULCPJWUGUVEFU-UHFFFAOYSA-N Phthiocol Natural products C1=CC=C2C(=O)C(C)=C(O)C(=O)C2=C1 LULCPJWUGUVEFU-UHFFFAOYSA-N 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 206010070834 Sensitisation Diseases 0.000 description 1
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- YSMRWXYRXBRSND-UHFFFAOYSA-N TOTP Chemical compound CC1=CC=CC=C1OP(=O)(OC=1C(=CC=CC=1)C)OC1=CC=CC=C1C YSMRWXYRXBRSND-UHFFFAOYSA-N 0.000 description 1
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 description 1
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 1
- PRRGXULZOZTZDK-UHFFFAOYSA-N [(2,6-dichlorobenzoyl)-(2,5-dimethylphenyl)phosphoryl]-(2,6-dichlorophenyl)methanone Chemical compound CC1=CC=C(C)C(P(=O)(C(=O)C=2C(=CC=CC=2Cl)Cl)C(=O)C=2C(=CC=CC=2Cl)Cl)=C1 PRRGXULZOZTZDK-UHFFFAOYSA-N 0.000 description 1
- SLCCGASTYVDERR-UHFFFAOYSA-N [(2,6-dichlorobenzoyl)-(4-propylphenyl)phosphanyl]-(2,6-dichlorophenyl)methanone Chemical compound C1=CC(CCC)=CC=C1P(C(=O)C=1C(=CC=CC=1Cl)Cl)C(=O)C1=C(Cl)C=CC=C1Cl SLCCGASTYVDERR-UHFFFAOYSA-N 0.000 description 1
- LFOXEOLGJPJZAA-UHFFFAOYSA-N [(2,6-dimethoxybenzoyl)-(2,4,4-trimethylpentyl)phosphoryl]-(2,6-dimethoxyphenyl)methanone Chemical compound COC1=CC=CC(OC)=C1C(=O)P(=O)(CC(C)CC(C)(C)C)C(=O)C1=C(OC)C=CC=C1OC LFOXEOLGJPJZAA-UHFFFAOYSA-N 0.000 description 1
- QROGIFZRVHSFLM-QHHAFSJGSA-N [(e)-prop-1-enyl]benzene Chemical compound C\C=C\C1=CC=CC=C1 QROGIFZRVHSFLM-QHHAFSJGSA-N 0.000 description 1
- FDLQZKYLHJJBHD-UHFFFAOYSA-N [3-(aminomethyl)phenyl]methanamine Chemical compound NCC1=CC=CC(CN)=C1 FDLQZKYLHJJBHD-UHFFFAOYSA-N 0.000 description 1
- UKLDJPRMSDWDSL-UHFFFAOYSA-L [dibutyl(dodecanoyloxy)stannyl] dodecanoate Chemical compound CCCCCCCCCCCC(=O)O[Sn](CCCC)(CCCC)OC(=O)CCCCCCCCCCC UKLDJPRMSDWDSL-UHFFFAOYSA-L 0.000 description 1
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 239000001361 adipic acid Substances 0.000 description 1
- 235000011037 adipic acid Nutrition 0.000 description 1
- IBVAQQYNSHJXBV-UHFFFAOYSA-N adipic acid dihydrazide Chemical compound NNC(=O)CCCCC(=O)NN IBVAQQYNSHJXBV-UHFFFAOYSA-N 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 238000007754 air knife coating Methods 0.000 description 1
- 239000005456 alcohol based solvent Substances 0.000 description 1
- 125000003342 alkenyl group Chemical group 0.000 description 1
- 150000008064 anhydrides Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 239000002518 antifoaming agent Substances 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- XKRFYHLGVUSROY-UHFFFAOYSA-N argon Substances [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 1
- 229910052786 argon Inorganic materials 0.000 description 1
- 239000003849 aromatic solvent Substances 0.000 description 1
- 125000004429 atom Chemical group 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 239000002585 base Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- 230000005540 biological transmission Effects 0.000 description 1
- SAOKZLXYCUGLFA-UHFFFAOYSA-N bis(2-ethylhexyl) adipate Chemical compound CCCCC(CC)COC(=O)CCCCC(=O)OCC(CC)CCCC SAOKZLXYCUGLFA-UHFFFAOYSA-N 0.000 description 1
- BJQHLKABXJIVAM-UHFFFAOYSA-N bis(2-ethylhexyl) phthalate Chemical compound CCCCC(CC)COC(=O)C1=CC=CC=C1C(=O)OCC(CC)CCCC BJQHLKABXJIVAM-UHFFFAOYSA-N 0.000 description 1
- 238000004061 bleaching Methods 0.000 description 1
- 150000001642 boronic acid derivatives Chemical class 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 description 1
- SMTOKHQOVJRXLK-UHFFFAOYSA-N butane-1,4-dithiol Chemical compound SCCCCS SMTOKHQOVJRXLK-UHFFFAOYSA-N 0.000 description 1
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 1
- 229920002301 cellulose acetate Polymers 0.000 description 1
- 239000012986 chain transfer agent Substances 0.000 description 1
- 239000007809 chemical reaction catalyst Substances 0.000 description 1
- 150000001860 citric acid derivatives Chemical class 0.000 description 1
- 229920006026 co-polymeric resin Polymers 0.000 description 1
- 239000011247 coating layer Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000007859 condensation product Substances 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 239000000470 constituent Substances 0.000 description 1
- 238000003851 corona treatment Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- XLJMAIOERFSOGZ-UHFFFAOYSA-M cyanate Chemical compound [O-]C#N XLJMAIOERFSOGZ-UHFFFAOYSA-M 0.000 description 1
- 125000006165 cyclic alkyl group Chemical group 0.000 description 1
- 125000000753 cycloalkyl group Chemical group 0.000 description 1
- VKIRRGRTJUUZHS-UHFFFAOYSA-N cyclohexane-1,4-diamine Chemical compound NC1CCC(N)CC1 VKIRRGRTJUUZHS-UHFFFAOYSA-N 0.000 description 1
- ZWAJLVLEBYIOTI-UHFFFAOYSA-N cyclohexene oxide Chemical compound C1CCCC2OC21 ZWAJLVLEBYIOTI-UHFFFAOYSA-N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 230000003247 decreasing effect Effects 0.000 description 1
- 238000007872 degassing Methods 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- AYOHIQLKSOJJQH-UHFFFAOYSA-N dibutyltin Chemical compound CCCC[Sn]CCCC AYOHIQLKSOJJQH-UHFFFAOYSA-N 0.000 description 1
- 239000012975 dibutyltin dilaurate Substances 0.000 description 1
- 150000001991 dicarboxylic acids Chemical class 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- KORSJDCBLAPZEQ-UHFFFAOYSA-N dicyclohexylmethane-4,4'-diisocyanate Chemical compound C1CC(N=C=O)CCC1CC1CCC(N=C=O)CC1 KORSJDCBLAPZEQ-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 125000005442 diisocyanate group Chemical group 0.000 description 1
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 1
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 1
- XXBDWLFCJWSEKW-UHFFFAOYSA-N dimethylbenzylamine Chemical compound CN(C)CC1=CC=CC=C1 XXBDWLFCJWSEKW-UHFFFAOYSA-N 0.000 description 1
- MIMDHDXOBDPUQW-UHFFFAOYSA-N dioctyl decanedioate Chemical compound CCCCCCCCOC(=O)CCCCCCCCC(=O)OCCCCCCCC MIMDHDXOBDPUQW-UHFFFAOYSA-N 0.000 description 1
- ROORDVPLFPIABK-UHFFFAOYSA-N diphenyl carbonate Chemical compound C=1C=CC=CC=1OC(=O)OC1=CC=CC=C1 ROORDVPLFPIABK-UHFFFAOYSA-N 0.000 description 1
- ZZTCPWRAHWXWCH-UHFFFAOYSA-N diphenylmethanediamine Chemical compound C=1C=CC=CC=1C(N)(N)C1=CC=CC=C1 ZZTCPWRAHWXWCH-UHFFFAOYSA-N 0.000 description 1
- YIJMUXUNBGFYSI-UHFFFAOYSA-N diphenylmethanone hydrate Chemical compound O.C=1C=CC=CC=1C(=O)C1=CC=CC=C1 YIJMUXUNBGFYSI-UHFFFAOYSA-N 0.000 description 1
- VFHVQBAGLAREND-UHFFFAOYSA-N diphenylphosphoryl-(2,4,6-trimethylphenyl)methanone Chemical compound CC1=CC(C)=CC(C)=C1C(=O)P(=O)(C=1C=CC=CC=1)C1=CC=CC=C1 VFHVQBAGLAREND-UHFFFAOYSA-N 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 150000004662 dithiols Chemical class 0.000 description 1
- QQVHEQUEHCEAKS-UHFFFAOYSA-N diundecyl benzene-1,2-dicarboxylate Chemical compound CCCCCCCCCCCOC(=O)C1=CC=CC=C1C(=O)OCCCCCCCCCCC QQVHEQUEHCEAKS-UHFFFAOYSA-N 0.000 description 1
- LRBBIFXICMMTOW-UHFFFAOYSA-N dodecan-6-ol Chemical compound CCCCCCC(O)CCCCC LRBBIFXICMMTOW-UHFFFAOYSA-N 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 239000004210 ether based solvent Substances 0.000 description 1
- QPMJENKZJUFOON-PLNGDYQASA-N ethyl (z)-3-chloro-2-cyano-4,4,4-trifluorobut-2-enoate Chemical compound CCOC(=O)C(\C#N)=C(/Cl)C(F)(F)F QPMJENKZJUFOON-PLNGDYQASA-N 0.000 description 1
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229910052731 fluorine Inorganic materials 0.000 description 1
- 239000011737 fluorine Substances 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 235000019256 formaldehyde Nutrition 0.000 description 1
- ANSXAPJVJOKRDJ-UHFFFAOYSA-N furo[3,4-f][2]benzofuran-1,3,5,7-tetrone Chemical compound C1=C2C(=O)OC(=O)C2=CC2=C1C(=O)OC2=O ANSXAPJVJOKRDJ-UHFFFAOYSA-N 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 125000003827 glycol group Chemical group 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- 229910052736 halogen Inorganic materials 0.000 description 1
- 150000002367 halogens Chemical class 0.000 description 1
- CPBQJMYROZQQJC-UHFFFAOYSA-N helium neon Chemical compound [He].[Ne] CPBQJMYROZQQJC-UHFFFAOYSA-N 0.000 description 1
- CATSNJVOTSVZJV-UHFFFAOYSA-N heptan-2-one Chemical compound CCCCCC(C)=O CATSNJVOTSVZJV-UHFFFAOYSA-N 0.000 description 1
- 125000006289 hydroxybenzyl group Chemical group 0.000 description 1
- 238000005286 illumination Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000001746 injection moulding Methods 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- 150000002496 iodine Chemical class 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical class CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 239000005453 ketone based solvent Substances 0.000 description 1
- 229910052743 krypton Inorganic materials 0.000 description 1
- DNNSSWSSYDEUBZ-UHFFFAOYSA-N krypton atom Chemical compound [Kr] DNNSSWSSYDEUBZ-UHFFFAOYSA-N 0.000 description 1
- 230000031700 light absorption Effects 0.000 description 1
- 230000000670 limiting effect Effects 0.000 description 1
- GPSDUZXPYCFOSQ-UHFFFAOYSA-M m-toluate Chemical compound CC1=CC=CC(C([O-])=O)=C1 GPSDUZXPYCFOSQ-UHFFFAOYSA-M 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 125000005397 methacrylic acid ester group Chemical group 0.000 description 1
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 1
- GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
- 239000012046 mixed solvent Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 125000001971 neopentyl group Chemical group [H]C([*])([H])C(C([H])([H])[H])(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- SFBTTWXNCQVIEC-UHFFFAOYSA-N o-Vinylanisole Chemical compound COC1=CC=CC=C1C=C SFBTTWXNCQVIEC-UHFFFAOYSA-N 0.000 description 1
- ZWLPBLYKEWSWPD-UHFFFAOYSA-M o-toluate Chemical compound CC1=CC=CC=C1C([O-])=O ZWLPBLYKEWSWPD-UHFFFAOYSA-M 0.000 description 1
- 150000001451 organic peroxides Chemical class 0.000 description 1
- AHHWIHXENZJRFG-UHFFFAOYSA-N oxetane Chemical compound C1COC1 AHHWIHXENZJRFG-UHFFFAOYSA-N 0.000 description 1
- 150000002921 oxetanes Chemical class 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- HDBWAWNLGGMZRQ-UHFFFAOYSA-N p-Vinylbiphenyl Chemical compound C1=CC(C=C)=CC=C1C1=CC=CC=C1 HDBWAWNLGGMZRQ-UHFFFAOYSA-N 0.000 description 1
- LPNBBFKOUUSUDB-UHFFFAOYSA-M p-toluate Chemical compound CC1=CC=C(C([O-])=O)C=C1 LPNBBFKOUUSUDB-UHFFFAOYSA-M 0.000 description 1
- 238000004806 packaging method and process Methods 0.000 description 1
- 230000036961 partial effect Effects 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- UCUUFSAXZMGPGH-UHFFFAOYSA-N penta-1,4-dien-3-one Chemical class C=CC(=O)C=C UCUUFSAXZMGPGH-UHFFFAOYSA-N 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- PGMYKACGEOXYJE-UHFFFAOYSA-N pentyl acetate Chemical group CCCCCOC(C)=O PGMYKACGEOXYJE-UHFFFAOYSA-N 0.000 description 1
- PNJWIWWMYCMZRO-UHFFFAOYSA-N pent‐4‐en‐2‐one Natural products CC(=O)CC=C PNJWIWWMYCMZRO-UHFFFAOYSA-N 0.000 description 1
- 229950011087 perflunafene Drugs 0.000 description 1
- 125000005010 perfluoroalkyl group Chemical group 0.000 description 1
- UWEYRJFJVCLAGH-IJWZVTFUSA-N perfluorodecalin Chemical compound FC1(F)C(F)(F)C(F)(F)C(F)(F)[C@@]2(F)C(F)(F)C(F)(F)C(F)(F)C(F)(F)[C@@]21F UWEYRJFJVCLAGH-IJWZVTFUSA-N 0.000 description 1
- 229960005323 phenoxyethanol Drugs 0.000 description 1
- 125000003170 phenylsulfonyl group Chemical group C1(=CC=CC=C1)S(=O)(=O)* 0.000 description 1
- 235000021317 phosphate Nutrition 0.000 description 1
- 150000003003 phosphines Chemical group 0.000 description 1
- 150000004714 phosphonium salts Chemical group 0.000 description 1
- 150000003013 phosphoric acid derivatives Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 description 1
- 150000003021 phthalic acid derivatives Chemical class 0.000 description 1
- XKJCHHZQLQNZHY-UHFFFAOYSA-N phthalimide Chemical compound C1=CC=C2C(=O)NC(=O)C2=C1 XKJCHHZQLQNZHY-UHFFFAOYSA-N 0.000 description 1
- 229950010765 pivalate Drugs 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 239000002798 polar solvent Substances 0.000 description 1
- 230000010287 polarization Effects 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 238000006068 polycondensation reaction Methods 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920000921 polyethylene adipate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 150000007519 polyprotic acids Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920005749 polyurethane resin Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 150000003141 primary amines Chemical group 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- BOQSSGDQNWEFSX-UHFFFAOYSA-N propan-2-yl 2-methylprop-2-enoate Chemical compound CC(C)OC(=O)C(C)=C BOQSSGDQNWEFSX-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- 238000004080 punching Methods 0.000 description 1
- HNJBEVLQSNELDL-UHFFFAOYSA-N pyrrolidin-2-one Chemical compound O=C1CCCN1 HNJBEVLQSNELDL-UHFFFAOYSA-N 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000010526 radical polymerization reaction Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000000565 sealant Substances 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 150000003335 secondary amines Chemical group 0.000 description 1
