EP2453750A2 - Combinaisons de substances actives synergiques contenant des phényltriazoles - Google Patents

Combinaisons de substances actives synergiques contenant des phényltriazoles

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Publication number
EP2453750A2
EP2453750A2 EP10737493A EP10737493A EP2453750A2 EP 2453750 A2 EP2453750 A2 EP 2453750A2 EP 10737493 A EP10737493 A EP 10737493A EP 10737493 A EP10737493 A EP 10737493A EP 2453750 A2 EP2453750 A2 EP 2453750A2
Authority
EP
European Patent Office
Prior art keywords
methyl
spp
formula
phenyl
group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Application number
EP10737493A
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German (de)
English (en)
Inventor
Wolfram Andersch
Heike Hungenberg
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Bayer Intellectual Property GmbH
Original Assignee
Bayer CropScience AG
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Publication date
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Publication of EP2453750A2 publication Critical patent/EP2453750A2/fr
Withdrawn legal-status Critical Current

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Classifications

    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/647—Triazoles; Hydrogenated triazoles
    • A01N43/653—1,2,4-Triazoles; Hydrogenated 1,2,4-triazoles
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
    • A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
    • A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
    • A01N43/18—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with sulfur as the ring hetero atom
    • A—HUMAN NECESSITIES
    • A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
    • A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
    • A01N47/10—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof
    • A01N47/12—Carbamic acid derivatives, i.e. containing the group —O—CO—N<; Thio analogues thereof containing a —O—CO—N< group, or a thio analogue thereof, neither directly attached to a ring nor the nitrogen atom being a member of a heterocyclic ring

Definitions

  • the present invention relates to novel drug combinations which contain a known compound of the formula (I) on the one hand and at least one known fungicidal active ingredient on the other hand and are very well suited for controlling unwanted animal pests such as insects and unwanted phytopathogenic fungi.
  • R 1 is H or NH 2
  • R 2 is CH 3 or F
  • have insecticidal activity see WO 1999/055668 and WO 2006/043635).
  • substituted halopyrimidines have fungicidal properties (cf., DE-Al-196 46 407, EP-B-712 396).
  • the compounds of the formula (I) have a chiral sulfoxide group such that they form two enantiomers with R or S configuration on the sulfur in the absence of further chiral centers: (IA), R-enantiomers,
  • Methods eg. B. characterized by X-ray structure analysis or rotation determination.
  • the present invention therefore also relates to novel drug combinations which contain the R- or S-enantiomers of the compounds of the formula (I) and at least one further fungicidal active ingredient. It has now been found that active compound combinations of at least one compound of the formula (I) and at least one active compound selected from the groups (2) to (27) mentioned below are synergistically active and have very good insecticidal and fungicidal properties.
  • a 2 is NH or O
  • a 3 is N or CH
  • R 11 is in each case optionally monosubstituted or disubstituted by identical or different chlorine, cyano, methyl or trifluoromethyl-substituted phenyl, phenoxy or pyridinyl, or for 1- (4-chlorophenyl) -pyrazol-3-yl or for 1,2-propanedione bis (O-methyloxime) -1-yl, R 12 is hydrogen or fluorine;
  • R 15 and R 17 together then represent -CH 2 -CH 2 -CH [CH (CHj) 2 ] - or -CH 2 -CH r C (CH 3 ) 2 -, represents C or Si (silicon),
  • a 4 also represents -N (R 17 ) - and A 5 also together with R 15 and R 16 represents the group
  • R 15 is hydrogen, hydroxy or cyano
  • R 16 represents 1-cyclopropylethyl, 1-chlorocyclopropyl, C r C 4 alkyl, C r C 6 hydroxyalkyl, C 1 -C 4 - alkylcarbonyl, C r C 2 haloalkoxy C 1 -C 2 -alkyl, trimethylsilylC r C 2 -alkyl, monofluorophenyl, or phenyl,
  • R 15 and R 16 also together represent -0-CH 2 -CH (R 18 ) -O-, -O-CH 2 -CH (R 18 ) -CH 2 -, or -O-CH- (2-chlorophenyl) -, R 18 is hydrogen, C 1 -C 4 -alkyl or bromine; Group (4) sulfenamides of the general formula (IV)
  • X is 2-chloro-3-pyridinyl, 1-methylpyrazol-4-yl which is substituted in the 3-position by methyl, trifluoromethyl or difluoroethyl and in the 5-position by hydrogen, fluorine or chlorine, for 4-ethyl 2-ethylamino-1, 3-thiazol-5-yl, for 1-methylcyclohexyl, for 2,2-dichloro-1-ethyl-3-methylcyclopropyl, for 2-fluoro-2-propyl, 3, 4-dichloroisothiazol-5-yl, 5,6-dihydro-2-methyl-1,4-oxathiin-3-yl, 4-methyl-1,2,3-thiadiazol-5-yl, 4,5- dimethyl-2-trimethylsilyl-thiophen-3-yl, L-methylpyrrol-3-yl, which is substituted in the 4-position by methyl or trifluoromethyl and in the 5-position by hydrogen or chlorine, or represents phenyl which is monosub
  • a 6 is CH or N
  • R 20 represents hydrogen, chlorine, cyano, C 1 -C 6 -alkyl, optionally substituted once or twice, identically or differently by chlorine or di (C 1 -C 3 -alkyl) aminocarbonyl
  • R 21 is hydrogen, chlorine or isopropoxy
  • R 22 represents hydrogen, chlorine, hydroxyl, methyl, trifluoromethyl or di (C 1 -C 3 -alkyl) aminocarbonyl
  • R 20 and R 21 also together represent * -CH (CH 3 ) -CH 2 -C (CH 3 ) 2 - or * -CH (CH 3 ) -OC (CH 3 ) 2 -, wherein the bond marked with * is linked to R 20 or out of line for a rest stands;
  • R 24 is methyl, cyclopropyl or 1-propynyl
  • R 25 and R 26 are each hydrogen or together are -O-CF 2 -O-,
  • R 27 is hydrogen, Ci-Gi-alkylaminocarbonyl or 3,5-dimethylisoxazol-4-ylsulfonyl,
  • R 28 is chloro, methoxycarbonylamino, chlorophenyl, furyl or thiazolyl;
  • Group (11) Carbamates of the general formula (DO
  • R is n- or isopropyl
  • R 3Ü is di (C 1 -C 2 -alkyl) amino C 2 -C 4 alkyl or diethoxyphenyl, including salts of these compounds; as well as the carbamate pyribencarb.
  • R and R independently of one another represent hydrogen or methyl
  • R 33 is C r C 14 alkyl (preferably C] 2 -C 14 alkyl), C 5 -C 2 cycloalkyl (preferably C 0 -C 2 -Cycloal- alkyl), phenyl-Ci-C 4 alkyl, which may be substituted in the phenyl moiety by halogen or CpGi-alkyl, or acrylyl which is substituted by chlorophenyl and dimethoxyphenyl;
  • R 34 is chlorine or cyano
  • R 35 is chlorine or nitro
  • R j is chlorine
  • R and R together also represent -O-CF 2 -O-;
  • R 37 is phenyl, phenyl, 2-naphthyl, 1,2,3,4-tetrahydronaphthyl or indanyl unsubstituted or substituted by fluorine, chlorine, bromine, methyl or ethyl;
  • R> 3 y 9 is C 1 -C 6 -alkyl
  • R 4 ⁇ 6 alkenyl stands for Ci-Q-alkyl or C 2 -C
  • R 41 is C r C 6 alkyl
  • R 40 and R 41 also together represent C 4 -C 5 alkanediyl (alkylene) which is monosubstituted or disubstituted by Q-Ce-alkyl,
  • R 42 represents bromine or chlorine, R and R independently of one another represent hydrogen, fluorine, chlorine or methyl,
  • R and R independently of one another represent hydrogen or fluorine, R 45 represents hydrogen, fluorine or methyl, Group (23): iodochromones of the general formula (XV)
  • R " 5 is C r C 6 -alkyl
  • K> 4 ⁇ 9 is C 1 -C 6 -alkyl, C 2 -C 6 -alkenyl or C 2 -C 6 -alkynyl;
  • R is hydrogen or fluorine
  • R 51 is fluorine, chlorine, bromine, methyl, trifluoromethyl, trifluoromethoxy
  • R 52 is hydrogen, fluorine, chlorine, bromine, methyl or trifluoromethyl
  • Het is one of the following radicals Hetl to Het 7:
  • R 53 is iodine, methyl, difluoromethyl or trifluoromethyl
  • R 54 is hydrogen, fluorine, chlorine or methyl
  • R 55 is methyl, difluoromethyl or trifluoromethyl
  • R 56 is chlorine, bromine, iodine, methyl, difluoromethyl or trifluoromethyl
  • R 57 is methyl or trifluoromethyl.
  • Group (25) Sulfonamides (25-1) Amisulbrom Group (26): Thiazolidines (26-1) Flutianil Group (27): Dinitrophenols (27-1) Meptyldinocap
  • the fungicidal action of the active compound combinations according to the invention is substantially higher than the sum of the effects of the individual active compounds. So there is an unpredictable, true synergistic effect and not just an effect supplement.
  • the insecticidal activity of the active compound combinations according to the invention is likewise substantially higher than the sum of the effects of the individual active compounds. So there is an unpredictable, true synergistic effect and not just an effect supplement.
  • the active compound combinations according to the invention contain, in addition to at least one compound of the formula (I), at least one active compound of the abovementioned groups (2) to (27).
  • the active compound combinations according to the invention preferably contain exactly one compound of the formula (I) and exactly one active compound of the groups (2) to (27) listed above. Further preferred are active compound combinations which contain a compound of the formula (I) and two active compounds of the groups (2) to (27) listed above. Also preferred are active compound combinations which comprise two compounds of the formula (I) and one active ingredient of the groups (2) to (27) listed above.
  • preferred subgroups for the compounds of the abovementioned formula (I) are listed in the active compound combinations according to the invention with at least one active compound of the abovementioned groups (2) to (27).
  • R 1 is hydrogen.
  • R 1 is NH 2 .
  • Li of another highlighted group of compounds of formula (I) R 2 is methyl.
  • R 2 is fluorine.
