WO2006050248A2 - Aqueous-based method for producing ultra-fine metal powders - Google Patents
Aqueous-based method for producing ultra-fine metal powders Download PDFInfo
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- WO2006050248A2 WO2006050248A2 PCT/US2005/039237 US2005039237W WO2006050248A2 WO 2006050248 A2 WO2006050248 A2 WO 2006050248A2 US 2005039237 W US2005039237 W US 2005039237W WO 2006050248 A2 WO2006050248 A2 WO 2006050248A2
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- metallic particles
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F9/00—Making metallic powder or suspensions thereof
- B22F9/16—Making metallic powder or suspensions thereof using chemical processes
- B22F9/18—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds
- B22F9/24—Making metallic powder or suspensions thereof using chemical processes with reduction of metal compounds starting from liquid metal compounds, e.g. solutions
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F1/00—Metallic powder; Treatment of metallic powder, e.g. to facilitate working or to improve properties
- B22F1/05—Metallic powder characterised by the size or surface area of the particles
- B22F1/054—Nanosized particles
- B22F1/0545—Dispersions or suspensions of nanosized particles
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F2998/00—Supplementary information concerning processes or compositions relating to powder metallurgy
Definitions
- the present invention relates generally to ultra-fine metallic compositions and methods of making the same.
- the present invention further relates to methods of coating various substrates with ultra-fine metallic compositions.
- Ultra-fine metallic particles have many unique physical and chemical characteristics, which make them ideal materials for a variety of applications, such as electronics, catalysis, metallurgy, and decorations.
- the methods based on the chemical precipitation in solutions provide several advantages, e.g., low manufacturing cost and a very good control of the mechanism of metal particles formation.
- Others in the art have successfully prepared micron and submicron-size metallic powders of Co, Cu, Ni, Pb, and Ag using chemical-based techniques, such as the ones based on the reduction in alcohols or polyols.
- U.S. Patent No. 4,539,041 discusses a method for producing micrometer-size metallic particles by using polyols to convert various metallic compounds into metal powders.
- U.S. Pat. Nos. 3,620,713 and3,620,714 to Short disclose a method for making platinum and platinum alloy powders for electronic components, having an average particle size of from 0.5 to 2 ⁇ m, in which a platinum ammonia complex is freshly precipitated with ammonium hydroxide and then reduced with hydrazine to produce the metal.
- U.S. Pat. Nos. 3,620,713 and3,620,714 to Short disclose a method for making platinum and platinum alloy powders for electronic components, having an average particle size of from 0.5 to 2 ⁇ m, in which a platinum ammonia complex is freshly precipitated with ammonium hydroxide and then reduced with hydrazine to produce the metal.
- 4,456,473 and 4,456,474 to Jost disclose a similar process in which a silver ammonium complex is reduced in water with hydrazine, to produce particles with diameters averaging 0.6 to 5 ⁇ m.
- U.S. Pat. No. 5,413,617 to Lin et al. also discloses reduction of a silver ammonium complex with aqueous hydrazine under a particular temperature regime to give high surface area powder of undisclosed particle size. According to U.S. Pat. No.
- the present invention provides a method for forming compositions having a plurality of ultra-fine metallic particles, and the metallic composition produced therewith, where the plurality of ultra-fine metallic particles is obtained in accordance with a process including:
- the metal-ammonia complex is the complex of ammonia with a transitional metal or a noble metal, e.g., Cu, Pd, and Ag, formed by reacting a solution comprising a metal salt with ammonium hydroxide or ammonia.
- the reducing agent is a saccharide, such as D-glucose.
- the stabilizing agent is a water-soluble resin (e.g., a natural occurring, synthetic, or semi ⁇ synthetic water-soluble resin) or gum arabic. The gum arabic may be removed during the isolation of the metallic particles through hydrolysis.
- the plurality of ultra-fine metallic particles may have at least one desirable feature, such as tight size distribution, low degree of agglomeration, high degree of crystallinity, and the ability to be fully re-dispersed into a liquid (e.g. an aqueous solution) to form a stable dispersion.
