AR101298A1 - Composición catalizadora y proceso para la oligomerización de etileno para producir 1-hexeno y/o 1-octeno - Google Patents

Composición catalizadora y proceso para la oligomerización de etileno para producir 1-hexeno y/o 1-octeno

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Publication number
AR101298A1
AR101298A1 ARP150102351A ARP150102351A AR101298A1 AR 101298 A1 AR101298 A1 AR 101298A1 AR P150102351 A ARP150102351 A AR P150102351A AR P150102351 A ARP150102351 A AR P150102351A AR 101298 A1 AR101298 A1 AR 101298A1
Authority
AR
Argentina
Prior art keywords
oligomerization
octene
ethylene
produce
hexeno
Prior art date
Application number
ARP150102351A
Other languages
English (en)
Inventor
H Al-Hazmi Mohammed
Alqahtani Abdullah
Rosenthal Uwe
H Mller Bernd
Peulecke Normen
Harff Marco
Whl Anina
Meiswinkel Andreas
Blt Heinz
Mller Wolfgang
Original Assignee
Sabic Global Technologies Bv
Linde Ag
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Sabic Global Technologies Bv, Linde Ag filed Critical Sabic Global Technologies Bv
Publication of AR101298A1 publication Critical patent/AR101298A1/es

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    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/189—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms containing both nitrogen and phosphorus as complexing atoms, including e.g. phosphino moieties, in one at least bidentate or bridging ligand
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • B01J31/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms
    • B01J31/1845—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony as complexing atoms, e.g. in pyridine ligands, or in resonance therewith, e.g. in isocyanide ligands C=N-R or as complexed central atoms the ligands containing phosphorus
    • B01J31/1865—Phosphonites (RP(OR)2), their isomeric phosphinates (R2(RO)P=O) and RO-substitution derivatives thereof
    • B01J31/187—Amide derivatives thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • B01J31/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • B01J31/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • B01J31/143—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron of aluminium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J31/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • B01J31/26—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24
    • B01J31/34—Catalysts comprising hydrides, coordination complexes or organic compounds containing in addition, inorganic metal compounds not provided for in groups B01J31/02 - B01J31/24 of chromium, molybdenum or tungsten
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C11/00—Aliphatic unsaturated hydrocarbons
    • C07C11/02—Alkenes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/30—Catalytic processes with hydrides or organic compounds containing metal-to-carbon bond; Metal hydrides
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/32—Catalytic processes with hydrides or organic compounds as complexes, e.g. acetyl-acetonates
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2/00—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
    • C07C2/02—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons
    • C07C2/04—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
    • C07C2/06—Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms by addition between unsaturated hydrocarbons by oligomerisation of well-defined unsaturated hydrocarbons without ring formation of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
    • C07C2/08—Catalytic processes
    • C07C2/26—Catalytic processes with hydrides or organic compounds
    • C07C2/36—Catalytic processes with hydrides or organic compounds as phosphines, arsines, stilbines or bismuthines
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2231/00—Catalytic reactions performed with catalysts classified in B01J31/00
    • B01J2231/20—Olefin oligomerisation or telomerisation
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J2531/00—Additional information regarding catalytic systems classified in B01J31/00
    • B01J2531/60—Complexes comprising metals of Group VI (VIA or VIB) as the central metal
    • B01J2531/62—Chromium
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/02—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides
    • C07C2531/12—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides
    • C07C2531/14—Catalysts comprising hydrides, coordination complexes or organic compounds containing organic compounds or metal hydrides containing organo-metallic compounds or metal hydrides of aluminium or boron
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/18—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes containing nitrogen, phosphorus, arsenic or antimony
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/22—Organic complexes
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C2531/00—Catalysts comprising hydrides, coordination complexes or organic compounds
    • C07C2531/16—Catalysts comprising hydrides, coordination complexes or organic compounds containing coordination complexes
    • C07C2531/24—Phosphines
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Catalysts (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

Abstract

La presente se refiere a una composición catalizadora y un proceso para la oligomerización de etileno para producir 1-hexeno o 1-octeno, donde la composición catalizadora comprende un compuesto de cromo; un ligando NPNPN de la fórmula (R¹)(R²)N-P(R³)-N(R⁴)-P(R⁵)-N(R⁶)(R⁷), donde R¹, R², R³, R⁴, R⁵, R⁶, y R⁷ son cada uno independientemente hidrógeno, halógeno, amino, trimetilsilil o hidrocarbilo C₁₋₂₀, preferentemente alquilo C₁₋₁₀ de cadena recta o ramificada, fenilo, arilo C₆₋₂₀ o fenilo alquil-sustituido C₆₋₂₀.
ARP150102351A 2014-07-24 2015-07-24 Composición catalizadora y proceso para la oligomerización de etileno para producir 1-hexeno y/o 1-octeno AR101298A1 (es)

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
US201462028558P 2014-07-24 2014-07-24

Publications (1)

Publication Number Publication Date
AR101298A1 true AR101298A1 (es) 2016-12-07

Family

ID=54199271

Family Applications (1)

Application Number Title Priority Date Filing Date
ARP150102351A AR101298A1 (es) 2014-07-24 2015-07-24 Composición catalizadora y proceso para la oligomerización de etileno para producir 1-hexeno y/o 1-octeno

