FR2870251A1 - Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention - Google Patents

Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention

Info

Publication number
FR2870251A1
FR2870251A1 FR0405120A FR0405120A FR2870251A1 FR 2870251 A1 FR2870251 A1 FR 2870251A1 FR 0405120 A FR0405120 A FR 0405120A FR 0405120 A FR0405120 A FR 0405120A FR 2870251 A1 FR2870251 A1 FR 2870251A1
Authority
FR
France
Prior art keywords
block
carbon nanotubes
cnt
copolymer
obtaining
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
FR0405120A
Other languages
English (en)
Other versions
FR2870251B1 (fr
Inventor
Olivier Guerret
Piecourt Christelle Guerret
Laurent Billon
Vitaliy Datsyuk
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Centre National de la Recherche Scientifique CNRS
Arkema SA
Original Assignee
Centre National de la Recherche Scientifique CNRS
Arkema SA
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0405120A priority Critical patent/FR2870251B1/fr
Application filed by Centre National de la Recherche Scientifique CNRS, Arkema SA filed Critical Centre National de la Recherche Scientifique CNRS
Priority to EP10180902A priority patent/EP2277947A3/fr
Priority to AT10180899T priority patent/ATE531763T1/de
Priority to CNA2005800151250A priority patent/CN1984954A/zh
Priority to PCT/EP2005/005135 priority patent/WO2005108485A2/fr
Priority to JP2007512095A priority patent/JP2007537313A/ja
Priority to AT05748178T priority patent/ATE529477T1/de
Priority to ES05748178T priority patent/ES2374556T3/es
Priority to KR1020067023546A priority patent/KR20070034469A/ko
Priority to EP10180899A priority patent/EP2275487B1/fr
Priority to US11/579,839 priority patent/US20070232748A1/en
Priority to EP05748178A priority patent/EP1751232B1/fr
Priority to CA002566702A priority patent/CA2566702A1/fr
Priority to TW094115235A priority patent/TW200609284A/zh
Publication of FR2870251A1 publication Critical patent/FR2870251A1/fr
Application granted granted Critical
Publication of FR2870251B1 publication Critical patent/FR2870251B1/fr
Anticipated expiration legal-status Critical
Expired - Fee Related legal-status Critical Current

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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
    • C08L33/08—Homopolymers or copolymers of acrylic acid esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L53/00—Compositions of block copolymers containing at least one sequence of a polymer obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
    • C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
    • C08F220/04—Acids; Metal salts or ammonium salts thereof
    • C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
    • C08F293/00—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule
    • C08F293/005—Macromolecular compounds obtained by polymerisation on to a macromolecule having groups capable of inducing the formation of new polymer chains bound exclusively at one or both ends of the starting macromolecule using free radical "living" or "controlled" polymerisation, e.g. using a complexing agent
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/005—Reinforced macromolecular compounds with nanosized materials, e.g. nanoparticles, nanofibres, nanotubes, nanowires, nanorods or nanolayered materials
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K7/00—Use of ingredients characterised by shape
    • C08K7/22—Expanded, porous or hollow particles
    • C08K7/24—Expanded, porous or hollow particles inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/24—Electrically-conducting paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/26—Thermosensitive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/70—Additives characterised by shape, e.g. fibres, flakes or microspheres
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/02—Elements
    • C08K3/04—Carbon

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Wood Science & Technology (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Nanotechnology (AREA)
  • Inorganic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Physics & Mathematics (AREA)
  • Composite Materials (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Carbon And Carbon Compounds (AREA)
  • Graft Or Block Polymers (AREA)
  • Paints Or Removers (AREA)

Abstract

La présente invention décrit un matériau composite à base de matrice polymère dans laquelle sont dispersés des nanotubes de carbone ainsi qu'un procédé d'obtention d'un tel matériau.Le procédé de l'invention est basé sur l'utilisation comme compatibilisant d'un copolymère à blocs obtenu par la polymérisation radicalaire contrôlée et présentant au moins un bloc portant des fonctions acides et/ou anhydrides.Un tel compatibilisant permet le contrôle et l'optimisation des interactions inter faciales et l'obtention ainsi d'un matériau composite stable et présentant des bonnes propriétés d'usage.
FR0405120A 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention Expired - Fee Related FR2870251B1 (fr)

Priority Applications (14)

