JP2019123782A - 耐スクラッチ性を有するフィルム及び表面コーティング組成物 - Google Patents
耐スクラッチ性を有するフィルム及び表面コーティング組成物 Download PDFInfo
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- JP2019123782A JP2019123782A JP2018004034A JP2018004034A JP2019123782A JP 2019123782 A JP2019123782 A JP 2019123782A JP 2018004034 A JP2018004034 A JP 2018004034A JP 2018004034 A JP2018004034 A JP 2018004034A JP 2019123782 A JP2019123782 A JP 2019123782A
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- film
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- urethane resin
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Abstract
Description
厚み80μmのポリ塩化ビニルフィルムにポリエチレンテレフタレート(PET)フィルムを予め加熱ラミネートして透明樹脂基材層を得た。ポリ塩化ビニルフィルムの組成は、ポリ塩化ビニル/エステル系可塑剤/有機系安定剤(アクリル樹脂、ステアリン酸亜鉛等)=72/16/12(質量比)であった。PETフィルムはテイジン(登録商標)テトロン(登録商標)フィルムG2 50μm厚(帝人フィルムソリューション株式会社、日本国東京都千代田区)であった。
ウレタン樹脂ビーズ、アルミナ球状粒子、ナノシリカ粒子及びバインダー樹脂を含む、表2に示す組成の混合液を自公転型遠心撹拌機THINKY AR−250(株式会社シンキー、日本国東京都千代田区)を用いて3.5分間撹拌して表面コーティング組成物を得た。表面コーティング組成物を、透明樹脂基材層のポリ塩化ビニルフィルム上にナイフコーターを用いギャップを60μmとして塗布し、温度65℃のオーブンで2分間、温度120℃のオーブンで5分間乾燥及び熱硬化させて、乾燥厚み約30μmの表面層を形成した。透明樹脂基材層からPETフィルムを剥離し、表面層を有するポリ塩化ビニルフィルムと、厚み80μmの黒色ポリ塩化ビニルフィルム(ポリ塩化ビニル/エステル系可塑剤/有機系安定剤、顔料等(アクリル樹脂、ステアリン酸亜鉛、カーボンブラック等)=72/16/12(質量比))と積層し、加熱加工ロールによりライン速度7m/分、ニップ圧力0.2MPa、温度60℃の条件で押圧してフィルムを得た。
ウレタン樹脂ビーズとアルミナ球状粒子の合計配合量を変化させずに、ウレタン樹脂ビーズとアルミナ球状粒子との質量比を表2に記載のとおり変更した以外は例1と同様にして表面コーティング組成物を調製し、フィルムを得た。
ウレタン樹脂ビーズとアルミナ球状粒子の質量比を変更せずに、バインダーに対するウレタン樹脂ビーズ及びアルミナ球状粒子の質量比を表2に記載のとおり変更して、例1と同様に表面コーティング組成物を調製し、フィルムを得た。
アルミナ球状粒子の平均粒径を変更した以外は例1と同様にして表面コーティング組成物を調製し、フィルムを得た。
ウレタン樹脂ビーズの平均粒径を変更した以外は例1と同様にして表面コーティング組成物を調製し、フィルムを得た。
バインダーに対するナノシリカ粒子の質量比、及びそれに伴ってバインダーに対するウレタン樹脂ビーズ及びアルミナ球状粒子の質量比を表2に記載のとおり変更して、例1と同様に表面コーティング組成物を調製し、フィルムを得た。
ウレタン樹脂ビーズを使用せずに表2に記載の配合で例1と同様に表面コーティング組成物を調製し、フィルムを得た。
アルミナ球状粒子を使用せずに表2に記載の配合で例1と同様に表面コーティング組成物を調製し、フィルムを得た。
ウレタン樹脂ビーズとアルミナ球状粒子の質量比を変更せずに、バインダーに対するウレタン樹脂ビーズ及びアルミナ球状粒子の質量比を表2に記載のとおり変更して、例1と同様に表面コーティング組成物を調製し、フィルムを得た。
アルミナ球状粒子の平均粒径を変更した以外は例1と同様にして表面コーティング組成物を調製し、フィルムを得た。
ウレタン樹脂ビーズの平均粒径を変更した以外は例1と同様にして表面コーティング組成物を調製し、フィルムを得た。
ウレタン樹脂ビーズをアクリル樹脂ビーズに変更した以外は例1と同様にして表面コーティング組成物を調製し、フィルムを得た。
ナノシリカ粒子を使用せずに表2に記載の配合で例1と同様に表面コーティング組成物を調製し、フィルムを得た。
バインダーに対するナノシリカ粒子の質量比、及びそれに伴ってバインダーに対するウレタン樹脂ビーズ及びアルミナ球状粒子の質量比を表2に記載のとおり変更して、例1と同様に表面コーティング組成物を調製し、フィルムを得た。
ウレタン樹脂ビーズ及びナノシリカ粒子を使用せずに表2に記載の配合で例1と同様に表面コーティング組成物を調製し、フィルムを得た。
携帯型光沢計BYKガードナー・マイクロ−トリ−グロス(ビックケミー・ジャパン株式会社、日本国東京都新宿区)を用いて、表面層の光沢度を測定角20°/60°/85°にて測定した。光沢度が60°で5.5GU以下である場合、実用的な低光沢条件を充たすと評価できる。また、測定角20°で0.6GU以下、60°で5.5GU以下、85°で6.5GU以下の3つを満たす場合、良好な低光沢表面外観を示すと評価できる。
分光測色計CM−3700d(コニカミノルタジャパン株式会社、日本国東京都港区)を用いて光源D65/10°、正反射処理SCI、UV反射0%にて明度L*値の測定を行った。明度L*値が27以下の場合、表面が低光沢で良好な明度を示すものと評価できる。
