NO148241B - FUNGICID PREPARATION CONTAINING A PYRIMIDINE AND A BENZIMIDAZOLE COMPOUND. - Google Patents
FUNGICID PREPARATION CONTAINING A PYRIMIDINE AND A BENZIMIDAZOLE COMPOUND.Info
- Publication number
- NO148241B NO148241B NO821513A NO821513A NO148241B NO 148241 B NO148241 B NO 148241B NO 821513 A NO821513 A NO 821513A NO 821513 A NO821513 A NO 821513A NO 148241 B NO148241 B NO 148241B
- Authority
- NO
- Norway
- Prior art keywords
- formula
- compound
- pyrimidine
- preparation containing
- benzimidazole compound
- Prior art date
Links
- 238000002360 preparation method Methods 0.000 title claims description 14
- -1 BENZIMIDAZOLE COMPOUND Chemical class 0.000 title claims description 6
- CZPWVGJYEJSRLH-UHFFFAOYSA-N Pyrimidine Chemical compound C1=CN=CN=C1 CZPWVGJYEJSRLH-UHFFFAOYSA-N 0.000 title 1
- 150000001875 compounds Chemical class 0.000 claims description 12
- 239000004480 active ingredient Substances 0.000 claims description 5
- 229910052801 chlorine Inorganic materials 0.000 claims description 5
- 239000000460 chlorine Substances 0.000 claims description 5
- 125000001309 chloro group Chemical group Cl* 0.000 claims description 5
- 230000000855 fungicidal effect Effects 0.000 claims description 4
- 239000000969 carrier Substances 0.000 claims description 3
- 229910052731 fluorine Chemical group 0.000 claims description 3
- 239000011737 fluorine Chemical group 0.000 claims description 3
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical group FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 claims description 2
- 231100001184 nonphytotoxic Toxicity 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 description 9
- TWFZGCMQGLPBSX-UHFFFAOYSA-N carbendazim Chemical compound C1=CC=C2NC(NC(=O)OC)=NC2=C1 TWFZGCMQGLPBSX-UHFFFAOYSA-N 0.000 description 8
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
- 201000010099 disease Diseases 0.000 description 5
- 208000037265 diseases, disorders, signs and symptoms Diseases 0.000 description 5
- LMBFAGIMSUYTBN-MPZNNTNKSA-N teixobactin Chemical compound C([C@H](C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H](CCC(N)=O)C(=O)N[C@H]([C@@H](C)CC)C(=O)N[C@@H]([C@@H](C)CC)C(=O)N[C@@H](CO)C(=O)N[C@H]1C(N[C@@H](C)C(=O)N[C@@H](C[C@@H]2NC(=N)NC2)C(=O)N[C@H](C(=O)O[C@H]1C)[C@@H](C)CC)=O)NC)C1=CC=CC=C1 LMBFAGIMSUYTBN-MPZNNTNKSA-N 0.000 description 5
- 239000000843 powder Substances 0.000 description 4
- 239000004094 surface-active agent Substances 0.000 description 4
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 3
- 206010017533 Fungal infection Diseases 0.000 description 3
- 208000031888 Mycoses Diseases 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- 241000219094 Vitaceae Species 0.000 description 3
- 239000007900 aqueous suspension Substances 0.000 description 3
- HVFLCNVBZFFHBT-ZKDACBOMSA-N cefepime Chemical compound S([C@@H]1[C@@H](C(N1C=1C([O-])=O)=O)NC(=O)\C(=N/OC)C=2N=C(N)SC=2)CC=1C[N+]1(C)CCCC1 HVFLCNVBZFFHBT-ZKDACBOMSA-N 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 235000021021 grapes Nutrition 0.000 description 3
- 239000002562 thickening agent Substances 0.000 description 3
- NHOWDZOIZKMVAI-UHFFFAOYSA-N (2-chlorophenyl)(4-chlorophenyl)pyrimidin-5-ylmethanol Chemical compound C=1N=CN=CC=1C(C=1C(=CC=CC=1)Cl)(O)C1=CC=C(Cl)C=C1 NHOWDZOIZKMVAI-UHFFFAOYSA-N 0.000 description 2
- 241000221785 Erysiphales Species 0.000 description 2
- 239000005909 Kieselgur Substances 0.000 description 2
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 2
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 2
- 239000002518 antifoaming agent Substances 0.000 description 2
- 239000006013 carbendazim Substances 0.000 description 2
- 239000012141 concentrate Substances 0.000 description 2
- 239000012895 dilution Substances 0.000 description 2
- 238000010790 dilution Methods 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 238000011534 incubation Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- PSZYNBSKGUBXEH-UHFFFAOYSA-N naphthalene-1-sulfonic acid Chemical class C1=CC=C2C(S(=O)(=O)O)=CC=CC2=C1 PSZYNBSKGUBXEH-UHFFFAOYSA-N 0.000 description 2
- 229920001296 polysiloxane Polymers 0.000 description 2
- 239000003755 preservative agent Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- WPRAXAOJIODQJR-UHFFFAOYSA-N 1-(3,4-dimethylphenyl)ethanone Chemical compound CC(=O)C1=CC=C(C)C(C)=C1 WPRAXAOJIODQJR-UHFFFAOYSA-N 0.000 description 1
