JP2009093178A - トナー粒子及びトナー粒子の製造方法 - Google Patents
トナー粒子及びトナー粒子の製造方法 Download PDFInfo
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- JP2009093178A JP2009093178A JP2008259492A JP2008259492A JP2009093178A JP 2009093178 A JP2009093178 A JP 2009093178A JP 2008259492 A JP2008259492 A JP 2008259492A JP 2008259492 A JP2008259492 A JP 2008259492A JP 2009093178 A JP2009093178 A JP 2009093178A
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- toner
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- metal oxide
- polymer
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- SOGRSIKDVNNTNN-UHFFFAOYSA-N naphthalene;terephthalic acid Chemical compound C1=CC=CC2=CC=CC=C21.OC(=O)C1=CC=C(C(O)=O)C=C1 SOGRSIKDVNNTNN-UHFFFAOYSA-N 0.000 description 1
- 229910017604 nitric acid Inorganic materials 0.000 description 1
- 229910052757 nitrogen Inorganic materials 0.000 description 1
- CXQXSVUQTKDNFP-UHFFFAOYSA-N octamethyltrisiloxane Chemical compound C[Si](C)(C)O[Si](C)(C)O[Si](C)(C)C CXQXSVUQTKDNFP-UHFFFAOYSA-N 0.000 description 1
- 229920002114 octoxynol-9 Polymers 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 description 1
- 150000004028 organic sulfates Chemical class 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- TWNQGVIAIRXVLR-UHFFFAOYSA-N oxo(oxoalumanyloxy)alumane Chemical compound O=[Al]O[Al]=O TWNQGVIAIRXVLR-UHFFFAOYSA-N 0.000 description 1
- SOQBVABWOPYFQZ-UHFFFAOYSA-N oxygen(2-);titanium(4+) Chemical group [O-2].[O-2].[Ti+4] SOQBVABWOPYFQZ-UHFFFAOYSA-N 0.000 description 1
- 239000003973 paint Substances 0.000 description 1
- 108091008695 photoreceptors Proteins 0.000 description 1
- 238000004987 plasma desorption mass spectroscopy Methods 0.000 description 1
- 229920001485 poly(butyl acrylate) polymer Polymers 0.000 description 1
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000767 polyaniline Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920000139 polyethylene terephthalate Polymers 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 229920001721 polyimide Polymers 0.000 description 1
- 229920001470 polyketone Polymers 0.000 description 1
- 229920005672 polyolefin resin Polymers 0.000 description 1
- 229920000259 polyoxyethylene lauryl ether Polymers 0.000 description 1
- 239000000256 polyoxyethylene sorbitan monolaurate Substances 0.000 description 1
- 235000010486 polyoxyethylene sorbitan monolaurate Nutrition 0.000 description 1
- 229920001299 polypropylene fumarate Polymers 0.000 description 1
- 229920001296 polysiloxane Polymers 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920002981 polyvinylidene fluoride Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 150000003141 primary amines Chemical class 0.000 description 1
- OIMDJNFWDDTLOZ-UHFFFAOYSA-N propyl prop-2-enoate;styrene Chemical compound CCCOC(=O)C=C.C=CC1=CC=CC=C1 OIMDJNFWDDTLOZ-UHFFFAOYSA-N 0.000 description 1
- WGYKZJWCGVVSQN-UHFFFAOYSA-N propylamine Chemical group CCCN WGYKZJWCGVVSQN-UHFFFAOYSA-N 0.000 description 1
- 150000003856 quaternary ammonium compounds Chemical class 0.000 description 1
- 239000011541 reaction mixture Substances 0.000 description 1
