JP2014141647A - 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 - Google Patents
透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 Download PDFInfo
- Publication number
- JP2014141647A JP2014141647A JP2013262192A JP2013262192A JP2014141647A JP 2014141647 A JP2014141647 A JP 2014141647A JP 2013262192 A JP2013262192 A JP 2013262192A JP 2013262192 A JP2013262192 A JP 2013262192A JP 2014141647 A JP2014141647 A JP 2014141647A
- Authority
- JP
- Japan
- Prior art keywords
- transparent conductive
- meth
- water
- sensitive adhesive
- adhesive layer
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000010410 layer Substances 0.000 title claims abstract description 193
- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000012790 adhesive layer Substances 0.000 title claims abstract description 68
- 239000006185 dispersion Substances 0.000 title claims abstract description 51
- 230000001070 adhesive effect Effects 0.000 title claims abstract description 26
- 239000000853 adhesive Substances 0.000 title claims abstract description 23
- 239000012788 optical film Substances 0.000 title claims description 50
- 239000004973 liquid crystal related substance Substances 0.000 title claims description 35
- 239000000178 monomer Substances 0.000 claims abstract description 98
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 80
- 239000004094 surface-active agent Substances 0.000 claims abstract description 79
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 50
- 229920000058 polyacrylate Polymers 0.000 claims abstract description 33
- 125000004432 carbon atom Chemical group C* 0.000 claims abstract description 26
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 25
- 125000005702 oxyalkylene group Chemical group 0.000 claims abstract description 24
- 230000000379 polymerizing effect Effects 0.000 claims abstract description 9
- 239000004820 Pressure-sensitive adhesive Substances 0.000 claims description 126
- -1 phosphate ester compound Chemical class 0.000 claims description 93
- 229920000642 polymer Polymers 0.000 claims description 32
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 claims description 21
- 150000001875 compounds Chemical class 0.000 claims description 19
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical group N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 claims description 16
- 229910019142 PO4 Inorganic materials 0.000 claims description 11
- 239000010452 phosphate Substances 0.000 claims description 11
- 239000003795 chemical substances by application Substances 0.000 claims description 8
- 229910021529 ammonia Inorganic materials 0.000 claims description 7
- 239000010409 thin film Substances 0.000 abstract description 47
- 230000007797 corrosion Effects 0.000 abstract description 34
- 238000005260 corrosion Methods 0.000 abstract description 34
- 230000003287 optical effect Effects 0.000 abstract description 11
- 230000002401 inhibitory effect Effects 0.000 abstract description 9
- 239000010408 film Substances 0.000 description 101
- 238000002360 preparation method Methods 0.000 description 36
- 229920005989 resin Polymers 0.000 description 29
- 239000011347 resin Substances 0.000 description 29
- 238000000034 method Methods 0.000 description 28
- 239000000126 substance Substances 0.000 description 24
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 21
- 238000001035 drying Methods 0.000 description 20
- 230000000052 comparative effect Effects 0.000 description 19
- 239000003431 cross linking reagent Substances 0.000 description 18
- 230000010287 polarization Effects 0.000 description 16
- 229920002451 polyvinyl alcohol Polymers 0.000 description 16
- 239000004372 Polyvinyl alcohol Substances 0.000 description 15
- 239000006087 Silane Coupling Agent Substances 0.000 description 15
- 239000000463 material Substances 0.000 description 15
- 230000015572 biosynthetic process Effects 0.000 description 13
- 125000002467 phosphate group Chemical group [H]OP(=O)(O[H])O[*] 0.000 description 13
- 239000000758 substrate Substances 0.000 description 13
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 12
- 238000006116 polymerization reaction Methods 0.000 description 12
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 11
- 239000000839 emulsion Substances 0.000 description 11
- 230000001681 protective effect Effects 0.000 description 11
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 description 11
- VHUUQVKOLVNVRT-UHFFFAOYSA-N Ammonium hydroxide Chemical compound [NH4+].[OH-] VHUUQVKOLVNVRT-UHFFFAOYSA-N 0.000 description 10
- 235000011114 ammonium hydroxide Nutrition 0.000 description 10
- 210000002858 crystal cell Anatomy 0.000 description 10
- 230000000694 effects Effects 0.000 description 10
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 description 9
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 9
- 238000007720 emulsion polymerization reaction Methods 0.000 description 9
- 239000003995 emulsifying agent Substances 0.000 description 8
- 239000011734 sodium Substances 0.000 description 8
- HRPVXLWXLXDGHG-UHFFFAOYSA-N Acrylamide Chemical compound NC(=O)C=C HRPVXLWXLXDGHG-UHFFFAOYSA-N 0.000 description 7
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 7
- 239000007864 aqueous solution Substances 0.000 description 7
- 239000002585 base Substances 0.000 description 7
- 238000000576 coating method Methods 0.000 description 7
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000002184 metal Substances 0.000 description 7
- 229910044991 metal oxide Inorganic materials 0.000 description 7
- 150000004706 metal oxides Chemical class 0.000 description 7
- 238000002156 mixing Methods 0.000 description 7
- 229920000728 polyester Polymers 0.000 description 7
- 229910052708 sodium Inorganic materials 0.000 description 7
- 239000007787 solid Substances 0.000 description 7
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 description 6
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 6
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 6
- 239000011248 coating agent Substances 0.000 description 6
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 6
- 229910052740 iodine Inorganic materials 0.000 description 6
- 239000011630 iodine Substances 0.000 description 6
- NLKNQRATVPKPDG-UHFFFAOYSA-M potassium iodide Chemical compound [K+].[I-] NLKNQRATVPKPDG-UHFFFAOYSA-M 0.000 description 6
- 239000007870 radical polymerization initiator Substances 0.000 description 6
- 150000003839 salts Chemical class 0.000 description 6
- 239000004593 Epoxy Substances 0.000 description 5
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 5
- 229910004298 SiO 2 Inorganic materials 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 5
- 239000002253 acid Substances 0.000 description 5
- 125000003647 acryloyl group Chemical group O=C([*])C([H])=C([H])[H] 0.000 description 5
- 238000006243 chemical reaction Methods 0.000 description 5
- 229920001577 copolymer Polymers 0.000 description 5
- KZNICNPSHKQLFF-UHFFFAOYSA-N dihydromaleimide Natural products O=C1CCC(=O)N1 KZNICNPSHKQLFF-UHFFFAOYSA-N 0.000 description 5
- 238000004043 dyeing Methods 0.000 description 5
- 125000000524 functional group Chemical group 0.000 description 5
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 5
- 239000003999 initiator Substances 0.000 description 5
- 229910052757 nitrogen Inorganic materials 0.000 description 5
- 229920000139 polyethylene terephthalate Polymers 0.000 description 5
- 239000005020 polyethylene terephthalate Substances 0.000 description 5
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 4
- 229920002284 Cellulose triacetate Polymers 0.000 description 4
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 4
- NNLVGZFZQQXQNW-ADJNRHBOSA-N [(2r,3r,4s,5r,6s)-4,5-diacetyloxy-3-[(2s,3r,4s,5r,6r)-3,4,5-triacetyloxy-6-(acetyloxymethyl)oxan-2-yl]oxy-6-[(2r,3r,4s,5r,6s)-4,5,6-triacetyloxy-2-(acetyloxymethyl)oxan-3-yl]oxyoxan-2-yl]methyl acetate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](OC(C)=O)[C@H]1OC(C)=O)O[C@H]1[C@@H]([C@@H](OC(C)=O)[C@H](OC(C)=O)[C@@H](COC(C)=O)O1)OC(C)=O)COC(=O)C)[C@@H]1[C@@H](COC(C)=O)O[C@@H](OC(C)=O)[C@H](OC(C)=O)[C@H]1OC(C)=O NNLVGZFZQQXQNW-ADJNRHBOSA-N 0.000 description 4