- HYZJCKYKOHLVJF-UHFFFAOYSA-N 1H-benzimidazole Chemical group C1=CC=C2NC=NC2=C1 HYZJCKYKOHLVJF-UHFFFAOYSA-N 0.000 description 1
- FJKROLUGYXJWQN-UHFFFAOYSA-N 4-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=C(O)C=C1 FJKROLUGYXJWQN-UHFFFAOYSA-N 0.000 description 1
- UGDWWCJKEUBONY-UHFFFAOYSA-N 6-chloro-6-methylcyclohexa-1,3-dien-1-ol Chemical compound CC1(Cl)CC=CC=C1O UGDWWCJKEUBONY-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical class C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 244000043261 Hevea brasiliensis Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- 229920001732 Lignosulfonate Polymers 0.000 description 1
- 241001123569 Puccinia recondita Species 0.000 description 1
- 241000209140 Triticum Species 0.000 description 1
- 241001409553 Uredo Species 0.000 description 1
- 239000013543 active substance Substances 0.000 description 1
- 150000008051 alkyl sulfates Chemical class 0.000 description 1
- 235000012211 aluminium silicate Nutrition 0.000 description 1
- 230000000844 anti-bacterial effect Effects 0.000 description 1
- 230000002528 anti-freeze Effects 0.000 description 1
- 239000007798 antifreeze agent Substances 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 229960000892 attapulgite Drugs 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 239000001913 cellulose Substances 0.000 description 1
- 229920002678 cellulose Polymers 0.000 description 1
- 239000004927 clay Substances 0.000 description 1
- GUJOJGAPFQRJSV-UHFFFAOYSA-N dialuminum;dioxosilane;oxygen(2-);hydrate Chemical compound O.[O-2].[O-2].[O-2].[Al+3].[Al+3].O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O GUJOJGAPFQRJSV-UHFFFAOYSA-N 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 125000001153 fluoro group Chemical group F* 0.000 description 1
- 230000002538 fungal effect Effects 0.000 description 1
- 230000035784 germination Effects 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000003306 harvesting Methods 0.000 description 1
- 229920003063 hydroxymethyl cellulose Polymers 0.000 description 1
- 229940031574 hydroxymethyl cellulose Drugs 0.000 description 1
- 208000015181 infectious disease Diseases 0.000 description 1
- 239000011872 intimate mixture Substances 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 235000019357 lignosulphonate Nutrition 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000010445 mica Substances 0.000 description 1
- 229910052618 mica group Inorganic materials 0.000 description 1
- 229920003052 natural elastomer Polymers 0.000 description 1
- 229920001194 natural rubber Polymers 0.000 description 1
- 239000002736 nonionic surfactant Substances 0.000 description 1
- 229920000847 nonoxynol Polymers 0.000 description 1
- SNQQPOLDUKLAAF-UHFFFAOYSA-N nonylphenol Chemical class CCCCCCCCCC1=CC=CC=C1O SNQQPOLDUKLAAF-UHFFFAOYSA-N 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 229910052625 palygorskite Inorganic materials 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 230000005070 ripening Effects 0.000 description 1
- 150000004760 silicates Chemical class 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 208000024891 symptom Diseases 0.000 description 1
- 239000000454 talc Substances 0.000 description 1
- 229910052623 talc Inorganic materials 0.000 description 1
- 239000004563 wettable powder Substances 0.000 description 1
- 239000000230 xanthan gum Substances 0.000 description 1
- 229920001285 xanthan gum Polymers 0.000 description 1
- 229940082509 xanthan gum Drugs 0.000 description 1
- 235000010493 xanthan gum Nutrition 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
- A01N47/18—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, directly attached to a heterocyclic or cycloaliphatic ring
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/10—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds
- A01N57/12—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-oxygen bonds or phosphorus-to-sulfur bonds containing acyclic or cycloaliphatic radicals
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
Description
Foreliggende oppfinnelse vedrører et fungicid preparat for- The present invention relates to a fungicidal preparation for
behandling av soppinfeksjoner hos dyrkede planter, innehold- , ende nye kombinasjoner av kjemiske stoffer. treatment of fungal infections in cultivated plants, content, and new combinations of chemical substances.