  • a preferred subgroup of the compounds of the formula (I) are those of the formula (I-1)
  • Another preferred subgroup of the compounds of the formula (I) are those of the formula (1-3)
  • Particularly preferred subgroups of the compounds of formula (I) are the respective R or S enantiomers of formulas (I-1A), (MB), (I-2A), (I-2B), (I-3A), ( I-3B), (1-4A), (I-4B):
  • Formula (II) encompasses the following preferred combination partners of group (2): (2-1) azoxystrobin (known from EP-A 0 382 375) of the formula
  • the formula (HI) comprises the following preferred combination partners of group (3):
  • the formula (IV) comprises the following preferred combination partners of group (4):
  • Preferred combination partners of group (5) are
  • Penthiopyrad (known from EP-A 0 737 682) of the formula
  • Preferred combination partners of group (7) are (7-1) Mancozeb (known from DE-A 12 34 704) with the IUPAC name Manganese ethylenebis (dithiocarbamate) (polymeric) complex with zinc
  • Zinc ammoniate ethylenebis (dithiocarbamate) - poly (ethylenethiuram disulfide)
  • the formula (VI) comprises the following preferred combination partners of the group (8):
  • the formula (VII) comprises the following preferred combination partners of the group (9):
  • the formula (VIII) comprises the following preferred combination partners of group (10):
  • the formula (IX) comprises the following preferred combination partners of the group (11):
  • the formula (X) comprises the following preferred combination partners of group (15):
  • Formula (XI) comprises the following preferred combination partners of group (16): (16-1) fenpiclonil (known from EP-A 0 236 272) of the formula
  • Preferred combination partners of group (17) are (17-1) fosetyl-Al (known from DE-A 24 56 627) of the formula (17-2) Phosphonic acid of the formula
  • the formula (XII) comprises the following preferred combination partners of group (18), which are known from WO 96/23793 and may each be present as (E) - or fZ ⁇ -isomers. Compounds of the formula (XII) can therefore be present as a mixture of different isomers or else in the form of a single isomer. Preference is given to compounds of the formula (XII) in the form of their (E) -isomer:
  • Metrafenone (known from EP-A 0 897 904) of the formula
  • Preferred combination partners of group (20) are:
  • Preferred combination partners of the group (21) are:
  • Preferred combination partners of group (22) are (22-1) 5-chloro-N - [ ⁇ S; -2,2,2-trifluoro-1-methylethyl] -6- (2,4,6-trifluorophenyl) [l , 2,4] triazolo [l, 5-a] - pyrimidin-7-amine (known from US 5,986,135) of the formula
  • Preferred combination partners of group (24) are (24-1) N-CS''-dichloro-S-fluoro-1J'-biphenyl-Z-y-O-S-cydifluoromethyl-1-methyl-1H-pyrazole-1-carboxamide (known from WO 03/070705) formula
  • Meptyldinocap (RS) -2- (1-methylheptyl) -4,6-dinitrophenyl crotonate (Known from ': Meptyldinocap: a new active substance for control of powdery mildew Hufnagl, AE; Distler, B .; Bacci, L .; Valverde, P. Dow AgroSciences, Mougins, Fr. International Plant Protection Congress, Proceedings, 16th, Glasgow, United Kingdom, Oct. 15-18, 2007 (2007), 1 32-39 Publisher: British Crop Production Council, Alton, UK)
  • the compound (6-7) carpropamid has three asymmetric substituted carbon atoms.
  • the compound (6-7) may therefore be present as a mixture of different isomers or in the form of a single component. Particularly preferred are the compounds
  • the active compound combinations according to the invention preferably comprise one of the compounds of the formula (I) which is selected from the group consisting of the compounds of the abovementioned formulas (I-1), (1-2), (1-3) or (1-4 ), and an active ingredient selected from the above-mentioned groups (2) to (27).
  • the active compound combinations according to the invention also particularly preferably contain one of the compounds of the formula (I) which is selected from the group consisting of the compounds of the abovementioned formulas (I-1) or (1-4) and an active compound selected from the abovementioned groups (2) to (27).
  • the active compound combinations according to the invention very particularly preferably contain the compound of the formula (I-1) and an active compound selected from the abovementioned groups (2) to (27).
  • the active compound combinations according to the invention contain the compound of the formula (1-4) and an active compound selected from the abovementioned groups (2) to (27).
  • the following active substances are particularly preferred:
  • very particularly preferred embodiments of the invention each provide combinations of enantiomerically pure compounds of formula (I-1), i. the compounds of the formulas (I-1A) and (I-1B) with an active compound of groups 2 to 27 according to Table 1, in particular preferred embodiments represent such combinations which the compound of formula (I-IA) and an active ingredient of Groups 2 to 27 according to Table 1 included.
  • very particularly preferred embodiments according to the invention each represent combinations of enantiomerically pure compounds of the formula (I-2), ie the compounds of the formulas (I-2A) and (I-2B) with an active compound of groups 2 to 27 according to Table 2, in particular Preferred embodiments are those combinations which contain the compound of the formula (I-2A) and an active compound of the groups 2 to 27 according to Table 2. Furthermore, the combinations listed in Table 3 are obtained, each combination representing a preferred embodiment according to the invention.
  • each combination represents combinations of enantiomerically pure compounds of the formula (1-3), ie the compounds of the formulas (I-3A) and (I-3B) with an active compound of groups 2 to 27 according to Table 3, in particular Preferred embodiments are those combinations which contain the compound of the formula (I-3A) and an active compound of the groups 2 to 27 according to Table 3. Furthermore, one obtains the combinations listed in Table 4, each combination represents a preferred embodiment of the invention itself.
  • Also very particularly preferred embodiments according to the invention each represent combinations of enantiomerically pure compounds of the formula (1-4), ie the compounds of the formulas (I-4A) and (I-4B) with an active compound of groups 2 to 27 according to Table 4, in particular Preferred embodiments are those combinations which contain the compound of the formula (I-4A) and an active compound of the groups 2 to 27 according to Table 4.
  • the active compound combinations according to the invention comprise, in addition to a compound of the formula (I), at least one active compound of the groups (2) to (27). You may also contain other fungicidal Zumischkomponenten.
  • the combinations according to the invention contain compounds of the formula (I) and a combination partner from one of the groups (2) to (27) in the mixing ratios exemplified in the table below.
  • the mixing ratios are based on weight ratios. The ratio is to be understood as compound of the formula (I): combination partner
  • Group (2) Strobilurins 125: 1 to 1: 2000 50: 1 to 1 1000
  • Group (3) triazoles 125: 1 to 1: 2000 50: 1 to 1: 1000
  • Group (9) Anilino-pyrimidines 500: 1 to 1100 250: 1 to 1 50
  • Group (11) Carbamate 500: 1 to 1100 250: 1 to 1 50
  • Group (12) dicarboximides 500: 1 to 1100 250: 1 to 1 50
  • Dithianone 500 1 to 1 100 250 1 to 1 50
  • Metrafenone 125 1 to 1 2000 50 1 to 1 1000
  • Triazolopyrimidines 125 1 to 1 2000 50 1 to 1 1000
  • the compounds of the formula (I) or the active compounds from the abovementioned groups (2) to (27) having at least one basic center are capable of forming, for example, acid addition salts, for example with strong inorganic acids such as mineral acids, eg perchloric acid, sulfuric acid , Nitric acid, nitrous acid, a phosphoric acid or a hydrohalic acid, with strong organic carboxylic acids such as unsubstituted or substituted, eg halogen-substituted, C r C 4 alkanecarboxylic acids, eg acetic acid, saturated or unsaturated dicarboxylic acids, eg oxalic acid, malonic acid, succinic acid, maleic acid, Fumaric acid and phthalic acid, hydroxycarboxylic acids, for example ascorbic acid, lactic acid, malic acid, tartaric acid and citric acid, or benzoic acid, or with organic sulfonic acids such as unsubstituted or substituted, for example
  • the compounds of the formula (I) or the active compounds from the abovementioned groups (2) to (27) having at least one acidic group are capable of forming, for example, salts with bases, for example metal salts such as alkali metal or alkaline earth metal salts, eg Sodium, potassium or magnesium salts, or salts with ammonia or an organic amine such as morpholine, piperidine, pyrrolidine, a lower mono-, di- or trialkylamine, for example ethyl, diethyl, triethyl or dimethylpropylamine, or a lower mono- , Di- or trihydroxyalkylamine, for example mono-, di- or triethanolamine.
  • bases for example metal salts such as alkali metal or alkaline earth metal salts, eg Sodium, potassium or magnesium salts, or salts with ammonia or an organic amine such as morpholine, piperidine, pyrrolidine, a lower mono-, di- or trialkylamine, for example
  • Agrochemically advantageous salts are preferred in the context of the invention.
  • any reference to the free compounds of formula (I ) or to free active compounds from the abovementioned groups (2) to (27) or their salts so that the corresponding salts or the free compounds of the formula (I) or the free active compounds from the groups listed above ( 2) to (27), if appropriate and appropriate.
  • This also applies correspondingly to tautomers of the compounds of the formula (I) or of the active compounds from the abovementioned groups (2) to (27) and to their salts.
  • active substance combination stands for different combinations of compounds of the formula (I) and active compounds from the abovementioned groups (2) to (27), for example in the form of a single ready-mix ("ready-mix").
  • ready-mix a combined spray mixture composed of separate formulations of the individual active ingredients, eg a tank mix or in a combined use of the individual active substances, if they are applied sequentially, for example successively within a reasonably short period of time, eg a few hours or days
  • the order of application of the compounds is the Formula (I) and the active compounds from the above-mentioned groups (2) to (27) are not critical to the practice of the present invention.
  • the application rate of the active compound combinations according to the invention is in the treatment of parts of plants, for example leaves from 0.1 to 1000 g / ha, preferably from 10 to 500 g / ha, particularly preferably from 50 to 300 g / ha (when used by pouring or drops the application rate can even be reduced, especially if inert substrates such as rockwool or perlite are used); in the seed treatment from 1 to 2000 g per 100 kg of seed, preferably from 2 to 1000 g per 100 kg of seed, more preferably from 3 to 750 g per 100 kg of seed, most preferably from 5 to 500 g per 100 kg of seed; in the soil treatment from 0.1 to 5000 g / ha, preferably from 1 to 1000 g / ha.