- 230000008313 sensitization Effects 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000003381 stabilizer Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 229960002317 succinimide Drugs 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 239000011593 sulfur Substances 0.000 description 1
- RKHXQBLJXBGEKF-UHFFFAOYSA-M tetrabutylphosphanium;bromide Chemical compound [Br-].CCCC[P+](CCCC)(CCCC)CCCC RKHXQBLJXBGEKF-UHFFFAOYSA-M 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- DDFYFBUWEBINLX-UHFFFAOYSA-M tetramethylammonium bromide Chemical compound [Br-].C[N+](C)(C)C DDFYFBUWEBINLX-UHFFFAOYSA-M 0.000 description 1
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- DVKJHBMWWAPEIU-UHFFFAOYSA-N toluene 2,4-diisocyanate Chemical compound CC1=CC=C(N=C=O)C=C1N=C=O DVKJHBMWWAPEIU-UHFFFAOYSA-N 0.000 description 1
- 125000005628 tolylene group Chemical group 0.000 description 1
- 238000013519 translation Methods 0.000 description 1
- 125000005409 triarylsulfonium group Chemical group 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- FIQMHBFVRAXMOP-UHFFFAOYSA-N triphenylphosphane oxide Chemical compound C=1C=CC=CC=1P(C=1C=CC=CC=1)(=O)C1=CC=CC=C1 FIQMHBFVRAXMOP-UHFFFAOYSA-N 0.000 description 1
- 239000013598 vector Substances 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
Classifications
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/004—Recording, reproducing or erasing methods; Read, write or erase circuits therefor
- G11B7/0065—Recording, reproducing or erasing by using optical interference patterns, e.g. holograms
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/2403—Layers; Shape, structure or physical properties thereof
- G11B7/24035—Recording layers
- G11B7/24044—Recording layers for storing optical interference patterns, e.g. holograms; for storing data in three dimensions, e.g. volume storage
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/245—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing a polymeric component
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/26—Apparatus or processes specially adapted for the manufacture of record carriers
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H1/024—Hologram nature or properties
- G03H1/0248—Volume holograms
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/02—Details of features involved during the holographic process; Replication of holograms without interference recording
- G03H2001/026—Recording materials or recording processes
- G03H2001/0264—Organic recording material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H1/00—Holographic processes or apparatus using light, infrared or ultraviolet waves for obtaining holograms or for obtaining an image from them; Details peculiar thereto
- G03H1/04—Processes or apparatus for producing holograms
- G03H1/18—Particular processing of hologram record carriers, e.g. for obtaining blazed holograms
- G03H2001/186—Swelling or shrinking the holographic record or compensation thereof, e.g. for controlling the reconstructed wavelength
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2260/00—Recording materials or recording processes
- G03H2260/12—Photopolymer
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2260/00—Recording materials or recording processes
- G03H2260/30—Details of photosensitive recording material not otherwise provided for
- G03H2260/31—Ageing or resistance of the material
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03H—HOLOGRAPHIC PROCESSES OR APPARATUS
- G03H2270/00—Substrate bearing the hologram
- G03H2270/53—Recording material dispersed into porous substrate
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B2007/0003—Recording, reproducing or erasing systems characterised by the structure or type of the carrier
- G11B2007/0009—Recording, reproducing or erasing systems characterised by the structure or type of the carrier for carriers having data stored in three dimensions, e.g. volume storage
-
- G—PHYSICS
- G11—INFORMATION STORAGE
- G11B—INFORMATION STORAGE BASED ON RELATIVE MOVEMENT BETWEEN RECORD CARRIER AND TRANSDUCER
- G11B7/00—Recording or reproducing by optical means, e.g. recording using a thermal beam of optical radiation by modifying optical properties or the physical structure, reproducing using an optical beam at lower power by sensing optical properties; Record carriers therefor
- G11B7/24—Record carriers characterised by shape, structure or physical properties, or by the selection of the material
- G11B7/241—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material
- G11B7/242—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers
- G11B7/244—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only
- G11B7/246—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes
- G11B7/247—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes
- G11B7/2472—Record carriers characterised by shape, structure or physical properties, or by the selection of the material characterised by the selection of the material of recording layers comprising organic materials only containing dyes methine or polymethine dyes cyanine
Definitions
- Volume hologram optical recording medium volume hologram recording layer forming composition, volume hologram recording material, and volume hologram optical recording method
- the present invention relates to a volume hologram optical recording medium and the like, and more particularly to a volume hologram optical recording medium and the like capable of three-dimensional information recording by irradiation with a plurality of coherent lights.
- Non-Patent Document 1 General principles relating to the production of holograms are described in several documents and technical books (see Non-Patent Document 1). According to these, one of the two light beams of coherent laser light is irradiated onto the recording object, and a photosensitive hologram recording material is placed at a position where the light can be received.
- the hologram recording material is directly irradiated with the other coherent light in addition to the light from the object without hitting the object.
- the light from the object is called object light
- the light directly irradiated on the recording material is called reference light.
- interference fringes between the reference beam and the object beam are recorded as image information.
- the hologram is diffracted by the hologram so as to reproduce the wavefront of the reflected light that first reaches the recording material from the object. Is done.
- the same object image as the real image of the object can be observed in three dimensions.
- the hologram formed by making the reference light and the object light incident on the hologram recording material from the same direction is called a transmission hologram! /
- the hologram formed by making the reference light and the object light incident from the opposite side! This is called a reflection hologram.
- a hologram having a sufficiently thick film thickness with respect to the interference fringe interval (usually a film thickness of about 5 times the interference fringe interval or about 1 ⁇ m or more) is called a volume hologram.
- Volume holograms can be recorded in the film thickness direction, so recording with higher density is possible with larger film thickness.
- a write-once type that does not require wet processing or bleaching.
- the composition is generally a resin matrix in which a photoactive compound is compatible.
- a photopolymer method in which a monomer that can be cationically polymerized by radical polymerization is combined with a resin matrix (see Patent Documents 1 to 4, etc.).
- the object light is irradiated onto the recording layer together with the reference light so that the object light and the reference light interfere with each other in the recording layer.
- the interference light changes the photoactive compound in the recording layer.
- the photoactive compound is a polymerizable monomer
- polymerization is initiated, and a concentration gradient of the photoactive compound is generated accordingly, and the photoactive compound diffuses and moves from a weak part to a strong part.
- a refractive index difference occurs in the recording layer due to the density of the photoactive compound in the recording layer, and the interference fringes recorded in the recording layer are recorded as a hologram. Since the diffraction efficiency increases as the refractive index difference in the recording layer increases, either the resin matrix or the photoactive compound has an aromatic ring, a hetero ring, chlorine, an odor, etc. in order to generate the refractive index difference.
- Non-Patent Document 1 Junpei Uchiuchi, “Holographic Display”, Chapter 2, Industrial Books
- Patent Document 1 Japanese Patent No. 3737306
- Patent Document 2 Patent No. 3645480
- Patent Document 3 JP 2005-43862 A
- Patent Document 4 Japanese Translation of Special Publication 2005 502918
- Various methods may be used as a method for forming the resin matrix.
- isocyanate-hydroxyl stage polymerization (urethane formation), isocyanate-amine amine polymerization (urea formation), cationic epoxy polymerization, cationic butyl ether polymerization, cationic alkenyl ether polymerization, epoxy-amine amine polymerization, epoxy mercaptan stage polymerization, etc.
- this resin matrix contains a polyether skeleton from the viewpoint of compatibility with the photoactive compound before photoreaction and compatibility with the polymer obtained from the photoactive compound after photoreaction. Synthetic resins are often used.
- Patent Document 1 in practice, a synthetic resin having a structure of an alkylene oxide having C1 to C3 carbon atoms is often used as a main component. Further, Patent Document 2 of this later application has a problem that this resin matrix tends to absorb moisture during storage, the material expands, the refractive index changes spatially non-uniformly, and the shelf life is limited. It is described that there is.
- Patent Document 2 describes a method of packaging a recording layer in a sealed glass plate and sealing the periphery with a moisture-proof sealant! There is no description.
- the recording characteristics of the information when stored on the medium (Shelf Life) and the storage stability of the recorded information (Archival Life) are particularly important issues. There are no specific details yet.
- an object of the present invention is to provide a volume hologram optical recording medium having a recording layer with low hygroscopicity.
- Another object of the present invention is to provide a composition for forming a volume hologram recording layer that has low hygroscopicity, excellent storage stability, and excellent compatibility with other components.
- Another object of the present invention is to provide a volume hologram recording material. Another object of the present invention is to provide a volume hologram optical recording method. Means for solving the problem
- the present inventors have excellent storage stability when the moisture absorption rate of the formed recording layer is 1.5% by weight or less, and other components. It has been found that a volume hologram optical recording medium excellent in compatibility with can be obtained.
- the glass transition temperature (Tg) is unlikely to decrease because the amount of moisture mixed into the matrix is small. Hard to happen. For this reason, the initial state in which the photoactive compound is uniformly dissolved and dispersed in the resin matrix is maintained, and even when the medium is stored for a long period of time, the sensitivity is high. It is thought that information can be recorded frequently.
- the movement of the photoactive compound is small after recording, it is considered that the storage stability of the recorded information is also improved. Further, when the moisture absorption rate is low, the recording layer itself is not easily expanded, so that a spatial refractive index change occurs, so that a uniform state is maintained and the optical quality is not impaired. In addition, the influence on the visible light polymerization initiator is reduced, and it is considered that recording is performed with high sensitivity.
- the recording layer contains the resin matrix (A) and / or the resin matrix (B) and the photoactive compound (C).
- the present inventors have found that this can be achieved by measures such as reducing the concentration of the hydrophilic functional group and the like, and adding an additive having a hydrophobic structure.
- the resin matrix (B) is obtained by reacting an epoxy compound (B1) having two or more epoxy groups in one molecule and a curing agent (B2).
- the recording layer has a multilayer structure including at least a transparent substrate and a recording layer containing a synthetic resin, and the recording layer is irradiated with a plurality of coherent lights.
- a volume hologram optical recording medium capable of recording information three-dimensionally by interference fringes formed therein, wherein the formed recording layer has a moisture absorption of 1.5% by weight or less.
- An optical recording medium is provided.
- the recording layer includes a resin matrix (A) and / or a resin matrix (B), and a photoactive compound (C).