Ifølge oppfinnelsen er det tilveiebragt et fungicid prepa- According to the invention, a fungicidal preparation is provided
rat som er kjennetegnet ved at det består av eller inneholder en pyrimidinforbindelse med formelen: rat which is characterized in that it consists of or contains a pyrimidine compound with the formula:
hvor X er klor eller fluor, og en benzimidazol med formelen: where X is chlorine or fluorine, and a benzimidazole of the formula:
De ovennevnte forbindelser er kjente og kan fremstilles ved hjelp av i og for seg kjente metoder. Kombinasjonene av aktive bestanddeler som definert ovenfor, er nye og er funnet å være overraskende effektive når det gjelder å kontrollere eller bekjempe soppinfeksjoner hos dyrkede planter, idet kombinasjonen av en forbindelse med formelen I og en forbindelse med formelen II er funnet å være spesielt nyttig ved behandling av sykdommer hos korn, slik som pulvermeldugg, rothalsråte, og andre blad- eller akssyk- The above-mentioned compounds are known and can be prepared using methods known per se. The combinations of active ingredients as defined above are novel and have been found to be surprisingly effective in controlling or combating fungal infections in cultivated plants, the combination of a compound of formula I and a compound of formula II being found to be particularly useful in treatment of diseases in cereals, such as powdery mildew, root neck rot, and other leaf or axis diseases
domraer som påvirker kornsorter i modningstrinnet. factors that affect grain varieties in the ripening stage.
Ved behandling av soppinfeksjoner hos planter, spesielt kornsorter og druer, <p>åføres en fungicid effektiv mengde av et fungicid preparat som definert ovenfor, på de infiserte planter. Preparatet påføres fortrinnsvis på bladene ved et hvilket som helst tidspunkt etter spiring inntil inn-høstningen finner sted, idet mengden og frekvensen for på-føring bestemmes ut fra graden eller den forventede grad av soppangrep. Man har imidlertid funnet det spesielt fordel-aktig at en redusert behandlingsfrekvens, f.eks. bare en gang hver annen eller tredje uke for bekjem<p>else av meldugg-infeksjoner hos druer, med effektiv virkning kan foretas, When treating fungal infections in plants, especially cereals and grapes, <p>a fungicidally effective amount of a fungicidal preparation as defined above is applied to the infected plants. The preparation is preferably applied to the leaves at any time after germination until the harvest takes place, the amount and frequency of application being determined based on the degree or expected degree of fungal attack. However, it has been found particularly advantageous that a reduced treatment frequency, e.g. only once every two or three weeks for the control<p>of powdery mildew infections in grapes, with effective effect can be done,
og man oppnår derved en viktig reduksjon i arbeidsomkost-ninger . and you thereby achieve an important reduction in labor costs.
Komponentene i foreliggende preparat kan påføres etter hver andre eller samtidig på planten som er under behandling, idet det sistnevnte foretrekkes. Forbindelsen med formel I påføres fortrinnsvis i en mengde på 10-100 g, helst The components in the present preparation can be applied one after the other or simultaneously to the plant being treated, the latter being preferred. The compound of formula I is preferably applied in an amount of 10-100 g, preferably
10-30 g/hektar ved behandling av druer, mens forbindelsen med formel II fortrinnsvis påføres i mengder på 100-3000 g/ hektar. Således kan forholdet mellom forbindelser med formelen I og forbindelser med formel II i foreliggende preparater variere fra 5:1 til 1:300, beregnet på vekt. Forholdet mellom forbindelsen med formel I og formel II ligger fortrinnsvis mellom 1:1 og 1:25, idet 20-100 g/hektar av forbindelsen med formel I anvendes, mens man kan anvende 100-500 g/hektar av forbindelsen med formel II. 10-30 g/hectare when treating grapes, while the compound of formula II is preferably applied in quantities of 100-3000 g/hectare. Thus, the ratio between compounds of formula I and compounds of formula II in the present preparations can vary from 5:1 to 1:300, calculated by weight. The ratio between the compound of formula I and formula II is preferably between 1:1 and 1:25, with 20-100 g/hectare of the compound of formula I being used, while 100-500 g/hectare of the compound of formula II can be used.
