FR3040172B1 - Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation - Google Patents

Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation Download PDF

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FR3040172B1
FR3040172B1 FR1557822A FR1557822A FR3040172B1 FR 3040172 B1 FR3040172 B1 FR 3040172B1 FR 1557822 A FR1557822 A FR 1557822A FR 1557822 A FR1557822 A FR 1557822A FR 3040172 B1 FR3040172 B1 FR 3040172B1
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Prior art keywords
composition
crosslinked polymers
boronic esters
exchangeable
preparation
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FR1557822A
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FR3040172A1 (fr
Inventor
Ludwik Leibler
Renaud Nicolay
Max ROTTGER
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Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
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Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
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Application filed by Ecole Superieure de Physique et Chimie Industrielles de Ville Paris filed Critical Ecole Superieure de Physique et Chimie Industrielles de Ville Paris
Priority to FR1557822A priority Critical patent/FR3040172B1/fr
Priority to FR1559955A priority patent/FR3040173B1/fr
Priority to JP2018509514A priority patent/JP7018688B2/ja
Priority to US15/243,449 priority patent/US10005900B2/en
Priority to CA3032023A priority patent/CA3032023C/fr
Priority to CN201680061297.XA priority patent/CN108473629B/zh
Priority to DK16759706.1T priority patent/DK3337834T3/da
Priority to CN202010244872.8A priority patent/CN111410711B/zh
Priority to CN201680061296.5A priority patent/CN108368206B/zh
Priority to JP2018509508A priority patent/JP7125211B2/ja
Priority to PCT/EP2016/069783 priority patent/WO2017029413A1/fr
Priority to EP16758123.0A priority patent/EP3337833B1/fr
Priority to US15/243,621 priority patent/US10011711B2/en
Priority to PCT/EP2016/069781 priority patent/WO2017029412A1/fr
Priority to EP16759706.1A priority patent/EP3337834B1/fr
Priority to CA3032026A priority patent/CA3032026C/fr
Publication of FR3040172A1 publication Critical patent/FR3040172A1/fr
Priority to US15/988,895 priority patent/US10329414B2/en
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    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F210/00—Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
    • C08F210/02—Ethene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F212/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring
    • C08F212/02—Monomers containing only one unsaturated aliphatic radical
    • C08F212/04—Monomers containing only one unsaturated aliphatic radical containing one ring
    • C08F212/06—Hydrocarbons
    • C08F212/08—Styrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/14—Methyl esters, e.g. methyl (meth)acrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/12—Esters of monohydric alcohols or phenols
    • C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F230/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
    • C08F230/04—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal
    • C08F230/06—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron
    • C08F230/065—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal containing a metal containing boron the monomer being a polymerisable borane, e.g. dimethyl(vinyl)borane
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F8/00—Chemical modification by after-treatment
    • C08F8/42—Introducing metal atoms or metal-containing groups
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J3/00—Processes of treating or compounding macromolecular substances
    • C08J3/24—Crosslinking, e.g. vulcanising, of macromolecules
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00—Use of organic ingredients
    • C08K5/55—Boron-containing compounds
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/14—Homopolymers or copolymers of esters of esters containing halogen, nitrogen, sulfur, or oxygen atoms in addition to the carboxy oxygen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L43/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium or a metal; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/28—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety
    • C08F220/282—Esters containing oxygen in addition to the carboxy oxygen containing no aromatic rings in the alcohol moiety and containing two or more oxygen atoms
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/10—Esters
    • C08F220/26—Esters containing oxygen in addition to the carboxy oxygen
    • C08F220/30—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety
    • C08F220/303—Esters containing oxygen in addition to the carboxy oxygen containing aromatic rings in the alcohol moiety and one or more carboxylic moieties in the chain
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2438/00—Living radical polymerisation
    • C08F2438/03—Use of a di- or tri-thiocarbonylthio compound, e.g. di- or tri-thioester, di- or tri-thiocarbamate, or a xanthate as chain transfer agent, e.g . Reversible Addition Fragmentation chain Transfer [RAFT] or Macromolecular Design via Interchange of Xanthates [MADIX]
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2500/00—Characteristics or properties of obtained polyolefins; Use thereof
    • C08F2500/07—High density, i.e. > 0.95 g/cm3
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F2810/00—Chemical modification of a polymer
    • C08F2810/20—Chemical modification of a polymer leading to a crosslinking, either explicitly or inherently
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2333/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2333/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C08J2333/06—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters of esters containing only carbon, hydrogen, and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C08J2333/10—Homopolymers or copolymers of methacrylic acid esters
    • C08J2333/12—Homopolymers or copolymers of methyl methacrylate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
    • C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2207/00—Properties characterising the ingredient of the composition
    • C08L2207/06—Properties of polyethylene
    • C08L2207/062—HDPE
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2312/00—Crosslinking