  • the active compound combinations according to the invention can be used to protect plants within a certain period of time after the treatment against attack by phytopathogenic fungi and / or animal pests.
  • the period of time within which protection is afforded generally ranges from 1 to 28 days, preferably from 1 to 14 days, more preferably from 1 to 10 days, most preferably from 1 to 7 days after treatment of the plants with the active ingredients or up to 200 days after seed treatment.
  • the active compound combinations according to the invention are suitable for plant tolerance, favorable warm-blooded toxicity and good environmental compatibility for the protection of plants and plant organs, for increasing crop yields, improving the quality of the crop and for controlling phytopathogenic fungi such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc., and animal pests, in particular insects, arachnids, helminths, nematodes and molluscs, which are found in agriculture, horticulture, livestock, forestry, gardens and recreational facilities, in the protection of materials and materials and in the hygiene sector.
  • phytopathogenic fungi such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
  • animal pests in
  • the active compound combinations according to the invention have very good fungicidal properties and can be used for controlling phytopathogenic fungi, such as Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes, Deuteromycetes, etc.
  • the active compound combinations according to the invention are particularly suitable for controlling Phytophthora infestans, Plasmopara viticola and Botrytis cinerea.
  • Fungicides can be used in crop protection to combat Plasmodiophoromycetes, Oomycetes, Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromycetes.
  • Bactericides can be used in crop protection for controlling Pseudomonadaceae, Rhizobiaceae, Enterobacteriaceae, Corynebacteriaceae and Streptomycetaceae.
  • Blumeria species such as Blumeria graminis
  • Podosphaera species such as Podosphaera leucotricha
  • Sphaerotheca species such as Sphaerotheca fuliginea
  • Uncinula species such as Uncinula necator
  • Gymnosporangium species such as, for example, Gymnosporangium sabinae Hemileia species, such as, for example, Hemileia vastatrix;
  • Phakopsora species such as Phakopsora pachyrhizi and Phakopsora meibomiae
  • Puccinia species such as Puccinia recondita
  • Uromyces species such as Uromyces appendicularus
  • Bremia species such as Bremia lactucae
  • Peronospora species such as Peronospora pisi or P. brassicae;
  • Phytophthora species such as Phytophthora infestans
  • Plasmopara species such as Plasmopara viticola
  • Pseudoperonospora species such as Pseudoperonospora humuli or Pseudoperonospora cubensis;
  • Pythium species such as Pythium ultimum
  • Alternaria species such as Alternaria solani;
  • Cercospora species such as Cercospora beticola
  • Cladiosporum species such as Cladiosporium cucumerinum
  • Cochliobolus species such as Cochliobolus sativus
  • Colletotrichum species such as Colletotrichum lindemuthanium
  • Cycloconium species such as cycloconium oleaginum
  • Diaporthe species such as Diaporthe citri;
  • Elsinoe species such as Elsinoe fawcettii
  • Gloeosporium species such as, for example, Gloeosporium laeticolor
  • Glomerella species such as Glomerella cingulata
  • Guignardia species such as Guignardia bidwelli;
  • Leptosphaeria species such as Leptosphaeria maculans
  • Magnaporthe species such as Magnaporthe grisea
  • Mycosphaerella species such as Mycosphaerelle graminicola
  • Phaeosphaeria species such as Phaeosphaeria nodorum
  • Pyrenophora species such as, for example, Pyrenophora teres
  • Ramularia species such as Ramularia collo-cygni
  • Rhynchosporium species such as Rhynchosporium secalis
  • Septoria species such as Septoria apii
  • Typhula species such as Typhula incarnata
  • Venturia species such as Venturia inaequalis
  • Corticium species such as Corticium graminearum
  • Fusarium species such as Fusarium oxysporum
  • Gaeumannomyces species such as Gaeumannomyces graminis
  • Rhizoctonia species such as Rhizoctonia solani
  • Tapesia species such as Tapesia acuformis
  • Thielaviopsis species such as Thielaviopsis basicola
  • Ear and panicle diseases caused by e.g.
  • Alternaria species such as Alternaria spp .
  • Aspergillus species such as Aspergillus flavus
  • Cladosporium species such as Cladosporium spp .
  • Claviceps species such as Claviceps purpurea
  • Fusarium species such as Fusarium culmorum
  • Gibberella species such as Gibberella zeae
  • Monographella species such as Monographella nivalis
  • Sphacelotheca species such as Sphacelotheca reiliana
  • Tilletia species such as Tilletia caries
  • Urocystis species such as Urocystis occulta; Ustilago species such as Ustilago nuda; Fruit rot caused by, for example, Aspergillus species such as Aspergillus flavus; Botrytis species, such as Botrytis cinerea; Penicillium species such as Penicillium expansum; Sclerotinia species, such as Sclerotinia sclerotiorum; Verticilium species such as Verticilium alboatrum;
  • Phytophthora species such as Phytophthora cactorum
  • Pythium species such as Pythium ultimum
  • Rhizoctonia species such as Rhizoctonia solani
  • Sclerotium species such as Sclerotium rolfsii; Cancers, galls and witches brooms caused by e.g.
  • Nectria species such as Nectria galligena
  • Monilinia species such as Monilinia laxa
  • Esca species such as Phaemoniella clamydospora
  • Botrytis species such as Botrytis cinerea
  • Diseases of plant tubers caused by eg Rhizoctonia species, such as Rhizoctonia solani
  • Diseases caused by bacterial pathogens such as Xanthomonas species, such as Xanthomonas campestris pv. Oryzae
  • Pseudomonas species such as Pseudomonas syringae pv. Lachrymans
  • Erwinia species such as Erwinia amylovora
  • the following diseases of soybean beans can be controlled: fungal diseases on leaves, stems, pods and seeds caused by e.g. Alternaria leaf spot (Alternaria spec. Atrans tenuissima), Anthracnose (Colletotrichum gloeosporoides dematium var.
  • Black Root Red (Calonectria crotalariae), Charcoal Red (Macrophomina phaseolina), Fusarium Blight or Wiit, Root Red, and Pod and Collar Red (Fusarium oxysporum, Fusarium orthoceras, Fusarium semitectum, Fusarium equiseti), Mycoleptodiscus Root Red (Mycoleptodiscus terrestris), Neocosmospora (Neocosmopspora vasinfecta), Pod and Star Blight (Diaporthe phaseolorum), Stem Canker (Diaporthe phaseolorum var.
  • Phytophthora red (Phytophthora megasperma), Brown Stem Red (Phialophora gregata), Pythium Red (Pythium aphanidermatum, Pythium irregular, Pythium Debaryanum, Pythium myriotylum, Pythium ultimum), Rhizoctonia Root Red, Stem Decay, and Damping Off (Rhizoctonia solani), Sclerotinia Stem Decay (Sclerotinia sclerotiorum), Sclerotinia Southern Blight (Sclerotinia rolfsii), Thielaviopsis Root Red (Thielaviopsis basicola).
  • the active compound combinations according to the invention can be used particularly successfully for combating cereal diseases, such as, for example, against Puccinia species and diseases in the wine, fruit and vegetable growing, such. against Botrytis, Venturia or Alternaria species.
  • the active compound combinations according to the invention also have very good antifungal effects. They have a very broad antimycotic spectrum of activity, in particular against dermatophytes and yeasts, mold and diphasic fungi (eg against Candida species such as Candida albicans, Candida glabrata) and Epidermophyton floccosum, Aspergillus species such as Aspergillus niger and Aspergillus fumigatus, Trichophyton species such as Trichophyton mentagrophytes, microsporon species such as Microsporon canis and audouinii.
  • Candida species such as Candida albicans, Candida glabrata
  • Epidermophyton floccosum Aspergillus species such as Aspergillus niger and Aspergillus fumigatus
  • Trichophyton species such as Trichophyton mentagrophytes
  • microsporon species such as Microsporon canis and audouinii.
  • the list of these fungi is by no means a limitation of the
  • the active compound combinations according to the invention also have very good insecticidal effects. They have a very broad insecticidal activity spectrum, in particular against the following animal pests:
  • Anoplura e.g. Damalinia spp., Haematopinus spp., Linognathus spp., Pediculus spp., Trichodectes spp.
  • arachnids e.g. Acarus siro, Aceria sheldoni, Aculops spp., Aculus spp., Amblyomma spp., Argas spp., Boophilus spp., Brevipalpus spp., Bryobia praetiosa, Chorioptes spp., Dermanyssus gallinae, Eotetranychus spp., Epitrimerus pyri, Eutetranychus spp.
  • Starchus spp. Symphyletes spp., Tenebrio molitor, Tribolium spp., Trogoderma spp., Tychius spp., Xylotrechus spp., Zabrus spp.
  • Gastropoda e.g. Arion spp., Biomphalaria spp., Bulinus spp., Deroceras spp., Galba spp., Lymnaea spp., Oncomelania spp., Succinea spp.
  • helminths from the class of helminths, for example, Ancylostoma duodenale, Ancylostoma ceylanicum, Acylostoma braziliensis, Ancylostoma spp., Ascaris lubricoides, Ascaris spp., Brugia malayi, Brugia timori, Bunostomum spp., Chabertia spp., Clonorchis spp., Cooperia spp., Dicrocoelium spp , Dictyocaulus filaria, Diphyllobothrium latum, Dracunculus medinensis, Echinococcus granulosus, Echinococcus multilocularis, Enterobius vermicularis, Faciola spp., Haemonchus spp., Heterakis spp., Hymenolepis nana, Hyostrongulus spp., Lo
  • protozoa such as Eimeria
  • Eimeria protozoa
  • Pseudaletia spp., Pseudoplusia includens, Pyrausta nubilalis, Rachiplusia ni, Spodoptera spp., Thermesia gemmatalis, Tinea pellionella, Tineola bisselliella, Tortrix viridana, Trichoplusia spp., Tuta spp.
  • Orthoptera e.g. Acheta domesticus, Blatta orientalis, Blattella germanica, Gryllotalpa spp., Leucophaea maderae, Locusta spp., Melanoplus spp., Periplaneta americana, Schistocerca gregaria.
  • siphonaptera e.g. Ceratophyllus spp., Xenopsylla cheopis.
  • Symphyla e.g. Scutigerella immaculata.
