SK5482002A3 - Catalyst systems and their use in a polymerization process - Google Patents

Catalyst systems and their use in a polymerization process Download PDF

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Publication number
SK5482002A3
SK5482002A3 SK548-2002A SK5482002A SK5482002A3 SK 5482002 A3 SK5482002 A3 SK 5482002A3 SK 5482002 A SK5482002 A SK 5482002A SK 5482002 A3 SK5482002 A3 SK 5482002A3
Authority
SK
Slovakia
Prior art keywords
group
catalyst
hafnium
compound
polymerization
Prior art date
Application number
SK548-2002A
Other languages
English (en)
Slovak (sk)
Inventor
David H Mcconville
Donald R Loveday
Original Assignee
Univation Tech Llc
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority claimed from US09/425,390 external-priority patent/US6300438B1/en
Priority claimed from US09/428,576 external-priority patent/US6271323B1/en
Application filed by Univation Tech Llc filed Critical Univation Tech Llc
Publication of SK5482002A3 publication Critical patent/SK5482002A3/sk

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F10/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F110/00—Homopolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F110/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/16—Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2410/00—Features related to the catalyst preparation, the catalyst use or to the deactivation of the catalyst
    • C08F2410/02—Anti-static agent incorporated into the catalyst
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65912—Component covered by group C08F4/64 containing a transition metal-carbon bond in combination with an organoaluminium compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/65916—Component covered by group C08F4/64 containing a transition metal-carbon bond supported on a carrier, e.g. silica, MgCl2, polymer
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65925—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually non-bridged
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F4/00—Polymerisation catalysts
    • C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
    • C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
    • C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
    • C08F4/62—Refractory metals or compounds thereof
    • C08F4/64—Titanium, zirconium, hafnium or compounds thereof
    • C08F4/659—Component covered by group C08F4/64 containing a transition metal-carbon bond
    • C08F4/6592—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
    • C08F4/65922—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not
    • C08F4/65927—Component covered by group C08F4/64 containing a transition metal-carbon bond containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring containing at least two cyclopentadienyl rings, fused or not two cyclopentadienyl rings being mutually bridged

Landscapes

  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
SK548-2002A 1999-10-22 2000-05-15 Catalyst systems and their use in a polymerization process SK5482002A3 (en)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
US09/425,390 US6300438B1 (en) 1999-10-22 1999-10-22 Hafnium transition metal catalyst compounds, catalyst systems and their use in a polymerization process
US09/428,576 US6271323B1 (en) 1999-10-28 1999-10-28 Mixed catalyst compounds, catalyst systems and their use in a polymerization process
PCT/US2000/013310 WO2001030860A1 (fr) 1999-10-22 2000-05-15 Systemes catalyseurs et leur utilisation dans un procede de polymerisation

Publications (1)

Publication Number Publication Date
SK5482002A3 true SK5482002A3 (en) 2003-02-04

Family

ID=27026667

Family Applications (1)

Application Number Title Priority Date Filing Date
SK548-2002A SK5482002A3 (en) 1999-10-22 2000-05-15 Catalyst systems and their use in a polymerization process

Country Status (23)

Country Link
EP (1) EP1226191B1 (fr)
JP (1) JP3746234B2 (fr)
KR (1) KR100567304B1 (fr)
CN (1) CN1184242C (fr)
AR (1) AR025163A1 (fr)
AT (1) ATE299898T1 (fr)
AU (1) AU764962B2 (fr)
BR (1) BR0015241B1 (fr)
CA (1) CA2387877C (fr)
CZ (1) CZ20021401A3 (fr)
DE (1) DE60021405T2 (fr)
EG (1) EG22573A (fr)
IL (1) IL149174A0 (fr)
MX (1) MXPA02004000A (fr)
MY (1) MY126752A (fr)
NO (1) NO20021863L (fr)
PL (1) PL354578A1 (fr)
RU (1) RU2241717C2 (fr)
SA (1) SA00210261B1 (fr)
SK (1) SK5482002A3 (fr)
TR (1) TR200201083T2 (fr)
TW (1) TW538051B (fr)
WO (1) WO2001030860A1 (fr)

