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  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
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  • B01D53/34—Chemical or biological purification of waste gases
  • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
  • B01D53/86—Catalytic processes
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  • B01D53/8625—Nitrogen oxides
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  • B01D53/34—Chemical or biological purification of waste gases
  • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
  • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
  • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
  • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
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  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
  • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
  • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
  • B01J21/063—Titanium; Oxides or hydroxides thereof
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  • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
  • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
  • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
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  • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
  • B01J37/02—Impregnation, coating or precipitation
  • B01J37/0201—Impregnation
  • B01J37/0211—Impregnation using a colloidal suspension
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  • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
  • B01J37/02—Impregnation, coating or precipitation
  • B01J37/0215—Coating
  • B01J37/0221—Coating of particles
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  • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
  • B01J37/08—Heat treatment
  • B01J37/10—Heat treatment in the presence of water, e.g. steam
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B82—NANOTECHNOLOGY
  • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
  • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
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  • C01G23/00—Compounds of titanium
  • C01G23/04—Oxides; Hydroxides
  • C01G23/047—Titanium dioxide
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  • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
  • C01G23/00—Compounds of titanium
  • C01G23/04—Oxides; Hydroxides
  • C01G23/047—Titanium dioxide
  • C01G23/08—Drying; Calcining ; After treatment of titanium oxide
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  • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
  • C01G25/00—Compounds of zirconium
  • C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
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  • C01—INORGANIC CHEMISTRY
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  • C01G25/02—Oxides
• • B—PERFORMING OPERATIONS; TRANSPORTING
  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
  • B01D—SEPARATION
  • B01D2251/00—Reactants
  • B01D2251/20—Reductants
  • B01D2251/206—Ammonium compounds
  • B01D2251/2067—Urea
• • B—PERFORMING OPERATIONS; TRANSPORTING
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  • B01D2255/20—Metals or compounds thereof
  • B01D2255/207—Transition metals
  • B01D2255/20707—Titanium
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  • B01D2255/20715—Zirconium
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  • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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  • B01D2255/30—Silica
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  • C01P2002/00—Crystal-structural characteristics
  • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
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  • C01P2004/60—Particles characterised by their size
  • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
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  • C01P2006/13—Surface area thermal stability thereof at high temperatures
• • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
  • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
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  • Y02T10/12—Improving ICE efficiencies

Definitions

• the present invention relates to a composition based on a zirconium oxide, a titanium oxide or a mixed oxide of zirconium and titanium on a silica-based support, its methods of preparation and its use as a catalyst.
• the catalysts often consist of an active phase which is one which has the desired catalytic properties and a support on which this active phase is deposited. It is important for the efficiency of the catalyst that the active phase is dispersed as finely as possible on the support, that is to say that this active phase is in the form of fine particles, not aggregated on the support. In addition, since the catalysts are often exposed to high temperatures, the finely divided state of the active phase should also be maintained at these temperatures. In other words, there should be no sintering of the particles.
• the object of the invention is the development of catalysts meeting these conditions.
• the composition of the invention comprises at least one supported oxide, based on a zirconium oxide, a titanium oxide or a mixed oxide of zirconium and titanium on a support based on silica, and it is characterized in that, after calcination for 4 hours at 900 ° C., the supported oxide is in the form of particles deposited on said support, the size of which is at most 5 nm when the supported oxide is based on a zirconium oxide; at most 10 nm when the supported oxide is based on a titanium oxide; at most 8 nm when the supported oxide is based on a mixed oxide of zirconium and titanium.
• the composition comprises at least the same type of supported oxide and the same type of support and is characterized in that, after calcination for 4 hours at 1000 ° C., the supported oxide is in the form of particles, deposited on said support, whose size is at most 7 nm when the supported oxide is based on a zirconium oxide; at most 19 nm when the supported oxide is based on a titanium oxide; at most 10 nm when the supported oxide is based on a mixed oxide of zirconium and titanium.
• Rare earth means the elements of the group constituted by yttrium and the elements of the periodic classification of atomic number inclusive between 57 and 71.
• specific surface means the specific surface area B. AND. determined by nitrogen adsorption according to ASTM D 3663-78 based on the BRUNAUER method -
• calcinations for a given temperature and duration correspond, unless otherwise indicated, to calcinations under air at a temperature level over the time indicated.
• composition of the invention comprises an oxide supported in the form of particles of nanometric dimensions, these particles being deposited on a support.
• the supported oxide particles are predominantly present on the surface of this support, it being understood that the particles may be present within the pores of the support but remaining on the surface of these pores.
• This supported oxide may be first a single zirconium oxide, single oxide, in ZrO 2 form.
