FR3031744B1 - Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant - Google Patents

Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant

Info

Publication number
FR3031744B1
FR3031744B1 FR1550328A FR1550328A FR3031744B1 FR 3031744 B1 FR3031744 B1 FR 3031744B1 FR 1550328 A FR1550328 A FR 1550328A FR 1550328 A FR1550328 A FR 1550328A FR 3031744 B1 FR3031744 B1 FR 3031744B1
Authority
FR
France
Prior art keywords
compositions
thermoassociative
additives
association
controlled
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Active
Application number
FR1550328A
Other languages
English (en)
Other versions
FR3031744A1 (fr
Inventor
Renaud Nicolay
Thi Hang Nga Nguyen
Raphaele Iovine
Gregory Descroix
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
TotalEnergies Onetech SAS
Original Assignee
Centre National de la Recherche Scientifique CNRS
Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
Total Marketing Services SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR1550328A priority Critical patent/FR3031744B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Ecole Superieure de Physique et Chimie Industrielles de Ville Paris , Total Marketing Services SA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to BR112017015040-9A priority patent/BR112017015040A2/pt
Priority to MA40661A priority patent/MA40661B1/fr
Priority to CN201680005777.4A priority patent/CN107109285B/zh
Priority to EP16700342.5A priority patent/EP3245276B1/fr
Priority to US15/543,100 priority patent/US10508250B2/en
Priority to PCT/EP2016/050400 priority patent/WO2016113229A1/fr
Priority to KR1020177021655A priority patent/KR20170128221A/ko
Priority to JP2017537494A priority patent/JP6778685B2/ja
Priority to CA2971690A priority patent/CA2971690A1/fr
Publication of FR3031744A1 publication Critical patent/FR3031744A1/fr
Application granted granted Critical
Publication of FR3031744B1 publication Critical patent/FR3031744B1/fr
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M169/00—Lubricating compositions characterised by containing as components a mixture of at least two types of ingredient selected from base-materials, thickeners or additives, covered by the preceding groups, each of these compounds being essential
    • C10M169/04—Mixtures of base-materials and additives
    • C10M169/044—Mixtures of base-materials and additives the additives being a mixture of non-macromolecular and macromolecular compounds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M161/00—Lubricating compositions characterised by the additive being a mixture of a macromolecular compound and a non-macromolecular compound, each of these compounds being essential
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M105/00—Lubricating compositions characterised by the base-material being a non-macromolecular organic compound
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M129/00—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen
    • C10M129/02—Lubricating compositions characterised by the additive being an organic non-macromolecular compound containing oxygen having a carbon chain of less than 30 atoms
    • C10M129/04—Hydroxy compounds
    • C10M129/06—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M129/08—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least 2 hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M155/00—Lubricating compositions characterised by the additive being a macromolecular compound containing atoms of elements not provided for in groups C10M143/00 - C10M153/00
    • C10M155/04—Monomer containing boron
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/003—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2203/00—Organic non-macromolecular hydrocarbon compounds and hydrocarbon fractions as ingredients in lubricant compositions
    • C10M2203/10—Petroleum or coal fractions, e.g. tars, solvents, bitumen
    • C10M2203/102—Aliphatic fractions
    • C10M2203/1025—Aliphatic fractions used as base material
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2205/00—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions
    • C10M2205/04—Organic macromolecular hydrocarbon compounds or fractions, whether or not modified by oxidation as ingredients in lubricant compositions containing aromatic monomers, e.g. styrene
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2207/00—Organic non-macromolecular hydrocarbon compounds containing hydrogen, carbon and oxygen as ingredients in lubricant compositions
    • C10M2207/02—Hydroxy compounds
    • C10M2207/021—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms
    • C10M2207/022—Hydroxy compounds having hydroxy groups bound to acyclic or cycloaliphatic carbon atoms containing at least two hydroxy groups
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an alcohol or ester thereof; bound to an aldehyde, ketonic, ether, ketal or acetal radical
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2209/00—Organic macromolecular compounds containing oxygen as ingredients in lubricant compositions
    • C10M2209/02—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2209/08—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to a carboxyl radical, e.g. acrylate type
    • C10M2209/084—Acrylate; Methacrylate
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2217/00—Organic macromolecular compounds containing nitrogen as ingredients in lubricant compositions
    • C10M2217/02—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds
    • C10M2217/024—Macromolecular compounds obtained from nitrogen containing monomers by reactions only involving carbon-to-carbon unsaturated bonds containing monomers having an unsaturated radical bound to an amido or imido group
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2221/00—Organic macromolecular compounds containing sulfur, selenium or tellurium as ingredients in lubricant compositions
    • C10M2221/02—Macromolecular compounds obtained by reactions of monomers involving only carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10M—LUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
    • C10M2229/00—Organic macromolecular compounds containing atoms of elements not provided for in groups C10M2205/00, C10M2209/00, C10M2213/00, C10M2217/00, C10M2221/00 or C10M2225/00 as ingredients in lubricant compositions
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/02—Pour-point; Viscosity index
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2030/00—Specified physical or chemical properties which is improved by the additive characterising the lubricating composition, e.g. multifunctional additives
    • C10N2030/68—Shear stability
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10N—INDEXING SCHEME ASSOCIATED WITH SUBCLASS C10M RELATING TO LUBRICATING COMPOSITIONS
    • C10N2070/00—Specific manufacturing methods for lubricant compositions
    • C10N2070/02—Concentrating of additives

