TWI440753B - 合成纖維用處理劑,合成纖維用處理劑水性液,合成纖維之處理方法及合成纖維 - Google Patents
合成纖維用處理劑,合成纖維用處理劑水性液,合成纖維之處理方法及合成纖維 Download PDFInfo
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Description
本發明係關於一種合成纖維用處理劑、該合成纖維用處理劑之水性液、使用該水性液之合成纖維之處理方法及藉由該處理方法而得之合成纖維。
聚酯或聚醯胺等合成纖維之製造或加工係藉由將合成纖維用處理劑、例如將紡絲油劑以非水系進行供給或以水系進行供給而進行。然而,若將合成纖維用處理劑以非水系、例如稀釋於有機溶劑中之狀態進行供給(例如參照專利文獻1及2),則於成本方面、防災方面及安全方面產生問題較多。
另一方面,若將合成纖維用處理劑以低濃度之水系、例如以10%左右之乳液之狀態進行供給(例如參照專利文獻3),則雖可消除成本方面、防災方面及安全方面之問題,但於絲品質或染色性上產生問題較多。
亦提出有將合成纖維用處理劑製成更高濃度、例如以30%左右、進而50%左右之乳液而進行供給(例如參照專利文獻4),若如此進行,則合成纖維用處理劑之乳液發生凝膠化,無法使合成纖維用處理劑均勻附著於絲上,結果,存在無法同時充分滿足所要求之高
度製絲性、絲品質及染色性之問題。
[專利文獻1]日本專利特開昭57-199868號公報
[專利文獻2]日本專利特開平6-57541號公報
[專利文獻3]日本專利特開平7-216733號公報
[專利文獻4]日本專利特開平6-280160號公報
本發明所欲解決之課題在於提供一種於合成纖維之製造或加工中,於成本方面、防災方面及安全方面不產生問題,並維持良好之製絲性而可獲得具有優異之絲品質及染色性之合成纖維的合成纖維用處理劑、該合成纖維用處理劑之水性液、使用該水性液之合成纖維之處理方法及藉由該處理方法而得之合成纖維。
發明者等人為了解決上述課題已進行研究,結果發現,以特定比率含有特定之5種成分而成之合成纖維用處理劑正合適,又,較佳為將該合成纖維用處理劑製成特定濃度之水性液,使之附著於合成纖維。
即,本發明係關於一種合成纖維用處理劑,其特徵在於:以含有下述A成分20~70質量%、下述B成分5~45質量%、下述C成分1~20質量%、下述D成分5~35質量%及下述E成分1~20質量%(合計100質量%)之比率而成。
A成分:總碳數為10~100之酯油及/或於30℃下之動黏度為1~500mm2
/s之礦物油
B成分:選自下述化1所表示之化合物、下述化2所表示之化合物、分子中具有以1~100個氧化乙烯單位構成之(聚)氧乙烯基之(聚)氧乙烯蓖麻油醚與碳數6~22之脂肪族單羧酸發生酯化所得之蓖麻油衍生物、及分子中具有以1~100個氧化乙烯單位構成之(聚)氧乙烯基之(聚)氧乙烯氫化蓖麻油醚與碳數6~22之脂肪族單羧酸發生酯化所得之氫化蓖麻油衍生物中之一者或兩者以上
[化1]R1
-X1
-R2
R1
:自碳數6~22之脂肪族單羧酸之羧基中除去氫原子所得之殘基
X1
:自分子中具有以1~20個氧化乙烯單位構成之(聚)氧乙烯基之(聚)乙二醇中除去所有羥基所得之殘基
R2
:自碳數6~22之脂肪族單羧酸之羧基中除去氫原子所得之殘基、自碳數6~22之脂肪族單醇之羥基中除去氫原子所得之殘基或羥基
[化2]R3
-X2
-Y1
-X3
-R4
R3
、R4
:自碳數6~22之脂肪族單羧酸之羧基中除去氫原子所得之殘基
X2
、X3
:自分子中具有以1~20個氧化乙烯單位構成之(聚)氧乙烯基之(聚)乙二醇中除去所有羥基所得之殘基
