JP2017522396A - シラン末端ポリマーをベースとするスズおよびフタレートを含まないシーラント - Google Patents
シラン末端ポリマーをベースとするスズおよびフタレートを含まないシーラント Download PDFInfo
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- JP2017522396A JP2017522396A JP2016567822A JP2016567822A JP2017522396A JP 2017522396 A JP2017522396 A JP 2017522396A JP 2016567822 A JP2016567822 A JP 2016567822A JP 2016567822 A JP2016567822 A JP 2016567822A JP 2017522396 A JP2017522396 A JP 2017522396A
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- Prior art keywords
- sealant
- silane
- polymer
- functional
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
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- 239000000565 sealant Substances 0.000 title claims abstract description 147
- 239000003707 silyl modified polymer Substances 0.000 title claims description 12
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 title claims description 7
- 229920001002 functional polymer Polymers 0.000 claims abstract description 56
- 150000001875 compounds Chemical class 0.000 claims abstract description 34
- 239000003054 catalyst Substances 0.000 claims abstract description 25
- 238000004132 cross linking Methods 0.000 claims abstract description 10
- -1 phthalate compound Chemical class 0.000 claims description 89
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 claims description 71
- 229910000077 silane Inorganic materials 0.000 claims description 54
- 229920000642 polymer Polymers 0.000 claims description 49
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 45
- 239000004814 polyurethane Substances 0.000 claims description 29
- 229920002635 polyurethane Polymers 0.000 claims description 29
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 claims description 27
- 239000004014 plasticizer Substances 0.000 claims description 25
- 238000006243 chemical reaction Methods 0.000 claims description 21
- 239000000203 mixture Substances 0.000 claims description 21
- VTYYLEPIZMXCLO-UHFFFAOYSA-L Calcium carbonate Chemical compound [Ca+2].[O-]C([O-])=O VTYYLEPIZMXCLO-UHFFFAOYSA-L 0.000 claims description 20
- 239000002994 raw material Substances 0.000 claims description 19
- 239000000945 filler Substances 0.000 claims description 18
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 13
- 235000014113 dietary fatty acids Nutrition 0.000 claims description 12
- 239000000194 fatty acid Substances 0.000 claims description 12
- 229930195729 fatty acid Natural products 0.000 claims description 12
- 150000004702 methyl esters Chemical class 0.000 claims description 12
- 125000003739 carbamimidoyl group Chemical group C(N)(=N)* 0.000 claims description 10
- 229910000019 calcium carbonate Inorganic materials 0.000 claims description 9
- 239000004359 castor oil Substances 0.000 claims description 9
- 235000019438 castor oil Nutrition 0.000 claims description 9
- 239000000470 constituent Substances 0.000 claims description 9
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 claims description 9
- 238000011084 recovery Methods 0.000 claims description 9
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 claims description 8
- 235000019484 Rapeseed oil Nutrition 0.000 claims description 8
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 claims description 7
