US3810793A - Process of manufacturing a reinforcing bar steel for prestressed concrete - Google Patents

Process of manufacturing a reinforcing bar steel for prestressed concrete Download PDF

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Publication number
US3810793A
US3810793A US00264669A US26466972A US3810793A US 3810793 A US3810793 A US 3810793A US 00264669 A US00264669 A US 00264669A US 26466972 A US26466972 A US 26466972A US 3810793 A US3810793 A US 3810793A
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United States
Prior art keywords
steel
weight percent
tempering
temperature
prestressed concrete
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Expired - Lifetime
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US00264669A
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English (en)
Inventor
W Heller
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Fried Krupp Huettenwerke AG
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Fried Krupp Huettenwerke AG
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Classifications

    • CCHEMISTRY; METALLURGY
    • C21METALLURGY OF IRON
    • C21DMODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING
    • C21D8/00Modifying the physical properties by deformation combined with, or followed by, heat treatment
    • C21D8/06Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires
    • C21D8/08Modifying the physical properties by deformation combined with, or followed by, heat treatment during manufacturing of rods or wires for concrete reinforcement
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P10/00Technologies related to metal processing
    • Y02P10/20Recycling

Definitions

  • the balance consisting essentially of iron by cooling it in quiet air from the hot-rolled state with the formation of bainite structure and, thereafter, either cold deforming it plastically without essential increase of tensile strength and tempering the same at a temperature in the range of 100 to 400 C. or tempering it in the temperature range between 150 and 550 C.
  • This invention is directed to providing a steel composition particularly useful as a bar steel for prestressed concrete to lend support to such concrete. More particularly, this invention is directed to an unannealed reinforcing b ar steel to reinforce prestressed concrete provided by a process involving the selection of a suitable particular steel composition and treating the same either by cold-deforming the same plastically and subjecting it to a tempering operation carried out at a temperature between 100 and 400 C. or by tempering the same (without preceding cold-deforming) at a temperature between 150 and 550 C.
  • Bar steels of greater strength would permit higher prestressing forces with the same steel cross section, or for a given prestressing force they would permit a reduction in the number of bars needed. This would not only permit a reduction in material costs but also it would reduce the manufacturing costs and make possible more slender constructions.
  • the invention is aimed at accomplishing this objective, and its purpose was to manufacture an unannealed, plain or deformed reinforcing steel with a high tensile strength and a high notch ductility for prestressed concrete, in a dimensional range of from 15 to 60 millimeters diameter, with a minimum tensile strength of 120 ltg/mm. and a minimum reduction of area at failure of 25%.
  • this invention contemplates a process for manufacturing an unannealed reinforcing bar steel for prestressed concrete which comprises providing a steel having a composition of:
  • the steel of the present inveniton may contain an amount of molybdenum up to 0.40 Wt.-percent and/or a quantity of vanadium up to 0.40 wt.-percent and/or a quantity of boron up to 0.01 wt.-percent.
  • molybdenum up to 0.40 Wt.-percent and/or a quantity of vanadium up to 0.40 wt.-percent and/or a quantity of boron up to 0.01 wt.-percent.
  • the steel of the present invention can be prepared in essentially two different manners starting from the initial steel composition having the required contents of carbon, silicon, manganese, chromium, iron and the required relationship between the manganese and chromium.
  • the steel is cooled from a temperature at or near the hot-roll end temperature in quiet air and thereafter cold-deforming the same after the steel has been cooled from the hot-rolled state and thereafter tempering at a temperature between 100 and 400 C.
  • Another embodiment of the present invention involves tempering the steel cooled from the hot-rolling state without cold-deforming at a temperature between and 550 C.
  • such steel is referred to as a plain steel in contrast to one which has been deformed.
  • a tempering temperature between 300 and 500 C.
  • time and temperature are inversely proportional to one another.
  • temperatures at the lower portion of the range are employed, it is generally desirable to temper for a longer period of time than would be employed had the temperature been towards the upper limit of the range.
  • the cold-deforming operation for the plain bars and the deformed bars is preferably carried out at a room temperature.
  • the deformation of the steel generally by means of a cold stretching in a range from 0.1 to 1.0%, preferably in the range from 0.2 to 0.5%.
