RU2015155269A - Способ изготовления анионообменных и халатирующих смол, включающих в свою структуру амино-алифатические функциональные группировки - Google Patents
Способ изготовления анионообменных и халатирующих смол, включающих в свою структуру амино-алифатические функциональные группировки Download PDFInfo
- Publication number
- RU2015155269A RU2015155269A RU2015155269A RU2015155269A RU2015155269A RU 2015155269 A RU2015155269 A RU 2015155269A RU 2015155269 A RU2015155269 A RU 2015155269A RU 2015155269 A RU2015155269 A RU 2015155269A RU 2015155269 A RU2015155269 A RU 2015155269A
- Authority
- RU
- Russia
- Prior art keywords
- nitro compound
- vinyl aromatic
- polymer
- aromatic polymer
- chalating
- Prior art date
Links
- 238000005349 anion exchange Methods 0.000 title claims 2
- 238000004519 manufacturing process Methods 0.000 title 1
- 229920005989 resin Polymers 0.000 title 1
- 239000011347 resin Substances 0.000 title 1
- 238000000034 method Methods 0.000 claims 7
- 150000002828 nitro derivatives Chemical class 0.000 claims 6
- 229920000642 polymer Polymers 0.000 claims 6
- 229920002554 vinyl polymer Polymers 0.000 claims 4
- 239000003153 chemical reaction reagent Substances 0.000 claims 3
- 239000002184 metal Substances 0.000 claims 3
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 claims 2
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims 2
- 125000004432 carbon atom Chemical group C* 0.000 claims 2
- 238000006243 chemical reaction Methods 0.000 claims 2
- 125000000449 nitro group Chemical group [O-][N+](*)=O 0.000 claims 2
- JSZOAYXJRCEYSX-UHFFFAOYSA-N 1-nitropropane Chemical compound CCC[N+]([O-])=O JSZOAYXJRCEYSX-UHFFFAOYSA-N 0.000 claims 1
- FGLBSLMDCBOPQK-UHFFFAOYSA-N 2-nitropropane Chemical compound CC(C)[N+]([O-])=O FGLBSLMDCBOPQK-UHFFFAOYSA-N 0.000 claims 1
- 125000003118 aryl group Chemical group 0.000 claims 1
- 229910052799 carbon Inorganic materials 0.000 claims 1
- 229920001429 chelating resin Polymers 0.000 claims 1
- 238000003487 electrochemical reaction Methods 0.000 claims 1
- 125000000524 functional group Chemical group 0.000 claims 1
- 125000004435 hydrogen atom Chemical group [H]* 0.000 claims 1
- 125000004971 nitroalkyl group Chemical group 0.000 claims 1
- MCSAJNNLRCFZED-UHFFFAOYSA-N nitroethane Chemical compound CC[N+]([O-])=O MCSAJNNLRCFZED-UHFFFAOYSA-N 0.000 claims 1
- LYGJENNIWJXYER-UHFFFAOYSA-N nitromethane Chemical compound C[N+]([O-])=O LYGJENNIWJXYER-UHFFFAOYSA-N 0.000 claims 1
- 230000003647 oxidation Effects 0.000 claims 1
- 238000007254 oxidation reaction Methods 0.000 claims 1
- 239000011541 reaction mixture Substances 0.000 claims 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/14—Macromolecular compounds obtained by reactions only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/05—Processes using organic exchangers in the strongly basic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/04—Processes using organic exchangers
- B01J41/07—Processes using organic exchangers in the weakly basic form
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J41/00—Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/08—Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
- B01J41/12—Macromolecular compounds
- B01J41/13—Macromolecular compounds obtained otherwise than by reactions only involving unsaturated carbon-to-carbon bonds
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J45/00—Ion-exchange in which a complex or a chelate is formed; Use of material as complex or chelate forming ion-exchangers; Treatment of material for improving the complex or chelate forming ion-exchange properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
- C08F212/34—Monomers containing two or more unsaturated aliphatic radicals
- C08F212/36—Divinylbenzene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/04—Reduction, e.g. hydrogenation
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- General Chemical & Material Sciences (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Manufacture Of Macromolecular Shaped Articles (AREA)
Claims (9)
1. Способ получения анионоообменной или хелатирующей смолы, включающий в себя такие стадии, как:
i) проведение взаимодействия винилового ароматического полимера с нитро-соединением с образованием полимера, содержащего в своей структуре повторяющееся структурное звено, содержащее в своем составе ароматический кольцевой фрагмент, замещенный нитрогруппой, в котором нитро-соединение, предпочтительно, содержит в своей структуре в интервале 1-12 углеродных атомов, при условии, что альфа (α) углеродный атом, несет, по меньшей мере, один атом водорода и
ii) восстановление нитрогруппы с образованием амино-алифатической функциональной группировки.
