JP6344812B2 - 透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 - Google Patents
透明導電層用水分散型粘着剤組成物、透明導電層用粘着剤層、粘着剤層付き光学フィルム、及び、液晶表示装置 Download PDFInfo
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- WDUXKFKVDQRWJN-UHFFFAOYSA-N triethoxysilylmethyl prop-2-enoate Chemical compound CCO[Si](OCC)(OCC)COC(=O)C=C WDUXKFKVDQRWJN-UHFFFAOYSA-N 0.000 description 1
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- NWONKYPBYAMBJT-UHFFFAOYSA-L zinc sulfate Chemical compound [Zn+2].[O-]S([O-])(=O)=O NWONKYPBYAMBJT-UHFFFAOYSA-L 0.000 description 1
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- 229910052726 zirconium Inorganic materials 0.000 description 1
Images
Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/10—Homopolymers or copolymers of methacrylic acid esters
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/04—Homopolymers or copolymers of esters
- C09J133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09J133/08—Homopolymers or copolymers of acrylic acid esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
- C09J7/38—Pressure-sensitive adhesives [PSA]
- C09J7/381—Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/385—Acrylic polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2203/00—Applications of adhesives in processes or use of adhesives in the form of films or foils
- C09J2203/318—Applications of adhesives in processes or use of adhesives in the form of films or foils for the production of liquid crystal displays
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2301/00—Additional features of adhesives in the form of films or foils
- C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
- C09J2301/314—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive layer and/or the carrier being conductive
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2433/00—Presence of (meth)acrylic polymer
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Adhesive Tapes (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Liquid Crystal (AREA)
- Polarising Elements (AREA)
Description
前記界面活性剤が、オキシアルキレン繰り返し単位を3以下含む反応性界面活性剤、及び/又は、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とする透明導電層用水分散型粘着剤組成物に関する。
本発明の透明導電層用水分散型粘着剤組成物は、炭素数4〜14のアルキル基を有するアルキル(メタ)アクリレートを含むモノマー成分を、界面活性剤の存在下、重合して得られる(メタ)アクリル系ポリマーを含み、前記界面活性剤が、オキシアルキレン繰り返し単位を3以下含む反応性界面活性剤、及び/又は、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とするものである。
本発明の透明導電層用粘着剤層は、前記透明導電層用水分散型粘着剤組成物から形成されるものである。
本発明の粘着剤層付き光学フィルムは、光学フィルムの一方の面に、前記透明導電層用粘着剤層を形成したものである。当該粘着剤層付き光学フィルムは、本発明の粘着剤層を有するため、金属酸化物により形成された透明導電性薄膜に直接貼り合せても、透明導電性薄膜の腐食を抑制することができるものである。
本発明の粘着剤層付き光学フィルムの粘着剤層は、透明導電性薄膜層に直接貼付されても、透明導電性薄膜の腐食を抑制することができるため、透明導電性薄膜層を有する液晶セル等にも貼付することができる。従って、本発明の粘着剤層付き光学フィルムは、各種液晶表示装置において好適に用いることができる。
(水分散液の調製)
容器に、原料としてブチルアクリレート1000部、アクリル酸70部、モノ[ポリ(プロピレンオキシド)メタクリレート]リン酸エステル(プロピレンオキシドの平均重合度5.0)28部、及び3−メタクリロイルオキシプロピル−トリエトキシシラン(信越化学工業(株)製、KBM−503)0.69部を加えて混合し、モノマー混合物を得た。次いで、上記割合で調製したモノマー混合物600部に対して、反応性界面活性剤としてエレミノールJS−20(三洋化成工業(株)製)10部(固形分量で4部)、イオン交換水360部を加え、ホモジナイザー(特殊機化工業(株)製)を用い、3分間、7000rpmで攪拌し、モノマーエマルションを調製した。