  • the forces depend on the cross section and the yield point after cooling the steel in quiet air (as rolled condition).
  • steels of the present invention have minimum tensile strengths of 120 kg./mm.
  • such steels generally have a tensile strength between 120 and 180 kg./mm. preferably between 135 and 160 kg./ mmf They also have a minimum reduction of area at failure of at least 25%, generally at least 40%.
  • the plastic deformation is done by stretching the bar so that it is elongated or extended in an amount between 0.1 and 1.0%.
  • the deforming or stretching operation should be carried out over a period of time between 5 sec. and 3 min.
  • the process of the present invention employs a tempering in the stated temperature ranges depending upon whether an as rolled or a cold-deformed steel is desired.
  • the tempering operation should be carried out for a period of time between 1 min. and 12 hours, depending on whether it is done by continuous annealing or by batch annealing in a furnace.
  • the strength of a 30 mm. bar for example can be estimated on the basis of the formula and a suitable composition can be selected accordingly.
  • the tensile strength can be found in kg./mm. if the percentages of the alloying components are given in percentages by weight.
  • the reinforcing steel has a content of 0.02 to 0.40 wt.-percent Mo and/ or 0.02 to 0.40 wt.-percent V and/or 0.001 to 0.01 wt.-percent B.
  • the reinforcing bar made by the process of the invention attains considerably better strength values for equal toughness characteristics.
  • the desired mechanical characteristics can be achieved either by a tempering operation e.g., one half hour at 400 C. bar steel with 26.4 mm. diameter or by stretching followed by tempering.
  • the yield point can be adjusted to the desired value by varying the stretch percentage.
  • the tempering operation that follows may be performed at 270 C. over a period of between 5 and -60 minutes, although its effect does not vary appreciably from that achieved by a tempering time of 5 minutes. In the case of tempering below 200 C. the tempering time would, in a known manner, have to be extended; if the tempering were performed at temperatures above 300 C. the time could be less than 5 minutes.
  • the notch was made by machining; the notch depth was 0.5 mm., the notch radius was 0.25 mm. and the angle of the flanks was 45 TABLE II Steel used at the New steel, 30 mm. present time,
  • the steel of the invention in spite of the sparing use of alloying elements and its uncomplicated and inexpensive method of manufacture, offers an outstanding and improved combination of properties, especially in regard to tensile strength and reduction of area at rupture. Furthermore, it is characterized by a very good creep resistance, which is especially important for use in prestressed concrete construction in which it is subject to long-term high tensile stress.
  • the simple, inexpensive process of the present invention provides steels having a minimum tensile strength of 120 kg./mm. and a minimum reduction of area at failure of 25% and upwardly of about 43%. Additionally, the properties with respect to the notched steel are compared favorably with steels prepared by prior art processes. Note that such notched steels have substantially better elongation at rupture and compare quite favorably to prior art steels which 'have not been notched. The reduction of area at rupture for a notched steel is 17%, whereas the same value for the notched steel of the prior art is too small to measure. Thus, it is seen that the inexpensive process of the present invention provides steels which are substantially superior in elongation, tensile strength and reduction of rupture to those heretofore provided. Such has been provided with such steels even though the diameter is slightly less.
  • unannealed steel in this description means that the steel is not subjected to a heat treatment consisting of hardening the steel by quenching it from hardening temperatures and subsequently tempering of the quenched (hardened) steel.
  • a kg./mm. yield strength at a yield stress in kg./mrn.- at which the steel exhibits a deviation of 0.2% from proportionality of stress and strain;
  • kg./mm. tensile strength in l g./mm. the maximum stress at fracture (breaking) in tensile test;
  • Reduction of area at failure the difference, expressed as a percentage of the original cross-sectional area, between the original cross-sectional area of a tensile test specimen and the minimum cross-sectional area after complete separation;
  • Plain bar means a bar with a smooth surface
  • deformed bar means a bar equipped with ribs or the like on its surface.
  • the balance consisting essentially of iron and hot rolling it followed by immediate cooling from a temperature at or near the hot roll temperature in quiet air, thereafter, either cold-deforming the same plastically without substantial strength increase and thereafter tempering it at temperatures between and 400 C. or tempering the same at a temperature between and 550 C.
  • a process according to claim 1 wherein the steel composition is selected to satisfy the formula 9.
  • a process according to claim 1 wherein the tempering is carried out over a period of time between one minute and twelve hours, wherein the shorter times belong to continuous annealing and the longer time batch annealing.