Y1
:自碳數3~12之脂肪族二羧酸之羧基中除去氫原子所得之殘
基
C成分:山梨醇酐與碳數10~22之脂肪族單羧酸之酯
D成分:碳數2~22之脂肪族醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為100~1500
E成分:選自脂肪酸鹽、脂肪族磷酸鹽及脂肪族磺酸鹽中之一者或兩者以上
又,本發明係關於一種合成纖維用處理劑水性液,其係由40~90質量%之該合成纖維用處理劑及10~60質量%之水(合計100質量%)之比率而成者,其利用特定之穩定性評價方法進行評價時水性液穩定,且利用特定之黏度測定方法測定之水性液之動黏度為50~300mm2
/s。進而,本發明係關於一種合成纖維之處理方法,其係使該水性液相對於合成纖維以按合成纖維用處理劑計為0.1~5質量%之方式附著。進而又,本發明係關於一種合成纖維,其係藉由該處理方法而獲得。
首先,針對本發明之合成纖維用處理劑(以下,稱為本發明之處理劑)進行說明。本發明之處理劑係以含有上述A成分20~70質量%、上述B成分5~45質量%、上述C成分1~20質量%、上述D成分5~35質量%及上述E成分1~20質量%(合計100質量%)之比率而成。
作為A成分中之總碳數為10~100之酯油,可列舉:硬脂酸丁酯、硬脂酸辛酯、月桂酸油酯、油酸油酯等脂肪族一元醇與脂肪族單羧酸發生酯化而成者,三羥甲基丙烷單油酸酯單月桂酸酯、1,6-己二醇二癸酸酯等脂肪族多元醇與脂肪族單羧酸發生酯化而成者,十四酸二異硬脂酯、己二酸二月桂酯、壬二酸二油酯等脂肪族一元醇與
脂肪族多元羧酸發生酯化而成者等,其中,較佳為硬脂酸辛酯、月桂酸油酯、油酸油酯、十四酸二異硬脂酯等碳數6~22之脂肪族單醇與碳數6~22之脂肪族單羧酸發生酯化而成者。
作為A成分中於30℃下之動黏度為1~500mm2
/s之礦物油,可列舉液態石蠟油等,其中,較佳為30℃下之動黏度為1~200mm2
/s之液態石蠟油。
作為B成分中之化1所表示之化合物,可列舉:α-己基-ω-羥基-聚氧乙烯辛酸酯、α-辛基-ω-羥基-聚氧乙烯辛酸酯、α-癸基-ω-羥基-聚氧乙烯辛酸酯、α-十二基-ω-羥基-聚氧乙烯辛酸酯、α-十四基-ω-羥基-聚氧乙烯辛酸酯、α-十六基-ω-羥基-聚氧乙烯辛酸酯、α-十八基-ω-羥基-聚氧乙烯辛酸酯、α-十八烯基-ω-羥基-聚氧乙烯辛酸酯、α-二十基-ω-羥基-聚氧乙烯辛酸酯、α-己基-ω-羥基-聚氧乙烯癸酸酯、α-辛基-ω-羥基-聚氧乙烯癸酸酯、α-癸基-ω-羥基-聚氧乙烯癸酸酯、α-十二基-ω-羥基-聚氧乙烯癸酸酯、α-十四基-ω-羥基-聚氧乙烯癸酸酯、α-十六基-ω-羥基-聚氧乙烯癸酸酯、α-十八基-ω-羥基-聚氧乙烯癸酸酯、α-十八烯基-ω-羥基-聚氧乙烯癸酸酯、α-二十基-ω-羥基-聚氧乙烯癸酸酯、α-己基-ω-羥基-聚氧乙烯十二酸酯、α-辛基-ω-羥基-聚氧乙烯十二酸酯、α-癸基-ω-羥基-聚氧乙烯十二酸酯、α-十二基-ω-羥基-聚氧乙烯十二酸酯、α-十四基-ω-羥基-聚氧乙烯十二酸酯、α-十六基-ω-羥基-聚氧乙烯十二酸酯、α-十八烷基-ω-羥基-聚氧乙烯十二酸酯、α-十八烯基-ω-羥基-聚氧乙烯十二酸酯、α-二十基-ω-羥基-聚氧乙烯十二酸酯、α-己基-ω-羥基-聚氧乙烯油酸酯、α-辛基-ω-羥基-聚氧乙烯油酸酯、α-癸基-ω-羥基-聚氧乙烯油酸酯、α-十二基-ω-羥基-聚氧乙烯油酸酯、α-十四基-ω-羥基-聚氧乙烯油酸酯、α-十六基-ω-羥基-聚氧乙烯油酸酯、α-十八基-ω-羥基