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 229940116351 sebacate Drugs 0.000 description 1
- 150000004756 silanes Chemical class 0.000 description 1
- 239000010703 silicon Substances 0.000 description 1
- 229910052710 silicon Inorganic materials 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000011115 styrene butadiene Substances 0.000 description 1
- 229920003048 styrene butadiene rubber Polymers 0.000 description 1
- 229920001909 styrene-acrylic polymer Polymers 0.000 description 1
- KKEYFWRCBNTPAC-UHFFFAOYSA-L terephthalate(2-) Chemical compound [O-]C(=O)C1=CC=C(C([O-])=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-L 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000010936 titanium Substances 0.000 description 1
- 229910052719 titanium Inorganic materials 0.000 description 1
- QQQSFSZALRVCSZ-UHFFFAOYSA-N triethoxysilane Chemical compound CCO[SiH](OCC)OCC QQQSFSZALRVCSZ-UHFFFAOYSA-N 0.000 description 1
- 229940075466 undecylenate Drugs 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- 239000001060 yellow colorant Substances 0.000 description 1
- NDKWCCLKSWNDBG-UHFFFAOYSA-N zinc;dioxido(dioxo)chromium Chemical compound [Zn+2].[O-][Cr]([O-])(=O)=O NDKWCCLKSWNDBG-UHFFFAOYSA-N 0.000 description 1
- 229910052845 zircon Inorganic materials 0.000 description 1
- GFQYVLUOOAAOGM-UHFFFAOYSA-N zirconium(iv) silicate Chemical compound [Zr+4].[O-][Si]([O-])([O-])[O-] GFQYVLUOOAAOGM-UHFFFAOYSA-N 0.000 description 1
Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/097—Plasticisers; Charge controlling agents
- G03G9/09708—Inorganic compounds
- G03G9/09716—Inorganic compounds treated with organic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08742—Binders for toner particles comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08755—Polyesters
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08795—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their chemical properties, e.g. acidity, molecular weight, sensitivity to reactants
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08784—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775
- G03G9/08797—Macromolecular material not specially provided for in a single one of groups G03G9/08702 - G03G9/08775 characterised by their physical properties, e.g. viscosity, solubility, melting temperature, softening temperature, glass transition temperature
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/093—Encapsulated toner particles
- G03G9/09307—Encapsulated toner particles specified by the shell material
- G03G9/09314—Macromolecular compounds
- G03G9/09328—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/093—Encapsulated toner particles
- G03G9/09307—Encapsulated toner particles specified by the shell material
- G03G9/09342—Inorganic compounds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/093—Encapsulated toner particles
- G03G9/0935—Encapsulated toner particles specified by the core material
- G03G9/09357—Macromolecular compounds
- G03G9/09371—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/093—Encapsulated toner particles
- G03G9/09392—Preparation thereof
-
- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/097—Plasticisers; Charge controlling agents
