KR970706420A - 무세척 인산염 처리법(no-rinse phosphatising process) - Google Patents

무세척 인산염 처리법(no-rinse phosphatising process) Download PDF

Info

Publication number
KR970706420A
KR970706420A KR1019970701888A KR19970701888A KR970706420A KR 970706420 A KR970706420 A KR 970706420A KR 1019970701888 A KR1019970701888 A KR 1019970701888A KR 19970701888 A KR19970701888 A KR 19970701888A KR 970706420 A KR970706420 A KR 970706420A
Authority
KR
South Korea
Prior art keywords
phosphate
zinc
acid
weight
ions
Prior art date
Application number
KR1019970701888A
Other languages
English (en)
Other versions
KR100347405B1 (ko
Inventor
라인하르트 자이델
베른트 마이어
멜라니 요펜
멜리타 크라우제
요르그 리소프
Original Assignee
베르크만 미카엘, 글라슬 요한
헨켈 코만디트게젤샤프트 아우프 아크티엔
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 베르크만 미카엘, 글라슬 요한, 헨켈 코만디트게젤샤프트 아우프 아크티엔 filed Critical 베르크만 미카엘, 글라슬 요한
Publication of KR970706420A publication Critical patent/KR970706420A/ko
Application granted granted Critical
Publication of KR100347405B1 publication Critical patent/KR100347405B1/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/18—Orthophosphates containing manganese cations
    • C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
    • C23C22/184—Orthophosphates containing manganese cations containing also zinc cations containing also nickel cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/12—Orthophosphates containing zinc cations
    • C23C22/17—Orthophosphates containing zinc cations containing also organic acids
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/07—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing phosphates
    • C23C22/08—Orthophosphates
    • C23C22/18—Orthophosphates containing manganese cations
    • C23C22/182—Orthophosphates containing manganese cations containing also zinc cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/362—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also zinc cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C23C22/36—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates
    • C23C22/364—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations
    • C23C22/365—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides containing also phosphates containing also manganese cations containing also zinc and nickel cations
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/73—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals characterised by the process
    • C23C22/76—Applying the liquid by spraying

Landscapes

  • Chemical & Material Sciences (AREA)
  • General Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Chemical Treatment Of Metals (AREA)
  • Saccharide Compounds (AREA)

Abstract

본 발명의 인산염 처리액과 상기 인산염 처리액에 의한 인산염 처리법은 강, 아연-도금된 강 또는 알루미늄 스트립의 웨브를 씻지 않고 인산염 처리하는데에 사용되는 것이 좋다(무세척 인산염처리). 이 인산염 처리액은 적어도 2 내지 25g/1의 아연 이온 및 50 내지 300g/1의 인산연 이온을 함유한다.

Description

무세척 인산염 처리법(NO-RINSE PHOSPHATISING PROCESS)
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (18)