For å forenkle fremstilling, lagring og transport, vil kombinasjonene av forbindelsene med formel I og formel II normalt leveres i konsentratform beregnet for fortynning i vann til den grad som er nødvendig for at man lett skal kunne oppnå de ovenfor nevnte påføringsmengder. Slike konsentrerte preparater kan inneholde 0,5-90 vekt-%, fortrinnsvis 5-90 vekt-% aktive bestanddeler i forbindelse med en eller flere ikke-fytotoksiske bærere. Slike preparater vil vanligvis være i form av et fuktbart pulver eller støv, eller vandig suspensjon. Konsentratpreparatene er beregnet for passende fortynning med vann før bruk. Denne dannelse av en vandig dispersjon kan utføres i konvensjonelle sprøytebeholdere egnet for formålet. In order to simplify manufacture, storage and transport, the combinations of the compounds of formula I and formula II will normally be delivered in concentrate form intended for dilution in water to the extent necessary to easily achieve the above-mentioned application amounts. Such concentrated preparations can contain 0.5-90% by weight, preferably 5-90% by weight, of active ingredients in connection with one or more non-phytotoxic carriers. Such preparations will usually be in the form of a wettable powder or dust, or an aqueous suspension. The concentrate preparations are intended for suitable dilution with water before use. This formation of an aqueous dispersion can be carried out in conventional spray containers suitable for the purpose.
Fuktbare pulvere eller støv omfatter en intim blanding av de aktive bestanddeler, en eller flere inerte bærere og passende overflateaktive midler. Den inerte bærer kan velges fra attapulgittleire, montmorillonittleire, diatome-jord, kaoliner, glimmer, talk og rensede silikater. Effektive overflateaktive midler finnes blant sulfonerte ligninei naftalensulfonater og kondenserte naftalensulfonater, alkyl-suksinater, alkylbenzensulfonater, alkylsulfater og ikke-ioniske overflateaktive midler, slik som etylenoksyd-addukter av fenol. Eksempler på fuktbare pulvere som omfattes av foreliggende oppfinnelse er de som har følgende sammensetning: Wettable powders or dusts comprise an intimate mixture of the active ingredients, one or more inert carriers and suitable surfactants. The inert carrier can be selected from attapulgite clay, montmorillonite clay, diatomaceous earth, kaolins, mica, talc and purified silicates. Effective surfactants are found among sulfonated lignins, naphthalene sulfonates and condensed naphthalene sulfonates, alkyl succinates, alkylbenzene sulfonates, alkyl sulfates, and nonionic surfactants, such as ethylene oxide adducts of phenol. Examples of wettable powders covered by the present invention are those with the following composition:
Vandige suspensjoner og oppløsninger omfatter de aktive bestanddeler suspendert eller oppløst i vann eller egnede oppløsningsmidler, respektivt, sammen med eventuelle ønskede overflateaktive midler, fortykningsmidler, antifrysemidler eller preservativer. Egnede overflateaktive midler kan velges fra de som er nevnt i forbindelse med fuktbare pulver Fortykningsmidler, dersom slike brukes, velges normalt fra passende cellulosematerialer og naturgummier, mens glykoler i alminnelighet vil bli benyttet når det er nødvendig med et anti-frysemiddel. Preservativer kan velges fra forskjel] materialer, slik som de forskjellige paraben-antibakterielle stoffer, fenol, o-klorkresol, fenylmerkurinitrat og formalde-hyd. Typiske eksempler på vandige suspensjoner som omfattes av oppfinnelsen er: Aqueous suspensions and solutions comprise the active ingredients suspended or dissolved in water or suitable solvents, respectively, together with any desired surfactants, thickeners, antifreezes or preservatives. Suitable surface-active agents can be selected from those mentioned in connection with wettable powders Thickening agents, if such are used, are normally selected from suitable cellulose materials and natural rubbers, while glycols will generally be used when an anti-freeze agent is required. Preservatives can be selected from different materials, such as the various paraben antibacterial substances, phenol, o-chlorocresol, phenylmercury nitrate and formaldehyde. Typical examples of aqueous suspensions covered by the invention are:
Følgende eksempler illustrerer oppfinnelsen. I disse eksempler representerer betegnelsen "CCPM" forbindelsen med formel I hvor X er klor, mens den beslektede forbindelse hvori X er fluor representeres ved betegnelsen "CFPM". Likeledes betegnes forbindelsen med formel II med symbolet The following examples illustrate the invention. In these examples, the designation "CCPM" represents the compound of formula I wherein X is chlorine, while the related compound wherein X is fluorine is represented by the designation "CFPM." Likewise, the compound of formula II is denoted by the symbol
"MBC". "MBC".