- 239000013008 thixotropic agent Substances 0.000 claims description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 7
- BUZRAOJSFRKWPD-UHFFFAOYSA-N isocyanatosilane Chemical compound [SiH3]N=C=O BUZRAOJSFRKWPD-UHFFFAOYSA-N 0.000 claims description 6
- 238000000034 method Methods 0.000 claims description 6
- QSAWQNUELGIYBC-UHFFFAOYSA-N cyclohexane-1,2-dicarboxylic acid Chemical compound OC(=O)C1CCCCC1C(O)=O QSAWQNUELGIYBC-UHFFFAOYSA-N 0.000 claims description 5
- 239000002480 mineral oil Substances 0.000 claims description 5
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 claims description 4
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 claims description 4
- 235000010446 mineral oil Nutrition 0.000 claims description 4
- 230000008569 process Effects 0.000 claims description 3
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 2
- 230000008030 elimination Effects 0.000 claims description 2
- 238000003379 elimination reaction Methods 0.000 claims description 2
- 238000006459 hydrosilylation reaction Methods 0.000 claims description 2
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- 150000003254 radicals Chemical class 0.000 description 30
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 25
- 125000004432 carbon atom Chemical group C* 0.000 description 21
- 238000001723 curing Methods 0.000 description 16
- 239000000047 product Substances 0.000 description 14
- 150000002009 diols Chemical class 0.000 description 13
- 239000004215 Carbon black (E152) Substances 0.000 description 12
- 239000003795 chemical substances by application Substances 0.000 description 12
- 229930195733 hydrocarbon Natural products 0.000 description 12
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 12
- 239000003446 ligand Substances 0.000 description 12
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 11
- 239000005056 polyisocyanate Substances 0.000 description 11
- 229920001228 polyisocyanate Polymers 0.000 description 11
- 229920001451 polypropylene glycol Polymers 0.000 description 11
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 10
- 239000000126 substance Substances 0.000 description 10
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 9
- 125000001301 ethoxy group Chemical group [H]C([H])([H])C([H])([H])O* 0.000 description 9
- 125000000956 methoxy group Chemical group [H]C([H])([H])O* 0.000 description 9
- 150000004756 silanes Chemical class 0.000 description 9
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 8
- 125000003545 alkoxy group Chemical group 0.000 description 7
- 230000036541 health Effects 0.000 description 7
- 239000000463 material Substances 0.000 description 7
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- GQHTUMJGOHRCHB-UHFFFAOYSA-N 2,3,4,6,7,8,9,10-octahydropyrimido[1,2-a]azepine Chemical compound C1CCCCN2CCCN=C21 GQHTUMJGOHRCHB-UHFFFAOYSA-N 0.000 description 6
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 6
- XSTXAVWGXDQKEL-UHFFFAOYSA-N Trichloroethylene Chemical compound ClC=C(Cl)Cl XSTXAVWGXDQKEL-UHFFFAOYSA-N 0.000 description 6
- XXROGKLTLUQVRX-UHFFFAOYSA-N allyl alcohol Chemical compound OCC=C XXROGKLTLUQVRX-UHFFFAOYSA-N 0.000 description 6
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical compound [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 6
