KR900001657A - 피라졸 유도체 및 그를 함유하는 제초제 - Google Patents

피라졸 유도체 및 그를 함유하는 제초제 Download PDF

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KR900001657A
KR900001657A KR1019890010068A KR890010068A KR900001657A KR 900001657 A KR900001657 A KR 900001657A KR 1019890010068 A KR1019890010068 A KR 1019890010068A KR 890010068 A KR890010068 A KR 890010068A KR 900001657 A KR900001657 A KR 900001657A
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에이이찌 오오야
쥰이찌 와따나베
야쓰오 곤도
다꾸야 가꾸따
고오이찌 스즈끼
쓰도무 나와마끼
시게오미 와따나베
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나까이 다께오
닛산가가꾸고요교 가부시끼가이샤
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    • C07D231/18—One oxygen or sulfur atom
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    • C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
    • C07D231/18—One oxygen or sulfur atom
    • C07D231/20—One oxygen atom attached in position 3 or 5
    • C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
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Abstract

내용 없음

Description

피라졸 유도체 및 그를 함유하는 제초제
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (5)

  1. 하기일반식(I)의 피라졸 유도체 및 그의 염.
    [식중, A는 C1~C4알킬기, C2~C4알케닐기 또는 C2~C4알키닐기이며 ; B는 수소원자, C1~C3알킬기, 할로겐원자, C1~C3할로알킬기, C1~C3알콕시기, C1~C3알킬티오기, C2~C4알콕시 알킬기, C2~C4알킬티오알킬기 또는 C2~C4알콕시카르보닐기이며 ; X는 C1~C6알킬기, C1~C6알콕시기, 할로겐원자, 니트로기, 시아노기, C1~C6할로알킬기, C2~C6알콕시알킬기, C2~C6알킬카르보닐기, C2~C6알콕시카르보닐기, 수소원자 또는 C1~C6알킬기에 의해 각각 치환된 아미노카르보닐기, C1~C6할로알콕시기, C1~C6알킬티오기 또는 C2~C6알킬티오알킬기이며; Y는 -OR1(식중, R1은 C3~C8시클로알킬기, C4~C8시클로알킬알킬기, C3~C6알케닐기, C2~C6알키닐기, C1~C6할로알킬기, C3~C8할로시클로알킬알킬기, C3~C6할로알케닐기, C2~C6할로알키닐기, C2~C6니트로알킬기 또는 C1~C3알킬기, 할로겐원자, 니트로기 또는 C1~C3알콕시기에 의해 치환될 수 있는 페닐기이다.) -O-L-O-R1(식중, L은 C1~C3알킬기에 의해 치환될 수 있는 C1~C6알킬렌기이고, R1은 상기와 동일하다.), -O-L-OH(식중, L은 상기와 동일하다.), -O-L-O-L-O-R2(식중, L은 상기와 동일하고, R2는 수소원자, C1~C6알킬기 또는 C1~C3알킬기, 할로겐원자, 니트로기 또는 C1~C3알콕시기에 의해 치환될 수 있는 페닐기이다.), -O-L-R3(식중, L은 상기와 동일하고, R3는 C1~C3알킬기, 할로겐원자, 니트로기 또는 C1~C3알콕시기에 의해 치환될 수 있는 페닐기이다.), -O-M(식중, M은 2개 이하의 황 또는 산소원자를 함유하며, 1 내지 4개의 탄소원자의 결합에 의해 형성된 3 내지 6원소의 지방족고리기이다)., -O-L-M(식중, L 및 M은 상기와 동일하다.), O-L-NR4R5(식중, L은 상기와 동일하고, 동일 또는 상이할 수 있는 R4및 R5의 각각은 수소원자 또는 C1~C6알킬기이거나, 또는 R4및 R5는 인접한 질소원자와 함께 고리를 형성한다.), -O-L-COOR4(식중, L 및 R4는 상기와 동일하다.), -O-CH=CH-COOR4(식중 R4는 상기와 동일하다.), -O-L-CN(식중, L은 상기와 동일하다.), -O-L-C(O)-R2(식중, L 및 R2는 상기와 동일하다.), -O-L-S(O)n-R4(식중, L 및 R4는 상기와 동일하고, n은 0 내지 2의 정수이다.), -O-COOR4(식중, R4는 상기와 동일하다.), O-CONR4R6(식중, R4및 R5는 상기와 동일하다.), -OP(O)(OR4)2(식중, R4는 상기와 동일하다.), -S(O)nR1(식중, R1및 n은 상기와 동일하다.), 또는 -S(O)n-L-O-R1(식중, L,R1및 n은 상기와 동일하다.)