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Materials Engineering (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Polyoxymethylene Polymers And Polymers With Carbon-To-Carbon Bonds (AREA)
  • Processes Of Treating Macromolecular Substances (AREA)
  • Polymerisation Methods In General (AREA)
  • Graft Or Block Polymers (AREA)

Abstract

L'invention a pour objet une composition comprenant (a) des polymères réticulés contenant des liaisons pendantes échangeables et des points de réticulation échangeables, par réactions de métathèse des esters boroniques, obtenu par réticulation de polymères linéaires ou branchés et (b) des esters boroniques libres monofonctionnels, lesdits esters boroniques étant choisis parmi les cycles dioxaborolane et dioxaborinane comprenant un radical hydrocarboné lié à l'atome de bore du cycle dioxaborolane et dioxaborinane par une liaison covalente via un atome de carbone. L'invention a également pour objets des procédés pour préparer cette composition, et des matériaux et formulation comprenant cette composition. L'invention a aussi pour objet l'utilisation d'additifs en présence d'un polymère linéaire ou branché pour la formation d'une composition comprenant des polymères réticulés, avantageusement un réseau réticulé, contenant des liaisons pendantes échangeables et des points de réticulation échangeables par réactions de métathèse des esters boroniques.
FR1557822A 2015-08-20 2015-08-20 Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation Active FR3040172B1 (fr)

Priority Applications (17)

Application Number Priority Date Filing Date Title
FR1557822A FR3040172B1 (fr) 2015-08-20 2015-08-20 Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation
FR1559955A FR3040173B1 (fr) 2015-08-20 2015-10-19 Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation
EP16758123.0A EP3337833B1 (fr) 2015-08-20 2016-08-22 Compositions polymères comprenant des polymères réticulés comprenant des fonctions ester boronique permettant des réactions d'échange, procédé pour leur préparation et leur utilisation
CA3032023A CA3032023C (fr) 2015-08-20 2016-08-22 Compositions polymeres comprenant des polymeres reticules comprenant des fonctions ester boronique permettant des reactions d'echange, procede pour leur preparation et leur utilis ation
CN201680061297.XA CN108473629B (zh) 2015-08-20 2016-08-22 包含具有能进行交换反应的硼酸酯官能团的交联聚合物的聚合物组合物、其制备方法及用途
DK16759706.1T DK3337834T3 (da) 2015-08-20 2016-08-22 Polymersammensætninger omfattende tværbundne polymerer omfattende boresterfunktioner, der muliggør udskiftningsreaktioner, fremgangsmåde til fremstilling af dem og deres anvendelse
CN202010244872.8A CN111410711B (zh) 2015-08-20 2016-08-22 包含具有能够进行交换反应的硼酸酯官能团的交联聚合物的聚合物组合物、制备方法及用途
CN201680061296.5A CN108368206B (zh) 2015-08-20 2016-08-22 包含含有能够进行交换反应的硼酸酯官能团的交联聚合物的聚合物组合物、其制备方法及其用途
JP2018509514A JP7018688B2 (ja) 2015-08-20 2016-08-22 交換反応を可能にするボロン酸エステル官能基を含む架橋ポリマーを含むポリマー組成物、その調製方法及びその使用
PCT/EP2016/069783 WO2017029413A1 (fr) 2015-08-20 2016-08-22 Compositions polymères comprenant des polymères réticulés comprenant des fonctions esters boroniques permettant des réactions d'échange, leur procédé de préparation et leur utilisation
US15/243,449 US10005900B2 (en) 2015-08-20 2016-08-22 Polymer compositions comprising cross-linked polymers comprising boronic ester functions enabling exchange reactions, process for preparing them and their use
US15/243,621 US10011711B2 (en) 2015-08-20 2016-08-22 Polymer compositions comprising cross-linked polymers comprising boronic ester functions enabling exchange reactions, process for preparing them and their use
PCT/EP2016/069781 WO2017029412A1 (fr) 2015-08-20 2016-08-22 Compositions polymères comprenant des polymères réticulés comprenant des fonctions ester boronique permettant des réactions d'échange, procédé pour leur préparation et leur utilisation
EP16759706.1A EP3337834B1 (fr) 2015-08-20 2016-08-22 Compositions polymères comprenant des polymères réticulés comprenant des fonctions esters boroniques permettant des réactions d'échange, leur procédé de préparation et leur utilisation
CA3032026A CA3032026C (fr) 2015-08-20 2016-08-22 Compositions polymeres comprenant des polymeres reticules comprenant des fonctions esters boroniques permettant des reactions d'echange, leur procede de preparation et leur utilis ation
JP2018509508A JP7125211B2 (ja) 2015-08-20 2016-08-22 交換反応を可能にするボロン酸エステル官能基を含む架橋ポリマーを含むポリマー組成物、その調製方法及びその使用
US15/988,895 US10329414B2 (en) 2015-08-20 2018-05-24 Boronic polymer crosslinking