Application Number Priority Date Filing Date Title
FR0405120A FR2870251B1 (fr) 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention
US11/579,839 US20070232748A1 (en) 2004-05-11 2005-05-10 Composite Materials Based on Carbon Nanotubes and Polymer Matrices and Processes for Obtaining Same
CNA2005800151250A CN1984954A (zh) 2004-05-11 2005-05-10 基于碳纳米管和聚合物基质的复合材料以及获得该材料的方法
PCT/EP2005/005135 WO2005108485A2 (fr) 2004-05-11 2005-05-10 Materiaux composites bases sur des nanotubes de carbone et des matrices polymeriques, et procedes de production de ces materiaux
JP2007512095A JP2007537313A (ja) 2004-05-11 2005-05-10 カーボンナノチューブとポリマーマトリックスとをベースにした複合材料と、その製造方法
AT05748178T ATE529477T1 (de) 2004-05-11 2005-05-10 Verbundwerkstoffe auf basis von kohlenstoffnanoröhren und polymermatrizes und herstellungsverfahren dafür
ES05748178T ES2374556T3 (es) 2004-05-11 2005-05-10 Materiales compuestos basados en nanotubos de carbono y matrices poliméricas y procesos para obtener los mismos.
KR1020067023546A KR20070034469A (ko) 2004-05-11 2005-05-10 탄소 나노튜브 및 중합체 매트릭스 기재 복합 재료 및 그의수득 방법
EP10180902A EP2277947A3 (fr) 2004-05-11 2005-05-10 Matériaux composites basés sur des nanotubes de carbone et des matrices polymériques, et procédés de production de ces matériaux
AT10180899T ATE531763T1 (de) 2004-05-11 2005-05-10 Verbundmaterialien auf der basis von kohlenstoffnanoröhren und polymermatrizen und deren herstellungsverfahren
EP05748178A EP1751232B1 (fr) 2004-05-11 2005-05-10 Materiaux composites bases sur des nanotubes de carbone et des matrices polymeriques, et procedes de production de ces materiaux
CA002566702A CA2566702A1 (fr) 2004-05-11 2005-05-10 Materiaux composites bases sur des nanotubes de carbone et des matrices polymeriques, et procedes de production de ces materiaux
EP10180899A EP2275487B1 (fr) 2004-05-11 2005-05-10 Matériaux composites basés sur des nanotubes de carbone et des matrices polymériques, et procédés de production de ces matériaux
TW094115235A TW200609284A (en) 2004-05-11 2005-05-11 Composite materials based on carbon nanotubes and polymer matrices and processes for obtaining same

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0405120A FR2870251B1 (fr) 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention

Publications (2)

Publication Number Publication Date
FR2870251A1 true FR2870251A1 (fr) 2005-11-18
FR2870251B1 FR2870251B1 (fr) 2010-09-17

Family

ID=34946446

Family Applications (1)

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FR0405120A Expired - Fee Related FR2870251B1 (fr) 2004-05-11 2004-05-11 Materiaux composites a base de nanotubes de carbone et matrices polymeres et leurs procedes d'obtention

Country Status (11)

Country Link
US (1) US20070232748A1 (fr)
EP (3) EP2277947A3 (fr)
JP (1) JP2007537313A (fr)
KR (1) KR20070034469A (fr)
CN (1) CN1984954A (fr)
AT (2) ATE529477T1 (fr)
CA (1) CA2566702A1 (fr)
ES (1) ES2374556T3 (fr)
FR (1) FR2870251B1 (fr)
TW (1) TW200609284A (fr)
WO (1) WO2005108485A2 (fr)

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FR2893946A1 (fr) * 2005-11-30 2007-06-01 Arkema Sa Composition pulverulente a base de nanotubes de carbone, ses procedes d'obtention et ses utilisations, notamment dans des materiaux polymeres
FR2893947A1 (fr) * 2005-11-30 2007-06-01 Arkema Sa Composition pulverulente de nanotubes de carbone, ses procedes d'obtention et ses utilisations, notamment dans des materiaux polymeres.
FR2937323A1 (fr) * 2008-10-22 2010-04-23 Arkema France Procede de preparation d'un materiau composite thermoplastique a base de nanotubes, notamment de carbone
WO2012056184A2 (fr) 2010-10-28 2012-05-03 Centre National De La Recherche Scientifique - Cnrs Méthode de purification de nanotubes de carbone