- a liquid e.g. an aqueous solution
- the present invention provides a substrate coated with the plurality of ultra-fine metallic particles obtained in accordance with the method disclosed herein.
- Figure 1 depicts an experimental set-up used in the synthesis of ultra-fine silver particles.
- Figure 2 shows the FE-SEM images of ultra-fine silver particles produced using the method of the present invention, (a) 198.7 g AgNO 3 and flow rate at 8 ml/min; (b) 382 g AgNO 3 and flow rate at 8 ml/min; and (c) 382 g AgNO 3 and flow rate at 30 ml/min. Images were acquired using a FE-SEM at two magnifications (25,000 and 100,000).
- Figure 3 illustrates the particle size distribution (PSD) of silver particles as number (%) (a) and volume (%) (b), obtained from 382 g AgNO 3 at a flow rate of the metallic precursor solution of 30 ml/min.
- Figure 4 shows the X-ray diffraction patterns of silver particles shown in Figure
- the present invention generally provides a simple and cost-effective chemical- based method for producing highly dispersed ultra-fine metallic powders.
- the present invention also provides ultra-fine metallic particles having at least one desirable feature, such as tight size distribution, low degree of agglomeration, high degree of crystallinity, and the ability to re- disperse fully into a liquid (e.g. an aqueous solution) to form stable dispersions.
- the present invention provides a method for producing metallic powders, and also the metallic powders produced thereby, that comprises the steps of (a) providing a reducing solution containing a reducing agent and a stabilizing agent; (b) providing an aqueous solution containing a metal-ammonia complex; (c) forming a reaction mixture containing the reducing solution and the aqueous solution; (d) maintaining the reaction mixture under a suitable conditions (e.g. pH and temperature) for a time sufficient to reduce the metal-ammonia complex to metallic particles; and optionally, (e) isolating the metallic particles.
- a suitable conditions e.g. pH and temperature
- the process of the present invention may be used to manufacture ultra-fine particles of various metals, such as Ag, Au, Co, Cr, Cu, Fe, Ir, Mo, Ni, Nb, Os, Pd, Pt, Re, Rh, Ru, Sn, Ta, Ti, V, and W, and alloys or composites containing these metals.
- the metal-ammonia complex may be mixed with a reducing composition or agent, which converts the metal ions to ultra-fine metal particles under various reaction conditions.
- the metal-ammonia complex used in the process of the present invention may be the complex of ammonium with those transition metals and noble metals, such as, Ag, Au, Co, Cu, In, Ir, Ni, Nb, Os, Pd, Pt, Re, Rh, and Ru, and combinations thereof, that are amenable to being produced by reduction of a precursor compound with a reducing sugar.
- the metal-ammonia complex may be obtained by reacting a solution containing a metal salt with ammonium hydroxide or ammonia. For example, 198.7 g AgNO 3 may be dissolved in 234 ml deionized water.
- reducing composition generally includes any reducing substance, and a combination thereof, which is capable of reducing metal ions to metallic particles, such as, without limitation, aldehydes, aldose, hydrazine hydrate, and especially reducing saccharides (including monosaccharides, disaccharides, oligosaccharides, and polysaccarides).
- reducing saccharides include, but are not limited to, ascorbic acid, glyceraldehyde, erythrose, threose, ribose, arabinose, xylose, lyxose, allose, altrose, glucose, dextrose, mannose, gulose, idose, galactose, talose, lactose, maltose, isomaltose, cellobiose, and starch.
- the nature of the reducing species and their composition in the process of the present invention may be dependent upon the particular metal being produced.
- stabilizing composition generally includes any stabilizing substance, such as, without limitation, water soluble resins (including, e.g., naturally occurring, synthetic, and semi-synthetic water soluble resins), gum arabic, polymers, polysaccharides, glycoproteins, nucleic acids, various salts of naphthalene sulphonic-formaldehyde co-polymers, and a combination thereof, which is capable of dispersing and stabilizing the newly formed ultra-fine metallic particles in the reaction mixture and thus preventing undesirable aggregation of these particles such that the size of the resulting metallic particles is less than about 10 ⁇ m, preferably, less than about 1 ⁇ m, and more preferably, less than about 100 nm.
