KR960031510A - 유기적으로 개질된 방사선 경화성 실록산 수지 제조법 - Google Patents

유기적으로 개질된 방사선 경화성 실록산 수지 제조법 Download PDF

Info

Publication number
KR960031510A
KR960031510A KR1019960004968A KR19960004968A KR960031510A KR 960031510 A KR960031510 A KR 960031510A KR 1019960004968 A KR1019960004968 A KR 1019960004968A KR 19960004968 A KR19960004968 A KR 19960004968A KR 960031510 A KR960031510 A KR 960031510A
Authority
KR
South Korea
Prior art keywords
group
alkoxy
alkoxysilane
organometallic compound
reaction product
Prior art date
Application number
KR1019960004968A
Other languages
English (en)
Inventor
도날드 블리자드 존
스티븐 통 제임스
Original Assignee
노만 에드워드 루이스
다우 코닝 코포레이션
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by 노만 에드워드 루이스, 다우 코닝 코포레이션 filed Critical 노만 에드워드 루이스
Publication of KR960031510A publication Critical patent/KR960031510A/ko

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D183/00—Coating compositions based on macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon, with or without sulfur, nitrogen, oxygen, or carbon only; Coating compositions based on derivatives of such polymers
    • C09D183/10—Block or graft copolymers containing polysiloxane sequences
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/22—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes
    • B05D7/227—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to internal surfaces, e.g. of tubes of containers, cans or the like
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F283/00—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
    • C08F283/12—Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G on to polysiloxanes
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L69/00—Compositions of polycarbonates; Compositions of derivatives of polycarbonates
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D4/00—Coating compositions, e.g. paints, varnishes or lacquers, based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; Coating compositions, based on monomers of macromolecular compounds of groups C09D183/00 - C09D183/16
    • C09D4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/13—Hollow or container type article [e.g., tube, vase, etc.]
    • Y10T428/1352—Polymer or resin containing [i.e., natural or synthetic]
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31507—Of polycarbonate
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31652—Of asbestos
    • Y10T428/31663—As siloxane, silicone or silane
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y10—TECHNICAL SUBJECTS COVERED BY FORMER USPC
    • Y10T—TECHNICAL SUBJECTS COVERED BY FORMER US CLASSIFICATION
    • Y10T428/00—Stock material or miscellaneous articles
    • Y10T428/31504—Composite [nonstructural laminate]
    • Y10T428/31786—Of polyester [e.g., alkyd, etc.]

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Silicon Polymers (AREA)
  • Paints Or Removers (AREA)
  • Macromonomer-Based Addition Polymer (AREA)
  • Treatments Of Macromolecular Shaped Articles (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

본 발명은 하나 이상의 다작용성 아크릴레이트(A)와 알콕시 작용성 유기 금속 화합물(a), 알콕시실란(b) 및 물(c)로부터 형성된 반응 생성물(B)로부터 제조한 방사선 경화성의 유기적으로 개질된 실록산 수지 조성물에 관한 것이다. 알콕시실란(b)는 알콕시실란을 다작용성 아크릴레이트(A)와 공중합가응하게 하는 하나 이상의 작용성 그룹을 포함한다. 바람직한 양태에 있어서, 알콕시 작용성 유기 금속 화합물(a)과 알콕시실란(b)은 실록산 중합 촉매(d)의 존재하에 공가수분해 및 공축합을 일으킨다.

Description

유기적으로 개질된 방사선 경화성 실록산 수지 제조법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (10)

