EA016492B9 - Каталитическая конверсия диоксида углерода в смесь синтез-газа - Google Patents
Каталитическая конверсия диоксида углерода в смесь синтез-газаInfo
- Publication number
- EA016492B9 EA016492B9 EA200901458A EA200901458A EA016492B9 EA 016492 B9 EA016492 B9 EA 016492B9 EA 200901458 A EA200901458 A EA 200901458A EA 200901458 A EA200901458 A EA 200901458A EA 016492 B9 EA016492 B9 EA 016492B9
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- carbon dioxide
- syngas mixture
- catalyst
- catalytic hydrogenation
- stream
- Prior art date
Links
Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/38—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals
- B01J23/54—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of noble metals combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/56—Platinum group metals
- B01J23/64—Platinum group metals with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/656—Manganese, technetium or rhenium
- B01J23/6562—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/002—Mixed oxides other than spinels, e.g. perovskite
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/32—Manganese, technetium or rhenium
- B01J23/34—Manganese
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
- C01B3/02—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
- C01B3/06—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents
- C01B3/12—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide
- C01B3/16—Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen by reaction of inorganic compounds containing electro-positively bound hydrogen, e.g. water, acids, bases, ammonia, with inorganic reducing agents by reaction of water vapour with carbon monoxide using catalysts
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
- C01B32/00—Carbon; Compounds thereof
- C01B32/40—Carbon monoxide
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/76—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
- B01J23/84—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36 with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
- B01J23/889—Manganese, technetium or rhenium
- B01J23/8892—Manganese
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2523/00—Constitutive chemical elements of heterogeneous catalysts
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/141—Feedstock
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/50—Improvements relating to the production of bulk chemicals
- Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Inorganic Chemistry (AREA)
- General Health & Medical Sciences (AREA)
- Combustion & Propulsion (AREA)
- Health & Medical Sciences (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Catalysts (AREA)
- Industrial Gases (AREA)
- Hydrogen, Water And Hydrids (AREA)
Abstract
Изобретение относится к способу приготовления смеси синтез-газа, содержащей водород, монооксид углерода и диоксид углерода, содержащему этап контактирования исходной газообразной смеси, содержащей диоксид углерода и водород, с катализатором, при этом данный катализатор, по существу, состоит из оксида Mn и оксида по меньшей мере одного элемента, выбранного из группы, состоящей из Cr, Ni, La, Ce, W и Pt. Этот способ делает возможным гидрогенизацию диоксида углерода в монооксид углерода с высокой селективностью и хорошей стабильностью катализатора с течением времени и в условиях изменений рабочих режимов. Способ может применяться отдельно, но может также и объединяться с другими способами, как предшествующими ему, так и следующими за ним, такими как риформинг метана или другие процессы синтеза, предназначаемые для получения таких продуктов, как алканы, альдегиды или спирты.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
EP07008587 | 2007-04-27 | ||
PCT/EP2008/003258 WO2008131898A1 (en) | 2007-04-27 | 2008-04-23 | Catalytic hydrogenation of carbon dioxide into syngas mixture |
Publications (3)
Publication Number | Publication Date |
---|---|
EA200901458A1 EA200901458A1 (ru) | 2010-04-30 |
EA016492B1 EA016492B1 (ru) | 2012-05-30 |
EA016492B9 true EA016492B9 (ru) | 2012-07-30 |
Family
ID=38291211
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA200901458A EA016492B9 (ru) | 2007-04-27 | 2008-04-23 | Каталитическая конверсия диоксида углерода в смесь синтез-газа |
Country Status (6)
Country | Link |
---|---|
