JP2004189727A - 毛髪化粧料 - Google Patents
毛髪化粧料 Download PDFInfo
- Publication number
- JP2004189727A JP2004189727A JP2003388913A JP2003388913A JP2004189727A JP 2004189727 A JP2004189727 A JP 2004189727A JP 2003388913 A JP2003388913 A JP 2003388913A JP 2003388913 A JP2003388913 A JP 2003388913A JP 2004189727 A JP2004189727 A JP 2004189727A
- Authority
- JP
- Japan
- Prior art keywords
- hair
- acid
- group
- salt
- evaluation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000002537 cosmetic Substances 0.000 title claims abstract description 33
- -1 alkylene carbonate Chemical compound 0.000 claims abstract description 37
- JVTAAEKCZFNVCJ-UHFFFAOYSA-N lactic acid Chemical compound CC(O)C(O)=O JVTAAEKCZFNVCJ-UHFFFAOYSA-N 0.000 claims abstract description 32
- BJEPYKJPYRNKOW-REOHCLBHSA-N (S)-malic acid Chemical compound OC(=O)[C@@H](O)CC(O)=O BJEPYKJPYRNKOW-REOHCLBHSA-N 0.000 claims abstract description 18
- BJEPYKJPYRNKOW-UHFFFAOYSA-N alpha-hydroxysuccinic acid Natural products OC(=O)C(O)CC(O)=O BJEPYKJPYRNKOW-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000001630 malic acid Substances 0.000 claims abstract description 18
- 235000011090 malic acid Nutrition 0.000 claims abstract description 18
- 239000004310 lactic acid Substances 0.000 claims abstract description 16
- 235000014655 lactic acid Nutrition 0.000 claims abstract description 16
- 150000003839 salts Chemical class 0.000 claims abstract description 16
- 150000002596 lactones Chemical class 0.000 claims abstract description 7
- 150000003997 cyclic ketones Chemical class 0.000 claims abstract description 6
- 239000003960 organic solvent Substances 0.000 claims abstract description 6
- 229920001451 polypropylene glycol Polymers 0.000 claims abstract description 6
- 239000000203 mixture Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 17
- 229920000642 polymer Polymers 0.000 claims description 16
- 239000003676 hair preparation Substances 0.000 claims description 11
- 239000002253 acid Substances 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 4
- 238000002715 modification method Methods 0.000 claims 1
- 230000000051 modifying effect Effects 0.000 abstract description 11
- WVDDGKGOMKODPV-UHFFFAOYSA-N Benzyl alcohol Chemical compound OCC1=CC=CC=C1 WVDDGKGOMKODPV-UHFFFAOYSA-N 0.000 abstract description 6
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- 238000011156 evaluation Methods 0.000 description 40
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 30
- 230000000694 effects Effects 0.000 description 25
- 229920001296 polysiloxane Polymers 0.000 description 24
- 238000011282 treatment Methods 0.000 description 21
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 16
