JP4562070B2 - 粘着剤組成物、粘着シート類、および表面保護フィルム - Google Patents
粘着剤組成物、粘着シート類、および表面保護フィルム Download PDFInfo
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- JP4562070B2 JP4562070B2 JP2004145206A JP2004145206A JP4562070B2 JP 4562070 B2 JP4562070 B2 JP 4562070B2 JP 2004145206 A JP2004145206 A JP 2004145206A JP 2004145206 A JP2004145206 A JP 2004145206A JP 4562070 B2 JP4562070 B2 JP 4562070B2
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- sensitive adhesive
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- acrylic
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- 229920000909 polytetrahydrofuran Polymers 0.000 description 1
- 229920000123 polythiophene Polymers 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- ADYYRXNLCZOUSU-UHFFFAOYSA-M potassium;propan-2-ol;hydroxide Chemical compound [OH-].[K+].CC(C)O ADYYRXNLCZOUSU-UHFFFAOYSA-M 0.000 description 1
- 125000002924 primary amino group Chemical group [H]N([H])* 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- KRIOVPPHQSLHCZ-UHFFFAOYSA-N propiophenone Chemical class CCC(=O)C1=CC=CC=C1 KRIOVPPHQSLHCZ-UHFFFAOYSA-N 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 229920005604 random copolymer Polymers 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000011342 resin composition Substances 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 229920006012 semi-aromatic polyamide Polymers 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- 238000005118 spray pyrolysis Methods 0.000 description 1
- 238000004544 sputter deposition Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 150000003458 sulfonic acid derivatives Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 150000003467 sulfuric acid derivatives Chemical class 0.000 description 1
- 238000010557 suspension polymerization reaction Methods 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 238000003786 synthesis reaction Methods 0.000 description 1
- 125000001302 tertiary amino group Chemical group 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 1
- 239000011135 tin Substances 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 238000001771 vacuum deposition Methods 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 238000009736 wetting Methods 0.000 description 1
- 239000008096 xylene Substances 0.000 description 1
- 239000011787 zinc oxide Substances 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/04—Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2666/00—Composition of polymers characterized by a further compound in the blend, being organic macromolecular compounds, natural resins, waxes or and bituminous materials, non-macromolecular organic substances, inorganic substances or characterized by their function in the composition