-聚氧乙烯油酸酯、α-十八烯基-ω-羥基-聚氧乙烯油酸酯、α-二十基-ω-羥基-聚氧乙烯油酸酯、聚氧乙烯辛酸酯、聚氧乙烯癸酸酯、聚氧乙烯十二酸酯、聚氧乙烯油酸酯、聚氧乙烯硬脂酸酯、聚氧乙烯二辛酸酯、聚氧乙烯二癸酸酯、聚氧乙烯二-十二酸酯、聚氧乙烯二油酸酯、聚氧乙烯二硬脂酸酯等。
作為B成分中之化2所表示之化合物,可列舉:雙(α-辛基-ω-羥基-聚氧乙烯)丁二酸酯、雙(α-辛基-ω-羥基-聚氧乙烯)己二酸酯、雙(α-辛基-ω-羥基-聚氧乙烯)癸二酸酯、雙(α-癸基-ω-羥基-聚氧乙烯)丁二酸酯、雙(α-癸基-ω-羥基-聚氧乙烯)己二酸酯、雙(α-癸基-ω-羥基-聚氧乙烯)癸二酸酯、雙(α-十二基-ω-羥基-聚氧乙烯)丁二酸酯、雙(α-十二基-ω-羥基-聚氧乙烯)己二酸酯、雙(α-十二基-ω-羥基-聚氧乙烯)癸二酸酯等。
作為B成分中之分子中具有以1~100個氧化乙烯單位構成之(聚)氧乙烯基之(聚)氧乙烯蓖麻油醚與碳數6~22之脂肪族單羧酸發生酯化而得之蓖麻油衍生物,可列舉:(聚)氧乙烯蓖麻油醚1莫耳與碳數6~22之脂肪族單羧酸1莫耳之部分酯化物、(聚)氧乙烯蓖麻油醚1莫耳與碳數6~22之脂肪族單羧酸2莫耳之部分酯化物、(聚)氧乙烯蓖麻油醚1莫耳與碳數6~22之脂肪族單羧酸3莫耳之酯化物等。
作為B成分中之分子中具有以1~100個氧化乙烯單位構成之(聚)氧乙烯基之(聚)氧乙烯氫化蓖麻油醚與碳數6~22之脂肪族單羧酸發生酯化所得之氫化蓖麻油衍生物,可列舉:(聚)氧乙烯氫化蓖麻油醚1莫耳與碳數6~22之脂肪族單羧酸1莫耳之部分酯化物、(聚)氧乙烯氫化蓖麻油醚1莫耳與碳數6~22之脂肪族單羧酸2莫耳之部分酯化物、(聚)氧乙烯氫化蓖麻油醚1莫耳與碳數6~22之脂肪族單羧
酸3莫耳之酯化物等。
化1或化2中之R1
、R3
、R4
為自己酸、辛酸、2-乙基己酸、癸酸、月桂酸、肉豆蔻酸、棕櫚酸、油酸、硬脂酸等碳數6~22之脂肪族單羧酸之羧基中除去氫原子所得之殘基。
化1中之R2
為關於R1
、R3
、R4
,上述之自脂肪族單羧酸之羧基中除去氫原子所得之殘基、自碳數6~22之脂肪族單醇之羥基中除去氫原子所得之殘基或羥基。
化1或化2中之X1
、X2
、X3
為自分子中具有以1~20個氧化乙烯單位構成之(聚)氧乙烯基之(聚)乙二醇中除去所有羥基所得之殘基。
化2中之Y1
為自丙二酸、丁二酸、己二酸、反丁烯二酸、癸二酸、壬二酸等碳數3~12之脂肪族二羧酸之羧基中除去氫原子所得之殘基。
作為C成分,可列舉:山梨醇酐單癸酸酯、山梨醇酐單十二酸酯、山梨醇酐單月桂酸酯、山梨醇酐單油酸酯、山梨醇酐單硬脂酸酯、山梨醇酐倍半月桂酸酯、山梨醇酐倍半油酸酯、山梨醇酐三月桂酸酯、山梨醇酐三油酸酯、山梨醇酐三硬脂酸酯等山梨醇酐與碳數10~22之脂肪族單羧酸之酯。
作為D成分,可列舉:乙醇、丙醇、丁醇、己醇、辛醇、壬醇、癸醇、十二醇、十三醇等直鏈脂肪族醇,或異辛醇、2-甲基戊醇、2-乙基己醇、2-甲基辛醇、2-丙基庚醇、2-丁基辛醇等分支脂肪族醇等碳數2~22之脂肪族醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為100~1500,較佳為由下述D1
成分及下述D2
成分而成者,且處於D1
/(D1
+D2
)=0.20~0.60(質量比)之範圍內。
D1
成分:碳數2~8之脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為600~1200
D2
成分:碳數10~18之脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為300~900