- 239000012986 chain transfer agent Substances 0.000 description 4
- 230000008859 change Effects 0.000 description 4
- 229920001940 conductive polymer Polymers 0.000 description 4
- 150000005690 diesters Chemical class 0.000 description 4
- 150000002148 esters Chemical class 0.000 description 4
- 239000011737 fluorine Substances 0.000 description 4
- 229910052731 fluorine Inorganic materials 0.000 description 4
- 239000011521 glass Substances 0.000 description 4
- 229920001225 polyester resin Polymers 0.000 description 4
- 239000004645 polyester resin Substances 0.000 description 4
- 229910052700 potassium Inorganic materials 0.000 description 4
- 238000010526 radical polymerization reaction Methods 0.000 description 4
- 229920000178 Acrylic resin Polymers 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 3
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004743 Polypropylene Substances 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- ZMANZCXQSJIPKH-UHFFFAOYSA-N Triethylamine Chemical compound CCN(CC)CC ZMANZCXQSJIPKH-UHFFFAOYSA-N 0.000 description 3
- 230000002411 adverse Effects 0.000 description 3
- 125000003342 alkenyl group Chemical group 0.000 description 3
- 125000002947 alkylene group Chemical group 0.000 description 3
- 239000002216 antistatic agent Substances 0.000 description 3
- 238000007334 copolymerization reaction Methods 0.000 description 3
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 3
- 238000011156 evaluation Methods 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
- 229910003437 indium oxide Inorganic materials 0.000 description 3
- PJXISJQVUVHSOJ-UHFFFAOYSA-N indium(iii) oxide Chemical compound [O-2].[O-2].[O-2].[In+3].[In+3] PJXISJQVUVHSOJ-UHFFFAOYSA-N 0.000 description 3
- 229910010272 inorganic material Inorganic materials 0.000 description 3
- 239000011147 inorganic material Substances 0.000 description 3
- 239000012948 isocyanate Substances 0.000 description 3
- 150000002513 isocyanates Chemical class 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 239000011777 magnesium Substances 0.000 description 3
- 125000004108 n-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 3
- 150000002894 organic compounds Chemical group 0.000 description 3
- 239000002245 particle Substances 0.000 description 3
- 229920006393 polyether sulfone Polymers 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920001155 polypropylene Polymers 0.000 description 3
- 229920001296 polysiloxane Polymers 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000004814 polyurethane Substances 0.000 description 3
- 239000004800 polyvinyl chloride Substances 0.000 description 3
- 229920000915 polyvinyl chloride Polymers 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 239000000243 solution Substances 0.000 description 3
- 125000005504 styryl group Chemical group 0.000 description 3
- 229960002317 succinimide Drugs 0.000 description 3
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 3
- 229910001887 tin oxide Inorganic materials 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- DTGKSKDOIYIVQL-WEDXCCLWSA-N (+)-borneol Chemical group C1C[C@@]2(C)[C@@H](O)C[C@@H]1C2(C)C DTGKSKDOIYIVQL-WEDXCCLWSA-N 0.000 description 2
- MYRTYDVEIRVNKP-UHFFFAOYSA-N 1,2-Divinylbenzene Chemical compound C=CC1=CC=CC=C1C=C MYRTYDVEIRVNKP-UHFFFAOYSA-N 0.000 description 2
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- 125000003903 2-propenyl group Chemical group [H]C([*])([H])C([H])=C([H])[H] 0.000 description 2
- SJECZPVISLOESU-UHFFFAOYSA-N 3-trimethoxysilylpropan-1-amine Chemical compound CO[Si](OC)(OC)CCCN SJECZPVISLOESU-UHFFFAOYSA-N 0.000 description 2
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 2
- PAYRUJLWNCNPSJ-UHFFFAOYSA-N Aniline Chemical compound NC1=CC=CC=C1 PAYRUJLWNCNPSJ-UHFFFAOYSA-N 0.000 description 2
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 2
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 description 2
- 239000004695 Polyether sulfone Substances 0.000 description 2
- 239000004721 Polyphenylene oxide Substances 0.000 description 2
- 239000004734 Polyphenylene sulfide Substances 0.000 description 2
- 239000004793 Polystyrene Substances 0.000 description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 description 2
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical group CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 2
- KYQCOXFCLRTKLS-UHFFFAOYSA-N Pyrazine Chemical compound C1=CN=CC=N1 KYQCOXFCLRTKLS-UHFFFAOYSA-N 0.000 description 2
- JUJWROOIHBZHMG-UHFFFAOYSA-N Pyridine Chemical compound C1=CC=NC=C1 JUJWROOIHBZHMG-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 2
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 2
- QYKIQEUNHZKYBP-UHFFFAOYSA-N Vinyl ether Chemical compound C=COC=C QYKIQEUNHZKYBP-UHFFFAOYSA-N 0.000 description 2
- 150000001252 acrylic acid derivatives Chemical class 0.000 description 2
- 230000004913 activation Effects 0.000 description 2
- 239000000654 additive Substances 0.000 description 2
- 125000005037 alkyl phenyl group Chemical group 0.000 description 2
- 125000003277 amino group Chemical group 0.000 description 2
- ROOXNKNUYICQNP-UHFFFAOYSA-N ammonium peroxydisulfate Substances [NH4+].[NH4+].[O-]S(=O)(=O)OOS([O-])(=O)=O ROOXNKNUYICQNP-UHFFFAOYSA-N 0.000 description 2
- VAZSKTXWXKYQJF-UHFFFAOYSA-N ammonium persulfate Chemical compound [NH4+].[NH4+].[O-]S(=O)OOS([O-])=O VAZSKTXWXKYQJF-UHFFFAOYSA-N 0.000 description 2
- 229910001870 ammonium persulfate Inorganic materials 0.000 description 2
- 125000004429 atom Chemical group 0.000 description 2
- KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical compound OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
- 239000004327 boric acid Substances 0.000 description 2
- HQABUPZFAYXKJW-UHFFFAOYSA-N butan-1-amine Chemical compound CCCCN HQABUPZFAYXKJW-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 239000011575 calcium Substances 0.000 description 2
- 150000001718 carbodiimides Chemical class 0.000 description 2
- 229910052799 carbon Inorganic materials 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 239000013522 chelant Substances 0.000 description 2
- 239000000470 constituent Substances 0.000 description 2
- 238000003851 corona treatment Methods 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 239000000975 dye Substances 0.000 description 2
- 230000001804 emulsifying effect Effects 0.000 description 2
- DECIPOUIJURFOJ-UHFFFAOYSA-N ethoxyquin Chemical compound N1C(C)(C)C=C(C)C2=CC(OCC)=CC=C21 DECIPOUIJURFOJ-UHFFFAOYSA-N 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- 238000005227 gel permeation chromatography Methods 0.000 description 2
- 125000003055 glycidyl group Chemical group C(C1CO1)* 0.000 description 2
- 125000005843 halogen group Chemical group 0.000 description 2
- 150000003949 imides Chemical class 0.000 description 2
- 238000007733 ion plating Methods 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 125000001972 isopentyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])C([H])([H])* 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 238000006386 neutralization reaction Methods 0.000 description 2
- 125000000962 organic group Chemical group 0.000 description 2
- 125000004430 oxygen atom Chemical group O* 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000009832 plasma treatment Methods 0.000 description 2
- 229920003207 poly(ethylene-2,6-naphthalate) Polymers 0.000 description 2
- 229920000570 polyether Polymers 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 239000011112 polyethylene naphthalate Substances 0.000 description 2
- 229920001721 polyimide Polymers 0.000 description 2
- 239000009719 polyimide resin Substances 0.000 description 2
- 239000002861 polymer material Substances 0.000 description 2
- 229920000098 polyolefin Polymers 0.000 description 2