- the resin matrix (B) is obtained by reacting an epoxy compound (B1) having two or more epoxy groups in one molecule with a curing agent (B2). Is preferred.
- the polyisocyanate (A1) has three or more isocyanate groups in one molecule.
- the epoxy compound (B1) has a carbon number of 4 or more and 10 or less. It is preferable to have the following alkylene oxide.
- the curing agent (B2) may be at least one selected from the group consisting of amines, acid anhydrides, phenols, anion polymerization initiators and cationic polymerization initiators. I like it.
- the photoactive compound (C) is preferably a radical polymerizable monomer.
- the ratio of the photoactive compound (C) is 100 parts by weight of the resin matrix (A) or the resin matrix (B) or the sum of the resin matrix (A) and the resin matrix (B) ((A) + (B)) It is preferably 0.5 parts by weight or more and 100 parts by weight or less with respect to 100 parts by weight.
- a composition for forming a volume hologram recording layer which is obtained by reacting a compound (B1) with a curing agent (B2).
- volume hologram recording material comprising at least the composition for forming a volume hologram recording layer according to claim 8.
- the recording layer of the volume hologram optical recording medium is irradiated with excitation light and reference light, and volume hologram recording is performed on the recording layer by interference between the excitation light and the reference light.
- a volume hologram optical recording method is provided.
- a volume holographic optical recording medium having a recording layer with low hygroscopicity and excellent storage stability can be obtained.
- a volume hologram optical recording medium to which the present embodiment is applied has a multilayer structure including at least a transparent substrate and a recording layer containing a synthetic resin. Moisture absorption is 1.5% by weight or less.
- the moisture absorption rate of the recording layer formed in the present embodiment is evaluated in the state of a thin film having a thickness of 500 ⁇ peeled from the substrate.
- the moisture absorption rate (%) is set immediately after the recording layer is prepared, that is, the weight of the recording layer before moisture absorption is W1 (23 ° C, 50% RH), and is placed in an environment of 60 ° C, 90% RH for 24 hours. Then, the weight of the recording layer measured immediately after that is W2, and is calculated by the following formula.
- (meth) acrylic acid is a generic term for acrylic acid and methacrylic acid.
- (meth) acrylamide is a generic term for acrylic acid and methacrylic acid.
- (meth) acrylamide is a generic term for acrylic acid and methacrylic acid.
- (meth) acrylamide is a generic term for acrylic acid and methacrylic acid.
- (meth) acrylamide is a generic term for acrylic acid and methacrylic acid.
- (meth) acrylamide is a generic term for acrylic acid and methacrylic acid.
- a 500 m-thick recording layer formed on the substrate using the composition is peeled off from the substrate, and moisture is contained in an environment of 60 ° C. and 90% RH. It has the property that the weight increase (moisture absorption rate) after being saturated is 1.5% by weight or less based on the initial weight.
- compositions for forming a volume hologram recording layer examples include those containing at least a resin matrix (A) and / or a resin matrix (B) (hereinafter sometimes simply referred to as “resin matrix”) and a photoactive compound (C).
- resin matrix a resin matrix
- C a photoactive compound
- hydrophilic functional groups include functional groups and structures such as urethane bonds, urea bonds, hydroxyl groups, amino groups, carboxyl groups, ethylene glycol residues, and propylene glycol residues.
- hydrophobic structures include C4 or higher cyclic or non-cyclic alkyl groups, hydrocarbon groups such as alkylene groups; structures containing fluorine atoms such as perfluoroalkyl structures and perfluoroalkylene structures; and Examples include a siloxane structure.
- a specific measure for reducing the hydrophilic functional group concentration in the matrix for example, a method of forming a matrix using a polyol or polyisocyanate having a relatively high molecular weight; There is a method of reducing the urethane bond concentration in the matrix as a result by reducing the number of functional groups per molecule contained in cyanate.
- the hydrophilic functional groups in the matrix can also be reduced by reducing residual hydroxyl groups, isocyanate groups, epoxy groups (or hydroxyl groups formed by ring opening of epoxy groups), etc.
- the base concentration can be reduced.
- the refractive index of the photoactive compound (C) is further increased by polymerization than before polymerization. Therefore, the resin matrix is preferably designed so as to have a refractive index lower than that of the photoactive compound (C). Therefore, the photoactive compound (C) is preferably a compound having a relatively high refractive index and having an aromatic ring, a hetero ring, an alicyclic structure, bromine, chlorine or the like. The resin matrix is preferably designed not to have the above structure. The greater the refractive index difference between the resin matrix and the photoactive compound (C), the higher the diffraction efficiency.
- the polyisocyanate (A1) used for the resin matrix (A) is not particularly limited as long as it has two or more isocyanate groups in one molecule.
- the number of isocyanate groups contained in the polyisocyanate (A1) is usually not particularly limited as long as it is 2 or more, and particularly preferably 3 or more. If the number of isocyanate groups is too small, the hardness required for the matrix may not be obtained. If the number of isocyanate groups is excessive, recording sensitivity tends to increase.
- the upper limit of the number of isocyanate groups is not particularly limited, but is usually about 20 or less isocyanate groups per molecule of polyisocyanate (A1). In this case, the range of the isocyanate group content (NCO%) contained in the polyisocyanate (A1) is usually 1% to 80%, preferably 3% to 60%. Used.
- Examples of the polyisocyanate (A1) used in the present embodiment include aliphatics such as hexamethylene diisocyanate, lysine methyl ester diisocyanate, and 2, 4, 4 trimethylhexamethyylene diisocyanate.
- the multimer is preferably a 3-7 mer of these compounds.
- reaction material with polyhydric alcohols such as water, a trimethylol ethane, a trimethylol propane, etc. are mentioned.
- polyhydric alcohols such as water, a trimethylol ethane, a trimethylol propane, etc. are mentioned.
- Hexamethylene diisocyanate multimers or derivatives thereof are particularly preferred.
- Examples of such "compounds having two or more active hydrogens in the molecule” include, for example, ethylene glycolol, propylene glycolanol, 1,4 butanediol, 1,5-pentanediol, and 3-methylolene 1 , 5-pentanediol, 1, 6-hexanediol, neopentylene glycoleno, gentylene glycolanol, 1,4-cyclohexanediol, 1,4-sic hexanedimethanol, decamethylene glycol, polyethylene glycol, Use polytetramethylene glycol, ethylenediamine, propylenediamine, isophoronediamine, 4,4 'diaminodicyclohexylmethane, 2,2,4 trimethylhexamethylenediamine, 1,4 diaminocyclohexane, etc. Can do.
- the molecular weight of the polyisocyanate is a number-average molecular weight of 100 or more and 50,000 or less, preferably S, more preferably ⁇ is 150 or more and 10,000 or less, and more preferably ⁇ is 150 or more and 5,000 or less. . If the number average molecular weight is excessively small, the crosslink density increases, so that the hardness of the matrix becomes too high and the recording speed may decrease. On the other hand, if the number average molecular weight is excessively large, the compatibility with other components may decrease, or the crosslink density may decrease, so that the hardness of the matrix becomes too low and the recorded content may be lost.
- the polyisocyanate (A1) contains constituents other than the isocyanate group within the range that does not significantly impair the effects of the present invention!
- the upper limit of the number of hydroxyl groups is not particularly limited, but is usually preferably 5 or less. If many hydroxyl groups remain in the matrix, the matrix becomes more hygroscopic and may affect the storage stability of the record.
- the poly-strength prolataton polyol is obtained by reacting the rataton with a diol or a polyhydric alcohol.
- Examples of the ratataton include ⁇ -force prolatatatone, ⁇ -force prolatathone, ⁇ -force prolacton, ⁇ -force prolacton, ⁇ -methinolet ⁇ -force prolatathon, ⁇ -methinolet ⁇ -force prolatathone, and the like.
- diol or polyhydric alcohol examples include ethylene glycol, propylene glycol, 1,4 butanediol, 1,5-pentanediol, 3-methyl-1,5-pentanediol, and 1,6-hexanediol.
- Neopentinoglycol diethylene glycol, 1,4-cyclohexanediol, 1,4-cyclohexanedimethanol, decamethylene glycol, polyethylene glycol, polytetramethylene glycol and the like.
- Examples of commercially available poly-strength prolataton polyols obtained from the reaction of one-strength prolatatone include, for example, praxenole 205, praxenore 210, praxenore 220, praxenore 230, praxenore 240, praxenore 303, praxenore 305, 308, Plaxel 312, Plaxel 320 (all are trade names manufactured by Daicel Chemical Industries, Ltd.)
- polycarbonate polyol a compound obtained by a dealcoholization condensation reaction between a glycol and a dialkyl carbonate (eg, dimethyl carbonate, jetyl carbonate, etc.); a dephenol condensation reaction between a glycol and a diphenyl carbonate A compound obtained by a deglycolization condensation reaction between glycols and carbonates (for example, ethylene carbonate, diethyl carbonate, etc.), etc.
- glycols examples include aliphatic diols such as 1,6 hexanediol, diethylene glycol, propylene glycolanol, 1,4 butanediole, 3-methanole 1,5pentanediole, and neopentyl glycol; Alicyclic diols such as 1,4-cyclohexanediol and 1,4-cyclohexanedimethanol.
- a poly (hexamethylene carbonate) polyol obtained by a condensation reaction of 1,6 hexanediol and jetyl carbonate
- examples include poly (pentylene carbonate) obtained by condensation reaction with til carbonate; 1,4 poly (butylene carbonate) obtained by condensation reaction of butanediol and jetyl carbonate.
- polycarbonate polyols include Plaxel CD CD205, Plaxel CD CD210, Plaxel CD CD220 (both trade names manufactured by Daicel Chemical Industries, Ltd.), PCDL T5651, PCDL T5652, PCDL T5650J (All of them are trade names) manufactured by Asahi Kasei Corporation.
- polyester polyols include those obtained by polycondensation of dicarboxylic acids or their anhydrides with polyols.
- dicarboxylic acid include succinic acid, adipic acid, sebacic acid, azelaic acid, dimer acid, maleic anhydride, isophthalic acid, terephthalic acid, trimellitic acid and the like.
- polyol examples include ethylene glycol, propylene glycol, 1,4-butanediol, 1,5-pentanediol, 3-methyl-1,5-pentanediol, 1,6-hexanediol, and neopentyl glycol.
- polyester polyols examples include polyethylene adipate, polybrylene adipate, and polyhexamethylene adipate.
- Commercially available polyester polyols include Ade force New Ace F series, Ade force New Ace ⁇ series, Ade force New Ace NS series (trade name, manufactured by Ade force Co., Ltd.), Kuraray Polyol ⁇ —2010, ⁇ —4011, ⁇ —1020 (all Kuraray Co., Ltd., trade names), etc., C—1000, C—1066, U—21, U—24, U—53, U—253, U—502, U— 118mm (V, Missouri made by Mitsui Chemicals Polyurethane Co., Ltd., trade name).
- the water absorption of the recording layer can be suppressed to 1.5% by weight or less.
- the concentration of the hydrophilic functional group contained in the recording layer is greatly restricted, and the selection of the raw material for the composition for forming a volume hologram recording layer tends to be restricted.
- the resin matrix (A) contains other components in addition to the above-described polyisocyanate (A1) and polyol (A2), as long as not departing from the spirit of the present invention. May be.
- Examples of such other components include ethylene glycol, propylene glycol, 1,4 butanediol, 1,5-pentanediol, and 3-methylolene for the purpose of changing the physical properties of the resin matrix (A).
- a catalyst or an additive can be blended.
- catalysts include conventional urethanization reaction catalysts; for example, tin-based catalysts such as dibutyltin dilaurate, dioctyltin dilaurate, and dibutyltin ditatoate; tertiary amines such as triethylamine and triethylenediamine A catalyst is mentioned.
- tin-based catalysts such as dibutyltin dilaurate, dioctyltin dilaurate, and dibutyltin ditatoate
- tertiary amines such as triethylamine and triethylenediamine A catalyst is mentioned.
- the amount of the catalyst used is usually 0.001% by weight or more, preferably 0.001% by weight or more, as a ratio to the resin matrix (A). Further, it is usually 10% by weight or less, preferably 5% by weight or less. If the amount of catalyst used is too small, curing may take too long. On the other hand, if the amount used is excessive, it may be difficult to control the curing reaction. There is a match.
- the resin matrix (B) used in the volume hologram recording layer forming composition of the present embodiment comprises an epoxy compound (B1) having two or more epoxy groups in one molecule, and a curing agent (B2). Contains at least.
- the type of epoxy compound (B1) used for the resin matrix (B) is not particularly limited as long as it has two or more epoxy groups in one molecule. There are cases where the number of epoxy groups is small and the hardness required for the matrix cannot be obtained.
- the upper limit of the number of epoxy groups is not particularly limited, but is usually 8 or less, preferably 4 or less. If the number of epoxy groups is excessively large, it takes a long time to consume the epoxy groups, and it may take too much time S to form the matrix.
