SG11201610495QA - Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene - Google Patents

Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene

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Publication number
SG11201610495QA
SG11201610495QA SG11201610495QA SG11201610495QA SG11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA SG 11201610495Q A SG11201610495Q A SG 11201610495QA
Authority
SG
Singapore
Prior art keywords
oligomerization
octene
hexene
ethylene
produce
Prior art date
Application number
SG11201610495QA
Other languages
English (en)
Inventor
Mohammed H Al-Hazmi
Abdullah Alqahtani
Uwe Rosenthal
Bernd H Muller
Normen N Peulecke
Marco Harff
Anina Wohl
Andreas Meiswinkle
Heinz Bolt
Wolfgang Muller
Original Assignee
Sabic Global Technologies Bv
Linde Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sabic Global Technologies Bv, Linde Ag filed Critical Sabic Global Technologies Bv
Publication of SG11201610495QA publication Critical patent/SG11201610495QA/en

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187Amide derivatives thereof
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00Aliphatic unsaturated hydrocarbons
    • C07C11/02Alkenes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/30Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/32Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08Catalytic processes
    • C07C2/26Catalytic processes with hydrides or organic compounds
    • C07C2/36Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20Olefin oligomerisation or telomerisation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62Chromium
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/18Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22Organic complexes
    • CCHEMISTRY; METALLURGY
    • C07ORGANIC CHEMISTRY
    • C07CACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24Phosphines
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/50Improvements relating to the production of bulk chemicals
    • Y02P20/52Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
SG11201610495QA 2014-07-24 2015-07-22 Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene SG11201610495QA (en)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US201462028558P 2014-07-24 2014-07-24
PCT/IB2015/055532 WO2016012948A1 (en) 2014-07-24 2015-07-22 Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene

Publications (1)

Publication Number Publication Date
SG11201610495QA true SG11201610495QA (en) 2017-01-27

Family

ID=54199271

Family Applications (1)

Application Number Title Priority Date Filing Date
SG11201610495QA SG11201610495QA (en) 2014-07-24 2015-07-22 Catalyst composition and process for oligomerization of ethylene to produce 1-hexene and/or 1-octene

Country Status (14)

Country Link
US (1) US10421064B2 (ko)
EP (1) EP3171974B1 (ko)
JP (1) JP6598846B2 (ko)
KR (1) KR20170035889A (ko)
CN (1) CN106573236B (ko)
AR (1) AR101298A1 (ko)
BR (1) BR112017001004A2 (ko)
CA (1) CA2954836C (ko)
ES (1) ES2676354T3 (ko)
MX (1) MX2017000799A (ko)
RU (1) RU2665551C1 (ko)
SG (1) SG11201610495QA (ko)
TW (1) TWI615380B (ko)
WO (1) WO2016012948A1 (ko)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017093940A1 (en) * 2015-12-04 2017-06-08 Sabic Global Technologies B.V. Process for flushing an oligomerization reactor and oligomerization of an olefin
EP3266757B1 (de) * 2016-07-08 2019-12-25 Evonik Operations GmbH Herstellung von zumindest 1-hexen und octen aus ethen
EP3562586A1 (en) * 2016-12-30 2019-11-06 SABIC Global Technologies B.V. Methods of producing linear alpha olefins
WO2018170054A1 (en) 2017-03-14 2018-09-20 Saudi Arabian Oil Company Process for ethylene oligomerization to produce alpha-olefins
ES2943660T3 (es) * 2018-11-12 2023-06-15 Sabic Global Technologies Bv Ligandos para la producción de 1-octeno en el proceso de oligomerización de etileno asistido por cromo
CN113260457B (zh) * 2018-11-12 2024-04-02 沙特基础全球技术有限公司 用于铬辅助乙烯低聚工艺中生产1-己烯的配体
JP7502325B2 (ja) * 2019-03-19 2024-06-18 サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ クロム補助エチレンオリゴマー化方法において1-オクテンを製造するための配位子
CN110801864B (zh) * 2019-10-23 2022-08-19 迈瑞尔实验设备(上海)有限公司 一种乙烯四聚催化剂组合物及其应用
WO2023118226A1 (en) 2021-12-23 2023-06-29 Sabic Global Technologies B.V. Catalyst composition for oligomerization reaction

Family Cites Families (12)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
JP4266827B2 (ja) 2001-12-20 2009-05-20 サソル テクノロジー (ピーティーワイ)リミテッド クロムを主成分とした触媒を使用したオレフィン類の三量化およびオリゴマー化
ATE457196T1 (de) 2002-12-20 2010-02-15 Sasol Tech Pty Ltd Trimerisierung von olefinen
KR100752372B1 (ko) * 2006-04-10 2007-08-27 희성엥겔하드주식회사 황화수소 저감을 위한 제오라이트를 포함한 배기가스정화용 촉매조성물
SG191441A1 (en) 2006-12-22 2013-07-31 Shell Int Research Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
CA2583007C (en) 2007-03-29 2015-03-31 Nova Chemicals Corporation Amino phosphine
CN101687189A (zh) * 2007-05-28 2010-03-31 Sasol技术股份有限公司 低聚催化剂的两段活化和在如此活化的低聚催化剂的存在下烯属化合物的低聚
MY148675A (en) * 2007-07-11 2013-05-31 Linde Ag Catalyst composition and process for di-, tri-and/or tetramerization of ethylene
MX2010005266A (es) * 2007-11-28 2010-06-02 Linde Ag Composicion catalizadora y proceso para oligomerizacion de etileno.
ES2371218T3 (es) 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
CA2716714C (en) 2010-10-06 2017-05-16 Nova Chemicals Corporation Tetramerization ligands
KR101846031B1 (ko) * 2012-03-16 2018-04-05 에스케이이노베이션 주식회사 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계

Also Published As

Publication number Publication date
TW201619097A (zh) 2016-06-01
WO2016012948A1 (en) 2016-01-28
US10421064B2 (en) 2019-09-24
CN106573236A (zh) 2017-04-19
RU2665551C1 (ru) 2018-08-31
KR20170035889A (ko) 2017-03-31
CN106573236B (zh) 2020-05-29
ES2676354T3 (es) 2018-07-18
JP2017523908A (ja) 2017-08-24
EP3171974B1 (en) 2018-04-18
US20170203288A1 (en) 2017-07-20
BR112017001004A2 (pt) 2017-11-14
CA2954836A1 (en) 2016-01-28
JP6598846B2 (ja) 2019-10-30
TWI615380B (zh) 2018-02-21
MX2017000799A (es) 2017-05-04
AR101298A1 (es) 2016-12-07
CA2954836C (en) 2018-10-09
EP3171974A1 (en) 2017-05-31

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