- 229920001577 copolymer Polymers 0.000 description 6
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 6
- 125000005842 heteroatom Chemical group 0.000 description 6
- 229910052751 metal Inorganic materials 0.000 description 6
- 239000002184 metal Substances 0.000 description 6
- 229920000570 polyether Polymers 0.000 description 6
- 229910052710 silicon Inorganic materials 0.000 description 6
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical group [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 description 5
- 239000002318 adhesion promoter Substances 0.000 description 5
- 150000001409 amidines Chemical class 0.000 description 5
- HORIEOQXBKUKGQ-UHFFFAOYSA-N bis(7-methyloctyl) cyclohexane-1,2-dicarboxylate Chemical compound CC(C)CCCCCCOC(=O)C1CCCCC1C(=O)OCCCCCCC(C)C HORIEOQXBKUKGQ-UHFFFAOYSA-N 0.000 description 5
- 125000004122 cyclic group Chemical group 0.000 description 5
- 239000004806 diisononylester Substances 0.000 description 5
- 239000003925 fat Substances 0.000 description 5
- 235000019197 fats Nutrition 0.000 description 5
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 5
- 238000005259 measurement Methods 0.000 description 5
- 229920005906 polyester polyol Polymers 0.000 description 5
- 150000005846 sugar alcohols Polymers 0.000 description 5
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 4
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 4
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 4
- 239000005058 Isophorone diisocyanate Substances 0.000 description 4
- 239000005062 Polybutadiene Substances 0.000 description 4
- 239000004698 Polyethylene Substances 0.000 description 4
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 125000000217 alkyl group Chemical group 0.000 description 4
- 150000004645 aluminates Chemical class 0.000 description 4
- 125000003118 aryl group Chemical group 0.000 description 4
- 239000004567 concrete Substances 0.000 description 4
- 150000001993 dienes Chemical class 0.000 description 4
- 125000005442 diisocyanate group Chemical group 0.000 description 4
- 238000001125 extrusion Methods 0.000 description 4
- 125000003253 isopropoxy group Chemical group [H]C([H])([H])C([H])(O*)C([H])([H])[H] 0.000 description 4
- 229920002857 polybutadiene Polymers 0.000 description 4
- 239000004417 polycarbonate Substances 0.000 description 4
- 229920000515 polycarbonate Polymers 0.000 description 4
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- 238000002360 preparation method Methods 0.000 description 4
- 239000010703 silicon Substances 0.000 description 4
- 238000003756 stirring Methods 0.000 description 4
- 238000003860 storage Methods 0.000 description 4
- 235000015112 vegetable and seed oil Nutrition 0.000 description 4
- 239000008158 vegetable oil Substances 0.000 description 4
- ZYAASQNKCWTPKI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propan-1-amine Chemical compound CO[Si](C)(OC)CCCN ZYAASQNKCWTPKI-UHFFFAOYSA-N 0.000 description 3
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 3
- 239000004721 Polyphenylene oxide Substances 0.000 description 3
- 229920002396 Polyurea Polymers 0.000 description 3
- 239000004809 Teflon Substances 0.000 description 3
- 229920006362 Teflon® Polymers 0.000 description 3