- water soluble resins including, e.g., naturally occurring, synthetic, and semi-synthetic water soluble resins
- gum arabic polymers
- polysaccharides glycoproteins
- nucleic acids include various salts of naphthalene sulphonic-formalde
- ultra- fine particles generally includes particles having diameters of less than about 10 ⁇ m, preferably, less than about 1,000 nm, and more preferably, less than about 500 nm, and even more preferably, less than about 100 nm.
- the stabilizing composition used in the process of the present invention may be commanded by the particular reaction.
- suitable stabilizing agents include, without limitation, gum arabic, cellulose derivatives (e.g., carboxymethyl cellulose, carboxyethyl cellulose, methyl cellulose, etc.) and modified products thereof, polyvinyl alcohol and derivatives thereof, polyvinyl pyrrolidone, polyacrylamide and copolymers thereof, acrylic acid copolymers, vinylmethyl ether-maleic anhydride copolymers, vinyl acetate-maleic anhydride copolymers, various salts of naphthalene sulphonic-formaldehyde co-polymers, styrene-maleic anhydride copolymers, calcined dextrin, acid-decomposed dextrin, acid-decomposed etherified dextrin, agarose, and salmon sperm DNA.
- the stabilizing agent may be gum arabic.
- the stabilizing agent may be gum arabic.
- the stabilizing agent such as gum arabic
- the stabilizing agent may be removed after the reaction.
- a number of protocols for removing the stabilizing agent are known in the art, such as, acid, alkaline, and/or enzymatic hydrolysis.
- gum arabic may be removed from the reaction mixture after the reaction through alkaline hydrolysis.
- the hydrolysis may be performed for extended time at high temperature (e.g. between about 70 0 C and about 100 0 C, or between about 80 0 C and about 90 0 C, or between about 82 0 C and about 88 0 C) and high pH (e.g. pH 1 1.5).
- the hydrolysis of the gum may generally be performed for about 0.2 to 10 hours, or about 1 to 5 hours, or about 2 to 3 hours.
- the resulting ultra-fine metal particles may be isolated following standard protocols known in the art, such as by precipitation, filtration, and centrifugation.
- the particles may further be washed, such as by using methanol or ethanol, and dried, such as by air, N 2 , or vacuum.
- the ultra-fine metallic particles may also have at least one desirable feature, such as, tight size distribution, low degree of agglomeration, high degree of crystallinity, ability to re- disperse fully into a liquid (e.g. an aqueous solution) to form stable dispersion, or a combination thereof.
- the system of the present invention produces metallic powders that include ultra-fine metallic particles that have a tight size distribution.
- the breadth of the size distribution generally refers to the degree of variation in the diameter of the ultra-fine metallic particles in a metallic composition.
- the ultra-fine metallic particles are deemed to have a tight size distribution when the diameters of at least about 80%, preferably, at least about 85%, more preferably, at least about 95%, and most preferably 99-100% of the ultra-fine metallic particles of the present invention are within the range of N ⁇ 15% N, where N is the average diameter of the ultra-fine metallic particles.
- the diameters of the ultra-fine metallic particles may be measured by a number of techniques, such as by electron microscopy with a scanning electron microscope (e.g. field emission scanning electron microscope).
- the metallic powders produced in accordance with the present invention may also include ultra-fine metallic particles that have a low degree of agglomeration, as illustrated in Figure 3.
- the degree of agglomeration may be expressed using the index of agglomeration I agg i, which is the ratio between the average particle size distribution of the metallic particles ("PSD50%”) and the average diameter of the particles.
- the average particle size distribution may be determined by any methods known in the art, including, but not limited to, dynamic light scattering (DLS), laser diffraction, and sedimentation methods, while the average particle size may be determined by averaging the diameter of the individual ultra-fine metallic particles obtained by, e.g., electron microscopy.
- An I agg i value of 1.0 indicates a complete lack of agglomeration, while an increase in I agg ⁇ value indicates an increase in the degree of aggregation.