Eksempler 1 og 2 Examples 1 and 2
Følgende fuktbare pulvere ble fremstilt: The following wettable powders were prepared:
(2) vekt-% CFPM 3 , 0 MBC 4 5,0 Natriumalkylnaftalensulfonat 8,0 Diatoméjord 6,0 Monmorillonitt til 100,0 (3) vekt-% CFPM 4,0 MBC 4 0,0 Polyoksyetylenpolyoksypropylen-blokk-kopolymer 2,0 Xantangummi 0,4 Silikon-antiskum 0,1 Vann til 100,0 (4) vekt-% CCPM 5, 0 MBC 40,0 Etoksylert nonylfenol 4,0 Hydroksymetylcellulose 2,0 Silikon-antiskum 0,15 Propylenglykol 6,0 Vann til 100,0 (2) wt% CFPM 3 , 0 MBC 4 5.0 Sodium alkylnaphthalenesulfonate 8.0 Diatomaceous earth 6.0 Monmorillonite to 100.0 (3) wt% CFPM 4.0 MBC 4 0.0 Polyoxyethylene polyoxypropylene block copolymer 2, 0 Xanthan gum 0.4 Silicone antifoam 0.1 Water to 100.0 (4) wt% CCPM 5.0 MBC 40.0 Ethoxylated nonylphenol 4.0 Hydroxymethyl cellulose 2.0 Silicone antifoam 0.15 Propylene glycol 6.0 Water to 100.0
størrelsen til begge de aktive stoffer ble ytterligere redusert ved væskemaling, idet resten av fortykningsmidlet ble tilsatt, hvoretter produktet fikk anledning til å hydratisere, og produktet ble fortynnet til ønsket volum med vann. the size of both active substances was further reduced by liquid painting, as the remainder of the thickener was added, after which the product was allowed to hydrate, and the product was diluted to the desired volume with water.
Sammenligningsforsøk. Comparison experiment.
Kombinasjoner av fungicidene fenarimol (forbindelsen med Combinations of the fungicides fenarimol (the compound with
formel I hvor X er klor) og karbendazim (forbindelsen med formel II) ble testet og funnet å utvise synergisme. formula I where X is chlorine) and carbendazim (the compound of formula II) were tested and found to exhibit synergism.
Vandige dusjpreparater inneholdende 10 og 20 ppm fenarimol og 100 ppm karbendazim ble først fremstilt. De ble påført alene og i kombinasjon på hveteplanter. Etter at plantene hadde tørket etter behandlingen ble de inokkulert med uredo-sporer av rustsoppen Puccinia recondita og deretter plassert i et inkubasjonskammer i 48 timer. Da inkubasjonsperioden var fullført ble plantene anbragt i et drivhus for å gi syk-doms symptomene anledning til å utvikle seg. En verdi for Aqueous shower preparations containing 10 and 20 ppm fenarimol and 100 ppm carbendazim were first prepared. They were applied alone and in combination to wheat plants. After the plants had dried after the treatment, they were inoculated with uredo spores of the rust fungus Puccinia recondita and then placed in an incubation chamber for 48 hours. When the incubation period was complete, the plants were placed in a greenhouse to give the disease symptoms the opportunity to develop. A value for
i sykdomskontroll ble beregnet ut fra sammenligning med ube-handlede kontrollplanter. in disease control was calculated based on comparison with untreated control plants.