- Examples of the epoxy compound (B1) having two or more epoxy groups in one molecule include, for example, (poly) ethylene glycol, (poly) propylene glycol, (poly) tetramethylene glycol, tri Polyglycidyl ether compounds of polyols such as methylol propane and glycerin; 3, 4-epoxycyclohexenoremethylolene 3, 4-epoxycyclohexane canolepoxylate, 3, 4-epoxy 1-methylcyclohexyl lu 3, 4-epoxy Cycloaliphatic epoxy compounds having a 4- to 7-membered cyclic aliphatic group such as 1-methylhexanecarboxylate; bisphenol A type epoxy compound, hydrogenated bisphenol A type epoxy compound, bisphenol F type Examples thereof include epoxy compounds, phenol or cresol nopolac type epoxy compounds.
- the carbon number is usually 4 or more, and usually 10 or less, especially 8 or less, Furthermore, the range of 6 or less is preferable.
- the number of carbon atoms is too large, the hydrophobicity is improved, but the polarity of the molecule is lowered, so that the compatibility with a photoactive compound, a polymerization initiator, a catalyst and the like may be lowered.
- the recording speed may decrease, optical non-uniformity may occur, and this may cause data errors during hologram recording.
- alkylene oxides having a carbon number power of 10 or less examples include alkyl trimethylene oxides obtained by opening an oxetane having a substituent containing a carbon atom, and tetrahydridofurans by opening a ring. And tetramethylene oxide.
- tetramethylene oxide is particularly preferable from the viewpoint of balance between hydrophobicity, compatibility, and glass transition temperature.
- an alkylene oxide obtained by copolymerizing tetramethylene oxide with neopentyldaricol can also be used.
- the amount of alkylene oxide is usually in the range of 10% by weight or more, preferably 50% by weight or more based on the entire epoxy compound (B1). If the amount of alkylene oxide is small, the Tg of the matrix becomes too high and the recording speed may decrease. On the other hand, the upper limit is not particularly limited and is less than 100%.
- the epoxy compound (B1) satisfying the above conditions can be synthesized by a known method. In general, it is possible to synthesize using glycol having an alkylene oxide chain having a carbon number power or more and epichlorohydrin.
- the number average molecular weight of the epoxy compound (B1) is preferably 200 or more and 50,000 or less, more preferably 300 or more and 20,000 or less, and further preferably ⁇ or 300 or more and 10,000 or less. If the molecular weight is too small, the hardness of the matrix becomes too high, and the recording speed may decrease. On the other hand, if the molecular weight is excessively large, the hardness of the matrix is too small and the recorded content may be lost.
- the type of the curing agent (B2) used in the resin matrix (B) is not particularly limited as long as it is a compound having a functional group that reacts with an epoxy group, and may be appropriately selected from known compounds. Is possible.
- Examples of the curing agent (B2) include polyfunctional phenols, amines, acid anhydrides, thiols, cation polymerization initiators, and cationic polymerization initiators.
- Examples of the polyfunctional phenol include bisphenol, nopolac-type phenol resin, and resole-type phenol resin.
- amines those containing a primary amine group or a secondary amine group can be used.
- examples of such amines include ethylenediamine, diethylenetriamine and the like.
- Aliphatic polyamines such as derivatives thereof; alicyclic polyamines such as isophorone diamine, mentandiamine, N-aminoethylbiperazine and derivatives thereof; aromatic polyamines, polyamides, imidazole compounds and the like.
- Examples of the alicyclic polyamine include isophorone diamine, menthane diamine, N-aminoethyl biperazine, and derivatives thereof.
- Examples of aromatic polyamines include m-xylylenediamine, diaminodiphenylmethane, and derivatives thereof.
- Examples of the polyamide include a condensation product of a dicarboxylic acid such as dimer acid and the above-mentioned polyamine.
- Examples of imidazole compounds include imidazole, 2-methylimidazole and derivatives thereof.
- Examples of other polyamines include dicyandiamide and adipic dihydrazide.
- acid anhydrides include monofunctional acid anhydrides such as phthalic anhydride, tetrahydred phthalic anhydride, and derivatives thereof, and bifunctional acid anhydrides such as pyromellitic anhydride, Examples thereof include water benzophenone tetracarboxylic acid and derivatives thereof.
- thiols include 1,3-butanedithiol, 1,4 butanedithiol, 2,3 butanedithionole, 1,2 benzenedithionole, 1,3 benzenedithionole, 1,4 benzenedithiol 1, 10-decanedithiol, 1,2-ethanedithiol, 1,6 hexanedithiol, 1,9-nonanedithiol, etc., epomate QX10 (manufactured by Japan Epoxy Resin Co., Ltd.), epomate QX11 (Japan Epoxy Resin Co., Ltd.) Dithiols such as thiocols; thiocol (made by Toray Fine Chemicals Co., Ltd.), cupcure 3-800 (made by Japan Epoxy Resin Co., Ltd.), and epicure QX40 (made by Japan Epoxy Resin Co., Ltd.) and thiol compounds such as polythiol .
- thiols such
- the anion polymerization initiator generates anion by heat or irradiation with active energy rays, and examples thereof include amines.
- examples of amines include amino group-containing compounds such as dimethylbenzilamine, dimethylaminomethylphenol, 1,8 diazabicyclo [5.4.0] undecene 7, and derivatives thereof; imidazole, 2-methylimidazole, 2 Imidyl compounds such as ethyl 4-methylimidazole, and derivatives thereof A conductor etc. are mentioned.
- the cationic polymerization initiator generates a cation by irradiation with heat or active energy rays, and examples thereof include an aromatic onium salt.
- an aromatic onium salt for example, SbF
- the curing agent (B2) is preferably at least one selected from the group consisting of amines, acid anhydrides, thiols, anion polymerization initiators, and cationic polymerization initiators. This is because these have a high curing rate and are excellent in matrix productivity.
- the amount of the curing agent (B2) used differs depending on whether or not the curing agent (B2) is a cation initiator or a cationic initiator.
- the amount used is usually a percentage of the number of moles of epoxy groups.
- the amount used is usually 0.001% by weight or more, particularly 0.01% by weight, based on the ratio to the resin matrix (B). % Or more, and usually 50% by weight or less, preferably 10% by weight or less. If the amount of curing agent used is too small, the initiator concentration may be too low and the polymerization reaction may take too much time S. On the other hand, if the amount of curing agent used is excessive, continuous ring-opening reaction may not occur as a polymerization reaction.
- any of the various curing agents illustrated above may be used alone, or two or more may be used in any combination and ratio. When two or more kinds of curing agents are used in combination, the total amount thereof should be within the above range.
- the imidazole compound can also function as an anion initiator. It is also possible to function as amines. That is, when an imidazole compound is used in an amount within a preferred range as an anion initiator, it functions as an anion initiator, and when used in an amount within a preferred range as an amine, it functions as an amine. Therefore, considering this point, the usage amount may be selected according to the target function.
- the resin matrix (B) in the present embodiment may contain other components in addition to the above-described epoxy compound (B1) and curing agent (B2) as long as it does not contradict the gist of the present invention.
- additives can be blended in the resin matrix (B) as necessary.
- the additive include a curing accelerator.
- curing accelerators include tertiary amines such as benzyldimethylamine; imidazoles such as 2-ethyl-4-methylimidazole; tertiary phosphines such as triphenylphosphine; tetrabutylphosphonium bromide And quaternary phosphonium salts such as tetramethyl ammonium bromide.
- tertiary amines such as benzyldimethylamine
- imidazoles such as 2-ethyl-4-methylimidazole
- tertiary phosphines such as triphenylphosphine
- tetrabutylphosphonium bromide tetrabutylphosphonium bromide
- quaternary phosphonium salts such as tetramethyl ammonium bromide.
- the use amount of the curing accelerator is usually 0.001% by weight or more, more preferably 0.001% by weight or more, and usually 10% by weight or less, especially 5% by weight or less as a ratio to the resin matrix (B).
- a range is preferred. If too little curing accelerator is used, curing may take too much time. On the other hand, if the amount of the curing accelerator used is too large, it may be difficult to control the curing reaction. When two or more kinds of curing accelerators are used in combination, the total amount thereof should satisfy the above range.
- polystyrene resin examples include polyethylene glycol, polypropylene glycol, poly 1,4 butane diol, poly 1,5-pentane diol, poly 3 -Methinore 1,5-pentanediole, poly 1,6 xanthionole, polyneopentino glycole, diethylene glycol, poly 1,4-cyclohexanediol, poly 1,4-cyclohexanedimethanol, polydecamethylene glycol, polytetra Examples include polyols such as methylene glycol.
- the resin matrix (B) has an alkylene oxide having 4 to 10 carbon atoms, and other than an epoxy compound (B 1) having two or more epoxy groups in one molecule.
- Other epoxy compounds can be used.
- the concentration of hydrophilic functional groups such as hydroxyl groups, isocyanate groups, urethane bonds, urea bonds, etc. contained in the recording layer is reduced as much as possible, and hydrophobic additives are introduced into the recording layer forming composition. It is effective to do.
- a measure for reducing the hydrophilic functional group concentration in the resin matrix for example, a method using a relatively high molecular weight polyisocyanate or polyol; a reaction contained in a polyisocyanate or polyol, etc. A method using a small number of functional groups! /, Or a method using as many unreacted hydroxyl groups or isocyanate groups as possible.
- the concentration of the hydrophilic functional group in the recording layer is 0.5 meq to 50 meq, preferably 1 meq to 25 meq, more preferably 1 meq to 20 mm per lg of the recording layer. Desirable to be in the equivalent range! / ,.
- the kind of photoactive compound (C) used in the composition for forming a volume hologram recording layer of the present embodiment is not particularly limited, and can be appropriately selected from known compounds. Usually, a polymerizable monomer is used.
- polymerizable monomer examples include a cationic polymerizable monomer, an anion polymerizable monomer, and a radical polymerizable monomer.
- Examples of the cationic polymerizable monomer include (1) a compound having an oxysilane ring, (2) styrene and derivatives thereof, (3) burnaphthalene and derivatives thereof, (4) butyl ethers, (5) N butyl compounds, (6)
- Examples include compounds having an oxetane ring. Among them, it is preferable to use a compound having at least an oxetane ring. Further, it is preferable to use a compound having an oxetane ring together with a compound having an oxetane ring.
- Examples of the compound having an oxysilane ring include prepolymers having two or more oxysilane rings in one molecule.
- Examples of such prepolymers include cycloaliphatic polyepoxies, polyglycidyl esters of polybasic acids, polyglycidyl enoate of polyhydric alcohols, polyglycidino ol of polyvalent xylanolene glycolenoles.
- Examples include etherols, aromatic polyol polyglycidyl ethers, aromatic polyol polyglycidyl ethers hydrogenated compounds, urethane polyepoxy compounds, and epoxidized polybutadienes.
- These prepolymers may be used alone or in combination of two or more in any combination and ratio! /.
- styrene and its derivatives examples include styrene, p-methylstyrene, p-methoxystyrene, ⁇ -methylstyrene, ⁇ -methyl- ⁇ -methylstyrene, ⁇ -methylstyrene, ⁇ -methoxy-13-methylstyrene, dibutenebenzene, etc. Is mentioned.
- burnaphthalene and derivatives thereof include 1-bur naphthalenes, ⁇ -methylolene 1-bur naphthalenes, / 3-methyl -1- 1-bur naphthalenes, 4-methyl 1-bin naphthalenes. 4-methoxy-1-burnaphthalene and the like.
- butyl ethers include isobutyl ether, ethyl bulle ether, phenino levinino le etherenore, ⁇ methino levinino levinino le tenole, ⁇ methoxy phenino levinyl ether, ⁇ methyl phenyl And vinyl ether, ⁇ -methylisobutyl vinyl ether, 13-chloro isobutyl butyl ether, and the like.
- bulle compounds include: ⁇ ⁇ Bull carbazole, ⁇ ⁇ ⁇ Bull pyrrolidone, ⁇ Vinino lane donole, ⁇ Vinino repiro mononore, ⁇ Vinino levenothiazine, ⁇ Vinole acetoanilide, ⁇ —Buluetilacetamide, ⁇ vinyl succinimide, ⁇ vinyl phthalimide, ⁇ bull force prolatatam, ⁇ ⁇ burimidazole and the like.
- Examples of the compound having an oxetane ring include various known oxetane compounds described in, for example, JP-A Nos. 2001-220526 and 2001-310937. Any one of the above-exemplified cationic polymerizable monomers may be used alone, or two or more of them may be used in any combination and ratio.
- anion polymerizable monomer examples include hydrocarbon monomers and polar monomers.
- hydrocarbon monomer examples include styrene, ⁇ -methylstyrene, butadiene, isoprene, bullypyridine, buranthracene, and derivatives thereof.
- Examples of polar monomers include methacrylic acid esters such as methyl methacrylate, ethyl acetate and isopropyl methacrylate; acrylate esters such as methyl acrylate and ethyl acrylate; methyl vinyl ketone and isopropyl vinyl.
- Vinyl ketones such as ketone, cyclohexyl vinyl ketone, and phenyl vinyl ketone; isopropenyl ketones such as methyl isopropenyl ketone and phenyl isopropenyl ketone; acrylonitrile, acrylamide, nitroethylene, methylene malonate, cyanoacrylate, And other polar monomers such as vinylidene cyanide.