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Thermal Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Heat Treatment Of Steel (AREA)
  • Heat Treatment Of Strip Materials And Filament Materials (AREA)
  • Heat Treatment Of Articles (AREA)
US00264669A 1971-06-24 1972-06-20 Process of manufacturing a reinforcing bar steel for prestressed concrete Expired - Lifetime US3810793A (en)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
DE2131318A DE2131318C3 (de) 1971-06-24 1971-06-24 Verfahren zum Herstellen eines Beweh rungs Stabstahles für Spannbeton

Publications (1)

Publication Number Publication Date
US3810793A true US3810793A (en) 1974-05-14

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US00264669A Expired - Lifetime US3810793A (en) 1971-06-24 1972-06-20 Process of manufacturing a reinforcing bar steel for prestressed concrete

Country Status (17)

Country Link
US (1) US3810793A (de)
JP (1) JPS52446B1 (de)
AT (1) AT327977B (de)
BE (1) BE784097A (de)
BR (1) BR7204065D0 (de)
CA (1) CA958311A (de)
CH (1) CH586751A5 (de)
DE (1) DE2131318C3 (de)
ES (1) ES403952A1 (de)
FR (1) FR2143382B1 (de)
GB (1) GB1334349A (de)
IT (1) IT965788B (de)
LU (1) LU65413A1 (de)
NL (1) NL156446B (de)
SE (1) SE382076B (de)
TR (1) TR17213A (de)
ZA (1) ZA723765B (de)