150mm×50mmに予めカットしたサンプルを端から25mmの位置で両端をチャックに固定し、測定長を100mmとして、テンシロン万能試験機RTC−1210A(株式会社エー・アンド・デイ、日本国東京都豊島区)を用いて温度20℃、相対湿度60%の環境下で100mm/分の速度で150%伸長した。伸長後のサンプルの表面測色を行った。フィルムの伸長前の明度をL* 1、150%伸長後の明度をL* 2、明度差をΔL*=L* 2−L* 1としたときの明度差ΔL*を計算した。明度差ΔL*が5.5以下である場合、伸長による低光沢性の損失(白化)が少ないと評価できる。
JIS K5600−5−4:1999に準拠した鉛筆硬度試験機器を用い、荷重1.7kg、鉛筆硬度9Hの条件で、耐スクラッチ性を評価した。フィルム表面を引っかいた後、表面層の凝集破壊による損傷が、初期領域(長さ10mm)を除いて50%以下観察された場合を良好、50%以上観察された場合を不良とした。
10 表面層
12 バインダー
14 ウレタン樹脂ビーズ
16 硬質粒子
18 ナノシリカ粒子
20 基材層
Claims (23)
- ウレタン樹脂を含むバインダーと、
3μm以上、30μm以下の平均粒径を有するウレタン樹脂ビーズと、
5μm以上、45μm以下の平均粒径を有する硬質粒子と、
ナノシリカ粒子と
を含む表面層を有する耐スクラッチ性を有するフィルムであって、
前記表面層が、前記バインダー100質量部を基準として、前記硬質粒子を30質量部以上、500質量部以下含み、前記表面層の光沢度が60度で5.5GU以下である、耐スクラッチ性を有するフィルム。 - 前記ナノシリカ粒子の平均粒径が10nm以上、100nm以下である、請求項1に記載の耐スクラッチ性を有するフィルム。
- 前記表面層が、前記バインダー100質量部を基準として、前記ウレタン樹脂ビーズを13質量部以上、120質量部以下含む、請求項1又は2のいずれかに記載の耐スクラッチ性を有するフィルム。
- 前記表面層が、前記バインダー100質量部を基準として、前記ナノシリカ粒子を30質量部以上、500質量部以下含む、請求項1〜3のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 前記硬質粒子がアルミナビーズを含む、請求項1〜4のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 前記耐スクラッチ性を有するフィルムの伸長前の明度をL* 1、150%伸長後の明度をL* 2、明度差をΔL*=L* 2−L* 1としたときに、明度差ΔL*が5.5以下である、請求項1〜5のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 前記表面層の光沢度が、20度で0.6GU以下、60度で5.5GU以下、85度で7GU以下である、請求項1〜6のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 前記バインダーがセルロースエステルをさらに含む、請求項1〜7のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 前記ウレタン樹脂が2液型ウレタン樹脂組成物の硬化物を含む、請求項1〜8のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 前記表面層がイソシアネート又は水酸基と反応可能な官能基を有するシリコーン変性ポリマーをさらに含む、請求項1〜9のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 伸長可能な基材層をさらに含む、請求項1〜10のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 前記基材層が、有色又は無色であり、不透明、半透明又は透明であり、略平滑な表面又は構造化表面を有する、請求項11に記載の耐スクラッチ性を有するフィルム。
- 前記基材層が、ポリ塩化ビニル、ポリウレタン、ポリエチレン、ポリプロピレン、塩化ビニル−酢酸ビニル樹脂、アクリル樹脂、セルロース樹脂、及びフッ素樹脂からなる群より選択される少なくとも1種の樹脂層を含む、請求項11又は12のいずれかに記載の耐スクラッチ性を有するフィルム。
- 前記基材層が、透明ポリ塩化ビニル樹脂層と、有色ポリ塩化ビニル樹脂層とを含む請求項11〜13のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- 建造物又は車両の内装材又は外装材に貼り付けられる、請求項1〜14のいずれか一項に記載の耐スクラッチ性を有するフィルム。
- ウレタン樹脂組成物を含むバインダー前駆体と、
3μm以上、30μm以下の平均粒径を有するウレタン樹脂ビーズと、
5μm以上、45μm以下の平均粒径を有する硬質粒子と、
ナノシリカ粒子と
を含む表面コーティング組成物であって、
前記バインダー前駆体100質量部を基準として、前記硬質粒子を30質量部以上、500質量部以下含む、表面コーティング組成物。 - 前記ナノシリカ粒子の平均粒径が10nm以上、100nm以下である、請求項16に記載の表面コーティング組成物。
- 前記バインダー前駆体100質量部を基準として、前記ウレタン樹脂ビーズを5質量部以上、120質量部以下含む、請求項16又は17のいずれかに記載の表面コーティング組成物。
- 前記バインダー前駆体100質量部を基準として、前記ナノシリカ粒子を30質量部以上、500質量部以下含む、請求項16〜18のいずれか一項に記載の表面コーティング組成物。
- 前記硬質粒子がアルミナビーズを含む、請求項16〜19のいずれか一項に記載の表面コーティング組成物。
- 前記バインダー前駆体がセルロースエステルをさらに含む、請求項16〜20のいずれか一項に記載の表面コーティング組成物。