  • Thysanoptera e.g. Basothrips biformis, Enneothrips flavens, Frankliniella spp., Heliothrips spp., Hercinothrips femoralis, Kakothrips spp., Rhipiphorothrips cruentatus, Scirtothrips spp., Taeniothrips cardamoni, Thrips spp.
  • Thysanura e.g. Lepisma saccharina.
  • the plant parasitic nematodes include, for example, Anguina spp., Aphelenchoides spp., Belonoaimus spp., Bursaphelenchus spp., Ditylenchus dipsaci, Globodera spp., Heliocotylenchus spp., Heterodera spp., Longidorus spp., Meloidogyne spp., Pratylenchus spp., Radopholus similis, Rotylenchus spp., Trichodorus spp., Tylenchorhynchus spp., Tylenchulus spp., Tylenchulus semipenetrans, Xiphinema spp.
  • the active compound combinations according to the invention can be used to protect industrial materials against infestation and destruction by undesired microorganisms.
  • Technical materials as used herein mean non-living materials that have been prepared for use in the art.
  • technical materials to be protected from microbial change or destruction by the active compounds of the invention may be adhesives, glues, paper and cardboard, textiles, leather, wood, paints and plastics, coolants, and other materials that may be infested or degraded by microorganisms .
  • materials to be protected are also parts of production plants, such as cooling water circuits, called, which can be affected by the proliferation of microorganisms.
  • technical materials which may be mentioned are preferably adhesives, glues, papers and cartons, leather, wood, paints, cooling lubricants and heat transfer fluids, particularly preferably wood.
  • microorganisms that can cause degradation or a change in the technical materials, for example, bacteria, fungi, yeasts, algae and mucus organisms may be mentioned.
  • the active compound combinations according to the invention preferably act against fungi, in particular molds, wood-discolouring and wood-destroying fungi (Basidiomycetes) and against slime organisms and algae.
  • Aspergillus such as Aspergillus niger
  • Chaetomium such as Chaetomium globosum
  • Coniophora like Coniophora puetana,
  • Lentinus such as Lentinus tigrinus
  • Penicillium such as Penicillium glaucum
  • Polyporus such as Polyporus versicolor
  • Aureobasidium such as Aureobasidium pullulans
  • Sclerophoma such as Sclerophoma pityophila
  • Trichoderma such as Trichoderma viride
  • Escherichia such as Escherichia coli
  • Pseudomonas such as Pseudomonas aeruginosa
  • Staphylococcus such as Staphylococcus aureus.
  • the active compound combinations according to the invention have a high insecticidal activity against insects which destroy industrial materials.
  • insects By way of example and preferably without limiting however, the following insects are mentioned:
  • Hymenoptera such as Sirex juvencus, Urocerus gigas, Urocerus gigas taignus, Urocerus augur.
  • Termites such as Kalotermes flavicollis, Cryptotermes brevis, Heterotermes indicola, Reticulitermes flavipes, Reticulitermes santonensis, Reticulitermes lucifugus, Mastotermes darwiniensis, Zootermopsis nevadensis, Coptotermes formosanus.
  • Non-living materials such as preferably plastics, adhesives, glues, papers and cardboard, leather, wood, wood processing products and paints.
  • the material to be protected from insect attack is wood and woodworking products.
  • Wood and woodworking products which can be protected by the active substance combinations according to the invention are to be understood by way of example: lumber, wooden beams, railway sleepers, bridge parts, boat jetties, wooden vehicles, crates, pallets, containers, telephone poles, wooden cladding, wooden windows and doors, plywood, Chipboard, carpentry or wood products, which are generally used in building or in the joinery.
  • the WirkstoflEkombinationen can be used as such, in the form of concentrates or generally customary formulations such as powders, granules, solutions, suspensions, emulsions or pastes.
  • the formulations mentioned can be prepared in a manner known per se, e.g. by mixing the active compounds with at least one solvent or diluent, emulsifier, dispersing and / or binding or fixing agent, water repellent, optionally siccatives and UV stabilizers and optionally dyes and pigments, and further processing aids.
  • the insecticidal active ingredient combinations or concentrates used for the protection of wood and wood-based materials contain the active ingredient according to the invention in a concentration of 0.0001 to 95 wt .-%, in particular 0.001 to 60 wt .-%.
  • the amount of active ingredient combinations or concentrates used depends on the nature and occurrence of the insects and on the medium.
  • the optimal amount used can be determined in each case by test series. In general, however, it is sufficient to use 0.0001 to 20% by weight, preferably 0.001 to 10% by weight, of the active ingredient, based on the material to be protected.
  • insects in particular insects, arachnids and mites, which are used in enclosed spaces, such as, for example, apartments, factory halls, offices, vehicle cabins and the like. occurrence. They can be used to control these pests in household insecticide products. They are effective against sensitive and resistant species and against all stages of development. These pests include:
  • Acarina e.g. Argas persicus, Argas reflexus, Bryobia ssp., Dermanyssus gallinae, Glyciphagus domesticus, Ornithodorus moubat, Rhipicephalus sanguineus, Trombicula alfreddugesi, Neutrombicula autumnalis, Dermatophagoides pteronissimus, Dermatophagoides forinae.
  • Opiliones eg Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
  • the Opiliones eg Pseudoscorpiones chelifer, Pseudoscorpiones cheiridium, Opiliones phalangium.
  • the Isopoda eg Oniscus asellus, Porcellio scaber.
  • Diplopoda eg Blaniulus guttulatus, Polydesmus spp.
  • Chilopoda eg Geophilus spp.
  • Zygentoma e.g. Ctenolepisma spp., Lepisma saccharina, Lepismodes inquilinus.
  • the Blattaria e.g. Blatta orientalies, Blattella germanica, Blattella asahinai, Leucophaea maderae, Panchlora spp., Parcoblatta spp., Periplaneta australasiae, Periplaneta americana, Periplaneta brunnea, Periplaneta fuliginosa, Supella longipalpa.
  • Saltatoria e.g. Acheta domesticus.
  • Dermaptera e.g. Forf ⁇ cula auricularia.
  • Isoptera e.g. Kalotermes spp.
  • Reticulitermes spp. From the order of Psocoptera e.g. Lepinatus spp., Liposcelis spp.
  • Lepidoptera e.g. Achroia grisella, Galleria mellonella, Plodia interpunctella, Tinea cloacella, Tinea pellionella, Tineola bisselliella.
  • Ctenocephalides canis Ctenocephalides felis, Pulex irritans, Tunga penetrans, Xenopsylla cheopis.
  • Hymenoptera From the order of the Hymenoptera, for example, Camponotus herculeanus, Lasius fuliginosus, Lasius niger, Lasius umbratus, Monomorium pharaonis, Paravespula spp., Tetramorium caespitum. From the order of the Anoplura eg Pediculus humanus capitis, Pediculus humanus co ⁇ oris, Phthirus pubis. From the order of Heteroptera eg Cimex hemipterus, Cimex lectularius, Rhodinus prolixus, Triatoma infestans.
  • Application is in aerosols, non-pressurized sprays, e.g. Pump and atomizer sprays, misting machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-less or passive evaporation systems, moth papers, moth cakes and moth gels, as granules or dusts, in straw baits or bait stations.
  • Pump and atomizer sprays misting machines, foggers, foams, gels, evaporator products with cellulose or plastic evaporator plates, liquid evaporators, gel and membrane evaporators, propeller-driven evaporators, energy-less or passive evaporation systems, moth papers, moth cakes and moth gels, as granules or dusts, in straw baits or bait stations.
  • the active compound combinations of the invention not only against plant, hygiene and storage pests, but also in the veterinary sector against animal parasites (ecotasparasites) such as ticks, leather ticks, mange mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, Hair pieces, featherlings and fleas.
  • animal parasites ecotasparasites
  • ticks leather ticks, mange mites, running mites, flies (stinging and licking), parasitic fly larvae, lice, Hair pieces, featherlings and fleas.
  • Anoplurida e.g. Haematopinus spp., Linognathus spp., Pediculus spp., Phtirus spp., Solenopotes spp.
  • Trimenopon spp. Menopon spp., Trinoton spp., Bovicola spp., Werneckiella spp., Lepikentron spp., Damalina spp., Trichodectes spp., Felicola spp.
  • Nematocerina and Brachycerina e.g. Aedes spp., Anopheles spp., Culex spp., Simulium spp., Eusimulium spp., Phlebotomus spp., Lutzomyia spp., Culicoides spp., Chrysops spp., Hybomitra spp., Atylotus spp., Tabanus spp., Haematopota spp , Philipomyia spp., Braula spp., Musca spp., Hydrotaea spp., Stomoxys spp., Haematobia spp., Morellia spp., Fannia spp., Glossina spp., Calliphora spp., Glossina spp., Chrysomyia spppp
  • siphonaptrida e.g. Pulex spp., Ctenocephalides spp., Xenopsylla spp., Ceratophyllus spp.
  • heteropterid e.g. Cimex spp., Triatoma spp., Rhodnius spp., Panstrongylus spp.
  • Actinedida Prostigmata
  • Acaridida e.g. Acarapis spp., Cheyletiella spp., Ornitrocheyletia spp., Myobia spp., Psorergates spp., Demodex spp., Trombicula spp., Listrophorus spp., Acarus spp., Tyrophagus spp., Caloglyphus spp., Hypodectes spp., Pterolichus spp , Psoroptes spp., Chorioptes spp., Otodectes spp., Sarcoptes spp., Notoedres spp., Knemidocoptes spp., Cytodites spp., Laminosioptes spp.
  • the active compound combinations according to the invention are also suitable for controlling arthropods which are farm animals, such as e.g. Cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, such. Hamsters, guinea pigs, rats and mice.
  • arthropods are farm animals, such as e.g. Cattle, sheep, goats, horses, pigs, donkeys, camels, buffaloes, rabbits, chickens, turkeys, ducks, geese, bees, other pets such as e.g. Dogs, cats, caged birds, aquarium fish and so-called experimental animals, such. Hamsters, guinea pigs, rats and mice.