• the supported oxide may also be a doped zirconium oxide, that is to say it may be based on a zirconium oxide and at least one oxide of another element M chosen from praseodymium. , lanthanum, neodymium and yttrium.
• zirconium oxide ZrO 2 is the essential or majority constituent, the element or elements M then constitute the rest of the supported oxide.
• the content of element M is at most 50% by weight, zirconium oxide constituting at least 50% by weight of the supported oxide. This content is expressed as the mass of oxide of the element M or of all the elements M, relative to the mass of the supported oxide as a whole (zirconium oxide and oxide (s) element (s) ) M). This content of element M may vary over a wide range and may especially be between 5% and 40% and more particularly between 10% and 40%. This content may be especially between 10% and 30%.
• the supported oxide may also be TiO 2 titanium oxide.
• the supported oxide may be a mixed oxide of zirconium and titanium.
• mixed oxide is meant here a solid solution of titanium oxide and zirconium in the form of a pure crystallographic phase structure ZrTiO 4 .
• XRD X-ray diffraction technique
• This solid solution is generally present for proportions which may be between 30% and 40% by weight of titanium oxide relative to the total mass of the mixed oxide.
• composition may comprise several types of oxide on the support, that is to say both zirconium oxide particles, titanium oxide particles and mixed oxide particles.
• the supported oxide is in crystalline form.
• the supported oxide is present in the composition of the invention in the form of particles of nanometric dimensions.
• these particles can be either individualized or possibly in the form of aggregates.
• the size values given in the present description are average sizes determined by the XRD technique. The value measured
• DRX is the size of the coherent domain calculated from the width of the three most intense diffraction lines in the x, y, z space group and using the Debye-Scherrer model.
• the particle sizes of the supported oxide were given above depending on the supported oxide and the calcination conditions of the composition. It may be noted here that the values which have been given for a composition calcined at 1000 ° C. (second embodiment) can be applied to a composition which has also been previously calcined at 900 ° C.
• the particle sizes of the supported oxide may be even smaller than those given above.
• this size may be at most 4 nm when the supported oxide is based on an optionally doped zirconium oxide and at most 7 nm when the The supported oxide is based on a titanium oxide or a mixed oxide of zirconium and titanium.
• the minimum particle sizes are not critics and they can be very weak.
• the particle size may be at least 2 nm, more particularly at least 3 nm when the supported oxide is based on a zirconium oxide, optionally doped, and at least 3 nm.
• this size can be at most 6 nm when the supported oxide is based on a zirconium oxide, optionally doped, of at most 15 nm when the oxide supported is based on a titanium oxide and at most 8 nm when the supported oxide is based on a mixed oxide of zirconium and titanium.
• the particle size may be at least 2 nm, more particularly at least 3 nm when the supported oxide is based on an optionally doped zirconium oxide of at least 6 nm, more particularly at least 7 nm, when the supported oxide is based on a titanium oxide and at least 5 nm, more particularly at least 6 nm when the supported oxide is based on a mixed oxide of zirconium and titanium.
• the supported oxide content of the composition of the invention is generally at most 50% by weight of the entire composition (supported oxide and support). It may be in particular of not more than 30%.
• the minimum supported oxide content is that from which one skilled in the art knows that sufficient catalytic activity can be obtained and is set according to the desired performance of the composition. By way of example only, this minimum content is generally at least 3%, more particularly at least 4% by weight.
• the supported oxide content may in particular be between 10% and
• the support of the compositions of the invention is based on silica.
• a silica suitable for these uses is used, and preferably a silica having a high and stable specific surface area, that is to say which remains at a sufficient value. even after exposure to high temperature.
• This silica may be a precipitated silica or a pyrogenation silica.
• the silica may optionally be stabilized by a stabilizing element such as aluminum, for example.
• suitable silicas for the invention are those described in WO 2005/061384 and WO 99/49850.
• compositions of the invention may have a high BET surface area which may be, after calcination for 4 hours at 900 ° C., of at least 80 m 2 / g, more particularly at least 120 m 2 / g more particularly at least 150 m 2 / g. After calcination at 1000 ° C. for 4 hours, these compositions may have an area of at least 50 m 2 / g, more particularly at least 80 m 2 / g, still more particularly at least 100 m 2 / g.
• silicas which have been calcined beforehand at a temperature of between 600 ° C. and 650 ° C. and 900 ° C. and which have a loss on ignition (PAF) of between 2% and 15% are used as support. %, more particularly between 2 and 10% (measured at constant weight).
• PAF loss on ignition
• compositions of the invention can be prepared by various methods which will now be described.
• This first method comprises the following steps:
• the first step of this process is therefore to form a mixture from a colloidal dispersion of a zirconium compound or a colloidal dispersion of a titanium compound or a dispersion comprising both a compound of zirconium and a titanium compound this depending on the nature of the oxide supported in the composition that is to be prepared.
