JPS6112801A - Production of powder for dispersion-strengthened alloy - Google Patents
Production of powder for dispersion-strengthened alloyInfo
- Publication number
- JPS6112801A JPS6112801A JP59133852A JP13385284A JPS6112801A JP S6112801 A JPS6112801 A JP S6112801A JP 59133852 A JP59133852 A JP 59133852A JP 13385284 A JP13385284 A JP 13385284A JP S6112801 A JPS6112801 A JP S6112801A
- Authority
- JP
- Japan
- Prior art keywords
- powder
- metal
- alloy
- dispersion
- producing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000000843 powder Substances 0.000 title claims abstract description 112
- 239000000956 alloy Substances 0.000 title claims abstract description 47
- 229910045601 alloy Inorganic materials 0.000 title claims abstract description 47
- 238000004519 manufacturing process Methods 0.000 title claims description 24
- 239000011248 coating agent Substances 0.000 claims abstract description 26
- 238000000576 coating method Methods 0.000 claims abstract description 26
- 239000011247 coating layer Substances 0.000 claims abstract description 20
- 238000010298 pulverizing process Methods 0.000 claims abstract description 20
- 230000003301 hydrolyzing effect Effects 0.000 claims abstract description 15
- 238000000034 method Methods 0.000 claims abstract description 15
- 238000009703 powder rolling Methods 0.000 claims abstract description 8
- 229910052751 metal Inorganic materials 0.000 claims description 76
- 239000002184 metal Substances 0.000 claims description 76
- 150000002736 metal compounds Chemical class 0.000 claims description 42
- 229910000000 metal hydroxide Inorganic materials 0.000 claims description 31
- 150000004692 metal hydroxides Chemical class 0.000 claims description 31
- 238000010438 heat treatment Methods 0.000 claims description 20
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 14
- 229910044991 metal oxide Inorganic materials 0.000 claims description 14
- 150000004706 metal oxides Chemical class 0.000 claims description 14
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 12
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 12
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 12
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 claims description 11
- 229910052782 aluminium Inorganic materials 0.000 claims description 9
- 229910052802 copper Inorganic materials 0.000 claims description 9
- 239000010949 copper Substances 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 8
- 229910052709 silver Inorganic materials 0.000 claims description 8
- 239000010936 titanium Substances 0.000 claims description 8
- 229910052719 titanium Inorganic materials 0.000 claims description 8
- 229910052804 chromium Inorganic materials 0.000 claims description 7
- 239000011651 chromium Substances 0.000 claims description 7
- 229910052742 iron Inorganic materials 0.000 claims description 7
- 229910052750 molybdenum Inorganic materials 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- 229910052726 zirconium Inorganic materials 0.000 claims description 7
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 claims description 6
- 229910000881 Cu alloy Inorganic materials 0.000 claims description 6
- 229910000990 Ni alloy Inorganic materials 0.000 claims description 6
- 229910052759 nickel Inorganic materials 0.000 claims description 6
- 239000004332 silver Substances 0.000 claims description 6
- 229910052721 tungsten Inorganic materials 0.000 claims description 6
- 229910000838 Al alloy Inorganic materials 0.000 claims description 5
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 claims description 5
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 claims description 5
- 229910001069 Ti alloy Inorganic materials 0.000 claims description 5
- 239000010419 fine particle Substances 0.000 claims description 5
- 229910052749 magnesium Inorganic materials 0.000 claims description 5
- 239000011777 magnesium Substances 0.000 claims description 5
- 239000011733 molybdenum Substances 0.000 claims description 5
- 229910001316 Ag alloy Inorganic materials 0.000 claims description 4
- 229910000599 Cr alloy Inorganic materials 0.000 claims description 4
- 229910000640 Fe alloy Inorganic materials 0.000 claims description 4
- 229910000861 Mg alloy Inorganic materials 0.000 claims description 4
- 229910052758 niobium Inorganic materials 0.000 claims description 4
- 239000010955 niobium Substances 0.000 claims description 4
- 229910052761 rare earth metal Inorganic materials 0.000 claims description 4
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 claims description 4
- 239000010937 tungsten Substances 0.000 claims description 4
- 229910052720 vanadium Inorganic materials 0.000 claims description 4
- 229910001182 Mo alloy Inorganic materials 0.000 claims description 3
- 229910001080 W alloy Inorganic materials 0.000 claims description 3
- 229910052796 boron Inorganic materials 0.000 claims description 3
- 239000000788 chromium alloy Substances 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000006185 dispersion Substances 0.000 claims description 2
- 229910052710 silicon Inorganic materials 0.000 claims 2
- 239000002245 particle Substances 0.000 abstract description 29
- 230000007062 hydrolysis Effects 0.000 abstract description 10
- 238000006460 hydrolysis reaction Methods 0.000 abstract description 10
- 238000005979 thermal decomposition reaction Methods 0.000 abstract description 7
- 239000010953 base metal Substances 0.000 abstract description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 abstract 3
- 238000000354 decomposition reaction Methods 0.000 abstract 1
- 230000007774 longterm Effects 0.000 abstract 1
- XKRFYHLGVUSROY-UHFFFAOYSA-N Argon Chemical compound [Ar] XKRFYHLGVUSROY-UHFFFAOYSA-N 0.000 description 40
- 229910052786 argon Inorganic materials 0.000 description 20
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 15
- 239000001257 hydrogen Substances 0.000 description 10
- 229910052739 hydrogen Inorganic materials 0.000 description 10
- 239000000463 material Substances 0.000 description 10
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 9
- 238000000465 moulding Methods 0.000 description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 7
- 229910052799 carbon Inorganic materials 0.000 description 7
- 239000000243 solution Substances 0.000 description 7
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 238000009864 tensile test Methods 0.000 description 6
- 239000012298 atmosphere Substances 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 5
- -1 metal complex compounds Chemical class 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 239000003779 heat-resistant material Substances 0.000 description 4
- 150000004677 hydrates Chemical class 0.000 description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 3
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 3
- 239000013522 chelant Substances 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 3
- WWZKQHOCKIZLMA-UHFFFAOYSA-N octanoic acid Chemical compound CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 3
- 150000002902 organometallic compounds Chemical class 0.000 description 3
- OGHBATFHNDZKSO-UHFFFAOYSA-N propan-2-olate Chemical compound CC(C)[O-] OGHBATFHNDZKSO-UHFFFAOYSA-N 0.000 description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 3
- 229910052727 yttrium Inorganic materials 0.000 description 3
- POILWHVDKZOXJZ-ARJAWSKDSA-M (z)-4-oxopent-2-en-2-olate Chemical class C\C([O-])=C\C(C)=O POILWHVDKZOXJZ-ARJAWSKDSA-M 0.000 description 2
- IVORCBKUUYGUOL-UHFFFAOYSA-N 1-ethynyl-2,4-dimethoxybenzene Chemical compound COC1=CC=C(C#C)C(OC)=C1 IVORCBKUUYGUOL-UHFFFAOYSA-N 0.000 description 2
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 description 2
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 2
- QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 2
- 150000004703 alkoxides Chemical class 0.000 description 2
- 238000005275 alloying Methods 0.000 description 2
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 2
- VYLVYHXQOHJDJL-UHFFFAOYSA-K cerium trichloride Chemical compound Cl[Ce](Cl)Cl VYLVYHXQOHJDJL-UHFFFAOYSA-K 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 235000019441 ethanol Nutrition 0.000 description 2
- 229910001510 metal chloride Inorganic materials 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000003960 organic solvent Substances 0.000 description 2
- 238000005096 rolling process Methods 0.000 description 2