- C08L2666/02—Organic macromolecular compounds, natural resins, waxes or and bituminous materials
- C08L2666/14—Macromolecular compounds according to C08L59/00 - C08L87/00; Derivatives thereof
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/40—Additional features of adhesives in the form of films or foils characterized by the presence of essential components
- C09J2301/408—Additional features of adhesives in the form of films or foils characterized by the presence of essential components additives as essential feature of the adhesive layer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Laminated Bodies (AREA)
Description
作製したポリマーの重量平均分子量は、GPC(ゲル・パーミエーション・クロマトグラフィー)により測定した。
カラム:
サンプルカラム;東ソー社製、TSKguardcolumn Super HZ−H(1本)+TSKgel Super HZM−H(2本)
リファレンスカラム;東ソー社製、TSKgel Super H−RC(1本)
流量:0.6ml /min
サンプル注入量:10μl
カラム温度:40℃
溶離液:THF
注入試料濃度:0.2重量%
検出器:示差屈折計
なお、重量平均分子量はポリスチレン換算により算出した。
ガラス転移温度Tg(℃)は、各モノマーによるホモポリマーのガラス転移温度Tgn(℃)として下記の文献値を用い、下記の式により求めた。
(式中、Tg(℃)は共重合体のガラス転移温度、Wn(−)は各モノマーの重量分率、Tgn(℃)は各モノマーによるホモポリマーのガラス転移温度、nは各モノマーの種類を表す。)
2−エチルヘキシルアクリレート:−70℃
イソノニルアクリレート:−82℃
ブチルアクリレート:−55℃
エチルアクリレート:−22℃
2−ヒドロキシエチルアクリレート:−15℃
アクリル酸:106℃
なお、文献値として「アクリル樹脂の合成・設計と新用途開発」(中央経営開発センター出版部発行)を参照した。
酸価は、自動滴定装置(平沼産業社製、COM−550)を用いて測定を行い、下記式より求めた。
A;酸価
Y;サンプル溶液の滴定量(ml)
X;混合溶媒50gのみの溶液の滴定量(ml)
f;滴定溶液のファクター
M;ポリマーサンプルの重量(g)
なお、測定条件は下記の通りである。
電極:ガラス電極;GE−101、比較電極;RE−201
測定モード:石油製品中和価試験1
表面保護フィルムを幅70mm、長さ130mmのサイズにカットし、セパレーターを剥離した後、あらかじめ除電しておいた厚み1mm、幅70mm、長さ100mmのアクリル板に貼り合わせた偏光板(日東電工社製、SEG1425EWVAGS2B、サイズ:幅70mm、長さ100mm)表面に片方の端部が30mmはみ出すようにハンドローラーにて圧着した。23℃×50%RHの環境下に一日放置した後、下記に示すように所定の位置にサンプルをセットした。30mmはみ出した片方の端部を自動巻取り機に固定し、剥離角度150°、剥離速度10m/minとなるように剥離した。このときに発生する偏光板表面の電位を、所定の位置に固定してある電位測定機(春日電機社製、KSD−0103)にて測定した。測定は、23℃×50%RHの環境下で行った。
作製した表面保護フィルムを、幅30mm、長さ80mmのサイズにカットし、セパレーターを剥離した後、偏光板(日東電工社製、SEG1425EWVAGS2B、サイズ:幅70mm、長さ100mm)にハンドローラーにて圧着した。23℃×50%RHの環境下に一日放置した後、表面保護フィルムをステンレス板から手で剥離し、その際のステンレス板表面の汚染の状態を目視にて観察した。評価基準は以下のとおりである。
汚染が認められた場合:×
厚み90μmのトリアセチルセルロースフィルム(富士写真フィルム社製、フジタック)を幅70mm、長さ100mmにカットし、60℃の水酸化ナトリウム水溶液(10重量%)に1分間浸漬した後、蒸留水にて洗浄し被着体を作製した。上記被着体を23℃×50%RHの環境下で1日放置した後、幅25mm、長さ100mmのサイズにカットした粘着シートを0.25MPaの圧力でラミネートし、評価サンプルを作製した。ラミネート後30分間放置した後、万能引張試験機にて剥離速度30m/分剥離角度180°で剥離したときの粘着力を測定した。測定は23℃×50%RHの環境下で行った。
〔アクリル系ポリマー(A)〕
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた四つ口フラスコに2−エチルヘキシルアクリレート200重量部、2−ヒドロキシエチルアクリレート8重量部、重合開始剤として2,2’−アゾビスイソブチロニトリル0.4重量部、酢酸エチル312重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を65℃付近に保って約6時間重合反応を行い、アクリル系ポリマー(A)溶液(40重量%)を調製した。前記アクリル系ポリマー(A)の重量平均分子量は50万、ガラス転移温度(Tg)は−68℃、酸価は0.0であった。
