PH26505A - Catalyst for regulating the molecular weight distributor of ethylene polymers - Google Patents

Catalyst for regulating the molecular weight distributor of ethylene polymers Download PDF

Info

Publication number: PH26505A
Authority: PH; Philippines
Prior art keywords: molecular weight; carbon atoms; regulator; catalyst system; silicon
Prior art date: 1988-12-30

Application number

PH39817A

Other languages

English (en)

Inventor

Sun Chueh Kao

Frederick John Karol

Original Assignee

Union Carbide Chem Plastic

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-12-30

Filing date

1989-12-29

Publication date

1992-08-07

1989-12-29 Application filed by Union Carbide Chem Plastic filed Critical Union Carbide Chem Plastic

1992-08-07 Publication of PH26505A publication Critical patent/PH26505A/en

Links

239000003054 catalyst Substances 0.000 title claims description 65
229920000573 polyethylene Polymers 0.000 title description 7
230000001105 regulatory effect Effects 0.000 title description 3
-1 boron halide Chemical class 0.000 claims description 44
238000006116 polymerization reaction Methods 0.000 claims description 41
229910052720 vanadium Inorganic materials 0.000 claims description 38
LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims description 38
125000004432 carbon atom Chemical group C* 0.000 claims description 37
238000009826 distribution Methods 0.000 claims description 30
239000003607 modifier Substances 0.000 claims description 23
125000005234 alkyl aluminium group Chemical group 0.000 claims description 19
XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 18
239000007795 chemical reaction product Substances 0.000 claims description 18
229910052710 silicon Inorganic materials 0.000 claims description 18
239000010703 silicon Substances 0.000 claims description 18
239000011949 solid catalyst Substances 0.000 claims description 18
239000002243 precursor Substances 0.000 claims description 14
229910052796 boron Inorganic materials 0.000 claims description 12
125000001931 aliphatic group Chemical group 0.000 claims description 10
229930195733 hydrocarbon Natural products 0.000 claims description 10
239000004215 Carbon black (E152) Substances 0.000 claims description 9
239000001257 hydrogen Substances 0.000 claims description 8
229910052739 hydrogen Inorganic materials 0.000 claims description 8
239000007787 solid Substances 0.000 claims description 8
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 6
BOTDANWDWHJENH-UHFFFAOYSA-N Tetraethyl orthosilicate Chemical group CCO[Si](OCC)(OCC)OCC BOTDANWDWHJENH-UHFFFAOYSA-N 0.000 claims description 5
150000005826 halohydrocarbons Chemical class 0.000 claims description 5
150000003254 radicals Chemical class 0.000 claims description 5
150000005840 aryl radicals Chemical class 0.000 claims description 4
229910052736 halogen Inorganic materials 0.000 claims description 4
150000002367 halogens Chemical class 0.000 claims description 4
239000012018 catalyst precursor Substances 0.000 claims description 3
125000004429 atom Chemical group 0.000 claims description 2
229930195734 saturated hydrocarbon Natural products 0.000 claims description 2
229910017709 Ni Co Inorganic materials 0.000 claims 1
ZMAPKOCENOWQRE-UHFFFAOYSA-N diethoxy(diethyl)silane Chemical group CCO[Si](CC)(CC)OCC ZMAPKOCENOWQRE-UHFFFAOYSA-N 0.000 claims 1
229920000642 polymer Polymers 0.000 description 34
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 27
239000002904 solvent Substances 0.000 description 22
239000000203 mixture Substances 0.000 description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 14
239000005977 Ethylene Substances 0.000 description 14
WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 12
238000006243 chemical reaction Methods 0.000 description 12
239000007788 liquid Substances 0.000 description 12
239000002002 slurry Substances 0.000 description 12
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 11
150000001875 compounds Chemical class 0.000 description 11
239000002210 silicon-based material Substances 0.000 description 11
238000002360 preparation method Methods 0.000 description 9
229910052757 nitrogen Inorganic materials 0.000 description 8
239000000155 melt Substances 0.000 description 7
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 6
238000001035 drying Methods 0.000 description 6
239000000843 powder Substances 0.000 description 6
YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 6
230000000694 effects Effects 0.000 description 5
239000012530 fluid Substances 0.000 description 5
239000007789 gas Substances 0.000 description 5
238000000034 method Methods 0.000 description 5