- 239000000370 acceptor Substances 0.000 description 3
- 150000001298 alcohols Chemical class 0.000 description 3
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 3
- 125000003277 amino group Chemical group 0.000 description 3
- 239000006229 carbon black Substances 0.000 description 3
- 150000007942 carboxylates Chemical group 0.000 description 3
- 238000006482 condensation reaction Methods 0.000 description 3
- 239000002274 desiccant Substances 0.000 description 3
- 125000004177 diethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 150000002148 esters Chemical class 0.000 description 3
- NKSJNEHGWDZZQF-UHFFFAOYSA-N ethenyl(trimethoxy)silane Chemical compound CO[Si](OC)(OC)C=C NKSJNEHGWDZZQF-UHFFFAOYSA-N 0.000 description 3
- 150000004665 fatty acids Chemical class 0.000 description 3
- 239000003063 flame retardant Substances 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 238000005984 hydrogenation reaction Methods 0.000 description 3
- 230000007062 hydrolysis Effects 0.000 description 3
- 238000006460 hydrolysis reaction Methods 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 238000004519 manufacturing process Methods 0.000 description 3
- 229910052757 nitrogen Inorganic materials 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
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- WYTZZXDRDKSJID-UHFFFAOYSA-N (3-aminopropyl)triethoxysilane Chemical compound CCO[Si](OCC)(OCC)CCCN WYTZZXDRDKSJID-UHFFFAOYSA-N 0.000 description 2
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 2
- UPMLOUAZCHDJJD-UHFFFAOYSA-N 4,4'-Diphenylmethane Diisocyanate Chemical compound C1=CC(N=C=O)=CC=C1CC1=CC=C(N=C=O)C=C1 UPMLOUAZCHDJJD-UHFFFAOYSA-N 0.000 description 2
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- LCKIEQZJEYYRIY-UHFFFAOYSA-N Titanium ion Chemical compound [Ti+4] LCKIEQZJEYYRIY-UHFFFAOYSA-N 0.000 description 2
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- FTTATHOUSOIFOQ-UHFFFAOYSA-N 1,2,3,4,6,7,8,8a-octahydropyrrolo[1,2-a]pyrazine Chemical compound C1NCCN2CCCC21 FTTATHOUSOIFOQ-UHFFFAOYSA-N 0.000 description 1
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- TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
- OEIJHBUUFURJLI-UHFFFAOYSA-N octane-1,8-diol Chemical compound OCCCCCCCCO OEIJHBUUFURJLI-UHFFFAOYSA-N 0.000 description 1
- 239000012766 organic filler Substances 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- 238000005949 ozonolysis reaction Methods 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
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- 150000002989 phenols Chemical class 0.000 description 1
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 1
- 239000008029 phthalate plasticizer Substances 0.000 description 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-N phthalic acid Chemical class OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 1
- 239000011505 plaster Substances 0.000 description 1
- 229920000058 polyacrylate Polymers 0.000 description 1
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- 229920000582 polyisocyanurate Polymers 0.000 description 1
- 239000011495 polyisocyanurate Substances 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920000166 polytrimethylene carbonate Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- QQONPFPTGQHPMA-UHFFFAOYSA-N propylene Natural products CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 1
