RU2019133873A - Прозрачная древесина и способ ее получения - Google Patents

Прозрачная древесина и способ ее получения Download PDF

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RU2019133873A
RU2019133873A RU2019133873A RU2019133873A RU2019133873A RU 2019133873 A RU2019133873 A RU 2019133873A RU 2019133873 A RU2019133873 A RU 2019133873A RU 2019133873 A RU2019133873 A RU 2019133873A RU 2019133873 A RU2019133873 A RU 2019133873A
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wood
transparent wood
transparent
substrate
lignin
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RU2019133873A
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RU2755823C2 (ru
RU2019133873A3 (ru
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Юаньюань ЛИ
Рамиро РОХАС
Ларс БЕРГЛУНД
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Селлутек Аб
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/15Impregnating involving polymerisation including use of polymer-containing impregnating agents
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/04Combined bleaching or impregnating and drying of wood
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials
    • C08L97/02Lignocellulosic material, e.g. wood, straw or bagasse
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/0207Pretreatment of wood before impregnation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K3/00Impregnating wood, e.g. impregnation pretreatment, for example puncturing; Wood impregnation aids not directly involved in the impregnation process
    • B27K3/02Processes; Apparatus
    • B27K3/0278Processes; Apparatus involving an additional treatment during or after impregnation
    • B27K3/0292Processes; Apparatus involving an additional treatment during or after impregnation for improving fixation
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B27WORKING OR PRESERVING WOOD OR SIMILAR MATERIAL; NAILING OR STAPLING MACHINES IN GENERAL
    • B27KPROCESSES, APPARATUS OR SELECTION OF SUBSTANCES FOR IMPREGNATING, STAINING, DYEING, BLEACHING OF WOOD OR SIMILAR MATERIALS, OR TREATING OF WOOD OR SIMILAR MATERIALS WITH PERMEANT LIQUIDS, NOT OTHERWISE PROVIDED FOR; CHEMICAL OR PHYSICAL TREATMENT OF CORK, CANE, REED, STRAW OR SIMILAR MATERIALS
    • B27K5/00Treating of wood not provided for in groups B27K1/00, B27K3/00
    • B27K5/02Staining or dyeing wood; Bleaching wood
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L25/00Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
    • C08L25/02Homopolymers or copolymers of hydrocarbons
    • C08L25/04Homopolymers or copolymers of styrene
    • C08L25/06Polystyrene
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04Homopolymers or copolymers of esters
    • C08L33/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/10Homopolymers or copolymers of methacrylic acid esters
    • C08L33/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • C09D133/04Homopolymers or copolymers of esters
    • C09D133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09D133/10Homopolymers or copolymers of methacrylic acid esters
    • C09D133/12Homopolymers or copolymers of methyl methacrylate
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08HDERIVATIVES OF NATURAL MACROMOLECULAR COMPOUNDS
    • C08H8/00Macromolecular compounds derived from lignocellulosic materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/10Transparent films; Clear coatings; Transparent materials
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L97/00Compositions of lignin-containing materials

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Forests & Forestry (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Chemical And Physical Treatments For Wood And The Like (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

Claims (17)

1. Прозрачная древесина, содержащая древесный субстрат и по меньшей мере один полимер, где указанная прозрачная древесина имеет оптический коэффициент пропускания по меньшей мере 60% при длине волны в электромагнитном спектре длин волн от 400 до 1000 нм, и где древесный субстрат содержит более 15% лигнина, измеренного как лигнин Класона.
2. Прозрачная древесина по п. 1, дополнительно характеризующаяся мутностью по меньшей мере 60% при длине волны в электромагнитном спектре длин волн от 400 до 1000 нм.
3. Прозрачная древесина по п. 1 или 2, оптический коэффициент пропускания которой составляет по меньшей мере 70%.
4. Прозрачная древесина по любому из пп. 1-3, имеющая толщину по меньшей мере 0,3 мм.
5. Прозрачная древесина по любому из пп. 1-4, в которой полимер имеет показатель преломления от 1,3 до 1,7.
6. Способ получения прозрачной древесины, включающий стадии:
- получения по меньшей мере одного куска древесного субстрата;
- добавления отбеливающей жидкости для того, чтобы инактивировать хромофоры в древесном субстрате, с получением таким образом отбеленного древесного субстрата, содержащего по меньшей мере 15% лигнина;
- пропитки отбеленного древесного субстрата, полученного на стадии (b), раствором, содержащим пре-полимеры или мономеры, или их комбинацию,
- полимеризации пропитывающих пре-полимеров или мономеров, или их комбинации, с получением прозрачной древесины, содержащей древесный субстрат и по меньшей мере один полимер.
7. Способ по п. 6, в котором пероксидные системы, используемые на стадии (b), содержат пероксид водорода.
8. Способ по любому из пп. 6, 7, дополнительно включающий стадию удаления ионов металлов из куска древесины на стадии (a), например путем добавления DTPA, перед добавлением отбеливающей жидкости на стадии (b).
9. Способ по любому из пп. 6-8, в котором отбеливание древесины на стадии (b) проводят до тех пор, пока древесный субстрат не приобретет яркость по меньшей мере 70%.
10. Способ по любому из пп. 6-9, в котором отбеливающая жидкость на стадии (b) дополнительно содержит стабилизаторы и хелатообразующие реагенты.
11. Способ по любому из пп. 6-10, дополнительно включающий стадию обмена с растворителем после получения отбеленной древесины на стадии (b).
12. Способ по любому из пп. 6-11, в котором полимер, полученный на стадии (d), имеет показатель преломления от 1,3 до 1,7.
13. Прозрачная древесина, полученная способом по любому из пп. 6-12, в которой древесный субстрат содержит более 15% лигнина, измеренного как лигнин Класона.
RU2019133873A 2017-03-29 2018-03-29 Прозрачная древесина и способ ее получения RU2755823C2 (ru)

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Application Number Priority Date Filing Date Title
SE1750376 2017-03-29
SE1750376-4 2017-03-29
PCT/SE2018/050344 WO2018182497A1 (en) 2017-03-29 2018-03-29 Transparent wood and a method for its preparation

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RU2019133873A true RU2019133873A (ru) 2021-04-29
RU2019133873A3 RU2019133873A3 (ru) 2021-07-19
RU2755823C2 RU2755823C2 (ru) 2021-09-21

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EP (1) EP3600806B1 (ru)
JP (1) JP7101699B2 (ru)
CN (1) CN110603124B (ru)
AU (1) AU2018245016B2 (ru)
CA (1) CA3055904A1 (ru)
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RU2755823C2 (ru) 2017-03-29 2021-09-21 Селлутек Аб Прозрачная древесина и способ ее получения
FR3067275B1 (fr) 2017-06-07 2022-08-12 Timothee Boitouzet Procede de delignification partielle par voie supercritique ou subcritique et de remplissage d'un materiau ligno-cellulosique
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RU2755823C2 (ru) 2021-09-21
JP2020515437A (ja) 2020-05-28
WO2018182497A1 (en) 2018-10-04
EP3600806A1 (en) 2020-02-05
US11602872B2 (en) 2023-03-14
EP3600806A4 (en) 2021-01-20
CN110603124B (zh) 2022-03-04
CA3055904A1 (en) 2018-10-04
JP7101699B2 (ja) 2022-07-15
EP3600806B1 (en) 2023-06-07
RU2019133873A3 (ru) 2021-07-19
US20200023546A1 (en) 2020-01-23
AU2018245016A1 (en) 2019-11-07
CN110603124A (zh) 2019-12-20
AU2018245016B2 (en) 2023-06-08

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