이며 ; Z는 할로겐원자, 니트로기, C1~C3알콕시기, 트리플루오로메틸기, 트리플루오로메톡시기, 시아노기 또는 -S(O)nR6(식중, n은 상기와 동일하고, R6는 C1~C3알킬기 또는 C1~C3할로알칼기이다.)이며 ; V는 수소원자, 할로겐원자, C1~C4알킬기 또는 C1~C4알콕시기이며 ; W는 수소원자, 할로겐원자, C1~C4알킬기, C1~C4할로알킬기, C1~C4알콕시기, C2~C6알콕시알킬기, C2~C5알콕시카르보닐기, C1~C3할로알콕시기, 니트로기, 시아노기 또는 -S(O)nR6(식중, n및 R6은 상기와 동일하다.)이고 ; Q는 수소원자, 할로겐원자에 의해 치환될 수 있는 C1~C6알킬기, 할로겐원자에 의해 치환될 수 있는 C1~C6알케닐기, 할로겐원자에 의해 치환될 수 있는 C1~C6알키닐기, 시아노메틸기, C(O)-R7(식중, R6은 C1~C6알킬기, C1~C6알케닐기, C1~C6알키닐기, C1~C6할로알킬기, C1~C6할로알케닐기, C1~C6할로알키닐기, 할로겐원자, 니트로기 및 트리플루오로메틸기를 포함하는 군으로부터 선택한 동일 또는 상이한 치환체에 의해 치환될 수 있는 페닐기, C1~C6알킬기, C1~C6알콕시기 또는 히드록실기이다.), -S(O)2R7(식중, R7은 상기와 동일하다.), -P(O)(OR7)2(식중, R7은 상기와 동일하다.), -L-C(O)-R7(식중, L 및 R7는 상기와 동일하다.), -L-C(O)-N(R8)(R9)(식중, L은 상기와 동일하고, 동일 또는 상이할 수 있는 R8및 R9의 각각은 수소원자 또는 C1~C6알킬기이다.), -L-R10(식중, L은 상기와 동일하고, R10은 할로겐원자, 니트로기 및 트리플루오로메틸기를 포함하는 군으로부터 선택한 동일 또는 상이한 치환체에 의해 치환될 수 있는 페닐기, C1~C6알킬기, C1~C6알콕시기 또는 히드록실기이다.), -L-N(R8)(R9)(식중, L,R8및 R9는 상기와 동일하다.), -L-OR11(식중, L은 상기와 동일하고, R11은 수소원자, C1~C6알킬기 또는 C1~C6알케닐기이다.), -L-OC(O)R11(식중, L은 상기와 동일하고, R12는 C1~C6알킬기 또는 C1~C6알콕시기이다.), -L-S(O)nR11(식중, L,n 및 R11은 상기와 동일하다.), -L-SC(O)R8(식중, L 및 R8은 상기와 동일하다.),(식중, 동일 또는 상이할 수 있는 L1 및 L2의 각각은 메틸렌기, 산소원자 또는 황원자이며, R12는 수소원자 또는 C1~C3알킬기이고, m은 2 또는 3이다.)이다.]
  2. 제1항에 있어서, A,B,X,Y,Z 및 O가 A : Me,Et,n-Pr,i-Pr, CH2CH=CH2,CH2C CH,t-Bu
    B : H,Me,Et,n-Pr,i-Pr,Cl,Br,CH2Cl,CF3,OMe,OEt,OPr-i,SMe,CH2OMe,CH2SMe, CO2Me,CO2Et
    X : Me,Et,n-Pr,i-Pr,n-Bu,i-Bu,s-Bu,t-Bu,OMe,OEt,OPr-n,OPr-i,OBu-n, OBu-i,OBu-s,OBu-t,F,Cl,Br,I,NO2,CN,CH2F,CHF2,CF3,CH2CF3, CH2Cl,CCl3, CHCIMe, CH2CH2Cl,CHClCH2Cl,CH2Br,CHBrMe,CH2CH2Br,CH2OMe,CH2OEt,CH2OPr-n,CH2OPr-i, CH2OBu-i,CH2u-s,CH2OBu-t,CHMeOMe,CHMeOEt,OHMeOPr-n,CHMeOPr-i,CHMeOBu-n,CHMeOBu-i, CHMeOBu-s,CHMeOBu-t,CH2CH2OMe,CH2CH2OEt,CH2CH2OPr-i,Ac,COEt,COPr-n,COPr-i, COOMe,COOEt,COOPr-i,CONHMe,CONHEt,CONMe2,CONET2,CONEtMe,OCHF2,OCF3,OCH2CF3, SMe, SEt,CH2SMe,CH2SEt,CHMeSMe,CHMeSEt