- 238000000197 pyrolysis Methods 0.000 description 1
- 230000035484 reaction time Effects 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 239000006254 rheological additive Substances 0.000 description 1
- 238000007142 ring opening reaction Methods 0.000 description 1
- CXMXRPHRNRROMY-UHFFFAOYSA-N sebacic acid Chemical class OC(=O)CCCCCCCCC(O)=O CXMXRPHRNRROMY-UHFFFAOYSA-N 0.000 description 1
- 125000000467 secondary amino group Chemical group [H]N([*:1])[*:2] 0.000 description 1
- 125000005372 silanol group Chemical group 0.000 description 1
- LIVNPJMFVYWSIS-UHFFFAOYSA-N silicon monoxide Inorganic materials [Si-]#[O+] LIVNPJMFVYWSIS-UHFFFAOYSA-N 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 239000000600 sorbitol Substances 0.000 description 1
- 235000010356 sorbitol Nutrition 0.000 description 1
- 235000012424 soybean oil Nutrition 0.000 description 1
- 239000003549 soybean oil Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 238000003892 spreading Methods 0.000 description 1
- 230000007480 spreading Effects 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 125000001424 substituent group Chemical group 0.000 description 1
- 239000005720 sucrose Substances 0.000 description 1
- 235000000346 sugar Nutrition 0.000 description 1
- 150000008163 sugars Chemical class 0.000 description 1
- TXDNPSYEJHXKMK-UHFFFAOYSA-N sulfanylsilane Chemical class S[SiH3] TXDNPSYEJHXKMK-UHFFFAOYSA-N 0.000 description 1
- 150000003459 sulfonic acid esters Chemical class 0.000 description 1
- AYEKOFBPNLCAJY-UHFFFAOYSA-O thiamine pyrophosphate Chemical compound CC1=C(CCOP(O)(=O)OP(O)(O)=O)SC=[N+]1CC1=CN=C(C)N=C1N AYEKOFBPNLCAJY-UHFFFAOYSA-O 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 230000009974 thixotropic effect Effects 0.000 description 1
- 150000003606 tin compounds Chemical class 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 238000004448 titration Methods 0.000 description 1
- RUELTTOHQODFPA-UHFFFAOYSA-N toluene 2,6-diisocyanate Chemical compound CC1=C(N=C=O)C=CC=C1N=C=O RUELTTOHQODFPA-UHFFFAOYSA-N 0.000 description 1
- 231100000331 toxic Toxicity 0.000 description 1
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- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- YUYCVXFAYWRXLS-UHFFFAOYSA-N trimethoxysilane Chemical compound CO[SiH](OC)OC YUYCVXFAYWRXLS-UHFFFAOYSA-N 0.000 description 1
- QXJQHYBHAIHNGG-UHFFFAOYSA-N trimethylolethane Chemical compound OCC(C)(CO)CO QXJQHYBHAIHNGG-UHFFFAOYSA-N 0.000 description 1
- GRXOWOKLKIZFNP-UHFFFAOYSA-N undecane-1,1-diol Chemical compound CCCCCCCCCCC(O)O GRXOWOKLKIZFNP-UHFFFAOYSA-N 0.000 description 1
- 150000003672 ureas Chemical class 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 125000005023 xylyl group Chemical group 0.000 description 1
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- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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Abstract
Description
a)少なくとも1つのシラン官能性ポリマーPと、
b)シラン官能性ポリマーPの架橋用の少なくとも1つの触媒と
を含む湿気硬化型シーラントであって、
有機スズ化合物を含まず、かつ硬化状態で、すなわち、23℃および50%相対湿度で7日間にわたり硬化させた後に、0.4MPa未満の、DIN EN ISO 8339に従って測定される100%伸びおよび23℃での割線係数と、70%超の、DIN EN ISO 7389に従って測定される100%伸びでの弾性回復とを有する、シーラントに関する。