Fra vardiene oppnådd når fungicidene ble benyttet alene var det mulig å beregne en teoretisk verdi for sykdomskontroll for blandingene ved anvendelse av den velkjente Colby-ligning (Weeds 15, sidene 20-22, 1967), og synergisme ble demonstrert ut fra det faktum at den observerte verdien var større enn den beregnede teoretiske verdi. From the values obtained when the fungicides were used alone it was possible to calculate a theoretical disease control value for the mixtures using the well-known Colby equation (Weeds 15, pages 20-22, 1967), and synergism was demonstrated from the fact that the observed value was greater than the calculated theoretical value.
Claims (3)
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| GB12972/77A GB1596380A (en) | 1977-03-28 | 1977-03-28 | Fungicidal combinations |
Publications (3)
| Publication Number | Publication Date |
|---|---|
| NO821513L NO821513L (en) | 1978-09-29 |
| NO148241B true NO148241B (en) | 1983-05-30 |
| NO148241C NO148241C (en) | 1983-09-07 |
Family
ID=10014480
Family Applications (4)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO781040A NO147260C (en) | 1977-03-28 | 1978-03-22 | FUNGICID PREPARATION COMPREHENSIVE TRIAZOL AND BENZIMIDAZOLE COMPOUNDS |
| NO821513A NO148241C (en) | 1977-03-28 | 1982-05-07 | FUNGICID PREPARATION CONTAINING A PYRIMIDINE AND A BENZIMIDAZOLE COMPOUND |
| NO821512A NO148622C (en) | 1977-03-28 | 1982-05-07 | FUNGICID PREPARATION CONTAINING A TRIAZINE COMPOUND AND AN ALUMINUM SALT. |
| NO821514A NO148621C (en) | 1977-03-28 | 1982-05-07 | FUNGICID PREPARATION CONTAINING A MIXTURE OF A PYRIMID CONNECTION AND AN ALUMINUM SALT |
Family Applications Before (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO781040A NO147260C (en) | 1977-03-28 | 1978-03-22 | FUNGICID PREPARATION COMPREHENSIVE TRIAZOL AND BENZIMIDAZOLE COMPOUNDS |
Family Applications After (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| NO821512A NO148622C (en) | 1977-03-28 | 1982-05-07 | FUNGICID PREPARATION CONTAINING A TRIAZINE COMPOUND AND AN ALUMINUM SALT. |
| NO821514A NO148621C (en) | 1977-03-28 | 1982-05-07 | FUNGICID PREPARATION CONTAINING A MIXTURE OF A PYRIMID CONNECTION AND AN ALUMINUM SALT |
Country Status (34)
| Country | Link |
|---|---|
| JP (1) | JPS53121932A (en) |
| AR (2) | AR227124A1 (en) |
| AT (1) | AT362195B (en) |
| AU (1) | AU515204B2 (en) |
| BE (1) | BE865215A (en) |
| BG (4) | BG30167A4 (en) |
| BR (1) | BR7801746A (en) |
| CA (1) | CA1108046A (en) |
| CH (1) | CH629363A5 (en) |
| CS (4) | CS198292B2 (en) |
| DD (1) | DD135031A5 (en) |
| DE (2) | DE2858350C2 (en) |
| DK (1) | DK149442C (en) |
| ES (1) | ES468098A1 (en) |
| FR (4) | FR2390096A1 (en) |
| GB (1) | GB1596380A (en) |
| GR (1) | GR64791B (en) |
| HU (2) | HU179506B (en) |
| IE (1) | IE46690B1 (en) |
| IL (1) | IL54318A (en) |
| IN (1) | IN147690B (en) |
| IT (1) | IT1105157B (en) |
| LU (1) | LU79285A1 (en) |
| MX (1) | MX5640E (en) |
| NL (1) | NL7803064A (en) |
| NO (4) | NO147260C (en) |
| NZ (1) | NZ186757A (en) |
| PL (4) | PL112622B1 (en) |
| PT (1) | PT67801A (en) |
| RO (4) | RO78273A (en) |
| SE (5) | SE447783B (en) |
| SU (1) | SU1409119A3 (en) |
| TR (1) | TR20072A (en) |
| ZA (1) | ZA781700B (en) |