- 229920000069 polyphenylene sulfide Polymers 0.000 description 2
- 229920001451 polypropylene glycol Polymers 0.000 description 2
- 229920002223 polystyrene Polymers 0.000 description 2
- 229920005990 polystyrene resin Polymers 0.000 description 2
- 150000008117 polysulfides Polymers 0.000 description 2
- 229920005749 polyurethane resin Polymers 0.000 description 2
- 239000011591 potassium Substances 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 238000010926 purge Methods 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- 239000000344 soap Substances 0.000 description 2
- 238000004544 sputter deposition Methods 0.000 description 2
- 230000000087 stabilizing effect Effects 0.000 description 2
- 238000012360 testing method Methods 0.000 description 2
- CWERGRDVMFNCDR-UHFFFAOYSA-N thioglycolic acid Chemical compound OC(=O)CS CWERGRDVMFNCDR-UHFFFAOYSA-N 0.000 description 2
- 125000003396 thiol group Chemical group [H]S* 0.000 description 2
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 2
- 230000007704 transition Effects 0.000 description 2
- GETQZCLCWQTVFV-UHFFFAOYSA-N trimethylamine Chemical compound CN(C)C GETQZCLCWQTVFV-UHFFFAOYSA-N 0.000 description 2
- 238000001771 vacuum deposition Methods 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- JIAARYAFYJHUJI-UHFFFAOYSA-L zinc dichloride Chemical compound [Cl-].[Cl-].[Zn+2] JIAARYAFYJHUJI-UHFFFAOYSA-L 0.000 description 2
- DGVVWUTYPXICAM-UHFFFAOYSA-N β‐Mercaptoethanol Chemical compound OCCS DGVVWUTYPXICAM-UHFFFAOYSA-N 0.000 description 2
- AURYLBASVGNSON-UHFFFAOYSA-N (2,5-dioxopyrrolidin-3-ylidene)methyl prop-2-enoate Chemical compound C=CC(=O)OC=C1CC(=O)NC1=O AURYLBASVGNSON-UHFFFAOYSA-N 0.000 description 1
- LTQBNYCMVZQRSD-UHFFFAOYSA-N (4-ethenylphenyl)-trimethoxysilane Chemical compound CO[Si](OC)(OC)C1=CC=C(C=C)C=C1 LTQBNYCMVZQRSD-UHFFFAOYSA-N 0.000 description 1
- HNSDLXPSAYFUHK-UHFFFAOYSA-N 1,4-bis(2-ethylhexyl) sulfosuccinate Chemical compound CCCCC(CC)COC(=O)CC(S(O)(=O)=O)C(=O)OCC(CC)CCCC HNSDLXPSAYFUHK-UHFFFAOYSA-N 0.000 description 1
- BQTPKSBXMONSJI-UHFFFAOYSA-N 1-cyclohexylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1CCCCC1 BQTPKSBXMONSJI-UHFFFAOYSA-N 0.000 description 1
- SJLLJZNSZJHXQN-UHFFFAOYSA-N 1-dodecylpyrrole-2,5-dione Chemical compound CCCCCCCCCCCCN1C(=O)C=CC1=O SJLLJZNSZJHXQN-UHFFFAOYSA-N 0.000 description 1
- OZFIGURLAJSLIR-UHFFFAOYSA-N 1-ethenyl-2h-pyridine Chemical compound C=CN1CC=CC=C1 OZFIGURLAJSLIR-UHFFFAOYSA-N 0.000 description 1
- LNKDTZRRFHHCCV-UHFFFAOYSA-N 1-ethenyl-2h-pyrimidine Chemical compound C=CN1CN=CC=C1 LNKDTZRRFHHCCV-UHFFFAOYSA-N 0.000 description 1
- OSSNTDFYBPYIEC-UHFFFAOYSA-N 1-ethenylimidazole Chemical compound C=CN1C=CN=C1 OSSNTDFYBPYIEC-UHFFFAOYSA-N 0.000 description 1
- DCRYNQTXGUTACA-UHFFFAOYSA-N 1-ethenylpiperazine Chemical compound C=CN1CCNCC1 DCRYNQTXGUTACA-UHFFFAOYSA-N 0.000 description 1
- PBGPBHYPCGDFEZ-UHFFFAOYSA-N 1-ethenylpiperidin-2-one Chemical compound C=CN1CCCCC1=O PBGPBHYPCGDFEZ-UHFFFAOYSA-N 0.000 description 1
- CTXUTPWZJZHRJC-UHFFFAOYSA-N 1-ethenylpyrrole Chemical compound C=CN1C=CC=C1 CTXUTPWZJZHRJC-UHFFFAOYSA-N 0.000 description 1
- BMZZOWWYEBTMBX-UHFFFAOYSA-N 1-ethyl-3-methylidenepyrrolidine-2,5-dione Chemical compound CCN1C(=O)CC(=C)C1=O BMZZOWWYEBTMBX-UHFFFAOYSA-N 0.000 description 1
- CSCSROFYRUZJJH-UHFFFAOYSA-N 1-methoxyethane-1,2-diol Chemical compound COC(O)CO CSCSROFYRUZJJH-UHFFFAOYSA-N 0.000 description 1
- QSWFISOPXPJUCT-UHFFFAOYSA-N 1-methyl-3-methylidenepyrrolidine-2,5-dione Chemical compound CN1C(=O)CC(=C)C1=O QSWFISOPXPJUCT-UHFFFAOYSA-N 0.000 description 1
- XLPJNCYCZORXHG-UHFFFAOYSA-N 1-morpholin-4-ylprop-2-en-1-one Chemical compound C=CC(=O)N1CCOCC1 XLPJNCYCZORXHG-UHFFFAOYSA-N 0.000 description 1
- HIDBROSJWZYGSZ-UHFFFAOYSA-N 1-phenylpyrrole-2,5-dione Chemical compound O=C1C=CC(=O)N1C1=CC=CC=C1 HIDBROSJWZYGSZ-UHFFFAOYSA-N 0.000 description 1
- HMPUKFGKTNAIRX-UHFFFAOYSA-N 1-prop-1-en-2-ylpyrrolidin-2-one Chemical compound CC(=C)N1CCCC1=O HMPUKFGKTNAIRX-UHFFFAOYSA-N 0.000 description 1
- NQDOCLXQTQYUDH-UHFFFAOYSA-N 1-propan-2-ylpyrrole-2,5-dione Chemical compound CC(C)N1C(=O)C=CC1=O NQDOCLXQTQYUDH-UHFFFAOYSA-N 0.000 description 1
- BDERNNFJNOPAEC-UHFFFAOYSA-N 1-propanol Substances CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 1
- VILCJCGEZXAXTO-UHFFFAOYSA-N 2,2,2-tetramine Chemical compound NCCNCCNCCN VILCJCGEZXAXTO-UHFFFAOYSA-N 0.000 description 1
- XIWVNXGNLGFNSO-UHFFFAOYSA-N 2-(2-dodecoxyethoxy)ethyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOCCOCCOP(O)(O)=O XIWVNXGNLGFNSO-UHFFFAOYSA-N 0.000 description 1
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 1
- OEPOKWHJYJXUGD-UHFFFAOYSA-N 2-(3-phenylmethoxyphenyl)-1,3-thiazole-4-carbaldehyde Chemical compound O=CC1=CSC(C=2C=C(OCC=3C=CC=CC=3)C=CC=2)=N1 OEPOKWHJYJXUGD-UHFFFAOYSA-N 0.000 description 1
- IMSODMZESSGVBE-UHFFFAOYSA-N 2-Oxazoline Chemical compound C1CN=CO1 IMSODMZESSGVBE-UHFFFAOYSA-N 0.000 description 1
- GAMXOFKSAQTGLL-UHFFFAOYSA-N 2-[(1-amino-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidamide;sulfo hydrogen sulfate Chemical compound OS(=O)(=O)OS(O)(=O)=O.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N GAMXOFKSAQTGLL-UHFFFAOYSA-N 0.000 description 1
- FGLHFQPDMSLJBI-UHFFFAOYSA-N 2-[2-(2-octadecoxyethoxy)ethoxy]ethyl dihydrogen phosphate Chemical compound [H]OP(=O)(O[H])OC([H])([H])C([H])([H])OC([H])([H])C([H])([H])OC([H])([H])C([H])([H])OC([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])C([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] FGLHFQPDMSLJBI-UHFFFAOYSA-N 0.000 description 1
- TXBCBTDQIULDIA-UHFFFAOYSA-N 2-[[3-hydroxy-2,2-bis(hydroxymethyl)propoxy]methyl]-2-(hydroxymethyl)propane-1,3-diol Chemical compound OCC(CO)(CO)COCC(CO)(CO)CO TXBCBTDQIULDIA-UHFFFAOYSA-N 0.000 description 1
- XJQCUIPISBNYLK-UHFFFAOYSA-N 2-[diethoxy(methyl)silyl]ethyl prop-2-enoate Chemical compound CCO[Si](C)(OCC)CCOC(=O)C=C XJQCUIPISBNYLK-UHFFFAOYSA-N 0.000 description 1
- CUGQQXKZSRAAEC-UHFFFAOYSA-N 2-[dimethoxy(methyl)silyl]ethyl prop-2-enoate Chemical compound CO[Si](C)(OC)CCOC(=O)C=C CUGQQXKZSRAAEC-UHFFFAOYSA-N 0.000 description 1
- 125000000022 2-aminoethyl group Chemical group [H]C([*])([H])C([H])([H])N([H])[H] 0.000 description 1
- CBECDWUDYQOTSW-UHFFFAOYSA-N 2-ethylbut-3-enal Chemical compound CCC(C=C)C=O CBECDWUDYQOTSW-UHFFFAOYSA-N 0.000 description 1
- OWHSTLLOZWTNTQ-UHFFFAOYSA-N 2-ethylhexyl 2-sulfanylacetate Chemical compound CCCCC(CC)COC(=O)CS OWHSTLLOZWTNTQ-UHFFFAOYSA-N 0.000 description 1
- GWZMWHWAWHPNHN-UHFFFAOYSA-N 2-hydroxypropyl prop-2-enoate Chemical compound CC(O)COC(=O)C=C GWZMWHWAWHPNHN-UHFFFAOYSA-N 0.000 description 1
- PMNLUUOXGOOLSP-UHFFFAOYSA-N 2-mercaptopropanoic acid Chemical class CC(S)C(O)=O PMNLUUOXGOOLSP-UHFFFAOYSA-N 0.000 description 1
- LXBGSDVWAMZHDD-UHFFFAOYSA-N 2-methyl-1h-imidazole Chemical compound CC1=NC=CN1 LXBGSDVWAMZHDD-UHFFFAOYSA-N 0.000 description 1
- AUZRCMMVHXRSGT-UHFFFAOYSA-N 2-methylpropane-1-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CC(C)CS(O)(=O)=O AUZRCMMVHXRSGT-UHFFFAOYSA-N 0.000 description 1
- 125000003504 2-oxazolinyl group Chemical group O1C(=NCC1)* 0.000 description 1
- AGBXYHCHUYARJY-UHFFFAOYSA-N 2-phenylethenesulfonic acid Chemical compound OS(=O)(=O)C=CC1=CC=CC=C1 AGBXYHCHUYARJY-UHFFFAOYSA-N 0.000 description 1
- YYIOIHBNJMVSBH-UHFFFAOYSA-N 2-prop-2-enoyloxynaphthalene-1-sulfonic acid Chemical compound C1=CC=C2C(S(=O)(=O)O)=C(OC(=O)C=C)C=CC2=C1 YYIOIHBNJMVSBH-UHFFFAOYSA-N 0.000 description 1
- PSLRXNFNXYNXEK-UHFFFAOYSA-N 2-triethoxysilylethyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCOC(=O)C=C PSLRXNFNXYNXEK-UHFFFAOYSA-N 0.000 description 1
- BUJVPKZRXOTBGA-UHFFFAOYSA-N 2-trimethoxysilylethyl prop-2-enoate Chemical compound CO[Si](OC)(OC)CCOC(=O)C=C BUJVPKZRXOTBGA-UHFFFAOYSA-N 0.000 description 1
- YVXUBCNTKZUKRU-UHFFFAOYSA-N 3-[dibutoxy(ethyl)silyl]propyl prop-2-enoate Chemical compound CCCCO[Si](CC)(OCCCC)CCCOC(=O)C=C YVXUBCNTKZUKRU-UHFFFAOYSA-N 0.000 description 1
- NQXLZDZOOIINDQ-UHFFFAOYSA-N 3-[dibutoxy(methyl)silyl]propyl prop-2-enoate Chemical compound CCCCO[Si](C)(OCCCC)CCCOC(=O)C=C NQXLZDZOOIINDQ-UHFFFAOYSA-N 0.000 description 1