2. Способ по п.1, в котором нитро-соединение представляет собой нитроалкан.
3. Способ по п.1, в котором нитро-соединение выбирают из, по меньшей мере, одного из: нитрометана, нитроэтана, 1-нитропропана и 2-нитропропана.
4. Способ по п.1, в котором реакцию между виниловым ароматическим полимером и нитро-соединением проводят в присутствии металлического реагента, обладающего восстановительным потенциалом, составляющим в интервале 1,0 до 2,5 В.
5. Способ по п.1, отличающийся тем, что реакцию между виниловым ароматическим полимером и нитро-соединением проводят в присутствии металлического реагента, выбираемого из, по меньшей мере, одного из: Mn+3 и Ce+4.
6. Способ по п.1, в котором металлический реагент регенерируют посредством электрохимических реакций путем анодного окисления.
7. Способ по п.1, в котором виниловый ароматический полимер представляет собой полимер, получаемый из реакционной смеси, содержащей стирол и дивинилбензол.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| US201361836769P | 2013-06-19 | 2013-06-19 | |
| US61/836,769 | 2013-06-19 | ||
| PCT/US2014/041458 WO2014204686A1 (en) | 2013-06-19 | 2014-06-09 | Method for making anion exchange and chelant resins including aliphatic amino functional groups |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| RU2015155269A true RU2015155269A (ru) | 2017-07-24 |
| RU2658003C2 RU2658003C2 (ru) | 2018-06-19 |
Family
ID=51062993
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| RU2015155269A RU2658003C2 (ru) | 2013-06-19 | 2014-06-09 | Способ изготовления анионообменных и хелатирующих смол, включающих в свою структуру амино-алифатические функциональные группировки |
Country Status (7)
| Country | Link |
|---|---|
| US (1) | US9486798B2 (ru) |
| EP (1) | EP2986651B1 (ru) |
| JP (1) | JP6185663B2 (ru) |
| KR (1) | KR102167236B1 (ru) |
| CN (1) | CN105263971B (ru) |
| RU (1) | RU2658003C2 (ru) |
| WO (1) | WO2014204686A1 (ru) |
Family Cites Families (28)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| NL241315A (ru) | 1958-07-18 | |||
| US3791996A (en) * | 1971-11-01 | 1974-02-12 | Rohm & Haas | Direct acylaminomethylation of aromatic polymers |
| JPS5326889A (en) * | 1976-08-25 | 1978-03-13 | Kanebo Ltd | Preparation of adsorbent for heavy metals |
| US4666673A (en) | 1980-10-30 | 1987-05-19 | The Dow Chemical Company | Apparatus for preparing large quantities of uniform size drops |
| CA1166413A (en) | 1980-10-30 | 1984-05-01 | Edward E. Timm | Process and apparatus for preparing uniform size polymer beads |
| US4419245A (en) | 1982-06-30 | 1983-12-06 | Rohm And Haas Company | Copolymer process and product therefrom consisting of crosslinked seed bead swollen by styrene monomer |
| US4564644A (en) | 1982-08-02 | 1986-01-14 | The Dow Chemical Company | Ion exchange resins prepared by sequential monomer addition |
| US4582859A (en) | 1983-12-02 | 1986-04-15 | Rohm And Haas Company | Process for producing an expanded seed copolymer and product therefrom |
| US4623706A (en) | 1984-08-23 | 1986-11-18 | The Dow Chemical Company | Process for preparing uniformly sized polymer particles by suspension polymerization of vibratorily excited monomers in a gaseous or liquid stream |
| DE3704307A1 (de) | 1987-02-12 | 1988-08-25 | Dow Chemical Gmbh | Komplexbildendes harz des geltyps und seine verwendung zur verringerung der konzentration mehrwertiger erdalkali- und/oder schwermetallionen in loesungen |