  • the application of the active compound combinations according to the invention is done in the veterinary sector in a known manner by enteral administration in the form of, for example, tablets, capsules, infusions, Drenchen, granules, pastes, BoIi, the feed-through process, suppositories, by parenteral administration, such as by Injections (intramuscular, subcutaneous, intravenous, intraperitoneal, etc.), implants, by nasal application, by dermal application in the form of, for example, dipping or bathing (dipping), spraying (spray), pouring (pour-on and spot-on), washing , powdering and with the aid of active substance-containing moldings, such as collars, ear tags, tail marks, limb bands, holsters, marking devices, etc.
  • enteral administration in the form of, for example, tablets, capsules, infusions, Drenchen, granules, pastes, BoIi, the feed-through process, suppositories
  • parenteral administration such as by
  • the active ingredient combinations as formulations for example, powders, emulsions, flowable agents
  • the active ingredients in an amount of 1 to 80% by weight apply directly or after 100 to 10 000 dilution or use as a chemical bath.
  • the active compound combinations according to the invention may optionally also be used in certain concentrations or application rates as herbicides, safeners, growth regulators or
  • Fungicides antimycotics, bactericides, viricides (including anti-viral agents) or as Agents against MLO (Mycoplasma-like-organism) and RLO (Rickettsia-like-organism) are used.
  • the active compounds can be converted into the customary formulations, such as solutions, emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble granules, scattering granules, suspension-emulsion concentrates, active substance-impregnated natural products, Active substance-impregnated synthetic substances, fertilizers and ultrafine encapsulations in polymeric substances.
  • customary formulations such as solutions, emulsions, wettable powders, water- and oil-based suspensions, powders, dusts, pastes, soluble powders, soluble granules, scattering granules, suspension-emulsion concentrates, active substance-impregnated natural products, Active substance-impregnated synthetic substances, fertilizers and ultrafine encapsulations in polymeric substances.
  • formulations are prepared in a known manner, e.g. by mixing the active compounds with extenders, ie liquid solvents and / or solid carriers, if appropriate using surface-active agents, ie emulsifiers and / or dispersants and / or foam-forming agents.
  • extenders ie liquid solvents and / or solid carriers
  • surface-active agents ie emulsifiers and / or dispersants and / or foam-forming agents.
  • Excipients which can be used are those which are suitable for imparting special properties to the composition itself and / or preparations derived therefrom (for example spray liquor, seed dressing), such as certain technical properties and / or specific biological properties.
  • Typical auxiliaries are: extenders, solvents and carriers.
  • Suitable extenders include, for example, water, polar and non-polar organic chemical liquids, for example from the classes of aromatic and non-aromatic hydrocarbons (such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes), alcohols and polyols (which may also be substituted, etherified and / or esterified ketones (such as acetone, cyclohexanone), esters (including fats and oils) and (poly) ethers, simple and substituted amines, amides, lactams (such as N-alkylpyrrolidones) and lactones, sulfones and sulfoxides (such as dimethyl sulfoxide).
  • aromatic and non-aromatic hydrocarbons such as paraffins, alkylbenzenes, alkylnaphthalenes, chlorobenzenes
  • alcohols and polyols which may also be substituted, etherified and / or
  • organic solvents can also be used as auxiliary solvents.
  • Suitable liquid solvents are essentially: aromatics, such as xylene, toluene, or alkylnaphthalenes, chlorinated aromatics and chlorinated aliphatic hydrocarbons, such as chlorobenzenes, chloroethylenes or methylene chloride, aliphatic hydrocarbons, such as cyclohexane or paraffins, for example petroleum fractions, mineral and vegetable oils, alcohols such as butanol or glycol and their ethers and esters, ketones such as acetone, methyl ethyl ketone, methyl isobutyl ketone or cyclohexanone, strongly polar solvents such as dimethyl sulfoxide, and water.
  • the carrier means a natural or synthetic, organic or inorganic substance which may be solid or liquid, with which the active ingredients are mixed or combined for better applicability, in particular for application to plants or plant parts or seeds.
  • the solid or liquid carrier is generally inert and should be useful in agriculture.
  • Suitable solid or liquid carriers are: e.g. Ammonium salts and ground natural minerals, such as kaolins, clays, talc, chalk, quartz, attapulgite, montmorillonite or diatomaceous earth, and ground synthetic minerals, such as finely divided silica, alumina and silicates, as solid carriers for granules are suitable: e.g. crushed and fractionated natural rocks such as calcite, marble, pumice, sepiolite, dolomite and synthetic granules of inorganic and organic flours and granules of organic material such as paper, sawdust, coconut shells, corn cobs and tobacco stems; suitable emulsifiers and / or foam formers are: e.g.
  • nonionic and anionic emulsifiers such as polyoxyethylene fatty acid esters, polyoxyethylene fatty alcohol ethers, e.g. Alkylaryl polyglycol ethers, alkylsulfonates, alkyl sulfates, arylsulfonates and protein hydrolysates;
  • suitable dispersants are non-ionic and / or ionic substances, e.g.
  • Adhesives such as carboxymethylcellulose, natural and synthetic powdery, granular or latex-type polymers such as gum arabic, polyvinyl alcohol, polyvinyl acetate, and natural phospholipids such as cephalins and lecithins and synthetic phospholipids may be used in the formulations.
  • Dyes such as inorganic pigments such as iron oxide, titanium oxide, ferrocyan blue and organic dyes such as alizarin, azo and metal phthalocyanine dyes and trace nutrients such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc can be used.
  • Other additives may be fragrances, mineral or vegetable optionally modified oils, waxes and nutrients (also trace nutrients), such as salts of iron, manganese, boron, copper, cobalt, molybdenum and zinc.
  • Stabilizers such as cold stabilizers, preservatives, antioxidants, light stabilizers or other chemical and / or physical stability-improving agents may also be present.
  • the active substance content of the application forms prepared from the commercial formulations can vary within wide ranges.
  • the active ingredient concentration of the use forms is in the range of 0.00000001 to 97 wt .-% of active ingredient, preferably in the range of 0.0000001 to 97 wt .-%, particularly preferably in the range of 0.000001 to 83 wt .-% or 0, 000001 to 5 wt .-% and most preferably in the range of 0.0001 to 1 wt .-%.
  • the active compound combinations according to the invention can be present in their commercially available formulations and in the formulations prepared from these formulations in admixture with other active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals.
  • active ingredients such as insecticides, attractants, sterilants, bactericides, acaricides, nematicides, fungicides, growth-regulating substances, herbicides, safeners, fertilizers or semiochemicals.
  • a mixture with other known active ingredients, such as herbicides, fertilizers, growth regulators, safeners, semiochemicals, or with agents for improving the plant properties is possible.
  • the active compound combinations according to the invention can furthermore be present in mixtures with synergists when used as fungicides and / or insecticides in their commercial formulations and in the forms of use prepared from these formulations.
  • Synergists are compounds that increase the effect of the active ingredients without the added synergist itself having to be active.
  • the active compound combinations according to the invention can also be present in their commercial formulations and in the forms of use prepared from these formulations in mixtures with inhibitors which inhibit degradation of the active substance after application in the environment of the plant, on the surface of plant parts or in plant tissues.
  • the application is done in a custom forms adapted to the application forms.
  • all plants and parts of plants can be treated.
  • plants are understood as meaning all plants and plant populations, such as desired and undesired wild plants or crop plants (including naturally occurring crop plants).
  • Crop plants can be plants which can be obtained by conventional breeding and optimization methods or by biotechnological and genetic engineering methods or combinations of these methods, including the transgenic plants and including the plant varieties which can or can not be protected by plant breeders' rights.
  • Plant parts are to be understood as meaning all aboveground and underground parts and organs of the plants, such as shoot, leaf, flower and root, by way of example leaves, needles, stems, stems, flowers, fruiting bodies, fruits and seeds and roots, tubers and rhizomes.
  • the plant parts also include crops and vegetative and generative propagation material, for example fruits, seeds, cuttings, tubers, rhizomes, offshoots, seeds, bulbs, sinkers and shoots.
  • the treatment according to the invention of the plants and plant parts with the active ingredient combinations takes place directly or by acting on their environment, habitat or storage space according to the usual treatment methods, e.g. by dipping, spraying, evaporating, atomizing, spreading, brushing, injecting and in propagating material, in particular in seeds, further by single or multilayer coating.
  • the active ingredient combinations can be prepared before the treatment by mixing the individual active ingredients.
  • the treatment is carried out successively by using first a compound of the formula (I) followed by the treatment with an active compound of the groups (2) to (27).
  • plants which can be treated according to the invention mention may be made of the following: cotton, flax, grapevine, fruits, vegetables, such as Rosaceae sp. (For example, pomes such as apple and pear, but also stone fruits such as apricots, cherries, almonds and peaches and soft fruits such
  • Rubiaceae sp. for example, coffee
  • Theaceae sp. Sterculiceae sp.
  • Rutaceae sp. for example, lemons, organs and grapefruit
  • Solanaceae sp. for example
  • Tomatoes Tomatoes
  • Liliaceae sp. Asteraceae sp. (for example, lettuce), Umbelliferae sp., Cruciferae sp.,
  • Papilionaceae sp. for example, peas
  • Main crops such as Gramineae sp.
  • Asteraceae sp. for example sunflower
  • Brassicaceae sp. for example, white cabbage, red cabbage, Broccoli, cauliflower, Brussels sprouts, pak choi, kohlrabi, radishes and rape, mustard, horseradish and cress
  • Fabacae sp. for example, bean, peanuts
  • Papilionaceae sp. for example, soybean
  • Solanaceae sp. for example potatoes
  • Chenopodiaceae sp. for example, sugar beet, fodder beet, Swiss chard, beet
  • the treatment method according to the invention can be used for the treatment of genetically modified organisms (GMOs), eg. As plants or seeds are used.
  • GMOs genetically modified organisms
  • Genetically modified plants are plants in which a heterologous gene has been stably integrated into the genome.
  • the term "heterologous gene” essentially refers to a gene which is provided or assembled outside the plant and which, when introduced into the nuclear genome, chloroplast genome or hypochondriacal genome, imparts new or improved agronomic or other properties to the transformed plant Expressing protein or polypeptide or that it is downregulating or shutting down another gene present in the plant or other genes present in the plant (for example by antisense technology, cosuppression technology or RNAi technology [RNA Interference]).
  • a heterologous gene present in the genome is also referred to as a transgene.
  • a transgene defined by its specific presence in the plant genome is referred to as a transformation or transgenic event.