  1. 하나 이상의 다작용성 아크릴레이트(A)와 일반식 M(OR)4의 하나 이상의 알콕시 작용성 유기 금속화합물(a)(여기서, M은 Si 및 Ti로부터 선택되며, OR은 각각 동일하거나 상이한 알콕시 그룹이다), 일반식의 하나 이상의 알콕시 작용성 실란(b)〔여기서, OR은 각각 위에서 정의한 바와 같고, X는 각각 알콕시실란이 다작용성 아크릴레이트(A)와 공중합될 수 있도록 하는 1가 라디칼이며, 각각 독립적으로 일반식 〔QNH〕dQNZH의 알킬아민(여기서, Q는 2가 탄화수소 그룹이며, Q 그룹은 동일하거나 상이할 수 있고, Z는 수소원자 또는 1가 탄화수소 라디칼이며, d는 0 또는 1이다) 및 1가 불포화 탄화수소 라디칼로 이루어진 그룹으로부터 선택되며, R'는 각각 독립적으로 1가 탄화수소 라디칼이고, a는 1, 2 또는 3이며, b는 1, 2 또는 3이고, c는 0, 1 또는 2이며, a+b+c=4이다〕 및 반응생성물(B)를 겔화시키거나 이로부터 침전물을 형성시키지 않고 공가수분해와 공축합이 일어나게 하기에 충분한 예정된 양의 물(c)을 공가수분해 및 공축합시킴으로써 형성된 반응 생성물(B)을 포함하는 방사선 경화성 조성물.
  2. 제1항에 있어서, 1가 불포화 탄화수소 라디칼이 비닐, 헥세닐, 메타크릴옥시, 아크릴옥시, 스티릴 및 비닐에테르 라디칼로 이루어진 그룹으로부터 선택되는 조성물.
  3. 지지체의 하나 이상의 표면을 제1항 또는 제2항의 조성물로 피복하고 피복된 지지체 위의 피막을 경화시켜 제품을 제조하기 위한, 제1항 또는 제2항의 조성물의 용도.
  4. 제3항에 있어서, 지지체가 폴리에틸렌 테레프탈레이트 또는 폴리카보네이트인 제품.
  5. 제4항에 있어서, 지지체가 음료 용기의 형태인 제품.
  6. 일반식 M(OR)4의 하나 이상의 알콕시 작용성 유기 금속 화합물(a)(여기서, M은 Si 및 Ti로부터 선택되며, OR은 각각 동일하거나 상이한 알콕시 그룹이다), 일반식의 하나 이상의 알콕시 작용성 실란(b)〔여기서, OR은 각각 위에서 정의한 바와 같고, X는 각각 알콕시실란이 다작용성 아크릴레이트(A)와 공중합될 수 있도록 하는 1가 라디칼이며, 각각 독립적으로 일반식 〔QNH〕dQNZH의 알킬아민(여기서, Q는 2가 탄화수소 그룹이며, Q 그룹은 동일하거나 상이할 수 있고, Z는 수소원자 또는 1가 탄화수소 라디칼이며, d는 0 또는 1이다) 및 1가 불포화 탄화수소 라디칼로 이루어진 그룹으로부터 선택되며, R'는 각각 독립적으로 1가 탄화수소 라디칼이고, a는 1, 2 또는 3이며, b는 1, 2 또는 3이고, c는 0, 1 또는 2이며, a+b+c=4이다〕 및 겔화를 일으키거나 침전물을 발생시키지 않고 알콕시 작용성 유기 금속 화합물(a)과 알콕시실란(b)이 공가수분해와 공축합을 일으키도록 하기에 충분한 예정된 양의 물(c)을 공가수분해시키고 공축합시키는 단계(1) 및 하나 이상의 다작용성 아크릴레이트를 성분(a), (b) 및 (c)와 혼합하거나 단계(a)에서 수득한 이의 반응 생성물(B)과 혼합하는 단계(2)를 포함하여, 유기적으로 개질된 방사선 경화성 실록산 수지를 제조하는 방법.
  7. 제6항에 있어서, 반응 생성물(B)이 H2SO4, HClO4, 트리플루오로메탄 설폰산, 아크릴산, KOH, NaOH 및 아민 함유 화합물로 이루어진 그룹으로부터 선택된 실록산 중합촉매(d)를 추가로 포함하는 방법.
  8. 제6항 또는 제7항에 있어서, 하나 이상의 알콕시 작용성 유기 금속 화합물(a)과 하나 이상의 알콕시실란(b)을 반응단계(1) 동안 성분(a)와 성분(b)가 공가수분해와 공축합을 일으키도록 하기에 충분한 예정된 양의 물(c)과 동시 혼합시키는 방법.
  9. 제8항에 있어서, 공가수분해와 공축합이 다작용성 아크릴레이트의 존재하에 일어나는 방법.
  10. 제9항에 있어서, 하나 이상의 광개시제를 단계(1)과 (2)에서 수득한 생성물과 혼합시키는 단계(3)를 추가로 포함하는 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019960004968A 1995-02-28 1996-02-28 유기적으로 개질된 방사선 경화성 실록산 수지 제조법 KR960031510A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
US39525095A 1995-02-28 1995-02-28
US08/395,250 1995-02-28