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR1557822 2015-08-20
FR1557822A FR3040172B1 (fr) 2015-08-20 2015-08-20 Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation

Publications (2)

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FR3040172A1 FR3040172A1 (fr) 2017-02-24
FR3040172B1 true FR3040172B1 (fr) 2020-01-24

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FR1557822A Active FR3040172B1 (fr) 2015-08-20 2015-08-20 Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation
FR1559955A Active FR3040173B1 (fr) 2015-08-20 2015-10-19 Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation

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FR1559955A Active FR3040173B1 (fr) 2015-08-20 2015-10-19 Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation

Country Status (8)

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US (3) US10011711B2 (fr)
EP (2) EP3337834B1 (fr)
JP (2) JP7125211B2 (fr)
CN (3) CN108473629B (fr)
CA (2) CA3032026C (fr)
DK (1) DK3337834T3 (fr)
FR (2) FR3040172B1 (fr)
WO (2) WO2017029412A1 (fr)

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FR3031744B1 (fr) * 2015-01-15 2017-02-10 Total Marketing Services Compositions d'additifs thermoassociatifs dont l'association est controlee et compositions lubrifiantes les contenant
FR3040172B1 (fr) * 2015-08-20 2020-01-24 Ecole Superieure De Physique Et De Chimie Industrielles De La Ville De Paris Compositions de polymere comprenant des polymeres reticules comprenant des fonctions ester boronique, permettant des reactions d'echange, procede de preparation et utilisation
FR3051792B1 (fr) 2016-05-30 2020-01-24 Ecole Superieure De Physique Et De Chimie Industrielles De La Ville De Paris Nouveaux composes, derives de dioxoborolane ou de dioxaborinane fonctionnalises, leur procede de preparation et leurs utilisations
CN107298737A (zh) * 2017-06-20 2017-10-27 西南科技大学 一种三维动态聚丙烯的制备方法
FR3078706B1 (fr) 2018-03-07 2020-12-18 Total Marketing Services Copolymeres thermoassociatifs et echangeables, composition les comprenant
FR3081464B1 (fr) * 2018-05-24 2020-09-18 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081466B1 (fr) * 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
FR3081465B1 (fr) * 2018-05-24 2020-06-12 Total Marketing Services Oligomeres associatifs et echangeables, composition les comprenant
CN108752370B (zh) * 2018-06-27 2020-07-03 苏州大学 基于动态共价交联剂的可拉伸自修复水凝胶及其制备方法
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