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた四つ口フラスコにイソノニルアクリレート200重量部、2−ヒドロキシエチルアクリレート8重量部、重合開始剤として2,2’−アゾビスイソブチロニトリル0.4重量部、酢酸エチル312重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を65℃付近に保って約6時間重合反応を行い、アクリル系ポリマー(B)溶液(40重量%)を調整した。前記アクリル系ポリマー(B)の重量平均分子量は54万、ガラス転移温度(Tg)は−80℃、酸価は0.0であった。
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた四つ口フラスコにブチルアクリレート200重量部、2−ヒドロキシエチルアクリレート8重量部、重合開始剤として2,2’−アゾビスイソブチロニトリル0.4重量部、酢酸エチル625重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を65℃付近に保って約6時間重合反応を行い、アクリル系ポリマー(C)溶液(25重量%)を調整した。前記アクリル系ポリマー(C)の重量平均分子量は55万、ガラス転移温度(Tg)は−54℃、酸価は0.0であった。
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた四つ口フラスコに2−エチルヘキシルアクリレート180重量部、エチルアクリレート20重量部、2−ヒドロキシエチルアクリレート8重量部、重合開始剤として2,2’−アゾビスイソブチロニトリル0.4重量部、酢酸エチル340重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を65℃付近に保って約6時間重合反応を行い、アクリル系ポリマー(D)溶液(38重量%)を調整した。前記アクリル系ポリマー(D)の重量平均分子量は65万、ガラス転移温度(Tg)は−64℃、酸価は0.0であった。
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた四つ口フラスコに2−エチルヘキシルアクリレート100重量部、エチルアクリレート100重量部、2−ヒドロキシエチルアクリレート8重量部、重合開始剤として2,2’−アゾビスイソブチロニトリル0.4重量部、酢酸エチル486重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を65℃付近に保って約6時間重合反応を行い、アクリル系ポリマー(E)溶液(30重量%)を調整した。前記アクリル系ポリマー(E)の重量平均分子量は62万、ガラス転移温度(Tg)は−47℃、酸価は0.0であった。
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた四つ口フラスコに2−エチルヘキシルアクリレート200重量部、アクリル酸8重量部、重合開始剤として2,2’−アゾビスイソブチロニトリル0.4重量部、酢酸エチル312重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を65℃付近に保って約6時間重合反応を行い、アクリル系ポリマー(F)溶液(40重量%)を調整した。前記アクリル系ポリマー(F)の重量平均分子量は54万、ガラス転移温度(Tg)は−66℃、酸価は29.5であった。
攪拌羽根、温度計、窒素ガス導入管、冷却器を備えた四つ口フラスコに2−エチルヘキシルアクリレート200重量部、2−ヒドロキシエチルアクリレート3.6重量部、アクリル酸0.4重量部、重合開始剤として2,2’−アゾビスイソブチロニトリル0.4重量部、酢酸エチル312重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を65℃付近に保って約6時間重合反応を行い、アクリル系ポリマー(G)溶液(40重量%)を調整した。前記アクリル系ポリマー(G)の重量平均分子量は56万、ガラス転移温度(Tg)は−66℃、酸価は1.3であった。
〔帯電防止剤溶液(a)〕
攪拌羽根、温度計、冷却器を備えた四つ口フラスコにヨウ化リチウム0.1重量部、ポリプロピレングリコール(ジオール型、数平均分子量2000)9.9重量部、酢酸エチル10重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を80℃付近に保って約2時間混合撹拌を行い、帯電防止剤溶液(a)(50重量%)を調製した。
攪拌羽根、温度計、冷却器を備えた四つ口フラスコに過塩素酸リチウム0.1重量部、ポリプロピレングリコール(ジオール型、数平均分子量2000)9.9重量部、酢酸エチル10重量部を仕込み、緩やかに攪拌しながら窒素ガスを導入し、フラスコ内の液温を80℃付近に保って約2時間混合撹拌を行い、帯電防止剤溶液(b)(50重量%)を調製した。
帯電防止剤(ソルベックス社製、マイクロソルバーRMd−142、主成分:酸化スズおよびポリエステル樹脂)10重量部を、水30重量部とメタノール70重量部からなる混合溶媒で希釈することにより帯電防止剤溶液を調整した。得られた前記帯電防止剤溶液を、ポリエチレンテレフタレート(PET)フィルム(厚さ38μm)上にマイヤーバーを用いて塗布し、130℃で1分間乾燥することにより溶剤を除去して帯電防止層(厚さ0.2μm)を形成し、帯電防止処理ポリエチレンテレフタレートフィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系ポリマー(A)溶液(40重量%)を酢酸エチルで20重量%に希釈し、この溶液100重量部に上記帯電防止剤溶液(a)(50重量%)2.6重量部、架橋剤としてヘキサメチレンジイソシアネートのイソシアヌレート体(日本ポリウレタン工業社製、コロネートHX)0.6重量部、架橋触媒としてジラウリン酸ジブチルスズ(1重量%酢酸エチル溶液)0.4重量部を加えて25℃付近に保って約1分間混合撹拌を行い、アクリル系粘着剤溶液(1)を調製した。なお、アクリル系粘着剤溶液(1)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.065重量部であった。