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 16
- 239000000126 substance Substances 0.000 description 14
- 125000000217 alkyl group Chemical group 0.000 description 13
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- CUZKCNWZBXLAJX-UHFFFAOYSA-N 2-phenylmethoxyethanol Chemical compound OCCOCC1=CC=CC=C1 CUZKCNWZBXLAJX-UHFFFAOYSA-N 0.000 description 11
- KBPLFHHGFOOTCA-UHFFFAOYSA-N 1-Octanol Chemical compound CCCCCCCCO KBPLFHHGFOOTCA-UHFFFAOYSA-N 0.000 description 10
- 239000003205 fragrance Substances 0.000 description 10
- VBIIFPGSPJYLRR-UHFFFAOYSA-M Stearyltrimethylammonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCC[N+](C)(C)C VBIIFPGSPJYLRR-UHFFFAOYSA-M 0.000 description 9
- 239000003002 pH adjusting agent Substances 0.000 description 9
- 239000004094 surface-active agent Substances 0.000 description 9
- 125000004432 carbon atom Chemical group C* 0.000 description 8
- 235000014113 dietary fatty acids Nutrition 0.000 description 8
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- 229930195729 fatty acid Natural products 0.000 description 8
- 235000011187 glycerol Nutrition 0.000 description 8
- 238000000034 method Methods 0.000 description 8
- 239000003921 oil Substances 0.000 description 8
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- 150000001875 compounds Chemical class 0.000 description 7
- 239000002453 shampoo Substances 0.000 description 7
- 239000007921 spray Substances 0.000 description 7
- LEEDMQGKBNGPDN-UHFFFAOYSA-N 2-methylnonadecane Chemical compound CCCCCCCCCCCCCCCCCC(C)C LEEDMQGKBNGPDN-UHFFFAOYSA-N 0.000 description 6
- YEJRWHAVMIAJKC-UHFFFAOYSA-N 4-Butyrolactone Chemical compound O=C1CCCO1 YEJRWHAVMIAJKC-UHFFFAOYSA-N 0.000 description 6
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- PRAKJMSDJKAYCZ-UHFFFAOYSA-N dodecahydrosqualene Natural products CC(C)CCCC(C)CCCC(C)CCCCC(C)CCCC(C)CCCC(C)C PRAKJMSDJKAYCZ-UHFFFAOYSA-N 0.000 description 6
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 description 6
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 5
- 230000037308 hair color Effects 0.000 description 5
- 238000005063 solubilization Methods 0.000 description 5
- 230000007928 solubilization Effects 0.000 description 5
- WRMNZCZEMHIOCP-UHFFFAOYSA-N 2-phenylethanol Chemical compound OCCC1=CC=CC=C1 WRMNZCZEMHIOCP-UHFFFAOYSA-N 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 4
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical group OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 4
- 230000002378 acidificating effect Effects 0.000 description 4
- 239000000443 aerosol Substances 0.000 description 4
- 239000004359 castor oil Substances 0.000 description 4
- 235000019438 castor oil Nutrition 0.000 description 4