- UULWRBNKTKMMHF-UHFFFAOYSA-N 3-[diethoxy(ethyl)silyl]propyl prop-2-enoate Chemical compound CCO[Si](CC)(OCC)CCCOC(=O)C=C UULWRBNKTKMMHF-UHFFFAOYSA-N 0.000 description 1
- UDWIZRDPCQAYRF-UHFFFAOYSA-N 3-[diethoxy(methyl)silyl]propyl prop-2-enoate Chemical compound CCO[Si](C)(OCC)CCCOC(=O)C=C UDWIZRDPCQAYRF-UHFFFAOYSA-N 0.000 description 1
- SLBYAIPZBNHSTH-UHFFFAOYSA-N 3-[diethoxy(propyl)silyl]propyl prop-2-enoate Chemical compound CCC[Si](OCC)(OCC)CCCOC(=O)C=C SLBYAIPZBNHSTH-UHFFFAOYSA-N 0.000 description 1
- IKYAJDOSWUATPI-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propane-1-thiol Chemical compound CO[Si](C)(OC)CCCS IKYAJDOSWUATPI-UHFFFAOYSA-N 0.000 description 1
- MCDBEBOBROAQSH-UHFFFAOYSA-N 3-[dimethoxy(methyl)silyl]propyl prop-2-enoate Chemical compound CO[Si](C)(OC)CCCOC(=O)C=C MCDBEBOBROAQSH-UHFFFAOYSA-N 0.000 description 1
- FAQMOPJEFYMJGL-UHFFFAOYSA-N 3-[dimethoxy(propyl)silyl]propyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)CCCOC(=O)C=C FAQMOPJEFYMJGL-UHFFFAOYSA-N 0.000 description 1
- YDSKIYLJGKSHFX-UHFFFAOYSA-N 3-[ethyl(dimethoxy)silyl]propyl prop-2-enoate Chemical compound CC[Si](OC)(OC)CCCOC(=O)C=C YDSKIYLJGKSHFX-UHFFFAOYSA-N 0.000 description 1
- YBPAYECBYADYCO-UHFFFAOYSA-N 3-[ethyl-di(propan-2-yloxy)silyl]propyl prop-2-enoate Chemical compound C(C=C)(=O)OCCC[Si](OC(C)C)(OC(C)C)CC YBPAYECBYADYCO-UHFFFAOYSA-N 0.000 description 1
- MYEFGHBUFAPKJO-UHFFFAOYSA-N 3-[methyl(dipropoxy)silyl]propyl prop-2-enoate Chemical compound CCCO[Si](C)(OCCC)CCCOC(=O)C=C MYEFGHBUFAPKJO-UHFFFAOYSA-N 0.000 description 1
- DKJUNSCWORCQSY-UHFFFAOYSA-N 3-[methyl-di(propan-2-yloxy)silyl]propyl prop-2-enoate Chemical compound CC(C)O[Si](C)(OC(C)C)CCCOC(=O)C=C DKJUNSCWORCQSY-UHFFFAOYSA-N 0.000 description 1
- NIAXWFTYAJQENP-UHFFFAOYSA-N 3-ethenyl-2h-1,3-oxazole Chemical compound C=CN1COC=C1 NIAXWFTYAJQENP-UHFFFAOYSA-N 0.000 description 1
- FKAWETHEYBZGSR-UHFFFAOYSA-N 3-methylidenepyrrolidine-2,5-dione Chemical compound C=C1CC(=O)NC1=O FKAWETHEYBZGSR-UHFFFAOYSA-N 0.000 description 1
- YFISHOAHNLGUEL-UHFFFAOYSA-N 3-tributoxysilylpropyl prop-2-enoate Chemical compound CCCCO[Si](OCCCC)(OCCCC)CCCOC(=O)C=C YFISHOAHNLGUEL-UHFFFAOYSA-N 0.000 description 1
- URDOJQUSEUXVRP-UHFFFAOYSA-N 3-triethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C(C)=C URDOJQUSEUXVRP-UHFFFAOYSA-N 0.000 description 1
- XDQWJFXZTAWJST-UHFFFAOYSA-N 3-triethoxysilylpropyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)CCCOC(=O)C=C XDQWJFXZTAWJST-UHFFFAOYSA-N 0.000 description 1
- XDLMVUHYZWKMMD-UHFFFAOYSA-N 3-trimethoxysilylpropyl 2-methylprop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C(C)=C XDLMVUHYZWKMMD-UHFFFAOYSA-N 0.000 description 1
- KBQVDAIIQCXKPI-UHFFFAOYSA-N 3-trimethoxysilylpropyl prop-2-enoate Chemical compound CO[Si](OC)(OC)CCCOC(=O)C=C KBQVDAIIQCXKPI-UHFFFAOYSA-N 0.000 description 1
- HGEKXQRHZRDGKO-UHFFFAOYSA-N 3-tripropoxysilylpropyl prop-2-enoate Chemical compound CCCO[Si](OCCC)(OCCC)CCCOC(=O)C=C HGEKXQRHZRDGKO-UHFFFAOYSA-N 0.000 description 1
- CFZDMXAOSDDDRT-UHFFFAOYSA-N 4-ethenylmorpholine Chemical compound C=CN1CCOCC1 CFZDMXAOSDDDRT-UHFFFAOYSA-N 0.000 description 1
- PRKPGWQEKNEVEU-UHFFFAOYSA-N 4-methyl-n-(3-triethoxysilylpropyl)pentan-2-imine Chemical compound CCO[Si](OCC)(OCC)CCCN=C(C)CC(C)C PRKPGWQEKNEVEU-UHFFFAOYSA-N 0.000 description 1
- FWEOQOXTVHGIFQ-UHFFFAOYSA-N 8-anilinonaphthalene-1-sulfonic acid Chemical compound C=12C(S(=O)(=O)O)=CC=CC2=CC=CC=1NC1=CC=CC=C1 FWEOQOXTVHGIFQ-UHFFFAOYSA-N 0.000 description 1
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- 229910018072 Al 2 O 3 Inorganic materials 0.000 description 1
- 229910016036 BaF 2 Inorganic materials 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
- RXYDZWWGSDXHLZ-UHFFFAOYSA-N C=CC(O)=O.C=CC(O)=O.C=CC(O)=O.N Chemical group C=CC(O)=O.C=CC(O)=O.C=CC(O)=O.N RXYDZWWGSDXHLZ-UHFFFAOYSA-N 0.000 description 1
- 229910004261 CaF 2 Inorganic materials 0.000 description 1
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- RPNUMPOLZDHAAY-UHFFFAOYSA-N Diethylenetriamine Chemical compound NCCNCCN RPNUMPOLZDHAAY-UHFFFAOYSA-N 0.000 description 1
- RWSOTUBLDIXVET-UHFFFAOYSA-N Dihydrogen sulfide Chemical class S RWSOTUBLDIXVET-UHFFFAOYSA-N 0.000 description 1
- 239000004386 Erythritol Substances 0.000 description 1
- UNXHWFMMPAWVPI-UHFFFAOYSA-N Erythritol Natural products OCC(O)C(O)CO UNXHWFMMPAWVPI-UHFFFAOYSA-N 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical class CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical group C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- PIICEJLVQHRZGT-UHFFFAOYSA-N Ethylenediamine Chemical compound NCCN PIICEJLVQHRZGT-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical group CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 1
- 229910017768 LaF 3 Inorganic materials 0.000 description 1
- PEEHTFAAVSWFBL-UHFFFAOYSA-N Maleimide Chemical compound O=C1NC(=O)C=C1 PEEHTFAAVSWFBL-UHFFFAOYSA-N 0.000 description 1
- CERQOIWHTDAKMF-UHFFFAOYSA-M Methacrylate Chemical compound CC(=C)C([O-])=O CERQOIWHTDAKMF-UHFFFAOYSA-M 0.000 description 1
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 1
- UEEJHVSXFDXPFK-UHFFFAOYSA-N N-dimethylaminoethanol Chemical compound CN(C)CCO UEEJHVSXFDXPFK-UHFFFAOYSA-N 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- PCNDJXKNXGMECE-UHFFFAOYSA-N Phenazine Natural products C1=CC=CC2=NC3=CC=CC=C3N=C21 PCNDJXKNXGMECE-UHFFFAOYSA-N 0.000 description 1
- 239000004696 Poly ether ether ketone Substances 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 229920002873 Polyethylenimine Polymers 0.000 description 1
- 229920001328 Polyvinylidene chloride Polymers 0.000 description 1
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 1
- 229920000297 Rayon Polymers 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
- DBMJMQXJHONAFJ-UHFFFAOYSA-M Sodium laurylsulphate Chemical compound [Na+].CCCCCCCCCCCCOS([O-])(=O)=O DBMJMQXJHONAFJ-UHFFFAOYSA-M 0.000 description 1
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 1
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 1
- LXEKPEMOWBOYRF-UHFFFAOYSA-N [2-[(1-azaniumyl-1-imino-2-methylpropan-2-yl)diazenyl]-2-methylpropanimidoyl]azanium;dichloride Chemical compound Cl.Cl.NC(=N)C(C)(C)N=NC(C)(C)C(N)=N LXEKPEMOWBOYRF-UHFFFAOYSA-N 0.000 description 1
- SOQDVGQHVVOWLF-UHFFFAOYSA-N [diethoxy(methyl)silyl]methyl prop-2-enoate Chemical compound CCO[Si](C)(OCC)COC(=O)C=C SOQDVGQHVVOWLF-UHFFFAOYSA-N 0.000 description 1
- UIJDAGBZCJCLNO-UHFFFAOYSA-N [dimethoxy(methyl)silyl]methyl prop-2-enoate Chemical compound CO[Si](C)(OC)COC(=O)C=C UIJDAGBZCJCLNO-UHFFFAOYSA-N 0.000 description 1
- RMKZLFMHXZAGTM-UHFFFAOYSA-N [dimethoxy(propyl)silyl]oxymethyl prop-2-enoate Chemical compound CCC[Si](OC)(OC)OCOC(=O)C=C RMKZLFMHXZAGTM-UHFFFAOYSA-N 0.000 description 1
- 239000006096 absorbing agent Substances 0.000 description 1
- 125000002339 acetoacetyl group Chemical group O=C([*])C([H])([H])C(=O)C([H])([H])[H] 0.000 description 1
- 150000007513 acids Chemical class 0.000 description 1
- 239000003522 acrylic cement Substances 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 229910052783 alkali metal Inorganic materials 0.000 description 1
- 150000008044 alkali metal hydroxides Chemical class 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- 229910052784 alkaline earth metal Inorganic materials 0.000 description 1
- 229910001860 alkaline earth metal hydroxide Inorganic materials 0.000 description 1
- 150000001342 alkaline earth metals Chemical class 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 125000005907 alkyl ester group Chemical group 0.000 description 1
- 150000005215 alkyl ethers Chemical class 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 150000001408 amides Chemical class 0.000 description 1
- 150000001412 amines Chemical group 0.000 description 1
- CBTVGIZVANVGBH-UHFFFAOYSA-N aminomethyl propanol Chemical compound CC(C)(N)CO CBTVGIZVANVGBH-UHFFFAOYSA-N 0.000 description 1