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US6960635B2 (en) * 2001-11-06 2005-11-01 Dow Global Technologies Inc. Isotactic propylene copolymers, their preparation and use
US7094848B2 (en) 2003-05-13 2006-08-22 Exxonmobil Chemical Patents Inc. Olefin polymerization catalyst system
US7045583B2 (en) 2003-12-22 2006-05-16 Exxon Mobil Chemical Patents Inc. Olefin polymerization catalyst system
EP1805226A1 (fr) 2004-10-29 2007-07-11 Exxonmobil Chemical Patents Inc. Compose catalytique contenant un ligand tridente divalent
US7323526B2 (en) * 2005-07-29 2008-01-29 Univation Technologies, Llc Supported metallocene-alkyl catalyst composition
EP1803747A1 (fr) * 2005-12-30 2007-07-04 Borealis Technology Oy Catalyseur de polymérisation à surface modifiée pour réduire la formation de gels dans des films
AU2007319883B2 (en) * 2006-11-14 2012-12-13 Univation Technologies, Llc. Catalyst systems and polymerization processes
BRPI0808314B1 (pt) 2007-03-07 2019-04-09 Dow Global Technologies Inc. Complexo metálico suportado e processo de polimerização por adição.
TW200936619A (en) 2007-11-15 2009-09-01 Univation Tech Llc Polymerization catalysts, methods of making, methods of using, and polyolefin products made therefrom
CN102712701A (zh) 2009-12-07 2012-10-03 尤尼威蒂恩技术有限责任公司 减少催化剂的静电荷的方法和使用该催化剂生产聚烯烃的方法
MY159256A (en) 2010-02-18 2016-12-30 Univation Tech Llc Methods for operating a polymerization reactor
BR112012021122B1 (pt) 2010-02-22 2020-01-07 Univation Technologies, Llc Sistema catalítico, método para preparar o sistema catalítico e método para polimerização de olefinas
WO2011129956A1 (fr) 2010-04-13 2011-10-20 Univation Technologies, Llc Mélanges de polymères et films obtenus à partir de ceux-ci
BR112013000679A2 (pt) 2010-07-16 2016-05-31 Univation Tech Llc sistemas e métodos para medir acúmulo de partícula em superfícies de reator
WO2012009215A1 (fr) 2010-07-16 2012-01-19 Univation Technologies, Llc Systèmes et procédés pour mesurer la charge statique portée par des particules
WO2012015898A1 (fr) 2010-07-28 2012-02-02 Univation Technologies, Llc Systèmes et procédés pour mesurer la vitesse d'un mélange particule/fluide
US8742041B2 (en) 2010-11-30 2014-06-03 Univation Technologies, Llc Processes for the polymerization of olefins with extracted metal carboxylate salts
JP5859561B2 (ja) 2010-11-30 2016-02-10 ユニベーション・テクノロジーズ・エルエルシー 改善された流動特性を有する触媒組成物並びにその製造方法及び使用方法
CN103298842B (zh) 2010-12-17 2016-08-31 尤尼威蒂恩技术有限责任公司 从聚烯烃吹扫气体产物回收烃的***以及方法
RU2577324C2 (ru) 2010-12-22 2016-03-20 Юнивейшн Текнолоджиз, Ллк Добавка для способов полимеризации полиолефина
RU2598023C2 (ru) 2011-05-13 2016-09-20 Юнивейшн Текнолоджиз, Ллк Полученные распылительной сушкой каталитические композиции и способы полимеризации, в которых они применяются
WO2013028283A1 (fr) 2011-08-19 2013-02-28 Univation Technologies, Llc Systèmes de catalyseur et leurs procédés d'utilisation pour la production de produits de polyoléfine
EP2776476B1 (fr) 2011-11-08 2019-03-13 Univation Technologies, LLC Procédés pour la production de polyoléfines avec des systèmes de catalyseur
WO2013070601A2 (fr) 2011-11-08 2013-05-16 Univation Technologies, Llc Procédés de préparation d'un système catalyseur
EP2938434B1 (fr) 2012-12-28 2022-05-04 Univation Technologies, LLC Catalyseur supporté ayant un écoulement amélioré
US20150353651A1 (en) 2013-01-30 2015-12-10 Univation Technologies, Llc Processes for making catalyst compositions having improved flow
KR102113899B1 (ko) 2013-02-07 2020-05-21 유니베이션 테크놀로지즈, 엘엘씨 폴리올레핀의 제조
JP6360549B2 (ja) 2013-03-15 2018-07-18 ユニベーション・テクノロジーズ・エルエルシー オレフィン重合触媒用の三座窒素系配位子
CN107266620B (zh) 2013-03-15 2020-09-01 尤尼威蒂恩技术有限责任公司 催化剂的配体
EP2970525B1 (fr) 2013-03-15 2021-03-24 Univation Technologies, LLC Système de catalyseur multiple comprenant des métallocènes et des complexes de ligand à base d'azote tridentate pour la polymérisation des oléfines
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BR112017003306B1 (pt) 2014-08-19 2022-03-03 Univation Technologies, Llc Método para preparar um suporte de catalisador fluorado e sistema de catalisador
US10208139B2 (en) 2014-08-19 2019-02-19 Univation Technologies, Llc Fluorinated catalyst supports and catalyst systems
EP3915759A1 (fr) 2015-01-21 2021-12-01 Univation Technologies, LLC Procédé de commande d'une scission de chaînes polymères
WO2016118566A1 (fr) 2015-01-21 2016-07-28 Univation Technologies, Llc Procédés de réduction de la teneur en gel des polyoléfines
SG11201707037TA (en) 2015-03-10 2017-09-28 Univation Tech Llc Spray dried catalyst compositions, methods for preparation and use in olefin polymerization processes
BR112017021161B1 (pt) 2015-04-08 2021-12-07 Univation Technologies, Llc Método para a transição de um reator de polimerização em fase gasosa
EP3283532B1 (fr) 2015-04-17 2022-05-18 Univation Technologies, LLC Procédés et systèmes permettant la polymérisation d'oléfines
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EP3288984B1 (fr) 2015-04-27 2023-08-09 Univation Technologies, LLC Compositions de catalyseur supporté aux propriétés de coulabilité améliorées et leur préparation
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WO2021119089A1 (fr) 2019-12-11 2021-06-17 Exxonmobil Chemical Patents Inc. Procédés d'introduction d'activateurs liquides dans des réactions de polymérisation d'oléfines
WO2021126523A1 (fr) 2019-12-19 2021-06-24 Exxonmobil Chemical Patents Inc. Production d'un copolymère de polypropylène résistant aux chocs à l'aide de catalyseurs métallocène et ziegler-natta dans des réacteurs parallèles
US20230141606A1 (en) 2020-03-25 2023-05-11 Exxonmobil Chemical Patents Inc. Alkylation of Transition Metal Coordination Catalyst Complexes
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Also Published As