- 239000004205 dimethyl polysiloxane Substances 0.000 description 4
- 235000013870 dimethyl polysiloxane Nutrition 0.000 description 4
- 238000001035 drying Methods 0.000 description 4
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 4
- 150000004665 fatty acids Chemical class 0.000 description 4
- 239000006260 foam Substances 0.000 description 4
- JBFHTYHTHYHCDJ-UHFFFAOYSA-N gamma-caprolactone Chemical compound CCC1CCC(=O)O1 JBFHTYHTHYHCDJ-UHFFFAOYSA-N 0.000 description 4
- 239000000499 gel Substances 0.000 description 4
- ZEMPKEQAKRGZGQ-XOQCFJPHSA-N glycerol triricinoleate Natural products CCCCCC[C@@H](O)CC=CCCCCCCCC(=O)OC[C@@H](COC(=O)CCCCCCCC=CC[C@@H](O)CCCCCC)OC(=O)CCCCCCCC=CC[C@H](O)CCCCCC ZEMPKEQAKRGZGQ-XOQCFJPHSA-N 0.000 description 4
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 4
- 230000014759 maintenance of location Effects 0.000 description 4
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- 239000002904 solvent Substances 0.000 description 4
- 239000011550 stock solution Substances 0.000 description 4
- 150000005846 sugar alcohols Polymers 0.000 description 4
- OFOBLEOULBTSOW-UHFFFAOYSA-N Malonic acid Chemical compound OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 3
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 description 3
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 3
- 150000005215 alkyl ethers Chemical class 0.000 description 3
- 239000003093 cationic surfactant Substances 0.000 description 3
- KRKNYBCHXYNGOX-UHFFFAOYSA-N citric acid Chemical compound OC(=O)CC(O)(C(O)=O)CC(O)=O KRKNYBCHXYNGOX-UHFFFAOYSA-N 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 150000002430 hydrocarbons Chemical group 0.000 description 3
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- 239000006210 lotion Substances 0.000 description 3
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 150000007522 mineralic acids Chemical class 0.000 description 3
- 229920000058 polyacrylate Polymers 0.000 description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 description 3
- 229920000036 polyvinylpyrrolidone Polymers 0.000 description 3
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 description 3
- RUOJZAUFBMNUDX-UHFFFAOYSA-N propylene carbonate Chemical compound CC1COC(=O)O1 RUOJZAUFBMNUDX-UHFFFAOYSA-N 0.000 description 3
- LDHQCZJRKDOVOX-UHFFFAOYSA-N trans-crotonic acid Natural products CC=CC(O)=O LDHQCZJRKDOVOX-UHFFFAOYSA-N 0.000 description 3
- PUPZLCDOIYMWBV-UHFFFAOYSA-N (+/-)-1,3-Butanediol Chemical compound CC(O)CCO PUPZLCDOIYMWBV-UHFFFAOYSA-N 0.000 description 2
- YYGNTYWPHWGJRM-UHFFFAOYSA-N (6E,10E,14E,18E)-2,6,10,15,19,23-hexamethyltetracosa-2,6,10,14,18,22-hexaene Chemical compound CC(C)=CCCC(C)=CCCC(C)=CCCC=C(C)CCC=C(C)CCC=C(C)C YYGNTYWPHWGJRM-UHFFFAOYSA-N 0.000 description 2