作為D1
成分,可列舉:乙醇、丙醇、丁醇、己醇、辛醇等碳數2~8之脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為600~1200。
作為D2
成分,可列舉:十一醇、十二醇、三-十二醇、十四醇、十五醇、十六醇、2-丁基辛醇、2-戊基壬醇、2-己基癸醇等碳數10~18脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為300~900。
作為E成分,可列舉:丙酸、己酸、羊脂酸(octanoic acid)、2-乙基己酸(octylic acid)、癸酸、月桂酸等之脂肪酸鹽,聚氧化月桂基磷酸鉀、聚氧化油醇磷酸鉀等脂肪族磷酸鹽,及癸烷磺酸鈉、十二烷磺酸鈉、十四烷磺酸鋰、十六烷磺酸鉀、丁基苯磺酸鈉、十四基苯磺酸鉀、十八基苯磺酸鉀等脂肪族磺酸鹽。
本發明之處理劑係以含有以上說明之A成分20~70質量%、B成分5~45質量%、C成分1~20質量%、D成分5~35質量%及E成分1~20質量%(合計100質量%)之比率而成者,較佳為以含有A成分30~60質量%、B成分15~35質量%、C成分5~15質量%、D成分5~20質量%及E成分5~15質量%(合計100質量%)之比率而成者。
本發明之處理劑中可合乎目的地併用其他成分,例如消泡劑、抗氧化劑、防腐劑、防銹劑等,其併用量較佳為於無損本發明
之效果之範圍內儘可能設為較少量。
繼而,針對本發明之合成纖維用處理劑水性液(以下,稱為本發明之水性液)進行說明。本發明之水性液係由40~90質量%之本發明之處理劑及10~60質量%之水(合計100質量%)之比率而成之合成纖維用處理劑水性液,於下述穩定性評價方法中水性液被評價為穩定,且利用下述黏度測定方法測定之水性液之動黏度為50~300mm2
/s之範圍內。
穩定性評價方法為如下者:分別製備100ml合成纖維用處理劑之40質量%、50質量%、60質量%、70質量%及90質量%之各水性液,添加至200ml燒杯中,於開放燒杯上部之狀態下於40℃下靜置2週,將無分離者評價為穩定。
黏度測定方法為如下者:分別製備100ml合成纖維用處理劑之40質量%、50質量%、60質量%、70質量%及90質量%之各水性液,針對各水性液利用坎農-芬斯克法(Cannon-Fenske)測定30℃下之動黏度(單位:mm2
/s)。
本發明之水性液係由40~90質量%之本發明之處理劑及10~60質量%之水(合計100質量%)之比率而成者,較佳為由40~70質量%之本發明之處理劑及30~60質量%之水(合計100質量%)之比率而成者。
繼而,針對本發明之合成纖維之處理方法(以下,稱為本發明之處理方法)進行說明。本發明之處理方法係使以上說明之本發明之水性液相對於合成纖維以按本發明之處理劑計為0.1~5質量%、較佳為0.5~2質量%之方式附著。作為使本發明之水性液附著之步驟,可列舉紡絲步驟、延伸步驟、同時進行紡絲與延伸之步驟等。又,作
為使本發明之水性液附著之方法,可列舉:輥供給法、使用計量泵之導引供給法、浸漬供給法、噴霧供給法等。進而,作為合成纖維,可列舉:聚酯纖維、聚醯胺纖維、聚烯烴纖維、丙烯酸系纖維等,其中於聚酯系纖維之情形時,效果之表現較高,較佳。
最後,針對本發明之合成纖維進行說明。本發明之合成纖維係藉由以上說明之本發明之處理方法而得之合成纖維。
若根據以上說明之本發明,則具有如下效果:於合成纖維之製造或加工中,可利用高濃度之水系供給合成纖維用處理劑,並且可以良好之製絲性進行操作,同時,可獲得具有優異之絲品質及染色性之合成纖維。