US (1) | US8961829B2 (ru) |
EP (1) | EP2152409B1 (ru) |
JP (1) | JP5592250B2 (ru) |
CN (1) | CN101678329B (ru) |
EA (1) | EA016492B9 (ru) |
WO (1) | WO2008131898A1 (ru) |
Families Citing this family (50)
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GB0814053D0 (en) * | 2008-08-01 | 2008-09-10 | Johnson Matthey Plc | Process |
JP5823873B2 (ja) * | 2008-12-17 | 2015-11-25 | サウディ ベーシック インダストリーズ コーポレイション | 合成ガス混合物中の一酸化炭素含有量を増加させるプロセス |
CN102513102A (zh) * | 2011-11-22 | 2012-06-27 | 北京化工大学 | 一种二氧化钛负载钌催化剂的制备方法及其应用 |
US8962702B2 (en) * | 2011-12-08 | 2015-02-24 | Saudi Basic Industries Corporation | Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use |
WO2013135662A1 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxidkatalysatoren |
WO2013135710A2 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren zur durchführung der rwgs-reaktion in einem rohrbündelreaktor |
WO2013135663A1 (de) | 2012-03-13 | 2013-09-19 | Bayer Intellectual Property Gmbh | Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxid-katalysatoren umfassend edelmetalle |
WO2013190500A2 (en) | 2012-06-21 | 2013-12-27 | Saudi Basic Industries Corporation | Process for producing a synthesis gas mixture |
US8551434B1 (en) | 2012-06-29 | 2013-10-08 | Saudi Basic Industries Corporation | Method of forming a syngas mixture |
WO2014070419A2 (en) * | 2012-10-31 | 2014-05-08 | Physical Shockwave Industrial Applications, Llc | Process and apparatus for supersonic collision shockwave reaction mechanism making chemical compounds |
CN103183346B (zh) * | 2012-12-13 | 2014-12-17 | 浙江海洋学院 | 一种逆水煤气变换催化剂用于逆水煤气变换反应的方法 |
EP2969188A1 (en) * | 2013-03-14 | 2016-01-20 | Johnson Matthey Public Limited Company | Cerium-modified manganese octahedral molecular sieves as catalysts for selective catalytic reduction |
CN105473495A (zh) | 2013-07-31 | 2016-04-06 | 沙特基础工业公司 | 通过基于费-托的合成产生烯烃的方法 |
EP3027716A2 (en) | 2013-07-31 | 2016-06-08 | Saudi Basic Industries Corporation | A process for the production of olefins through fischer-tropsch based synthesis |
JP2015044926A (ja) * | 2013-08-28 | 2015-03-12 | 独立行政法人産業技術総合研究所 | 炭化水素製造方法及び炭化水素製造装置 |
US9688593B2 (en) | 2013-10-29 | 2017-06-27 | Saudi Basic Industries Corporation | Method for carbon dioxide hydrogenation of syngas and the integration of the process with syngas conversion processes |
CN105593160A (zh) | 2013-11-11 | 2016-05-18 | 沙特基础工业公司 | 在绝热金属反应器中氢化co2的方法 |
WO2015103592A1 (en) | 2014-01-06 | 2015-07-09 | Saudi Basic Industries Corporation | Method for carbon dioxide hydrogenation of syngas |
WO2015153610A1 (en) | 2014-04-03 | 2015-10-08 | Saudi Basic Industries Corporation | Process for converting of methane stream reforming syngas with co2 |
CN105080564B (zh) * | 2014-05-14 | 2017-09-15 | 中国石油化工股份有限公司 | 用于二氧化碳转化制一氧化碳的催化剂及其使用方法 |
WO2017085594A2 (en) * | 2015-11-16 | 2017-05-26 | Sabic Global Technologies B.V. | Process and catalyst for conversion of co2 to syngas for a simultaneous production of olefins and methanol |
CN106881084B (zh) * | 2015-12-10 | 2019-04-30 | 中国科学院大连化学物理研究所 | 一种用于逆水煤气变换反应贵金属催化剂及其制备和应用 |
RU2632701C1 (ru) * | 2016-06-21 | 2017-10-09 | ФЕДЕРАЛЬНОЕ ГОСУДАРСТВЕННОЕ БЮДЖЕТНОЕ УЧРЕЖДЕНИЕ НАУКИ ИНСТИТУТ ОРГАНИЧЕСКОЙ ХИМИИ им. Н.Д. ЗЕЛИНСКОГО РОССИЙСКОЙ АКАДЕМИИ НАУК (ИОХ РАН) | Способ получения синтез-газа из CO2 |
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2008
- 2008-04-23 JP JP2010504530A patent/JP5592250B2/ja not_active Expired - Fee Related
- 2008-04-23 WO PCT/EP2008/003258 patent/WO2008131898A1/en active Application Filing
- 2008-04-23 EA EA200901458A patent/EA016492B9/ru not_active IP Right Cessation
- 2008-04-23 CN CN200880013889XA patent/CN101678329B/zh not_active Expired - Fee Related
- 2008-04-23 EP EP08735374.4A patent/EP2152409B1/en not_active Not-in-force
- 2008-04-23 US US12/450,818 patent/US8961829B2/en not_active Expired - Fee Related
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EA016492B1 (ru) | 2012-05-30 |
JP5592250B2 (ja) | 2014-09-17 |
EA200901458A1 (ru) | 2010-04-30 |
WO2008131898A1 (en) | 2008-11-06 |
JP2010525118A (ja) | 2010-07-22 |
US8961829B2 (en) | 2015-02-24 |
CN101678329B (zh) | 2013-09-18 |
EP2152409B1 (en) | 2016-06-29 |
EP2152409A1 (en) | 2010-02-17 |
CN101678329A (zh) | 2010-03-24 |
US20100190874A1 (en) | 2010-07-29 |
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