JP5592250B2 - 二酸化炭素の合成ガスへの接触水素化 - Google Patents
二酸化炭素の合成ガスへの接触水素化 Download PDFInfo
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- JP5592250B2 JP5592250B2 JP2010504530A JP2010504530A JP5592250B2 JP 5592250 B2 JP5592250 B2 JP 5592250B2 JP 2010504530 A JP2010504530 A JP 2010504530A JP 2010504530 A JP2010504530 A JP 2010504530A JP 5592250 B2 JP5592250 B2 JP 5592250B2
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- catalyst
- carbon dioxide
- synthesis gas
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6562—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Description
混合酸化物触媒組成物である1%のLi−10%のCr−8%のMn−O/Al2O3を、アルミナ担体を表記の金属の硝酸塩の水溶液に含浸し、担体上に金属を析出させ、固体を単離し、その後、約4時間の期間で、約120℃で乾燥させ、約500℃でか焼することによって、製造した。触媒組成物の金属含有量は、X線回折および元素分析により決定し、1%のLi−10%のCr−8%のMn−O/Al2O3の表記の総組成に基づく質量%で表される。
実施例1に類似しているが、二酸化炭素がそれより少ない供給ガスについて、実験を行った。時間による触媒性能、および空気(酸素)を添加する効果をテストした。表2に収集されている結果は、反応装置を通る空気により、選択性およびSNにほとんど影響なく、触媒を再度活性化させ、二酸化炭素の転化率を回復できることを示している。
これらの実験において、3mlの触媒組成物の0.3%のPt−20%のCe−4%のMn−O/MgOが充填されたガラス管を適用した。それ以外は、実施例3と同様に実験を行った。結果が表4に示されている。
Claims (13)
- 水素、一酸化炭素および二酸化炭素を含有する合成ガス混合物を製造する方法であって、二酸化炭素および水素を含有するガス状供給混合物を触媒に接触させる工程を有してなり、Mn酸化物およびLa酸化物、あるいはMn酸化物、La酸化物、ならびにCr、Ni、Ce、WおよびPtからなる群より選択される少なくとも1つの元素の酸化物が、前記触媒の活性部位を形成することを特徴とする方法(但し、前記触媒がCuを含有する場合を除く)。
- 前記触媒が、少なくとも1種類のアルカリ金属またはアルカリ土類金属をさらに含むことを特徴とする請求項1記載の方法。
- 前記金属が、Li、K、CsおよびSrからなる群より選択されることを特徴とする請求項2記載の方法。
- 前記触媒が担体をさらに含むことを特徴とする、請求項1から3いずれか1項記載の方法。
- 前記担体が、Al2O3、MgO、SiO2、TiO2およびZrO2からなる群より選択されることを特徴とする請求項4記載の方法。
- 前記接触工程が、300から900℃の温度、0.1から6MPaの圧力、および0.5から6秒の接触時間で行われることを特徴とする請求項1から5いずれか1項記載の方法。
- 前記供給混合物における二酸化炭素に対する水素のモル比が1から5までであることを特徴とする、請求項1から6いずれか1項記載の方法。
- 前記合成ガス混合物が、0.1から3.0の化学量数を有し、化学量数=([H2]−[CO2])/([CO]+[CO2])である、請求項1から7いずれか1項記載の方法。
- 前記供給混合物がアルカンをさらに含むことを特徴とする請求項1から8いずれか1項記載の方法。
- 前記アルカンがメタンであることを特徴とする請求項9記載の方法。
- メタン改質工程をさらに含む、請求項1から10いずれか1項記載の方法。
- 請求項1から11いずれか1項記載の方法によって製造した合成ガス混合物を中間体または供給材料として使用する、化学生成物を製造する方法。
- メタノール製造、オレフィン合成、芳香族製造、オレフィンのヒドロホルミル化、メタノールのカルボニル化、またはオレフィンのカルボニル化の方法であることを特徴とする、請求項12記載の方法。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
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EP07008587.3 | 2007-04-27 | ||
EP07008587 | 2007-04-27 | ||
PCT/EP2008/003258 WO2008131898A1 (en) | 2007-04-27 | 2008-04-23 | Catalytic hydrogenation of carbon dioxide into syngas mixture |
Publications (2)
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JP2010525118A JP2010525118A (ja) | 2010-07-22 |
JP5592250B2 true JP5592250B2 (ja) | 2014-09-17 |
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JP2010504530A Expired - Fee Related JP5592250B2 (ja) | 2007-04-27 | 2008-04-23 | 二酸化炭素の合成ガスへの接触水素化 |