- 238000005245 sintering Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XFNJVJPLKCPIBV-UHFFFAOYSA-N trimethylenediamine Chemical compound NCCCN XFNJVJPLKCPIBV-UHFFFAOYSA-N 0.000 description 2
- 239000011882 ultra-fine particle Substances 0.000 description 2
- VWQVUPCCIRVNHF-UHFFFAOYSA-N yttrium atom Chemical compound [Y] VWQVUPCCIRVNHF-UHFFFAOYSA-N 0.000 description 2
- DUNKXUFBGCUVQW-UHFFFAOYSA-J zirconium tetrachloride Chemical compound Cl[Zr](Cl)(Cl)Cl DUNKXUFBGCUVQW-UHFFFAOYSA-J 0.000 description 2
- YOBOXHGSEJBUPB-MTOQALJVSA-N (z)-4-hydroxypent-3-en-2-one;zirconium Chemical compound [Zr].C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O.C\C(O)=C\C(C)=O YOBOXHGSEJBUPB-MTOQALJVSA-N 0.000 description 1
- HNNQYHFROJDYHQ-UHFFFAOYSA-N 3-(4-ethylcyclohexyl)propanoic acid 3-(3-ethylcyclopentyl)propanoic acid Chemical compound CCC1CCC(CCC(O)=O)C1.CCC1CCC(CCC(O)=O)CC1 HNNQYHFROJDYHQ-UHFFFAOYSA-N 0.000 description 1
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonium chloride Substances [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 description 1
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 1
- FIPWRIJSWJWJAI-UHFFFAOYSA-N Butyl carbitol 6-propylpiperonyl ether Chemical compound C1=C(CCC)C(COCCOCCOCCCC)=CC2=C1OCO2 FIPWRIJSWJWJAI-UHFFFAOYSA-N 0.000 description 1
- 239000005635 Caprylic acid (CAS 124-07-2) Substances 0.000 description 1
- 235000021538 Chard Nutrition 0.000 description 1
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 1
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical class OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 1
- WRQNANDWMGAFTP-UHFFFAOYSA-N Methylacetoacetic acid Chemical compound COC(=O)CC(C)=O WRQNANDWMGAFTP-UHFFFAOYSA-N 0.000 description 1
- 235000009827 Prunus armeniaca Nutrition 0.000 description 1
- 244000018633 Prunus armeniaca Species 0.000 description 1
- 229910021550 Vanadium Chloride Inorganic materials 0.000 description 1
- 238000002441 X-ray diffraction Methods 0.000 description 1
- 229910008253 Zr2O3 Inorganic materials 0.000 description 1
- 150000004720 acetoacetic acids Chemical class 0.000 description 1
- 230000002378 acidificating effect Effects 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- SMZOGRDCAXLAAR-UHFFFAOYSA-N aluminium isopropoxide Chemical compound [Al+3].CC(C)[O-].CC(C)[O-].CC(C)[O-] SMZOGRDCAXLAAR-UHFFFAOYSA-N 0.000 description 1
- 235000011114 ammonium hydroxide Nutrition 0.000 description 1
- 238000000137 annealing Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- PYPNFSVOZBISQN-LNTINUHCSA-K cerium acetylacetonate Chemical compound [Ce+3].C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O.C\C([O-])=C\C(C)=O PYPNFSVOZBISQN-LNTINUHCSA-K 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 150000001805 chlorine compounds Chemical class 0.000 description 1
- UPHIPHFJVNKLMR-UHFFFAOYSA-N chromium iron Chemical compound [Cr].[Fe] UPHIPHFJVNKLMR-UHFFFAOYSA-N 0.000 description 1
- 229910017052 cobalt Inorganic materials 0.000 description 1
- 239000010941 cobalt Substances 0.000 description 1
- GUTLYIVDDKVIGB-UHFFFAOYSA-N cobalt atom Chemical compound [Co] GUTLYIVDDKVIGB-UHFFFAOYSA-N 0.000 description 1
- 238000010273 cold forging Methods 0.000 description 1
- 239000004020 conductor Substances 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 238000001035 drying Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- HHFAWKCIHAUFRX-UHFFFAOYSA-N ethoxide Chemical compound CC[O-] HHFAWKCIHAUFRX-UHFFFAOYSA-N 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 239000010408 film Substances 0.000 description 1
- 238000010304 firing Methods 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 150000002334 glycols Chemical class 0.000 description 1
- 238000005098 hot rolling Methods 0.000 description 1
- 150000002431 hydrogen Chemical class 0.000 description 1
- 230000002706 hydrostatic effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 239000002075 main ingredient Substances 0.000 description 1
- 238000005551 mechanical alloying Methods 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
- 230000008018 melting Effects 0.000 description 1
- 150000001247 metal acetylides Chemical class 0.000 description 1
- NBTOZLQBSIZIKS-UHFFFAOYSA-N methoxide Chemical compound [O-]C NBTOZLQBSIZIKS-UHFFFAOYSA-N 0.000 description 1
- GUCVJGMIXFAOAE-UHFFFAOYSA-N niobium atom Chemical compound [Nb] GUCVJGMIXFAOAE-UHFFFAOYSA-N 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- 239000012299 nitrogen atmosphere Substances 0.000 description 1
- 229960002446 octanoic acid Drugs 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- YHBDIEWMOMLKOO-UHFFFAOYSA-I pentachloroniobium Chemical compound Cl[Nb](Cl)(Cl)(Cl)Cl YHBDIEWMOMLKOO-UHFFFAOYSA-I 0.000 description 1
- RPESBQCJGHJMTK-UHFFFAOYSA-I pentachlorovanadium Chemical compound [Cl-].[Cl-].[Cl-].[Cl-].[Cl-].[V+5] RPESBQCJGHJMTK-UHFFFAOYSA-I 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-M phenolate Chemical compound [O-]C1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-M 0.000 description 1
- 229960005235 piperonyl butoxide Drugs 0.000 description 1
- 238000007780 powder milling Methods 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- IKNCGYCHMGNBCP-UHFFFAOYSA-N propan-1-olate Chemical compound CCC[O-] IKNCGYCHMGNBCP-UHFFFAOYSA-N 0.000 description 1
- XPGAWFIWCWKDDL-UHFFFAOYSA-N propan-1-olate;zirconium(4+) Chemical compound [Zr+4].CCC[O-].CCC[O-].CCC[O-].CCC[O-] XPGAWFIWCWKDDL-UHFFFAOYSA-N 0.000 description 1
- AOHJOMMDDJHIJH-UHFFFAOYSA-N propylenediamine Chemical compound CC(N)CN AOHJOMMDDJHIJH-UHFFFAOYSA-N 0.000 description 1
- FDNAPBUWERUEDA-UHFFFAOYSA-N silicon tetrachloride Chemical compound Cl[Si](Cl)(Cl)Cl FDNAPBUWERUEDA-UHFFFAOYSA-N 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000005728 strengthening Methods 0.000 description 1
- 229910052715 tantalum Inorganic materials 0.000 description 1
- GUVRBAGPIYLISA-UHFFFAOYSA-N tantalum atom Chemical compound [Ta] GUVRBAGPIYLISA-UHFFFAOYSA-N 0.000 description 1
- 239000010409 thin film Substances 0.000 description 1
- GPPXJZIENCGNKB-UHFFFAOYSA-N vanadium Chemical compound [V]#[V] GPPXJZIENCGNKB-UHFFFAOYSA-N 0.000 description 1
- 150000003746 yttrium Chemical class 0.000 description 1
- GONBZNBMLOZYAM-UHFFFAOYSA-K yttrium(3+);triformate Chemical compound [Y+3].[O-]C=O.[O-]C=O.[O-]C=O GONBZNBMLOZYAM-UHFFFAOYSA-K 0.000 description 1
- 150000003754 zirconium Chemical class 0.000 description 1
- 229910021512 zirconium (IV) hydroxide Inorganic materials 0.000 description 1
Landscapes
- Powder Metallurgy (AREA)
- Chemically Coating (AREA)
Abstract
Description
【発明の詳細な説明】
〔産業上の利用分野〕
本発明は、分散強化型合金用粉末の製造方法に関するも
のであり、より詳しくは引張強度、延性２硬度、靭性、
耐熱性、電気的特性及び耐中性子照射性に優れた分散強
化型合金を得る為の粉末の製造方法に関するものである
。[Detailed Description of the Invention] [Industrial Application Field] The present invention relates to a method for producing powder for dispersion-strengthened alloys, and more specifically, it relates to a method for producing powder for dispersion-strengthened alloys, and more specifically, tensile strength, ductility, hardness, toughness,
The present invention relates to a method for producing powder for obtaining a dispersion-strengthened alloy with excellent heat resistance, electrical properties, and neutron irradiation resistance.
従来、分散強化型合金用粉末を製造する方法としては、
基地金属となる金属粉末と酸化物、炭化物、窒化物又は
炭窒化物等からなる硬質粒子とを混合し、これをメカニ
カルアロイング法により粉砕合金化して合金粉末を得る
という方法が行われ、既に一部で実用化されている。Conventionally, the method for producing powder for dispersion-strengthened alloys is as follows:
A method has already been used in which metal powder serving as a base metal is mixed with hard particles made of oxides, carbides, nitrides, carbonitrides, etc., and the mixture is pulverized and alloyed using a mechanical alloying method to obtain an alloy powder. It has been put into practical use in some areas.
前記従来法においては、基地金属に硬質粒子を均一に分
散させるには長時間の粉砕を必要とするという問題があ
る。また、この方法による場合、硬質粒子そのものは粉
砕工程で粉砕されることが少ないので、最初から微細な
硬質粒子を使用する必要があるが、このような微細な硬
質粒子は大量生産が困難なため非常に高価なものになる
という問題もある。The above-mentioned conventional method has a problem in that a long period of pulverization is required to uniformly disperse the hard particles in the base metal. In addition, when using this method, the hard particles themselves are rarely crushed during the crushing process, so it is necessary to use fine hard particles from the beginning, but such fine hard particles are difficult to mass produce. Another problem is that it is very expensive.
本発明は、前記従来法の欠点を除去、改善した新たな分
散強化型合金用粉末の製造方法を提供せんとするもので
ある。The present invention aims to provide a new method for producing powder for dispersion-strengthened alloys, which eliminates and improves the drawbacks of the conventional methods.