ラジカルR1は、1〜8個のC原子を有する線状または分岐の一価の炭化水素ラジカル、より具体的にはメチルまたはエチル基であり、
ラジカルR2は、1〜5個のC原子を有するアシルラジカルまたは線状もしくは分岐の一価の炭化水素ラジカル、より具体的にはメチル、エチルまたはイソプロピル基、好ましくはエチルまたはイソプロピル基であり、
添字aは、0または1または2、より特に0であり、
ラジカルR3は、任意選択的に環状フラクションおよび任意選択的に1つまたは複数のヘテロ原子、より具体的には1つまたは複数の窒素原子を有する、1〜12個のC原子を有する線状または分岐の二価の炭化水素ラジカル、およびより特に1〜6個のC原子、好ましくは2〜6個のC原子を有するアルキレン基、より具体的にはプロピレン基である)
の末端基を特に有する、少なくとも1つのシラン官能性ポリマーPを含む。
ラジカルR5およびR6は各場合に互いに独立して、水素原子または−R8、−COOR8、および−CNからなる群からのラジカルであり、
ラジカルR7は、水素原子または−CH2−COOR8、−COOR8、−CONHR8、−CON(R8)2、−CN、−NO2、−PO(OR8)2、−SO2R8、および−SO2OR8からなる群からのラジカルであり、
ラジカルR8は、少なくとも1つのヘテロ原子を任意選択的に含有する1〜20個のC原子を有する炭化水素ラジカルである)
のラジカルである)
のアミノシランASである。
ラジカルR21は、水素原子または1〜8個のC原子を有する線状または分岐アルキル基、より具体的にはメチル基であり、
ラジカルR22は、水素原子またはヘテロ原子を任意選択的に含有する1〜8個のC原子を有する線状または分岐アルキル基であり、より特に水素原子であり、
ラジカルR23は、水素原子または1〜8個、より特に1〜3個のC原子を有するアルキル基であるか、または1〜8個、より特に1〜3個のC原子を有する線状または分岐アルコキシ基である)
の配位子である。
ラジカルR21、R22、およびR23は、式(VII)において上に定義された通りであり、
ラジカルR24は、2〜20個のC原子を有する線状または分岐アルキルラジカル、より具体的にはイソブチルまたはイソプロピルラジカルであり、
nは、1または2、より特に2である)
の有機チタネートである。
ラジカルR11は、水素原子、1〜10個のC原子を有する一価の炭化水素ラジカルであるか、またはR14と一緒に、1〜10個のC原子を有する任意選択的に置換された、二価の炭化水素ラジカルであり、
ラジカルR12は、水素原子、任意選択的に環状または芳香族フラクションを有し、かつ任意選択的に1つまたは複数のヘテロ原子、アミノ基を有する、1〜12個のC原子を有する一価の炭化水素であるか、またはR13と一緒に、1〜10個のC原子を有する任意選択的に置換された、二価の炭化水素ラジカルであり、
ラジカルR13は、水素原子、任意選択的に環状または芳香族フラクションを有し、かつ任意選択的に1つまたは複数のヘテロ原子を有する、1〜12個のC原子を有する一価の炭化水素ラジカルであるか、またはR12と一緒に、1〜10個のC原子を有する任意選択的に置換された、二価の炭化水素ラジカルであり、
ラジカルR14は、水素原子、1〜10個のC原子を有する一価の炭化水素ラジカルであるか、またはR11と一緒に、1〜10個のC原子を有する任意選択的に置換された、二価の炭化水素ラジカルである)
の化合物である。
a)20〜30重量%の少なくとも1つのシラン官能性ポリマーP、より具体的にはγ−シラン末端ポリマーであって、シラン官能性ポリマーPが好ましくは硬化時にメタノールを脱離しない、少なくとも1つのシラン官能性ポリマーP、より具体的にはγ−シラン末端ポリマーと、
b)0.01〜2重量%の、シラン官能性ポリマーPの架橋用の少なくとも1つの触媒、より具体的には、少なくとも1つのアミジノ基を有する化合物、より具体的には二環式アミジン、および/または有機チタネート、好ましくは、少なくとも1つのアミジノ基を有する化合物、より具体的には二環式アミジンと、有機チタネートとの組み合わせと、
c1)0〜50重量%、より特に1〜20重量%、好ましくは5〜15重量%の、例えば植物油および/または植物油のエステル、より具体的には菜種油メチルエステルのような再生可能な原材料をベースとする少なくとも1つの可塑剤と、
c2)0〜50重量%の、再生可能な原材料をベースとしない少なくとも1つの可塑剤、より具体的には鉱油、フェノールのアルキルスルホン酸エステル、脂肪酸アルキルエステルまたはそれらの組み合わせ、好ましくは1,2−シクロヘキサンジカルボン酸ジイソノニルと、
d)10〜60重量%の少なくとも1つの充填材と
を含み、好ましくは、硬化時にメタノールを放出しないシーラントである。
a)300%超の、DIN 53504に従って測定される破断点伸び;
b)10〜40の、DIN 53505に従って測定されるショアA硬度;
c)20〜360分のスキンオーバー時間
の少なくとも1つを満たす。
割線係数は、DIN EN ISO 8339に従って100%伸びおよび23℃で測定する。
窒素雰囲気下で、700gのAcclaim(登録商標)12200ポリオール(Bayer MaterialScience AG,Germany;低モノオールポリオキシプロピレンジオール;OH数 11.0mg KOH/g;含水率 約0.02重量%)、32.1gのイソホロンジイソシアネート(Vestanat(登録商標)IPDI、Evonik Degussa GmbH,Germany)、85.4gの2,2,4−トリメチル−1,3−ペンタンジオールジイソブチレート(Eastman TXIBTM;Eastman Chemical Compan,USA)、および0.1gのビスマストリス(ネオデカノエート)(Hexamoll(登録商標)DINCH,BASF SE,Germany中10重量%)を、連続攪拌しながら90℃に加熱し、この温度で放置した。1時間の反応時間後に、滴定により、0.7重量%の遊離イソシアネート基含有量と分かった。次に、0.14モル(NCO基とシランとの化学量論的反応に相当する)の反応性のシラン(Int−EtO)を添加し、攪拌をさらに2〜3時間にわたり90℃で続行した。遊離イソシアネートがIR分光法(2275〜2230cm−1)によってもはや検出できなくなると直ちに反応を停止した。生成物を室温(23℃)まで冷却し、湿気の不在下に貯蔵した(理論的ポリマー含有量=90%)。
メトキシ末端基を有するシラン官能性ポリウレタンポリマーP−MeOは、反応性のシランInt−EtOの代わりに反応性のシランInt−MeO(N−(3−トリメトキシシリルプロピル)アミノコハク酸ジエチル)を使用したことを除いて、エトキシ末端基を有するシラン官能性ポリウレタンポリマーP−EtOと同じ方法で製造した。反応性のシランInt−MeOは、反応性のシランInt−EtOと同じ方法で、しかし3−アミノプロピルトリエトキシシランではなくて3−アミノプロピルトリメトキシシランを使用して調製した。
真空ミキサーに、1000gの1,2−シクロヘキサンジカルボン酸ジイソノニル(DINCH,Hexamoll(登録商標)DINCH)および160gの4,4’−ジフェニルメタンジイソシアネート(Desmodur(登録商標)44 MC L,Bayer MaterialScience AG,Germany)を装入し、この初期装入物をわずかに温めた。次に、激しく攪拌しながら90gのモノブチルアミンをゆっくりと滴加した。形成された白色ペーストを、減圧下で、冷却しながらさらに1時間にわたり攪拌した。チキソトロープ剤TMは、80重量%のDINCH中に20重量%のチキソトロープ剤を含有する。