- G03G9/09708—Inorganic compounds
- G03G9/09725—Silicon-oxides; Silicates
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- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Developing Agents For Electrophotography (AREA)
Abstract
【解決手段】少なくとも1種の結着剤と、少なくとも1種の着色剤と、少なくとも1種の金属酸化物表面添加剤と、を含むトナー粒子であって、前記少なくとも1種の金属酸化物表面添加剤が、少なくとも1種の重縮合ポリマーに共有結合した金属酸化物粒子を含むことを特徴とするトナー粒子。
【選択図】なし
Description
少なくとも1種の着色剤と、
少なくとも1種の金属酸化物表面添加剤と、を含むトナー粒子であって、
前記少なくとも1種の金属酸化物表面添加剤が、少なくとも1種の重縮合ポリマーに共有結合した金属酸化物粒子を含むことを特徴とするトナー粒子が得られる。
コアの形成に続いて、シェル材料の乳化液を導入し、凝集を続けて、前記コア上に前記シェル材料から成るシェルを形成することと、
その後、凝集を止めて、コア−シェル構造のトナー粒子を回収すること
と、を含むトナー粒子の製造方法であって、
前記シェル材料は、少なくとも1種の重縮合ポリマーに共有結合した金属酸化物粒子から成る少なくとも1種の金属酸化物表面添加剤を含むことを特徴とするトナー粒子の製造方法が得られる。
以下に、官能化二酸化珪素(SiO2)ナノ粒子の官能基として働く一級アミンと共有結合を形成するための反応部位を提供する、ポリステル鎖上のエポキシ基の具体例を示す。
ステップ1:ポリエステル樹脂の官能化
Claims (2)
- 少なくとも1種の結着剤と、
少なくとも1種の着色剤と、
少なくとも1種の金属酸化物表面添加剤と、を含むトナー粒子であって、
前記少なくとも1種の金属酸化物表面添加剤が、少なくとも1種の重縮合ポリマーに共有結合した金属酸化物粒子を含むことを特徴とするトナー粒子。 - ポリマー結着剤および少なくとも1種の着色剤を含む乳化液を凝集させてコアを形成することと、
コアの形成に続いて、シェル材料の乳化液を導入し、凝集を続けて、前記コア上に前記シェル材料から成るシェルを形成することと、
その後、凝集を止めて、コア−シェル構造のトナー粒子を回収すること
と、を含むトナー粒子の製造方法であって、
前記シェル材料は、少なくとも1種の重縮合ポリマーに共有結合した金属酸化物粒子から成る少なくとも1種の金属酸化物表面添加剤を含むことを特徴とするトナー粒子の製造方法。
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US11/867,250 US8080352B2 (en) | 2007-10-04 | 2007-10-04 | Grafting metal oxides onto polymer for toner |
US11/867,250 | 2007-10-04 |
Publications (3)
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JP2009093178A true JP2009093178A (ja) | 2009-04-30 |
JP2009093178A5 JP2009093178A5 (ja) | 2011-11-24 |
JP5406500B2 JP5406500B2 (ja) | 2014-02-05 |
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JP2008259492A Active JP5406500B2 (ja) | 2007-10-04 | 2008-10-06 | トナー粒子及びトナー粒子の製造方法 |
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JP (1) | JP5406500B2 (ja) |
CA (1) | CA2639951C (ja) |
Cited By (8)
Publication number | Priority date | Publication date | Assignee | Title |
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JP2011008249A (ja) * | 2009-06-29 | 2011-01-13 | Xerox Corp | トナー組成物 |
JP2011065155A (ja) * | 2009-09-15 | 2011-03-31 | Xerox Corp | 硬化性トナー組成物およびプロセス |
JP2011242500A (ja) * | 2010-05-17 | 2011-12-01 | Konica Minolta Business Technologies Inc | 静電荷像現像用トナーの製造方法、静電荷像現像用トナー |
JP2013092748A (ja) * | 2011-10-26 | 2013-05-16 | Cabot Corp | 複合体粒子を含むトナー添加剤 |
JP2014025063A (ja) * | 2012-07-27 | 2014-02-06 | Xerox Corp | ポリエステルエマルションに対する再生可能な油の化学結合 |
JP2015045858A (ja) * | 2013-07-31 | 2015-03-12 | キヤノン株式会社 | トナー |
CN104730873A (zh) * | 2013-12-20 | 2015-06-24 | 京瓷办公信息***株式会社 | 调色剂 |
US9116462B2 (en) | 2013-11-15 | 2015-08-25 | Fuji Xerox Co., Ltd. | Image forming apparatus |
Families Citing this family (9)
Publication number | Priority date | Publication date | Assignee | Title |
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US8357749B2 (en) * | 2003-08-25 | 2013-01-22 | Dow Global Technologies Llc | Coating composition and articles made therefrom |
US8158711B2 (en) * | 2003-08-25 | 2012-04-17 | Dow Global Technologies Llc | Aqueous dispersion, its production method, and its use |