Landscapes

  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Other Resins Obtained By Reactions Not Involving Carbon-To-Carbon Unsaturated Bonds (AREA)
FR1550328A 2015-01-15 2015-01-15 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant Active FR3031744B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR1550328A FR3031744B1 (fr) 2015-01-15 2015-01-15 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
JP2017537494A JP6778685B2 (ja) 2015-01-15 2016-01-11 制御された会合性を有する熱会合性添加剤組成物、およびそれを含む潤滑剤組成物
CN201680005777.4A CN107109285B (zh) 2015-01-15 2016-01-11 受控缔合的热缔合添加剂组合物和包含其的润滑剂组合物
EP16700342.5A EP3245276B1 (fr) 2015-01-15 2016-01-11 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
US15/543,100 US10508250B2 (en) 2015-01-15 2016-01-11 Compositions of thermoassociative additives with controlled association and lubricant compositions containing them
PCT/EP2016/050400 WO2016113229A1 (fr) 2015-01-15 2016-01-11 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
BR112017015040-9A BR112017015040A2 (pt) 2015-01-15 2016-01-11 composições de aditivos termoassociativos com associação controlada e composições lubrificantes que as contêm
MA40661A MA40661B1 (fr) 2015-01-15 2016-01-11 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
CA2971690A CA2971690A1 (fr) 2015-01-15 2016-01-11 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
KR1020177021655A KR20170128221A (ko) 2015-01-15 2016-01-11 열결합 첨가제 조성물, 제어되는 결합체, 이를 포함하는 윤활유 조성물

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR1550328A FR3031744B1 (fr) 2015-01-15 2015-01-15 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant

Publications (2)

Publication Number Publication Date
FR3031744A1 FR3031744A1 (fr) 2016-07-22
FR3031744B1 true FR3031744B1 (fr) 2017-02-10

Family

ID=53008654

Family Applications (1)

Application Number Title Priority Date Filing Date
FR1550328A Active FR3031744B1 (fr) 2015-01-15 2015-01-15 Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant

Country Status (10)

Country Link
US (1) US10508250B2 (fr)
EP (1) EP3245276B1 (fr)
JP (1) JP6778685B2 (fr)
KR (1) KR20170128221A (fr)
CN (1) CN107109285B (fr)
BR (1) BR112017015040A2 (fr)
CA (1) CA2971690A1 (fr)
FR (1) FR3031744B1 (fr)
MA (1) MA40661B1 (fr)
WO (1) WO2016113229A1 (fr)