| DE3733033A1 (de) | 1987-09-30 | 1989-04-13 | Bayer Ag | Verfahren zur herstellung von kunstharzen mit anionenaustauschenden eigenschaften |
| ZW16289A1 (en) | 1988-12-19 | 1990-03-21 | Mineral Tech Council | Gold selective ion exchange resins |
| USRE34112E (en) | 1989-10-17 | 1992-10-27 | The Dow Chemical Company | Condensate purification process |
| JP2846390B2 (ja) * | 1990-02-14 | 1999-01-13 | 株式会社バイオマテリアル研究所 | 表面にアミノ基を有する光透過性芳香族ビニル系重合体成型品およびその製造方法 |
| US5244926A (en) | 1992-06-16 | 1993-09-14 | The Dow Chemical Company | Preparation of ion exchange and adsorbent copolymers |
| JPH06287221A (ja) * | 1993-03-30 | 1994-10-11 | Maruzen Petrochem Co Ltd | ビニルフェノール系重合体のアミノ化物の製造方法 |
| DE19634393A1 (de) | 1996-08-26 | 1998-03-05 | Bayer Ag | Verfahren zur Herstellung vernetzter Polymerisate |
| US6251996B1 (en) | 1998-12-09 | 2001-06-26 | The Dow Chemical Company | Gel-type copolymer bead and ion-exchange resins made therefrom |
| DE50014560D1 (de) | 1999-08-27 | 2007-09-27 | Lanxess Deutschland Gmbh | Verfahren zur Herstellung von monodispersen, vernetzten Perlpolymerisaten mit Thioharnstoffgruppen und ihre Verwendung zur Adsorption von Metallverbindungen |
| DE10010002A1 (de) * | 2000-03-02 | 2001-09-06 | Celanese Ventures Gmbh | Verfahren zur Nitrierung und Aminierung von Arylpolymer |
| JP4635162B2 (ja) | 2000-04-27 | 2011-02-16 | 独立行政法人理化学研究所 | 芳香族ジアミンの製造方法及び芳香族ジアミン化合物 |
| DE10049807A1 (de) | 2000-10-09 | 2002-04-18 | Bayer Ag | Verwendung monodisperser Ionenaustauscher zur Arsen-/Antimonentfernung |
| US6756462B2 (en) | 2001-07-03 | 2004-06-29 | Rohm And Haas Company | Method for preparation of anion exchange resins |
| DE10214844A1 (de) | 2002-04-04 | 2003-10-16 | Bayer Ag | Verfahren zur Herstellung von grobkörnigen gelförmigen Anionenaustauschern |
| EP1568660B1 (en) | 2004-02-24 | 2010-12-15 | Rohm And Haas Company | Method for removal of arsenic from water |
| US8163138B2 (en) | 2007-05-23 | 2012-04-24 | Dow Global Technologies Llc | Method for processing effluent from chloromethylation of vinyl aromatic polymers |
| EP2396351B1 (en) * | 2009-02-13 | 2013-09-11 | Dow Global Technologies LLC | Amination of vinyl aromatic polymers with tertiary amines |
| RU2429070C1 (ru) * | 2010-02-17 | 2011-09-20 | Олег Алексеевич Шпигун | Анионообменный сорбент для одновременного ионохроматографического определения поляризуемых и неполяризуемых неорганических анионов и способ его изготовления |
-
2014
- 2014-06-09 KR KR1020167000629A patent/KR102167236B1/ko active IP Right Grant
- 2014-06-09 CN CN201480032274.7A patent/CN105263971B/zh not_active Expired - Fee Related
- 2014-06-09 JP JP2016519567A patent/JP6185663B2/ja not_active Expired - Fee Related
- 2014-06-09 US US14/384,101 patent/US9486798B2/en active Active
- 2014-06-09 EP EP14735061.5A patent/EP2986651B1/en not_active Not-in-force
- 2014-06-09 WO PCT/US2014/041458 patent/WO2014204686A1/en active Application Filing
- 2014-06-09 RU RU2015155269A patent/RU2658003C2/ru active
Also Published As
| Publication number | Publication date |
|---|---|
| EP2986651A1 (en) | 2016-02-24 |
| CN105263971A (zh) | 2016-01-20 |
| KR20160037881A (ko) | 2016-04-06 |
| US20160236187A1 (en) | 2016-08-18 |
| CN105263971B (zh) | 2018-04-27 |
| RU2658003C2 (ru) | 2018-06-19 |
| EP2986651B1 (en) | 2017-02-22 |
| KR102167236B1 (ko) | 2020-10-20 |
| JP6185663B2 (ja) | 2017-08-23 |
| WO2014204686A1 (en) | 2014-12-24 |
| JP2016521800A (ja) | 2016-07-25 |
| US9486798B2 (en) | 2016-11-08 |
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