上記アクリル系粘着剤溶液(1)を、上述のように作製した帯電防止処理ポリエチレンテレフタレートフィルムの帯電防止処理面とは反対の面に塗布し、110℃で3分間加熱して、厚さ20μmの粘着剤層を形成した。次いで、上記粘着剤層の表面に、片面にシリコーン処理を施したポリエチレンテレフタレートフィルム(厚さ25μm)のシリコーン処理面を貼合せ、保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系粘着剤溶液(A)(40重量%)を酢酸エチルで20重量%に希釈した溶液100重量部に代えて、上記アクリル系粘着剤溶液(B)(40重量%)を酢酸エチルで20重量%に希釈した溶液100重量部を用いた以外は、実施例1と同様の方法によりアクリル系粘着剤溶液(2)を調製した。なお、アクリル系粘着剤溶液(2)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.065重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、上記アクリル系粘着剤溶液(2)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系ポリマー(A)溶液(40重量%)を酢酸エチルで20重量%に希釈し、この溶液100重量部に上記帯電防止剤溶液(b)(50重量%)1.6重量部、架橋剤としてヘキサメチレンジイソシアネートのイソシアヌレート体(日本ポリウレタン工業社製、コロネートHX)0.4重量部、架橋触媒としてジラウリン酸ジブチルスズ(1重量%酢酸エチル溶液)0.4重量部を加えて25℃付近に保って約1分間混合撹拌を行い、アクリル系粘着剤溶液(3)を調製した。なお、アクリル系粘着剤溶液(1)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.040重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、上記アクリル系粘着剤溶液(3)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系粘着剤溶液(A)(40重量%)を酢酸エチルで20重量%に希釈した溶液100重量部に代えて、上記アクリル系粘着剤溶液(C)(25重量%)を酢酸エチルで20重量%に希釈した溶液100重量部を用いた以外は、実施例1と同様の方法によりアクリル系粘着剤溶液(4)を調製した。なお、アクリル系粘着剤溶液(4)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.065重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、前記アクリル系粘着剤溶液(4)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系ポリマー(D)溶液(38重量%)を酢酸エチルで20重量%に希釈し、この溶液100重量部に上記帯電防止剤溶液(b)(50重量%)2.6重量部、架橋剤としてヘキサメチレンジイソシアネートのイソシアヌレート体(日本ポリウレタン工業社製、コロネートHX)0.4重量部、架橋触媒としてジラウリン酸ジブチルスズ(1重量%酢酸エチル溶液)0.4重量部を加えて25℃付近に保って約1分間混合撹拌を行い、アクリル系粘着剤溶液(5)を調製した。なお、アクリル系粘着剤溶液(1)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.065重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、前記アクリル系粘着剤溶液(5)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系粘着剤溶液(D)(38重量%)を酢酸エチルで20重量%に希釈した溶液100重量部に代えて、上記アクリル系粘着剤溶液(E)(30重量%)を酢酸エチルで20重量%に希釈した溶液100重量部を用いた以外は、比較例2と同様の方法によりアクリル系粘着剤溶液(6)を調製した。なお、アクリル系粘着剤溶液(6)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.065重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、上記アクリル系粘着剤溶液(6)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系ポリマー(F)溶液(40重量%)を酢酸エチルで20重量%に希釈し、この溶液100重量部に上記帯電防止剤溶液(a)(50重量%)2.6重量部、架橋剤として1,3−ビス(N,N−ジグリシジルアミノメチル)シクロヘキサン(三菱瓦斯化学社製、TETRAD−C)0.8重量部、トリメチロールプロパン/トリレンジイソシアネート3量体付加物(日本ポリウレタン工業社製、コロネートL)0.3重量部を加えて25℃付近に保って約1分間混合撹拌を行い、アクリル系粘着剤溶液(7)を調製した。なお、アクリル系粘着剤溶液(7)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.065重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、前記アクリル系粘着剤溶液(7)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記アクリル系粘着剤溶液(A)(40重量%)を酢酸エチルで20重量%に希釈した溶液100重量部に代えて、上記アクリル系粘着剤溶液(G)(40重量%)を酢酸エチルで20重量%に希釈した溶液100重量部を用いた以外は、実施例1と同様の方法によりアクリル系粘着剤溶液(8)を調製した。なお、アクリル系粘着剤溶液(8)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.065重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、上記アクリル系粘着剤溶液(8)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