239000000047 product Substances 0.000 description 5
239000000377 silicon dioxide Substances 0.000 description 5
VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 4
230000000052 comparative effect Effects 0.000 description 4
150000002170 ethers Chemical class 0.000 description 4
238000010438 heat treatment Methods 0.000 description 4
125000001424 substituent group Chemical group 0.000 description 4
239000004711 α-olefin Substances 0.000 description 4
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 3
ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 3
239000012986 chain transfer agent Substances 0.000 description 3
229910052801 chlorine Inorganic materials 0.000 description 3
239000000460 chlorine Substances 0.000 description 3
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 3
239000000178 monomer Substances 0.000 description 3
238000010926 purge Methods 0.000 description 3
230000009467 reduction Effects 0.000 description 3
WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 2
CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 2
CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
150000001336 alkenes Chemical class 0.000 description 2
125000005907 alkyl ester group Chemical group 0.000 description 2
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
229910052782 aluminium Inorganic materials 0.000 description 2
238000009835 boiling Methods 0.000 description 2
GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 2
229910052794 bromium Inorganic materials 0.000 description 2
229920001577 copolymer Polymers 0.000 description 2
150000001993 dienes Chemical class 0.000 description 2
150000004820 halides Chemical class 0.000 description 2
150000002430 hydrocarbons Chemical class 0.000 description 2
150000002431 hydrogen Chemical class 0.000 description 2
229910010272 inorganic material Inorganic materials 0.000 description 2
239000011147 inorganic material Substances 0.000 description 2
PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 2
QWTDNUCVQCZILF-UHFFFAOYSA-N isopentane Chemical compound CCC(C)C QWTDNUCVQCZILF-UHFFFAOYSA-N 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical class C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
239000002480 mineral oil Substances 0.000 description 2
235000010446 mineral oil Nutrition 0.000 description 2
238000003756 stirring Methods 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
239000008096 xylene Substances 0.000 description 2
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 1
UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
241001663154 Electron Species 0.000 description 1
OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
241000286904 Leptothecata Species 0.000 description 1
239000002879 Lewis base Substances 0.000 description 1
229910019142 PO4 Inorganic materials 0.000 description 1
239000004698 Polyethylene Substances 0.000 description 1
108700038496 S-(4-azidophenacyl)glutathione Proteins 0.000 description 1
BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
229910021551 Vanadium(III) chloride Inorganic materials 0.000 description 1
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 1
LNUFLCYMSVYYNW-ZPJMAFJPSA-N [(2r,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[(2r,3r,4s,5r,6r)-6-[[(3s,5s,8r,9s,10s,13r,14s,17r)-10,13-dimethyl-17-[(2r)-6-methylheptan-2-yl]-2,3,4,5,6,7,8,9,11,12,14,15,16,17-tetradecahydro-1h-cyclopenta[a]phenanthren-3-yl]oxy]-4,5-disulfo Chemical compound O([C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1[C@@H](COS(O)(=O)=O)O[C@H]([C@@H]([C@H]1OS(O)(=O)=O)OS(O)(=O)=O)O[C@@H]1C[C@@H]2CC[C@H]3[C@@H]4CC[C@@H]([C@]4(CC[C@@H]3[C@@]2(C)CC1)C)[C@H](C)CCCC(C)C)[C@H]1O[C@H](COS(O)(=O)=O)[C@@H](OS(O)(=O)=O)[C@H](OS(O)(=O)=O)[C@H]1OS(O)(=O)=O LNUFLCYMSVYYNW-ZPJMAFJPSA-N 0.000 description 1
239000002253 acid Substances 0.000 description 1
150000007513 acids Chemical class 0.000 description 1
238000005054 agglomeration Methods 0.000 description 1
230000002776 aggregation Effects 0.000 description 1
OFHCOWSQAMBJIW-AVJTYSNKSA-N alfacalcidol Chemical compound C1(/[C@@H]2CC[C@@H]([C@]2(CCC1)C)[C@H](C)CCCC(C)C)=C\C=C1\C[C@@H](O)C[C@H](O)C1=C OFHCOWSQAMBJIW-AVJTYSNKSA-N 0.000 description 1
150000001350 alkyl halides Chemical class 0.000 description 1
HSFWRNGVRCDJHI-UHFFFAOYSA-N alpha-acetylene Natural products C#C HSFWRNGVRCDJHI-UHFFFAOYSA-N 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000013459 approach Methods 0.000 description 1
QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
BBXRRTJNJCPGBU-UHFFFAOYSA-N beta-naphthyl N-acetylphenylalaninate Chemical compound C=1C=C2C=CC=CC2=CC=1OC(=O)C(NC(=O)C)CC1=CC=CC=C1 BBXRRTJNJCPGBU-UHFFFAOYSA-N 0.000 description 1