本願の第１番目の発明は、一種以上の無機金属化合物若
しくは有機金属化合物を加水分解若しくは熱分解するこ
とによって得られる金属水酸化物若しくは金属水和物か
らなる被覆層を金属粉末表面に形成することを特徴とす
る分散強化型合金用粉末の製造方法である。本願の第２
番目の発明は、一種以上の無機金属化合物若しくは有機
金属化合物を加水分解若しくは熱分解することによって
得られる金属水酸化物若しくは金属水和物からなる被覆
層を表面に有する金属粉末を、機械粉砕混合法若しくは
粉末圧延粉砕混合法の一以上の方法により粉砕処理する
ことを特徴とする分散強化型合金用粉末の製造方法であ
る。The first invention of the present application forms a coating layer on the surface of a metal powder, which is made of a metal hydroxide or metal hydrate obtained by hydrolyzing or thermally decomposing one or more types of inorganic metal compounds or organic metal compounds. This is a method for producing powder for dispersion-strengthened alloys. Second part of the application
The second invention is to mechanically pulverize and mix metal powder having a coating layer on the surface of a metal hydroxide or metal hydrate obtained by hydrolyzing or thermally decomposing one or more inorganic metal compounds or organic metal compounds. This is a method for producing powder for a dispersion-strengthened alloy, characterized in that the powder is pulverized by one or more of the following methods: powder milling, powder rolling, pulverizing, and mixing.
本発明において使用する無機金属化合物若しくは有機金
属化合物に含まれる金属は、Ａｌ、Ｔｉ、Ｃｕ。The metals contained in the inorganic metal compound or organic metal compound used in the present invention are Al, Ti, and Cu.
Ｆ ｅ ＋ Ｍ Ｏ＋ Ｉ’ｌ ＋飄ｕ ＋へｇ＋Ｓｉ
’、Ｎｂ、Ｖ、Ｚｒ、Ｔａ、Ｙ＋Ｃｒ、Ｂ及び希土類元
素の中から選ばれる一種以上である。F e + M O+ I'l + 飄u + え g + Si
', Nb, V, Zr, Ta, Y+Cr, B, and rare earth elements.
これらの金属を含む無機金属化合物若しくは有機金属化
合物は、加水分解若しくは熱分解によって金属水酸化物
若しくは金属水和物とされる。この加水分解若しくは熱
分解前の無機金属化合物若しくは有機金属化合物として
は、金属塩化物例えば塩化アルミニウム、塩化ジルコニ
ウム、塩化バナジウム、塩化ニオブ、塩化ケイ素、塩化
イ・ノトリウムや塩化セリウムなどのＲ，Ｅ （希土類
元素）塩素化合物、金属の錯化合物例えばアセチルアセ
トナトキレート トリメチレンジアミンキレート。Inorganic metal compounds or organometallic compounds containing these metals are converted into metal hydroxides or metal hydrates by hydrolysis or thermal decomposition. The inorganic or organic metal compound before hydrolysis or thermal decomposition includes metal chlorides such as aluminum chloride, zirconium chloride, vanadium chloride, niobium chloride, silicon chloride, inotrium chloride, cerium chloride, etc. rare earth elements) chlorine compounds, metal complex compounds such as acetylacetonatochelate, trimethylenediamine chelate.
プロピレンジアミンキレート等のキレート化合物、アル
コキシド例えばメトキシド、エトキシド、プロポキシド
、ブトキシド、フェノキシト等、金属塩例えばナフテン
酸金属塩、オクチル酸金属塩。Chelate compounds such as propylene diamine chelate, alkoxides such as methoxide, ethoxide, propoxide, butoxide, phenoxide, etc., metal salts such as naphthenic acid metal salts, octylic acid metal salts.
カプリル酸金属塩、カルボン酸金属塩、又は有機金属脂
肪酸等である。These include caprylic acid metal salts, carboxylic acid metal salts, organometallic fatty acids, and the like.
前記金属粉末の表面に形成される金属水酸化物若しくは
金属水和物からなる被覆層は、無機金属化合物若しくは
有機金属化合物を金属粉末表面に被覆した後加水分解若
しくは熱分解することによって得てもよく、或いは無機
金属化合物若しくは有機金属化合物を加水分解若しくは
熱分解した後金属粉末表面に被覆することによって得て
もよい。The coating layer made of a metal hydroxide or metal hydrate formed on the surface of the metal powder may be obtained by coating the surface of the metal powder with an inorganic metal compound or an organic metal compound and then hydrolyzing or thermally decomposing it. Alternatively, it may be obtained by hydrolyzing or thermally decomposing an inorganic metal compound or an organic metal compound and then coating the surface of a metal powder.
前記被覆層を形成するに際し、加水分解若しくは熱分解
前の化合物が有機金属化合物であり、常温で液状の場合
はそのまま適用し、固体状若しくは粉末状の場合は加熱
溶融して適用する。また、何れの場合も溶媒に溶解させ
るか或いは更にその溶媒に被覆助剤を添加しておいても
よい。溶媒としては、例えばアルコール頻、ベンゼン、
アセトン、エーテルなどの有機溶媒を使用する。また、
被覆助剤としては、アセト酢酸類、グリコール類。When forming the coating layer, the compound before hydrolysis or thermal decomposition is an organometallic compound, and if it is liquid at room temperature, it is applied as is, and if it is solid or powder, it is applied after being heated and melted. Further, in either case, it may be dissolved in a solvent or a coating aid may be added to the solvent. Examples of solvents include alcohol, benzene,
Use organic solvents such as acetone and ether. Also,
Coating aids include acetoacetic acids and glycols.
エチレングリコール類などが好ましい。加水分解前の化
合物が無機金属化合物である場合には、ゲル又はゾル状
にした後、水又は溶媒に溶かして金属粉末表面に被覆す
る。有機金属化合物や無機金属化合物の中には、室温等
の低い温度で急速に加水分解により金属水酸化物若しく
は金属水和物に変化するものもある。このような物質は
、化合物の粒子が大きく成長し、分散強化粒子も粗大化
するので、理想的な強度は得られない。そのため、被覆
助剤等を添加することにより、反応速度を遅くして金属
粉末表面に対する密着性をよくし、徐。Ethylene glycols and the like are preferred. When the compound before hydrolysis is an inorganic metal compound, it is formed into a gel or sol, then dissolved in water or a solvent and coated on the surface of the metal powder. Some organic metal compounds and inorganic metal compounds rapidly change into metal hydroxides or metal hydrates by hydrolysis at low temperatures such as room temperature. In such a substance, the compound particles grow large and the dispersion-strengthening particles also become coarse, so that ideal strength cannot be obtained. Therefore, by adding coating aids, etc., the reaction rate is slowed down and the adhesion to the metal powder surface is improved.
々に反応を進行させる必要がある。また、例えば一部の
アセチルアセトナート化合物のように反応の進行が遅い
場合には遊離炭素が残るが、特に遊離炭素の残留により
焼結性を悪くするときには、湿水素雰囲気等での熱分解
により金属水酸化物若しくは金属水和物に変化させる必
要がある。その際、加熱速度が速いか又は加熱温度が高
い場合には、粗大化した酸化物粒子となるため、比較的
低い温度で徐々に加熱を行う必要がある。熱分解の温度
は、１００℃から７００℃程度が好ましい。アルコキシ
ド等の場合には、加熱等により無機金属水酸化物に変化
しても遊離炭素は残らないが、有機金属化合物等を杏金
粉末表面に被覆した場合で遊離炭素を除去する必要があ
る場合には、水分を含む空気中または水分を含むアルゴ
ン、窒素、酸素。It is necessary to allow the reaction to proceed. In addition, if the reaction progresses slowly, as in the case of some acetylacetonate compounds, free carbon remains, but if the residual free carbon worsens sinterability, thermal decomposition in a wet hydrogen atmosphere, etc. It is necessary to convert it into metal hydroxide or metal hydrate. At this time, if the heating rate is fast or the heating temperature is high, the oxide particles will become coarse, so it is necessary to gradually heat the particles at a relatively low temperature. The thermal decomposition temperature is preferably about 100°C to 700°C. In the case of alkoxides, etc., no free carbon remains even if they are converted into inorganic metal hydroxides by heating, etc. However, if the surface of the apricot powder is coated with an organic metal compound, etc., it is necessary to remove the free carbon. This includes air containing moisture or argon, nitrogen, and oxygen containing moisture.
水素中で加水分解処理をして金属水酸化物若しくは金属
水和物とした後加熱処理を行うものとする。After hydrolysis treatment in hydrogen to form a metal hydroxide or metal hydrate, heat treatment is performed.
この熱処理温度は約１００℃から融点近くまでの温度で
行うのが好ましい。特に銅、ニッケル、銀等の金属粉末
を加熱焼結する場合、遊離炭素が含まれていると焼結性
を悪くする為、遊離炭素を充分に除去して金属水酸化物
若しくは金属水和物にして表面被覆を行うものとする。The heat treatment temperature is preferably from about 100° C. to close to the melting point. In particular, when heating and sintering metal powders such as copper, nickel, and silver, if free carbon is included, the sinterability will deteriorate, so remove the free carbon sufficiently to form metal hydroxides or metal hydrates. Surface coating shall be carried out.
或いは、表面被覆後、加圧成形の前に金属水酸化物若し
くは金属水和物とする。Alternatively, after surface coating, the metal hydroxide or metal hydrate is formed before pressure molding.