以下,為了使本發明之構成及效果更具體而舉出實施例等,但本發明並不限定於該等實施例。再者,於以下實施例等中,份表示質量份,又,%表示質量%。
以作為A成分的下述表1中所記載之A-1 22%、A-2 22%,作為B成分的下述表2中所記載之B-1 6%、B-3 3%、B-8 3%、B-9 2%、B-11 3%、B-12 6%,作為C成分的下述表3中所記載之C-1 2%、C-2 5%,
作為D成分的下述表4中所記載之D1
-1 5%、表5中所記載之D2
-1 8%,作為E成分之下述表6中所記載之E-1 3%、E-2 5%、E-3 5%(合計100質量%)之比率均勻混合,製備合成纖維處理劑(P-1)。
以與實施例1相同之方式製備實施例2~16之合成纖維用處理劑(P-2)~(P-16)及比較例1~7之合成纖維用處理劑(R-1)~(R-7)。將以上各例之合成纖維用處理劑之製備中使用的成分之內容示於表1~表6,又,將以上各例中製備之合成纖維用處理劑之內容匯總示於表7~9。
將試驗分類1中製備之合成纖維處理劑(P-1)之所需量與離子交換水之所需量均勻混合,製備濃度40%、50%、60%、70%及90%之合成纖維用處理劑水性液。自所製備之各合成纖維用處理劑水性液中分別取出100ml,添加至200ml燒杯中,於開放燒杯上部之狀態下於40℃下靜置2週,將無分離者記作○、存在分離者記作×而對穩定性進行評價。將結果匯總示於表10。又,自所製備之各合成纖維用處理劑水性液中分別取出100ml,針對各水性液利用坎農-芬斯克法測定30℃下之動黏度(單位:mm2
/s),將測定結果匯總示於表10。
以與實施例17相同之方式製備實施例18~32之合成纖維用處理劑水性液及比較例8~14之合成纖維用處理劑水性液,進行穩定性之評價及動黏度之測定,將結果匯總示於表10。
於表10中,* 1:由於合成纖維用處理劑水性液發生凝膠化,故而無法測定。
* 2:合成纖維用處理劑水性液未發生乳液化,而為不均勻狀態或發生分離,故而無法測定。
將試驗分類1中製備之合成纖維處理劑(P-1)55份與離子交換水45份均勻混合,製備濃度55%之合成纖維用處理劑水性液。藉由常用方法使固有黏度0.64、氧化鈦含量0.2%之聚對苯二甲酸乙二酯之碎片(chip)乾燥後,使用擠出機於295℃下進行紡絲,自紡絲頭吐出並使其冷卻固化後,對移行絲條利用使用計量泵之導引供給法使上述合成纖維用處理劑水性液相對於移行絲條以合成纖維用處理劑計為1.0%之方式附著後,利用導引使其彙聚,利用加熱至90℃之拉取輥以1400m/min之速度進行拉取,繼而,於拉取輥與以4800m/min之速度旋轉之延伸輥之間延伸至3.2倍,製造83.3德士(75丹尼爾)36絲之聚酯纖維。從而利用以下方法對聚酯纖維製造時之附著量、紡絲性、絲品質及染色性進行測定或評價,將結果匯總示於表11。
準確稱量所製造之聚酯纖維2g,以正己烷/乙醇=7/3(容量比)之混合溶液10ml進行萃取處理,於準確稱量有萃取液之鋁盤上以100℃乾燥5分鐘後,測定質量,利用下述數1求出油劑附著量。
[數1]
於數1中,A:鋁盤之重量
B:包括萃取出之油劑在內之鋁盤之重量
S:萃取中使用之纖維之重量
測定10次製造聚酯纖維時每1噸絲之斷頭次數,利用下述基準對其平均值進行評價。
◎:斷頭次數未滿0.5次
○:斷頭次數未滿0.5次~1.0次
△:斷頭次數未滿1.0次~2.0次
×:斷頭次數為2.0次以上
使用USTER公司製造之USTER TESTER UT-5,以絲速度200m/min對製造之聚酯纖維之USTER斑U%進行評價。進行5次相同之評價,根據各次之結果,以下述基準進行評價。