Families Citing this family (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| DE2560510C2 (en) * | 1975-11-26 | 1989-02-16 | Bayer Ag, 5090 Leverkusen, De | |
| IT1143721B (en) * | 1977-12-01 | 1986-10-22 | Sipcam Spa | FUNGICIDAL COMPOSITION FOR THE FIGHT AGAINST PLANT DISEASES |
| DE2846038A1 (en) * | 1978-10-23 | 1980-05-08 | Basf Ag | 1,2,4-TRIAZOLE DERIVATIVES, THEIR PRODUCTION AND USE |
| DE3208142A1 (en) * | 1982-03-06 | 1983-09-08 | Bayer Ag, 5090 Leverkusen | FUNGICIDAL AGENT |
| FR2524261A1 (en) * | 1982-04-01 | 1983-10-07 | Rhone Poulenc Agrochimie | FENARIMOL FUNGICIDE POWDER COMPOSITION |
| GB8629360D0 (en) * | 1986-12-09 | 1987-01-21 | Sandoz Ltd | Fungicides |
| JPH01167287U (en) * | 1988-05-16 | 1989-11-24 | ||
| DE3818903A1 (en) * | 1988-06-03 | 1989-12-14 | Stama Maschinenfabrik Gmbh | DRILLING AND MILLING PLANT |
| JPH0274094U (en) * | 1988-11-28 | 1990-06-06 | ||
| JPH071190Y2 (en) * | 1989-03-01 | 1995-01-18 | 狭山精密工業株式会社 | Spiral control mechanism in pachinko ball lifting device |
| NZ260462A (en) * | 1994-05-05 | 1996-04-26 | Horticulture & Food Res Inst | Tree treatment and composition comprising phosphorous acid, a bioprecursor or a salt thereof and a triazole |
| FR2732191B1 (en) * | 1995-03-30 | 2000-12-29 | Rhone Poulenc Agrochimie | ANTIFUNGAL TREATMENT OF BANANA TREES |
| GB0811079D0 (en) * | 2008-06-17 | 2008-07-23 | Syngenta Participations Ag | Herbicide formulation |
| CN103583541B (en) * | 2012-08-17 | 2015-11-11 | 陕西美邦农药有限公司 | A kind of bactericidal composition containing Fenarimol |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| FR1569940A (en) * | 1967-04-27 | 1969-06-06 | ||
| FR2140205B1 (en) | 1971-06-04 | 1977-12-23 | Oreal | |
| US3912752A (en) * | 1972-01-11 | 1975-10-14 | Bayer Ag | 1-Substituted-1,2,4-triazoles |
| US3869456A (en) * | 1972-03-13 | 1975-03-04 | Lilly Co Eli | Synthesis of 5-pyrimidinecarbinols |
| US3868244A (en) | 1972-03-13 | 1975-02-25 | Lilly Co Eli | Plant growth regulation |
| DE2303757A1 (en) * | 1973-01-26 | 1974-08-15 | Hoechst Ag | Fungicidal wettable powders contg. benzimidazole carbamates - mixed with powdered carrier, penetrating agent, but without emulsifying agents |
| DE2354467C3 (en) * | 1973-10-31 | 1981-07-30 | Hoechst Ag, 6000 Frankfurt | Fungicidal dispersions based on benzimidazole methyl carbamate |
| DE2456627C2 (en) * | 1973-12-14 | 1984-05-10 | PEPRO - Société pour le Développement et la Vente de Spécialités Chimiques, Lyon | Fungicidal agents based on phosphonic acid esters |
| FR2254276B1 (en) * | 1973-12-14 | 1977-03-04 | Philagro Sa | |
| FR2279331A1 (en) * | 1974-07-24 | 1976-02-20 | Hoechst Ag | Fungicidal wettable powders contg. benzimidazole carbamates - mixed with powdered carrier, penetrating agent, but without emulsifying agents |
| DE2560510C2 (en) * | 1975-11-26 | 1989-02-16 | Bayer Ag, 5090 Leverkusen, De |
-
1977
- 1977-03-28 GB GB12972/77A patent/GB1596380A/en not_active Expired
-
1978
- 1978-03-15 IT IT48444/78A patent/IT1105157B/en active
- 1978-03-20 CA CA299,331A patent/CA1108046A/en not_active Expired
- 1978-03-20 IN IN295/CAL/78A patent/IN147690B/en unknown
- 1978-03-20 PT PT67801A patent/PT67801A/en unknown
- 1978-03-20 SE SE7803184A patent/SE447783B/en not_active IP Right Cessation
- 1978-03-20 FR FR7807978A patent/FR2390096A1/en active Granted