- BTBJBAZGXNKLQC-UHFFFAOYSA-N ammonium lauryl sulfate Chemical compound [NH4+].CCCCCCCCCCCCOS([O-])(=O)=O BTBJBAZGXNKLQC-UHFFFAOYSA-N 0.000 description 1
- 229940063953 ammonium lauryl sulfate Drugs 0.000 description 1
- 150000003863 ammonium salts Chemical class 0.000 description 1
- 125000000129 anionic group Chemical group 0.000 description 1
- 230000003373 anti-fouling effect Effects 0.000 description 1
- 239000003963 antioxidant agent Substances 0.000 description 1
- 239000004760 aramid Substances 0.000 description 1
- 229920003235 aromatic polyamide Polymers 0.000 description 1
- 239000012298 atmosphere Substances 0.000 description 1
- RQPZNWPYLFFXCP-UHFFFAOYSA-L barium dihydroxide Chemical compound [OH-].[OH-].[Ba+2] RQPZNWPYLFFXCP-UHFFFAOYSA-L 0.000 description 1
- 229910001863 barium hydroxide Inorganic materials 0.000 description 1
- 230000004888 barrier function Effects 0.000 description 1
- 239000011324 bead Substances 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- LBSPZZSGTIBOFG-UHFFFAOYSA-N bis[2-(4,5-dihydro-1h-imidazol-2-yl)propan-2-yl]diazene;dihydrochloride Chemical compound Cl.Cl.N=1CCNC=1C(C)(C)N=NC(C)(C)C1=NCCN1 LBSPZZSGTIBOFG-UHFFFAOYSA-N 0.000 description 1
- 239000002981 blocking agent Substances 0.000 description 1
- 238000009835 boiling Methods 0.000 description 1
- CQEYYJKEWSMYFG-UHFFFAOYSA-N butyl acrylate Chemical compound CCCCOC(=O)C=C CQEYYJKEWSMYFG-UHFFFAOYSA-N 0.000 description 1
- QHIWVLPBUQWDMQ-UHFFFAOYSA-N butyl prop-2-enoate;methyl 2-methylprop-2-enoate;prop-2-enoic acid Chemical compound OC(=O)C=C.COC(=O)C(C)=C.CCCCOC(=O)C=C QHIWVLPBUQWDMQ-UHFFFAOYSA-N 0.000 description 1
- AXCZMVOFGPJBDE-UHFFFAOYSA-L calcium dihydroxide Chemical compound [OH-].[OH-].[Ca+2] AXCZMVOFGPJBDE-UHFFFAOYSA-L 0.000 description 1
- 239000000920 calcium hydroxide Substances 0.000 description 1
- 229910001861 calcium hydroxide Inorganic materials 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 239000011203 carbon fibre reinforced carbon Substances 0.000 description 1
- 125000002915 carbonyl group Chemical group [*:2]C([*:1])=O 0.000 description 1
- 150000001767 cationic compounds Chemical class 0.000 description 1
- 125000002091 cationic group Chemical group 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 210000004027 cell Anatomy 0.000 description 1
- 239000012461 cellulose resin Substances 0.000 description 1
- 229910000420 cerium oxide Inorganic materials 0.000 description 1
- 229910052804 chromium Inorganic materials 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000004040 coloring Methods 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 1
- 125000004093 cyano group Chemical group *C#N 0.000 description 1
- 125000000113 cyclohexyl group Chemical group [H]C1([H])C([H])([H])C([H])([H])C([H])(*)C([H])([H])C1([H])[H] 0.000 description 1
- 125000002704 decyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- 230000006866 deterioration Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 229920005994 diacetyl cellulose Polymers 0.000 description 1
- ZBCBWPMODOFKDW-UHFFFAOYSA-N diethanolamine Chemical compound OCCNCCO ZBCBWPMODOFKDW-UHFFFAOYSA-N 0.000 description 1
- OTARVPUIYXHRRB-UHFFFAOYSA-N diethoxy-methyl-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CCO[Si](C)(OCC)CCCOCC1CO1 OTARVPUIYXHRRB-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 238000007865 diluting Methods 0.000 description 1
- WNAHIZMDSQCWRP-UHFFFAOYSA-N dodecane-1-thiol Chemical compound CCCCCCCCCCCCS WNAHIZMDSQCWRP-UHFFFAOYSA-N 0.000 description 1
- GVGUFUZHNYFZLC-UHFFFAOYSA-N dodecyl benzenesulfonate;sodium Chemical compound [Na].CCCCCCCCCCCCOS(=O)(=O)C1=CC=CC=C1 GVGUFUZHNYFZLC-UHFFFAOYSA-N 0.000 description 1
- TVACALAUIQMRDF-UHFFFAOYSA-N dodecyl dihydrogen phosphate Chemical compound CCCCCCCCCCCCOP(O)(O)=O TVACALAUIQMRDF-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 238000010556 emulsion polymerization method Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- UNXHWFMMPAWVPI-ZXZARUISSA-N erythritol Chemical compound OC[C@H](O)[C@H](O)CO UNXHWFMMPAWVPI-ZXZARUISSA-N 0.000 description 1
- 229940009714 erythritol Drugs 0.000 description 1
- 235000019414 erythritol Nutrition 0.000 description 1
- BLCTWBJQROOONQ-UHFFFAOYSA-N ethenyl prop-2-enoate Chemical compound C=COC(=O)C=C BLCTWBJQROOONQ-UHFFFAOYSA-N 0.000 description 1
- UIWXSTHGICQLQT-UHFFFAOYSA-N ethenyl propanoate Chemical compound CCC(=O)OC=C UIWXSTHGICQLQT-UHFFFAOYSA-N 0.000 description 1
- FWDBOZPQNFPOLF-UHFFFAOYSA-N ethenyl(triethoxy)silane Chemical compound CCO[Si](OCC)(OCC)C=C FWDBOZPQNFPOLF-UHFFFAOYSA-N 0.000 description 1
- NNBRCHPBPDRPIT-UHFFFAOYSA-N ethenyl(tripropoxy)silane Chemical compound CCCO[Si](OCCC)(OCCC)C=C NNBRCHPBPDRPIT-UHFFFAOYSA-N 0.000 description 1
- MABAWBWRUSBLKQ-UHFFFAOYSA-N ethenyl-tri(propan-2-yloxy)silane Chemical compound CC(C)O[Si](OC(C)C)(OC(C)C)C=C MABAWBWRUSBLKQ-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 125000005448 ethoxyethyl group Chemical group [H]C([H])([H])C([H])([H])OC([H])([H])C([H])([H])* 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- IPZIVCLZBFDXTA-UHFFFAOYSA-N ethyl n-prop-2-enoylcarbamate Chemical compound CCOC(=O)NC(=O)C=C IPZIVCLZBFDXTA-UHFFFAOYSA-N 0.000 description 1
- 239000000284 extract Substances 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000007765 extrusion coating Methods 0.000 description 1
- 239000004744 fabric Substances 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 239000006260 foam Substances 0.000 description 1
- 239000011888 foil Substances 0.000 description 1
- 239000001530 fumaric acid Substances 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 239000003365 glass fiber Substances 0.000 description 1
- 125000003187 heptyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- 150000002391 heterocyclic compounds Chemical class 0.000 description 1
- 125000000623 heterocyclic group Chemical group 0.000 description 1
- XXMIOPMDWAUFGU-UHFFFAOYSA-N hexane-1,6-diol Chemical compound OCCCCCCO XXMIOPMDWAUFGU-UHFFFAOYSA-N 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 229920001477 hydrophilic polymer Polymers 0.000 description 1
- 150000002466 imines Chemical class 0.000 description 1
- 229910052738 indium Inorganic materials 0.000 description 1
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 229910001411 inorganic cation Inorganic materials 0.000 description 1
- PNDPGZBMCMUPRI-UHFFFAOYSA-N iodine Chemical compound II PNDPGZBMCMUPRI-UHFFFAOYSA-N 0.000 description 1
- 239000002563 ionic surfactant Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
- 125000001449 isopropyl group Chemical group [H]C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 238000004898 kneading Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000004816 latex Substances 0.000 description 1
- 229920000126 latex Polymers 0.000 description 1
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 1
- 239000011976 maleic acid Substances 0.000 description 1
- 229910052748 manganese Inorganic materials 0.000 description 1
- 239000011572 manganese Substances 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 238000000691 measurement method Methods 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- RBQRWNWVPQDTJJ-UHFFFAOYSA-N methacryloyloxyethyl isocyanate Chemical compound CC(=C)C(=O)OCCN=C=O RBQRWNWVPQDTJJ-UHFFFAOYSA-N 0.000 description 1
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 1
- 239000011259 mixed solution Substances 0.000 description 1
- 239000003607 modifier Substances 0.000 description 1
- MQWFLKHKWJMCEN-UHFFFAOYSA-N n'-[3-[dimethoxy(methyl)silyl]propyl]ethane-1,2-diamine Chemical compound CO[Si](C)(OC)CCCNCCN MQWFLKHKWJMCEN-UHFFFAOYSA-N 0.000 description 1
- ZQXSMRAEXCEDJD-UHFFFAOYSA-N n-ethenylformamide Chemical class C=CNC=O ZQXSMRAEXCEDJD-UHFFFAOYSA-N 0.000 description 1
- 125000001280 n-hexyl group Chemical group C(CCCCC)* 0.000 description 1
- 125000000740 n-pentyl group Chemical group [H]C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])* 0.000 description 1
- JTHNLKXLWOXOQK-UHFFFAOYSA-N n-propyl vinyl ketone Natural products CCCC(=O)C=C JTHNLKXLWOXOQK-UHFFFAOYSA-N 0.000 description 1