- Any of the above-exemplified anion polymerizable monomers may be used alone, or two or more may be used in any combination and ratio.
- the radical polymerizable monomer is a compound having one or more ethylenically unsaturated double bonds in one molecule. Examples thereof include (meth) acrylic acid esters, (meth) acrylamides, bulule esters, Examples thereof include styrenes.
- Examples of (meth) acrylic acid esters include methyl (meth) acrylate, ethyl (meth) acrylate, ( ⁇ or i) propyl (meth) acrylate, (ni sec or t) petit (Meth) Athalylate, Aminore (Meth) Athalylate, (Meth) Adamantyl Acrylate, Black-Ethyl (Meth) Athalylate, 2-Hydroxyethyl (Meth) Athalylate, 2-Hydroxypropyl (Meth) Atharily 2-hydroxypentyl (meth) acrylate, cyclohexyl (meth) acrylate, allyl (meth) acrylate, trimethylolpropane mono (meth) acrylate, pentaerythritol mono (meth) acrylate, benzyl (meta) ) Atarylate, Methoxybenzil (meth) atalylate, Black Benzyl
- Examples of (meth) acrylamides include (meth) acrylamide, N-methyl (meth) acrylamide, N-ethyl (meth) acrylamide, N-propyl (meth) acrylamide, N-butyl (meth) acrylamide, N-benzyl (Meth) acrylamide, N hydroxyethyl (meth) acrylolamide, N phenyl (meth) acrylamide, N tolyl (meth) acrylamide, N— (hydroxyphenyl) (meth) acrylamide, N- (sulfamoylphenyl) (meth) ) Acrylamide, N (phenylsulfonyl) (meth) acrylamide, N (tolylsulfonyl) (meth) acrylolamide, N, N dimethyl (meth) acrylamide, N methyl-N-phenyl (meth) acrylamide, N hydroxyethyl N-methyl (meth)
- butyl esters include butyl acetate, butyl butyrate, burbenzoate, benzoate butyl, butyl butyl benzoate, black mouth benzoate butyl, 4-oxyl benzoate butyl, 4 ethyl Examples include butyl benzoate, 4-methyl benzoate, 3-methyl benzoate, 2-methyl benzoate, 4-phenyl benzoate and pivalate.
- styrenes examples include styrene, p-acetyl styrene, p-benzoyl styrene,
- Any one of the above exemplified radical polymerizable monomers may be used alone, or two or more thereof may be used in any combination and ratio.
- any of the above-exemplified cationic polymerizable monomers, anion polymerizable monomers, and radical polymerizable monomers may be used, or two or more of them may be used in combination.
- NCO is the isocyanate group concentration.
- OH is the hydroxyl group concentration.
- the ratio of the photoactive compound (C) to 100 parts by weight of the resin matrix (A) and / or resin matrix (B) is 0.5 parts by weight or more and 100 parts by weight or less, and more preferably 1 part by weight or more and 50 parts by weight or less. It is preferable that If the amount of the photoactive compound used is excessively small, the change in refractive index is small and the recording efficiency may be low. On the other hand, if the amount of photoactive compound used is excessively large, a large amount of unreacted photoactive compound remains, which may cause bleeding out when used as a recording material.
- composition for forming a volume hologram recording layer of the present embodiment is not limited to the above-described resin matrix (A), resin matrix (B), and photoactive compound (C), as long as not departing from the spirit of the present invention. It may contain components.
- composition for volume hologram recording material of the present embodiment is blended with any additive as necessary for controlling the excitation wavelength and excitation energy of the sensitizer, controlling the reaction, improving the characteristics, etc. can do.
- additive include the following compounds.
- Examples of the compound that controls excitation of the sensitizer include a sensitization aid and the like.
- Examples of the compound used for controlling the reaction include a polymerization initiator, a chain transfer agent, a polymerization terminator, a compatibilizing agent, a reaction aid and the like.
- any one of these additives may be used alone, or two or more thereof may be used in any combination and ratio.
- the amount of the additive used is generally 0.001% by weight or more, particularly 0.01% by weight or more, and usually 30% by weight or less, especially 10% by weight, based on the composition for forming a volume hologram recording layer of the present invention.
- the following range is preferable. When two or more additives are used in combination, the total amount thereof should be within the above range.
- examples of suitable additives when the photoactive compound (C) is a radical polymerizable monomer include a polymerization initiator and a sensitizer. These will be described in detail below.
- any known radical photopolymerization initiator can be used. Examples include azo compounds, azide compounds, organic peroxides, organic borates, onium salts, bisimidazole derivatives, titanocene compounds, iodine salts, organic thiol compounds, halogenated hydrocarbon derivatives, and the like. Any one of these may be used alone, or two or more may be used in any combination and ratio. Of these, titanocene compounds and acylphosphine oxide compounds are preferred as polymerization initiators because of the polymerization reaction occurring in the visible light region.
- a titanocene compound is used as a polymerization initiator
- the kind thereof is not particularly limited, but is described in, for example, JP-A-59-152396, JP-A-61-151197, and the like. Can be used by appropriately selecting from various titanocene compounds
- titanocene compounds include dicyclopentadiene Ti-dichloride, dicyclopentageninore Ti-bis fenenore, dicyclopentageninole Ti bis 2, 3, 4, 5, 6 Pentafunoreolopheny 1-inore, dicyclopentageninolet Ti—bis 2, 3, 5, 6 Tetrafunoleololophene 1-inore, dicyclopentageninore —Ti—Bis 2, 4, 6—Trifno Leo Mouth Feni 1-inole, G-cyclopentageninore Ti Bis 2, 6 Gifnoreoro Fennie 1-inole, Gicyclopenta Geninore Ti-bis 1, 2, 4-Difluoro Phenyl-1-yl, di-methylcyclopentadiene Ti-bis 2, 3, 4, 5, 6-Pentafluoropheny 1-yl, dimethylcyclopentaenyl-Ti Ti-bis-1,3 , 5, 6 Tetrafluorophenyl 1-y
- dicyclopentagenyl 1 Ti bis 1 2, 6 difluoro 1- (Pyri 1-yl) pheny 1-yl has absorption up to about 550 nm, so it is an Argon ion laser as a light source. (488 nm) and FD Nd / YAG laser (532 nm) can be used, and since it is highly versatile, it is preferably used as a polymerization initiator.
- acylphosphine oxide compounds include monofunctional initiators that have only one light-excited point in a molecule, and two light-excited points in a molecule 2 Examples include functional initiators.
- Examples of such monofunctional initiators include triphenylphosphine oxide, 2,4,6 trimethylbenzoyldiphenylphosphine oxide, 2,6 dichlorobenzene diphenylphosphine oxide, and the like. It is done.
- bifunctional initiator examples include bis (2, 4, 6 trimethylbenzoyl) phenyl phosphine oxide, bis (2, 6 dimethoxybenzoyl) 2, 4, 4 trimethylpentyl phosphine oxide, bis (2,6 dichlorobenzoyl) -4 propylphenylphosphine euside, bis (2,6 dichlorobenzoyl) 2,5 dimethylphenylphosphine oxide and the like.
- One of these various polymerization initiators may be used alone, or two or more thereof may be used in any combination and ratio! /.
- the amount of the polymerization initiator used is usually 0.1% by weight or more, particularly 0.5% by weight or more, and usually 10% by weight or less, as a ratio to the total solid content of the composition for volume hologram recording materials. Of these, the range of 5% by weight or less is preferable. If the amount of the polymerization initiator used is too small, the amount of radicals generated will be small, so the rate of photopolymerization will be slowed down, and hologram recording Recording sensitivity may be low. On the other hand, if the amount of the polymerization initiator used is excessively large, radicals generated by light irradiation recombine with each other or disproportionate, so that the contribution to photopolymerization is reduced. May decrease. When two or more polymerization initiators are used in combination, the total amount thereof should be within the above range.
- the sensitizer it can be arbitrarily selected from various known sensitizers.
- the type of initiator used is appropriately selected according to the wavelength of the laser beam used for recording.
- sensitizers include JP-A-5-241338, JP-A-2-69, JP-B-2-55446, JP-B-2-30321. And compounds described in JP-A-6-116313 and JP-A-47-2528.
- a sensitizer a colored compound such as a dye as described above is often used to absorb visible and ultraviolet laser light, but the final hologram optical recording medium is colorless.
- a cyanine dye it is preferable to use as a sensitizer.
- cyanine dyes are generally easily decomposed by light
- the cyanine dyes in the volume hologram recording material are decomposed by post-exposure, that is, by leaving them for several hours to several days under room light or sunlight.
- post-exposure that is, by leaving them for several hours to several days under room light or sunlight.
- the amount of the sensitizer is a ratio with respect to the force polymerization initiator that needs to be increased or decreased depending on the thickness of the layer containing the volume hologram recording material of the present invention. 1% by weight or more, usually 10% by weight or less, and preferably 5% by weight or less. If the amount of the sensitizer used is too small, the initiator efficiency may be reduced, and recording may take a long time. On the other hand, if the amount of sensitizer used is excessively large, the absorption of light used for recording and reproduction increases, and it may be difficult to reach the light in the depth direction. When two or more sensitizers are used in combination, the total amount thereof should satisfy the above range.
- plasticizers added for improving the reaction efficiency and adjusting the physical properties of the recording layer, and additives for controlling the water absorption rate of the recording layer can be mixed.
- examples include phthalic acid esters such as dioctyl phthalate, diisonoyl phthalate, diisodecyl phthalate, and diundecyl phthalate; bis (2-ethylhexyl) adipate, diisonoyl adipate, and dibutyl butyl adipate.
- Adipates such as dioctyl sebacate and dibutyl sebacate; phosphates such as tricresyl phosphate; citrates such as tributyl acetyl citrate; trimellitic esters such as trioctyl trimellitic acid ; Epoxidized soybean glycol ester; Over end alkoxylated polyals crisp glycol such as Le like.
- a compound having a hydrophobic structure is preferred.
- examples of such are 1H-perfluorodecane, perfluorododecane, novnoreo oral heptane, 1H-perfluoronore heptane, novoleo oral hexane, 1H perfluoro oral hexane, perfluoro Perfluoro compounds such as octane, nofanolol 2,11-dimethyldodecane, perfluoro-2,7 dimethyloctane, perfluoro-3,7 dimethyloctanoic acid, perfluorodecalin, perfluoro-1,10-decanedicarboxylic acid Fluorine-containing compounds; polyether-modified silicones, methylstyryl-modified silicones, alkyl-modified silicones, fatty acid ester-modified silicones, alkoxy-modified silicones, silicone compounds
- the usage fee for these additives is usually from 0.01% by weight to 50% by weight, preferably from 0.05% by weight to 20% by weight, based on the total solid content of the composition for forming a volume hologram recording layer. It is used in the range of weight percent or less. If the amount added is too small, the water absorption rate may not be reduced sufficiently. If the amount added is excessively large, the transparency of the recording layer tends to decrease, and bleeding out of the additive tends to become noticeable.
- the composition for forming a volume hologram recording layer of the present embodiment is used for a volume hologram recording material.
- a volume hologram recording material for example, characteristics such as low hygroscopicity, excellent storage stability, and excellent compatibility. It can.
- the volume hologram recording material using the composition for forming a volume hologram recording layer of the present embodiment is hereinafter referred to as “volume hologram recording material of the present embodiment”.
- the volume hologram recording material of the present embodiment may be composed of only the volume hologram recording layer forming composition of the present embodiment, or may contain other components! / Yo! / ⁇ .
- Other components are not particularly limited, but examples include various additive agents such as a light dispersant and a coloring material. The content of other components is arbitrary as long as the effects of the present invention are not significantly impaired.
- the volume hologram optical recording medium of the present embodiment includes at least a transparent substrate and a recording layer configured to contain a synthetic resin. There are no restrictions on other specific configurations of the volume hologram optical recording medium of the present embodiment.
- a volume hologram optical recording medium according to an embodiment of the present invention (this may be referred to as “optical recording medium of the present embodiment”) will be described in detail.
- the optical recording medium of the present embodiment is configured to include at least a transparent substrate and a recording layer formed using the volume hologram recording material of the present embodiment described above.
- the optical recording medium of the present embodiment is configured to include other layers as necessary.
- the recording layer is a layer on which information is recorded. Information is usually recorded as a hologram.
- the thickness of the recording layer is not particularly limited and may be appropriately determined in consideration of the recording method and the like. Generally, it is usually at least lrn, preferably at least 10 m, and usually at most lcm, preferably The range is less than 2, OOO ⁇ m. If the recording layer is too thick, the selectivity of each hologram may be lowered during multiplex recording on an optical recording medium, and the degree of multiplex recording may be reduced. If the recording layer is too thin, it is difficult to form the entire recording layer uniformly, and it may be difficult to perform multiplex recording with uniform hologram diffraction efficiency and a high S / N ratio.
- an optical recording medium has a transparent substrate, and a recording layer and other layers are stacked on the transparent substrate to constitute an optical recording medium.
- the transparent substrate has the required strength and durability, any transparent substrate with no particular restrictions on the details thereof can be used.
- the shape of the transparent substrate is not limited, but is usually formed in a flat plate shape or a film shape.