    OCHMeCH=CH2,OCMe2CH=CH2,OCH2CMe=CH2,OCH2CH=CHMe,OCH2CH=CMe2,OCH2C CH,OCHMeC CH, OCMe2C CH,OCH2C CMe,OCH2CH2F,OCH2CHF2,OCH2CF3,OCH2CH2Cl,OCHM eCH2Cl,OCH2CCl3, OCH2CH2CH2Cl, OCH2CH2BrOCH2CCl=C2,OCH2CH2CH=CH2,OCH2CCl=CHCl,OCH2CH2NO2, OPh,OPh-Me-2OPh-Cl-4, OPh-NO2-4,OCH2CH2OMe,OCH2CH2OEt,OCH2CH2OPr-N,OCH2CH2OPr-i,OCH2CH2OBu-n,OCH2CH2OBu-i,OCH2CH2Bu-s,OCH2CH2OBu-t,OCHMeCH2OMe,OHC2CH2OPh, OCH2CH2OCH2CH2OMe,OCH2CH2OH,OCH2CH2OCHMe CH2OMe,OCH2Ph,OCHMePh,OCH2Ph-4-ME,OCH2Ph-4-Cl,OCH2CH2Ph,
    OCH2CH2NH2,OCH2CH2NHMe,OCH2CH2NMe2,OCH2CH2NEt2,,OCH2,COOMe,OCH2COOEt,OCH2COOPrn,OCH2COOPri,OCH2COOBut,OCHMeCOOMe,OCHMeCOOEtOCHMeCOOPrn,OCHMeCOOPr-i,OCHMeCOOBut,OCH2CH2CN,OCH2CN,OCHMeCN,OCH2SMe,OCH2C(O)Ph,OCH2C(O)Me,OCH2CH2SMe,OCH2CH2SOMe,OCH2CH2SO2Me,OCH2CH2SEt,OCH2SO2Et,OCOOMe,OCOOEt,OCOOPri,OCONH2,OCONHMe,OCONMe2,OP(O)(OMe)2,OP(O)(OEt)2,SCH2CH=CH2,SCH2C CH,SCH2CF3, SCH2CH2Cl,SCH2CCl,SPh, SCH2CH2OMe, SCH2CH2OEt, SCH2CH2OPr-i, SCH2CH2OPh,S(O)CH2CH=CH2,S(O)CH2CHCH,S(O)CH2CF3,S(O)CH2CH2Cl,S(O)Ph, S(O)CH2CH2OMe,S(O)CH2CH2OEt,S(O)CH2CH2OPr-i, S(O)CH2CH2OPh,SO2CH2CH=CH2SO2CH2CCH, SO2CH2CF3,SO2CH2CHSO2CH2CH2OMe, SO2CH2CH2OEt, SO2CH2CH2OPr-i, Z: F,Cl,Br,I ,NO2,OMe,OEt, OPr-n,OPr-i,CH3,CN,SMe,SOMe,SO2Me,SCF3,SOCF3,SO2CF3 Q: H, Me,Et, N-Pr,i-Pr, n-Bu,i-Bu,s-Bu,t-Bu,CH2CH2Cl, CH2CF3, CHClMe, CH2CH2Br, CHClCH2Cl, CH2CH=CH2, CH2CMe=CH2,CH2CH=CHMe,CH2C CH,CH2CCl=CH2,CH2CN,CH2Ph,CH2Ph-Cl-2, CH2Ph-Cl-3, CH2Ph-Me-2,CH2Ph-Me2-2,4,CH2Ph-Me-4,CHMePh, CHEtPh, CH2Ph-NO2-2,CH2Ph-CF3-3,CH2OMe, CH2OEt, CH2OH,CHMeOH, CH2NHMe,CH2NMe2, CHMeNMe2,CH2COPh, CH2COPh-NO2-4,CH2COPh-Me-4,CH2COPh-Cl-4,CH2COPh-ME2-2,4, CH2COPh-CF3-4,CH2Ac,CH2COEt,CHMeAc,CH2CO2Me,CH2CO2Et,CH2CO2Pr-n,CH2CO2Pr-i, CH2CO2Bu-t,CH2CO2H,CHMeCO2H,CH2CONHMe,CH2CONMe2,CH2CONHEt,CH2CONEt2,CH2CONPr-n2, CH2OCH2CH=CH2,CH2,CH2OAc,CH2COEt,CH2COPr-i,CH2COBu-t,CH2OCO2Me,CH2OCO2Et,CH2OCO2Pr-i, CH2OCO2Bu-t,CH2SMe,CH2SEt,CH2SCH2CH=CH2,CH2SAc,CH2SCOBu-t,CH2SO2Me, CH2SO2Et, CH2SO2CH2CH=CH2,CH2NHCH2CH=CH2,CH2NMeCH2CH=CH2,CH2NHAc,CH2NHCOEt,CH2NHCO2Me, CH2NHCO2Et, CH2NHCO2Me,CH2NHCO2Et, CH2NMeCO2Me,COPh,COPh-Me-4,COPh-NO2-2,COPh-Cl2-2, 4, Ac, COEt,COPr-n,COPr-i,COBu-n,COBu-t,COCH2Cl,COCHCL2,COCCl3,COCF3, COCH2OMe, COCH2OPh,COCH2CH=CHCH3,CO2Me,CO2Et,CO2Bu-t,CO2Pr-i,CONHMe,CONMe2,CONHEt, CONEt2, CONPr-n2,CON(CH2CH=CH2)2,CONMePh,