真空ミキサーで、表1に示される重量部に従って、シラン官能性ポリマー(P−MeOまたはP−EtO)、可塑剤(Hexamoll DINCHおよび/または菜種油メチルエステル)、チキソトロープ剤(TMまたはThixatrol ST)ならびにビニルトリメトキシ−および/または−トリエトキシシラン(Evonik Degussa GmbH,Germany製のDynasylan(登録商標)VTMOおよび/またはVTEO)を5分間にわたり十分に混合した。その後充填材(Socal(登録商標)U1S2、Solvay SA,BelgiumおよびOmyacarb(登録商標)5−GU、Omya AG,Switzerland)を、60℃で15分間にわたり混練して組み込んだ。加熱のスイッチを切って、残りの構成物質(触媒、シラン)をその後添加し、減圧下で10分間にわたり処理して均一なペーストにした。このペーストを次に、内面被覆されたアルミニウムガン−適用カートリッジへ分配した。
製造された調合物を、上に報告された試験方法を用いて試験した。比較のために、同様にシラン官能性ポリマーをベースとする、以下の市販製品を同じ方法で試験した。
Sikaflex Sika製のSikaflex(登録商標)AT−Connection
Danalim Danalim(登録商標)MS Byggefuge 552
Ljungdahl Ljungdahl(登録商標)MS 20 Polymeric Modehvid
Sonolastic BASF製のSonolastic(登録商標)150 with VLM Technology
Claims (17)
- a)少なくとも1つのシラン官能性ポリマーPと、
b)前記シラン官能性ポリマーPの架橋用の少なくとも1つの触媒と
を含む湿気硬化型シーラントであって、
有機スズ化合物を含まず、かつ硬化状態で、0.4MPa未満の、DIN EN ISO 8339に従って測定される100%伸びおよび23℃での割線係数と、70%以上の、DIN EN ISO 7389に従って測定される100%伸びでの弾性回復とを有する、シーラント。 - フタレート含有化合物を含まないことを特徴とする、請求項1に記載のシーラント。
- 前記シラン官能性ポリマーPが、硬化時にメタノールを脱離せず、前記シーラントが好ましくは、硬化の過程でメタノールを脱離する構成物質を含まないことを特徴とする、請求項1または2に記載のシーラント。
- 800N未満の23℃での押出力を有することを特徴とする、請求項1〜3のいずれか一項に記載のシーラント。
- a)フタレート化合物を含まない、b)スズを含まない、c)硬化時にメタノールを脱離しない、およびd)再生可能な原材料を含むことを特徴とする、請求項1〜4のいずれか一項に記載のシーラント。
- ISO 11600によるクラス25LMの建築用シーラントであることを特徴とする、請求項1〜5のいずれか一項に記載のシーラント。
- c)好ましくは脂肪酸アルキルエステル、鉱油、フェノールのアルキルスルホン酸エステルおよび再生可能な原材料をベースとする可塑剤の少なくとも1つから選択される、少なくとも1つの可塑剤であって、より好ましくは、1,2−シクロヘキサンジカルボン酸ジイソノニル、フェノールのアルキルスルホン酸エステル、菜種油メチルエステルまたはそれらの組み合わせを含む、少なくとも1つの可塑剤、および/または
d)少なくとも1つの充填材であって、好ましくは10〜80重量%の量で前記シーラント中に存在する、充填材
をさらに含むことを特徴とする、請求項1〜6のいずれか一項に記載のシーラント。 - c)再生可能な原材料をベースとする少なくとも10重量%の1つまたは複数の可塑剤であって、好ましくは菜種油メチルエステルである、可塑剤
を含むことを特徴とする、請求項1〜7のいずれか一項に記載のシーラント。 - 前記シラン官能性ポリマーPの架橋用の前記触媒が、少なくとも1つのアミジノ基を有する化合物、より具体的には二環式アミジンもしくはグアニジン、または有機チタネート、または少なくとも1つのアミジノ基を有する化合物、より具体的には二環式アミジンもしくはグアニジンと、有機チタネートとの組み合わせを含むことを特徴とする、請求項1〜8のいずれか一項に記載のシーラント。
- 前記シラン官能性ポリマーPが、γ−シラン末端ポリマーであることを特徴とする、請求項1〜9のいずれか一項に記載のシーラント。
- a)20〜30重量%の少なくとも1つのシラン官能性ポリマーP、より具体的にはγ−シラン末端ポリマーであって、前記シラン官能性ポリマーPが好ましくは、硬化時にメタノールを脱離しないシラン官能性ポリマーPである、少なくとも1つのシラン官能性ポリマーP、より具体的にはγ−シラン末端ポリマーと、
b)0.01〜2重量%の、前記シラン官能性ポリマーPの架橋用の少なくとも1つの触媒、より具体的には、少なくとも1つのアミジノ基を有する化合物、より具体的には二環式アミジン、および/または有機チタネート、好ましくは、少なくとも1つのアミジノ基を有する化合物、より具体的には二環式アミジンと、有機チタネートとの組み合わせと、
c1)0〜50重量%、より特に1〜20重量%、好ましくは5〜15重量%の、再生可能な原材料、より具体的には菜種油メチルエステルをベースとする少なくとも1つの可塑剤と、
c2)0〜50重量%の、再生可能な原材料をベースとしない少なくとも1つの他の可塑剤、より具体的には鉱油、フェノールのアルキルスルホン酸エステルもしくは脂肪酸アルキルエステルまたはそれらの組み合わせ、好ましくは1,2−シクロヘキサンジカルボン酸ジイソノニルと、
d)10〜60重量%の少なくとも1つの充填材と
を含むことを特徴とする、請求項1〜10のいずれか一項に記載のシーラントであって、好ましくは、硬化時にメタノールを脱離しないシーラントである、シーラント。 - 前記硬化状態において、次の条件:
a)300%超の、DIN 53504に従って測定される破断点伸び;
b)10〜40の、DIN 53505に従って測定されるショアA硬度;
c)20〜360分のスキンオーバー時間
の少なくとも1つを満たすことを特徴とする、請求項1〜11のいずれか一項に記載のシーラント。 - 好ましくはγ−シラン末端ポリマーである、前記シラン官能性ポリマーPが、
− イソシアネート基に対して反応性である少なくとも1つの基を有するシランと、イソシアネート基を含有するポリウレタンポリマーとの反応によって得られる、シラン官能性ポリウレタンポリマーP1、
− イソシアナトシランISと、イソシアネート基に対して反応性である官能性末端基を有するポリマーとの反応によって得られる、シラン官能性ポリウレタンポリマーP2、または
− 末端二重結合を有するポリマーのヒドロシリル化反応によって得られる、シラン官能性ポリマーP3
から選択されることを特徴とする、請求項1〜12のいずれか一項に記載のシーラント。 - チキソトロープ剤としての有機変性ヒマシ油と、充填材としての沈澱被覆炭酸カルシウムとを含み、好ましくは他の充填材か存在しないことを特徴とする、請求項1〜13のいずれか一項に記載のシーラント。
- ASTM C719クラス50による要件を満たすことを特徴とする、請求項1〜14のいずれか一項に記載のシーラント。