  1. 강, 아연, 알루미늄 또는 그것들의 합금들의 표면을 산성 아연-및 인산염-함유 용액들에 의한 처리 및 상기 용액들의 무세척 건조에 의해 인산염 처리하기 위한 방법에 있어서, 상기 표면을 2 내지 25g/1의 아연 이온 및 50 내지 300g/1의 인산염 이온을 함유하며 pH값이 1 내지 4인 인산염 처리액과 접촉시킴을 특징으로 하는 방법.
  2. 청구항 1에 있어서, 상기 표면을 2 내지 25g/1의 망간 이온을 추가로 함유하는 인산염 처리액과 접촉시킴을 특징으로 하는 방법.
  3. 청구항 1 또는 청구항 2에 있어서, 상기 인산염 처리액은 다음의 성분들의 하나 또는 그 이상을 추가로 함유함을 특징으로 방법 : 바람직하게는 0.1 내지 15g/1의 양의 Ni, Co, Ca, Mg, 더욱 바람직하게는 Ni, 3 내지 200mg/1의 양의 구리, 0.01 내지 5g/1의 양의 철에서 선택된 하나 또는 그 이상 추가된 이가 금속이온, 0.01 내지 5g/1의 유리 또는 복합형의 불화물, 3 내지 6개의 탄소 원자를 함유하는 0.1 내지 100g/1의 킬레이트 히드록시카르복실산들, 바람직하게는 타르타르산 및/또는 시트르산.
  4. 청구항 1 내지 3의 한 항에 있어서, 상기 인산염 처리액은 유리 산의 함유량이 0 내지 100 포인트이고, 전체 산 함유량은 40 내지 400 포인트이며 바람직하게는 유리 산 대 전체 산의 비가 1 : 4 내지 1 : 20 임을 특징으로 하는 방법.
  5. 청구항 1 내지 4의 한 항에 있어서, 상기 인산염 처리액은 온도가 15 내지 80℃, 바람직하게는 20 내지 40℃임을 특징으로 하는 방법.
  6. 청구항 1 내지 5의 한 항에 있어서, 상기 인산염 처리액은 금속 이온들, 인산 및, 존재하는 경우, 청구항 2에 따른 기타 성분들의 합으로서 정의된 활성 물질의 함유량이 5.5 내지 35중량% 임을 특징으로 하는 방법.
  7. 청구항 1 내지 6의 한 항에 있어서, 이동 금속 스트립들의 표면을 처리하기 위한 것임을 특징으로 하는 방법.
  8. 청구항 1 내지 7의 한 항에 있어서, 상기 인산염 처리액을 표면에 분무하여, 바람직하게는 스퀴즈 롤들에 의해, 2 내지 10ml/㎡의 액체 필름 코팅이 되게 조절함을 특징으로 하는 방법.
  9. 청구항 1 내지 7의 한 항에 있어서, 상기 인산염 처리액을 2 내지 10ml/㎡의 액체 필름 코팅으로서 도포기롤들에 의해 표면에 도포함을 특징으로 하는 방법.
  10. 청구항 1 내지 7의 한 항에 있어서, 상기 표면을 인산염 처리액에 침지시키며, 이 인산염 처리액에서 빼낸 후, 그 표면상에, 바람직하게는 스퀴즈 롤들에 의해, 2 내지 10ml/㎡의 액체 필름 코팅을 조절함을 특징으로 하는 방법.
  11. 청구항 1 내지 10의 한 항에 있어서, 상기 인산염 처리액은 5.5 내지 35중량%의 활성 물질 함유량, 1.0 내지 2.2의 pH 값 및/또는 1 : 5 내지 1 : 6 의 (이가 금속 이온들의 합) 대 인산염의 중량비를 가짐을 특징으로 하는, 융해-아연도금된 강의 연속 스트립들의 표면을 처리하기 위한 방법.
  12. 청구항 1 내지 10의 한 항에 있어서, 상기 인산염 처리액은 5.5 내지 20중량%의 활성 물질 함유량, 1.5 내지 3.5의 pH값 및/또는 1 : 5 내지 1 : 6의 (이가 금속 이온들의 합) 대 인산염의 중량비 그리고 바람직하게는, 3 내지 6개의 탄소 원자를 함유하는 1 내지 5중량%의 킬레이트 히드록시카르복실산, 바람직하게는 시트르산 및/또는 타르타르산을 가짐을 특징으로 하는, 전기분해-아연도금된 강의 이동 스트립들의 표면을 처리하기 위한 방법.