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EP1777259B1 (fr) * 2005-10-24 2011-06-29 Basf Se Polymères renforcés par des nanotubes de carbone et leurs procédés de production
WO2007083771A1 (fr) * 2006-01-20 2007-07-26 Ezaki Glico Co., Ltd. Composition aqueuse pour revetement conducteur
US7863381B2 (en) * 2006-03-08 2011-01-04 3M Innovative Properties Company Polymer composites
JP4536031B2 (ja) * 2006-04-27 2010-09-01 株式会社竹中製作所 被覆組成物および被覆物
FR2901154B1 (fr) * 2006-05-18 2008-07-18 Arkema France Utilisation de materiaux composites a base de nanotubes de carbone comme agents viscosifiants de solutions aqueuses
JP5280016B2 (ja) * 2007-05-11 2013-09-04 大日精化工業株式会社 塗布液
FR2918067B1 (fr) * 2007-06-27 2011-07-01 Arkema France Materiau composite comprenant des nanotubes disperses dans une matrice polymerique fluroree.
JP2009079139A (ja) * 2007-09-26 2009-04-16 Mitsui Chemicals Polyurethanes Inc ペースト組成物、焼成体およびフラットパネルディスプレイ用部品
DE102008020135A1 (de) * 2008-04-22 2009-10-29 Bayer Materialscience Ag Reaktionsharz auf Basis eines ungesättigten Polyesters, radikalisch härtbaren Vinylverbindungen und Kohlenstoffnanoröhrchen
US8956556B2 (en) * 2008-07-02 2015-02-17 Eaton Corporation Dielectric isolators
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EP2151457A1 (fr) * 2008-07-28 2010-02-10 Total Petrochemicals France Procédé de fabrication d'un copolymère biséquencé doté d'une séquence de polymère monovinylaromatique
ITTO20080734A1 (it) * 2008-10-07 2010-04-08 Techfab S R L Composizione di rivestimento reticolabile a microonde e relativo procedimento di reticolazione a microoonde di rivestimenti
EP2241593A1 (fr) * 2009-04-08 2010-10-20 Bayer MaterialScience AG Nanotubes de carbone à polymère fonctionnalisé, leur procédé de fabrication et d'utilisation
FR2946176A1 (fr) 2009-05-27 2010-12-03 Arkema France Fibre conductrice multicouche et son procede d'obtention par co-extrusion.
FR2946178A1 (fr) 2009-05-27 2010-12-03 Arkema France Procede de fabrication d'une fibre conductrice multicouche par enduction-coagulation.
TWI403460B (zh) * 2009-07-31 2013-08-01 Chung Shan Inst Of Science 奈米碳管複合物及其製備方法
DE102009046680A1 (de) 2009-11-13 2011-05-19 BSH Bosch und Siemens Hausgeräte GmbH Hausgerät mit Wärmetauscher aus thermoplastischem Kunststoff enthaltendem Werkstoff, sowie solcher Wärmetauscher
FR2957910B1 (fr) * 2010-03-23 2012-05-11 Arkema France Melange maitre de nanotubes de carbone pour les formulations liquides, notamment dans les batteries li-ion
KR20110126998A (ko) * 2010-05-18 2011-11-24 삼성전자주식회사 Ｃｎｔ 조성물, ｃｎｔ 막구조체, 액정표시장치, ｃｎｔ 막구조체의 제조방법 및 액정표시장치의 제조방법
US20110301282A1 (en) * 2010-06-03 2011-12-08 Eric Magni Black colored master batch carbon nanotube and method of manufacture thereof
CA2801617C (fr) * 2010-06-11 2018-05-29 National Research Council Of Canada Nanotubes de carbone modifies et leur compatibilite
CN102296281B (zh) * 2010-06-22 2013-04-10 中国人民解放军军事医学科学院卫生装备研究所 碳纳米管、镍和铝复合粉末增强聚乙烯基复合材料的制备方法
FR2962127B1 (fr) * 2010-07-01 2012-07-27 Arkema France Procede de polymerisation radicalaire controlee en presence de nanotubes de carbone comme agent d'amorcage et de controle
JP5727604B2 (ja) * 2010-07-12 2015-06-03 ハンワ ケミカル コーポレイション 伝導性塗料組成物及びそれを用いた伝導膜の製造方法
EP2581405A1 (fr) * 2011-10-12 2013-04-17 Vrije Universiteit Brussel Nanocomposite à base de copolymère
JP5962175B2 (ja) * 2012-04-25 2016-08-03 日本ゼオン株式会社 反応性組成物及び反応射出成形体
JP2014101234A (ja) * 2012-11-16 2014-06-05 Asahi Kasei Chemicals Corp 表面処理カーボンナノチューブ
CN103193931A (zh) * 2013-04-25 2013-07-10 苏州立瓷电子技术有限公司 一种导电水凝胶接地材料的制备方法
DE102013216785A1 (de) 2013-08-23 2015-02-26 BSH Bosch und Siemens Hausgeräte GmbH Waschmaschine mit elektrischem Direktantrieb und verbesserter Nutzung der Motorverlustleistung
DE102014200774A1 (de) 2014-01-17 2015-07-23 BSH Hausgeräte GmbH Waschmaschine mit Riemenantrieb und verbesserter Nutzung der Motorverlustleistung
DE102014200775A1 (de) 2014-01-17 2015-07-23 BSH Hausgeräte GmbH Waschmaschine mit Ausnutzung der Elektronikmodulverlustwärme
JP6541147B2 (ja) * 2015-02-04 2019-07-10 本田技研工業株式会社 ナノ繊維−高分子複合体及びその製造方法
CN108441088A (zh) * 2018-03-01 2018-08-24 苏州甫众塑胶有限公司 一种防腐抗静电涂层材料及其制备方法
CN110667129A (zh) * 2019-09-09 2020-01-10 北京碳垣新材料科技有限公司 碳纳米管-聚磷腈复合材料及制备方法
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SHOFNER M L ET AL: "Single wall nanotube and vapor grown carbon fiber reinforced polymers processed by extrusion freeform fabrication", COMPOSITES PART A: APPLIED SCIENCE AND MANUFACTURING, ELSEVIER SCIENCE PUBLISHERS B.V., AMSTERDAM, NL, vol. 34, no. 12, December 2003 (2003-12-01), pages 1207 - 1217, XP004471077, ISSN: 1359-835X *