- Examples of the material for the transparent substrate include organic materials such as acrylic, polyethylene terephthalate, polyethylene naphthoate, polycarbonate, polyethylene, polypropylene, vinylmonopolyolefin, polystyrene, and cellulose acetate; and inorganic materials such as glass, silicon, and quartz. It is done. Among these, polycarbonate, acrylic, polyester, amorphous polyolefin, glass and the like are preferable, and polycarbonate, acrylic, amorphous polyolefin, and glass are more preferable.
- a transparent substrate coated with a metal such as gold, silver, or aluminum, or a dielectric such as magnesium fluoride or zirconium oxide may be used.
- the thickness of the transparent substrate is not particularly limited, but it is usually preferably in the range of 0.1 mm or more and 1 mm or less. If the transparent substrate is too thin, the mechanical strength of the optical recording medium may be insufficient and the substrate may be warped. If it is too thick, the amount of transmitted light may be reduced and the cost may be further increased. Processing may be performed. This surface treatment is usually performed to improve the adhesion between the transparent substrate and the recording layer. Examples of the surface treatment include performing a corona discharge treatment on the transparent substrate or forming an undercoat layer in advance on the transparent substrate.
- the composition of the undercoat layer may be a halogenated phenol or a partial Examples include hydrolyzed butyl chloride, butyl acetate copolymer, and polyurethane resin.
- the surface treatment may be performed for purposes other than the improvement of adhesiveness.
- examples include a reflective coating process that forms a reflective coating layer made of a metal such as gold, silver, or aluminum; a dielectric coating process that forms a dielectric layer such as magnesium fluoride or zirconium oxide. Is mentioned. These layers may be formed as a single layer or two or more layers.
- These surface treatments may be provided for the purpose of controlling the gas and moisture permeability of the substrate.
- the storage stability of the medium is improved by reducing the water absorption rate of the recording layer, but the function of suppressing the permeability of gas and moisture to the transparent substrate sandwiching the recording layer is also included. By providing this, the reliability of the medium can be further improved.
- the transparent substrate may be provided only on either the upper side or the lower side of the recording layer of the optical recording medium of the present embodiment, or may be provided on both.
- a transmissive or reflective hologram can be recorded.
- a transparent substrate having reflection characteristics on one side is used, a reflection hologram can be recorded.
- a pattern for data address may be provided on the transparent substrate.
- a pattern may be formed on a reflective layer (described later) or a combination of these may be formed on the transparent substrate itself. Good.
- the optical recording medium of this embodiment may be provided with other layers in addition to the recording layer and the transparent substrate described above.
- other layers include a protective layer, a reflective layer, an antireflection layer (antireflection film), and the like.
- the protective layer is a layer for preventing adverse effects such as a decrease in sensitivity and deterioration of storage stability due to oxygen and moisture.
- the force S can be used to form a layer made of a water-soluble polymer, an organic / inorganic material, etc. as a protective layer.
- the reflective layer is formed when the optical recording medium is configured in a reflective type. Reflective light In the case of a recording medium, the reflective layer may be formed between the transparent substrate and the recording layer, or may be formed on the outer surface of the transparent substrate. It is preferable that
- an antireflection film is provided on the side on which object light and readout light are incident and emitted, or between the recording layer and the transparent substrate. Also good.
- the antireflection film functions to improve the light utilization efficiency and suppress the generation of force and ghost images.
- the optical recording medium manufacturing method of the present embodiment can be manufactured by any method without any particular limitation.
- the volume hologram recording material of the present embodiment can be manufactured by coating a transparent substrate without a solvent and forming a recording layer.
- any coating method can be used. Specific examples include a spray method, a spin coat method, a wire bar method, a dip method, an air knife coating method, a roll coating method, a blade coating method, a doctor roll coating method, and the like.
- the volume hologram recording material of the present embodiment is molded in a mold, or coated on a release film.
- the recording layer can also be formed using a method such as punching a mold.
- the volume hologram recording material of the present embodiment described above may be mixed with a solvent to prepare a coating solution, which may be coated on a transparent substrate and dried to form a recording layer.
- a coating solution which may be coated on a transparent substrate and dried to form a recording layer.
- any coating method can be used. Examples include the same method as the above-described coating method.
- the type of solvent is not particularly limited! Usually, it is preferable to use a material that has sufficient solubility for the components used, gives good coating properties, and does not attack the transparent substrate.
- solvents examples include ketone solvents such as acetone, methyl ethyl ketone, methyl isobutyl ketone, cyclohexanone, and methyl amyl ketone; aromatic solvents such as toluene and xylene; methanol, ethanol, propanol, and n-butanol.
- Alcohol solvents such as diacetone alcohol, ketone alcohol such as 3 hydroxy-3 methyl-2 butanone Solvents: Ether solvents such as tetrahydrofuran and dioxane; Halogen solvents such as dichloromethane, dichloroethane, chloroform, etc .; Cellosolebol solvents such as acetate; propylene glycol solvents such as propylene glycol monomethyl ether, propylene glycol monoethylenoate, propylene glycol monomono butylene ethere, propylene glycol monomethyl ether acetate; ethyl acetate, butyl acetate, acetic acid Amyl, ester solvent of butyl acetate; tetrafluoropropanol, otata fanololopenentanol, hexafnoroleorobutanol, etc.
- Ether solvents such as tetrahydrofuran and dioxane
- Recono solvent High polar solvents such as dimethylformamide, dimethylacetamide, N-methylpyrrolidone, dimethyl sulfoxide; Chain hydrocarbon solvents such as n-hexane, n-octane; Cyclohexane, methylcyclohexane, etc. Or a mixed solvent of these cyclic hydrocarbon solvents.
- solvents may be used alone or in combination of two or more in any combination and ratio.
- the amount of the solvent used is about 1% by weight or more and 1,000% by weight or less.
- the volume hologram recording material of the present embodiment has a small amount of volatile components! /
- the volume hologram recording material of the present embodiment is molded by, for example, an injection molding method or a hot press method. Can be manufactured.
- the molded body when the molded body has sufficient thickness, rigidity, strength, etc., the molded body can be used as it is as the optical recording medium of the present embodiment.
- the resin matrix (A) or the resin matrix (B) described above is molded into a desired shape, and then impregnated with the photoactive compound (C) or other additives, whereby the volume of the present invention is increased.
- a recording layer made of a hologram recording material may be produced.
- the optical recording medium of the present embodiment manufactured by the above procedure can take the form of a self-supporting slab or a disk, and can be used for applications such as a three-dimensional image display device, a diffractive optical element, and a large capacity memory. [0141] [II-5.Recording and playback method]
- Both writing (recording) and reading (reproduction) of information with respect to the optical recording medium of the present embodiment are performed by light irradiation.
- the photoactive compound (C) is a polymerizable monomer
- the light that can cause the polymerization and concentration change is converted into object light. (Also called recording light).
- the object light in order to record information as a volume hologram, the object light is irradiated onto the recording layer together with the reference light so that the object light and the reference light interfere with each other in the recording layer.
- the interference light causes a change in the photoactive compound (C) in the recording layer (for example, when the photoactive compound (C) is a polymerizable monomer, its polymerization and concentration change).
- the interference fringes cause a refractive index difference in the recording layer, and the interference fringes recorded in the recording layer are recorded as holograms on the recording layer.
- the recording layer is irradiated with predetermined reproduction light (usually reference light).
- the irradiated reproduction light is diffracted according to the interference fringes. Since the diffracted light contains the same information as the recording layer, the information recorded on the recording layer can be reproduced by reading the diffracted light with an appropriate detection means.
- the wavelength range of the object light, the reproduction light, and the reference light is arbitrary depending on each application, and may be the visible light region or the ultraviolet region.
- these lights for example, solid lasers such as Noreby, glass, Nd-YAG, Nd-YVO, etc .; GaAs
- Diode lasers such as GaAs and GaN; gas lasers such as helium neon, anoregon, krypton, excimer, and CO; lasers with excellent monochromaticity and directivity, such as dye lasers with dyes.
- the irradiation amounts of the object light, the reproduction light, and the reference light are not limited, and the irradiation amount is arbitrary as long as recording and reproduction are possible. However, if the amount is extremely small, the chemical change of the photoactive compound (C) may be incomplete, and the heat resistance and mechanical properties of the recording layer may not be sufficiently expressed. There is a risk that the layer components (the volume hologram recording material of the present invention) may deteriorate. Therefore, the object light, the reproduction light, and the reference light are usually 0.1 l / cm in accordance with the composition of the volume hologram recording material of the present invention used for forming the recording layer, the type and blending amount of the polymerization initiator, and the like. 2 above, is irradiated at 20j / cm 2 or less.
- Sample bottle 1 is a compound obtained by adding 2-ethylhexanol to a trimer of hexamethylene diisocyanate as polyisocyanate (A1) (isocyanate group content 20. 8%) 5.25 g, photoactive compound (C) as paracumylphenol EO-modified (n 1) talylate 1. l lg, photopolymerization initiator bis (7) 5 — 2, 4-cyclopentagen 1-yl) one bis (2, 6 —Difluoro-1- (1H-pyrrole-1-yl) monophenol) Titanium 0 ⁇ 056 g was weighed and stirred until each component was dissolved.
- sample bottle 1 and the sample bottle 2 were put in a bell jar and degassed in a vacuum for 3 hours, and then the liquids in the sample bottle 1 and the sample bottle 2 were mixed and stirred and mixed, and the bell jar was vacuumed for several minutes. I was degassed.
- the vacuum degassed liquid was poured onto a glass slide on which a 500 m thick Teflon (registered trademark) sheet was placed on the two ends as a spacer, and a slide glass was placed on the glass.
- the recording area was prepared by fixing the periphery with a clip and heating at 60 ° C for 15 hours. Hologram recording was performed using a green laser.
- Example 1 a compound obtained by adding 2-ethylhexanol to a trimer of hexamethylene diisocyanate as polyisocyanate (A1) in sample bottle 1 (isocyanate group content 20. 8%) 5.
- A1 polyisocyanate group content 20. 8%
- C Bisphenol as photoactive compound
- C FEO modified
- sample bottle 2 as a polyol (A2), 9.81 g of polycarbonate diol having a molecular weight of 800 and 0.003 g of dioctyltin dilaurate were weighed and stirred until each component was dissolved.
- Example 2 the same operation as in Example 1 was performed to produce a recording layer.
- Hologram recording was performed using a green laser.
- sample bottle 1 was charged with polyisocyanate (A1) as hexamethylene diisocyanate (2 ⁇ 18 g), photoactive compound (C) as bisphenoxyethanol fluorene diatalylate (1 ⁇ l lg), photopolymerization initiator. as bis (7] 5 - 2, 4-cyclopentadiene-1 - I le) Single-bis (2, 6-Jifuruoro one 3- (1H-pyrrol-one 1-I le) one phenyl) and Chita Niumu 0. 056G Weighed and stirred until each component was dissolved.
- polyisocyanate (A1) as hexamethylene diisocyanate (2 ⁇ 18 g
- photoactive compound (C) as bisphenoxyethanol fluorene diatalylate (1 ⁇ l lg)
- photopolymerization initiator as bis (7] 5 - 2, 4-cyclopentadiene-1 - I le) Single-bis (2, 6-Jifuruoro one 3- (1H-pyrrol
- sample bottle 2 4.50 g of a poly force prolataton triol having a molecular weight of 500 and 0.002 g of dioctyltin dilaurate were weighed as polyol (A2) and stirred until each component was dissolved.
- Example 2 the same operation as in Example 1 was performed to produce a recording layer.
- Hologram recording was performed using a green laser.
- a poly force prolataton triol having a molecular weight of 500 as a polyol (A2) and 0.002 g of dioctyltin dilaurate were weighed and stirred until each component was dissolved. Subsequently, a recording layer was produced in the same manner as in Example 1. Hologram recording was performed using a blue laser. The transmittance of the obtained recording layer at a wavelength of 405 nm was 63%.
- polyisocyanate (A1) a compound obtained by adding 2-ethylhexanol to a trimer of hexamethylene diisocyanate (isocyanate group content 20. 8%) 2.64 g, photoactive Weigh 0.22 g of N-bulu force rubazole as the compound (C) and 0.22 g of bis (2,4,6-trimethylbenzoyl) monophenylphosphine oxide as the photopolymerization initiator, and dissolve each component. Stir until
- a polyol (A2) a trifunctional polypropylene having a molecular weight of 1,000, No. 4.
- 36 g a polyylene glycol, a monolayer, an unchanging series SS-2802 (manufactured by Toray Dow Cowing Co., Ltd.) 0 ⁇ 31 g and dioctyltin dilaurate 0 ⁇ OOlg were weighed and stirred until each component was dissolved.
- sample bottle 2 as a polyol (A2), polypropylene glycol (bifunctional) 3 ⁇ 56 g and dioctyltin dilaurate 0.002 g having a molecular weight of 1,000 were weighed and stirred until each component was dissolved. Subsequently, a recording layer was produced in the same manner as in Example 1. Hologram recording was performed using a blue laser.
- B1 an epoxy compound having two or more epoxy groups in one molecule in a sample bottle 10.