Country Status (14)

Country Link
US (1) US10421064B2 (es)
EP (1) EP3171974B1 (es)
JP (1) JP6598846B2 (es)
KR (1) KR20170035889A (es)
CN (1) CN106573236B (es)
AR (1) AR101298A1 (es)
BR (1) BR112017001004A2 (es)
CA (1) CA2954836C (es)
ES (1) ES2676354T3 (es)
MX (1) MX2017000799A (es)
RU (1) RU2665551C1 (es)
SG (1) SG11201610495QA (es)
TW (1) TWI615380B (es)
WO (1) WO2016012948A1 (es)

Families Citing this family (9)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
WO2017093940A1 (en) * 2015-12-04 2017-06-08 Sabic Global Technologies B.V. Process for flushing an oligomerization reactor and oligomerization of an olefin
EP3266757B1 (de) * 2016-07-08 2019-12-25 Evonik Operations GmbH Herstellung von zumindest 1-hexen und octen aus ethen
EP3562586A1 (en) * 2016-12-30 2019-11-06 SABIC Global Technologies B.V. Methods of producing linear alpha olefins
WO2018170054A1 (en) 2017-03-14 2018-09-20 Saudi Arabian Oil Company Process for ethylene oligomerization to produce alpha-olefins
ES2943660T3 (es) * 2018-11-12 2023-06-15 Sabic Global Technologies Bv Ligandos para la producción de 1-octeno en el proceso de oligomerización de etileno asistido por cromo
CN113260457B (zh) * 2018-11-12 2024-04-02 沙特基础全球技术有限公司 用于铬辅助乙烯低聚工艺中生产1-己烯的配体
JP7502325B2 (ja) * 2019-03-19 2024-06-18 サビック グローバル テクノロジーズ ベスローテン フェンノートシャップ クロム補助エチレンオリゴマー化方法において１－オクテンを製造するための配位子
CN110801864B (zh) * 2019-10-23 2022-08-19 迈瑞尔实验设备（上海）有限公司 一种乙烯四聚催化剂组合物及其应用
WO2023118226A1 (en) 2021-12-23 2023-06-29 Sabic Global Technologies B.V. Catalyst composition for oligomerization reaction

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Publication number Priority date Publication date Assignee Title
GB0016895D0 (en) 2000-07-11 2000-08-30 Bp Chem Int Ltd Olefin oligomerisation
JP4266827B2 (ja) 2001-12-20 2009-05-20 サソル テクノロジー （ピーティーワイ）リミテッド クロムを主成分とした触媒を使用したオレフィン類の三量化およびオリゴマー化
ATE457196T1 (de) 2002-12-20 2010-02-15 Sasol Tech Pty Ltd Trimerisierung von olefinen
KR100752372B1 (ko) * 2006-04-10 2007-08-27 희성엥겔하드주식회사 황화수소 저감을 위한 제오라이트를 포함한 배기가스정화용 촉매조성물
SG191441A1 (en) 2006-12-22 2013-07-31 Shell Int Research Ligands and catalyst systems thereof for the catalytic oligomerization of olefinic monomers
CA2583007C (en) 2007-03-29 2015-03-31 Nova Chemicals Corporation Amino phosphine
CN101687189A (zh) * 2007-05-28 2010-03-31 Sasol技术股份有限公司 低聚催化剂的两段活化和在如此活化的低聚催化剂的存在下烯属化合物的低聚
MY148675A (en) * 2007-07-11 2013-05-31 Linde Ag Catalyst composition and process for di-, tri-and/or tetramerization of ethylene
MX2010005266A (es) * 2007-11-28 2010-06-02 Linde Ag Composicion catalizadora y proceso para oligomerizacion de etileno.
ES2371218T3 (es) 2009-04-09 2011-12-28 Saudi Basic Industries Corporation Composición de catalizador y procedimiento para la oligomerización de etileno.
CA2716714C (en) 2010-10-06 2017-05-16 Nova Chemicals Corporation Tetramerization ligands
KR101846031B1 (ko) * 2012-03-16 2018-04-05 에스케이이노베이션 주식회사 에틸렌으로부터 1-헥센 및/또는 1-옥텐을 제조하기 위한 촉매계

Also Published As

Publication number Publication date
TW201619097A (zh) 2016-06-01
WO2016012948A1 (en) 2016-01-28
US10421064B2 (en) 2019-09-24
CN106573236A (zh) 2017-04-19
RU2665551C1 (ru) 2018-08-31
KR20170035889A (ko) 2017-03-31
CN106573236B (zh) 2020-05-29
SG11201610495QA (en) 2017-01-27
ES2676354T3 (es) 2018-07-18
JP2017523908A (ja) 2017-08-24
EP3171974B1 (en) 2018-04-18
US20170203288A1 (en) 2017-07-20
BR112017001004A2 (pt) 2017-11-14
CA2954836A1 (en) 2016-01-28
JP6598846B2 (ja) 2019-10-30
TWI615380B (zh) 2018-02-21
MX2017000799A (es) 2017-05-04
CA2954836C (en) 2018-10-09
EP3171974A1 (en) 2017-05-31

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