〔粘着剤溶液の調製〕
上記帯電防止剤溶液(a)(50重量%)2.6重量部に代えて、上記帯電防止剤溶液(a)(50重量%)4.0重量部を用いた以外は、実施例1と同様の方法によりアクリル系粘着剤溶液(9)を調製した。なお、アクリル系粘着剤溶液(9)においては、アクリル系ポリマー100重量部に対するアルカリ金属塩(リチウム塩)の配合量は0.10重量部であった。
上記アクリル系粘着剤溶液(1)に代えて、上記アクリル系粘着剤溶液(9)を用いた以外は、実施例1と同様の方法により保護フィルムを作製した。
Claims (7)
- 単量体成分として、炭素数6〜14であるアルキル基を有する(メタ)アクリル系モノマーを50重量%以上含有する(メタ)アクリル系ポリマー、ならびにポリエーテルポリオール化合物およびアルカリ金属塩を含む粘着剤組成物において、
前記(メタ)アクリル系ポリマーを構成する単量体成分中、炭素数6未満のアルキル基を有する(メタ)アクリル系モノマーを含有せず、
前記(メタ)アクリル系ポリマーの酸価が1.0以下であり、
前記(メタ)アクリル系ポリマー100重量部に対し、前記アルカリ金属塩0.1重量部未満を含有してなることを特徴とする粘着剤組成物。 - 前記アルカリ金属塩がリチウム塩であることを特徴とする請求項1に記載の粘着剤組成物。
- 前記(メタ)アクリル系ポリマーが、ヒドロキシル基を有する(メタ)アクリル系モノマーをさらに構成成分として含むことを特徴とする請求項1〜2のいずれかに記載の粘着剤組成物。
- 前記粘着剤組成物に架橋剤としてイソシアネート化合物のイソシアヌレート変性体を含むことを特徴とする請求項1〜3のいずれかに記載の粘着剤組成物。
- 請求項1〜4のいずれかに記載の粘着剤組成物を架橋してなる粘着剤層。
- 請求項1〜4のいずれかに記載の粘着剤組成物を架橋してなる粘着剤層を支持体上の片面または両面に形成してなることを特徴とする粘着シート類。
- 請求項1〜4のいずれかに記載の粘着剤組成物を架橋してなる粘着剤層を、帯電防止処理されてなるプラスチック基材からなる支持体上の片面または両面に形成してなることを特徴とする表面保護フィルム。
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TW094114364A TWI332025B (en) | 2004-05-14 | 2005-05-04 | Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets, and surface protecting film |
EP05010330A EP1595929B1 (en) | 2004-05-14 | 2005-05-12 | Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets, and surface protecting film |
KR1020050039817A KR101022079B1 (ko) | 2004-05-14 | 2005-05-12 | 점착제 조성물, 점착 시이트 및 표면 보호 필름 |
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US11/128,489 US20050256251A1 (en) | 2004-05-14 | 2005-05-13 | Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets, and surface protecting film |
CNB2005100728700A CN100572482C (zh) | 2004-05-14 | 2005-05-16 | 粘合剂组合物、粘合片类以及表面保护薄膜 |
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Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011202176A (ja) * | 2004-09-16 | 2011-10-13 | Nitto Denko Corp | 粘着剤組成物、粘着シート類、および表面保護フィルム |
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Families Citing this family (44)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US7691925B2 (en) | 2004-03-08 | 2010-04-06 | Nitto Denko Corporation | Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheets and surface protecting film |
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JP2011168751A (ja) * | 2010-02-22 | 2011-09-01 | Nitto Denko Corp | 表面保護フィルム |
EP2562228A4 (en) * | 2010-04-20 | 2014-01-15 | Nitto Denko Corp | WATER DISPERSIBLE ACRYLIC ADHESIVE COMPOSITION AND ADHESIVE FILM THEREOF |