Cited By (35)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4142919A (en) * 1977-03-14 1979-03-06 Sodetal, Societe Pour Le Developpement Du Filmentallique Manufacture of elongated bodies of high strength carbon steel
US4284438A (en) * 1977-06-20 1981-08-18 British Steel Corporation Manufacture of steel products
US4784922A (en) * 1985-10-11 1988-11-15 Mitsubishi Steel Mfg. Co., Ltd. Corrosion-resistant clad steel and method for producing the same
AU599158B2 (en) * 1986-09-19 1990-07-12 Aicher, Max Hot and cold rolled steel rod for reinforcement
US20070089813A1 (en) * 2003-04-25 2007-04-26 Tubos De Acero Mexico S.A. Seamless steel tube which is intended to be used as a guide pipe and production method thereof
WO2009065432A1 (en) * 2007-11-19 2009-05-28 Tenaris Connections Ag High strength bainitic steel for octg applications
US20100068549A1 (en) * 2006-06-29 2010-03-18 Tenaris Connections Ag Seamless precision steel tubes with improved isotropic toughness at low temperature for hydraulic cylinders and process for obtaining the same
US20100136363A1 (en) * 2008-11-25 2010-06-03 Maverick Tube, Llc Compact strip or thin slab processing of boron/titanium steels
US20100181761A1 (en) * 2007-07-16 2010-07-22 Tenaris Connections Ag Threaded joint with resilient seal ring
US20100181727A1 (en) * 2007-06-22 2010-07-22 Tenaris Connections Ag Threaded joint with energizable seal
US20100193085A1 (en) * 2007-04-17 2010-08-05 Alfonso Izquierdo Garcia Seamless steel pipe for use as vertical work-over sections
US20110008101A1 (en) * 2008-02-29 2011-01-13 Tenaris Connections Limited Threaded joint with improved resilient seal ring
US20110041581A1 (en) * 2007-08-24 2011-02-24 Tenaris Connections Ag Method for improving fatigue resistance of a threaded joint
US20110133449A1 (en) * 2009-11-24 2011-06-09 Tenaris Connections Limited Threaded joint sealed to internal and external pressures
US20110233925A1 (en) * 2010-03-25 2011-09-29 Tenaris Connections Limited Threaded joint with elastomeric seal flange
US8215680B2 (en) 2007-08-24 2012-07-10 Tenaris Connections Ag Threaded joint with high radial loads and differentially treated surfaces
US8328958B2 (en) 2007-07-06 2012-12-11 Tenaris Connections Limited Steels for sour service environments
US8333409B2 (en) 2007-06-27 2012-12-18 Tenaris Connections Limited Threaded joint with pressurizable seal
US8414715B2 (en) 2011-02-18 2013-04-09 Siderca S.A.I.C. Method of making ultra high strength steel having good toughness
US8636856B2 (en) 2011-02-18 2014-01-28 Siderca S.A.I.C. High strength steel having good toughness
US8821653B2 (en) 2011-02-07 2014-09-02 Dalmine S.P.A. Heavy wall steel pipes with excellent toughness at low temperature and sulfide stress corrosion cracking resistance
US8840152B2 (en) 2010-03-26 2014-09-23 Tenaris Connections Limited Thin-walled pipe joint
US9004544B2 (en) 2009-04-22 2015-04-14 Tenaris Connections Limited Threaded joint for tubes, pipes and the like
US9187811B2 (en) 2013-03-11 2015-11-17 Tenaris Connections Limited Low-carbon chromium steel having reduced vanadium and high corrosion resistance, and methods of manufacturing
US9340847B2 (en) 2012-04-10 2016-05-17 Tenaris Connections Limited Methods of manufacturing steel tubes for drilling rods with improved mechanical properties, and rods made by the same
US9598746B2 (en) 2011-02-07 2017-03-21 Dalmine S.P.A. High strength steel pipes with excellent toughness at low temperature and sulfide stress corrosion cracking resistance
US9644248B2 (en) 2013-04-08 2017-05-09 Dalmine S.P.A. Heavy wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes
US9657365B2 (en) 2013-04-08 2017-05-23 Dalmine S.P.A. High strength medium wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes
US9803256B2 (en) 2013-03-14 2017-10-31 Tenaris Coiled Tubes, Llc High performance material for coiled tubing applications and the method of producing the same
US9970242B2 (en) 2013-01-11 2018-05-15 Tenaris Connections B.V. Galling resistant drill pipe tool joint and corresponding drill pipe
US11105501B2 (en) 2013-06-25 2021-08-31 Tenaris Connections B.V. High-chromium heat-resistant steel
US11124852B2 (en) 2016-08-12 2021-09-21 Tenaris Coiled Tubes, Llc Method and system for manufacturing coiled tubing
CN114807746A (zh) * 2021-05-28 2022-07-29 广西柳钢华创科技研发有限公司 高速棒材生产的hrb500e螺纹钢筋
US11833561B2 (en) 2017-01-17 2023-12-05 Forum Us, Inc. Method of manufacturing a coiled tubing string
US11952648B2 (en) 2011-01-25 2024-04-09 Tenaris Coiled Tubes, Llc Method of forming and heat treating coiled tubing

Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS553322A (en) * 1978-06-19 1980-01-11 Nippon Kokan Kk Blast furnace water slag equipment net washing method
GB2297094B (en) * 1995-01-20 1998-09-23 British Steel Plc Improvements in and relating to Carbide-Free Bainitic Steels