本発明に使用する金属粉末としては、銅、銅合金、ニッ
ケル、ニッケル合金、銀、銀合金、クロム、クロム合金
、鉄、鉄合金、アルミニウム、アルミニウム合金、マグ
ネシウム、マグネシウム合金、チタン、チタン合金、モ
リブデン、モリブデン合金、タングステン及びタングス
テン合金の中から選ばれる一種以上である。銅、ニッケ
ル、銀。The metal powder used in the present invention includes copper, copper alloy, nickel, nickel alloy, silver, silver alloy, chromium, chromium alloy, iron, iron alloy, aluminum, aluminum alloy, magnesium, magnesium alloy, titanium, titanium alloy, One or more types selected from molybdenum, molybdenum alloys, tungsten, and tungsten alloys. copper, nickel, silver.
クロム、鉄、アルミニウム、マグネシウム、チタン、モ
リブデン及びタングステンの各合金には主成分以外に鉄
、クロム、ニッケル、チタン、モリブデン、ニオブ、バ
ナジウム、コバルト５銅、アルミニウム、マグネシウム
、ジルコニウム、銀。In addition to the main ingredients, each alloy of chromium, iron, aluminum, magnesium, titanium, molybdenum, and tungsten contains iron, chromium, nickel, titanium, molybdenum, niobium, vanadium, cobalt 5 copper, aluminum, magnesium, zirconium, and silver.
鉛、タンタル等を合金元素として含むか、又は粉末とし
て加えて合金化を行うものとする。It contains lead, tantalum, etc. as an alloying element, or is alloyed by adding it as a powder.
無機金属化合物若しくは有機金属化合物の添加量はその
化合物中に含まれる金属の量、目的とする合金組成によ
り決定されるが、無機金属化合物若しくは有機金属化合
物として金属粉末の５０重量％以下が好適で、それ以上
加えてもよいが均一微細に分散させることが困難となる
ばかりでなく、基地となる金属の有する固有の機械的或
いは化学的特性が希薄となり過ぎるので不利なことが多
い。The amount of the inorganic metal compound or organic metal compound added is determined by the amount of metal contained in the compound and the intended alloy composition, but it is preferable that the amount of the inorganic metal compound or organic metal compound is 50% by weight or less of the metal powder. , or more may be added, but it is often disadvantageous because not only is it difficult to uniformly and finely disperse the metal, but also the inherent mechanical or chemical properties of the base metal are too diluted.
本願発明では、前記金属水酸化物若しくは金属水和物か
らなる被覆層を表面に形成した金属粉末を、直接或いは
後述の熱処理を経た後成型加工することにより分散強化
型合金を得ることができる。In the present invention, a dispersion-strengthened alloy can be obtained by molding a metal powder on which a coating layer made of the metal hydroxide or metal hydrate is formed either directly or after undergoing heat treatment described below.
前記金属粉末表面の金属水酸化物若しくは金属水和物又
は金属酸化物は、成型加工或いは粉砕処理により、金属
粉末内部に均一に分散させられる。The metal hydroxide, metal hydrate, or metal oxide on the surface of the metal powder is uniformly dispersed inside the metal powder by molding or pulverization.
前記粉砕処理は、湿式′又は乾式ボールミル、コロイダ
ルミル、ブレンダー、振動ミルやアトライター等の機械
的粉砕混合法又は粉末圧延粉砕混合法の一以上の方法に
よる。粉末圧延粉砕混合法の場合は、前記金属水酸化物
若しくは金属水和物又は金属酸化物を表面被覆した金属
粉末を少量ずつ断続的に供給し、強圧延により粉末を強
薄片化し、機械的に前記金属水酸化物若しくは金属水和
物又は金属酸化物を金属粉末粒内に強制挿入させるもの
であり、−回の粉末強制圧延粉砕混合で所期の目的が達
成されない場合は、複数回繰り返すものとする。その後
、さらに振動ミル、アトライター等により粉砕微粉化を
行うこともできる。The pulverization treatment is carried out by one or more of a mechanical pulverization and mixing method using a wet or dry ball mill, a colloidal mill, a blender, a vibrating mill, an attritor, etc., or a powder rolling pulverization and mixing method. In the case of the powder rolling pulverization mixing method, the metal powder whose surface is coated with the metal hydroxide, metal hydrate, or metal oxide is intermittently fed in small quantities, the powder is made into strong flakes by strong rolling, and then mechanically The metal hydroxide, metal hydrate, or metal oxide is forcibly inserted into the metal powder grains, and if the intended purpose is not achieved after - times of forced rolling, pulverizing, and mixing of the powder, it is repeated multiple times. shall be. Thereafter, further pulverization may be performed using a vibrating mill, an attritor, or the like.
本発明において得・られる分散強化型合金用粉末を用い
て分散強化型合金を製造すれば、焼結時の熱により前記
金属水酸化物若しくは金属水和物は金属酸化物となるが
、分散強化型合金用粉末の段階で熱処理して前記金属水
酸化物若しくは金属水和物を金属酸化物としておいても
よい。つまり、本願の第１番目の発明では、得られた分
散強化型合金用粉末を成型加工前に熱処理し、本願の第
２番目の発明では、前記粉砕処理を施す前又は後に熱処
理をして、金属粉末表面に被覆した金属水酸化物若しく
は金属水和物を金属酸化物として生成させておいてもよ
い。金属酸化物を生成させる為の熱処理温度としては、
各合金粉末により異なるが２００℃以上１０００℃以下
が好ましい。前記熱処理の雰囲気は、真空中、アルゴン
中、水素雰囲気或いは窒素雰囲気でもよい。表面被覆の
際、有機金属化合物に有機溶媒を含む場合は湿水素等に
より加水分解を行い、特に遊離炭素の除去を十分に行、
う必要がある。また、金属塩化物又は酸性の金属塩を
金属粉末に表面被覆する場合にはアンモニアガス雰囲気
等のアルカリ雰囲気中で処理を行うのが好ましい。If a dispersion-strengthened alloy is produced using the dispersion-strengthened alloy powder obtained in the present invention, the metal hydroxide or metal hydrate will become a metal oxide due to the heat during sintering, but dispersion-strengthened The metal hydroxide or metal hydrate may be converted into a metal oxide by heat treatment at the stage of mold alloy powder. That is, in the first invention of the present application, the obtained dispersion-strengthened alloy powder is heat-treated before molding, and in the second invention of the present application, the obtained powder for dispersion-strengthened alloy is heat-treated before or after the pulverization treatment, A metal hydroxide or a metal hydrate coated on the surface of the metal powder may be generated as a metal oxide. The heat treatment temperature for producing metal oxides is as follows:
Although it varies depending on each alloy powder, it is preferably 200°C or more and 1000°C or less. The atmosphere for the heat treatment may be vacuum, argon, hydrogen atmosphere, or nitrogen atmosphere. When coating the surface, if the organometallic compound contains an organic solvent, perform hydrolysis using wet hydrogen, etc., and in particular, thoroughly remove free carbon.
It is necessary. Further, when the surface of metal powder is coated with a metal chloride or an acidic metal salt, it is preferable to carry out the treatment in an alkaline atmosphere such as an ammonia gas atmosphere.
以上の構成よりなるので、本発明の方法で得られた分散
強化型合金用粉末は、次のような効果を奏することがで
きる。即ち、本発明に係る分散強化型合金用粉末の製造
方法においては、金属粉末表面に形成される被覆層が、
無機金属化合物若しくは有機金属化合物を加水分解若し
くは熱分解することによって得られる金属水酸化物若し
くは金属水和物からなるから、均−且つ薄膜状のものと
なる。従って、市販の指定された粒度の酸化物ではなく
、本発明ではこの金属水酸化物若しくは金属水和物が熱
処理により変えられた金属酸化物を利用することになり
、粉砕処理或いは分散強化型合金を得る為の成型加工処
理によりこの金属酸化物が分散粒子として均一・微細に
分散することになるという効果を得ることができる。ま
た、本願の第２番目の発明では、前記効果に付は加えて
次の効果が得られる。即ち、表面に金属水酸化物若しく
は金属水和物からなる被覆層を形成した金属粉末を粉砕
処理しているから、金属酸化物の分散粒子が微細でしか
も均一に分散している分散強化型合金用粉末を短時間で
容易に製造できるという効果を得ることができる。With the above configuration, the dispersion-strengthened alloy powder obtained by the method of the present invention can have the following effects. That is, in the method for producing powder for dispersion-strengthened alloy according to the present invention, the coating layer formed on the surface of the metal powder is
Since it is made of a metal hydroxide or metal hydrate obtained by hydrolyzing or thermally decomposing an inorganic metal compound or an organic metal compound, it becomes a homogeneous and thin film. Therefore, instead of commercially available oxides having a specified particle size, the present invention uses metal oxides whose metal hydroxides or metal hydrates have been changed by heat treatment, and which are processed by pulverization treatment or dispersion-strengthened alloys. By the molding process to obtain the metal oxide, it is possible to obtain the effect that the metal oxide is uniformly and finely dispersed as dispersed particles. In addition to the above effects, the second invention of the present application provides the following effects. In other words, since metal powder with a coating layer made of metal hydroxide or metal hydrate formed on its surface is pulverized, it is a dispersion-strengthened alloy in which the dispersed particles of metal oxide are fine and uniformly dispersed. It is possible to obtain the effect that the powder for use can be easily produced in a short time.