- 1978-03-20 MX MX786944U patent/MX5640E/en unknown
- 1978-03-21 CH CH306178A patent/CH629363A5/en not_active IP Right Cessation
- 1978-03-21 RO RO7899323A patent/RO78273A/en unknown
- 1978-03-21 DE DE2858350A patent/DE2858350C2/de not_active Expired
- 1978-03-21 IL IL54318A patent/IL54318A/en unknown
- 1978-03-21 AR AR271494A patent/AR227124A1/en active
- 1978-03-21 GR GR55758A patent/GR64791B/en unknown
- 1978-03-21 RO RO7899324A patent/RO78274A/en unknown
- 1978-03-21 DK DK127978A patent/DK149442C/en not_active IP Right Cessation
- 1978-03-21 DE DE2812287A patent/DE2812287C2/en not_active Expired
- 1978-03-21 RO RO7899325A patent/RO78260A/en unknown
- 1978-03-21 RO RO7893574A patent/RO73042A/en unknown
- 1978-03-21 ES ES468098A patent/ES468098A1/en not_active Expired
- 1978-03-21 BR BR7801746A patent/BR7801746A/en unknown
- 1978-03-22 NO NO781040A patent/NO147260C/en unknown
- 1978-03-22 BG BG7841508A patent/BG30167A4/en unknown
- 1978-03-22 NL NL7803064A patent/NL7803064A/en not_active Application Discontinuation
- 1978-03-22 LU LU79285A patent/LU79285A1/en unknown
- 1978-03-22 NZ NZ186757A patent/NZ186757A/en unknown
- 1978-03-22 BG BG7839128A patent/BG29863A3/en unknown
- 1978-03-22 AT AT203678A patent/AT362195B/en not_active IP Right Cessation
- 1978-03-22 BG BG7841507A patent/BG30166A4/en unknown
- 1978-03-22 BG BG7841506A patent/BG30165A4/en unknown
- 1978-03-22 DD DD78204345A patent/DD135031A5/en unknown
- 1978-03-22 AU AU34430/78A patent/AU515204B2/en not_active Expired
- 1978-03-22 BE BE6046404A patent/BE865215A/en not_active IP Right Cessation
- 1978-03-23 TR TR20072A patent/TR20072A/en unknown
- 1978-03-23 ZA ZA00781700A patent/ZA781700B/en unknown
- 1978-03-23 HU HU78LI322A patent/HU179506B/en unknown
- 1978-03-23 IE IE588/78A patent/IE46690B1/en unknown
- 1978-03-23 HU HU812978A patent/HU188701B/en unknown
- 1978-03-24 CS CS789185A patent/CS198292B2/en unknown
- 1978-03-24 PL PL1978216611A patent/PL112622B1/en unknown
- 1978-03-24 JP JP3402678A patent/JPS53121932A/en active Granted
- 1978-03-24 CS CS789183A patent/CS198290B2/en unknown
- 1978-03-24 SU SU782594402A patent/SU1409119A3/en active
- 1978-03-24 PL PL1978216612A patent/PL112286B1/en unknown
- 1978-03-24 PL PL1978205555A patent/PL108903B1/en unknown
- 1978-03-24 CS CS789184A patent/CS198291B2/en unknown
- 1978-03-24 PL PL1978216610A patent/PL112146B1/en unknown
- 1978-03-24 CS CS781922A patent/CS198289B2/en unknown
- 1978-09-08 FR FR7825893A patent/FR2390097A1/en active Granted
- 1978-09-08 FR FR7825894A patent/FR2390098A1/en active Granted
- 1978-09-08 FR FR7825895A patent/FR2390099B1/fr not_active Expired
-
1981
- 1981-02-02 AR AR284171A patent/AR225793A1/en active
-
1982
- 1982-05-07 NO NO821513A patent/NO148241C/en unknown
- 1982-05-07 NO NO821512A patent/NO148622C/en unknown
- 1982-05-07 NO NO821514A patent/NO148621C/en unknown
-
1983
- 1983-03-23 SE SE8301606A patent/SE454398B/en not_active IP Right Cessation
-
1986
- 1986-05-30 SE SE8602470A patent/SE8602470D0/en not_active Application Discontinuation
-
1987
- 1987-08-19 SE SE8703223A patent/SE8703223L/en not_active Application Discontinuation
- 1987-08-19 SE SE8703224A patent/SE8703224D0/en not_active Application Discontinuation
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