125000001246 bromo group Chemical group Br* 0.000 description 1
IAQRGUVFOMOMEM-UHFFFAOYSA-N butene Natural products CC=CC IAQRGUVFOMOMEM-UHFFFAOYSA-N 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
229910002092 carbon dioxide Inorganic materials 0.000 description 1
239000001569 carbon dioxide Substances 0.000 description 1
229910002091 carbon monoxide Inorganic materials 0.000 description 1
239000012876 carrier material Substances 0.000 description 1
239000003795 chemical substances by application Substances 0.000 description 1
125000001309 chloro group Chemical group Cl* 0.000 description 1
239000003245 coal Substances 0.000 description 1
230000001143 conditioned effect Effects 0.000 description 1
238000001816 cooling Methods 0.000 description 1
125000004122 cyclic group Chemical group 0.000 description 1
235000013367 dietary fats Nutrition 0.000 description 1
ZZNQQQWFKKTOSD-UHFFFAOYSA-N diethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OCC)(OCC)C1=CC=CC=C1 ZZNQQQWFKKTOSD-UHFFFAOYSA-N 0.000 description 1
CQYBWJYIKCZXCN-UHFFFAOYSA-N diethylaluminum Chemical compound CC[Al]CC CQYBWJYIKCZXCN-UHFFFAOYSA-N 0.000 description 1
AHUXYBVKTIBBJW-UHFFFAOYSA-N dimethoxy(diphenyl)silane Chemical compound C=1C=CC=CC=1[Si](OC)(OC)C1=CC=CC=C1 AHUXYBVKTIBBJW-UHFFFAOYSA-N 0.000 description 1
AFABGHUZZDYHJO-UHFFFAOYSA-N dimethyl butane Natural products CCCC(C)C AFABGHUZZDYHJO-UHFFFAOYSA-N 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
150000002148 esters Chemical class 0.000 description 1
125000002534 ethynyl group Chemical group [H]C#C* 0.000 description 1
238000002474 experimental method Methods 0.000 description 1
229910052731 fluorine Inorganic materials 0.000 description 1
239000011737 fluorine Substances 0.000 description 1
ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
239000000499 gel Substances 0.000 description 1
239000010520 ghee Substances 0.000 description 1
238000005470 impregnation Methods 0.000 description 1
239000011261 inert gas Substances 0.000 description 1
238000009413 insulation Methods 0.000 description 1
150000002576 ketones Chemical class 0.000 description 1
150000007527 lewis bases Chemical class 0.000 description 1
239000000463 material Substances 0.000 description 1
STEPQTYSZVCJPV-UHFFFAOYSA-N metazachlor Chemical compound CC1=CC=CC(C)=C1N(C(=O)CCl)CN1N=CC=C1 STEPQTYSZVCJPV-UHFFFAOYSA-N 0.000 description 1
BFXIKLCIZHOAAZ-UHFFFAOYSA-N methyltrimethoxysilane Chemical compound CO[Si](C)(OC)OC BFXIKLCIZHOAAZ-UHFFFAOYSA-N 0.000 description 1
238000000465 moulding Methods 0.000 description 1
JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
239000001301 oxygen Substances 0.000 description 1
229910052760 oxygen Inorganic materials 0.000 description 1
239000002245 particle Substances 0.000 description 1
YWAKXRMUMFPDSH-UHFFFAOYSA-N pentene Chemical compound CCCC=C YWAKXRMUMFPDSH-UHFFFAOYSA-N 0.000 description 1
NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 1
239000010452 phosphate Substances 0.000 description 1
239000002574 poison Substances 0.000 description 1
231100000614 poison Toxicity 0.000 description 1
239000011148 porous material Substances 0.000 description 1
230000001376 precipitating effect Effects 0.000 description 1
QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 1
VMXUWOKSQNHOCA-UKTHLTGXSA-N ranitidine Chemical compound [O-][N+](=O)\C=C(/NC)NCCSCC1=CC=C(CN(C)C)O1 VMXUWOKSQNHOCA-UKTHLTGXSA-N 0.000 description 1
239000011541 reaction mixture Substances 0.000 description 1
238000010992 reflux Methods 0.000 description 1
229910000077 silane Inorganic materials 0.000 description 1
239000000741 silica gel Substances 0.000 description 1
229910002027 silica gel Inorganic materials 0.000 description 1
238000005245 sintering Methods 0.000 description 1
239000000243 solution Substances 0.000 description 1
238000012360 testing method Methods 0.000 description 1
WHRNULOCNSKMGB-UHFFFAOYSA-N tetrahydrofuran thf Chemical compound C1CCOC1.C1CCOC1 WHRNULOCNSKMGB-UHFFFAOYSA-N 0.000 description 1
238000012546 transfer Methods 0.000 description 1
HQYCOEXWFMFWLR-UHFFFAOYSA-K vanadium(iii) chloride Chemical compound [Cl-].[Cl-].[Cl-].[V+3] HQYCOEXWFMFWLR-UHFFFAOYSA-K 0.000 description 1
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
229910052726 zirconium Inorganic materials 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/06—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
- C08F4/20—Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen of antimony, bismuth, vanadium, niobium or tantalum
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts

Landscapes

Chemical & Material Sciences (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Organic Chemistry (AREA)
Engineering & Computer Science (AREA)
Materials Engineering (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)

PH39817A 1988-12-30 1989-12-29 Catalyst for regulating the molecular weight distributor of ethylene polymers PH26505A (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/292,268 US4999327A (en)	1988-12-30	1988-12-30	Catalyst for regulating the molecular weight distribution of ethylene polymers

Publications (1)

Publication Number	Publication Date
PH26505A true PH26505A (en)	1992-08-07

Family

ID=23123939

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
PH39817A PH26505A (en)	1988-12-30	1989-12-29	Catalyst for regulating the molecular weight distributor of ethylene polymers

Country Status (17)

Country	Link
US (1)	US4999327A (pt)
EP (1)	EP0376348A3 (pt)
JP (1)	JPH02263807A (pt)
KR (1)	KR940006448B1 (pt)
CN (1)	CN1044282A (pt)
AR (1)	AR244253A1 (pt)
AU (1)	AU613549B2 (pt)
BR (1)	BR8906837A (pt)
CA (1)	CA2006897A1 (pt)
FI (1)	FI896358A0 (pt)
HU (1)	HU208328B (pt)
MY (1)	MY105053A (pt)
NO (1)	NO895321L (pt)
NZ (1)	NZ231990A (pt)
PH (1)	PH26505A (pt)
PT (1)	PT92764A (pt)
ZA (1)	ZA899969B (pt)