Country Status (6)
Country | Link |
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US (1) | US8961829B2 (ja) |
EP (1) | EP2152409B1 (ja) |
JP (1) | JP5592250B2 (ja) |
CN (1) | CN101678329B (ja) |
EA (1) | EA016492B9 (ja) |
WO (1) | WO2008131898A1 (ja) |
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JP2000169411A (ja) | 1998-12-08 | 2000-06-20 | Jgc Corp | ジメチルエーテルの製造装置及びその方法 |
DE19929281A1 (de) * | 1999-06-25 | 2000-12-28 | Basf Ag | Verfahren und Katalysator zur Herstellung von C¶2¶-Oxygenaten aus Synthesegas |
FR2806073B1 (fr) * | 2000-03-07 | 2002-06-07 | Air Liquide | Procede de production de monoxyde de carbone par retroconversion inverse avec un catalyseur adapte |
DE60100918T2 (de) | 2000-04-27 | 2004-05-13 | Haldor Topsoe A/S | Verfahren zur Herstellung eines wasserstoffreichen Gases |
US6692545B2 (en) | 2001-02-09 | 2004-02-17 | General Motors Corporation | Combined water gas shift reactor/carbon dioxide adsorber for use in a fuel cell system |
EP1572353A2 (en) * | 2002-12-20 | 2005-09-14 | Honda Giken Kogyo Kabushiki Kaisha | Platinum-ruthenium containing catalyst formulations for hydrogen generation |
ES2381105T3 (es) | 2003-02-05 | 2012-05-23 | Haldor Topsoe A/S | Procedimiento para el tratamiento de gas de síntesis |
US7022306B1 (en) * | 2003-03-21 | 2006-04-04 | Uop Llc | Process for the production of hydrogen |
KR100555294B1 (ko) * | 2003-09-17 | 2006-03-03 | 한국과학기술연구원 | 역수성가스 반응을 이용한 디메틸에테르의 제조방법 |
AU2006227505B2 (en) * | 2005-03-24 | 2011-05-19 | University Of Regina | Catalysts for hydrogen production |
-
2008
- 2008-04-23 WO PCT/EP2008/003258 patent/WO2008131898A1/en active Application Filing
- 2008-04-23 EA EA200901458A patent/EA016492B9/ru not_active IP Right Cessation
- 2008-04-23 CN CN200880013889XA patent/CN101678329B/zh not_active Expired - Fee Related
- 2008-04-23 JP JP2010504530A patent/JP5592250B2/ja not_active Expired - Fee Related
- 2008-04-23 US US12/450,818 patent/US8961829B2/en not_active Expired - Fee Related
- 2008-04-23 EP EP08735374.4A patent/EP2152409B1/en not_active Not-in-force
Also Published As
Publication number | Publication date |
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US8961829B2 (en) | 2015-02-24 |
JP2010525118A (ja) | 2010-07-22 |
WO2008131898A1 (en) | 2008-11-06 |
CN101678329A (zh) | 2010-03-24 |
EP2152409A1 (en) | 2010-02-17 |
EA016492B9 (ru) | 2012-07-30 |
EP2152409B1 (en) | 2016-06-29 |
EA200901458A1 (ru) | 2010-04-30 |
CN101678329B (zh) | 2013-09-18 |
EA016492B1 (ru) | 2012-05-30 |
US20100190874A1 (en) | 2010-07-29 |
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