- OOCCDEMITAIZTP-QPJJXVBHSA-N (E)-cinnamyl alcohol Chemical compound OC\C=C\C1=CC=CC=C1 OOCCDEMITAIZTP-QPJJXVBHSA-N 0.000 description 2
- WNWHHMBRJJOGFJ-UHFFFAOYSA-N 16-methylheptadecan-1-ol Chemical compound CC(C)CCCCCCCCCCCCCCCO WNWHHMBRJJOGFJ-UHFFFAOYSA-N 0.000 description 2
- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 2
- CPELXLSAUQHCOX-UHFFFAOYSA-M Bromide Chemical compound [Br-] CPELXLSAUQHCOX-UHFFFAOYSA-M 0.000 description 2
- 229920002101 Chitin Polymers 0.000 description 2
- 229920001661 Chitosan Polymers 0.000 description 2
- VZCYOOQTPOCHFL-OWOJBTEDSA-N Fumaric acid Chemical compound OC(=O)\C=C\C(O)=O VZCYOOQTPOCHFL-OWOJBTEDSA-N 0.000 description 2
- AEMRFAOFKBGASW-UHFFFAOYSA-N Glycolic acid Chemical compound OCC(O)=O AEMRFAOFKBGASW-UHFFFAOYSA-N 0.000 description 2
- 241001315488 Inazuma Species 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 2
- WHNWPMSKXPGLAX-UHFFFAOYSA-N N-Vinyl-2-pyrrolidone Chemical compound C=CN1CCCC1=O WHNWPMSKXPGLAX-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- BHEOSNUKNHRBNM-UHFFFAOYSA-N Tetramethylsqualene Natural products CC(=C)C(C)CCC(=C)C(C)CCC(C)=CCCC=C(C)CCC(C)C(=C)CCC(C)C(C)=C BHEOSNUKNHRBNM-UHFFFAOYSA-N 0.000 description 2
- WNLRTRBMVRJNCN-UHFFFAOYSA-N adipic acid Chemical compound OC(=O)CCCCC(O)=O WNLRTRBMVRJNCN-UHFFFAOYSA-N 0.000 description 2
- 150000001298 alcohols Chemical class 0.000 description 2
- 125000003342 alkenyl group Chemical group 0.000 description 2
- 239000002280 amphoteric surfactant Substances 0.000 description 2
- 239000003945 anionic surfactant Substances 0.000 description 2
- 150000001450 anions Chemical class 0.000 description 2
- 239000008346 aqueous phase Substances 0.000 description 2
- YSJGOMATDFSEED-UHFFFAOYSA-M behentrimonium chloride Chemical compound [Cl-].CCCCCCCCCCCCCCCCCCCCCC[N+](C)(C)C YSJGOMATDFSEED-UHFFFAOYSA-M 0.000 description 2
- 125000001797 benzyl group Chemical group [H]C1=C([H])C([H])=C(C([H])=C1[H])C([H])([H])* 0.000 description 2
- 239000007844 bleaching agent Substances 0.000 description 2
- 238000007664 blowing Methods 0.000 description 2
- 229940006460 bromide ion Drugs 0.000 description 2
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 2
- 150000001735 carboxylic acids Chemical class 0.000 description 2
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 description 2
- 125000002091 cationic group Chemical group 0.000 description 2
- 229920006317 cationic polymer Polymers 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
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- 230000000052 comparative effect Effects 0.000 description 2