  13. 청구항 1 내지 10의 한 항에 있어서, 상기 인산염 처리액은 5.5 내지 25중량%의 활성 물질 함유량, 2.0 내지 4.0의 pH값 및/또는 1 : 2.5 내지 1: 6의 (이가 금속 이온들의 합) 대 인산염의 중량비 그리고 바람직하게는, 3 내지 6개의 탄소 원자를 함유하는 1 내지 10중량%의 킬레이트 히드록시카르복실산, 바람직하게는 시트르산 및/또는 타르타르산을 가짐을 특징으로 하는, 냉간압연-비아연도금된 강의 표면을 처리하기 위한 방법.
  14. 청구항 1 내지 13의 한 항에 있어서, 건조는 온도 50 내지 120℃에서 바람직하게는 60 내지 90℃에서, 바람직하게는 건조 오븐에서, 뜨거운 기체들 바람직하게는 공기를 불어넣기 및/또는 적외선 복사에의 노출에 의해 수행되고, 표면과 인산염 처리액간의 첫 번째 접촉과 건조 단계의 끝 사이의 시간 경과는 바람직하게는 3 내지 30초임을 특징으로 하는 방법.
  15. 청구항 1 내지 14의 한 항에 있어서, 0.3 내지 3g/㎡의 코팅 중량을 갖는 결정질 또는 X-선-비결정질 아연-함유 인산염 코팅을 제조하기 위해 강, 아연, 알루미늄 또는 그것들의 합금들의 표면을 예비처리함을 특징으로 하는 방법.
  16. 강, 아연, 알루미늄 또는 그것들의 합금들의 표면을 인산염으로 처리하기 위한 아연-및 망간-함유의 산성 수성 인산염 처리액으로서, 2 내지 25g/1의 아연이온, 2 내지 25g/1의 망간 이온 및 50 내지 300g/1의 인산염 이온을 함유하며 pH값이 1 내지 4임을 특징으로 하는 인산염 처리액.
  17. 청구항 16에 있어서, 다음의 성분들의 하나 또는 그 이상을 추가로 함유함을 특징으로 하는 인산염 처리액 : 바람직하게는, 0.1 내지 15g/1의 양의 Ni, Co, Ca, Mg, 더욱 바람직하게는 Ni, 0.01 내지 5g/1의 양의 철, 3 내지 200mg/1의 양의 구리에서 선택된 하나 또는 그 이상 추가된 이가 금속 이온, 0.01 내지 5g/1의 유리 또는 복합형의 불화물, 3 내지 6개의 탄소 원자를 함유하는 0.1 내지 100g/1의 킬레이트 히드록시카르복실산들, 바람직하게는 타르타르산 및/또는 시트르산.
  18. 청구항 16 또는 청구항 17에 있어서, 유리 산의 함유량이 0 내지 100 포인트이고, 전체 산 함유량은 40 내지 400포인트이며, 바람직하게는 유리 산 대 전체 산의 비가 1 : 4 내지 1 : 20 임을 특징으로 하는 인산염 처리액.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019970701888A 1994-09-23 1995-09-14 무세척 인산염처리법 KR100347405B1 (ko)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DEP4433946.1 1994-09-23
DE4433946A DE4433946A1 (de) 1994-09-23 1994-09-23 Phosphatierverfahren ohne Nachspülung
PCT/EP1995/003619 WO1996009422A1 (de) 1994-09-23 1995-09-14 Phosphatierverfahren ohne nachspülung