従って、本発明の方法により得られた分散強化型合金用
粉末は引張強度、延性、硬度、靭性、耐熱性、電気的特
性及び耐中性子照射性に優れた分散強化型合金を得る為
の粉末として有用なものである。本発明の方法により得
られた分散強化型合金用粉末を用いて製造される分散強
化型合金の用途としては次のようなものが考えられる。Therefore, the powder for dispersion-strengthened alloys obtained by the method of the present invention can be used as a powder for obtaining dispersion-strengthened alloys with excellent tensile strength, ductility, hardness, toughness, heat resistance, electrical properties, and neutron irradiation resistance. It is useful. The following are possible uses of the dispersion-strengthened alloy produced using the dispersion-strengthened alloy powder obtained by the method of the present invention.
銅合金：電気接点材料、バネ材、スポットｉ接尾チップ
、耐熱性材料、超電導用導電
線
ニッケル合金：耐熱性材料、高温ガス炉用材料銀合金：
電気接点材料（継電気、スイッチ、遮断器、マイクロス
イッチ）
鉄合金：耐熱性材料、中性子遮蔽材料、原子炉用構造用
材料
アルミニウム合金：自動車用部品、エンジン部品
マグネシウム合金：航空機材料
〔実施例〕
以下、本発明の実施例及び実験例を示す。Copper alloy: Electrical contact material, spring material, spot i suffix chip, heat-resistant material, conductive wire for superconducting Nickel alloy: heat-resistant material, material for high-temperature gas reactor Silver alloy:
Electrical contact materials (relays, switches, circuit breakers, microswitches) Iron alloys: Heat-resistant materials, neutron shielding materials, structural materials for nuclear reactors Aluminum alloys: Automotive parts, engine parts Magnesium alloys: Aircraft materials [Examples] Examples and experimental examples of the present invention are shown below.
実施例１
９０℃の薄情水中にアルミニウムイソアミラードをゆっ
くり滴下し、加水分解を行った。加水分解生成物である
金属水酸化物は、ＡＴＯ（ＯＨ）ゲルのＸ線回折パター
ンを示し、約５０人の微細粒子からなっていた。前記金
属水酸化物を２０時間熟成後、５ｗｔ％を平均粒径２μ
ｍの電解銅粉に被覆した。これを１１０℃で乾燥した後
、水素気流中３０分間４００°Ｃで熱処理をして非晶質
Ａｈ（ｈを銅粉末表面に生成させた。次いで、２ｔｏｎ
／ｃ＋１の圧力で粉末圧延粉砕した後、振動ミルで５時
間粉砕合金化して分散強化型合金用銅合金粉末を得た。Example 1 Aluminum isoamylade was slowly dropped into cold water at 90°C to perform hydrolysis. The hydrolysis product, metal hydroxide, showed an X-ray diffraction pattern of ATO(OH) gel and consisted of approximately 50 microscopic particles. After aging the metal hydroxide for 20 hours, 5wt% was mixed with an average particle size of 2μ.
It was coated on electrolytic copper powder of m. After drying this at 110°C, it was heat-treated at 400°C for 30 minutes in a hydrogen stream to form amorphous Ah (h) on the surface of the copper powder.
After powder rolling and pulverization at a pressure of /c+1, the powder was alloyed by pulverization in a vibration mill for 5 hours to obtain a copper alloy powder for dispersion-strengthened alloy.
この粉末には０゜９ｗｔ％のＡＴｚＯ：＋が含まれてい
た。This powder contained 0.9 wt% ATzO:+.
実験例１
実施例１によって得られた銅合金粉末をプレス成型した
後、アルゴン気流中で１０００°Ｃ１１時間焼結した。Experimental Example 1 The copper alloy powder obtained in Example 1 was press-molded and then sintered at 1000° C. for 11 hours in an argon stream.
これを冷間で鍛造後、アルゴン気流中で１０００°Ｃで
３０分間熱処理し、５ｍｍ Ｘ １０ｍｎ＋ Ｘ Ｏ，
５ｍｍの形状に仕上げ、引張試験を行った。その結果、
室温で４５ｋｇ／ｍｍ２．６００℃で１５ｋｇ／ｍｍ”
の引張強度を得た。After cold forging this, it was heat treated at 1000°C for 30 minutes in an argon stream to form a 5mm x 10mm+
It was finished into a shape of 5 mm and subjected to a tensile test. the result,
45kg/mm at room temperature2. 15kg/mm at 600℃
The tensile strength was obtained.
実施例２
ジルコニウム塩とイツトリウム塩を５：１の割合に混合
した水溶液にアンモニアを加えて加水分解してｖ、Ｚｒ
（ＯＨ）４の共沈ゾルを作り、それの５訂％を平均粒径
５μｍの銀粉末に表面被覆した。その後、１００℃１０
時間湿アルゴン気流中で熱分解を行ない、次いで振動ミ
ルで１０時間粉砕合金化した。Example 2 Ammonia was added to an aqueous solution containing a mixture of zirconium salt and yttrium salt at a ratio of 5:1 to hydrolyze v, Zr.
A coprecipitated sol of (OH)4 was prepared, and 5% of it was coated on the surface of silver powder with an average particle size of 5 μm. After that, 100℃10
Thermal decomposition was carried out in a humid argon stream for 1 hour, followed by grinding and alloying in a vibratory mill for 10 hours.
その後、７００℃１時間アルゴン気流中で加熱処理をし
た結果、（Ｙ＋ Ｚｒ） ｇｏｉの微粒子を０．３訂％
分散した分散強化型合金用銀粉末を得た。Thereafter, as a result of heat treatment at 700°C for 1 hour in an argon stream, the fine particles of (Y+Zr) goi were reduced to 0.3%.
Dispersed silver powder for dispersion-strengthened alloys was obtained.
実験例２
実施例２によって得られた銀粉末を用いて、押し出し加
工によって成型体となし、９００°Ｃ１時間アルゴン気
流中で焼結し、ビ・ノカース硬度測定を行なったところ
次の結果を得た。Experimental Example 2 Using the silver powder obtained in Example 2, a molded body was made by extrusion processing, sintered at 900°C in an argon stream for 1 hour, and the Bi-Nocas hardness was measured, and the following results were obtained. Ta.
常温 ３００℃ ５００℃ ７００℃硬さくＨＶ
） １１．０ ６０ ４０ ２０
実施例３
四塩化ジルコニウムをアンモニア溶液により加水分解し
てジルコニウム水酸化物であるゾル状の（Ｚｒ （ＯＨ
） ｔ）とし、これを平均粒径１０μｍのニッケル粉末
に表面被覆した。その後、水素気流中で６００℃３０分
間熱処理することにより、ニッケル粉末表面にＺ ｒ
Ｏ２が０，２ ｗｔ％被覆された分散強化型合金用ニッ
ケル合金粉末を得た。Normal temperature 300℃ 500℃ 700℃Hard HV
) 11.0 60 40 20
Example 3 Zirconium tetrachloride was hydrolyzed with an ammonia solution to produce zirconium hydroxide (Zr (OH
) t), and the surface of this was coated on nickel powder having an average particle size of 10 μm. Thereafter, by heat treatment at 600°C for 30 minutes in a hydrogen stream, Z r
A nickel alloy powder for dispersion-strengthened alloys coated with 0.2 wt% O2 was obtained.
実験例３
実施例３によって得られた二・ノケル合金粉末を粉末圧
延し、１１００℃で１時間アルゴン気流中で焼結し、さ
らにそれを冷間圧延後、１０００℃で１時間アルゴン気
流中で焼き鈍しを行った。得られた材料の室温および８
００℃での引張強度は、８０ｋｇ／ｍｍ２．６０ｋｇ／
ｍｍ２であり、耐熱材料として優れたものであった。Experimental Example 3 The Ni-Nokel alloy powder obtained in Example 3 was powder rolled, sintered at 1100°C for 1 hour in an argon stream, and then cold rolled and then sintered at 1000°C for 1 hour in an argon stream. Annealing was performed. Room temperature of the resulting material and 8
Tensile strength at 00℃ is 80kg/mm2.60kg/
mm2, and was excellent as a heat-resistant material.
実施例４
加水分解し、たゾル状の水酸化ジルコニウムをメチルア
ルコールに混合した後、平均粒径５μｍのアルミニウム
粉末に表面被覆して分散強化型合金用粉末を得た。Example 4 Hydrolyzed zirconium hydroxide in the form of a sol was mixed with methyl alcohol, and then the mixture was coated on aluminum powder with an average particle size of 5 μm to obtain powder for dispersion-strengthened alloys.
実験例４
実施例４によって得られた粉末を用いて押し出し加工を
し、次いで真空中５００℃１時間焼結をした。得られた
分散強化型アルミニウム合金を分析したところ、０．２
５ｗｔ％のｚ２０．が含まれていた。また、引張強度測
定をしたところ、次の結果を得た。Experimental Example 4 The powder obtained in Example 4 was extruded and then sintered at 500° C. for 1 hour in a vacuum. When the obtained dispersion strengthened aluminum alloy was analyzed, it was found that 0.2
5wt% z20. was included. Further, when tensile strength was measured, the following results were obtained.