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JP5982131B2 (ja) * | 2011-02-28 | 2016-08-31 | 日東電工株式会社 | 電池用粘着テープ、及び該粘着テープを使用した電池 |
KR101781645B1 (ko) * | 2011-04-20 | 2017-09-25 | 닛토덴코 가부시키가이샤 | 전기 화학 디바이스용 점착 테이프 |
JP5774375B2 (ja) * | 2011-05-23 | 2015-09-09 | 日東電工株式会社 | 粘着フィルム |
KR101910921B1 (ko) * | 2012-02-23 | 2018-10-24 | 다우 코닝 타이완 인코포레이티드 | 감압 접착 시트 및 이의 제조 방법 |
JP6081233B2 (ja) * | 2012-03-16 | 2017-02-15 | 日東電工株式会社 | 粘着剤組成物、及び、粘着シート |
JP6267854B2 (ja) * | 2012-04-06 | 2018-01-24 | 日東電工株式会社 | 粘着剤組成物、粘着シート、及び光学部材 |
KR101534899B1 (ko) * | 2012-06-21 | 2015-07-07 | (주)엘지하우시스 | Uv경화형 고무를 포함하는 점착제 조성물 및 이를 사용하는 보호필름 |
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JP6251687B2 (ja) * | 2012-12-19 | 2017-12-20 | 昭和電工株式会社 | 光学フィルム用粘着剤組成物及び表面保護フィルム |
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JP6538432B2 (ja) * | 2014-09-01 | 2019-07-03 | 日東電工株式会社 | 透明導電性フィルム用キャリアフィルム及び積層体 |
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JP6943732B2 (ja) * | 2017-11-14 | 2021-10-06 | 日本カーバイド工業株式会社 | 保護フィルム用粘着剤組成物及び保護フィルム |
KR102181892B1 (ko) * | 2019-02-20 | 2020-11-24 | 도레이첨단소재 주식회사 | 광학용 폴리에스테르 필름 |
CN110607146B (zh) * | 2019-09-18 | 2021-03-12 | 广东东立新材料科技股份有限公司 | 用于pet保护膜的压敏胶及其制备方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000044912A (ja) * | 1998-07-28 | 2000-02-15 | Ipposha Oil Ind Co Ltd | 粘着剤組成物 |
JP2000129235A (ja) * | 1998-10-27 | 2000-05-09 | Minnesota Mining & Mfg Co <3M> | 帯電防止性粘着剤組成物 |
JP2005298569A (ja) * | 2004-04-07 | 2005-10-27 | Nitto Denko Corp | 粘着剤組成物、およびそれを用いてなる粘着シート類 |
JP2006111856A (ja) * | 2004-09-16 | 2006-04-27 | Nitto Denko Corp | 粘着剤組成物、粘着シート類、および表面保護フィルム |
JP2007536427A (ja) * | 2004-08-24 | 2007-12-13 | エルジー・ケム・リミテッド | 帯電防止性能を有するアクリル系粘着剤組成物 |
Family Cites Families (34)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2929835A (en) * | 1957-06-06 | 1960-03-22 | Firestone Tire & Rubber Co | Reacting an alkylene oxide with an acrylic-type acid using an alkaline organic or inorganic catalyst |
JPS581711B2 (ja) * | 1979-08-11 | 1983-01-12 | 日東電工株式会社 | 感圧接着剤組成物 |
US4668730A (en) * | 1985-08-05 | 1987-05-26 | National Starch And Chemical Corp. | Colloid stabilized latex adhesives |
US4918211A (en) * | 1986-12-12 | 1990-04-17 | Dai-Ichi Kogyo Seiyaku Co., Ltd. | Surface active compounds having a polymerizable moiety |
US5635564A (en) * | 1988-12-09 | 1997-06-03 | Basf Lacke + Farben, Ag | Preparation of a multicoat coating, water-thinnable coating compositions, water-thinnable emulsion polymers and preparation of water-thinnable emulsion polymers |
US4968558A (en) * | 1989-11-02 | 1990-11-06 | Nalco Chemical Company | Ultraviolet radiation photopolymerization of acrylic ester pressure sensitive adhesive formulation |