次いで、上記水分散液(エマルション)100重量部に、濃度10%のアンモニア水3部を添加し、水分散型粘着剤組成物を調製した。
上記水分散型粘着剤組成物を、乾燥後の厚みが25μmとなるように、離型フィルム(三菱化学ポリエステル(株)製、ダイアホイルMRF−38、ポリエチレンテレフタレート基材)上にアプリケーターにより塗布した後、熱風循環式オーブンにより150℃で10分間乾燥して、透明導電層用粘着剤層(透明導電層用粘着剤層付き離型フィルム)を形成した。
厚さ80μmのポリビニルアルコールフィルムを40℃のヨウ素水溶液中で5倍に延伸したのち50℃で4分間乾燥させて偏光子を得た。この偏光子の両側にトリアセチルセルロースフィルムを、ポリビニルアルコール系接着剤を用いて接着して偏光板を得た。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例2の(水分散液の調製)において、モノマー混合物600部に対して、リン酸基含有エステル(商品名:フォスファノールSM−172、東邦化学工業(株)製)を0.6部添加したこと以外は、実施例2と同様にして粘着剤層付き偏光板を作製した。
実施例3の(水分散液の調製)において、リン酸基含有エステルの添加量を0.6部から6部に変えたこと以外は、実施例3と同様にして粘着剤層付き偏光板を作製した。
実施例3の(水分散液の調製)において、リン酸基含有エステルの種類をフォスファノールSM−172(商品名、東邦化学工業(株)製)からフォスファノールBH−650(商品名、東邦化学工業(株)製)に変えたこと以外は、実施例3と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水の添加量を3部から0.5部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の添加量を4部から30部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤の種類をエレミノールJS−20(三洋化成工業(株)製)から、ラテムルS−180A(花王(株)製)に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水の添加量を3部から0.5部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルS−180A(花王(株)製)30部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
比較例1の(水分散液の調製)において、モノマー混合物600部に対して、リン酸基含有エステル(商品名:フォスファノールSM−172、東邦化学工業(株)製)を0.6部添加したこと以外は、比較例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アデカリアソープSE−10(ADEKA(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アデカリアソープSE−10(ADEKA(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アントックスMS−60(日本乳化剤(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、アントックスMS−60(日本乳化剤(株)製)13部に変え、(水分散型粘着剤組成物の調製)においてアンモニア水を添加せず、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤であるエレミノールJS−20(三洋化成工業(株)製)4部から、非反応性ラテムルE−150(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤であるエレミノールJS−20(三洋化成工業(株)製)4部から、非反応性エマール2F−30(花王(株)製)13部に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、135℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
実施例1の(水分散液の調製)において、反応性界面活性剤をエレミノールJS−20(三洋化成工業(株)製)4部から、ラテムルPD−104(花王(株)製)13部に変え、(透明導電層用粘着剤層の形成)において乾燥条件を150℃、10分間から、100℃、2分間に変えたこと以外は、実施例1と同様にして粘着剤層付き偏光板を作製した。
粘着剤層の厚みは、ダイヤルゲージを用いて、離型フィルム上に形成された透明導電層用粘着剤層の全体厚さを測定し、その全体厚さから、離型フィルムの厚さを引くことにより求めた。
粘着剤層付き偏光板を15インチサイズに切りだし、サンプルを作製した。このサンプルをガラス板に貼り合せて偏光度を測定した。この時の偏光度を初期偏光度(A)とする。また、前記サンプルを80℃の環境下及び60℃、90%R.H.の環境下にそれぞれ500時間放置した後、前記と同様にして偏光度を測定した。この時の偏光度を処理後偏光度(B)とした。偏光度は、分光光度計(DOT−3C、(株)村上色彩研究所製)にて測定した。初期偏光度(A)と処理後偏光度(B)から、偏光度変化量(A−B)を算出した。
(結晶性ITO薄膜を有するフィルムの準備)
厚さ22nmの結晶性ITO薄膜を有するフィルムとして、日東電工(株)製のエレクリスタV270L−TFMEを用いた。当該結晶性ITO薄膜を有するフィルムは、評価試験前に140℃で90分間加熱処理を行った。処理後のフィルムのITO薄膜は結晶化されていた。
厚さ22nmの非晶性ITO薄膜を有するフィルムとして、日東電工(株)製のエレクリスタP400L−TNMEを用いた。当該非晶性ITO薄膜を有するフィルムは、評価試験前に140℃で90分間加熱処理を行った。処理後のフィルムのITO薄膜はアモルファスであった。
抵抗値の上昇率(%)=(投入後抵抗値/投入前抵抗値)×100
前記抵抗値の上昇率は低いほど好ましく、前記抵抗値の上昇率が130%以下であれば、耐腐食性を満足すると判断できる。
