JP6529519B2 - 重合性化合物及び光学異方体 - Google Patents
重合性化合物及び光学異方体 Download PDFInfo
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- JP6529519B2 JP6529519B2 JP2016567443A JP2016567443A JP6529519B2 JP 6529519 B2 JP6529519 B2 JP 6529519B2 JP 2016567443 A JP2016567443 A JP 2016567443A JP 2016567443 A JP2016567443 A JP 2016567443A JP 6529519 B2 JP6529519 B2 JP 6529519B2
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- LPOBDENYOSHMMX-UHFFFAOYSA-N CC(C)(C1)N(C)C(C)(C)CC1OC(CCCCCCCCC(OC1CC(C)(C)N(C)C(C)(C)C1)=O)=C1CCC1 Chemical compound CC(C)(C1)N(C)C(C)(C)CC1OC(CCCCCCCCC(OC1CC(C)(C)N(C)C(C)(C)C1)=O)=C1CCC1 LPOBDENYOSHMMX-UHFFFAOYSA-N 0.000 description 1
- XITRBUPOXXBIJN-UHFFFAOYSA-N CC(C)(C1)NC(C)(C)CC1OC(CCCCCCCCC(OC1CC(C)(C)NC(C)(C)C1)=O)=O Chemical compound CC(C)(C1)NC(C)(C)CC1OC(CCCCCCCCC(OC1CC(C)(C)NC(C)(C)C1)=O)=O XITRBUPOXXBIJN-UHFFFAOYSA-N 0.000 description 1
- LTPHFRZRQRDTGH-UHFFFAOYSA-N CCCCC(C(C(C(C1)CC1C1CC(C)(C)N(C)C(C)(C)C1)=O)C(OC1CC(C)(C)N(C)C(C)(C)C1)=O)c(cc1C(C)(C)C)cc(C(C)(C)C)c1O Chemical compound CCCCC(C(C(C(C1)CC1C1CC(C)(C)N(C)C(C)(C)C1)=O)C(OC1CC(C)(C)N(C)C(C)(C)C1)=O)c(cc1C(C)(C)C)cc(C(C)(C)C)c1O LTPHFRZRQRDTGH-UHFFFAOYSA-N 0.000 description 1
- XBGYUWKPJQMKSF-YLBKIDSQSA-O CCCC[U]c(cc(cc1)C(Oc(ccc(CCOC(c(cc2)ccc2-c2ccc(CCC)cc2)=O)c2S3)c2S/C3=C/c(ccc(/C=[NH+]/N=C/c2c(CCCC3)c3ccc2)c2C)c2F)=O)c1OCCCOCC1CC2OC2CC1 Chemical compound CCCC[U]c(cc(cc1)C(Oc(ccc(CCOC(c(cc2)ccc2-c2ccc(CCC)cc2)=O)c2S3)c2S/C3=C/c(ccc(/C=[NH+]/N=C/c2c(CCCC3)c3ccc2)c2C)c2F)=O)c1OCCCOCC1CC2OC2CC1 XBGYUWKPJQMKSF-YLBKIDSQSA-O 0.000 description 1
- TXCDCPKCNAJMEE-UHFFFAOYSA-N c(cc1)cc2c1[o]c1c2cccc1 Chemical compound c(cc1)cc2c1[o]c1c2cccc1 TXCDCPKCNAJMEE-UHFFFAOYSA-N 0.000 description 1
- IYYZUPMFVPLQIF-UHFFFAOYSA-N c(cc1)cc2c1[s]c1c2cccc1 Chemical compound c(cc1)cc2c1[s]c1c2cccc1 IYYZUPMFVPLQIF-UHFFFAOYSA-N 0.000 description 1
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- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F1/00—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
- G02F1/01—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour
- G02F1/13—Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics for the control of the intensity, phase, polarisation or colour based on liquid crystals, e.g. single liquid crystal display cells
- G02F1/133—Constructional arrangements; Operation of liquid crystal cells; Circuit arrangements
- G02F1/1333—Constructional arrangements; Manufacturing methods
- G02F1/1337—Surface-induced orientation of the liquid crystal molecules, e.g. by alignment layers
-
- G—PHYSICS
- G02—OPTICS
- G02F—OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
- G02F2202/00—Materials and properties
- G02F2202/02—Materials and properties organic material
- G02F2202/022—Materials and properties organic material polymeric
- G02F2202/023—Materials and properties organic material polymeric curable
Description
Ao/Ae>1 (式I)
を満たすことが好ましい。
(実施例1)式(I−1)で表される化合物の製造
MS(m/z):1064[M++1]
(実施例2)式(I−2)で表される化合物の製造
MS(m/z):1034[M++1]
(実施例3)式(I−3)で表される化合物の製造
MS(m/z):640[M++1]
(実施例4)式(I−4)で表される化合物の製造
MS(m/z):1032[M++1]
(実施例5)式(I−5)で表される化合物の製造
MS(m/z):842[M++1]
(実施例6)式(I−6)で表される化合物の製造
MS(m/z):1020[M++1]
(実施例7)式(I−7)で表される化合物の製造
MS(m/z):1265[M++1]
(実施例8)式(I−8)で表される化合物の製造
MS(m/z):1201[M++1]
(実施例9)式(I−9)で表される化合物の製造
MS(m/z):1035[M++1]
(実施例10)式(I−10)で表される化合物の製造
MS(m/z):1105[M++1]