    CO2CH2Ph,CO2Ph,SO2Me,SO2Et,SO2CH2CH=CH2,SO2Ph,SO2Ph-Me-4,SO2Ph-Cl-4,SO2Ph-(NO2)2-2,4,SO2CF3,P(=0)(OMe)2,P(O)(OEt)2,P(=O)(OPr-n)2,P(=O)(OPr-i)2,P(=S)(OMe)2,P(=S) (OEt)2,P(=O)OMeOPh,P(=O)(OCH2CH=CH2)2,P(=O)OPhOCH2CH=CH2; 임을 특징으로 하는 일반식(I)의 피라졸 유도체 및 그의 염.
  3. 제1항에 기재된 일반식(I)의 피라졸 유도체 또는 그의 염의 제초 유효량 및 농업용 담체 또는 희석제를 함유함을 특징으로 하는 선택성 제초 조성물.
  4. 제1항에 기재된 일반식(I)의 피라졸 유도체 또는 그의 염의 제초 유효량을 방제하려는 구역에 산포함을 특징으로 하는 잡초 방제방법.
  5. 하기일반식(II)의 치환된 벤젠 유도체 및 그의 염
    [식중, G는 카르복실기, 할로카르보닐기 또는 시아노카르보닐기이며 ; X는 C1~C6알킬기, C1~C6알콕시기, 할로겐원자, 니트로기, 시아노기, C1~C6할로알킬기, C2~C6알콕시알킬기, C2~C6알킬카르보닐기, C2~C6알콕시카르보닐기, 수소원자 또는 C1~C6알킬기에 의해 각각 치환된 아미노카르보닐기, C1~C6할로알콕시기, C1~C6알킬티오기 또는 C2~C6알킬티오 알킬기이며 ; Y는 -OR1(식중, R1은 C3~C8시클로알킬기, C4~C8시클로알킬알킬기, C3~C6알케닐기, C2~C6알키닐기, C1~C6할로알킬기, C3~C8할로시클로알킬알킬기, C3~C6할로알케닐기, C2~C6할로알키닐기, C2~C6니트로알킬기 또는 C1~C3알킬기, 할로겐원자, 니토로기 또는 C1~C3알콕시기에 의해 치환될 수 있는 페닐기이다.), -O-L-O-R1(식중, L은 C1~C3알킬기에 의해 치환될 수 있는 C1~C6알킬렌기이고, R1은 상기와 동일하다.), -O-L-OH(식중, L은 상기와 동일하다.), -O-L-O-L-O-R2(식중, L은 상기와 동일하고, R2는 수소원자, C1~C6알킬기 또는 C1~C3알킬기, 할로겐원자, 니트로기 또는 C1~C3알콕시기에 의해 치환될 수 있는 페닐기이다.), -O-L-R3(식중, L은 상기와 동일하고, R3는 C1~C3알킬기, 할로겐원자, 니트로기 또는 C1~C3알콕시기에 의해 치환될 수 있는 페닐기이다.),-O-M(식중, M은 2개이하의 황 또는 산소원자를 함유하며, 1 내지 4개의 탄소원자의 결합에 의해 형성된 3 내지 6원소의 지방족 고리기이다.), -O-L-M(식중, L 및 M은 상기와 동일하다.), O-L-NR4NR5(식중, L은 상기와 동일하고, 동일 또는 상이할 수 있는 R4및 R5의 각각의 수소원자 또는 C1~C6알킬기이거나, 또는 R4및 R5는 인접한 질소원자와 함께 고리를 형성한다.), -O-L-COOR4(식중, L 및 R4는 상기와 동일하다.), -O-CH=CH-COOR4(식중, R4는 상기와 동일하다.), -O-L-CN(식중, L은 상기와 동일하다.), -O-L-C(O)-R2(식중, L 및 R2는 상기와 동일하다.), -O-L-S(O)n-R4(식중, L 및 R4는 상기와 동일하고, n은 0 내지 2의 정수이다.), -O-COOR4(식중, R4는 상기와 동일하다.), O-CONR4R6(식중, R4및 R5는 상기와 동일하다.), -OP(O)(OR4)2(식중, R4는 상기와 동일하다.), -S(O)nR1(식중, R1및 n은 상기와 동일하다.), 또는 -S(O)n-L-O-R1(식중, L,R1및 n은 상기와 동일하다.)이며 ; Z는 할로겐원자, 니트로기, C1~C3알콕시기, 트리플루오로메틸기, 트리플루오로메톡시기, 시아노기 또는 -S(O)nR6(식중, n은 상기와 동일하고, R6는 C1~C3알킬기 또는 C1~C3할로알칼기이다.)이며 ; V는 수소원자, 할로겐원자, C1~C4알킬기 또는 C1~C4알콕시기이며 W는 수소원자, 할로겐원자, C1~C4알킬기, C1~C4할로알킬기, C1~C4알콕시기, C2~C6알콕시알킬기, C2~C5알콕시카르보닐기, C1~C3할로알콕시기, 니트로기, 시아노기 또는 -S(O)nR6(식중, n및 R6은 상기와 동일하다.)이다.]
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019890010068A 1988-07-15 1989-07-14 피라졸 유도체 및 그를 함유하는 제초제 KR0128286B1 (ko)