Publications (2)

Publication Number Publication Date
KR970706420A true KR970706420A (ko) 1997-11-03
KR100347405B1 KR100347405B1 (ko) 2002-12-05

Family

ID=6528963

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019970701888A KR100347405B1 (ko) 1994-09-23 1995-09-14 무세척 인산염처리법

Country Status (9)

Country Link
US (1) US5976272A (ko)
EP (1) EP0774016B1 (ko)
JP (1) JPH10505881A (ko)
KR (1) KR100347405B1 (ko)
AT (1) ATE182632T1 (ko)
CA (1) CA2200893A1 (ko)
DE (2) DE4433946A1 (ko)
ES (1) ES2135090T3 (ko)
WO (1) WO1996009422A1 (ko)

Families Citing this family (25)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE19639597C2 (de) * 1996-09-26 2000-01-20 Henkel Kgaa Verfahren zur Phosphatierung von laufenden Bändern aus kalt- oder warmgewalztem Stahl in schnellaufenden Bandanlagen
US6179934B1 (en) 1997-01-24 2001-01-30 Henkel Corporation Aqueous phosphating composition and process for metal surfaces
JPH10204649A (ja) * 1997-01-24 1998-08-04 Nippon Parkerizing Co Ltd 金属表面のりん酸塩処理水溶液及び処理方法
US5968240A (en) * 1997-08-19 1999-10-19 Sermatech International Inc. Phosphate bonding composition
DE19749508A1 (de) * 1997-11-08 1999-05-12 Henkel Kgaa Korrosionsschutz von verzinkten und legierungsverzinkten Stahlbändern
DE19844391C2 (de) 1998-09-28 2003-01-09 Chemetall Gmbh Verfahren zur Vorbereitung von Werkstücken für die Kaltumformung
US6162508A (en) * 1998-11-02 2000-12-19 Nortel Networks Limited Molybdenum phosphate based corrosion resistant conversion coatings
TW500827B (en) * 1999-08-06 2002-09-01 Sms Demag Ag Process and installation for hot galvanizing of hot rolled steel strip
DE10010355A1 (de) 2000-03-07 2001-09-13 Chemetall Gmbh Verfahren zum Aufbringen eines Phosphatüberzuges und Verwendung der derart phosphatierten Metallteile
JP2001295063A (ja) * 2000-04-10 2001-10-26 Nippon Parkerizing Co Ltd 非鉄金属材料およびめっき鋼板へのりん酸塩被膜の形成方法
DE10110834B4 (de) * 2001-03-06 2005-03-10 Chemetall Gmbh Verfahren zur Beschichtung von metallischen Oberflächen und Verwendung der derart beschichteten Substrate
DE10110833B4 (de) * 2001-03-06 2005-03-24 Chemetall Gmbh Verfahren zum Aufbringen eines Phosphatüberzuges und Verwendung der derart phosphatierten Metallteile
US20020164425A1 (en) * 2001-04-27 2002-11-07 Rivard Douglas Charles Method for treating iron based parts
EP1433875B1 (en) * 2002-12-24 2013-11-27 Chemetall GmbH Chemical conversion coating agent and surface-treated metal
DE102005023023B4 (de) * 2005-05-19 2017-02-09 Chemetall Gmbh Verfahren zur Vorbereitung von metallischen Werkstücken zum Kaltumformen, mit dem Verfahren beschichtete Werkstücke und ihre Verwendung
JP5114834B2 (ja) * 2005-09-21 2013-01-09 Ｊｆｅスチール株式会社 冷延鋼板およびその製造方法
US20080283152A1 (en) * 2007-05-17 2008-11-20 Jeffrey Allen Greene Rinse conditioner bath for treating a substrate and associated method
WO2009017535A2 (en) * 2007-06-07 2009-02-05 Henkel Ag & Co. Kgaa High manganese cobalt-modified zinc phosphate conversion coating
KR101016915B1 (ko) * 2007-11-28 2011-02-22 가부시키가이샤 고베 세이코쇼 표면 안정성이 우수한 알루미늄 합금재 및 그 제조 방법
CA2902066C (en) * 2013-03-06 2018-01-02 Quaker Chemical Corporation High temperature conversion coating on steel and iron substrates
MX2016017241A (es) * 2014-06-27 2017-04-25 Henkel Ag & Co Kgaa Lubricante seco para acero con recubrimiento de zinc.
KR101769302B1 (ko) * 2016-06-08 2017-08-18 현대자동차주식회사 망간 함량을 최적화시킨 인산염 피막 조성물 및 아연계 전기도금강판의 인산염 처리 방법
US10465292B2 (en) * 2016-10-07 2019-11-05 Goodrich Corporation Anti-corrosion and/or passivation composition for metal-containing substrates and methods for making, enhancing, and applying the same
DE102017207591A1 (de) * 2017-05-05 2018-11-08 Federal-Mogul Nürnberg GmbH Stahlkolben mit einer Phosphat-Schicht
WO2022232817A1 (en) * 2021-04-30 2022-11-03 Ppg Industries Ohio, Inc. Methods of making coating layers and substrates having same coating layers