Publications (1)

Publication Number Publication Date
KR960031510A true KR960031510A (ko) 1996-09-17

Family

ID=23562271

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019960004968A KR960031510A (ko) 1995-02-28 1996-02-28 유기적으로 개질된 방사선 경화성 실록산 수지 제조법

Country Status (8)

Country Link
US (1) US5840428A (ko)
EP (1) EP0730015B1 (ko)
JP (1) JPH08253708A (ko)
KR (1) KR960031510A (ko)
AT (1) ATE175711T1 (ko)
AU (1) AU698030B2 (ko)
DE (1) DE69601316T2 (ko)
ZA (1) ZA961315B (ko)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100773919B1 (ko) * 2005-08-01 2007-11-08 김영백 실란 화합물을 이용하는 금속 나노입자의 형성 및/또는고정 방법

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US5626964A (en) * 1995-10-24 1997-05-06 Dow Corning Corporation Radiation-curable silicone resins formulated from amine alcohols, tetra-alkoxysilanes and multifunctional acrylates
JP3419242B2 (ja) * 1996-07-18 2003-06-23 信越化学工業株式会社 バインダー組成物及び水系コーティング剤
GB9624881D0 (en) * 1996-11-29 1997-01-15 Courtaulds Coatings Holdings Coating compositions
KR19980079940A (ko) * 1997-03-05 1998-11-25 후지이 히로시 빗물오염방지성 도막, 도료 조성물, 도막 형성방법 및 도장물
US6281321B1 (en) 1997-11-27 2001-08-28 Akzo Nobel N.V. Coating compositions
JP3385217B2 (ja) * 1998-08-05 2003-03-10 日本合成化学工業株式会社 シリコン含有水性コーティング剤組成物の製造法
EP1045009A1 (en) * 1999-04-16 2000-10-18 Dow Corning Corporation Heat curable silcone acrylate coating compositions
DE19961632A1 (de) * 1999-12-14 2001-06-28 Inst Oberflaechenmodifizierung Kit zur Beschichtung von Oberflächen, strahlenhärtbares Beschichtungsmittel und Verfahren zur Erzeugung von kratz-, abrieb- und haftfesten Beschichtungen
US6531210B1 (en) 1999-12-30 2003-03-11 United States Gypsum Company Application of methylenediphenyldiisocyanate for producing gypsum/wood fiber board
JP2002012638A (ja) 2000-06-30 2002-01-15 Dow Corning Toray Silicone Co Ltd 高エネルギー線硬化性組成物および樹脂成形体
US6706821B1 (en) 2000-07-18 2004-03-16 Fmc Corporation Michael addition products of amine terminated polyolefins and polyfunctional acrylates
US7018057B2 (en) * 2000-08-23 2006-03-28 Vtec Technologies, Llc Transparent plastic optical components and abrasion resistant polymer substrates and methods for making the same
US6458462B1 (en) 2000-12-13 2002-10-01 3M Innovative Properties Company Sporting goods having a ceramer coating
US6822063B2 (en) * 2002-08-27 2004-11-23 Ecolab Inc. Highly durable waterborne radiation cured coating
JP4646497B2 (ja) * 2003-03-06 2011-03-09 東レ・ダウコーニング株式会社 高エネルギー線硬化性アクリロキシ官能シリコーン組成物
CN1935872B (zh) * 2005-09-23 2010-08-18 长兴化学工业股份有限公司 可辐射固化的烷氧硅烷化超支链化聚酯丙烯酸酯和其制备方法
JP2007126491A (ja) * 2005-11-01 2007-05-24 Soken Chem & Eng Co Ltd 反応性有機−無機ハイブリット成分含有の重合性有機モノマー液状組成物、その製造方法及びその用途
US9193880B2 (en) * 2006-12-19 2015-11-24 Dow Global Technologies Llc Adhesion promotion additives and methods for improving coating compositions
CN101558456B (zh) 2006-12-19 2013-07-24 陶氏环球技术公司 经改善的用于导电透明基材的复合材料和方法
US7939161B2 (en) 2006-12-19 2011-05-10 Dow Global Technologies Llc Encapsulated panel assemblies and methods for making same