室温 ３００℃ ５００℃ ６００℃実施例５
塩化セリウムにアンモニアを加えて加水分解したゾル状
のＣｅ （ＯＨ） ４をベンゼン溶液に溶解し、それを
平均粒径５μｍのチタン粉末にＣｅ（ＯＨ） ４３ｗｔ
％の割合で表面被覆した後、アトライターで１０時間粉
砕混合し、さらに５００℃で１時間アルゴン気流中で加
熱してＣｅｚ０３の超微粒子が０．３ ｗｔ％分散した
チタン粉末を得た。Room temperature 300℃ 500℃ 600℃Example 5 A sol-like Ce(OH) 4, which is obtained by adding ammonia to cerium chloride and hydrolyzing it, is dissolved in a benzene solution, and then Ce(OH) 43wt is added to titanium powder with an average particle size of 5 μm.
After coating the surface at a ratio of 0.3 wt %, the titanium powder was pulverized and mixed using an attritor for 10 hours, and further heated at 500° C. for 1 hour in an argon stream to obtain titanium powder in which 0.3 wt % of Cez03 ultrafine particles were dispersed.
実験例５
実施例５で得られたチタン粉末をプレス成型した後、８
００℃１時間加熱し、さらにそれをプレス成型して引張
強度を測定した結果、室温で５０ｋｇ／ｍｍ”、 ６０
０℃で３０ｋｇ／ｍｍＦの引張強度を得た。Experimental Example 5 After press molding the titanium powder obtained in Example 5, 8
After heating at 00°C for 1 hour, it was press-molded and the tensile strength was measured; the result was 50kg/mm'' at room temperature, 60
A tensile strength of 30 kg/mmF was obtained at 0°C.
実施例６
加水分解したギ酸イツトリウムを水に溶解し、さらにそ
れをエチルアルコールを混合した溶液を平均粒径１０μ
ｍのニッケル粉末に表面被覆した後、粉末圧延混合法に
より粉砕した。その後、５００℃１時間アンモニアガス
気流中で加熱処理をし、Ｙ２Ｏ、微粒子が０．４Ｌ％分
散したニッケル合金粉末を作製した。Example 6 A solution of hydrolyzed yttrium formate dissolved in water and mixed with ethyl alcohol was prepared with an average particle size of 10 μm.
After coating the surface of the nickel powder of m, the powder was pulverized by a powder rolling mixing method. Thereafter, heat treatment was performed at 500° C. for 1 hour in an ammonia gas stream to produce a nickel alloy powder in which 0.4 L% of Y2O and fine particles were dispersed.
実験例６
実施例６で得たニッケル粉末をプレス成型した後、１０
００°Ｃ１時間アルゴン気流中で焼成した。成型物の引
張強度を測定したところ、室温で７５ｋｇ／ｍｍ２．
ａｏｏ℃で７０ｋｇ／ｍｍ”の引張強度を得た。Experimental Example 6 After press molding the nickel powder obtained in Example 6, 10
It was fired at 00°C for 1 hour in an argon stream. When the tensile strength of the molded product was measured, it was 75 kg/mm2 at room temperature.
A tensile strength of 70 kg/mm'' was obtained at aoo°C.
実施例７
平均粒径１０μｍのチタン粉末に３ｗｔ％のセリウムア
セチルアセトナートをアセト酢酸エチルに溶解した溶液
を表面被覆した後、１００℃アルゴン気流中で加水分解
し、さらにそれを５００℃で１時間アルゴン気流中で加
熱して非晶質セリウム酸化被膜を被覆したチタン粉末を
得た。Example 7 Titanium powder with an average particle size of 10 μm was coated with a solution of 3 wt% cerium acetylacetonate dissolved in ethyl acetoacetate, then hydrolyzed in an argon stream at 100°C, and further heated at 500°C for 1 hour. Titanium powder coated with an amorphous cerium oxide film was obtained by heating in an argon stream.
実験例７
実施例７で得たチタン粉末を５Ｌの圧力でプレス成型し
た後、１０００℃アルゴン気流中で焼成して引張強度を
測定した結果、室温で５０ｋｇ／ｍｍ２．５００℃で３
０ｋｇ／ｍｍ２の引張強度を得た。Experimental Example 7 The titanium powder obtained in Example 7 was press-molded at a pressure of 5 L, then fired in an argon stream at 1000°C and the tensile strength was measured.
A tensile strength of 0 kg/mm2 was obtained.
実施例８
被覆助剤としてのアセト酢酸エチルをベンゼンに５ｗｔ
％添加した溶媒にイツトリウムイソプロポキシドを溶か
したものを、平均粒径１０μの鉄−１３％クロム粉末に
表面被覆した後、２００”Ｃで加熱して加水分解し、Ｙ
２（ＯＨ）３の非晶質被膜を鉄−１３％クロム粉末表面
に被覆した。この粉末をアトライターで１０時間粉砕し
た後、アルゴン気流中で６００°Ｃで加熱した結果、０
．３ ｗｔ％の微細なＶ２Ｏ３が含まれていた。Example 8 5wt of ethyl acetoacetate as coating aid in benzene
Yttrium isopropoxide dissolved in a solvent containing Yztrium isopropoxide was coated on the surface of iron-13% chromium powder with an average particle size of 10μ, and then heated at 200"C to hydrolyze it.
An amorphous coating of 2(OH)3 was applied to the surface of the iron-13% chromium powder. After grinding this powder with an attritor for 10 hours, it was heated at 600°C in an argon stream.
．． It contained 3 wt% of fine V2O3.
実験例８
実施例８によって得られた鉄−クロム粉末をプレス成型
した後、アルゴン気流中で１０００℃で１時間焼結した
。これを６００℃の熱間で圧延後、５龍ＸＩＱ＋＋ｍＸ
Ｏ，５鶴の形状に仕上げ、引張試験を行なった。その
結果、室温で５０ｋｇ／ｍｍ２．６００°Ｃで３５ｋｇ
／鰭２の引張強度を得た。Experimental Example 8 The iron-chromium powder obtained in Example 8 was press-molded and then sintered at 1000° C. for 1 hour in an argon stream. After hot rolling this at 600℃, 5 Dragon XIQ++mX
It was finished into the shape of an O.5 crane and subjected to a tensile test. As a result, 50kg/mm at room temperature, 35kg at 600°C
/The tensile strength of fin 2 was obtained.
実施例９
平均粒径１０μｍのＮｉ粉末にイソトリウムイソプロポ
キシドをＮ１粉末に対し３ｗｔ％ベンゼンに溶解したも
のを表面被覆した後、室温で加水分解したものを振動型
ボールミルで５時間粉砕処理をした。Example 9 After coating the surface of Ni powder with an average particle size of 10 μm with isotrium isopropoxide dissolved in benzene at 3 wt% based on N1 powder, the powder was hydrolyzed at room temperature and pulverized in a vibrating ball mill for 5 hours. did.
その後、６００℃でアルゴン気流中で処理をした結果、
０．５ｗｔ％の超微粒ｖ２０３を分散したＮｉ粉末を得
た。Afterwards, as a result of treatment at 600°C in an argon stream,
Ni powder in which 0.5 wt % of ultrafine particles v203 were dispersed was obtained.
実験例９
実施例９によって得たＮｉ粉末を５ｔの圧力で静水圧成
型（ＣＩＰ）ｌ、た後、水素中１０００”ｃで１時間焼
結した。その後、加工して引張試験を行なった結果、室
温で５５ｋｇ／ｍｍ２．６００℃で３５ｋｇ／ｍｍ２の
引張強度を得た。Experimental Example 9 The Ni powder obtained in Example 9 was subjected to hydrostatic pressing (CIP) at a pressure of 5 tons, and then sintered in hydrogen at 1000"C for 1 hour. After that, it was processed and subjected to a tensile test. , a tensile strength of 55 kg/mm2 at room temperature and 35 kg/mm2 at 600°C was obtained.
実施例１０
ジルコニウムに１０１’ｌｔ％のイツトリウムを含むイ
ソプロポキシドをベンゼンに溶解したものを平均粒径１
０μｍの銀粉末に表面被覆した後、室温、空気中で加水
分解し、それを５００℃で加熱した後粉末圧延粉砕した
結果、非晶質（Ｚｒ、 Ｙ） ２０３が０．４匈ｔ％分
散した銀粉末を得た。Example 10 Isopropoxide containing 101'lt% yttrium in zirconium was dissolved in benzene and the average particle size was 1.
After coating the surface with 0 μm silver powder, it was hydrolyzed in air at room temperature, heated at 500°C, and then powder rolled and pulverized. As a result, 0.4 hot% of amorphous (Zr, Y) 203 was dispersed. A silver powder was obtained.
実験例１０
実施例１０によって得た銀粉末を８００℃でＨＩＰ成型
した後硬度測定をした結果、ビッカース硬さ１３０であ
り、電気比抵抗は２．５μΩ−■であり、８００℃１時
間熱処理をしても硬度変化は認められず、電気接点材料
として有用なものであった。Experimental Example 10 The silver powder obtained in Example 10 was HIP-molded at 800°C, and the hardness was measured. As a result, the Vickers hardness was 130, and the electrical resistivity was 2.5 μΩ-■. However, no change in hardness was observed, and the material was useful as an electrical contact material.