- 239000002086 nanomaterial Substances 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 239000004745 nonwoven fabric Substances 0.000 description 1
- 125000003518 norbornenyl group Chemical group C12(C=CC(CC1)C2)* 0.000 description 1
- 229920001778 nylon Polymers 0.000 description 1
- 150000002892 organic cations Chemical group 0.000 description 1
- BMMGVYCKOGBVEV-UHFFFAOYSA-N oxo(oxoceriooxy)cerium Chemical compound [Ce]=O.O=[Ce]=O BMMGVYCKOGBVEV-UHFFFAOYSA-N 0.000 description 1
- 125000006353 oxyethylene group Chemical group 0.000 description 1
- 239000000123 paper Substances 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- JRKICGRDRMAZLK-UHFFFAOYSA-L peroxydisulfate Chemical compound [O-]S(=O)(=O)OOS([O-])(=O)=O JRKICGRDRMAZLK-UHFFFAOYSA-L 0.000 description 1
- 150000003014 phosphoric acid esters Chemical class 0.000 description 1
- 239000004014 plasticizer Substances 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920001281 polyalkylene Polymers 0.000 description 1
- 229920006122 polyamide resin Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001230 polyarylate Polymers 0.000 description 1
- 229920002857 polybutadiene Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 239000004417 polycarbonate Substances 0.000 description 1
- 229920000515 polycarbonate Polymers 0.000 description 1
- 239000004431 polycarbonate resin Substances 0.000 description 1
- 229920005668 polycarbonate resin Polymers 0.000 description 1
- 150000004291 polyenes Chemical class 0.000 description 1
- 229920006267 polyester film Polymers 0.000 description 1
- 229920002530 polyetherether ketone Polymers 0.000 description 1
- 229920002959 polymer blend Polymers 0.000 description 1
- 239000003505 polymerization initiator Substances 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 239000011116 polymethylpentene Substances 0.000 description 1
- 229920000306 polymethylpentene Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920002503 polyoxyethylene-polyoxypropylene Polymers 0.000 description 1
- 229920006324 polyoxymethylene Polymers 0.000 description 1
- 229920006264 polyurethane film Polymers 0.000 description 1
- 239000005033 polyvinylidene chloride Substances 0.000 description 1
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 1
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 1
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- USHAGKDGDHPEEY-UHFFFAOYSA-L potassium persulfate Chemical compound [K+].[K+].[O-]S(=O)(=O)OOS([O-])(=O)=O USHAGKDGDHPEEY-UHFFFAOYSA-L 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- AAYRWMCIKCRHIN-UHFFFAOYSA-N propane-1-sulfonic acid;prop-2-enamide Chemical compound NC(=O)C=C.CCCS(O)(=O)=O AAYRWMCIKCRHIN-UHFFFAOYSA-N 0.000 description 1
- ZMYXZXUHYAGGKG-UHFFFAOYSA-N propoxysilane Chemical compound CCCO[SiH3] ZMYXZXUHYAGGKG-UHFFFAOYSA-N 0.000 description 1
- 125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
- UMJSCPRVCHMLSP-UHFFFAOYSA-N pyridine Natural products COC1=CC=CN=C1 UMJSCPRVCHMLSP-UHFFFAOYSA-N 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009257 reactivity Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 230000002441 reversible effect Effects 0.000 description 1
- 125000002914 sec-butyl group Chemical group [H]C([H])([H])C([H])([H])C([H])(*)C([H])([H])[H] 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
- RMAQACBXLXPBSY-UHFFFAOYSA-N silicic acid Chemical compound O[Si](O)(O)O RMAQACBXLXPBSY-UHFFFAOYSA-N 0.000 description 1
- 229920005573 silicon-containing polymer Polymers 0.000 description 1
- 239000002356 single layer Substances 0.000 description 1
- 229940083542 sodium Drugs 0.000 description 1
- 229940080264 sodium dodecylbenzenesulfonate Drugs 0.000 description 1
- 235000019333 sodium laurylsulphate Nutrition 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000005846 sugar alcohols Polymers 0.000 description 1
- 150000003457 sulfones Chemical class 0.000 description 1
- 125000000542 sulfonic acid group Chemical group 0.000 description 1
- 230000008961 swelling Effects 0.000 description 1
- 229920003051 synthetic elastomer Polymers 0.000 description 1
- 239000005061 synthetic rubber Substances 0.000 description 1
- 125000000999 tert-butyl group Chemical group [H]C([H])([H])C(*)(C([H])([H])[H])C([H])([H])[H] 0.000 description 1
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 1
- UWHCKJMYHZGTIT-UHFFFAOYSA-N tetraethylene glycol Chemical compound OCCOCCOCCOCCO UWHCKJMYHZGTIT-UHFFFAOYSA-N 0.000 description 1
- FAGUFWYHJQFNRV-UHFFFAOYSA-N tetraethylenepentamine Chemical compound NCCNCCNCCNCCN FAGUFWYHJQFNRV-UHFFFAOYSA-N 0.000 description 1
- 229920001187 thermosetting polymer Polymers 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- 125000003944 tolyl group Chemical group 0.000 description 1
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- SGCFZHOZKKQIBU-UHFFFAOYSA-N tributoxy(ethenyl)silane Chemical compound CCCCO[Si](OCCCC)(OCCCC)C=C SGCFZHOZKKQIBU-UHFFFAOYSA-N 0.000 description 1
- FRGPKMWIYVTFIQ-UHFFFAOYSA-N triethoxy(3-isocyanatopropyl)silane Chemical compound CCO[Si](OCC)(OCC)CCCN=C=O FRGPKMWIYVTFIQ-UHFFFAOYSA-N 0.000 description 1
- WDUXKFKVDQRWJN-UHFFFAOYSA-N triethoxysilylmethyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)COC(=O)C=C WDUXKFKVDQRWJN-UHFFFAOYSA-N 0.000 description 1
- ZIBGPFATKBEMQZ-UHFFFAOYSA-N triethylene glycol Chemical compound OCCOCCOCCO ZIBGPFATKBEMQZ-UHFFFAOYSA-N 0.000 description 1
- DQZNLOXENNXVAD-UHFFFAOYSA-N trimethoxy-[2-(7-oxabicyclo[4.1.0]heptan-4-yl)ethyl]silane Chemical compound C1C(CC[Si](OC)(OC)OC)CCC2OC21 DQZNLOXENNXVAD-UHFFFAOYSA-N 0.000 description 1
- BPSIOYPQMFLKFR-UHFFFAOYSA-N trimethoxy-[3-(oxiran-2-ylmethoxy)propyl]silane Chemical compound CO[Si](OC)(OC)CCCOCC1CO1 BPSIOYPQMFLKFR-UHFFFAOYSA-N 0.000 description 1
- JPPHEZSCZWYTOP-UHFFFAOYSA-N trimethoxysilylmethyl prop-2-enoate Chemical compound CO[Si](OC)(OC)COC(=O)C=C JPPHEZSCZWYTOP-UHFFFAOYSA-N 0.000 description 1
- 229910052720 vanadium Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
- 229920001567 vinyl ester resin Polymers 0.000 description 1
- 239000004034 viscosity adjusting agent Substances 0.000 description 1
- 238000004383 yellowing Methods 0.000 description 1
- 229910052727 yttrium Inorganic materials 0.000 description 1
- 229910052725 zinc Inorganic materials 0.000 description 1
- 239000011701 zinc Substances 0.000 description 1
- 239000011592 zinc chloride Substances 0.000 description 1
- 235000005074 zinc chloride Nutrition 0.000 description 1
- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
- 229960001763 zinc sulfate Drugs 0.000 description 1
- 229910000368 zinc sulfate Inorganic materials 0.000 description 1
- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/314—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Liquid Crystal (AREA)
- Polarising Elements (AREA)
Abstract
【解決手段】炭素数4〜14のアルキル基を有するアルキル(メタ)アクリレートを含むモノマー成分を、界面活性剤の存在下、重合して得られる(メタ)アクリル系ポリマーを含む透明導電層用水分散型粘着剤組成物であって、前記界面活性剤が、オキシアルキレン繰り返し単位を3以下含む反応性界面活性剤、及び/又は、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とする透明導電層用水分散型粘着剤組成物である。
【選択図】図1
Description
前記界面活性剤が、オキシアルキレン繰り返し単位を3以下含む反応性界面活性剤、及び/又は、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とする透明導電層用水分散型粘着剤組成物に関する。
本発明の透明導電層用水分散型粘着剤組成物は、炭素数4〜14のアルキル基を有するアルキル(メタ)アクリレートを含むモノマー成分を、界面活性剤の存在下、重合して得られる(メタ)アクリル系ポリマーを含み、前記界面活性剤が、オキシアルキレン繰り返し単位を3以下含む反応性界面活性剤、及び/又は、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とするものである。
本発明の透明導電層用粘着剤層は、前記透明導電層用水分散型粘着剤組成物から形成されるものである。
本発明の粘着剤層付き光学フィルムは、光学フィルムの一方の面に、前記透明導電層用粘着剤層を形成したものである。当該粘着剤層付き光学フィルムは、本発明の粘着剤層を有するため、金属酸化物により形成された透明導電性薄膜に直接貼り合せても、透明導電性薄膜の腐食を抑制することができるものである。
本発明の粘着剤層付き光学フィルムの粘着剤層は、透明導電性薄膜層に直接貼付されても、透明導電性薄膜の腐食を抑制することができるため、透明導電性薄膜層を有する液晶セル等にも貼付することができる。従って、本発明の粘着剤層付き光学フィルムは、各種液晶表示装置において好適に用いることができる。
(水分散液の調製)
容器に、原料としてブチルアクリレート1000部、アクリル酸70部、モノ[ポリ(プロピレンオキシド)メタクリレート]リン酸エステル(プロピレンオキシドの平均重合度5.0)28部、及び3−メタクリロイルオキシプロピル−トリエトキシシラン(信越化学工業(株)製、KBM−503)0.69部を加えて混合し、モノマー混合物を得た。次いで、上記割合で調製したモノマー混合物600部に対して、反応性界面活性剤としてエレミノールJS−20(三洋化成工業(株)製)10部(固形分量で4部)、イオン交換水360部を加え、ホモジナイザー(特殊機化工業(株)製)を用い、3分間、7000rpmで攪拌し、モノマーエマルションを調製した。