- 建築用シーラントとしての、より具体的には屋外縁取りシーラントとしての、より好ましくはISO 11600によるクラス25LMの建築用シーラントとしての、および/またはASTM C719クラス50によるシーラントとしての請求項1〜15のいずれか一項に記載のシーラントの使用。
- 請求項1〜15のいずれか一項に記載のシーラントから、水での、より具体的には大気水分でのその硬化後に得られる硬化シーラント。
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007094276A1 (ja) * | 2006-02-16 | 2007-08-23 | Kaneka Corporation | 硬化性組成物 |
JP2010534260A (ja) * | 2007-07-23 | 2010-11-04 | ダウ コーニング コーポレーション | 断熱ガラスユニット用シーラント |
JP2013533353A (ja) * | 2010-06-30 | 2013-08-22 | ダウ グローバル テクノロジーズ エルエルシー | スズ不含有シリル末端ポリマー |
WO2013174940A2 (de) * | 2012-05-23 | 2013-11-28 | Sika Technology Ag | Zusammensetzung auf basis silanterminierter polymere, welche bei der aushärtung kein methanol abspaltet |
WO2014009557A1 (de) * | 2012-07-13 | 2014-01-16 | Sika Technology Ag | Hochgefüllte zusammensetzung auf basis von silanterminierten polymeren |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3971751A (en) | 1975-06-09 | 1976-07-27 | Kanegafuchi Kagaku Kogyo Kabushiki Kaisha | Vulcanizable silylether terminated polymer |
EP0918062B1 (en) | 1997-04-21 | 2004-02-18 | Asahi Glass Company Ltd. | Room temperature setting compositions |
JP2002179753A (ja) | 2000-12-13 | 2002-06-26 | Nippon Shiika Kk | 高耐候性ポリウレタン系一液型湿気硬化性組成物 |
DE10328844A1 (de) * | 2003-06-26 | 2005-02-03 | Consortium für elektrochemische Industrie GmbH | Alkoxysilanterminierte Prepolymere |
DE102007038661A1 (de) * | 2007-08-15 | 2009-02-19 | Henkel Ag & Co. Kgaa | Silanvernetzender Kleb- oder Dichtstoff mit N-Silylakylamiden und seine Verwendung |
PL2373716T3 (pl) * | 2008-12-05 | 2014-01-31 | Basf Se | Pochodne kwasów cykloheksanopolikarboksylowych jako plastyfikatory do klejów i szczeliw |
DE102010034997A1 (de) * | 2010-08-20 | 2012-02-23 | Stauf Klebstoffwerk Gmbh | Wasser-, Lösemittel-und Phthalat-freier silanmodifizierter Einkomponenten-Parkettklebstoff und dessen Verwendung zur hochgradig maßhaltigen Verklebung von Parkett, Holzbodenbelägen und Holzwerkstoffplatten im Innenausbau |
JP2012126881A (ja) * | 2010-11-24 | 2012-07-05 | Kaneka Corp | 硬化性組成物 |
DE102012205306A1 (de) * | 2012-03-30 | 2013-10-02 | Wacker Chemie Ag | Vernetzbare Massen auf Basis von organyloxysilanterminierten Polymeren |
-
2014
- 2014-06-04 EP EP14171163.0A patent/EP2952533A1/de not_active Withdrawn
-
2015
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Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2007094276A1 (ja) * | 2006-02-16 | 2007-08-23 | Kaneka Corporation | 硬化性組成物 |
JP2010534260A (ja) * | 2007-07-23 | 2010-11-04 | ダウ コーニング コーポレーション | 断熱ガラスユニット用シーラント |
JP2013533353A (ja) * | 2010-06-30 | 2013-08-22 | ダウ グローバル テクノロジーズ エルエルシー | スズ不含有シリル末端ポリマー |
WO2013174940A2 (de) * | 2012-05-23 | 2013-11-28 | Sika Technology Ag | Zusammensetzung auf basis silanterminierter polymere, welche bei der aushärtung kein methanol abspaltet |
WO2014009557A1 (de) * | 2012-07-13 | 2014-01-16 | Sika Technology Ag | Hochgefüllte zusammensetzung auf basis von silanterminierten polymeren |
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JP6641295B2 (ja) | 2020-02-05 |
US9994744B2 (en) | 2018-06-12 |
EP2952533A1 (de) | 2015-12-09 |
CN106414537B (zh) | 2020-08-11 |
WO2015185642A1 (de) | 2015-12-10 |
US20170101564A1 (en) | 2017-04-13 |
EP3152243A1 (de) | 2017-04-12 |
CN106414537A (zh) | 2017-02-15 |
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