US7763676B2 (en) | 2003-08-25 | 2010-07-27 | Dow Global Technologies Inc. | Aqueous polymer dispersions and products from those dispersions |
US7803865B2 (en) | 2003-08-25 | 2010-09-28 | Dow Global Technologies Inc. | Aqueous dispersion, its production method, and its use |
US7998649B2 (en) * | 2008-03-03 | 2011-08-16 | Xerox Corporation | Grafting functionalized pearlescent or metallic pigment onto polyester polymers for special effect images |
US20120065359A1 (en) * | 2010-09-10 | 2012-03-15 | Xerox Corporation | Colorant-polyesters and methods of producing colorant-polyesters |
US8652723B2 (en) | 2011-03-09 | 2014-02-18 | Xerox Corporation | Toner particles comprising colorant-polyesters |
JP6363202B2 (ja) | 2013-12-20 | 2018-07-25 | キャボット コーポレイションCabot Corporation | 化学機械平坦化用金属酸化物‐ポリマー複合粒子 |
JP6289432B2 (ja) * | 2014-11-28 | 2018-03-07 | キヤノン株式会社 | トナー及びトナーの製造方法 |
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US4734350A (en) * | 1986-12-29 | 1988-03-29 | Xerox Corporation | Positively charged developer compositions with modified charge enhancing additives containing amino alcohols |
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JP3229174B2 (ja) * | 1995-08-21 | 2001-11-12 | 日本アエロジル株式会社 | 表面改質金属酸化物微粉末およびその製造方法 |
JP2005082765A (ja) * | 2003-09-10 | 2005-03-31 | Orient Chem Ind Ltd | 有機−無機複合材料でなる微粒子及びトナー用外添剤 |
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- 2007-10-04 US US11/867,250 patent/US8080352B2/en active Active
-
2008
- 2008-09-26 CA CA2639951A patent/CA2639951C/en not_active Expired - Fee Related
- 2008-10-06 JP JP2008259492A patent/JP5406500B2/ja active Active
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JPH06170214A (ja) * | 1992-12-11 | 1994-06-21 | Fuji Xerox Co Ltd | マイクロカプセルおよびカプセルトナーならびにマイクロカプセルの製造方法 |
JPH07271093A (ja) * | 1994-03-25 | 1995-10-20 | Tomoegawa Paper Co Ltd | 電子写真用トナー |
JP2006267231A (ja) * | 2005-03-22 | 2006-10-05 | Fuji Xerox Co Ltd | 静電荷像現像用トナー及びその製造方法、静電荷像現像剤、並びに、画像形成方法 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011008249A (ja) * | 2009-06-29 | 2011-01-13 | Xerox Corp | トナー組成物 |
JP2011065155A (ja) * | 2009-09-15 | 2011-03-31 | Xerox Corp | 硬化性トナー組成物およびプロセス |
JP2011242500A (ja) * | 2010-05-17 | 2011-12-01 | Konica Minolta Business Technologies Inc | 静電荷像現像用トナーの製造方法、静電荷像現像用トナー |
JP2013092748A (ja) * | 2011-10-26 | 2013-05-16 | Cabot Corp | 複合体粒子を含むトナー添加剤 |
JP2015502567A (ja) * | 2011-10-26 | 2015-01-22 | キャボット コーポレイションCabot Corporation | 複合材粒子を含むトナー添加剤 |
JP2014025063A (ja) * | 2012-07-27 | 2014-02-06 | Xerox Corp | ポリエステルエマルションに対する再生可能な油の化学結合 |
JP2015045858A (ja) * | 2013-07-31 | 2015-03-12 | キヤノン株式会社 | トナー |
US9116462B2 (en) | 2013-11-15 | 2015-08-25 | Fuji Xerox Co., Ltd. | Image forming apparatus |
CN104730873A (zh) * | 2013-12-20 | 2015-06-24 | 京瓷办公信息***株式会社 | 调色剂 |
JP2015121582A (ja) * | 2013-12-20 | 2015-07-02 | 京セラドキュメントソリューションズ株式会社 | トナー |
CN104730873B (zh) * | 2013-12-20 | 2019-04-19 | 京瓷办公信息***株式会社 | 调色剂 |
Also Published As
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CA2639951A1 (en) | 2009-04-04 |
US20090092918A1 (en) | 2009-04-09 |
US8080352B2 (en) | 2011-12-20 |
JP5406500B2 (ja) | 2014-02-05 |
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