次いで、上記水分散液(エマルション)100重量部に、濃度10%のアンモニア水3部を添加し、水分散型粘着剤組成物を調製した。
上記水分散型粘着剤組成物を、乾燥後の厚みが25μmとなるように、離型フィルム(三菱化学ポリエステル(株)製、ダイアホイルMRF−38、ポリエチレンテレフタレート基材)上にアプリケーターにより塗布した後、熱風循環式オーブンにより150℃で10分間乾燥して、透明導電層用粘着剤層(透明導電層用粘着剤層付き離型フィルム)を形成した。
厚さ80μmのポリビニルアルコールフィルムを40℃のヨウ素水溶液中で5倍に延伸したのち50℃で4分間乾燥させて偏光子を得た。この偏光子の両側にトリアセチルセルロースフィルムを、ポリビニルアルコール系接着剤を用いて接着して偏光板を得た。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例2の(水分散液の調製)において、モノマー混合物600部に対して、リン酸基含有エステル(商品名:フォスファノールSM−172、東邦化学工業(株)製)を0.6部添加したこと以外は、実施例2と同様にして粘着剤層付き偏光板を作製した。
実施例3の(水分散液の調製)において、リン酸基含有エステルの添加量を0.6部から6部に変えたこと以外は、実施例3と同様にして粘着剤層付き偏光板を作製した。
実施例3の(水分散液の調製)において、リン酸基含有エステルの種類をフォスファノールSM−172(商品名、東邦化学工業(株)製)からフォスファノールBH−650(商品名、東邦化学工業(株)製)に変えたこと以外は、実施例3と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水の添加量を3部から0.5部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から30部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の種類をエレミノールJS−20(三洋化成工業(株)製)から、ラテムルS−180A(花王(株)製)に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水の添加量を3部から0.5部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)30部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
比較例1の(水分散液の調製)において、モノマー混合物600部に対して、リン酸基含有エステル(商品名:フォスファノールSM−172、東邦化学工業(株)製)を0.6部添加したこと以外は、比較例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アデカリアソープSE−10(ADEKA(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アデカリアソープSE−10(ADEKA(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アントックスMS−60(日本乳化剤(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アントックスMS−60(日本乳化剤(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤であるエレミノールJS−20(三洋化成工業(株)製)4部から、非反応性ラテムルE−150(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤であるエレミノールJS−20(三洋化成工業(株)製)4部から、非反応性エマール2F−30(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、100℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
粘着剤層の厚みは、ダイヤルゲージを用いて、離型フィルム上に形成された透明導電層用粘着剤層の全体厚さを測定し、その全体厚さから、離型フィルムの厚さを引くことにより求めた。
粘着剤層付き偏光板を15インチサイズに切りだし、サンプルを作製した。このサンプルをガラス板に貼り合せて偏光度を測定した。この時の偏光度を初期偏光度(A)とする。また、前記サンプルを80℃の環境下及び60℃、90%R.H.の環境下にそれぞれ500時間放置した後、前記と同様にして偏光度を測定した。この時の偏光度を処理後偏光度(B)とした。偏光度は、分光光度計(DOT−3C、(株)村上色彩研究所製)にて測定した。初期偏光度(A)と処理後偏光度(B)から、偏光度変化量(A−B)を算出した。
(結晶性ITO薄膜を有するフィルムの準備)
厚さ22nmの結晶性ITO薄膜を有するフィルムとして、日東電工(株)製のエレクリスタV270L−TFMEを用いた。当該結晶性ITO薄膜を有するフィルムは、評価試験前に140℃で90分間加熱処理を行った。処理後のフィルムのITO薄膜は結晶化されていた。
厚さ22nmの非晶性ITO薄膜を有するフィルムとして、日東電工(株)製のエレクリスタP400L−TNMEを用いた。当該非晶性ITO薄膜を有するフィルムは、評価試験前に140℃で90分間加熱処理を行った。処理後のフィルムのITO薄膜はアモルファスであった。
抵抗値の上昇率(%)=(投入後抵抗値/投入前抵抗値)×100
前記抵抗値の上昇率は低いほど好ましく、前記抵抗値の上昇率が130%以下であれば、耐腐食性を満足すると判断できる。
○:抵抗値の上昇率が130%以下
×:抵抗値の上昇率が130%を超える
粘着剤層付き偏光板を、9cm×9cmに切断し、離型フィルムを剥がした後に、純水中で、120℃で1時間の煮沸抽出を行った。この抽出液から、イオンクロマトグラム(DIONEX社製、DX−500)によりアンモニウムイオンを定量した。5検体について測定し、その値から平均値を導き、それを1cm2あたりに換算した値をアンモニウム成分量とした。
1’ アンカー層
2 透明導電層用粘着剤層
3 透明導電層
4 液晶セル
5 粘着剤層
6 光学フィルム
Claims (13)
- 炭素数4〜14のアルキル基を有するアルキル(メタ)アクリレートを含むモノマー成分を、界面活性剤の存在下、重合して得られる(メタ)アクリル系ポリマーを含む透明導電層用水分散型粘着剤組成物であって、
前記界面活性剤が、オキシアルキレン繰り返し単位を3以下含む反応性界面活性剤、及び/又は、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とする透明導電層用水分散型粘着剤組成物。 - 前記界面活性剤が、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とする請求項1に記載の透明導電層用水分散型粘着剤組成物。
- 前記界面活性剤の添加量が、(メタ)アクリル系ポリマーを構成する全モノマー成分100重量部に対して、0.1〜30重量部であることを特徴とする請求項1又は2に記載の透明導電層用水分散型粘着剤組成物。
- 前記モノマー成分が、カルボキシル基含有モノマーをさらに含み、前記カルボキシル基含有モノマーが、前記炭素数4〜14のアルキル基を有するアルキル(メタ)アクリレート100重量部に対して1〜8重量部であることを特徴とする請求項1〜3のいずれかに記載の透明導電層用水分散型粘着剤組成物。
- さらに、水溶性塩基性成分を含有することを特徴とする請求項1〜4のいずれかに記載の透明導電層用水分散型粘着剤組成物。
- 前記水溶性塩基性成分がアンモニアであることを特徴とする請求項5に記載の透明導電層用水分散型粘着剤組成物。
- さらに、リン酸エステル系化合物を含有することを特徴とする請求項1〜6のいずれかに記載の透明導電層用水分散型粘着剤組成物。
- 前記リン酸エステル系化合物が、非重合性化合物であることを特徴とする請求項7に記載の透明導電層用水分散型粘着剤組成物。
- 前記リン酸エステル系化合物の添加量が、前記(メタ)アクリル系ポリマーを構成する全モノマー成分100重量部に対して0.005〜5重量部であることを特徴とする請求項7又は8に記載の透明導電層用水分散型粘着剤組成物。
- 請求項1〜9のいずれかに記載の透明導電層用水分散型粘着剤組成物から形成されることを特徴とする透明導電層用粘着剤層。
- 1cm2あたりの水溶性塩基性成分含有量が1000ng以下であることを特徴とする請求項10に記載の透明導電層用粘着剤層。
- 光学フィルムの一方の面に、請求項10又は11のいずれかに記載の透明導電層用粘着剤層を有することを特徴とする粘着剤層付き光学フィルム。
- 請求項12に記載の粘着剤層付き光学フィルムを用いたことを特徴とする液晶表示装置。
Priority Applications (6)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2013262192A JP6344812B2 (ja) | 2012-12-28 | 2013-12-19 | 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 |
PCT/JP2013/084313 WO2014103952A1 (ja) | 2012-12-28 | 2013-12-20 | 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 |
CN201380059122.1A CN104781363B (zh) | 2012-12-28 | 2013-12-20 | 透明导电层用水分散型粘合剂组合物、透明导电层用粘合剂层、带有粘合剂层的光学膜、和液晶显示装置 |
KR1020157015818A KR102153297B1 (ko) | 2012-12-28 | 2013-12-20 | 투명 도전층용 수분산형 점착제 조성물, 투명 도전층용 점착제층, 점착제층이 형성된 광학 필름, 및 액정 표시 장치 |
US14/655,933 US20150353787A1 (en) | 2012-12-28 | 2013-12-20 | Water-dispersible pressure-sensitive adhesive composition for transparent conductive layer, pressure-sensitive adhesive layer for transparent conductive layer, pressure-sensitive adhesive layer-attached optical film, and liquid crystal display device |
TW102148263A TWI610999B (zh) | 2012-12-28 | 2013-12-25 | 透明導電層用水分散型黏著劑組合物、透明導電層用黏著劑層、附有黏著劑層之光學膜、及液晶顯示裝置 |
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2012287737 | 2012-12-28 | ||
JP2012287737 | 2012-12-28 | ||
JP2013262192A JP6344812B2 (ja) | 2012-12-28 | 2013-12-19 | 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 |
Publications (2)
Publication Number | Publication Date |
---|---|
JP2014141647A true JP2014141647A (ja) | 2014-08-07 |
JP6344812B2 JP6344812B2 (ja) | 2018-06-20 |
Family
ID=51021035
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
JP2013262192A Active JP6344812B2 (ja) | 2012-12-28 | 2013-12-19 | 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 |
Country Status (6)
Country | Link |
---|---|
US (1) | US20150353787A1 (ja) |
JP (1) | JP6344812B2 (ja) |
KR (1) | KR102153297B1 (ja) |
CN (1) | CN104781363B (ja) |
TW (1) | TWI610999B (ja) |
WO (1) | WO2014103952A1 (ja) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR20160078257A (ko) * | 2014-12-24 | 2016-07-04 | 닛토덴코 가부시키가이샤 | 코팅층이 형성된 편광 필름, 점착제층이 형성된 편광 필름, 및 화상 표시 장치 |
WO2016158513A1 (ja) * | 2015-03-31 | 2016-10-06 | 日東電工株式会社 | 液晶パネル及び画像表示装置 |
WO2017057097A1 (ja) * | 2015-09-30 | 2017-04-06 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
WO2017057102A1 (ja) * | 2015-09-30 | 2017-04-06 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
JPWO2018181477A1 (ja) * | 2017-03-28 | 2019-06-27 | 日東電工株式会社 | インセル型液晶パネルおよび液晶表示装置 |
US11256129B2 (en) | 2017-03-28 | 2022-02-22 | Nitto Denko Corporation | In-cell liquid crystal panel and liquid crystal display device |
KR102686627B1 (ko) | 2015-09-30 | 2024-07-22 | 닛토덴코 가부시키가이샤 | 인셀 액정 패널 및 액정 표시 장치 |
Families Citing this family (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102230320B1 (ko) * | 2013-06-28 | 2021-03-19 | 닛토덴코 가부시키가이샤 | 점착제층이 형성된 편광 필름, 적층체, 및 화상 표시 장치 |
WO2014208696A1 (ja) * | 2013-06-28 | 2014-12-31 | 日東電工株式会社 | 粘着剤組成物、透明導電層用粘着剤層、積層体、及び画像表示装置 |
JP6363410B2 (ja) * | 2013-06-28 | 2018-07-25 | 日東電工株式会社 | 粘着剤組成物、透明導電層用粘着剤層、積層体、及び画像表示装置 |
JP6472172B2 (ja) * | 2013-06-28 | 2019-02-20 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付き光学フィルム、液晶表示装置、及び、積層体 |
JP6404707B2 (ja) * | 2014-01-06 | 2018-10-10 | 日東電工株式会社 | アクリル系粘着剤組成物、アクリル系粘着剤層、粘着剤層付き基材フィルム、積層体、及び画像表示装置 |
JP2017003906A (ja) * | 2015-06-15 | 2017-01-05 | 日東電工株式会社 | 両面粘着剤層付偏光フィルムおよび画像表示装置 |
WO2017170767A1 (ja) * | 2016-04-01 | 2017-10-05 | 日東電工株式会社 | 液晶調光部材、光透過性導電フィルム、および液晶調光素子 |
KR20230004917A (ko) * | 2017-03-28 | 2023-01-06 | 닛토덴코 가부시키가이샤 | 점착제층을 구비한 편광 필름, 인셀형 액정 패널용 점착제층을 구비한 편광 필름, 인셀형 액정 패널 및 액정 표시 장치 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001040313A (ja) * | 1999-07-28 | 2001-02-13 | Chuo Rika Kogyo Corp | アクリルエマルジョン型感圧接着剤およびこれを用いた感圧接着剤製品 |
JP2005089490A (ja) * | 2003-09-12 | 2005-04-07 | Diatex Co Ltd | 再剥離性粘着テープ |
JP2006045410A (ja) * | 2004-08-06 | 2006-02-16 | Nippon Synthetic Chem Ind Co Ltd:The | 再剥離型水性粘着剤組成物 |
JP2006045411A (ja) * | 2004-08-06 | 2006-02-16 | Nippon Synthetic Chem Ind Co Ltd:The | 再剥離型水性粘着剤組成物 |
WO2007007499A1 (ja) * | 2005-07-14 | 2007-01-18 | Lintec Corporation | (メタ)アクリル系エマルション型粘着剤組成物及び粘着シート |
JP2010143985A (ja) * | 2008-12-17 | 2010-07-01 | Nippon Synthetic Chem Ind Co Ltd:The | 剥離型水性粘着剤組成物、剥離型水性粘着剤、及びそれを用いた剥離型粘着部材 |