- 前記ウレタン樹脂組成物が2液型ウレタン樹脂組成物を含む、請求項16〜21のいずれか一項に記載の表面コーティング組成物。
- イソシアネート又は水酸基と反応可能な官能基を有するシリコーン変性ポリマーをさらに含む、請求項16〜22のいずれか一項に記載の表面コーティング組成物。
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US16/962,275 US11904574B2 (en) | 2018-01-15 | 2019-01-15 | Scratch resistant film and surface coating composition |
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Publication number | Priority date | Publication date | Assignee | Title |
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WO2022009022A1 (en) * | 2020-07-07 | 2022-01-13 | 3M Innovative Properties Company | Film and method of producing the same |
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JP7330738B2 (ja) * | 2019-04-16 | 2023-08-22 | スリーエム イノベイティブ プロパティズ カンパニー | 低光沢な外観を呈する積層体及び表面コーティング剤 |
JP2021079646A (ja) * | 2019-11-20 | 2021-05-27 | スリーエム イノベイティブ プロパティズ カンパニー | 低光沢な外観を呈する無機ナノ粒子含有表面層を含む積層体及び無機ナノ粒子含有放射線硬化型インク |
JP2022166608A (ja) * | 2021-04-21 | 2022-11-02 | スリーエム イノベイティブ プロパティズ カンパニー | 耐スクラッチ性及び艶消し性を有する表面層を含む延伸性装飾フィルム及び表面コーティング組成物 |
KR102623457B1 (ko) * | 2021-12-17 | 2024-01-10 | 다이텍연구원 | 내마모성이 우수한 도장보호 접착필름용 폴리우레탄계 코팅제 조성물 |
CN116004137B (zh) * | 2023-01-09 | 2023-12-22 | 浙江新铭隆科技有限公司 | 一种双哑复合车贴膜及其生产工艺 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11227116A (ja) * | 1998-02-19 | 1999-08-24 | Dainippon Printing Co Ltd | 化粧材 |
JP2001335752A (ja) * | 2000-03-22 | 2001-12-04 | Sanyo Chem Ind Ltd | コーティング用組成物および被覆物 |
JP2008238602A (ja) * | 2007-03-27 | 2008-10-09 | Dainippon Printing Co Ltd | 化粧シート |
US20130041091A1 (en) * | 2010-04-07 | 2013-02-14 | Nuplex Resins B.V. | Crosslinkable composition crosslinkable with a latent base catalyst |
JP2017159544A (ja) * | 2016-03-09 | 2017-09-14 | 凸版印刷株式会社 | 化粧シート |
Family Cites Families (20)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US2987103A (en) * | 1958-03-06 | 1961-06-06 | Goodyear Tire & Rubber | Laminated polyvinyl chloride sheets and method of making same |
JP3332211B2 (ja) * | 1998-01-07 | 2002-10-07 | 株式会社きもと | プロジェクタ用反射型スクリーン |
JP4945032B2 (ja) * | 2001-05-08 | 2012-06-06 | 恵和株式会社 | 反射シート及びこれを用いたバックライトユニット |
JPWO2003032073A1 (ja) * | 2001-09-27 | 2005-01-27 | 株式会社ツジデン | 反射フイルム |
JP4200807B2 (ja) | 2003-04-23 | 2008-12-24 | 凸版印刷株式会社 | 化粧材 |
US7820574B2 (en) * | 2005-06-21 | 2010-10-26 | Kuraray Co., Ltd. | Grain leather-like sheet having excellent scratch resistance and abrasion resistance |
US8187695B2 (en) | 2005-09-30 | 2012-05-29 | Dai Nippon Printing Co., Ltd. | Shaping sheet, resin decorative material and method of producing the same |
JP2008087158A (ja) | 2006-09-29 | 2008-04-17 | Dainippon Printing Co Ltd | 化粧シート |