  • the treatment according to the invention can also lead to superadditive (“synergistic") effects.
  • the following effects are possible, which go beyond the expected effects: reduced application rates and / or extended spectrum of action and / or increased efficacy of the active ingredients and compositions that can be used according to the invention, better plant growth, increased tolerance to high or low
  • Temperatures increased tolerance to drought or water or soil salinity, increased flowering, harvest relief, ripening, higher yields, larger fruits, greater plant height, intense green color of the leaf, earlier flowering, higher quality and / or higher nutritional value of the harvested products, higher sugar concentration in the fruits, better storage and / or processability of the harvested products.
  • the active compound combinations according to the invention can also exert a strengthening effect on plants. They are therefore suitable for mobilizing the plant defense system against attack by undesirable phytopathogenic fungi and / or microorganisms and / or viruses. This may possibly be one of the reasons for the increased Effectiveness of the combinations according to the invention, for example against fungi.
  • Plant-strengthening (resistance-inducing) substances in the present context should also mean those substances or combinations of substances which are able to stimulate the plant defense system such that the treated plants, when subsequently inoculated with undesirable phytopathogenic fungi and / or microorganisms and / or viruses a considerable degree of resistance to these unwanted phytopathogenic fungi and / or microorganisms and / or viruses.
  • phytopathogenic fungi, bacteria and viruses are understood to be undesirable phytopathogenic fungi and / or microorganisms and / or viruses.
  • the substances according to the invention can therefore be employed for the protection of plants against attack by the mentioned pathogens within a certain period of time after the treatment.
  • the period of time over which a protective effect is achieved generally extends from 1 to 10 days, preferably 1 to 7 days, after the treatment of the plants with the active substances.
  • Plants and plant varieties which are preferably treated according to the invention include all plants which have genetic material conferring on these plants particularly advantageous, useful features (whether obtained by breeding and / or biotechnology).
  • Plants and plant varieties which are also preferably treated according to the invention are resistant to one or more biotic stressors, i. H. These plants have an improved defense against animal and microbial pests such as nematodes, insects, mites, phytopathogenic fungi, bacteria, viruses and / or viroids.
  • Plants and plant varieties which can also be treated according to the invention are those plants which are resistant to one or more abiotic stress factors.
  • Abiotic stress conditions may include, for example, drought, cold and heat conditions, osmotic stress, waterlogging, increased soil salinity, increased exposure to minerals, ozone conditions, high light conditions, limited availability of nitrogen nutrients, limited availability of phosphorous nutrients, or avoidance of shade.
  • Plants and plant varieties which can also be treated according to the invention are those plants which are characterized by increased yield properties.
  • An increased yield can in these plants z. B. based on improved plant physiology, improved plant growth and improved plant development, such as water efficiency, water retention efficiency, improved nitrogen utilization, increased carbon assimilation, improved photosynthesis, increased germination and accelerated Abreife.
  • Yield can be further influenced by improved plant architecture (under stress and non-stress conditions), including early flowering, control of flowering for the production of hybrid seed, seedling vigor, plant size, internode count and distance, rooting, seed size, fruit size, pod size, pod or ear number, number of seeds per pod or ear, seed mass, increased seed filling, reduced seed drop , reduced pod popping and stability.
  • Other yield-related traits include seed composition such as carbohydrate content, protein content, oil content and composition, nutritional value, reduction of nontoxic compounds, improved processability, and improved shelf life.
  • Plants which can be treated according to the invention are hybrid plants which already express the properties of heterosis or hybrid effect, which generally leads to higher yield, higher vigor, better health and better resistance to biotic and abiotic stress factors.
  • Such plants are typically produced by crossing an inbred male sterile parental line (the female crossover partner) with another inbred male fertile parent line (the male crossbred partner).
  • the hybrid seed is typically harvested from the male sterile plants and sold to propagators.
  • Pollen sterile plants can sometimes be produced (eg in maize) by delaving (ie mechanical removal of the male reproductive organs or the male flowers); however, it is more common for male sterility to be due to genetic determinants in the plant genome.
  • cytoplasmic male sterility have been described, for example, for Brassica species (WO 1992/005251, WO 1995/009910, WO 1998/27806, WO 2005/002324, WO 2006/021972 and US 6,229,072).
  • pollen sterile plants can also be obtained using plant biotechnology methods such as genetic engineering.
  • a particularly convenient means of producing male-sterile plants is described in WO 89/10396, wherein, for example, a ribonuclease such as a barnase is selectively expressed in the tapetum cells in the stamens. The fertility can then be restorated by expression of a ribonuclease inhibitor such as barstar in the tapetum cells (eg WO 1991/002069).
  • Plants or plant varieties obtained by methods of plant biotechnology, such as genetic engineering which can be treated according to the invention are herbicidally tolerant plants, ie plants that have been tolerated to one or more given herbicides. Such plants can be obtained either by genetic transformation or by selection of plants containing a mutation conferring such herbicide tolerance.
  • Herbicide-tolerant plants are, for example, glyphosate-tolerant plants, i. H. Plants tolerant to the herbicide glyphosate or its salts.
  • glyphosate-tolerant plants can be obtained by transforming the plant with a gene encoding the enzyme 5-enolpyruvylshikimate-3-phosphate synthase (EPSPS).
  • EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
  • EPSPS 5-enolpyruvylshikimate-3-phosphate synthase
  • AroA gene mutant CT7 of the bacterium Salmonella typhimurium (Comai et al., Science (1983), 221, 370-371)
  • the CP4 gene of the bacterium Agrobacterium sp. Barry et al., Curr Topics Plant Physiol.
  • Glyphosate-tolerant plants can also be obtained by expressing a gene coding for a glyphosate oxidoreductase enzyme as described in US 5,776,760 and US 5,463,175. Glyphosate-tolerant plants can also be obtained by expressing a gene encoding a glyphosate acetyltransferase enzyme as described in, e.g. As WO 2002/036782, WO 2003/092360, WO 2005/012515 and WO 2007/024782 is encoded. Glyphosate-tolerant plants can also be obtained by selecting plants containing naturally-occurring mutations of the above-mentioned genes, as described, for example, in WO 2001/024615 or WO 2003/013226.
  • herbicide-resistant plants are, for example, plants which have been tolerated to herbicides which inhibit the enzyme glutamine synthase, such as bialaphos, phosphinotricin or glufosinate. Such plants can be obtained by expressing an enzyme which detoxifies the herbicide or a mutant of the enzyme glutamine synthase, which is resistant to inhibition.
  • an effective detoxifying enzyme is, for example, an enzyme encoding a phosphinotricin acetyltransferase (such as the bar or pat protein of Streptomyces species).
  • Plants expressing an exogenous phosphinotricin acetyltransferase are described, for example, in US 5,561,236; US 5,648,477; US 5,646,024; US 5,273,894; US 5,637,489; US 5,276,268; US 5,739,082; US 5,908,810 and US 7,112,665.
  • Further herbicide-tolerant plants are also plants tolerant to the herbicides which inhibit the enzyme hydroxyphenylpyruvate dioxygenase (HPPD).
  • HPPD hydroxyphenylpyruvate dioxygenases
  • the hydroxyphenylpyruvate dioxygenases are enzymes that catalyze the reaction in which para-hydroxyphenylpyruvate (HPP) is converted to homogentisate.
  • Plants tolerant of HPPD inhibitors may be treated with a gene encoding a naturally occurring resistant HPPD enzyme or a gene encoding a mutant HPPD enzyme as described in WO 1996/038567, WO 1999/024585 and WO 1999 / 024586, are transformed. Tolerance to HPPD inhibitors can also be achieved by transforming plants with genes encoding certain enzymes that allow the formation of homogentisate despite inhibition of the native HPPD enzyme by the HPPD inhibitor. Such plants and genes are described in WO 1999/034008 and WO 2002/36787.
  • the tolerance of plants to HPPD inhibitors can also be improved by transforming plants in addition to a gene coding for an HPPD-tolerant enzyme with a gene coding for a prephenate dehydrogenase enzyme, as described in WO 2004 / 024928 is described.
  • ALS inhibitors include sulfonylurea, imidazolinone, triazolopyrimidines, pyrimidinyloxy (thio) benzoates and / or sulfonylaminocarbonyltriazolinone herbicides.
  • ALS also known as acetohydroxy acid synthase, AHAS
  • AHAS acetohydroxy acid synthase
  • plants which are tolerant to imidazolinone and / or sulfonylurea can be obtained by induced mutagenesis, selection in cell cultures in the presence of the herbicide or by mutation breeding, as for example for the soybean in US 5,084,082, for rice in WO 1997/41218, for the sugar beet in US 5,773,702 and WO 1999/057965, for salad in US 5,198,599 or for the sunflower in WO 2001/065922.
  • Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering
  • Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such insect resistance.
  • insect-resistant transgenic plant includes any plant containing at least one transgene comprising a coding sequence encoding: 1) an insecticidal crystal protein from Bacillus thuringiensis or an insecticidal portion thereof, such as the insecticidal crystal proteins by Crickmore et al., Microbiology and Molecular Biology Reviews (1998), 62, 807-813, by Crickmore et al. (2005) in the Bacillus thuringiensis toxin nomenclature, online at: http://www.lifesci.sussex.ac.uk/Home/Neil_Crickmore/Bt/), or insecticidal parts thereof, e.g. Proteins of the cry protein classes CrylAb, CrylAc, CrylF, Cry2Ab, Cry3Ae or Cry3Bb or insecticidal parts thereof; or
  • a crystal protein from Bacillus thuringiensis or a part thereof which is insecticidal in the presence of a second, different crystal protein than Bacillus thuringiensis or a part thereof, such as the binary toxin consisting of the crystal proteins Cy34 and Cy35 (Moellenbeck et al., Nat Biotechnol. (2001), 19, 668-72; Schnepf et al., Applied Environment Microb. (2006), 71, 1765-1774); or
  • an insecticidal hybrid protein comprising parts of two different insecticidal crystal proteins from Bacillus thuringiensis, such as a hybrid of the proteins of 1) above or a hybrid of the proteins of 2) above, e.g. The protein Cryl A.105 produced by the corn event MON98034 (WO 2007/027777); or
  • a secreted protein from Bacillus thuringiensis or Bacillus cereus which is insecticidal in the presence of a second secreted protein from Bacillus thuringiensis or B. cereus, such as the binary toxin consisting of the proteins VIPlA and VIP2A (WO 1994/21795); or
  • a hybrid insecticidal protein comprising parts of various secreted proteins of Bacillus thuringiensis or Bacillus cereus, such as a hybrid of the proteins of 1) or a
  • 8) a protein according to any one of items 1) to 3) above, in which some, in particular 1 to 10, amino acids have been replaced by another amino acid in order to achieve a higher insecticidal activity against a target insect species and / or the spectrum of the corresponding To expand target insect species and / or due to alterations induced in the coding DNA during cloning or transformation (preserving coding for an insecticidal protein) such as protein VIP3Aa in cotton event COT 102.