実施例１１
平均粒径５μｍの電解銅粉末に、電解銅粉末に対して３
ｗｔ％のアルミニウムイソプロポキシドを石油エーテル
に溶解した溶液を表面被覆した。次いで、湿水素中３０
０°Ｃで加水分解した後、３回の粉末圧延粉砕混合を行
ない、次いでアトライターで乾式粉砕混合を１０時間行
なって分散強化型銅粉末を得た。
′＼実験例１１
実施例１１によって得られた銅粉末を粉末押し出しをし
て直径１１０１Ａ、長さ３０ｍｍの円筒状成型体を作り
、アルゴン気流中で１０００℃６０分加熱焼成した。Example 11 Electrolytic copper powder with an average particle size of 5 μm was
The surface was coated with a solution of wt% aluminum isopropoxide in petroleum ether. Then, in wet hydrogen for 30
After hydrolyzing at 0°C, the powder was rolled, pulverized and mixed three times, and then dry pulverized and mixed in an attritor for 10 hours to obtain a dispersion-strengthened copper powder.
'\ Experimental Example 11 The copper powder obtained in Example 11 was extruded into a cylindrical molded body with a diameter of 1101 A and a length of 30 mm, which was then heated and fired at 1000° C. for 60 minutes in an argon stream.
得られた成型体を熱間鍛造して中ＩＱｉｎ、厚さ０．５
１の板状試験片として引張試験を行なった。その結果、
室温で引張強度５５ｋｇ／ｍｍ２．伸び１０．１％、６
００℃で２０ｋｇ／ｍｍ”、伸び１５％を得た。また、
電気抵抗は室温で１．７２μΩ−Ｇであり、耐熱導伝性
材料として有用であった。The obtained molded body is hot forged to have a medium IQin and a thickness of 0.5.
A tensile test was conducted using a plate-shaped test piece of No. 1. the result,
Tensile strength 55kg/mm2 at room temperature. Elongation 10.1%, 6
20 kg/mm” and elongation of 15% were obtained at 00°C.
The electrical resistance was 1.72 μΩ-G at room temperature, making it useful as a heat-resistant conductive material.
実施例１２
平均粒径２０μｍのチタン粉末に、ジルコニウムアセチ
ルアセトナート３訂％と酢酸エチル１訂％とを混合した
溶液を表面被覆した。その後、湿水素気流中１００℃で
加水分解して前記被覆物をＺｒ（ＯＨ）４とした。その
後、さらに５００℃で３０分アルゴン気流中で熱処理を
行なってチタン粉末表面にＺｒ２Ｏ３を生成させた。次
いで、３回の粉末圧延粉砕により薄片化し、その後アト
ライターにより１時間微粉化して分散強化型チタン合金
粉末を得た。Example 12 Titanium powder having an average particle size of 20 μm was coated with a solution containing 3% zirconium acetylacetonate and 1% ethyl acetate. Thereafter, the coating was hydrolyzed at 100° C. in a stream of wet hydrogen to form Zr(OH)4. Thereafter, heat treatment was further performed at 500°C for 30 minutes in an argon stream to generate Zr2O3 on the surface of the titanium powder. Next, it was made into thin pieces by powder rolling and pulverization three times, and then pulverized for 1 hour using an attritor to obtain a dispersion-strengthened titanium alloy powder.
実験例１２
実施例１２によって得られたチタン合金粉末を用いて、
ＨＩＰで９００℃１時間成型をした。得られた成型体を
冷間鍛造で巾１０１．厚さ０．５鶴の板状試料として引
張試験を行なった。その結果、室温で８５ｋｇ／ｍｍ”
、伸び１５％、６００℃で７５ｋｇ／ｍｍ”、伸び２０
％であった。Experimental Example 12 Using the titanium alloy powder obtained in Example 12,
Molding was carried out using HIP at 900°C for 1 hour. The obtained molded body was cold forged to a width of 101 mm. A tensile test was conducted using a plate-like sample with a thickness of 0.5 mm. As a result, the weight was 85kg/mm at room temperature.
, elongation 15%, 75kg/mm at 600℃, elongation 20
%Met.
実施例１３
平均粒径１０μｍのアルミニウム粉末に、アルミニウム
粉末に対し３れ％のジルコニウムプロポキシドを被覆助
剤としてアセト酢酸エチル１ｗｔ％添加したベンゼンに
溶解した溶液を表面被覆した。Example 13 An aluminum powder having an average particle size of 10 μm was coated with a solution in which zirconium propoxide (3% by weight based on the aluminum powder) was dissolved in benzene and 1% by weight of ethyl acetoacetate was added as a coating aid.
次いで、加水分解し、アトライターで５時間粉砕混合し
た後、５００℃で１時間アルゴン気流中で加熱し、Ｚｒ
Ｏ，を分散させた。Next, the Zr
O, was dispersed.
実験例１３
実施例１３で得た試料を粉末圧延成型した後５００℃１
時間アルゴン気流中で焼成し、引張試験をした結果、室
温で４０ｋｇ／ｍｍｚ、 ６００°Ｃで１５ｋｇ／ｍｍ
”の引張強度を得た。Experimental Example 13 The sample obtained in Example 13 was powder rolled and molded at 500°C1.
As a result of tensile test after firing in an argon stream for an hour, the result was 40kg/mmz at room temperature and 15kg/mmz at 600°C.
” tensile strength was obtained.
実施例１４
平均粒径１０μｍのアルミニウム粉末に、アルミニウム
粉末に対し３ｗｔ％のイツトリウムアセチルアセトナー
トをアセト酢酸メチルに熔解した溶液を表面被覆した。Example 14 An aluminum powder having an average particle size of 10 μm was coated with a solution of 3 wt % of yttrium acetylacetonate dissolved in methyl acetoacetate based on the aluminum powder.
次いで、３００℃で湿水素中で加水分解したものをさら
に５００℃で加熱し、ｙ２０３被膜とした後、振動型ボ
ールミルで１０時間粉砕し、ｙ２０３の超微粒子の分散
しているアルミニウム粉末を得た。Next, the product was hydrolyzed in wet hydrogen at 300°C and further heated at 500°C to form a Y203 coating, which was then ground in a vibrating ball mill for 10 hours to obtain aluminum powder in which ultrafine Y203 particles were dispersed. .
実験例１４
実施例１４で得た粉末をＨＩＰで５００℃、５ｔで加圧
成型した後、引張強度を測定した結果、室温で３５ｋｇ
／ｍｍ２．６００℃で２０ｋｇ／ｍｍ２の引張強度を得
た。Experimental Example 14 After pressure molding the powder obtained in Example 14 at 500°C and 5 tons using HIP, the tensile strength was measured, and the result was 35 kg at room temperature.
/mm2. A tensile strength of 20 kg/mm2 was obtained at 600°C.
Claims (15)
物を加水分解若しくは熱分解することによって得られる
金属水酸化物若しくは金属水和物からなる被覆層を金属
粉末表面に形成することを特徴とする分散強化型合金用
粉末の製造方法。(1) A dispersion characterized by forming a coating layer on the surface of a metal powder consisting of a metal hydroxide or metal hydrate obtained by hydrolyzing or thermally decomposing one or more inorganic metal compounds or organic metal compounds. A method for producing powder for reinforced alloys.
まれる金属が、Ａｌ、Ｔｉ、Ｃｕ、Ｆｅ、Ｍｏ、Ｗ、Ａ
ｕ、Ａｇ、Ｓｉ、Ｎｂ、Ｖ、Ｚｒ、Ｔａ、Ｙ、Ｃｒ、Ｂ
及び希土類元素の中から選ばれる一種以上である特許請
求の範囲第１項に記載の分散強化型合金用粉末の製造方
法。(2) The metal contained in the inorganic metal compound or organic metal compound is Al, Ti, Cu, Fe, Mo, W, A
u, Ag, Si, Nb, V, Zr, Ta, Y, Cr, B
The method for producing a dispersion-strengthened alloy powder according to claim 1, wherein the dispersion-strengthened alloy powder is one or more selected from rare earth elements.
ル合金、銀、銀合金、クロム、クロム合金、鉄、鉄合金
、アルミニウム、アルミニウム合金、マグネシウム、マ
グネシウム合金、チタン、チタン合金、モリブデン、モ
リブデン合金、タングステン及びタングステン合金の中
から選ばれる一種以上である特許請求の範囲第１項又は
第２項に記載の分散強化型合金用粉末の製造方法。(3) The metal powder is copper, copper alloy, nickel, nickel alloy, silver, silver alloy, chromium, chromium alloy, iron, iron alloy, aluminum, aluminum alloy, magnesium, magnesium alloy, titanium, titanium alloy, molybdenum, The method for producing a dispersion-strengthened alloy powder according to claim 1 or 2, which is one or more types selected from molybdenum alloys, tungsten, and tungsten alloys.
た溶媒に無機金属化合物若しくは有機金属化合物を溶解
させた特許請求の範囲第１項〜第３項の何れかに記載の
分散強化型合金用粉末の製造方法。(4) The dispersion-strengthened type according to any one of claims 1 to 3, wherein an inorganic metal compound or an organic metal compound is dissolved in a solvent to which a coating aid is added when forming the coating layer. A method for producing powder for alloys.
くは金属水和物からなる被覆層が、無機金属化合物若し
くは有機金属化合物を金属粉末表面に被覆した後加水分
解若しくは熱分解することによって得られたものである
特許請求の範囲第１項〜第４項の何れかに記載の分散強
化型合金用粉末の製造方法。(5) The coating layer made of metal hydroxide or metal hydrate formed on the surface of the metal powder is obtained by coating the surface of the metal powder with an inorganic metal compound or organic metal compound and then hydrolyzing or thermally decomposing it. A method for producing a powder for dispersion-strengthened alloy according to any one of claims 1 to 4.