Cited By (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2893946A1 (fr) * 2005-11-30 2007-06-01 Arkema Sa Composition pulverulente a base de nanotubes de carbone, ses procedes d'obtention et ses utilisations, notamment dans des materiaux polymeres
FR2893947A1 (fr) * 2005-11-30 2007-06-01 Arkema Sa Composition pulverulente de nanotubes de carbone, ses procedes d'obtention et ses utilisations, notamment dans des materiaux polymeres.
WO2007063253A1 (fr) * 2005-11-30 2007-06-07 Arkema France Composition pulvérulente à base de nanotubes de carbone, ses procédés d'obtention et ses utilisations, notamment dans des matériaux polymères.
FR2937323A1 (fr) * 2008-10-22 2010-04-23 Arkema France Procede de preparation d'un materiau composite thermoplastique a base de nanotubes, notamment de carbone
WO2010046606A1 (fr) * 2008-10-22 2010-04-29 Arkema France Procédé de préparation d'un matériau composite thermoplastique à base de nanotubes, notamment de carbone
WO2012056184A2 (fr) 2010-10-28 2012-05-03 Centre National De La Recherche Scientifique - Cnrs Méthode de purification de nanotubes de carbone

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US20070232748A1 (en) 2007-10-04
CN1984954A (zh) 2007-06-20
EP2277947A2 (fr) 2011-01-26
KR20070034469A (ko) 2007-03-28
EP2275487A3 (fr) 2011-03-09
EP2275487A2 (fr) 2011-01-19
EP2275487B1 (fr) 2011-11-02
TW200609284A (en) 2006-03-16
ATE529477T1 (de) 2011-11-15
CA2566702A1 (fr) 2005-11-17
WO2005108485A3 (fr) 2006-03-16
EP1751232B1 (fr) 2011-10-19
EP1751232A2 (fr) 2007-02-14
EP2277947A3 (fr) 2011-03-09
FR2870251B1 (fr) 2010-09-17
WO2005108485A2 (fr) 2005-11-17
ATE531763T1 (de) 2011-11-15
ES2374556T3 (es) 2012-02-17
JP2007537313A (ja) 2007-12-20

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