BRPI0823177A2 (pt) * 2007-04-24 2013-09-24 Dow Global Technologies Inc aditivo para uma composiÇço de primer, mÉtodo para melhorar o desempenho de uma composiÇço de primer, composiÇço de primer e kit
ATE536381T1 (de) * 2007-04-24 2011-12-15 Dow Global Technologies Llc Einteiliger glas-primer mit oxazoladin
JP5680410B2 (ja) * 2007-07-12 2015-03-04 ダウ グローバル テクノロジーズ エルエルシー 着色プライマー組成物及び方法
US8772407B2 (en) * 2007-09-17 2014-07-08 Ppg Industries Ohio, Inc. One component polysiloxane coating compositions and related coated substrates
CN101903483B (zh) * 2007-12-18 2014-09-10 陶氏环球技术公司 对玻璃粘合剂具有增强的粘合性的窗玻璃用保护涂层
EP2350211B1 (en) * 2008-10-29 2018-02-28 Dow Global Technologies LLC Low energy surface bonding system containing a primer with long open time
US8405233B2 (en) 2009-01-14 2013-03-26 Dow Corning Corporation Flexible barrier film, method of forming same, and organic electronic device including same
WO2010083242A1 (en) 2009-01-14 2010-07-22 Dow Corning Corporation Adhesive flexible barrier film, method of forming same, and organic electronic device including same
CN102782065A (zh) 2010-02-26 2012-11-14 新日铁化学株式会社 涂覆剂组合物
TWI537132B (zh) 2010-07-02 2016-06-11 ３Ｍ新設資產公司 阻隔組合
CA2855120A1 (en) 2011-11-10 2013-05-16 Momentive Performance Materials Inc. Moisture curable organopolysiloxane composition
JP6297498B2 (ja) 2011-12-15 2018-03-20 モーメンティブ・パフォーマンス・マテリアルズ・インク 湿気硬化性オルガノポリシロキサン組成物
CA2859356A1 (en) 2011-12-15 2013-06-20 Momentive Performance Materials, Inc. Moisture curable organopolysiloxane compositions
CA2861659A1 (en) 2011-12-29 2013-07-04 Momentive Performance Materials, Inc. Moisture curable organopolysiloxane composition
JP2015524003A (ja) * 2012-05-02 2015-08-20 モーメンティブ・パフォーマンス・マテリアルズ・インク 湿気硬化性オルガノポリシロキサン組成物
TWI610806B (zh) 2012-08-08 2018-01-11 ３Ｍ新設資產公司 障壁膜，製造該障壁膜之方法，及包含該障壁膜之物件
KR102126719B1 (ko) 2012-08-08 2020-06-25 쓰리엠 이노베이티브 프로퍼티즈 캄파니 배리어 필름 구조물 및 이의 제조방법
ES2688532T3 (es) 2013-01-18 2018-11-05 Basf Se Composiciones de recubrimiento a base de dispersión acrílica
TW201434882A (zh) 2013-03-13 2014-09-16 Momentive Performance Mat Inc 可濕氣固化之有機聚矽氧烷組成物
WO2014183029A2 (en) 2013-05-10 2014-11-13 Momentive Performance Materials Inc. Non-metal catalyzed room temperature moisture curable organopolysiloxane compositions
US10155858B2 (en) 2014-03-17 2018-12-18 Dow Corning Corporation Curable composition, cured product formed from the curable composition, and method of forming the cured product
WO2015142560A1 (en) 2014-03-17 2015-09-24 Dow Corning Corporation Fluorinated compound, curable composition comprising same, and cured product
CN104178024A (zh) * 2014-08-18 2014-12-03 陈东杰 一种固化后可成型的透明耐磨涂料的制备方法
DE102019112809A1 (de) * 2019-05-15 2020-11-19 Kds Holding Gmbh Korrosionsschutz für metallische Oberflächen, Verwendung eines Kunststoffs, Verfahren zum Aufbringen des Korrosionsschutzes und Set
CN113698870B (zh) * 2021-08-31 2022-05-24 河南金欧特实业集团股份有限公司 沥青路面高效还原修复剂、制备方法及应用