JPH03183545A (ja) * | 1989-12-14 | 1991-08-09 | Teijin Ltd | 制電易接着性フイルム、その製造方法及びそれを用いた磁気カード |
DE4039780C1 (ja) * | 1990-12-13 | 1992-08-06 | Lohmann Gmbh & Co Kg, 5450 Neuwied, De | |
DE69309795T2 (de) * | 1992-07-10 | 1997-11-27 | Nippon Catalytic Chem Ind | Acrylat Polymer, seine Verwendung und Verfahren zu seiner Herstellung |
JP3190743B2 (ja) * | 1992-10-14 | 2001-07-23 | 日東電工株式会社 | 粘着テープまたはシート |
US5508107A (en) * | 1993-07-28 | 1996-04-16 | Minnesota Mining And Manufacturing Company | Pressure-sensitive adhesive tapes for electronics applications |
US5670557A (en) * | 1994-01-28 | 1997-09-23 | Minnesota Mining And Manufacturing Company | Polymerized microemulsion pressure sensitive adhesive compositions and methods of preparing and using same |
US5914186A (en) * | 1994-05-06 | 1999-06-22 | Minnesota Mining And Manufacturing Company | High temperature resistant antistatic pressure-sensitive adhesive tape |
US5614310A (en) * | 1994-11-04 | 1997-03-25 | Minnesota Mining And Manufacturing Company | Low trauma wound dressing with improved moisture vapor permeability |
US5721313A (en) * | 1995-11-02 | 1998-02-24 | Rhone-Poulenc Inc. | Crosslinked polymer composition |
US5985990A (en) * | 1995-12-29 | 1999-11-16 | 3M Innovative Properties Company | Use of pendant free-radically polymerizable moieties with polar polymers to prepare hydrophilic pressure sensitive adhesive compositions |
US5885708A (en) * | 1997-02-14 | 1999-03-23 | Minnesota Mining And Manufacturing Company | Antistatic latex adhesives |
JP4531883B2 (ja) * | 1999-03-25 | 2010-08-25 | リンテック株式会社 | 帯電防止性粘着シート |
ID28481A (id) * | 1999-11-30 | 2001-05-31 | Takeda Chemical Industries Ltd | Komposisi emulsi berair dan komposisi bahan perekat |
JP5135494B2 (ja) * | 1999-12-22 | 2013-02-06 | 綜研化学株式会社 | アクリル系粘着テープおよびその製造方法 |
DE10111792A1 (de) * | 2001-03-12 | 2002-09-26 | Borchers Gmbh | Neue Polyurethane und ihre Verwendung zur Verdickung wässriger Systeme |
JP2003147325A (ja) * | 2001-11-14 | 2003-05-21 | Nitto Denko Corp | 表面変性粘着剤および粘着剤の表面変性方法並びに粘着テープ又はシート |
JP4151838B2 (ja) * | 2003-01-27 | 2008-09-17 | 日東電工株式会社 | 光学用保護テープ |
US7038746B2 (en) * | 2003-03-31 | 2006-05-02 | Sumitomo Chemical Company, Limited | Laminated polarizing film |
JP4686960B2 (ja) * | 2003-06-30 | 2011-05-25 | 綜研化学株式会社 | 表面保護フィルム用粘着剤および表面保護フィルム |
US7045414B2 (en) * | 2003-11-26 | 2006-05-16 | Taiwan Semiconductor Manufacturing Company, Ltd. | Method of fabricating high voltage transistor |
JP2005314579A (ja) * | 2004-04-30 | 2005-11-10 | Nitto Denko Corp | 粘着剤組成物、および粘着シート類 |
TW200617124A (en) * | 2004-06-01 | 2006-06-01 | Nitto Denko Corp | Pressure-sensitive adhesive composition, pressure-sensitive adhesive sheet and surface protecting film |
