JP5548626B2 - ハロゲン非含有難燃剤 - Google Patents

ハロゲン非含有難燃剤 Download PDF

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Publication number
JP5548626B2
JP5548626B2 JP2010549047A JP2010549047A JP5548626B2 JP 5548626 B2 JP5548626 B2 JP 5548626B2 JP 2010549047 A JP2010549047 A JP 2010549047A JP 2010549047 A JP2010549047 A JP 2010549047A JP 5548626 B2 JP5548626 B2 JP 5548626B2
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Prior art keywords
polyester
polymer
phosphorus
polymer composition
polyamide
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English (en)
Japanese (ja)
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JP2011514925A (ja
Inventor
グロナー，ウド
ストーザー，ウーヴェ
ケラー，ホルガー
リッケルト，ホルスト
Original Assignee
シル・プリュス・ザイラッハー・ゲーエムベーハー
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/68—Polyesters containing atoms other than carbon, hydrogen and oxygen
    • C08G63/692—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus
    • C08G63/6924—Polyesters containing atoms other than carbon, hydrogen and oxygen containing phosphorus derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/6926—Dicarboxylic acids and dihydroxy compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/02—Polyamides derived from omega-amino carboxylic acids or from lactams thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L77/00—Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
    • C08L77/06—Polyamides derived from polyamines and polycarboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
    • C09K21/00—Fireproofing materials
    • C09K21/14—Macromolecular materials
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00—General methods for the manufacture of artificial filaments or the like
    • D01F1/02—Addition of substances to the spinning solution or to the melt
    • D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
    • D—TEXTILES; PAPER
    • D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/58—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products
    • D01F6/60—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from homopolycondensation products from polyamides
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00—Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12—Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16—Dicarboxylic acids and dihydroxy compounds
    • C08G63/20—Polyesters having been prepared in the presence of compounds having one reactive group or more than two reactive groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L67/00—Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
    • C08L67/02—Polyesters derived from dicarboxylic acids and dihydroxy compounds

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Medicinal Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Polymers & Plastics (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Materials Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Artificial Filaments (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polyesters Or Polycarbonates (AREA)
JP2010549047A 2008-03-06 2009-03-02 ハロゲン非含有難燃剤 Active JP5548626B2 (ja)

Applications Claiming Priority (3)

Application Number Priority Date Filing Date Title
DE102008012806A DE102008012806A1 (de) 2008-03-06 2008-03-06 Halogenfreie Flammschutzmittel
DE102008012806.6 2008-03-06
PCT/EP2009/001463 WO2009109347A1 (de) 2008-03-06 2009-03-02 Halogenfreie flammschutzmittel

Publications (2)

Publication Number Publication Date
JP2011514925A JP2011514925A (ja) 2011-05-12
JP5548626B2 true JP5548626B2 (ja) 2014-07-16

Family

ID=40777915

Family Applications (1)

Application Number Title Priority Date Filing Date
JP2010549047A Active JP5548626B2 (ja) 2008-03-06 2009-03-02 ハロゲン非含有難燃剤

Country Status (12)

Country Link
US (1) US8470916B2 (ko)
EP (1) EP2144950B1 (ko)
JP (1) JP5548626B2 (ko)
KR (1) KR101527618B1 (ko)
CN (1) CN101743266B (ko)
BR (1) BRPI0903493A2 (ko)
CA (1) CA2686542C (ko)
DE (1) DE102008012806A1 (ko)
ES (1) ES2502522T3 (ko)
SA (1) SA109300155B1 (ko)
TW (1) TWI447142B (ko)
WO (1) WO2009109347A1 (ko)