- the powders of ultra- fine metallic particles of the present invention have an I agg i value of about 1.2 or less.
- the metallic powders produced in accordance with the present invention may also include ultra-fine metallic particles that have a high degree of crystallinity.
- degree of crystal Unity generally refers to the ratio between the size of the crystallites in the metallic powder and the diameter of the metallic particles.
- the size of the constituent crystallites may be deduced from XRD measurements using the Sherrer's equation, while the particle size may be determined by electron microscopy. A larger ratio of the size of the crystallites in comparison to the diameter of the metallic particles indicates an increased degree of crystallinity and a lower internal grain boundary surface.
- the ultra-fine metallic particles have a high degree of crystallinity if at least about 80%, preferably, at least about 85%, more preferably, at least about 90-95%, and even more preferably, about 100% of the ultra-fine metallic particles of the present invention are highly crystalline.
- the high degree of crystallinity is reflected by the visible splitting of the peaks corresponding to the (220), (31 1), and (222) reflections in the XRD spectrum (see Figure 4).
- the ultra-fine metallic particles produced in accordance with the present invention may form a free flowing dry powder in which the majority of the individual particles may not be strongly attached to each other and may be readily re-dispersed in a liquid of choice.
- the ultra-fine metallic particles forms stable dispersion when re-dispersed into a liquid, such as water, or an aqueous solution, where the majority of the individual particles may move substantially freely in the liquid in which they are dispersed.
- a liquid such as water, or an aqueous solution
- the particle dispersion may be stable for at least one week. In another embodiment, the particle dispersion may be stable for about 12 weeks.
- the present invention further provides a substrate coated with a plurality of ultra- fine metallic particles, where the plurality of ultra-fine metallic particles have at least one desired feature, such as, tight size distribution, a low degree of agglomeration, a high degree of crystallinity, and oxidation resistance and are prepared by the methods described herein.
- the substrate is coated by immersion in the reaction mixture in which the ultra-fine metallic particles are produced.
- substrate includes, without limitation, metallic subjects (e.g., metallic particles, flakes, tubes, and sheets), plastic materials, ceramic subjects, fibers, films, glasses, polymers, organic materials (e.g.
- the ultra-fine metallic particles may be the metallic particles of various metals, preferably, Cu, Pd, and Ag.
- DI deionised
- AgNO 3 (198.7 g) was dissolved in 234 ml DI water in a 2-1 glass beaker. After the silver nitrate was completely dissolved, 195 ml ammonium hydroxide was added with stirring, followed by the addition of 291 ml DI water to reach a final volume of 720 ml.
- METHOD A The reduction process was conducted by pumping the silver ammonium solution into the reducing solution at a flow rate of 8 ml/min using a peristaltic pump. When the addition of the silver complex solution was completed, the temperature was brought to 80 0 C. The entire process was conducted under continuous stirring (1700 rpm).
- METHOD B The D-glucose was separately dissolved in 720 ml water. The volume of the gum arabic solution was correspondingly reduced, and adjusted to a pH between 9 and 13 with sodium hydroxide.
- the reduction process was conducted by simultaneously pumping the silver ammonium solution and the D-glucose solution into the gum arabic solution at 8 ml/min, while maintaining the pH by the addition of sodium hydroxide solution as needed.
- the temperature was brought to 80 0 C.
- the entire process was conducted under continuous stirring (1700 rpm).
- a volume of 500 ml DI water was heated to 70 0 C in 2-1 glass beaker. When the temperature reached 70 0 C, 10 g gum arabic was slowly added into the water and dissolved by stirring the solution. 100 g of D-glucose were then added to the solution and the mixture was stirred at 1700 rpm for 5 minutes. The pH of solution was adjusted to 10.5 with 10.0 N NaOH.
- the reducing reaction was conducted by pumping the palladium ammonium solution into the reducing solution at a flow rate of 5 ml/min using a peristaltic pump. When the addition of the palladium complex solution was complete, the temperature was brought to 80 0 C. The process was conducted under continuous stirring (1700 rpm).