WO2011048874A1 (ja) * | 2009-10-23 | 2011-04-28 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
WO2012002178A1 (ja) * | 2010-06-28 | 2012-01-05 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP2012031295A (ja) * | 2010-07-30 | 2012-02-16 | Nitto Denko Corp | 透明導電性フィルム用粘着剤層、粘着剤層付き透明導電性フィルム、透明導電性積層体、およびタッチパネル |
Family Cites Families (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0841371A (ja) * | 1994-05-23 | 1996-02-13 | Daisutaa Japan Kk | 分散染料組成物 |
EP1628336B1 (en) * | 2004-08-18 | 2012-01-04 | Mitsubishi Gas Chemical Company, Inc. | Cleaning liquid and cleaning method |
JP5563195B2 (ja) * | 2005-01-21 | 2014-07-30 | コモンウェルス サイエンティフィック アンドインダストリアル リサーチ オーガナイゼーション | 改質物質を用いる活性化方法 |
TWI409313B (zh) * | 2005-01-26 | 2013-09-21 | Nitto Denko Corp | 黏著劑組成物、黏著型光學薄膜及影像顯示裝置 |
KR101258719B1 (ko) * | 2005-05-20 | 2013-04-26 | 닛토덴코 가부시키가이샤 | 점착제 조성물, 점착 시트 및 표면 보호 필름 |
TWI382069B (zh) * | 2009-02-25 | 2013-01-11 | Symbio Inc | 耐可塑劑之乳液型感壓黏著劑 |
JP6001241B2 (ja) * | 2010-05-18 | 2016-10-05 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP2012087290A (ja) * | 2010-09-21 | 2012-05-10 | Nitto Denko Corp | 光学フィルム用粘着剤層、その製造方法、粘着剤層付光学フィルムおよび画像表示装置 |
JP5890996B2 (ja) * | 2010-11-25 | 2016-03-22 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着剤層付光学フィルム、画像表示装置および光学フィルムの剥離方法 |
JP5893881B2 (ja) * | 2011-09-26 | 2016-03-23 | 日東電工株式会社 | 光学フィルム用粘着剤層の製造方法、光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP6023538B2 (ja) * | 2011-10-19 | 2016-11-09 | 日東電工株式会社 | 再剥離用水分散型アクリル系粘着剤組成物及び粘着シート |
JP2013148722A (ja) * | 2012-01-19 | 2013-08-01 | Nitto Denko Corp | 粘着剤層付光学フィルムおよび画像表示装置 |
JP6093624B2 (ja) * | 2012-05-24 | 2017-03-08 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着剤層付光学フィルム、及び、画像表示装置 |
JP6472172B2 (ja) * | 2013-06-28 | 2019-02-20 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付き光学フィルム、液晶表示装置、及び、積層体 |
-
2013
- 2013-12-19 JP JP2013262192A patent/JP6344812B2/ja active Active
- 2013-12-20 US US14/655,933 patent/US20150353787A1/en not_active Abandoned
- 2013-12-20 WO PCT/JP2013/084313 patent/WO2014103952A1/ja active Application Filing
- 2013-12-20 CN CN201380059122.1A patent/CN104781363B/zh active Active
- 2013-12-20 KR KR1020157015818A patent/KR102153297B1/ko active IP Right Grant
- 2013-12-25 TW TW102148263A patent/TWI610999B/zh active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2001040313A (ja) * | 1999-07-28 | 2001-02-13 | Chuo Rika Kogyo Corp | アクリルエマルジョン型感圧接着剤およびこれを用いた感圧接着剤製品 |
JP2005089490A (ja) * | 2003-09-12 | 2005-04-07 | Diatex Co Ltd | 再剥離性粘着テープ |
JP2006045410A (ja) * | 2004-08-06 | 2006-02-16 | Nippon Synthetic Chem Ind Co Ltd:The | 再剥離型水性粘着剤組成物 |
JP2006045411A (ja) * | 2004-08-06 | 2006-02-16 | Nippon Synthetic Chem Ind Co Ltd:The | 再剥離型水性粘着剤組成物 |
WO2007007499A1 (ja) * | 2005-07-14 | 2007-01-18 | Lintec Corporation | (メタ)アクリル系エマルション型粘着剤組成物及び粘着シート |
JP2010143985A (ja) * | 2008-12-17 | 2010-07-01 | Nippon Synthetic Chem Ind Co Ltd:The | 剥離型水性粘着剤組成物、剥離型水性粘着剤、及びそれを用いた剥離型粘着部材 |
WO2011048874A1 (ja) * | 2009-10-23 | 2011-04-28 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
WO2012002178A1 (ja) * | 2010-06-28 | 2012-01-05 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP2012031295A (ja) * | 2010-07-30 | 2012-02-16 | Nitto Denko Corp | 透明導電性フィルム用粘着剤層、粘着剤層付き透明導電性フィルム、透明導電性積層体、およびタッチパネル |
Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2016122054A (ja) * | 2014-12-24 | 2016-07-07 | 日東電工株式会社 | コーティング層付偏光フィルム、粘着剤層付偏光フィルム、及び画像表示装置 |
KR20160078257A (ko) * | 2014-12-24 | 2016-07-04 | 닛토덴코 가부시키가이샤 | 코팅층이 형성된 편광 필름, 점착제층이 형성된 편광 필름, 및 화상 표시 장치 |
KR102528043B1 (ko) * | 2014-12-24 | 2023-05-02 | 닛토덴코 가부시키가이샤 | 코팅층이 형성된 편광 필름, 점착제층이 형성된 편광 필름, 및 화상 표시 장치 |
TWI645233B (zh) * | 2015-03-31 | 2018-12-21 | 日商日東電工股份有限公司 | Liquid crystal panel and image display device |
WO2016158513A1 (ja) * | 2015-03-31 | 2016-10-06 | 日東電工株式会社 | 液晶パネル及び画像表示装置 |
JP2016191865A (ja) * | 2015-03-31 | 2016-11-10 | 日東電工株式会社 | 液晶パネル及び画像表示装置 |
TWI677736B (zh) * | 2015-03-31 | 2019-11-21 | 日商日東電工股份有限公司 | 液晶面板及圖像顯示裝置 |
WO2017057097A1 (ja) * | 2015-09-30 | 2017-04-06 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
JP2017068026A (ja) * | 2015-09-30 | 2017-04-06 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
WO2017057102A1 (ja) * | 2015-09-30 | 2017-04-06 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
TWI784930B (zh) * | 2015-09-30 | 2022-12-01 | 日商日東電工股份有限公司 | 內置型液晶面板及液晶顯示裝置 |
JP2017068022A (ja) * | 2015-09-30 | 2017-04-06 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
KR102686627B1 (ko) | 2015-09-30 | 2024-07-22 | 닛토덴코 가부시키가이샤 | 인셀 액정 패널 및 액정 표시 장치 |
JPWO2018181477A1 (ja) * | 2017-03-28 | 2019-06-27 | 日東電工株式会社 | インセル型液晶パネルおよび液晶表示装置 |
JP2019105828A (ja) * | 2017-03-28 | 2019-06-27 | 日東電工株式会社 | インセル型液晶パネルおよび液晶表示装置 |
JP2020091482A (ja) * | 2017-03-28 | 2020-06-11 | 日東電工株式会社 | インセル型液晶パネルおよび液晶表示装置 |
US11216127B2 (en) | 2017-03-28 | 2022-01-04 | Nitto Denko Corporation | In-cell liquid crystal panel and liquid crystal display device |
US11256129B2 (en) | 2017-03-28 | 2022-02-22 | Nitto Denko Corporation | In-cell liquid crystal panel and liquid crystal display device |
Also Published As
Publication number | Publication date |
---|---|
TWI610999B (zh) | 2018-01-11 |
JP6344812B2 (ja) | 2018-06-20 |
KR102153297B1 (ko) | 2020-09-08 |
WO2014103952A1 (ja) | 2014-07-03 |
CN104781363A (zh) | 2015-07-15 |
US20150353787A1 (en) | 2015-12-10 |
KR20150102978A (ko) | 2015-09-09 |
TW201431997A (zh) | 2014-08-16 |
CN104781363B (zh) | 2018-05-08 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
JP6344812B2 (ja) | 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 | |
JP6472172B2 (ja) | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付き光学フィルム、液晶表示装置、及び、積層体 | |
JP5612388B2 (ja) | 透明導電性フィルム用粘着剤層、粘着剤層付き透明導電性フィルム、透明導電性積層体、およびタッチパネル | |
JP6138002B2 (ja) | 透明導電膜用粘着剤層付偏光フィルム、積層体、及び、画像表示装置 | |
JP6001255B2 (ja) | 粘着シート | |
WO2014208695A1 (ja) | 粘着剤層付偏光フィルム、積層体、及び、画像表示装置 | |
JP5250292B2 (ja) | 粘着型光学フィルム | |
JP5000171B2 (ja) | 粘着フィルムおよび画像表示装置 | |
JP6404707B2 (ja) | アクリル系粘着剤組成物、アクリル系粘着剤層、粘着剤層付き基材フィルム、積層体、及び画像表示装置 | |
JP6178229B2 (ja) | 液晶パネル、及び画像表示装置 | |
WO2014208696A1 (ja) | 粘着剤組成物、透明導電層用粘着剤層、積層体、及び画像表示装置 | |
JP2020076105A (ja) | 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルム、及び画像表示装置 | |
JP2012031390A (ja) | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 | |
KR20160027012A (ko) | 점착제층이 형성된 편광 필름, 적층체, 및 화상 표시 장치 | |
JP5336323B2 (ja) | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 | |
JP5520187B2 (ja) | 透明導電性フィルム用粘着剤層、粘着剤層付き透明導電性フィルム、透明導電性積層体、およびタッチパネル | |
JP2015071740A (ja) | アクリル系粘着剤組成物、アクリル系粘着剤層の製造方法及び当該製造方法により得られるアクリル系粘着剤層、粘着剤層付偏光フィルム、積層体、画像表示装置、並びに、アクリル系粘着剤組成物の架橋促進方法 | |
JP5552364B2 (ja) | 光学フィルム用水分散型粘着剤組成物、光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 | |
WO2016159003A1 (ja) | 粘着剤組成物、粘着剤層、粘着剤層付偏光フィルム、及び画像表示装置 | |
JP6363410B2 (ja) | 粘着剤組成物、透明導電層用粘着剤層、積層体、及び画像表示装置 | |
WO2014208699A1 (ja) | アクリル系粘着剤組成物、粘着剤層の製造方法、粘着剤層付偏光フィルム及びアクリル系粘着剤組成物の架橋促進方法 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
A621 | Written request for application examination |
Free format text: JAPANESE INTERMEDIATE CODE: A621 Effective date: 20160923 |
|
A131 | Notification of reasons for refusal |
Free format text: JAPANESE INTERMEDIATE CODE: A131 Effective date: 20171212 |
|
A521 | Request for written amendment filed |
Free format text: JAPANESE INTERMEDIATE CODE: A523 Effective date: 20180205 |
|
TRDD | Decision of grant or rejection written | ||
A01 | Written decision to grant a patent or to grant a registration (utility model) |
Free format text: JAPANESE INTERMEDIATE CODE: A01 Effective date: 20180516 |
|
A61 | First payment of annual fees (during grant procedure) |
Free format text: JAPANESE INTERMEDIATE CODE: A61 Effective date: 20180518 |
|
R150 | Certificate of patent or registration of utility model |
Ref document number: 6344812 Country of ref document: JP Free format text: JAPANESE INTERMEDIATE CODE: R150 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |
|
R250 | Receipt of annual fees |
Free format text: JAPANESE INTERMEDIATE CODE: R250 |