- B2 Sun-Aid SI-60 (manufactured by Sanshin Chemical Co., Ltd.)
- B2 Paracumylphenol EO modified
- n 1 Atarylate 1 ⁇ l lg, as photoactive compound
- C As a photopolymerization initiator, 0.056 g of bis (2,4,6-trimethylbenzoyl) monophenylphosphine oxide was weighed and mixed with stirring until each component was dissolved.
- the mixed liquid onto a glass slide with a Teflon (registered trademark) sheet with a thickness of 500 m on both ends, cover the glass slide on it, and fix the periphery with clips.
- the recording layer was prepared by heating at 60 ° C for 15 hours. Hologram recording was performed using a blue laser.
- Example 1 As in Example 1, 6.96 g of a compound obtained by adding 2-ethylhexanol to a trimer of hexamethylene diisocyanate as a polyisocyanate (A1) in a sample bottle 1 as a photoactive compound (C) , Paracumylphenol EO modified (n 1) Atalylate 1 ⁇ 67g, photopolymerization initiator bis (7) 5 — 2, 4-cyclopentagen 1-yl) bis (2, 6-difluoro 1- (1H-pyrrole-1-yl) monophenyl) titanium 0 ⁇ 083 g was weighed and stirred until each component was dissolved.
- Sample bottle 2 was weighed with polyol (A2) as a polyol (A2) having a molecular weight of 700 g of triol having a polypropylene glycol skeleton of 0.04 g and dioctyltin dilaurate (0.008 g), and stirring until each component was dissolved.
- polyol (A2) as a polyol (A2) having a molecular weight of 700 g of triol having a polypropylene glycol skeleton of 0.04 g and dioctyltin dilaurate (0.008 g)
- Example 2 a recording layer was produced in the same manner as in Example 1. Hologram recording was performed using a green laser.
- a recording layer was prepared in the same manner as in Example 5 except that the silicone compound SS-2802 was not used among the compounds to be mixed in the sample bottle 2. Hologram recording A blue laser was used.
- Example 5 In the operation carried out in Example 5, as an epoxy compound (B1) having two or more epoxy groups in one molecule, polytetramethylene glycol having a molecular weight of 1,000 was replaced with polypropylene glycol, and other than that, A recording layer was prepared in the same manner as in 5. Hologram recording was performed using a blue laser.
- Teflon registered trademark
- the recording layer was produced by covering, fixing the periphery with a clip, and heating at 60 ° C for 15 hours.
- the recording layer obtained immediately after heating was peeled off from the glass, cut to 5 cm ⁇ 5 cm, and then immediately measured for its weight (measured at Wl, 23 ° C., 50% RH). From the weight (W2) measured immediately after being placed in an environment of 60 ° C and 90% RH for 24 hours, the moisture absorption rate (%) is expressed as [(W2) — (WD / W1) X 100 (unit:%) Table 1 shows the measurement results.
- the transparency of the obtained recording layer was judged visually based on the following criteria.
- the measurement was performed by (i) recording writeability immediately after sample preparation, (ii) record writing permission (Shelf Life) after sample moisture absorption (60 ° C, 90% RH, 72 hours), ( iii) Immediately after the sample was written, the recording / reproduction availability (Archival Life) after moisture absorption (60 ° C, 90% RH, 72 hours)! /, I got it.
- Fig. 1 is a diagram showing an outline of an apparatus used for hologram recording.
- S indicates a volume hologram recording material sample
- M1 to M3 indicate mirrors
- PBS indicates a polarization beam splitter
- L1 indicates a laser light source for recording light that emits light having a wavelength of 532 nm
- L2 indicates a laser light source for reproducing light that emits light with a wavelength of 633 nm.
- PD1 and PD2 are photo diodes.
- a Nd: YVO crystal is excited by a diode.
- the two beams were crossed on the recording surface so that the angle between them was 50.00 degrees.
- the bisector of the angle formed by the two beams is perpendicular to the recording surface, and the vibration planes of the electric field vectors of the two beams obtained by the division intersect. Irradiation was performed so as to be perpendicular to the plane containing the book beam.
- the recording layers prepared in Examples 1 to 7 have a low moisture absorption rate and good compatibility.
- hologram recording of a volume hologram optical recording medium having these recording layers (i) whether recording can be performed immediately after sample preparation, (ii) whether recording can be written after moisture absorption (Shelf Life) (iii) Immediately after sample preparation, it was found that good holographic recording was achieved with both recording / reproduction availability (Archival Life) after moisture absorption.
- the volume hologram optical recording medium having the recording layer prepared in Comparative Examples 1 to 3 was able to record (i) hologram recording with or without recording / writing immediately after sample preparation, but (ii) sample moisture absorption It can be seen that the recording / reproduction characteristics were poor with regard to the possibility of subsequent recording / writing and (iii) the possibility of recording / reproducing after the moisture absorption of the written recording immediately after sample preparation.
- composition for forming a volume hologram recording layer to which the present invention is applied and the volume hologram recording material using the composition are preferably used for applications such as a volume hologram optical recording medium.
- FIG. 1 is a diagram showing an outline of an apparatus used for hologram recording.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Holo Graphy (AREA)
- Optical Record Carriers And Manufacture Thereof (AREA)
Description
Claims
Priority Applications (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
US12/440,131 US20100039685A1 (en) | 2006-09-05 | 2007-09-03 | Volume hologram optical recording medium, composition for forming volume hologram recording layer, volume hologram recording material, and volume hologram optical recording method |
EP07806612A EP2063324B1 (en) | 2006-09-05 | 2007-09-03 | Volume hologram optical recording medium, composition for forming volume hologram recording layer, volume hologram recording material, and volume hologram optical recording method |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2006-240368 | 2006-09-05 | ||
JP2006240368 | 2006-09-05 |
Publications (1)
Publication Number | Publication Date |
---|---|
WO2008029765A1 true WO2008029765A1 (fr) | 2008-03-13 |
Family
ID=39157192
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
PCT/JP2007/067139 WO2008029765A1 (fr) | 2006-09-05 | 2007-09-03 | Support d'enregistrement optique d'hologramme volumique, composition pour fabriquer une couche d'enregistrement d'hologramme volumique, matériau d'enregistrement d'hologramme volumique et procédé d'enregistrement optique d'hologramme volumique |
Country Status (6)
Country | Link |
---|---|
US (1) | US20100039685A1 (ja) |
EP (1) | EP2063324B1 (ja) |
KR (1) | KR20090057363A (ja) |
CN (1) | CN101501579A (ja) |
TW (1) | TW200832395A (ja) |
WO (1) | WO2008029765A1 (ja) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2172502A1 (de) | 2008-10-01 | 2010-04-07 | Bayer MaterialScience AG | Polyetherbasierte Polyurethanformulierungen zur Herstellung holografischer Medien |
EP2172503A1 (de) | 2008-10-01 | 2010-04-07 | Bayer MaterialScience AG | Spezielle Polyetherbasierte Polyurethanformulierungen zur Herstellung holografischer Medien |
WO2017104424A1 (ja) * | 2015-12-17 | 2017-06-22 | コニカミノルタ株式会社 | 体積ホログラム製造用感光性組成物、体積ホログラムの製造方法、体積ホログラム及びホログラフィック光学素子 |
WO2024106374A1 (ja) * | 2022-11-14 | 2024-05-23 | 三菱ケミカル株式会社 | ホログラム記録媒体用硬化物の製造方法 |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2010037515A1 (de) * | 2008-10-01 | 2010-04-08 | Bayer Materialscience Ag | Medien für volumenholographische aufzeichnung basierend auf sich selbstentwickelndem polymer |
JP5524218B2 (ja) * | 2008-10-01 | 2014-06-18 | バイエル・マテリアルサイエンス・アクチェンゲゼルシャフト | ホログラフィック媒体製造用のプレポリマー系ポリウレタン配合物 |
TWI489204B (zh) * | 2009-11-03 | 2015-06-21 | Bayer Materialscience Ag | 製造全像媒體之方法 |
ES2511215T3 (es) * | 2012-01-05 | 2014-10-22 | Bayer Intellectual Property Gmbh | Estructura en capas con una capa protectora y una capa de fotopolímero expuesta a radiación |
JP6130122B2 (ja) * | 2012-10-15 | 2017-05-17 | 株式会社ダイセル | 体積ホログラム記録層形成用感光性組成物 |
TWI640428B (zh) * | 2013-02-27 | 2018-11-11 | 拜耳材料科學股份有限公司 | 以丙烯酸酯為基底之保護塗層與黏著劑 |
WO2015063064A1 (de) * | 2013-10-30 | 2015-05-07 | Bayer Materialscience Ag | Verbund umfassend ein substrat und einen photopolymerfilm |
CN107533318B (zh) * | 2015-04-27 | 2021-06-29 | 索尼公司 | 全息记录组合物、全息记录介质和全息记录介质的制造方法 |
WO2019240078A1 (ja) * | 2018-06-11 | 2019-12-19 | 三菱ケミカル株式会社 | ホログラム記録媒体用組成物、ホログラム記録媒体用硬化物、及びホログラム記録媒体 |
US20220119567A1 (en) * | 2019-02-18 | 2022-04-21 | The Regents Of The University Of Colorado, A Body Corporate | Network polymers and methods of making and using same |
Citations (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59152396A (ja) | 1983-02-11 | 1984-08-31 | チバ−ガイギ− アクチエンゲゼルシヤフト | メタロセン,その製造方法およびメタロセンを含む光重合性組成物 |
JPS61151197A (ja) | 1984-12-20 | 1986-07-09 | チバ‐ガイギー アーゲー | チタノセン類およびこれらのチタノセン類を含有する照射重合開始剤 |
JPH0269A (ja) | 1987-07-21 | 1990-01-05 | Mitsubishi Kasei Corp | 光重合性組成物 |
JPH0230321B2 (ja) | 1981-07-28 | 1990-07-05 | Mitsubishi Chem Ind | Hikarijugoseisoseibutsu |
JPH0255446B2 (ja) | 1980-07-14 | 1990-11-27 | Mitsubishi Chem Ind | |
JPH04174886A (ja) * | 1990-11-08 | 1992-06-23 | Canon Inc | 染料ボレート錯体を含有するホログラム記録媒体及び記録方法 |
JPH05241338A (ja) | 1992-02-26 | 1993-09-21 | Mitsubishi Kasei Corp | 光重合性組成物 |
JPH06116313A (ja) | 1992-08-20 | 1994-04-26 | Mitsubishi Kasei Corp | 光重合性組成物 |
JPH09101736A (ja) * | 1995-10-03 | 1997-04-15 | Denso Corp | ホログラムの製造方法 |
WO1998004601A1 (fr) * | 1996-07-30 | 1998-02-05 | Hitachi Chemical Co., Ltd. | Procede pour la preparation d'une resine optique non birefringente et d'elements optiques obtenus au moyen de cette resine |
JP2000010277A (ja) | 1998-06-19 | 2000-01-14 | Mitsubishi Chemicals Corp | 光重合性組成物 |