- a volume of 500 ml DI water was heated to 70 0 C in 2-1 glass beaker. When the temperature reached 70 0 C, 25 g gum Arabic was slowly added into the water and dissolved by stirring the solution with a stirring propeller at 1700 rpm for 55 minutes. 100 g of D-glucose were then added to the solution and the mixture was stirred at 1700 rpm for 5 minutes. The pH of solution was adjusted at 10.5 with 10.0 N NaOH.
- cupric nitrate (Cu(NO 3 ) 2 VA H 2 O) were dissolved in 50 ml DI water in a
- the reduction process was conducted by pumping the cupric ammonium solution into the reducing solution at a flow rate of 5 ml/min using a peristaltic pump. When the addition of the cupric complex solution was complete, the temperature was brought to 80 0 C. The process was conducted with continuous stirring (1700 rpm). The remaining steps are similar to those of Example 1.
- Example 1 The experimental conditions and results of Example 1 (Method A) are summarized in Table I. Method B gave somewhat smaller particles; at pH 12 particles with an average diameter of 40 nm were obtained.
Abstract
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Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
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CA002585644A CA2585644A1 (en) | 2004-10-29 | 2005-10-31 | Aqueous-based method for producing ultra-fine metal powders |
EP05815225A EP1804987A2 (en) | 2004-10-29 | 2005-10-31 | Aqueous-based method for producing ultra-fine metal powders |
JP2007539239A JP2008519156A (en) | 2004-10-29 | 2005-10-31 | Preparation of ultrafine metal powder in aqueous solution |
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US10/978,153 | 2004-10-29 | ||
US10/978,153 US8470066B2 (en) | 2004-10-29 | 2004-10-29 | Aqueous-based method for producing ultra-fine metal powders |
US10/981,074 US20060090598A1 (en) | 2004-11-03 | 2004-11-03 | Aqueous-based method for producing ultra-fine silver powders |
US10/981,074 | 2004-11-03 |
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WO2006050248A2 true WO2006050248A2 (en) | 2006-05-11 |
WO2006050248A3 WO2006050248A3 (en) | 2009-04-09 |
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PCT/US2005/039237 WO2006050248A2 (en) | 2004-10-29 | 2005-10-31 | Aqueous-based method for producing ultra-fine metal powders |
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EP (1) | EP1804987A2 (en) |
JP (1) | JP2008519156A (en) |
KR (1) | KR20070083988A (en) |
CA (1) | CA2585644A1 (en) |
WO (1) | WO2006050248A2 (en) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009131603A2 (en) * | 2008-01-09 | 2009-10-29 | Umicore Ag & Co Kg | Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions |
JP2009256779A (en) * | 2008-03-27 | 2009-11-05 | Furukawa Electric Co Ltd:The | Method for producing copper fine particle-dispersed aqueous solution, and method for storing the copper fine particle-dispersed aqueous solution |
US9731263B2 (en) | 2009-03-02 | 2017-08-15 | Colorobbia Italia S.P.A. | Process for preparing stable suspensions of metal nanoparticles and the stable colloidal suspensions obtained thereby |
CN114603131A (en) * | 2022-03-07 | 2022-06-10 | 石河子大学 | Preparation method of nano-silver sol |
Families Citing this family (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP5306966B2 (en) * | 2008-10-27 | 2013-10-02 | 古河電気工業株式会社 | Method for producing copper fine particle dispersed aqueous solution and method for storing copper fine particle dispersed aqueous solution |
JP5820202B2 (en) * | 2010-09-30 | 2015-11-24 | Dowaエレクトロニクス株式会社 | Copper powder for conductive paste and method for producing the same |
KR102588589B1 (en) * | 2015-05-18 | 2023-10-16 | 히데미 카키하라 | Antibacterial substances and liquid antibacterial agents and methods for producing liquid antibacterial agents |