○:抵抗値の上昇率が130%以下
×:抵抗値の上昇率が130%を超える
粘着剤層付き偏光板を、9cm×9cmに切断し、離型フィルムを剥がした後に、純水中で、120℃で1時間の煮沸抽出を行った。この抽出液から、イオンクロマトグラム(DIONEX社製、DX−500)によりアンモニウムイオンを定量した。5検体について測定し、その値から平均値を導き、それを1cm2あたりに換算した値をアンモニウム成分量とした。
1’ アンカー層
2 透明導電層用粘着剤層
3 透明導電層
4 液晶セル
5 粘着剤層
6 光学フィルム
Claims (11)
- 炭素数4〜14のアルキル基を有するアルキル(メタ)アクリレートを含むモノマー成分を、界面活性剤の存在下、重合して得られる(メタ)アクリル系ポリマーと、リン酸エステル系化合物を含有し、
前記界面活性剤が、オキシアルキレン繰り返し単位を3以下含む反応性界面活性剤、及び/又は、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であり、
前記リン酸エステル系化合物の添加量が、前記(メタ)アクリル系ポリマーを構成する全モノマー成分100重量部に対して0.005〜5重量部であることを特徴とする透明導電層用水分散型粘着剤組成物。 - 前記界面活性剤が、オキシアルキレン繰り返し単位を含まない反応性界面活性剤であることを特徴とする請求項1に記載の透明導電層用水分散型粘着剤組成物。
- 前記界面活性剤の添加量が、(メタ)アクリル系ポリマーを構成する全モノマー成分100重量部に対して、0.1〜30重量部であることを特徴とする請求項1又は2に記載の透明導電層用水分散型粘着剤組成物。
- 前記モノマー成分が、カルボキシル基含有モノマーをさらに含み、前記カルボキシル基含有モノマーが、前記炭素数4〜14のアルキル基を有するアルキル(メタ)アクリレート100重量部に対して1〜8重量部であることを特徴とする請求項1〜3のいずれかに記載の透明導電層用水分散型粘着剤組成物。
- さらに、水溶性塩基性成分を含有することを特徴とする請求項1〜4のいずれかに記載の透明導電層用水分散型粘着剤組成物。
- 前記水溶性塩基性成分がアンモニアであることを特徴とする請求項5に記載の透明導電層用水分散型粘着剤組成物。
- 前記リン酸エステル系化合物が、非重合性化合物であることを特徴とする請求項1〜6のいずれかに記載の透明導電層用水分散型粘着剤組成物。
- 請求項1〜7のいずれかに記載の透明導電層用水分散型粘着剤組成物から形成されることを特徴とする透明導電層用粘着剤層。
- 1cm2あたりの水溶性塩基性成分含有量が1000ng以下であることを特徴とする請求項8に記載の透明導電層用粘着剤層。
- 光学フィルムの一方の面に、請求項8又は9に記載の透明導電層用粘着剤層を有することを特徴とする粘着剤層付き光学フィルム。
- 請求項10に記載の粘着剤層付き光学フィルムを用いたことを特徴とする液晶表示装置。
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WO2014208696A1 (ja) * | 2013-06-28 | 2014-12-31 | 日東電工株式会社 | 粘着剤組成物、透明導電層用粘着剤層、積層体、及び画像表示装置 |
JP6472172B2 (ja) | 2013-06-28 | 2019-02-20 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付き光学フィルム、液晶表示装置、及び、積層体 |
JP6363410B2 (ja) * | 2013-06-28 | 2018-07-25 | 日東電工株式会社 | 粘着剤組成物、透明導電層用粘着剤層、積層体、及び画像表示装置 |
CN105339816B (zh) * | 2013-06-28 | 2019-02-05 | 日东电工株式会社 | 带粘合剂层的偏振膜、层叠体及图像显示装置 |
JP6404707B2 (ja) * | 2014-01-06 | 2018-10-10 | 日東電工株式会社 | アクリル系粘着剤組成物、アクリル系粘着剤層、粘着剤層付き基材フィルム、積層体、及び画像表示装置 |
JP6684043B2 (ja) * | 2014-12-24 | 2020-04-22 | 日東電工株式会社 | コーティング層付偏光フィルム、粘着剤層付偏光フィルム、及び画像表示装置 |
JP6068543B2 (ja) * | 2015-03-31 | 2017-01-25 | 日東電工株式会社 | 液晶パネル及び画像表示装置 |
JP2017003906A (ja) * | 2015-06-15 | 2017-01-05 | 日東電工株式会社 | 両面粘着剤層付偏光フィルムおよび画像表示装置 |
JP6830313B2 (ja) * | 2015-09-30 | 2021-02-17 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
JP6913435B2 (ja) * | 2015-09-30 | 2021-08-04 | 日東電工株式会社 | インセル液晶パネルおよび液晶表示装置 |
WO2017170767A1 (ja) * | 2016-04-01 | 2017-10-05 | 日東電工株式会社 | 液晶調光部材、光透過性導電フィルム、および液晶調光素子 |
KR20240042201A (ko) | 2017-03-28 | 2024-04-01 | 닛토덴코 가부시키가이샤 | 인셀형 액정 패널에 사용하는 점착제층을 구비한 편광 필름 |
TWI761293B (zh) * | 2017-03-28 | 2022-04-11 | 日商日東電工股份有限公司 | 附黏著劑層之偏光薄膜 |
CN110476093A (zh) * | 2017-03-28 | 2019-11-19 | 日东电工株式会社 | 带粘合剂层的偏振膜、内嵌型液晶面板用带粘合剂层的偏振膜、内嵌型液晶面板及液晶显示装置 |
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH0841371A (ja) * | 1994-05-23 | 1996-02-13 | Daisutaa Japan Kk | 分散染料組成物 |
JP4422239B2 (ja) * | 1999-07-28 | 2010-02-24 | 中央理化工業株式会社 | アクリルエマルジョン型感圧接着剤およびこれを用いた感圧接着剤製品 |