JP2001220526A (ja) | 2000-02-09 | 2001-08-14 | Brother Ind Ltd | インクジェット記録方式用エネルギー線硬化型組成物 |
JP2001310937A (ja) | 2000-04-27 | 2001-11-06 | Hitachi Chem Co Ltd | 硬化性オキセタン組成物およびその硬化方法ならびにその方法により得られる硬化物 |
JP2002169282A (ja) | 2000-11-29 | 2002-06-14 | Fuji Photo Film Co Ltd | 感光性組成物およびそれを用いた平版印刷用原版 |
JP2002268239A (ja) | 2001-03-06 | 2002-09-18 | Fuji Photo Film Co Ltd | 印刷版の製版方法 |
JP2002362326A (ja) | 2001-04-06 | 2002-12-18 | Asmo Co Ltd | ワイパアーム |
JP2004191938A (ja) | 2002-11-27 | 2004-07-08 | Mitsubishi Chemicals Corp | 青紫色レーザー感光性組成物並びにそれを用いた画像形成材料、画像形成材、及び画像形成方法 |
JP2004198446A (ja) | 2002-04-24 | 2004-07-15 | Mitsubishi Chemicals Corp | 光重合性組成物、並びにそれを用いた画像形成材料、画像形成材、及び画像形成方法 |
JP2004212958A (ja) | 2002-12-17 | 2004-07-29 | Mitsubishi Chemicals Corp | 感光性樹脂組成物、並びにそれを用いた感光性画像形成材料及び感光性画像形成材 |
JP2004252421A (ja) | 2003-01-27 | 2004-09-09 | Mitsubishi Chemicals Corp | 感光性樹脂組成物、並びにそれを用いた感光性画像形成材料及び感光性画像形成材 |
JP2005502918A (ja) | 2001-09-13 | 2005-01-27 | インフェイズ テクノロジーズ インコーポレイテッド | 環境耐性を有するセルフシーリング性光学製品 |
JP2005043862A (ja) | 2003-04-09 | 2005-02-17 | Konica Minolta Medical & Graphic Inc | ホログラフィック記録用組成物、ホログラフィック記録メディア及びその記録方法 |
JP3645480B2 (ja) | 1999-10-26 | 2005-05-11 | ルーセント テクノロジーズ インコーポレーテッド | 改良形のホログラフィ媒体 |
JP2005162415A (ja) | 2003-12-03 | 2005-06-23 | Canon Inc | 画像形成装置 |
WO2005078532A1 (ja) * | 2004-02-13 | 2005-08-25 | Toagosei Co., Ltd. | 体積型ホログラム記録材料および体積ホログラム記録媒体 |
JP3737306B2 (ja) | 1998-03-24 | 2006-01-18 | ルーセント テクノロジーズ インコーポレーテッド | 光学製品およびその製造法 |
JP2006154083A (ja) * | 2004-11-26 | 2006-06-15 | Toshiba Corp | ホログラム記録媒体 |
JP2007241144A (ja) * | 2006-03-10 | 2007-09-20 | Fujifilm Corp | 感光性組成物、並びに光記録媒体及びその製造方法、光記録方法、光記録装置 |
Family Cites Families (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US4963471A (en) * | 1989-07-14 | 1990-10-16 | E. I. Du Pont De Nemours And Company | Holographic photopolymer compositions and elements for refractive index imaging |
US6103454A (en) * | 1998-03-24 | 2000-08-15 | Lucent Technologies Inc. | Recording medium and process for forming medium |
US20030044690A1 (en) * | 2001-06-27 | 2003-03-06 | Imation Corp. | Holographic photopolymer data recording media, method of manufacture and method of holographically reading, recording and storing data |
CN1666294A (zh) * | 2002-05-29 | 2005-09-07 | 英法塞技术公司 | 含有铝盐化合物和不对称丙烯酸酯化合物的全息数据存储介质 |
US6864019B2 (en) * | 2002-06-27 | 2005-03-08 | Imation Corp. | Recording material formulations for holographic media |
WO2004090646A1 (ja) * | 2003-04-09 | 2004-10-21 | Konica Minolta Medical & Graphic, Inc. | ホログラフィック記録メディア及びその記録方法 |
KR20050077027A (ko) * | 2004-01-26 | 2005-07-29 | 닛본 페인트 가부시끼가이샤 | 다층 코팅 필름의 제조 방법 및 다층 코팅 필름 |
JP3914211B2 (ja) * | 2004-03-03 | 2007-05-16 | 株式会社東芝 | ホログラム記録媒体 |
US7736818B2 (en) * | 2004-12-27 | 2010-06-15 | Inphase Technologies, Inc. | Holographic recording medium and method of making it |
TW200830299A (en) * | 2006-10-25 | 2008-07-16 | Mitsubishi Chem Corp | Volume hologram optical recording medium, composition for volume hologram recording layer formation, and volume hologram recording material |
-
2007
- 2007-09-03 US US12/440,131 patent/US20100039685A1/en not_active Abandoned
- 2007-09-03 CN CNA2007800300822A patent/CN101501579A/zh active Pending
- 2007-09-03 EP EP07806612A patent/EP2063324B1/en active Active
- 2007-09-03 WO PCT/JP2007/067139 patent/WO2008029765A1/ja active Application Filing
- 2007-09-03 KR KR1020097001320A patent/KR20090057363A/ko not_active Application Discontinuation
- 2007-09-05 TW TW096132979A patent/TW200832395A/zh unknown
Patent Citations (28)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0255446B2 (ja) | 1980-07-14 | 1990-11-27 | Mitsubishi Chem Ind | |
JPH0230321B2 (ja) | 1981-07-28 | 1990-07-05 | Mitsubishi Chem Ind | Hikarijugoseisoseibutsu |
JPS59152396A (ja) | 1983-02-11 | 1984-08-31 | チバ−ガイギ− アクチエンゲゼルシヤフト | メタロセン,その製造方法およびメタロセンを含む光重合性組成物 |
JPS61151197A (ja) | 1984-12-20 | 1986-07-09 | チバ‐ガイギー アーゲー | チタノセン類およびこれらのチタノセン類を含有する照射重合開始剤 |
JPH0269A (ja) | 1987-07-21 | 1990-01-05 | Mitsubishi Kasei Corp | 光重合性組成物 |
JPH04174886A (ja) * | 1990-11-08 | 1992-06-23 | Canon Inc | 染料ボレート錯体を含有するホログラム記録媒体及び記録方法 |
JPH05241338A (ja) | 1992-02-26 | 1993-09-21 | Mitsubishi Kasei Corp | 光重合性組成物 |
JPH06116313A (ja) | 1992-08-20 | 1994-04-26 | Mitsubishi Kasei Corp | 光重合性組成物 |
JPH09101736A (ja) * | 1995-10-03 | 1997-04-15 | Denso Corp | ホログラムの製造方法 |
WO1998004601A1 (fr) * | 1996-07-30 | 1998-02-05 | Hitachi Chemical Co., Ltd. | Procede pour la preparation d'une resine optique non birefringente et d'elements optiques obtenus au moyen de cette resine |
JP3737306B2 (ja) | 1998-03-24 | 2006-01-18 | ルーセント テクノロジーズ インコーポレーテッド | 光学製品およびその製造法 |
JP2000010277A (ja) | 1998-06-19 | 2000-01-14 | Mitsubishi Chemicals Corp | 光重合性組成物 |
JP3645480B2 (ja) | 1999-10-26 | 2005-05-11 | ルーセント テクノロジーズ インコーポレーテッド | 改良形のホログラフィ媒体 |
JP2001220526A (ja) | 2000-02-09 | 2001-08-14 | Brother Ind Ltd | インクジェット記録方式用エネルギー線硬化型組成物 |
JP2001310937A (ja) | 2000-04-27 | 2001-11-06 | Hitachi Chem Co Ltd | 硬化性オキセタン組成物およびその硬化方法ならびにその方法により得られる硬化物 |
JP2002169282A (ja) | 2000-11-29 | 2002-06-14 | Fuji Photo Film Co Ltd | 感光性組成物およびそれを用いた平版印刷用原版 |
JP2002268239A (ja) | 2001-03-06 | 2002-09-18 | Fuji Photo Film Co Ltd | 印刷版の製版方法 |
JP2002362326A (ja) | 2001-04-06 | 2002-12-18 | Asmo Co Ltd | ワイパアーム |
JP2005502918A (ja) | 2001-09-13 | 2005-01-27 | インフェイズ テクノロジーズ インコーポレイテッド | 環境耐性を有するセルフシーリング性光学製品 |
JP2004198446A (ja) | 2002-04-24 | 2004-07-15 | Mitsubishi Chemicals Corp | 光重合性組成物、並びにそれを用いた画像形成材料、画像形成材、及び画像形成方法 |
JP2004191938A (ja) | 2002-11-27 | 2004-07-08 | Mitsubishi Chemicals Corp | 青紫色レーザー感光性組成物並びにそれを用いた画像形成材料、画像形成材、及び画像形成方法 |
JP2004212958A (ja) | 2002-12-17 | 2004-07-29 | Mitsubishi Chemicals Corp | 感光性樹脂組成物、並びにそれを用いた感光性画像形成材料及び感光性画像形成材 |
JP2004252421A (ja) | 2003-01-27 | 2004-09-09 | Mitsubishi Chemicals Corp | 感光性樹脂組成物、並びにそれを用いた感光性画像形成材料及び感光性画像形成材 |
JP2005043862A (ja) | 2003-04-09 | 2005-02-17 | Konica Minolta Medical & Graphic Inc | ホログラフィック記録用組成物、ホログラフィック記録メディア及びその記録方法 |
JP2005162415A (ja) | 2003-12-03 | 2005-06-23 | Canon Inc | 画像形成装置 |
WO2005078532A1 (ja) * | 2004-02-13 | 2005-08-25 | Toagosei Co., Ltd. | 体積型ホログラム記録材料および体積ホログラム記録媒体 |
JP2006154083A (ja) * | 2004-11-26 | 2006-06-15 | Toshiba Corp | ホログラム記録媒体 |
JP2007241144A (ja) * | 2006-03-10 | 2007-09-20 | Fujifilm Corp | 感光性組成物、並びに光記録媒体及びその製造方法、光記録方法、光記録装置 |
Non-Patent Citations (2)
Title |
---|
JUNPEI TUJIUCHI: "HOLOGRAPHIC DISPLAY", SANGYO TOSHO |
See also references of EP2063324A4 * |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2172502A1 (de) | 2008-10-01 | 2010-04-07 | Bayer MaterialScience AG | Polyetherbasierte Polyurethanformulierungen zur Herstellung holografischer Medien |
EP2172503A1 (de) | 2008-10-01 | 2010-04-07 | Bayer MaterialScience AG | Spezielle Polyetherbasierte Polyurethanformulierungen zur Herstellung holografischer Medien |
US8361678B2 (en) | 2008-10-01 | 2013-01-29 | Bayer Materialscience Ag | Special polyether-based polyurethane formulations for the production of holographic media |
WO2017104424A1 (ja) * | 2015-12-17 | 2017-06-22 | コニカミノルタ株式会社 | 体積ホログラム製造用感光性組成物、体積ホログラムの製造方法、体積ホログラム及びホログラフィック光学素子 |
WO2024106374A1 (ja) * | 2022-11-14 | 2024-05-23 | 三菱ケミカル株式会社 | ホログラム記録媒体用硬化物の製造方法 |
Also Published As
Publication number | Publication date |
---|---|
KR20090057363A (ko) | 2009-06-05 |
US20100039685A1 (en) | 2010-02-18 |
EP2063324A4 (en) | 2011-01-12 |
EP2063324A1 (en) | 2009-05-27 |
CN101501579A (zh) | 2009-08-05 |
TW200832395A (en) | 2008-08-01 |
EP2063324B1 (en) | 2012-03-21 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
WO2008029765A1 (fr) | Support d'enregistrement optique d'hologramme volumique, composition pour fabriquer une couche d'enregistrement d'hologramme volumique, matériau d'enregistrement d'hologramme volumique et procédé d'enregistrement optique d'hologramme volumique | |
JP5923041B2 (ja) | ホログラフィックフィルムの製造方法 | |
JP5495238B2 (ja) | ホログラフィ用途用の有利な記録媒体 | |
JP2008139768A (ja) | ホログラム光記録媒体 | |
EP1729184A1 (en) | Volume hologram recording material and volume hologram recording medium | |
JP2010018606A (ja) | 光反応性組成物、光学材料、ホログラム記録層形成用組成物、ホログラム記録材料およびホログラム記録媒体 | |
US20080311483A1 (en) | Radiation-Crosslinking And Thermally Crosslinking PU Systems-Based On Poly(epsilon-Caprolactone) Polyester Polyols | |
KR20100015466A (ko) | 이소시아네이트-반응성 블록 공중합체를 기재로 하는 방사선-가교 및 열 가교 pu 시스템 | |
US20070172742A1 (en) | Volume hologram recording material and volume hologram recording medium | |
JP2006154083A (ja) | ホログラム記録媒体 | |
CN110494456B (zh) | 感光聚合物组合物 | |
JP5493262B2 (ja) | 体積ホログラム光記録媒体、体積ホログラム記録層形成用組成物及び体積ホログラム記録材料 | |
JP5145825B2 (ja) | 体積ホログラム光記録媒体、体積ホログラム記録層形成用組成物、体積ホログラム記録材料及び体積ホログラム光記録方法 | |
WO2008050835A1 (en) | Volume hologram optical recording medium, composition for volume hologram recording layer formation, and volume hologram recording material | |
JP4305576B2 (ja) | 光ディスク用紫外線硬化型組成物および光ディスク | |
JP2016206488A (ja) | ホログラム記録媒体用組成物及びこれを用いたホログラム記録媒体、並びに化合物 | |
JP2009186758A (ja) | ホログラム記録媒体および化合物 | |
JP5310307B2 (ja) | 光記録層形成用組成物およびそれを用いた光記録媒体 | |
JP6677330B2 (ja) | カルバゾール化合物 | |
JP4765791B2 (ja) | 体積ホログラム記録材料用組成物、並びにそれを用いた体積ホログラム記録材料、体積ホログラム光記録媒体及び体積ホログラム光記録方法 | |
WO2023074790A1 (ja) | 光学素子の製造方法 | |
WO2024005141A1 (ja) | ホログラム記録媒体用組成物 | |
JP5098783B2 (ja) | 光ディスク用紫外線硬化型組成物および光ディスク | |
JP2024071169A (ja) | 光学素子の製造方法 | |
TW202422248A (zh) | 光學元件之製造方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
WWE | Wipo information: entry into national phase |
Ref document number: 200780030082.2 Country of ref document: CN |
|
121 | Ep: the epo has been informed by wipo that ep was designated in this application |
Ref document number: 07806612 Country of ref document: EP Kind code of ref document: A1 |
|
WWE | Wipo information: entry into national phase |
Ref document number: 1020097001320 Country of ref document: KR |
|
WWE | Wipo information: entry into national phase |
Ref document number: 2007806612 Country of ref document: EP |
|
WWE | Wipo information: entry into national phase |
Ref document number: 12440131 Country of ref document: US |
|
NENP | Non-entry into the national phase |
Ref country code: DE |