JP4917267B2 (ja) * | 2004-09-16 | 2012-04-18 | 日東電工株式会社 | 粘着剤組成物、粘着シート類、および表面保護フィルム |
KR100784991B1 (ko) * | 2005-06-10 | 2007-12-11 | 주식회사 엘지화학 | 아크릴계 점착제 조성물 |
JP5259940B2 (ja) * | 2005-09-05 | 2013-08-07 | 日東電工株式会社 | 粘着剤組成物、粘着シートおよび表面保護フィルム |
US7799853B2 (en) * | 2005-09-05 | 2010-09-21 | Nitto Denko Corporation | Adhesive composition, adhesive sheet, and surface protective film |
JP4814000B2 (ja) * | 2006-07-26 | 2011-11-09 | リンテック株式会社 | 光学機能性フィルム貼合用粘着剤、光学機能性フィルム及びその製造方法 |
JP5623020B2 (ja) * | 2009-02-27 | 2014-11-12 | 日東電工株式会社 | 粘着剤組成物、粘着剤層、及び、粘着シート |
-
2004
- 2004-05-14 JP JP2004145206A patent/JP4562070B2/ja not_active Expired - Lifetime
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- 2005-05-12 KR KR1020050039817A patent/KR101022079B1/ko active IP Right Grant
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- 2005-05-12 EP EP05010330A patent/EP1595929B1/en active Active
- 2005-05-13 US US11/128,489 patent/US20050256251A1/en not_active Abandoned
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-
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- 2010-11-11 KR KR1020100112172A patent/KR101085761B1/ko active IP Right Grant
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2000044912A (ja) * | 1998-07-28 | 2000-02-15 | Ipposha Oil Ind Co Ltd | 粘着剤組成物 |
JP2000129235A (ja) * | 1998-10-27 | 2000-05-09 | Minnesota Mining & Mfg Co <3M> | 帯電防止性粘着剤組成物 |
JP2005298569A (ja) * | 2004-04-07 | 2005-10-27 | Nitto Denko Corp | 粘着剤組成物、およびそれを用いてなる粘着シート類 |
JP2007536427A (ja) * | 2004-08-24 | 2007-12-13 | エルジー・ケム・リミテッド | 帯電防止性能を有するアクリル系粘着剤組成物 |
JP2006111856A (ja) * | 2004-09-16 | 2006-04-27 | Nitto Denko Corp | 粘着剤組成物、粘着シート類、および表面保護フィルム |
Cited By (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011202176A (ja) * | 2004-09-16 | 2011-10-13 | Nitto Denko Corp | 粘着剤組成物、粘着シート類、および表面保護フィルム |
US9328264B2 (en) | 2009-02-27 | 2016-05-03 | Nitto Denko Corporation | Pressure-sensitive adhesive composition, pressure-sensitive adhesive layer, and pressure-sensitive adhesive sheet |
Also Published As
Publication number | Publication date |
---|---|
TWI332025B (en) | 2010-10-21 |
CN100572482C (zh) | 2009-12-23 |
KR101085761B1 (ko) | 2011-11-21 |
EP1595929B1 (en) | 2007-04-18 |
KR20100138855A (ko) | 2010-12-31 |
TW200538527A (en) | 2005-12-01 |
CN1696230A (zh) | 2005-11-16 |
DE602005000905T2 (de) | 2008-01-17 |
US20050256251A1 (en) | 2005-11-17 |
KR20060047825A (ko) | 2006-05-18 |
DE602005000905D1 (de) | 2007-05-31 |
JP2005325255A (ja) | 2005-11-24 |
KR101022079B1 (ko) | 2011-03-17 |
EP1595929A1 (en) | 2005-11-16 |
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