  • insect-resistant transgenic plants in the present context also include any plant comprising a combination of genes encoding the proteins of any of the above classes 1 to 8.
  • an insect-resistant plant contains more than one transgene encoding a protein of any one of the above 1 to 8 in order to extend the spectrum of the corresponding target insect species or to delay the development of resistance of the insects to the plants by use different proteins which are insecticidal for the same target insect species, but have a different mode of action, such as binding to different receptor binding sites in the insect.
  • Plants or plant varieties which can also be treated according to the invention, are tolerant of abiotic stressors. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such stress resistance. Particularly useful plants with stress tolerance include the following: a. Plants which contain a transgene capable of reducing the expression and / or activity of the gene for the poly (ADP-ribose) polymerase (PARP) in the plant cells or plants, as described in WO 2000/004173 or EP 04077984.5 or EP 06009836.5 is described. b.
  • PARP ADP-ribose polymerase
  • Plants which contain a stress tolerance-promoting transgene capable of reducing the expression and / or activity of the PARG-encoding genes of the plants or plant cells as described, for example, in WO 2004/090140; c. Plants containing a stress tolerance enhancing transgene encoding a plant functional enzyme of the nicotinamide adenine dinucleotide salvage biosynthetic pathway, including nicotinamidase, nicotinate phosphoribosyltransferase, nicotinic acid mononucleotide adenyltransferase, nicotinamide adenine dinucleotide synthetase or nicotinamide phosphoribosyltransferase, as described e.g. In EP 04077624.7 or WO 2006/133827 or in PCT / EP07 / 002433.
  • Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering which can also be treated according to the invention have a changed quantity, quality and / or shelf life of the harvested product and / or altered characteristics of certain components of the harvested product, such as:
  • Transgenic plants which synthesize a modified starch with respect to their chemical-physical properties, in particular the amylose content or the amylose / amylopectin ratio, the degree of branching, the average chain length, the distribution of the side chains, the viscosity behavior, the gel strength, the starch grain size and / or starch grain morphology is altered in comparison to the synthesized starch in wild-type plant cells or plants, so that this modified starch is better suited for certain applications.
  • transgenic plants which synthesize a modified starch are described, for example, in EP 0571427, WO 1995/004826, EP 0719338, WO 1996/15248, WO 1996/19581, WO 1996/27674, WO 1997/11188, WO 1997/26362 WO 1997/32985, WO 1997/42328, WO 1997/44472, WO 1997/45545, WO 1998/27212, WO 1998/40503, WO 99/58688, WO 1999/58690, WO 1999/58654, WO 2000/008184 WO 2000/008185, WO 2000/28052, WO 2000/77229, WO 2001/12782, WO 2001/12826, WO 2002/101059, WO 2003/071860, WO 2004/056999, WO 2005/030942, WO 2005/030941 WO 2005/095632, WO 2005/095617, WO 2005/095619, WO 2005/095618, WO 2005/123927, WO 2006
  • Examples are plants which produce polyfructose, in particular of the inulin and levan type, as described in EP 0663956, WO 1996/001904, Wo 1996/021023, WO 1998/039460 and WO 1999/024593, plants which are alpha-1 To produce 4-glucans, as described in WO 1995/031553, US 2002/031826, US 6,284,479, US 5,712,107, WO 1997/047806, WO 1997/047807, WO 1997/047808 and WO 2000/14249, plants which alpha-1, 6-branched alpha-1,4-glucans, as described in WO 2000/73422, and plants producing alternan, as described in WO 2000/047727, EP 06077301.7, US 5,908,975 and EP 0728213 is.
  • Plants or plant varieties obtained by plant biotechnology methods such as genetic engineering), which can also be treated according to the invention, are plants such as cotton plants with altered fiber properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered fiber properties; These include: a) plants such as cotton plants containing an altered form of cellulose synthase genes, as described in WO 1998/000549; b) plants, such as cotton plants, containing an altered form of rsw2 or rsw3 homologous nucleic acids as described in U.S.
  • Pat WO 2004/053219 is described; c) plants such as cotton plants having increased expression of sucrose phosphate synthase as described in WO 2001/017333; d) plants such as cotton plants with an increased expression of sucrose synthase, as described in WO 02/45485; e) plants such as cotton plants in which the timing of the passage control of the Plasmodesmen is changed at the base of the fiber cell, z.
  • plants By down-regulating the fiber-selective ⁇ -l, 3-glucanase, as described in WO 2005/017157; f) plants such as cotton plants with modified reactivity fibers, e.g.
  • Plants or plant varieties which can also be treated according to the invention are plants such as oilseed rape or related Brassica plants with altered oil composition properties. Such plants can be obtained by genetic transformation or by selection of plants containing a mutation conferring such altered oil properties; These include: a) plants such as rape plants that produce high oleic oil, as described, for example, in US 5,969,169, US 5,840,946 or US 6,323,392 or US 6,063,947; b) plants such as oilseed rape plants which produce low linolenic acid oil, as described in US 6,270,828, US 6,169,190 or US 5,965,755. c) plants such as oilseed rape plants which produce oil with a low saturated fatty acid content, such as e.g. As described in US 5,434,283.
  • transgenic plants which can be treated according to the invention are plants having one or more genes which code for one or more toxins, the transgenic plants offered under the following commercial names: YIELD
  • GARD® for example corn, cotton, soybeans
  • KnockOut® for example corn
  • BiteGard® for example corn
  • BT-Xtra® for example maize
  • StarLink® for example corn
  • Herbicide-tolerant crops to be mentioned include, for example, corn, cotton and soybean varieties sold under the following tradenames: Roundup Ready® (glyphosate tolerance, for example corn, cotton, soybean), Liberty Link® (phosphinotricin tolerance, for example corn, cotton, soybean), Liberty Link® (phosphinotricin tolerance, for example corn, cotton, soybean), Liberty Link® (phosphinotricin tolerance, for example corn, cotton, soybean), Liberty Link® (phosphinotricin tolerance, for example
  • Example rapeseed IMI® (imidazolinone tolerance) and SCS® (Sylfonylurea tolerance), for example maize.
  • IMI® imidazolinone tolerance
  • SCS® Sylfonylurea tolerance
  • transgenic plants that can be treated according to the invention are plants that contain transformation events, or a combination of transformation events, and that are listed, for example, in the files of various national or regional authorities (see, for example, http: // /gmoinfo.jrc.it/gmp_browse.aspx and http://www.agbios.com/dbase.php).
  • the active compound combinations according to the invention are suitable for the treatment of seed.
  • a large part of the damage to crops caused by phytopathogenic fungi and / or animal pests already occurs through the infestation of the seed during storage and after introduction of the seed into the soil and during and immediately after germination of the plants.
  • This phase is particularly critical, as the roots and shoots of the growing plant are particularly sensitive and even minor damage can lead to the death of the entire plant.
  • suitable agents There is therefore a particular interest in protecting the seed and the germinating plant by the use of suitable agents.
  • the present invention therefore also relates in particular to a method for protecting seed and germinating plants from infestation by phytopathogenic fungi and / or animal pests by treating the seed with a combination of active substances according to the invention.
  • the inventive method for the protection of seeds and germinating plants from attack by phytopathogenic fungi and / or animal pests comprises a method in which the seed at the same time with a compound of formula (I) and a Active ingredient from the groups listed above (2) to (27) is treated. It also comprises a process in which the seed is treated at different times with a compound of formula (I) and an active ingredient from groups (2) to (27) listed above.
  • the invention also relates to the use of the active compound combinations according to the invention for the treatment of seed for the protection of the seed and the germinating plant from phytopathogenic fungi and / or by phytopathogenic fungi and / or animal pests.
  • the invention relates to seed which has been treated with a combination of active substances according to the invention for protection against phytopathogenic fungi and / or animal pests.
  • the invention also relates to seed treated at the same time with a compound of the formula (I) and an active ingredient from the groups (2) to (27) listed above.
  • the invention further relates to seed which has been treated at different times with a compound of formula (I) and an active ingredient from groups (2) to (27) listed above.
  • the individual active compounds of the active ingredient combination according to the invention may be present in different layers on the seed.
  • the layers which comprise a compound of the formula (I) and an active compound from the abovementioned groups (2) to (27) may optionally be separated by an intermediate layer.
  • the invention also relates to seed in which a compound of the formula (I) and an active compound from the abovementioned groups (2) to (27) are applied as a constituent of a coating or as a further layer or further layers in addition to a coating.
  • An advantage of the present invention is the synergistic increase in the insecticidal activity of the active compound combinations according to the invention over the insecticidal single active substance, which goes beyond the expected efficacy of the two individually applied active ingredients. Also advantageous is the synergistic increase in the fungicidal activity of the active compound combinations according to the invention compared with the fungicidal single active substance, which goes beyond the expected effectiveness of the individually applied active ingredient. This allows optimization of the amount of active ingredients used. Likewise, it is considered to be advantageous that the active compound combinations according to the invention can be used in particular also in transgenic seed.
  • the active compound combinations according to the invention are suitable for the protection of seed of any plant variety as already mentioned above, which are used in agriculture, in the greenhouse, in Forests or horticulture is used.
  • these are corn, peanut, canola, rapeseed, poppy, soybean, cotton, turnip (eg sugarbeet and fodder beet), rice, millet, wheat, barley, oats, rye, sunflower, tobacco, potatoes or vegetables ( eg tomatoes, cabbages, lettuce, etc.).