Family Cites Families (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3819425A (en) * 1972-10-18 1974-06-25 Diamond Shamrock Corp Composite coating adherent under shear condition
JPS50139039A (ko) * 1974-04-26 1975-11-06
US3939014A (en) * 1974-11-20 1976-02-17 Amchem Products, Inc. Aqueous zinc phosphating solution and method of rapid coating of steel for deforming
IT1065925B (it) * 1976-09-03 1985-03-04 Pirelli Apparato per riunire tra di loro dei filamenti sottili
JPS5339945A (en) * 1976-09-25 1978-04-12 Nippon Packaging Kk Surface treatment of zinc or zinc alloy
DE2905535A1 (de) * 1979-02-14 1980-09-04 Metallgesellschaft Ag Verfahren zur oberflaechenbehandlung von metallen
US4316751A (en) * 1980-04-14 1982-02-23 Hooker Chemicals & Plastics Corp. Electrical resistance coating for steel
DE3023479A1 (de) * 1980-06-24 1982-01-14 Metallgesellschaft Ag, 6000 Frankfurt Phosphatierverfahren
GB2148950B (en) * 1983-10-26 1987-02-04 Pyrene Chemical Services Ltd Phosphating composition and processes
DE3636390A1 (de) * 1986-10-25 1988-04-28 Metallgesellschaft Ag Verfahren zur erzeugung von phosphatueberzuegen auf metallen
DE3800834A1 (de) * 1988-01-14 1989-07-27 Henkel Kgaa Verfahren und mittel zum gleichzeitigen gleitschleifen, reinigen und passivieren metallischer werkstuecke
EP0327153B1 (de) * 1988-02-03 1993-08-04 Metallgesellschaft Ag Verfahren zur Erzeugung von Phosphatüberzügen auf Metallen
GB9207725D0 (en) * 1992-04-08 1992-05-27 Brent Chemicals Int Phosphating solution for metal substrates
DE4241134A1 (de) * 1992-12-07 1994-06-09 Henkel Kgaa Verfahren zur Phosphatierung von Metalloberflächen

Also Published As

Publication number Publication date
DE4433946A1 (de) 1996-03-28
WO1996009422A1 (de) 1996-03-28
EP0774016B1 (de) 1999-07-28
ATE182632T1 (de) 1999-08-15
ES2135090T3 (es) 1999-10-16
KR100347405B1 (ko) 2002-12-05
CA2200893A1 (en) 1996-03-28
EP0774016A1 (de) 1997-05-21
JPH10505881A (ja) 1998-06-09
DE59506484D1 (de) 1999-09-02
US5976272A (en) 1999-11-02

Similar Documents

Publication Publication Date Title
KR970706420A (ko) 무세척 인산염 처리법(no-rinse phosphatising process)
US4278477A (en) Metal treatment
JP3063920B2 (ja) リン酸塩で金属表面を処理する方法
US5089349A (en) Compositions and method for applying coatings to metallic surfaces
JPS5949315B2 (ja) アルミニウムのコ−テイング法およびコ−テイング組成物
FI70599B (fi) Vattenhaltiga sura zink-fosfatbelaeggningsloesningar och foerfaranden som fungerar vid en laog temperatur och anvaender desa vid bildande av en kemisk konversionsbelaeggning pao j aen och/eller zinkytor
BR9912332A (pt) Composição lìquida, e, processo para condicionar uma superfìcie metálica.
KR960705076A (ko) 니켈이 없는 인산화 방법(nickel-free phosphatization process)
US4963198A (en) Composition and process for treating metal surfaces
CA2309581C (en) Corrosion protection of steel strips coated with zinc or zinc alloy
DE59406893D1 (de) Verfahren zur phosphatierenden behandlung von einseitig verzinktem stahlband
US5891268A (en) High coating weight iron phosphating, compositions therefor, and use of the coating formed as a lubricant carrier
GB1498718A (en) Process for phosphating metal surfaces
JPH06228766A (ja) リン酸塩皮膜を形成する方法
WO2001055480A1 (en) Phosphate conversion coating process and composition
JPH0730454B2 (ja) 金属基材の化学的転換方法
JPS63186879A (ja) リン酸塩皮膜の形成方法
JPS6179782A (ja) りん酸塩処理方法
US5238505A (en) Method for applying tellurium-containing coatings to metallic surfaces using organic acids
JP2002088483A (ja) アルミニウム及びその合金の表面処理用組成物及び処理方法
JPH0129871B2 (ko)
CA2080033A1 (en) Method for applying tellurium-containing coatings to metallic surfaces using cyclodextrin/tellurium compositions
JPS6123769A (ja) 化成処理されたアルミニウム含有亜鉛めつき合金鋼板
JPS5839231B2 (ja) 錫メツキ缶の化成処理方法
JPS59205482A (ja) 合わせ板のリン酸塩皮膜化成処理方法

Legal Events

Date Code Title Description
A201 Request for examination
E701 Decision to grant or registration of patent right
GRNT Written decision to grant
LAPS Lapse due to unpaid annual fee