Families Citing this family (16)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
DE3834130A1 (de) *	1988-10-07	1990-04-12	Basf Ag	Verfahren zum herstellen von homopolymerisaten des ethens sowie copolymerisaten des ethens mit hoeheren (alpha)-monoolefinen mittels eines ziegler-katalysator-systems
DE3834088A1 (de) *	1988-10-07	1990-04-12	Basf Ag	Verfahren zum herstellen von homopolymerisaten des ethens sowie copolymerisaten des ethens mit hoeheren (alpha)-monoolefinen mittels eines ziegler-katalysatorsystems
US5055534A (en) *	1989-12-28	1991-10-08	Union Carbide Chemicals And Plastics Technology Corporation	Preparation of very low molecular weight polyethylene in a fluidized bed
US5034366A (en) *	1989-12-29	1991-07-23	Union Carbide Chemicals And Plastics Technology Corporation	High activity vanadium-based catalyst
US5030605A (en) *	1989-12-29	1991-07-09	Union Carbide Chemicals And Plastics Technology Corporation	Catalyst for regulating the molecular weight distribution of ethylene polymers
US5177042A (en) *	1989-12-29	1993-01-05	Union Carbide Chemicals And Plastics Technology Corporation	High activity vanadium-based catalyst
DE4008732A1 (de) *	1990-03-19	1991-09-26	Basf Ag	Uebergangsmetall-katalysatorkomponente fuer ein ziegler-katalysatorsystem und dessen verwendung
US5773537A (en) *	1992-05-19	1998-06-30	Basf Aktiengesellschaft	Ziegler-natta catalyst systems containing specific organosilicon compounds
US6103657A (en)	1997-07-02	2000-08-15	Union Carbide Chemicals & Plastics Technology Corporation	Catalyst for the production of olefin polymers
US6268447B1 (en)	1998-12-18	2001-07-31	Univation Technologies, L.L.C.	Olefin polymerization catalyst
US6323148B1 (en)	1998-12-04	2001-11-27	Equistar Chemicals, Lp	Ethylene polymerization catalyst and catalyst system
US6303719B1 (en)	1998-12-18	2001-10-16	Univation Technologies	Olefin polymerization catalyst system
CA2433295A1 (en) *	2000-12-28	2002-07-11	Rex Eugene Murray	Polymerization catalyst system, polymerization process and polymer therefrom
US20040249093A1 (en) *	2003-06-09	2004-12-09	Lynch Michael W.	Polyolefins with high levels of long chain branching
CN102718908B (zh) *	2011-03-31	2014-05-28	中国石油化工股份有限公司	一种乙丙共聚催化体系及应用
CN113754813A (zh) *	2020-06-05	2021-12-07	中国石油化工股份有限公司	一种烯烃-烯烃醇共聚物的制备方法

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
JPS57182303A (en) *	1981-05-07	1982-11-10	Nippon Oil Co Ltd	Production of polyolefin
US4451688A (en) *	1981-12-03	1984-05-29	Nippon Oil Company, Limited	Process for preparing polyolefins
US4550094A (en) *	1982-02-16	1985-10-29	Sumitomo Chemical Company, Limited	Solid catalyst component for olefin polymerization
US4508842A (en) *	1983-03-29	1985-04-02	Union Carbide Corporation	Ethylene polymerization using supported vanadium catalyst
JPH07678B2 (ja) *	1985-07-24	1995-01-11	三菱油化株式会社	エチレン共重合体の製造法
US4831000A (en) *	1988-01-15	1989-05-16	Mobil Oil Corporatiion	Catalyst composition for preparing high density or linear low density olefin polymers of controlled molecular weight distribution
US4954471A (en) *	1988-11-28	1990-09-04	Exxon Chemical Patents Inc.	Homogeneous or supported vanadium based catalyst for olefin polymerization
JP2538659B2 (ja) *	1988-12-28	1996-09-25	花王株式会社	感熱記録材料

1988
- 1988-12-30 US US07/292,268 patent/US4999327A/en not_active Expired - Fee Related
1989
- 1989-12-28 BR BR898906837A patent/BR8906837A/pt unknown
- 1989-12-28 JP JP1338830A patent/JPH02263807A/ja active Pending
- 1989-12-28 AR AR89315836A patent/AR244253A1/es active
- 1989-12-28 ZA ZA899969A patent/ZA899969B/xx unknown
- 1989-12-29 PT PT92764A patent/PT92764A/pt not_active Application Discontinuation
- 1989-12-29 FI FI896358A patent/FI896358A0/fi not_active IP Right Cessation
- 1989-12-29 HU HU896823A patent/HU208328B/hu not_active IP Right Cessation
- 1989-12-29 CA CA002006897A patent/CA2006897A1/en not_active Abandoned
- 1989-12-29 PH PH39817A patent/PH26505A/en unknown
- 1989-12-29 NO NO89895321A patent/NO895321L/no unknown
- 1989-12-29 KR KR1019890020040A patent/KR940006448B1/ko active IP Right Grant
- 1989-12-29 MY MYPI89001883A patent/MY105053A/en unknown
- 1989-12-29 CN CN89109857A patent/CN1044282A/zh active Pending
- 1989-12-29 EP EP19890124137 patent/EP0376348A3/en not_active Withdrawn
1990
- 1990-01-02 AU AU47604/90A patent/AU613549B2/en not_active Ceased
- 1990-01-04 NZ NZ231990A patent/NZ231990A/xx unknown