Publication number Publication date
WO2001030860A1 (fr) 2001-05-03
RU2002112853A (ru) 2004-01-20
JP3746234B2 (ja) 2006-02-15
IL149174A0 (en) 2002-11-10
JP2003513113A (ja) 2003-04-08
KR100567304B1 (ko) 2006-04-04
NO20021863D0 (no) 2002-04-19
BR0015241A (pt) 2002-12-24
CA2387877C (fr) 2006-12-19
EP1226191B1 (fr) 2005-07-20
AU5134800A (en) 2001-05-08
TW538051B (en) 2003-06-21
DE60021405T2 (de) 2006-05-18
EP1226191A1 (fr) 2002-07-31
EG22573A (en) 2003-04-30
CN1184242C (zh) 2005-01-12
SA00210261B1 (ar) 2005-11-23
NO20021863L (no) 2002-06-21
CZ20021401A3 (cs) 2002-10-16
BR0015241B1 (pt) 2010-10-05
KR20020081207A (ko) 2002-10-26
MY126752A (en) 2006-10-31
RU2241717C2 (ru) 2004-12-10
AU764962B2 (en) 2003-09-04
CA2387877A1 (fr) 2001-05-03
PL354578A1 (en) 2004-01-26
MXPA02004000A (es) 2002-10-23
CN1382162A (zh) 2002-11-27
TR200201083T2 (tr) 2002-10-21
AR025163A1 (es) 2002-11-13
ATE299898T1 (de) 2005-08-15
DE60021405D1 (de) 2005-08-25

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