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- LDHQCZJRKDOVOX-NSCUHMNNSA-N crotonic acid Chemical compound C\C=C\C(O)=O LDHQCZJRKDOVOX-NSCUHMNNSA-N 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
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- GHVNFZFCNZKVNT-UHFFFAOYSA-N decanoic acid Chemical compound CCCCCCCCCC(O)=O GHVNFZFCNZKVNT-UHFFFAOYSA-N 0.000 description 2
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- BXWNKGSJHAJOGX-UHFFFAOYSA-N hexadecan-1-ol Chemical compound CCCCCCCCCCCCCCCCO BXWNKGSJHAJOGX-UHFFFAOYSA-N 0.000 description 2
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Landscapes
- Cosmetics (AREA)
Abstract
【解決手段】 (a)リンゴ酸又はその塩、(b)乳酸又はその塩、(c)芳香族アルコール、N-アルキルピロリドン、アルキレンカーボネート、ポリプロピレングリコール、ラクトン及び環状ケトンからなる群より選ばれる有機溶剤を含む、洗い流さないタイプの毛髪化粧料。
【選択図】 なし
Description
(a)リンゴ酸又はその塩
(b)乳酸又はその塩
(c)芳香族アルコール、N-アルキルピロリドン、アルキレンカーボネート、ポリプロピレングリコール、ラクトン及び環状ケトンからなる群より選ばれる有機溶剤
を含有する、洗い流さないタイプの毛髪化粧料を提供するものである。
表2及び3に示す毛髪化粧料を調製し、「セット性」、「ハリ・コシ向上効果」、「まとまり性」、「感触」、及び「ツヤ」の評価を行った。これらの結果を表2及び3に示す。
「セット性」の評価
1)評価毛束
パーマ、ヘアカラー等の化学処理を行っていない日本人女性の毛髪を用いて、長さ10cm、幅1.5cm、重さ1gの毛束を作り、ブリーチ処理(花王社製,ラビナス カラーアピール イナズマブリーチ使用)を2回行い、セット性評価毛束とする。
・洗髪前評価(7回処理)
評価毛束をシャンプー(花王社製,ラビナス デザイニングシャンプー)し、タオルドライした後、本発明品又は比較品(以下「処理剤」という)0.1gを均一に塗布し、70℃の温風で10分間乾燥させた。この処理を計6回繰り返した。次に上記と同様にシャンプー、タオルドライ、処理剤の塗布後、毛束を直径4cmの円柱に巻きつけ、70℃の温風で10分間乾燥させた。
毛髪表面の処理剤を洗浄した後のセット保持性を評価することにより、髪の内部の改質効果を調べた。上記洗髪前評価の終了後、各毛束をシャンプー、タオルドライし、処理剤をつけずに、直径4cmの円柱に巻きつけ、70℃の温風で10分間乾燥させた。
セットされた毛束を円柱から外し、毛束にくし(リングコーム)を20回通じて毛束をばらばらにした。これを恒温恒湿箱(25℃,98%RH)に吊し、セット保持力を判定した。判定は、吊された毛束の長さ(束ねた部分から毛先までの距離)を測定し、吊した直後の毛束の長さをセット保持率100%、カールのない元の毛束の長さ(10cm)をセット保持率0%とし、30分後における毛束の長さの相対値(%)、すなわちセット保持率を下記の式
○:60%以上90%未満
△:50%以上60%未満
×:50%未満
1)評価毛束
パーマ、ヘアカラー等の化学処理を行っていない日本人女性の毛髪を用いて、長さ25cm、重さ6gの毛束を作り、ブリーチ処理(花王社製,ラビナス カラーアピール イナズマブリーチ使用)を2回行い、評価毛束とする。
・洗髪前評価
評価毛束をシャンプー(花王社製,ラビナス デザイニングシャンプー)し、タオルドライした後、処理剤0.6gを均一に塗布し、70℃の温風でリングコームを用いてくし通ししながら10分間乾燥させた。この処理を計7回繰り返した。
髪の内部の改質効果を調べるために、上記洗髪前評価を終了した各毛束をシャンプー、タオルドライし、70℃の温風でリングコームを用いてくし通ししながら10分間乾燥させた。
専門パネラー5名により、表1に示す基準に従って官能評価を行い、評価点の平均に基づいてランク分けを行った。
表4に示す毛髪化粧料について、実施例1でセット性評価に用いたものと同様の評価毛束を用い、以下の処理を施した後、実施例1と同様の評価手順・評価基準に従ってセット性を評価した。評価結果を表4に示す。
実施例1におけるセット性の洗髪前評価(7回処理)と同じ処理を行った毛束(温風乾燥)と、当該処理において最終段階の乾燥のみ、室温(25℃)の風を30分当てて風乾させる以外は同様に行った毛束(室温乾燥)の2種類を用意した。
表5に示す毛髪化粧料について、実施例1でセット性評価に用いたものと同様の評価毛束を用い、以下の処理を施した後、実施例1と同様の評価手順・評価基準に従ってセット性を評価した。評価結果を表5に示す。
評価毛束をシャンプー(花王社製,ラビナス デザイニングシャンプー)し、タオルドライした後、処理剤0.1gを均一に塗布し、直径4cmの円柱に巻きつけ、70℃の温風で10分間乾燥させた。
評価毛束をシャンプーし、タオルドライした後、処理剤0.1gを均一に塗布し、70℃の温風で10分間乾燥させた。この処理を計2回繰り返した。次にシャンプーし、上記と同様に処理剤を塗布した後、直径4cmの円柱に巻きつけ、70℃の温風で10分間乾燥させた。
実施例1の「洗髪前評価(7回処理)」と同じ処理を行った。
上記3種の洗髪前評価の終了後、各毛束をシャンプー、タオルドライし、処理剤をつけずに、直径4cmの円柱に巻きつけ、70℃の温風で10分間乾燥させた。
本発明品15
(重量%)
リンゴ酸 2.5
乳酸 2.5
塩化ステアリルトリメチルアンモニウム 0.25