◎:全部5次中USTER斑U%為1.0以下
○:5次中有1次USTER斑U%為1.0以上
△:5次中有2次USTER斑U%為1.0以上
×:5次中有3次以上USTER斑U%為1.0以上
由所製造之聚酯纖維,利用筒編織機製作直徑70mm、長度1.2mm之編織物。使用分散染料(日本化藥公司製造之商品名Kayalon Polyester Blue EBL-E)利用高壓染色法將該編織物染色。依據常用方法將經染色之編織物水洗,進行還原洗淨、乾燥後,安裝於直徑70mm、長度1.0mm之鐵製筒中,以肉眼觀察編織物表面之濃染部分,計算其點數並進行評價。進行5次相同之評價,以下述基準對各次計算出之濃染部分之點數之平均值進行評價。
◎:無濃染部分
○:有1~2點濃染部分
△:有3~6點濃染部分
×:有7點以上濃染部分
以與實施例33相同之方式製備實施例34~51及比較例15~22之各種濃度之合成纖維用處理劑水性液,製造聚酯纖維,並對紡絲性、絲品質及染色性進行評價,將結果匯總示於表11。
於表11中,附著量:以合成纖維用處理劑計之相對於聚酯纖維之附著量
* 3:合成纖維用處理劑水性液之黏性過高而無法供給。
根據表11之結果亦可明確,根據本發明,於合成纖維之製造或加工中,可利用高濃度之水系供給合成纖維用處理劑,並且可以良好之製絲性進行操作,同時,可獲得具有優異之絲品質及染色性之合成纖維。
Claims (12)
- 一種合成纖維用處理劑,其特徵在於:以含有下述A成分20~70質量%、下述B成分5~45質量%、下述C成分1~20質量%、下述D成分5~35質量%及下述E成分1~20質量%(合計100質量%)之比率而成,A成分:總碳數為10~100之酯油及/或於30℃下之動黏度為1~500mm2 /s之礦物油B成分:選自下述化1所表示之化合物、下述化2所表示之化合物、分子中具有以1~100個氧化乙烯單位構成之(聚)氧乙烯基之(聚)氧乙烯蓖麻油醚與碳數6~22之脂肪族單羧酸發生酯化所得之蓖麻油衍生物、及分子中具有以1~100個氧化乙烯單位構成之(聚)氧乙烯基之(聚)氧乙烯氫化蓖麻油醚與碳數6~22之脂肪族單羧酸發生酯化所得之氫化蓖麻油衍生物中之一者或兩者以上[化1]R1 -X1 -R2 R1 :自碳數6~22之脂肪族單羧酸之羧基中除去氫原子所得之殘基X1 :自分子中具有以1~20個氧化乙烯單位構成之(聚)氧乙烯基之(聚)乙二醇中除去所有羥基所得之殘基R2 :自碳數6~22之脂肪族單羧酸之羧基中除去氫原子所得之殘基、自碳數6~22之脂肪族單醇之羥基中除去氫原子所得之殘基或羥基[化2]R3 -X2 -Y1 -X3 -R4 R3 、R4 :自碳數6~22之脂肪族單羧酸之羧基中除去氫原子所得之 殘基X2 、X3 :自分子中具有以1~20個氧化乙烯單位構成之(聚)氧乙烯基之(聚)乙二醇中除去所有羥基所得之殘基Y1 :自碳數3~12之脂肪族二羧酸之羧基中除去氫原子所得之殘基C成分:山梨醇酐與碳數10~22之脂肪族單羧酸之酯D成分:碳數2~22之脂肪族醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為100~1500 E成分:選自脂肪酸鹽、脂肪族磷酸鹽及脂肪族磺酸鹽中之一者或兩者以上。
- 如申請專利範圍第1項之合成纖維用處理劑,其中,A成分中之酯油為碳數6~22之脂肪族單醇與碳數6~22之脂肪族單羧酸發生酯化而得者。
- 如申請專利範圍第2項之合成纖維用處理劑,其中,A成分中之礦物油為30℃下之動黏度為1~200mm2 /s之液態石蠟油。