Families Citing this family (45)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE102009005967A1 (de) * 2009-01-23 2010-07-29 Domo Caproleuna Gmbh Licht- und wärmestabilisierte Polyamide und Verfahren zu ihrer Herstellung
DE102009055434A1 (de) * 2009-12-31 2011-07-07 Chemische Fabrik Budenheim KG, 55257 Flammenschutzmittelzusammensetzung für thermoplastische Formmassen
US8575295B2 (en) 2010-12-16 2013-11-05 Basf Se Glow-wire resistant polyamides
JP5940087B2 (ja) 2010-12-16 2016-06-29 ビーエーエスエフ ソシエタス・ヨーロピアＢａｓｆ Ｓｅ 耐グローワイヤ性ポリアミド
EP2532698B1 (de) * 2011-06-08 2016-04-20 Uhde Inventa-Fischer GmbH Verfahren und Vorrichtung zur direkten, kontinuierlichen Modifizierung von Polymerschmelzen
US20140329942A1 (en) * 2011-10-21 2014-11-06 Toyobo Co., Ltd. Flame-retardant resin composition and melt-molded body
EP2784119A4 (en) * 2011-11-24 2015-08-19 Kaneka Corp ELECTRONIC ELECTRONIC COMPONENT USING POLYESTER RESIN FLAME RETARDANT COMPOSITION
EP2597179B1 (de) 2011-11-24 2014-01-08 EMS-Patent AG Flammhemmende Polymerfasern und deren Verwendung sowie diese Polymerfasern enthaltendes Textilgewebe
DE102012204642A1 (de) * 2012-03-22 2013-09-26 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Phosphorhaltige ungesättigte Polyester, Polyesterharze und ggf. faserverstärkte Bauteile daraus
TWI457353B (zh) * 2012-05-08 2014-10-21 Ind Tech Res Inst 高分子、高分子混摻物、與阻燃材料
DE102012215510A1 (de) 2012-08-31 2014-05-28 Henkel Ag & Co. Kgaa Flammgeschützte Benzoxazin-haltige Zusammensetzung
CN104395430B (zh) * 2012-09-21 2017-10-27 国防研究与发展组织总指挥部 阻燃组合物、纤维、制备方法及其应用
CN103772434A (zh) * 2012-10-26 2014-05-07 常州市华润复合材料有限公司 反应型无卤阻燃剂的制备方法
CN103897353A (zh) * 2012-12-24 2014-07-02 杜邦公司 基于聚对苯二甲酸丙二醇酯的阻燃组合物
DE102013101487A1 (de) * 2013-02-14 2014-08-14 Chemische Fabrik Budenheim Kg Duromer, Herstellungsverfahren, Verwendung und Zusammensetzungen
CN104211954B (zh) * 2013-05-30 2016-10-05 辽宁银珠化纺集团有限公司 一种无卤阻燃尼龙66聚合物的制备方法
CN103467832B (zh) * 2013-06-03 2015-11-04 公安部四川消防研究所 耐低温柔性可交联无卤阻燃电缆料及其制备方法
CN103275605B (zh) * 2013-06-26 2015-06-03 兰州理工大学 含磷醇酸树脂饰面型防火涂料及其制备方法
DE202013103502U1 (de) 2013-08-05 2013-10-04 Carl Weiske Gmbh & Co.Kg Kunststoffzusammensetzung und diese enthaltende Fasern mit hoher Lichtechtheit und Flammbeständigkeit
CN103694468B (zh) * 2014-01-14 2016-03-16 株洲时代新材料科技股份有限公司 一种尼龙树脂及其制备方法
US11306414B2 (en) 2014-01-17 2022-04-19 Qed Labs Inc. Articles with improved flame retardancy and/or melt dripping properties
CN103819666B (zh) * 2014-02-20 2017-01-25 株洲时代新材料科技股份有限公司 一种高阻燃性尼龙树脂及其制备方法