Family Cites Families (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US4455205A (en) * 1981-06-01 1984-06-19 General Electric Company UV Curable polysiloxane from colloidal silica, methacryloyl silane, diacrylate, resorcinol monobenzoate and photoinitiator
US4486504A (en) * 1982-03-19 1984-12-04 General Electric Company Solventless, ultraviolet radiation-curable silicone coating compositions
EP0486469B2 (en) * 1986-10-03 2000-06-21 PPG Industries Ohio, Inc. Organic-inorganic hybrid polymer
US4814017A (en) * 1986-10-03 1989-03-21 Ppg Industries, Inc. Aqueous organoalkoxysilane/metal oxide sol-gel compositions
CA2018237C (en) * 1989-07-14 2000-05-09 Antony P. Wright Radiation curable acryloxyfunctional silicone coating composition
JP3088511B2 (ja) * 1991-09-27 2000-09-18 三菱レイヨン株式会社 被覆用組成物及び表面被覆物品
US5318850A (en) * 1991-11-27 1994-06-07 General Electric Company UV curable abrasion-resistant coatings with improved weatherability
CA2086276C (en) * 1992-12-24 2001-12-11 Masamoto Uenishi Coated shaped articles and method of making same

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR100773919B1 (ko) * 2005-08-01 2007-11-08 김영백 실란 화합물을 이용하는 금속 나노입자의 형성 및/또는고정 방법

Also Published As

Publication number Publication date
AU4572496A (en) 1996-09-05
US5840428A (en) 1998-11-24
EP0730015B1 (en) 1999-01-13
DE69601316D1 (de) 1999-02-25
ATE175711T1 (de) 1999-01-15
ZA961315B (en) 1996-07-29
JPH08253708A (ja) 1996-10-01
AU698030B2 (en) 1998-10-22
DE69601316T2 (de) 1999-08-26
EP0730015A1 (en) 1996-09-04

Similar Documents

Publication Publication Date Title
KR960031510A (ko) 유기적으로 개질된 방사선 경화성 실록산 수지 제조법
US4921880A (en) Adhesion promoter for UV curable siloxane compositions and compositions containing same
US5188864A (en) Adhesion promoter for UV curable siloxane compositions and compositions containing same
CN1918256B (zh) 具有改进的表面性质的可固化硅氧烷组合物
JP3306442B2 (ja) フッ素を含有する無機縮重合体を基礎とする塗料組成物、その製造方法及びその利用方法
JP2605229B2 (ja) アクリル官能性シロキサン
KR100338136B1 (ko) 오르가노폴리실록산 및 오르가노폴리실록산의 제조방법
JP4646497B2 (ja) 高エネルギー線硬化性アクリロキシ官能シリコーン組成物
CA2279811C (en) Radiation-curable organosiloxane coating compositions
JPH0627277B2 (ja) アクリル化エポキシシリコーン被覆物品およびその製法
JPS62187475A (ja) 有機ケイ素化合物およびその製法
JPH0678433B2 (ja) Ｕｖ硬化性シリコーンコポリマーおよびその製法
CN109735144B (zh) 一种光固化poss/氟烃基硅氧烷改性聚丙烯酸酯涂料组合物及其应用
JPH11293198A (ja) 放射線硬化性被覆中での（メタ）アクリレ―ト基を含有するオルガノポリシロキサンの使用
KR20020003089A (ko) 고에너지 방사선 경화성 조성물 및 수지 성형품
AU546017B2 (en) Ultraviolet light, cationic curable hard coating compositionsof polysiloxanes
JP3022101B2 (ja) 剥離性オルガノポリシロキサン組成物及び剥離紙
JP2858645B2 (ja) 架橋性ポリオルガノシロキサン組成物
US5075349A (en) Novel radiation-curable polymeric composition containing a diorganopolysiloxane with (meth)acryloxy end groups
JPH06298773A (ja) ジオール置換有機ケイ素化合物及びその製造方法
US4908228A (en) Dioxolane, diol and diacrylate silicon compounds and method for their preparation and use
JPH0368670A (ja) 放射線硬化性コーティング剤
JPH08239437A (ja) 脂環式エポキシ基含有シリコーングラフト型ビニルポリマーおよびその製造方法
JPH07165921A (ja) 新規シリコーン化合物
JPH09208830A (ja) 硬化性組成物およびプラスチックフィルム

Legal Events

Date Code Title Description
A201 Request for examination
E902 Notification of reason for refusal
E601 Decision to refuse application