- 如申請專利範圍第1項之合成纖維用處理劑,其中,D成分係由下述D1 成分及下述D2 成分而成者,且質量比率為D1 /(D1 +D2 )=0.20~0.60(質量比)之範圍內,D1 成分:碳數2~8之脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為600~1200 D2 成分:碳數10~18之脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為300~900。
- 如申請專利範圍第3項之合成纖維用處理劑,其中,D成分係由下述D1 成分及下述D2 成分而成者,且質量比率為D1 /(D1 +D2 )=0.20~0.60(質量比)之範圍內, D1 成分:碳數2~8之脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為600~1200 D2 成分:碳數10~18之脂肪族單醇之環氧乙烷及環氧丙烷無規加成物,且重量平均分子量為300~900。
- 一種合成纖維用處理劑水性液,其係以40~90質量%之申請專利範圍第1項之合成纖維用處理劑及10~60質量%之水(合計100質量%)之比率而成者,其利用下述穩定性評價方法被評價為穩定,且利用下述黏度測定方法所測定之動黏度為50~300mm2 /s,穩定性評價方法為如下者:分別製備100ml合成纖維用處理劑之40質量%、50質量%、60質量%、70質量%及90質量%之各水性液,添加至200ml燒杯中,於開放燒杯上部之狀態下於40℃下靜置2週,將無分離者評價為穩定,黏度測定方法為如下者:分別製備100ml合成纖維用處理劑之40質量%、50質量%、60質量%、70質量%及90質量%之各水性液,針對各水性液利用坎農-芬斯克法(Cannon-Fenske)測定30℃下之動黏度(單位:mm2 /s)。
- 一種合成纖維用處理劑水性液,其係以40~90質量%之申請專利範圍第3項之合成纖維用處理劑及10~60質量%之水(合計100質量%)之比率而成者,其利用下述穩定性評價方法被評價為穩定,且利用下述黏度測定方法所測定之動黏度為50~300mm2 /s,穩定性評價方法為如下者:分別製備100ml合成纖維用處理劑之40質量%、50質量%、60質量%、70質量%及90質量%之各水性液,添加至200ml燒杯中,於開放燒杯上部之狀態下於40℃下靜置2週,將無分離者評價為穩定, 黏度測定方法為如下者:分別製備100ml合成纖維用處理劑之40質量%、50質量%、60質量%、70質量%及90質量%之各水性液,針對各水性液利用坎農-芬斯克法測定30℃下之動黏度(單位:mm2 /s)。
- 一種合成纖維之處理方法,其特徵在於:使申請專利範圍第6項之合成纖維用處理劑水性液相對於合成纖維以按合成纖維用處理劑計為0.1~5質量%之方式附著。
- 一種合成纖維之處理方法,其特徵在於:使申請專利範圍第7項之合成纖維用處理劑水性液相對於合成纖維以按合成纖維用處理劑計為0.1~5質量%之方式附著。
- 如申請專利範圍第8項之合成纖維之處理方法,其中,合成纖維用處理劑水性液係以40~70質量%之合成纖維用處理劑及30~60質量%之水(合計100質量%)之比率而成者。
- 如申請專利範圍第9項之合成纖維之處理方法,其中,合成纖維用處理劑水性液係以40~70質量%之合成纖維用處理劑及30~60質量%之水(合計100質量%)之比率而成者。
- 一種合成纖維,其係藉由申請專利範圍第8至11項中任一項之合成纖維之處理方法而獲得。
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