Cited By (50)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4142919A (en) * 1977-03-14 1979-03-06 Sodetal, Societe Pour Le Developpement Du Filmentallique Manufacture of elongated bodies of high strength carbon steel
US4284438A (en) * 1977-06-20 1981-08-18 British Steel Corporation Manufacture of steel products
US4784922A (en) * 1985-10-11 1988-11-15 Mitsubishi Steel Mfg. Co., Ltd. Corrosion-resistant clad steel and method for producing the same
AU599158B2 (en) * 1986-09-19 1990-07-12 Aicher, Max Hot and cold rolled steel rod for reinforcement
US8002910B2 (en) 2003-04-25 2011-08-23 Tubos De Acero De Mexico S.A. Seamless steel tube which is intended to be used as a guide pipe and production method thereof
US20070089813A1 (en) * 2003-04-25 2007-04-26 Tubos De Acero Mexico S.A. Seamless steel tube which is intended to be used as a guide pipe and production method thereof
US20100068549A1 (en) * 2006-06-29 2010-03-18 Tenaris Connections Ag Seamless precision steel tubes with improved isotropic toughness at low temperature for hydraulic cylinders and process for obtaining the same
US8926771B2 (en) 2006-06-29 2015-01-06 Tenaris Connections Limited Seamless precision steel tubes with improved isotropic toughness at low temperature for hydraulic cylinders and process for obtaining the same
US20100193085A1 (en) * 2007-04-17 2010-08-05 Alfonso Izquierdo Garcia Seamless steel pipe for use as vertical work-over sections
US20100181727A1 (en) * 2007-06-22 2010-07-22 Tenaris Connections Ag Threaded joint with energizable seal
US9234612B2 (en) 2007-06-22 2016-01-12 Tenaris Connections Limited Threaded joint with energizable seal
US8333409B2 (en) 2007-06-27 2012-12-18 Tenaris Connections Limited Threaded joint with pressurizable seal
US8328958B2 (en) 2007-07-06 2012-12-11 Tenaris Connections Limited Steels for sour service environments
US9383045B2 (en) 2007-07-16 2016-07-05 Tenaris Connections Limited Threaded joint with resilient seal ring
US20100181761A1 (en) * 2007-07-16 2010-07-22 Tenaris Connections Ag Threaded joint with resilient seal ring
US8544304B2 (en) 2007-08-24 2013-10-01 Tenaris Connections Limited Method for improving fatigue resistance of a threaded joint
US20110041581A1 (en) * 2007-08-24 2011-02-24 Tenaris Connections Ag Method for improving fatigue resistance of a threaded joint
US8215680B2 (en) 2007-08-24 2012-07-10 Tenaris Connections Ag Threaded joint with high radial loads and differentially treated surfaces
WO2009065432A1 (en) * 2007-11-19 2009-05-28 Tenaris Connections Ag High strength bainitic steel for octg applications
US8328960B2 (en) 2007-11-19 2012-12-11 Tenaris Connections Limited High strength bainitic steel for OCTG applications
US20100294401A1 (en) * 2007-11-19 2010-11-25 Tenaris Connections Limited High strength bainitic steel for octg applications
US8262140B2 (en) 2008-02-29 2012-09-11 Tenaris Connections Limited Threaded joint with improved resilient seal ring
US20110008101A1 (en) * 2008-02-29 2011-01-13 Tenaris Connections Limited Threaded joint with improved resilient seal ring
US20100136363A1 (en) * 2008-11-25 2010-06-03 Maverick Tube, Llc Compact strip or thin slab processing of boron/titanium steels
US8221562B2 (en) 2008-11-25 2012-07-17 Maverick Tube, Llc Compact strip or thin slab processing of boron/titanium steels
US9004544B2 (en) 2009-04-22 2015-04-14 Tenaris Connections Limited Threaded joint for tubes, pipes and the like
US10844669B2 (en) 2009-11-24 2020-11-24 Tenaris Connections B.V. Threaded joint sealed to internal and external pressures
US20110133449A1 (en) * 2009-11-24 2011-06-09 Tenaris Connections Limited Threaded joint sealed to internal and external pressures