US20080220224A1 (en) * | 2007-03-06 | 2008-09-11 | Naoki Tokumoto | Decorative Material |
US20090246439A1 (en) | 2008-03-31 | 2009-10-01 | 3M Innovative Properties Company | Decorative sheet |
JP2009290201A (ja) * | 2008-04-28 | 2009-12-10 | Asahi Kasei Chemicals Corp | 太陽電池バックシート用積層体およびそれを有するバックシート |
JP2011255552A (ja) | 2010-06-08 | 2011-12-22 | Toppan Cosmo Inc | エンボス化粧シート |
KR101980401B1 (ko) * | 2011-09-30 | 2019-05-20 | 다이니폰 인사츠 가부시키가이샤 | 장식 시트 및 그것을 사용하여 이루어지는 장식 수지 성형품 |
KR20150090061A (ko) * | 2012-11-22 | 2015-08-05 | 닛폰고세이가가쿠고교 가부시키가이샤 | 활성 에너지선 경화성 수지 조성물, 코팅제 조성물 및 적층체 |
JP6359265B2 (ja) * | 2013-11-21 | 2018-07-18 | 日本合成化学工業株式会社 | 活性エネルギー線硬化性樹脂組成物、コーティング剤組成物、及び積層体 |
KR101578914B1 (ko) * | 2013-03-15 | 2015-12-18 | 주식회사 엘지화학 | 플라스틱 필름 |
JP6199605B2 (ja) * | 2013-05-27 | 2017-09-20 | 日東電工株式会社 | ハードコートフィルム及びハードコートフィルム巻回体 |
WO2014203853A1 (ja) * | 2013-06-20 | 2014-12-24 | 株式会社Dnpファインケミカル | 表面保護層組成物及びそれを用いた加飾体 |
US20160200082A1 (en) * | 2013-09-30 | 2016-07-14 | Dai Nippon Printing Co., Ltd. | Decorative sheet, decorative resin molded article, and manufacturing method for decorative resin molded article |
JP5695726B1 (ja) * | 2013-12-18 | 2015-04-08 | 日新製鋼株式会社 | 印刷材 |
-
2018
- 2018-01-15 JP JP2018004034A patent/JP7088677B2/ja active Active
-
2019
- 2019-01-15 US US16/962,275 patent/US11904574B2/en active Active
- 2019-01-15 KR KR1020207021680A patent/KR20200106046A/ko not_active Application Discontinuation
- 2019-01-15 EP EP19738234.4A patent/EP3740527A4/en active Pending
- 2019-01-15 WO PCT/IB2019/050320 patent/WO2019138397A1/en unknown
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH11227116A (ja) * | 1998-02-19 | 1999-08-24 | Dainippon Printing Co Ltd | 化粧材 |
JP2001335752A (ja) * | 2000-03-22 | 2001-12-04 | Sanyo Chem Ind Ltd | コーティング用組成物および被覆物 |
JP2008238602A (ja) * | 2007-03-27 | 2008-10-09 | Dainippon Printing Co Ltd | 化粧シート |
US20130041091A1 (en) * | 2010-04-07 | 2013-02-14 | Nuplex Resins B.V. | Crosslinkable composition crosslinkable with a latent base catalyst |
JP2017159544A (ja) * | 2016-03-09 | 2017-09-14 | 凸版印刷株式会社 | 化粧シート |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2022009022A1 (en) * | 2020-07-07 | 2022-01-13 | 3M Innovative Properties Company | Film and method of producing the same |
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EP3740527A1 (en) | 2020-11-25 |
WO2019138397A1 (en) | 2019-07-18 |
JP7088677B2 (ja) | 2022-06-21 |
KR20200106046A (ko) | 2020-09-10 |
US11904574B2 (en) | 2024-02-20 |
EP3740527A4 (en) | 2021-09-15 |
US20210061968A1 (en) | 2021-03-04 |
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