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* Cited by examiner, † Cited by third party
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KR100643510B1 (ko) * 2005-01-20 2006-11-10 박현문 반도체 장비용 대형 오링의 제조장치 및 그 성형장치에의해 제조된 대형 오링

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ES2064388T3 (es) 1995-02-01
DK349289A (da) 1990-01-16
IL90819A (en) 1994-06-24
HUT51256A (en) 1990-04-28
US4986845A (en) 1991-01-22
BR8903486A (pt) 1990-03-13
HU205912B (en) 1992-07-28
AU618609B2 (en) 1992-01-02
DK349289D0 (da) 1989-07-14
ATE112271T1 (de) 1994-10-15
DE68918524T2 (de) 1995-05-04
CN1039586A (zh) 1990-02-14
RU1792280C (ru) 1993-01-30
EP0352543A1 (en) 1990-01-31
IL90819A0 (en) 1990-01-18
DE68918524D1 (de) 1994-11-03
EP0352543B1 (en) 1994-09-28
CA1338788C (en) 1996-12-10
RU2042667C1 (ru) 1995-08-27
AU3800589A (en) 1990-01-25
USRE34779E (en) 1994-11-08
DK170439B1 (da) 1995-09-04
KR0128286B1 (ko) 1998-04-02
CN1017240B (zh) 1992-07-01

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