US10407550B2 (en) 2014-08-14 2019-09-10 Hrl Laboratories, Llc Microlattice structures including flame retardant materials and compositions and methods for forming the same
KR101522697B1 (ko) * 2014-11-28 2015-05-26 주식회사 신아티앤씨 활성 에스터 인 변성 경화제 조성물, 활성 에스터 인 변성 경화제 및 이의 제조방법
CN104774344B (zh) * 2015-04-09 2017-06-30 上海工程技术大学 一种磷‑氮‑硅协效层状硅酸盐阻燃剂的制备方法
CN105040154B (zh) * 2015-07-22 2017-10-24 东华大学 一种阻燃聚酰胺66复合纤维及其制备方法
US10837131B2 (en) * 2016-11-17 2020-11-17 Drexel University Method to produce micro and nanofibers with controlled diameter and large yield
CN106750183A (zh) * 2016-12-06 2017-05-31 沈阳化工大学 一种dopo改性酸酐环氧树脂阻燃固化剂及其制备方法
KR20190134760A (ko) * 2017-04-25 2019-12-04 로디아 오퍼레이션스 난연성 중합체； 그의 제조 방법 및 그를 포함하는 열가소성 중합체 조성물
EP3476853A1 (en) * 2017-10-26 2019-05-01 Rhodia Operations Flame-retardant polymer; method for preparing it and thermoplastic polymer composition comprising it
CN107828055B (zh) * 2017-11-22 2019-10-01 浙江大学 一种含磷氮元素及具成炭功能的交联高分子阻燃剂及其制备方法和应用
DE102018100984A1 (de) 2018-01-17 2019-07-18 Chemische Fabrik Budenheim Kg Phosphorhaltige thermoplastische Polymere
CN109763193A (zh) * 2018-12-26 2019-05-17 澳帕曼安全织带(昆山)有限公司 一种阻燃增强涤纶丝、织带及制备方法
TWI697512B (zh) * 2019-01-18 2020-07-01 三晃股份有限公司 聚酯二醇、熱塑性聚胺基甲酸酯及其成型品
CN111607053B (zh) * 2019-02-26 2022-06-07 三晃股份有限公司 热塑性聚胺基甲酸酯及其成型品
CN110453499A (zh) * 2019-07-26 2019-11-15 温多利遮阳材料（德州）股份有限公司 阻燃聚丙烯复合纱线及其制品
CN112442072A (zh) * 2019-08-28 2021-03-05 广东广山新材料股份有限公司 一种带有羧酸或酸酐基团的反应型阻燃剂及其制备方法和应用
CN110528109B (zh) * 2019-08-28 2021-02-19 江苏索力得新材料集团有限公司 一种高强阻燃涤纶工业丝及其制备方法
CN110527140B (zh) * 2019-08-30 2021-04-06 苏州科技大学 一种含有环氧基团的磷阻燃剂及其制备方法
DE102019213793A1 (de) 2019-09-11 2021-03-11 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Phosphorhaltige Celluloseester, Verfahren zu ihrer Herstellung, Verwendung und Flammschutzmittel
US11396575B2 (en) 2019-09-19 2022-07-26 Sunko Ink Co., Ltd. Polyester polyol, thermoplastic polyurethane and article thereof
US11286327B2 (en) 2019-12-05 2022-03-29 The Boeing Company FR composite composition for light-based additive manufacturing
DE102019219029B4 (de) 2019-12-06 2022-04-07 Fraunhofer-Gesellschaft zur Förderung der angewandten Forschung e.V. Flammhemmendes Polymer umfassend phosphorhaltige Wiederholungseinheiten, Flammschutz- und Kunststoffzusammensetzung umfassend das flammhemmende Polymer, Verfahren zur Herstellung des flammhemmenden Polymers sowie dessen Verwendung
EP3858888A1 (en) 2020-01-29 2021-08-04 PolyTechnyl Polyamide composition comprising a flame retardant polyester and method for preparing it
DE102021002539A1 (de) 2021-05-14 2022-11-17 Schill + Seilacher Gmbh Verfahren zum Herstellen eines flammgeschützten Polyesters