Also Published As

Publication number	Publication date
AU4760490A (en)	1990-07-05
PT92764A (pt)	1990-07-31
NZ231990A (en)	1991-02-26
EP0376348A2 (en)	1990-07-04
JPH02263807A (ja)	1990-10-26
MY105053A (en)	1994-07-30
EP0376348A3 (en)	1991-07-03
NO895321D0 (no)	1989-12-29
KR900009708A (ko)	1990-07-05
FI896358A0 (fi)	1989-12-29
HUT53917A (en)	1990-12-28
KR940006448B1 (ko)	1994-07-20
ZA899969B (en)	1990-10-31
HU208328B (en)	1993-09-28
AU613549B2 (en)	1991-08-01
CA2006897A1 (en)	1990-06-30
NO895321L (no)	1990-07-02
CN1044282A (zh)	1990-08-01
US4999327A (en)	1991-03-12
HU896823D0 (en)	1990-03-28
BR8906837A (pt)	1990-09-18
AR244253A1 (es)	1993-10-29

Publication	Publication Date	Title
PH26505A (en)	1992-08-07	Catalyst for regulating the molecular weight distributor of ethylene polymers
RU2043150C1 (ru)	1995-09-10	Способ получения твердого катализатора, катализатор и способ получения (со)полимеров этилена
HU208983B (en)	1994-02-28	Process for gas phase polymerization of olefins, as well as granular prepolymer and process for producing same
EP0197166A1 (en)	1986-10-15	Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound and a process for alpha-olefin polymerization using such catalyst
AU3063684A (en)	1985-12-31	Novel titanium complexes and catalysts prepared therefrom
GB2049710A (en)	1980-12-31	Ethylene polymerisation
US4544647A (en)	1985-10-01	Catalyst prepared from organomagnesium compound, organic hydroxyl-containing compound, reducing halide source and transition metal compound
EP0349927B1 (en)	1993-11-03	Catalyst for regulating the molecular weight distribution of ethylene polymers
KR19980082807A (ko)	1998-12-05	올레핀 중합 및 공중합용 촉매
JPS648010B2 (pt)	1989-02-10
US4295992A (en)	1981-10-20	Support prepared from organomagnesium compounds and silicon halides; and catalysts for polymerizing olefins
KR100218045B1 (ko)	1999-09-01	에틸렌 중합 및 에틸렌/알파-올레핀 공중합용 담지촉매의 제조방법
KR19980082808A (ko)	1998-12-05	알파 올레핀 중합 및 공중합용 촉매
EP0294168B1 (en)	1991-11-13	Method for producing an ethylene-based polymer
AU621777B2 (en)	1992-03-19	High activity vanadium-based catalyst
GB2051094A (en)	1981-01-14	Process for Preparing Ethylene Copolymers
JP2767754B2 (ja)	1998-06-18	オレフィンの重合用触媒の製造方法
US4988784A (en)	1991-01-29	Catalyst for regulating the molecular weight distribution of ethylene polymers
JPS63162703A (ja)	1988-07-06	オレフイン重合用触媒成分の製造方法
KR100436493B1 (ko)	2004-06-24	에틸렌 중합 및 에틸렌/알파-올레핀 공중합용 담지촉매의제조방법
JPH09176226A (ja)	1997-07-08	エチレンの重合及びエチレンとα−オレフィンの共重合のための担持型触媒の製造方法
KR100359930B1 (ko)	2002-11-07	에틸렌 중합 또는 에틸렌/α-올레핀 공중합용 촉매의제조방법
JPS6339605B2 (pt)	1988-08-05
EP0439838A2 (en)	1991-08-07	Catalyst for regulating the molecular weight distribution of ethylene polymers
JPS5847004A (ja)	1983-03-18	オレフイン重合触媒による重合方法