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US3708313A (en) * | 1971-05-21 | 1973-01-02 | Du Pont | Metalizing compositions |
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JPS60248803A (en) * | 1984-05-22 | 1985-12-09 | Fukuda Kinzoku Hakufun Kogyo Kk | Production of silver powder |
JPS61276907A (en) * | 1985-05-31 | 1986-12-06 | Tanaka Kikinzoku Kogyo Kk | Production of fine silver particle |
JPS63274706A (en) * | 1987-05-02 | 1988-11-11 | Nippon Chem Ind Co Ltd:The | Production of metallic fine powder |
JPH06299211A (en) * | 1993-04-14 | 1994-10-25 | Mitsubishi Materials Corp | Production of oxidation resistant palladium powder |
JPH1143708A (en) * | 1997-07-23 | 1999-02-16 | Murata Mfg Co Ltd | Production of silver-palladium powder |
JP4569727B2 (en) * | 2000-09-08 | 2010-10-27 | Dowaエレクトロニクス株式会社 | Silver powder and method for producing the same |
JP4627376B2 (en) * | 2001-02-20 | 2011-02-09 | バンドー化学株式会社 | Metal colloid liquid and method for producing the same |
JP2002363618A (en) * | 2001-06-11 | 2002-12-18 | Sumitomo Electric Ind Ltd | Copper ultrafine grain and production method therefor |
JP4144856B2 (en) * | 2002-11-29 | 2008-09-03 | 三井金属鉱業株式会社 | Method for producing silver powder comprising ultrathin plate-like silver particles |
JP2004241294A (en) * | 2003-02-07 | 2004-08-26 | Toppan Forms Co Ltd | Conductive coating liquid containing metal nano fine particle and conductive metal foil |
JP2004285454A (en) * | 2003-03-25 | 2004-10-14 | Konica Minolta Holdings Inc | Homogeneous fine particle of inorganic metal, and manufacturing method |
-
2005
- 2005-10-31 KR KR1020077010223A patent/KR20070083988A/en not_active Application Discontinuation
- 2005-10-31 JP JP2007539239A patent/JP2008519156A/en active Pending
- 2005-10-31 EP EP05815225A patent/EP1804987A2/en not_active Withdrawn
- 2005-10-31 CA CA002585644A patent/CA2585644A1/en not_active Abandoned
- 2005-10-31 WO PCT/US2005/039237 patent/WO2006050248A2/en active Application Filing
Patent Citations (1)
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US3708313A (en) * | 1971-05-21 | 1973-01-02 | Du Pont | Metalizing compositions |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2009131603A2 (en) * | 2008-01-09 | 2009-10-29 | Umicore Ag & Co Kg | Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions |
WO2009131603A3 (en) * | 2008-01-09 | 2010-04-01 | Umicore Ag & Co Kg | Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions |
JP2011511885A (en) * | 2008-01-09 | 2011-04-14 | ユミコア・アクチエンゲゼルシャフト・ウント・コムパニー・コマンディットゲゼルシャフト | Method for producing noble metal nanoparticle dispersion and method for isolating such nanoparticles from said dispersion |
US8529963B2 (en) | 2008-01-09 | 2013-09-10 | Umicore Ag & Co. Kg | Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from said dispersions |
CN101939091B (en) * | 2008-01-09 | 2013-11-20 | 尤米科尔股份公司及两合公司 | Method for preparing dispersions of precious metal nanoparticles and for isolating such nanoparticles from the dispersions |
JP2009256779A (en) * | 2008-03-27 | 2009-11-05 | Furukawa Electric Co Ltd:The | Method for producing copper fine particle-dispersed aqueous solution, and method for storing the copper fine particle-dispersed aqueous solution |
US9731263B2 (en) | 2009-03-02 | 2017-08-15 | Colorobbia Italia S.P.A. | Process for preparing stable suspensions of metal nanoparticles and the stable colloidal suspensions obtained thereby |
CN114603131A (en) * | 2022-03-07 | 2022-06-10 | 石河子大学 | Preparation method of nano-silver sol |
Also Published As
Publication number | Publication date |
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JP2008519156A (en) | 2008-06-05 |
WO2006050248A3 (en) | 2009-04-09 |
EP1804987A2 (en) | 2007-07-11 |
CA2585644A1 (en) | 2006-05-11 |
KR20070083988A (en) | 2007-08-24 |
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