Family Cites Families (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE2148348A1 (de) 1971-09-28 1973-04-05 Hoechst Ag Verwendung von roten phosphor enthaltenden polymeren zur herstellung von flammwidrigen faeden und fasern
US4127590A (en) 1975-10-14 1978-11-28 Toyo Boseki Kabushiki Kaisha Phosphorus-containing compounds
JPS5247891A (en) * 1975-10-14 1977-04-16 Toyobo Co Ltd Phosphorus-containing flame retarders
US4157436A (en) * 1975-10-14 1979-06-05 Toyo Boseki Kabushiki Kaisha Phosphorus-containing polyesters
JPS53128195A (en) 1977-04-15 1978-11-08 Sanko Kaihatsu Kagaku Kenkiyuu Flame retarder
JPS5912693B2 (ja) * 1978-05-24 1984-03-24 株式会社三光開発科学研究所 難燃剤
JPS62174228A (ja) * 1985-10-18 1987-07-31 Nippon Ester Co Ltd コポリエステル
DE4436079A1 (de) * 1994-10-10 1996-04-11 Hoechst Ag Verfahren zur Herstellung phosphorhaltiger Dicarbonsäuren
US5665801A (en) * 1995-06-20 1997-09-09 Industrial Technology Research Institute High molecular weight polyester flame retardant and process for preparing the same
US5530088A (en) * 1995-06-21 1996-06-25 Industrial Technology Research Institute Heat resistant phosphorus-containing polymeric flame retardant and process for preparing the same
JP2969259B2 (ja) * 1996-07-25 1999-11-02 三洋化成工業株式会社 繊維用処理剤
JPH1180340A (ja) * 1997-09-08 1999-03-26 Saito Kaseihin Kenkyusho:Kk 難燃性ポリエステルの製造方法
DE19933901A1 (de) * 1999-07-22 2001-02-01 Clariant Gmbh Flammschutzmittel-Kombination
US6245880B1 (en) * 1999-10-08 2001-06-12 Toyo Boseki Kabushiki Kaisha Organophosphorous composition, method of producing organophosphorous compound, polyester composition and method of producing the same
JP4272393B2 (ja) * 2002-08-07 2009-06-03 互応化学工業株式会社 水性難燃性ポリエステル樹脂の製造方法
JP4673626B2 (ja) * 2002-12-27 2011-04-20 ポリプラスチックス株式会社 難燃性樹脂組成物
JP2006524264A (ja) * 2003-01-06 2006-10-26 トーレイ プラスティクス（アメリカ），インコーポレイティド 難燃性ポリエステル樹脂組成物及びそれから形成された物品
JP3923441B2 (ja) * 2003-03-25 2007-05-30 三光株式会社 難燃性合成樹脂組成物
EP1614713A4 (en) * 2003-04-17 2008-01-02 Goo Chemical Co Ltd FLAME RETARDANT EPOXY RESIN COMPOSITION, PREIMPREGNES CONTAINING THE SAME, LAMINATES IN PLATES AND PRINTED CARDS
AU2003250753A1 (en) * 2003-06-18 2005-01-04 Thuringisches Institut Fur Textil- Und Kunststoff-Forschung E.V. Method for producing organic compounds containing poly-dopo, and the use of the same
EP1816153B1 (en) * 2004-11-24 2011-08-03 Toyo Boseki Kabushiki Kaisha Flame-retardant polyester and process for producing the same
DE102005015605B4 (de) 2005-04-05 2008-04-17 Schill + Seilacher "Struktol" Aktiengesellschaft Phosphororganische Verbindungen enthaltende Prepolymere und Verwendungen dafür
JP2007070481A (ja) * 2005-09-07 2007-03-22 Toyobo Co Ltd 接着剤組成物およびこれを用いてなるフレキシブルプリント配線基板
CN101108864A (zh) * 2006-07-19 2008-01-23 魏铭杉 9,10-二氢-9-氧杂-10-膦杂菲-10-氧化物及其衍生物的制备方法
CN1911941B (zh) * 2006-08-30 2010-12-29 上海化学试剂研究所 Dopo的制备方法
JP5115172B2 (ja) * 2007-12-13 2013-01-09 株式会社カネカ 樹脂組成物

Also Published As

Publication number Publication date
US20100181696A1 (en) 2010-07-22
EP2144950A1 (de) 2010-01-20
KR101527618B1 (ko) 2015-06-09
BRPI0903493A2 (pt) 2015-06-23
CA2686542C (en) 2016-04-26
US8470916B2 (en) 2013-06-25
KR20100119855A (ko) 2010-11-11
SA109300155B1 (ar) 2011-10-03
CA2686542A1 (en) 2009-09-11
CN101743266A (zh) 2010-06-16
DE102008012806A1 (de) 2009-09-10
WO2009109347A1 (de) 2009-09-11
ES2502522T3 (es) 2014-10-03
TWI447142B (zh) 2014-08-01
TW200944551A (en) 2009-11-01
JP2011514925A (ja) 2011-05-12
EP2144950B1 (de) 2014-08-13
CN101743266B (zh) 2012-08-01

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