ポリオキシエチレン硬化ヒマシ油(60E.O.) 0.2
トリメチルグリシン 0.2
2-ベンジルオキシエタノール 2.5
エタノール 10.0
香料 0.05
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
本発明品15の毛髪化粧料をポンプミスト容器に入れ、以下のパネラーに使用させた。
風呂上がりの洗髪後のタオルドライした髪にスプレーし、ブラシでなじませた後、ドライヤーを用いて、ブラシブローで仕上げる。このような方法で、5日間使用したところ、髪がきれいにまとまる、毛先のはね、浮毛がなくなる、ツヤが出る、ごわつかず滑らかな感触、といった効果が見られた。
風呂上がりの洗髪後のタオルドライした髪にスプレーし、ブラシでなじませた後、ドライヤー乾燥する。このような方法で、5日間使用したところ、きれいなパーマウエーブが出る、ツヤが出る、感触がごわつかず滑らかである、といった効果が見られた。
風呂上がりの洗髪後のタオルドライした髪にスプレーし、ブラシでなじませた後、ドライヤー乾燥する。このような方法で、5日間使用したところ、ハリ・コシが出て髪が元気になる、ボリュームが出てふんわりする、ツヤが出る、といった効果が見られた。
(重量%)
リンゴ酸 2.50
乳酸 2.50
塩化ステアリルトリメチルアンモニウム 0.25
グリセリン 1.00
2-ベンジルオキシエタノール 2.50
エタノール 4.50
香料 0.02
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
(重量%)
リンゴ酸 4.00
乳酸 1.00
2-ベンジルオキシエタノール 2.50
ポリビニルピロリドン 3.00
エタノール 10.00
香料 0.05
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
(重量%)
リンゴ酸 2.50
乳酸 2.50
グリセリン 2.00
塩化ステアリルトリメチルアンモニウム 0.25
2-ベンジルオキシエタノール 2.50
ヒドロキシエチルセルロース 2.00
エタノール 10.00
香料 0.05
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
(重量%)
リンゴ酸 1.00
乳酸 4.00
塩化ステアリルトリメチルアンモニウム 0.25
グリセリン 1.00
2-ベンジルオキシエタノール 2.50
エタノール 10.00
香料 0.02
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
(重量%)
<原液>
リンゴ酸 2.50
乳酸 2.50
塩化ステアリルトリメチルアンモニウム 0.25
グリセリン 1.00
2-ベンジルオキシエタノール 2.50
エタノール 4.50
香料 0.02
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
<噴射剤>
窒素ガス
<原液/噴射剤比> 99.50/0.50
(重量%)
リンゴ酸 2.50
乳酸 2.50
ポリオキシエチレンラウリルエーテル(16E.O.) 1.00
塩化ステアリルトリメチルアンモニウム 0.25
グリセリン 1.00
2-ベンジルオキシエタノール 2.50
エタノール 4.50
香料 0.02
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
(重量%)
<原液>
リンゴ酸 4.00
乳酸 1.00
ポリオキシエチレンラウリルエーテル(16E.O.) 1.00
塩化ステアリルトリメチルアンモニウム 0.25
グリセリン 1.00
2-ベンジルオキシエタノール 2.50
エタノール 4.50
香料 0.02
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
<噴射剤>
LPG(0.44Mpa)
<原液/噴射剤比> 93.00/7.00
(重量%)
リンゴ酸 2.5
乳酸 2.5
2-ベンジルオキシエタノール 2.5
塩化ステアリルトリメチルアンモニウム 0.25
ポリエチレングリコール400 0.45
エタノール 4.5
水 残量
水酸化ナトリウム(pH調整剤) pH3.7に調整
本発明の毛髪化粧料は、毛髪を本質的に改質し、毛髪のツヤ、まとまり性、感触を向上させる効果に優れる。
Claims (5)
- 次の成分(a)〜(c)
(a)リンゴ酸又はその塩
(b)乳酸又はその塩
(c)芳香族アルコール、N-アルキルピロリドン、アルキレンカーボネート、ポリプロピレングリコール、ラクトン及び環状ケトンからなる群より選ばれる有機溶剤
を含有する、洗い流さないタイプの毛髪化粧料。 - (a)リンゴ酸又はその塩と(b)乳酸又はその塩との重量比率(酸としての)が、10/1〜1/10である請求項1記載の毛髪化粧料。
- 更に、セットポリマーを含有する請求項1又は2記載の毛髪化粧料。
- 更に、油剤を含有する請求項1〜3のいずれかに記載の毛髪化粧料。
- 請求項1〜4のいずれかに記載の毛髪化粧料を毛髪に適用後、加温する毛髪の改質方法。
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JP2008024610A (ja) * | 2006-07-19 | 2008-02-07 | Kao Corp | 乳化型毛髪化粧料 |
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WO2017111095A1 (ja) | 2015-12-25 | 2017-06-29 | 花王株式会社 | 毛髪処理方法 |
WO2018142484A1 (ja) | 2017-01-31 | 2018-08-09 | 花王株式会社 | 毛髪処理方法 |
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JP7103801B2 (ja) | 2018-02-14 | 2022-07-20 | 花王株式会社 | 睫用化粧料 |
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