(実施例11〜30、比較例1〜4)
実施例1から実施例10記載の式(I−1)から式(I−10)で表される化合物及び特許文献1記載の化合物(R−1)、特許文献2記載の化合物(R−2)を評価対象の化合物とした。
YI=100(1.28X−1.06Z)/Y
(式中、YIは黄色度、X、Y、ZはXYZ表色系における三刺激値を表す(JIS K7373)である。結果を下表に示す。
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JP2015006294 | 2015-01-16 | ||
PCT/JP2016/050983 WO2016114345A1 (ja) | 2015-01-16 | 2016-01-14 | 重合性化合物及び光学異方体 |
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JP (2) | JP6529519B2 (ja) |
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CN (1) | CN107108488A (ja) |
WO (1) | WO2016114345A1 (ja) |
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JP6473537B1 (ja) * | 2017-10-13 | 2019-02-20 | 大日本印刷株式会社 | 重合性液晶化合物、重合性組成物、重合体、位相差フィルム及びその製造方法、転写用積層体、光学部材及びその製造方法、並びに表示装置 |
CN109336740B (zh) * | 2018-11-27 | 2021-08-17 | 湖南有色郴州氟化学有限公司 | 一种4,4,4-三氟-1-丁醇的制备方法 |
JP7251291B2 (ja) * | 2019-04-23 | 2023-04-04 | コニカミノルタ株式会社 | 光応答性高分子化合物 |
JP7251193B2 (ja) * | 2019-02-14 | 2023-04-04 | コニカミノルタ株式会社 | 光応答性高分子材料、接着剤、トナーおよび画像形成方法 |
CN110423210B (zh) * | 2019-07-19 | 2021-07-27 | 暨南大学 | 一种苄基芳基硫醚衍生物及其制备方法和应用 |
CN114605350A (zh) * | 2022-03-23 | 2022-06-10 | 江苏创拓新材料有限公司 | 可聚合化合物及含有其的可聚合组合物和光学各向异性体 |
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JP4297436B2 (ja) * | 2004-08-19 | 2009-07-15 | 日東電工株式会社 | 液晶性ジ(メタ)アクリレート化合物及びこれを用いた位相差フィルム、光学フィルム、偏光板、液晶パネル並びに液晶表示装置 |
JP5186734B2 (ja) * | 2005-10-18 | 2013-04-24 | Dic株式会社 | アゾ化合物、光配向膜用組成物、光配向膜及び液晶表示素子 |
US8821994B2 (en) * | 2007-03-29 | 2014-09-02 | Akron Polymer Systems | Liquid crystal display having improved wavelength dispersion characteristics |
JP2009075494A (ja) * | 2007-09-25 | 2009-04-09 | Fujifilm Corp | 液晶組成物及び光学異方性材料 |
US8114310B2 (en) * | 2007-10-22 | 2012-02-14 | Merck Patent Gmbh | Liquid-crystal display |
TWI544062B (zh) * | 2009-02-20 | 2016-08-01 | Dainippon Ink & Chemicals | 聚合性液晶組成物 |
JP5899607B2 (ja) * | 2009-03-16 | 2016-04-06 | 住友化学株式会社 | 化合物、光学フィルム及び光学フィルムの製造方法 |
WO2012144331A1 (ja) * | 2011-04-18 | 2012-10-26 | Dic株式会社 | 末端環構造にラテラル置換基を有する重合性化合物 |
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JP2013003212A (ja) * | 2011-06-13 | 2013-01-07 | Nippon Zeon Co Ltd | パターン位相差フィルム、ディスプレイ装置及び立体画像表示システム |
WO2013161096A1 (ja) * | 2012-04-26 | 2013-10-31 | Dic株式会社 | ネマチック液晶組成物及びこれを用いた液晶表示素子 |
KR101972064B1 (ko) * | 2012-07-09 | 2019-04-24 | 제온 코포레이션 | 중합성 화합물, 중합성 조성물, 고분자, 광학 이방체, 및 중합성 화합물의 제조 방법 |
WO2014132978A1 (ja) * | 2013-02-28 | 2014-09-04 | 富士フイルム株式会社 | 位相差板、反射防止板、画像表示装置、および位相差板の製造方法 |
JP6427340B2 (ja) * | 2013-09-11 | 2018-11-21 | 富士フイルム株式会社 | 光学異方性層とその製造方法、積層体とその製造方法、偏光板、液晶表示装置及び有機el表示装置 |
JP6638181B2 (ja) * | 2013-10-31 | 2020-01-29 | Jnc株式会社 | 重合性液晶組成物およびツイスト配向を有する光学異方体 |
JP6333857B2 (ja) * | 2013-12-25 | 2018-05-30 | Dic株式会社 | メソゲン基を含有する化合物、それを用いた混合物、組成物、及び、光学異方体 |
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- 2016-01-14 US US15/542,537 patent/US20170362508A1/en not_active Abandoned
- 2016-01-14 JP JP2016567443A patent/JP6529519B2/ja not_active Expired - Fee Related
- 2016-01-14 CN CN201680005299.7A patent/CN107108488A/zh active Pending
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US20170362508A1 (en) | 2017-12-21 |
WO2016114345A1 (ja) | 2016-07-21 |
JP2018184599A (ja) | 2018-11-22 |
KR20170106953A (ko) | 2017-09-22 |
CN107108488A (zh) | 2017-08-29 |
JPWO2016114345A1 (ja) | 2017-04-27 |
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