US20110233925A1 (en) * 2010-03-25 2011-09-29 Tenaris Connections Limited Threaded joint with elastomeric seal flange
US8840152B2 (en) 2010-03-26 2014-09-23 Tenaris Connections Limited Thin-walled pipe joint
US11952648B2 (en) 2011-01-25 2024-04-09 Tenaris Coiled Tubes, Llc Method of forming and heat treating coiled tubing
US9598746B2 (en) 2011-02-07 2017-03-21 Dalmine S.P.A. High strength steel pipes with excellent toughness at low temperature and sulfide stress corrosion cracking resistance
US8821653B2 (en) 2011-02-07 2014-09-02 Dalmine S.P.A. Heavy wall steel pipes with excellent toughness at low temperature and sulfide stress corrosion cracking resistance
US9222156B2 (en) 2011-02-18 2015-12-29 Siderca S.A.I.C. High strength steel having good toughness
US8414715B2 (en) 2011-02-18 2013-04-09 Siderca S.A.I.C. Method of making ultra high strength steel having good toughness
US9188252B2 (en) 2011-02-18 2015-11-17 Siderca S.A.I.C. Ultra high strength steel having good toughness
US8636856B2 (en) 2011-02-18 2014-01-28 Siderca S.A.I.C. High strength steel having good toughness
US9340847B2 (en) 2012-04-10 2016-05-17 Tenaris Connections Limited Methods of manufacturing steel tubes for drilling rods with improved mechanical properties, and rods made by the same
US9970242B2 (en) 2013-01-11 2018-05-15 Tenaris Connections B.V. Galling resistant drill pipe tool joint and corresponding drill pipe
US9187811B2 (en) 2013-03-11 2015-11-17 Tenaris Connections Limited Low-carbon chromium steel having reduced vanadium and high corrosion resistance, and methods of manufacturing
US9803256B2 (en) 2013-03-14 2017-10-31 Tenaris Coiled Tubes, Llc High performance material for coiled tubing applications and the method of producing the same
US10378074B2 (en) 2013-03-14 2019-08-13 Tenaris Coiled Tubes, Llc High performance material for coiled tubing applications and the method of producing the same
US10378075B2 (en) 2013-03-14 2019-08-13 Tenaris Coiled Tubes, Llc High performance material for coiled tubing applications and the method of producing the same
US11377704B2 (en) 2013-03-14 2022-07-05 Tenaris Coiled Tubes, Llc High performance material for coiled tubing applications and the method of producing the same
US9657365B2 (en) 2013-04-08 2017-05-23 Dalmine S.P.A. High strength medium wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes
US9644248B2 (en) 2013-04-08 2017-05-09 Dalmine S.P.A. Heavy wall quenched and tempered seamless steel pipes and related method for manufacturing said steel pipes
US11105501B2 (en) 2013-06-25 2021-08-31 Tenaris Connections B.V. High-chromium heat-resistant steel
US11124852B2 (en) 2016-08-12 2021-09-21 Tenaris Coiled Tubes, Llc Method and system for manufacturing coiled tubing
US11833561B2 (en) 2017-01-17 2023-12-05 Forum Us, Inc. Method of manufacturing a coiled tubing string
CN114807746A (zh) * 2021-05-28 2022-07-29 广西柳钢华创科技研发有限公司 高速棒材生产的hrb500e螺纹钢筋

Also Published As

Publication number Publication date
NL156446B (nl) 1978-04-17
SE382076B (sv) 1976-01-12
GB1334349A (en) 1973-10-17
BE784097A (fr) 1972-09-18
CH586751A5 (de) 1977-04-15
DE2131318A1 (de) 1972-12-28
ES403952A1 (es) 1975-05-01
TR17213A (tr) 1976-05-02
IT965788B (it) 1974-02-11
DE2131318C3 (de) 1973-12-06
FR2143382A1 (de) 1973-02-02
ATA538772A (de) 1975-05-15
JPS52446B1 (de) 1977-01-07
AT327977B (de) 1976-02-25
BR7204065D0 (pt) 1973-05-15
DE2131318B2 (de) 1973-05-17
ZA723765B (en) 1973-03-28
NL7208702A (de) 1972-12-28
FR2143382B1 (de) 1974-08-30
CA958311A (en) 1974-11-26
LU65413A1 (de) 1972-08-24

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