JP4247827B2 (ja) * | 2003-09-12 | 2009-04-02 | ダイヤテックス株式会社 | 再剥離性粘着テープ |
JP4707983B2 (ja) * | 2004-08-06 | 2011-06-22 | 日本合成化学工業株式会社 | 再剥離型水性粘着剤組成物 |
JP4707982B2 (ja) * | 2004-08-06 | 2011-06-22 | 日本合成化学工業株式会社 | 再剥離型水性粘着剤組成物 |
EP1628336B1 (en) * | 2004-08-18 | 2012-01-04 | Mitsubishi Gas Chemical Company, Inc. | Cleaning liquid and cleaning method |
EP1828335B1 (en) * | 2005-01-21 | 2010-03-10 | Commonwealth Scientific And Industrial Research Organisation | Activation method using modifying agent |
TWI409313B (zh) * | 2005-01-26 | 2013-09-21 | Nitto Denko Corp | 黏著劑組成物、黏著型光學薄膜及影像顯示裝置 |
US8404344B2 (en) * | 2005-05-20 | 2013-03-26 | Nitto Denko Corporation | Pressure sensitive adhesive composition, pressure sensitive adhesive sheet and surface protective film |
JP4938256B2 (ja) * | 2005-07-14 | 2012-05-23 | リンテック株式会社 | (メタ)アクリル系エマルション型粘着剤組成物及び粘着シート |
JP5349031B2 (ja) * | 2008-12-17 | 2013-11-20 | 日本合成化学工業株式会社 | 剥離型水性粘着剤組成物、剥離型水性粘着剤、及びそれを用いた剥離型粘着部材 |
TWI382069B (zh) * | 2009-02-25 | 2013-01-11 | Symbio Inc | 耐可塑劑之乳液型感壓黏著劑 |
JP5336323B2 (ja) * | 2009-10-23 | 2013-11-06 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP6001241B2 (ja) * | 2010-05-18 | 2016-10-05 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP5917834B2 (ja) * | 2010-06-28 | 2016-05-18 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP5612388B2 (ja) * | 2010-07-30 | 2014-10-22 | 日東電工株式会社 | 透明導電性フィルム用粘着剤層、粘着剤層付き透明導電性フィルム、透明導電性積層体、およびタッチパネル |
JP2012087290A (ja) * | 2010-09-21 | 2012-05-10 | Nitto Denko Corp | 光学フィルム用粘着剤層、その製造方法、粘着剤層付光学フィルムおよび画像表示装置 |
JP5890996B2 (ja) * | 2010-11-25 | 2016-03-22 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着剤層付光学フィルム、画像表示装置および光学フィルムの剥離方法 |
JP5893881B2 (ja) * | 2011-09-26 | 2016-03-23 | 日東電工株式会社 | 光学フィルム用粘着剤層の製造方法、光学フィルム用粘着剤層、粘着型光学フィルムおよび画像表示装置 |
JP6023538B2 (ja) * | 2011-10-19 | 2016-11-09 | 日東電工株式会社 | 再剥離用水分散型アクリル系粘着剤組成物及び粘着シート |
JP2013148722A (ja) * | 2012-01-19 | 2013-08-01 | Nitto Denko Corp | 粘着剤層付光学フィルムおよび画像表示装置 |
JP6093624B2 (ja) * | 2012-05-24 | 2017-03-08 | 日東電工株式会社 | 光学フィルム用粘着剤層、粘着剤層付光学フィルム、及び、画像表示装置 |
JP6472172B2 (ja) * | 2013-06-28 | 2019-02-20 | 日東電工株式会社 | 光学フィルム用粘着剤組成物、光学フィルム用粘着剤層、粘着剤層付き光学フィルム、液晶表示装置、及び、積層体 |
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- 2013-12-20 CN CN201380059122.1A patent/CN104781363B/zh active Active
- 2013-12-20 KR KR1020157015818A patent/KR102153297B1/ko active IP Right Grant
- 2013-12-20 US US14/655,933 patent/US20150353787A1/en not_active Abandoned
- 2013-12-25 TW TW102148263A patent/TWI610999B/zh active
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KR102153297B1 (ko) | 2020-09-08 |
CN104781363A (zh) | 2015-07-15 |
WO2014103952A1 (ja) | 2014-07-03 |
TWI610999B (zh) | 2018-01-11 |
KR20150102978A (ko) | 2015-09-09 |
CN104781363B (zh) | 2018-05-08 |
TW201431997A (zh) | 2014-08-16 |
US20150353787A1 (en) | 2015-12-10 |
JP2014141647A (ja) | 2014-08-07 |
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