Families Citing this family (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR3031744B1 (fr) * 2015-01-15 2017-02-10 Total Marketing Services Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
FR3059006B1 (fr) * 2016-11-23 2020-06-12 Total Marketing Services Compositions d’additifs thermoassociatifs dont l’association est controlee et compositions lubrifiantes les contenant
FR3059005B1 (fr) 2016-11-23 2018-12-07 Total Marketing Services Copolymeres thermoassociatifs et echangeables, composition les comprenant
FR3078706B1 (fr) 2018-03-07 2020-12-18 Total Marketing Services Copolymeres thermoassociatifs et echangeables, composition les comprenant
FR3078710B1 (fr) * 2018-03-07 2020-10-30 Total Marketing Services Composition comprenant des copolymeres thermoassociatifs et echangeables
FR3081467B1 (fr) * 2018-05-24 2020-07-10 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081464B1 (fr) 2018-05-24 2020-09-18 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081465B1 (fr) * 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081466B1 (fr) 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
WO2023099637A1 (fr) 2021-12-03 2023-06-08 Totalenergies Onetech Compositions lubrifiantes
WO2023099634A1 (fr) 2021-12-03 2023-06-08 Totalenergies Onetech Compositions lubrifiantes
WO2023099632A1 (fr) 2021-12-03 2023-06-08 Evonik Operations Gmbh Polymères de poly(méth)acrylate d'alkyle modifiés par un ester boronique
WO2023099635A1 (fr) 2021-12-03 2023-06-08 Totalenergies Onetech Compositions lubrifiantes
WO2023099630A1 (fr) 2021-12-03 2023-06-08 Evonik Operations Gmbh Polymères de polyalkyl(méth)acrylate modifiés par un ester boronique
WO2023099631A1 (fr) 2021-12-03 2023-06-08 Evonik Operations Gmbh Polymères de poly(méth)acrylate d'alkyle modifiés par un ester boronique

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US4401797A (en) * 1981-05-20 1983-08-30 Syntex (U.S.A.) Inc. Copolymers and hydrogels: process and articles made thereof
US4889664A (en) * 1988-11-25 1989-12-26 Vistakon, Inc. Method of forming shaped hydrogel articles including contact lenses
IT1258916B (it) * 1992-05-15 1996-03-01 Mini Ricerca Scient Tecnolog Additivo per olii lubrificanti contenente boro e procedimento per la sua preparazione
JP3055851B2 (ja) * 1993-03-15 2000-06-26 株式会社クラレ 樹脂組成物
DE10314776A1 (de) * 2003-03-31 2004-10-14 Rohmax Additives Gmbh Schmierölzusammensetzung mit guten Reibeigenschaften
FR2855180B1 (fr) * 2003-05-23 2006-07-14 Rhodia Chimie Sa Fluide aqueux comprenant un polymere boronate et un polymere ligand et utilisation dans l'exploitation de gisement de petrole ou de gaz
FR2928934B1 (fr) 2008-03-20 2011-08-05 Total France Lubrifiant marin
US8454689B2 (en) * 2008-12-30 2013-06-04 Bausch & Lomb Incorporated Brush copolymers
DE102009001447A1 (de) * 2009-03-10 2010-09-16 Evonik Rohmax Additives Gmbh Verwendung von Kammpolymeren zur Verbesserung des Lasttragevermögens
FR2945754A1 (fr) 2009-05-20 2010-11-26 Total Raffinage Marketing Nouveaux additifs pour huiles transmission
WO2013147795A1 (fr) 2012-03-29 2013-10-03 Empire Technology Development Llc Copolymères de dioxaborinane et leurs utilisations
WO2015002669A1 (fr) * 2013-07-01 2015-01-08 Halliburton Energy Services, Inc. Agents de réticulation de type biopolymère boré et procédés s'y rapportant
FR3016885B1 (fr) 2014-01-27 2017-08-18 Total Marketing Services Copolymeres thermoassociatifs et echangeables, compositions les comprenant
FR3016887B1 (fr) * 2014-01-27 2016-02-05 Total Marketing Services Compositions lubrifiantes comprenant des copolymeres thermoassociatifs et echangeables
FR3031744B1 (fr) * 2015-01-15 2017-02-10 Total Marketing Services Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
FR3040172B1 (fr) * 2015-08-20 2020-01-24 Ecole Superieure De Physique Et De Chimie Industrielles De La Ville De Paris Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation

Also Published As

Publication number Publication date
CN107109285B (zh) 2020-10-02
US20180023028A1 (en) 2018-01-25
WO2016113229A1 (fr) 2016-07-21
CA2971690A1 (fr) 2016-07-21
CN107109285A (zh) 2017-08-29
US10508250B2 (en) 2019-12-17
BR112017015040A2 (pt) 2019-11-19
JP2018506620A (ja) 2018-03-08
MA40661B1 (fr) 2018-11-30
FR3031744A1 (fr) 2016-07-22
KR20170128221A (ko) 2017-11-22
EP3245276B1 (fr) 2021-09-08
EP3245276A1 (fr) 2017-11-22
MA40661A1 (fr) 2018-05-31
JP6778685B2 (ja) 2020-11-04

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