くは金属水和合物からなる被覆層が、無機金属化合物若
しくは有機金属化合物を加水分解若しくは熱分解した後
金属粉末表面に被覆することによって得られたものであ
る特許請求の範囲第１項〜第４項の何れかに記載の分散
強化型合金用粉末の製造方法。(6) The coating layer made of metal hydroxide or metal hydrate formed on the surface of the metal powder is obtained by coating the surface of the metal powder after hydrolyzing or thermally decomposing an inorganic metal compound or an organic metal compound. A method for producing a powder for dispersion-strengthened alloy according to any one of claims 1 to 4.
金属水酸化物若しくは金属水和物が、熱処理により非晶
質若しくは微細粒子の金属酸化物とされた特許請求の範
囲第１項〜第６項の何れかに記載の分散強化型合金用粉
末の製造方法。(7) The metal hydroxide or metal hydrate constituting the coating layer formed on the surface of the metal powder is made into an amorphous or fine particle metal oxide by heat treatment. A method for producing a dispersion-strengthened alloy powder according to any one of Item 6.
物を加水分解若しくは熱分解することによって得られる
金属水酸化物若しくは金属水和物からなる被覆層を表面
に有する金属粉末を、機械粉砕混合法若しくは粉末圧延
粉砕混合法の一以上の方法により粉砕処理することを特
徴とする分散強化型合金用粉末の製造方法。(8) A metal powder having a coating layer on its surface consisting of a metal hydroxide or metal hydrate obtained by hydrolyzing or thermally decomposing one or more inorganic metal compounds or organic metal compounds can be prepared by mechanical grinding and mixing. 1. A method for producing powder for dispersion-strengthened alloys, which comprises pulverizing by one or more methods of powder rolling, pulverizing, and mixing.
まれる金属が、Ａｌ、Ｔｉ、Ｃｕ、Ｆｅ、Ｍｏ、Ｗ、Ａ
ｕ、Ａｇ、Ｓｉ、Ｎｂ、Ｖ、Ｚｒ、Ｔａ、Ｙ、Ｃｒ、Ｂ
及び希土類元素の中から選ばれる一種以上である特許請
求の範囲第８項に記載の分散強化型合金用粉末の製造方
法。(9) The metal contained in the inorganic metal compound or organic metal compound is Al, Ti, Cu, Fe, Mo, W, A
u, Ag, Si, Nb, V, Zr, Ta, Y, Cr, B
The method for producing a dispersion-strengthened alloy powder according to claim 8, wherein the powder is one or more selected from rare earth elements.
ケル合金、銀、銀合金、クロム、クロム合金、鉄、鉄合
金、アルミニウム、アルミニウム合金、マグネシウム、
マグネシウム合金、チタン、チタン合金、モリブデン、
モリブデン合金、タングステン及びタングステン合金の
中から選ばれる一種以上である特許請求の範囲第８項又
は第９項に記載の分散強化型合金用粉末の製造方法。(10) The metal powder is copper, copper alloy, nickel, nickel alloy, silver, silver alloy, chromium, chromium alloy, iron, iron alloy, aluminum, aluminum alloy, magnesium,
Magnesium alloy, titanium, titanium alloy, molybdenum,
The method for producing a dispersion-strengthened alloy powder according to claim 8 or 9, wherein the powder is one or more selected from molybdenum alloys, tungsten, and tungsten alloys.
した溶媒に無機金属化合物若しくは有機金属化合物を溶
解させた特許請求の範囲第８項〜第１０項の何れかに記
載の分散強化型合金用粉末の製造方法。(11) The dispersion-strengthened type according to any one of claims 8 to 10, wherein an inorganic metal compound or an organic metal compound is dissolved in a solvent to which a coating aid is added when forming the coating layer. A method for producing powder for alloys.
被覆層を表面に有する金属粉末が、無機金属化合物若し
くは有機金属化合物を金属粉末表面に被覆した後加水分
解若しくは熱分解することによって得られたものである
特許請求の範囲第８項〜第１１項の何れかに記載の分散
強化型合金用粉末の製造方法。(12) The metal powder having the coating layer made of the metal hydroxide or metal hydrate on the surface is obtained by coating the surface of the metal powder with an inorganic metal compound or an organic metal compound and then hydrolyzing or thermally decomposing the metal powder. A method for producing a dispersion-strengthened alloy powder according to any one of claims 8 to 11.
被覆層を表面に有する金属粉末が、無機金属化合物若し
くは有機金属化合物を加水分解若しくは熱分解した後金
属粉末表面に被覆することによって得られたものである
特許請求の範囲第８項〜第１１項の何れかに記載の分散
強化型合金用粉末の製造方法。(13) The metal powder having a coating layer made of the metal hydroxide or metal hydrate on the surface is obtained by hydrolyzing or thermally decomposing an inorganic metal compound or an organic metal compound and then coating the surface of the metal powder. A method for producing a dispersion-strengthened alloy powder according to any one of claims 8 to 11.
る金属水酸化物若しくは金属水和物が、粉砕処理の前の
熱処理により非晶質若しくは微細粒子の金属酸化物とさ
れた特許請求の範囲第８項〜第１３項の何れかに記載の
分散強化型合金用粉末の製造方法。(14) A patent claim in which the metal hydroxide or metal hydrate constituting the coating layer formed on the surface of the metal powder is made into an amorphous or fine particle metal oxide by heat treatment before pulverization treatment. A method for producing a dispersion-strengthened alloy powder according to any one of items 8 to 13.
る金属水酸化物若しくは金属水和物が、粉砕処理の後の
熱処理により非晶質若しくは微細粒子の金属酸化物とさ
れた特許請求の範囲第８項〜第１３項の何れかに記載の
分散強化型合金用粉末の製造方法。(15) A patent claim in which the metal hydroxide or metal hydrate constituting the coating layer formed on the surface of the metal powder is made into an amorphous or fine-particle metal oxide by heat treatment after pulverization treatment. A method for producing a dispersion-strengthened alloy powder according to any one of items 8 to 13.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59133852A JPS6112801A (en) | 1984-06-27 | 1984-06-27 | Production of powder for dispersion-strengthened alloy |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP59133852A JPS6112801A (en) | 1984-06-27 | 1984-06-27 | Production of powder for dispersion-strengthened alloy |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| JPS6112801A true JPS6112801A (en) | 1986-01-21 |
| JPH0379402B2 JPH0379402B2 (en) | 1991-12-18 |
Family
ID=15114534
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| JP59133852A Granted JPS6112801A (en) | 1984-06-27 | 1984-06-27 | Production of powder for dispersion-strengthened alloy |
Country Status (1)
| Country | Link |
|---|---|
| JP (1) | JPS6112801A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11315041A (en) * | 1998-02-12 | 1999-11-16 | Samsung Display Devices Co Ltd | Metal oxide precursor composition and its production |
| CN107201435A (en) * | 2017-04-29 | 2017-09-26 | 天津大学 | With nanocluster and dislocation, the preparation method of the ferrous alloy of twins sub-structure |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS503908A (en) * | 1973-04-20 | 1975-01-16 | ||
| JPS5510655A (en) * | 1978-07-10 | 1980-01-25 | Hitachi Ltd | Terminal pressure controller |
| JPS5773103A (en) * | 1980-10-27 | 1982-05-07 | Res Dev Corp Of Japan | Production of high strength heat resistant metallic material |
| JPS5779137A (en) * | 1980-09-04 | 1982-05-18 | Gen Electric | Dispersion reinforced type copper alloy, stock powdery copper mixture thereof and production thereof |
| JPS5836660A (en) * | 1981-08-31 | 1983-03-03 | Fuji Xerox Co Ltd | Multiphase electric field curtain device |
-
1984
- 1984-06-27 JP JP59133852A patent/JPS6112801A/en active Granted
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS503908A (en) * | 1973-04-20 | 1975-01-16 | ||
| JPS5510655A (en) * | 1978-07-10 | 1980-01-25 | Hitachi Ltd | Terminal pressure controller |
| JPS5779137A (en) * | 1980-09-04 | 1982-05-18 | Gen Electric | Dispersion reinforced type copper alloy, stock powdery copper mixture thereof and production thereof |
| JPS5773103A (en) * | 1980-10-27 | 1982-05-07 | Res Dev Corp Of Japan | Production of high strength heat resistant metallic material |
| JPS5836660A (en) * | 1981-08-31 | 1983-03-03 | Fuji Xerox Co Ltd | Multiphase electric field curtain device |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPH11315041A (en) * | 1998-02-12 | 1999-11-16 | Samsung Display Devices Co Ltd | Metal oxide precursor composition and its production |
| CN107201435A (en) * | 2017-04-29 | 2017-09-26 | 天津大学 | With nanocluster and dislocation, the preparation method of the ferrous alloy of twins sub-structure |
Also Published As
| Publication number | Publication date |
|---|---|
| JPH0379402B2 (en) | 1991-12-18 |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| LAPS | Cancellation because of no payment of annual fees |