  • the active compound combinations according to the invention are likewise suitable for the treatment of the seed of fruit plants and vegetables as already mentioned above. Of particular importance is the treatment of the seeds of maize, soya, cotton, rice, wheat and canola or rapeseed.
  • the active ingredient combination according to the invention is applied to the seed alone or in a suitable formulation.
  • the seed is treated in a state where it is so stable that no damage occurs during the treatment.
  • the treatment of the seed can be done at any time between harvesting and sowing.
  • seed is used which has been separated from the plant and freed from flasks, shells, stems, hull, wool or pulp.
  • seed may be used which has been harvested, cleaned and dried to a moisture content below 15% by weight.
  • seed may also be used which, after drying, e.g. treated with water and then dried again.
  • compositions according to the invention can be applied directly, ie without containing further components and without being diluted.
  • suitable formulations and methods for seed treatment are known to those skilled in the art and are described e.g. in the following documents: US 4,272,417 A, US 4,245,432 A, US 4,808,430 A, US 5,876,739 A, US 2003/0176428 A1, WO 2002/080675 A1, WO 2002/028186 A2.
  • the active compounds which can be used according to the invention can be converted into the customary seed dressing formulations, such as solutions, emulsions, suspensions, powders, foams, slurries or other seed coating compositions, as well as ULV formulations.
  • formulations are prepared in a known manner by mixing the active ingredients with conventional additives, such as conventional extenders and solution or Diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also water.
  • conventional additives such as conventional extenders and solution or Diluents, dyes, wetting agents, dispersants, emulsifiers, defoamers, preservatives, secondary thickeners, adhesives, gibberellins and also water.
  • Dyes which may be present in the seed dressing formulations which can be used according to the invention are all dyes customary for such purposes. Both water-insoluble pigments and water-soluble dyes are useful in this case. Examples which may be mentioned under the names rhodamine B, CI. Pigment Red 112 and CI. Solvent Red 1 known dyes.
  • Suitable wetting agents which may be present in the seed dressing formulations which can be used according to the invention are all wetting-promoting substances customary for the formulation of agrochemical active compounds.
  • Preferably usable are alkylnaphthalene sulfonates such as diisopropyl or diisobutylnaphthalene sulfonates.
  • Suitable dispersants and / or emulsifiers which may be present in the seed dressing formulations which can be used according to the invention are all nonionic, anionic and cationic dispersants customary for the formulation of agrochemical active compounds.
  • Preferably usable are nonionic or anionic dispersants or mixtures of nonionic or anionic dispersants.
  • Particularly suitable nonionic dispersants are, in particular, ethylene oxide-propylene oxide, block polymers, alkylphenol polyglycol ethers and tristryrylphenol polyglycol ethers and their phosphated or sulfated derivatives.
  • Suitable anionic dispersants are in particular lignosulfonates, polyacrylic acid salts and arylsulfonate-formaldehyde condensates.
  • Defoamers which may be present in the seed-dressing formulations which can be used according to the invention are all foam-inhibiting substances customary for the formulation of agrochemical active compounds.
  • Preferably usable are silicone defoamers and magnesium stearate.
  • all substances which can be used for such purposes in agrochemical compositions can be present in the seed dressing formulations which can be used according to the invention.
  • examples include dichlorophen and Benzylalkoholhemiformal.
  • Suitable secondary thickeners which may be present in the seed dressing formulations which can be used according to the invention are all substances which can be used for such purposes in agrochemical compositions. Preference is given to cellulose derivatives, acrylic acid derivatives, xanthan, modified clays and highly dispersed silicic acid.
  • Suitable adhesives which may be present in the seed dressing formulations which can be used according to the invention are all customary binders which can be used in pickling agents. Preferably mentioned are polyvinylpyrrolidone, polyvinyl acetate, polyvinyl alcohol and Tylose.
  • the gibberellins are known (see R. Wegler "Chemie der convinced- und Swdlingsbekungsstoff", Vol. 2, Springer Verlag, 1970, pp. 401-412).
  • the seed dressing formulations which can be used according to the invention can be used either directly or after prior dilution with water for the treatment of seed of various kinds, including seed of transgenic plants. In this case, additional synergistic effects may occur in interaction with the substances formed by expression.
  • the seed dressing formulations which can be used according to the invention or the preparations prepared therefrom by the addition of water
  • all mixing devices customarily usable for the dressing can be considered. Specifically, in the pickling procedure, the seed is placed in a mixer which adds either desired amount of seed dressing formulations either as such or after prior dilution with water and mixes until evenly distributed the formulation on the seed.
  • a drying process follows.
  • the active compound combinations according to the invention are also suitable for increasing crop yield. They are also low toxicity and have good plant tolerance.
  • the active compound combinations according to the invention also have a strong tonic effect in plants. They are therefore suitable for mobilizing plant-own defenses against attack by unwanted microorganisms.
  • plant-strengthening (resistance-inducing) substances are to be understood as meaning those substances which are capable of stimulating the defense system of plants in such a way that the treated plants exhibit extensive resistance to these microorganisms with subsequent inoculation with undesired microorganisms.
  • Undesirable microorganisms in the present case are phytopathogenic fungi, bacteria and viruses.
  • the substances according to the invention can therefore be used to
  • the period within which protection is provided generally extends from 1 to 10 days, preferably 1 to 7 days after treatment of the plants with the active ingredients.
  • the plants listed can be treated particularly advantageously erf ⁇ ndungshack with the erfindungsgemasigem drug mixtures.
  • the preferred ranges given above for the active substance combinations also apply to the treatment of these plants.
  • Particularly emphasized is the plant treatment with the active ingredient combinations specifically mentioned in the present text.
  • a synergistic effect is always present in the case of insecticides and fungicides whenever the insecticidal or fungicidal action of the active substance combinations is greater than the sum of the effects of the individually applied active substances.
  • the expected insecticidal or fungicidal activity for a given combination of two drugs can be calculated as follows, according to S. Colby ("Calculating Synergistic and Antagonistic Responses of Herbicide Combinations", Weeds 1967.15, 20-22):
  • X denotes the degree of destruction or efficiency, expressed in% of the untreated control, when using the active compound A at a rate of application of mppm or g / ha,
  • Y means the degree of destruction or efficiency, expressed in% of the untreated control, when using the active substance B in an application rate of nppm or g / ha, and
  • E is the degree of kill or efficiency expressed as% of untreated control
  • the degree of kill or efficiency is determined in%. It means 0% a degree of kill or efficiency equal to that of the control, while a kill rate of 100% means that all animals are dead and an efficiency of 100% means that no infestation is observed. If the actual fungicidal or insecticidal effect is greater than calculated, the combination is over-additive in its effect, ie there is a synergistic effect. In this case, the actual observed efficiency must be greater than the expected efficiency value (E) calculated from the above formula.
  • dimethylformamide emulsifier 1.5 parts by weight of dimethylformamide emulsifier: 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica oleraceä) which are heavily infested with the green peach aphid ⁇ Myzus persicae) are treated by spraying with the preparation of active compound in the desired concentration.
  • the kill is determined in%. 100% means that all aphids have been killed; 0% means that no aphids have been killed.
  • the determined kill values are calculated according to the Colby formula. In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:
  • dimethylformamide emulsifier 1.5 parts by weight of dimethylformamide emulsifier: 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (Brassica olerace ⁇ ) are treated by being dipped into the preparation of active compound of the desired concentration and are populated with larvae of the horseradish leaf beetle ⁇ Phaedon cochleariae) while the leaves are still moist.
  • the kill is determined in%. 100% means that all beetle larvae have been killed; 0% means that no beetle larvae have been killed.
  • the determined kill values are calculated according to the Colby formula (see page 1). In this test, z. B. the following drug combinations according to the present application a synergistically enhanced efficacy compared to the individually applied drugs:
  • dimethylformamide emulsifier 1.5 parts by weight of dimethylformamide emulsifier: 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Bean leaf discs Phaseolus vulgaris
  • Triticae Tricholine
  • the effect is determined in%. 100% means that all spider mites have been killed; 0% means that no spider mites have been killed.
  • Emulsifier 0.5 part by weight of alkylaryl polyglycol ether
  • active compound 1 part by weight of active compound is mixed with the indicated amounts of solvent and emulsifier, and the concentrate is diluted with emulsifier-containing water to the desired concentration.
  • Cabbage leaves (ßrassica oleraceä) are treated by spraying with the preparation of active compound in the desired concentration and populated with larvae of the armyworm ⁇ Spodoptera frugiperda) while the leaves are still moist.
  • the kill is determined in%. 100% means that all caterpillars have been killed; 0% means that no caterpillars have been killed.
  • the determined kill values are calculated according to the Colby formula.

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Abstract

L'invention concerne de nouvelles combinaisons de substances actives qui contiennent au moins un composé connu de formule (I) dans laquelle R1 et R2 ont les significations indiquées dans la description, et au moins un autre agent actif connu appartenant aux groupes (2) à (27) décrits dans la description. Les combinaisons selon l'invention sont particulièrement appropriées pour lutter contre des animaux parasites tels que les insectes et les acariens indésirables, et contre les champignons phytopathogènes.
EP10737493A 2009-07-16 2010-07-06 Combinaisons de substances actives synergiques contenant des phényltriazoles Withdrawn EP2453750A2 (fr)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
DE102009027772 2009-07-16
PCT/EP2010/004101 WO2011006603A2 (fr) 2009-07-16 2010-07-06 Combinaisons de substances actives synergiques contenant des phényltriazoles

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KR20120051015A (ko) 2012-05-21
US20110166109A1 (en) 2011-07-07
CL2012000077A1 (es) 2012-10-05
CN103548836A (zh) 2014-02-05
IN2012DN01345A (fr) 2015-06-05
WO2011006603A3 (fr) 2011-07-28
MX2012000566A (es) 2012-03-06
JP2012532904A (ja) 2012-12-20
CN102510721A (zh) 2012-06-20
CO6491032A2 (es) 2012-07-31
BR112012001080A2 (pt) 2015-09-01
ZA201200309B (en) 2013-03-27
CN104430378A (zh) 2015-03-25
JP5642786B2 (ja) 2014-12-17
AU2010272872B2 (en) 2014-08-28
AU2010272872A1 (en) 2012-02-02
WO2011006603A2 (fr) 2011-01-20
CN102510721B (zh) 2014-11-19

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