• this mixture further comprises a colloidal dispersion of a oxide of this element. It is also possible to use a single colloidal dispersion in which the colloids are based on a mixed zirconium oxide and on the element M.
• the present description applies well understood here in the case where the supported oxide comprises several elements M and it is understood that one can then use in this case several dispersions of the different elements M or possibly a single colloidal dispersion comprising all the elements M.
• the dispersions of the different elements M or possibly a single colloidal dispersion comprising all the elements M.
• colloidal dispersion any system consisting of fine solid particles of colloidal dimensions, that is to say dimensions of between about 1 nm and about 100 nm (dimension measured by the quasi-elastic light scattering technique), based on a compound of zirconium, titanium and / or the element M, this compound being generally an oxide and / or a hydrated oxide, in stable suspension in an aqueous liquid phase, said particles possibly also possibly containing quantities residuals of bound or adsorbed ions such as, for example, nitrates, acetates, chlorides or ammoniums.
• titanium or element M can be either totally in the form of colloids, or simultaneously in the form of ions and in the form of colloids.
• a mixture of the dispersion is formed with a suspension of the support.
• a colloidal dispersion of silica may be used.
• the suspension is generally an aqueous suspension.
• the mixture is in the aqueous phase, generally water and for example distilled or permuted water.
• the second step of the process is a drying step.
• This drying is done by atomization.
• Spray drying is understood to mean spray drying of the mixture in a hot atmosphere (spray-drying).
• the atomization can be carried out using any sprayer known per se, for example by a spraying nozzle of the watering apple or other type. It is also possible to use so-called turbine atomizers.
• spraying techniques that can be implemented in the present process, reference may be made in particular to the basic work of MASTERS entitled "SPRAY-DRYING" (second edition, 1976, Editions George Godwin - London).
• the atomization output temperature may be, for example, between 80 ° C. and 150 ° C.
• the last step of the process is a calcination step.
• This calcination makes it possible to develop the crystallinity of the supported product and it can also be adjusted and / or chosen as a function of the temperature of subsequent use reserved for the composition according to the invention, and this taking into account that the specific surface area of the product is even lower than the calcination temperature used is higher.
• Such calcination is generally performed under air, but a calcination carried out for example under inert gas or under a controlled atmosphere (oxidizing or reducing) is obviously not excluded.
• the calcination temperature is generally limited to a range of values between 500 ° C. and 800 ° C., preferably between
• the duration of calcination is adjusted in a known manner, it can vary for example between 30 minutes and 4 hours, this duration being generally lower as the temperature is high.
• compositions of the invention may also be prepared by a second method which will be described below. This process comprises the following steps:
• the mixture thus formed is heated to a temperature of at least 100 ° C .;
• said precipitate is calcined.
• a suspension of the support is also started but it is mixed with a zirconium salt and / or a titanium salt and a salt of the element M, in the case of compositions in which the supported oxide is based on a zirconium oxide and an oxide of another element M.
• This mixture is in aqueous phase, usually water.
• the starting silica suspension may optionally be acidified.
• the salts are preferably inorganic salts and they may be chosen in particular from nitrates, sulphates, acetates and chlorides.
• zirconyl sulphate, zirconyl nitrate or zirconyl chloride may more particularly be mentioned. It is also possible to use an oxychloride or a titanium oxysulphate.
• the next step of the process is the step of heating the liquid mixture thus formed.
• the temperature at which the liquid mixture is heated is at least
• the heating operation can be conducted by introducing the liquid mixture in a closed chamber (closed reactor type autoclave). Under the conditions of the temperatures given above, and in aqueous medium, it is thus possible to specify, by way of illustration, that the pressure in the closed reactor can vary between a value greater than 1 bar (10 5 Pa) and 165 bar (1 bar). , 65. 10 7 Pa), preferably between 5 Bar (5 ⁇ 10 5 Pa) and 165 Bar (1, 65. 10 7 Pa). It is also possible to carry out heating in an open reactor for temperatures close to 100 ° C.
• the heating may be conducted either in air or in an atmosphere of inert gas, preferably nitrogen.
• the duration of the heating can vary within wide limits, for example between 1 and 48 hours, preferably between 2 and 24 hours.
• the rise in temperature is carried out at a speed which is not critical, and it is thus possible to reach the fixed reaction temperature by heating the liquid mixture for example between 30 minutes and 4 hours, these values being given as to indicative.
• a solid precipitate is recovered which can be separated from its medium by any conventional solid-liquid separation technique such as, for example, filtration, decantation, spinning or centrifugation.
• the product as recovered can then be subjected to washes, which are then operated with water or optionally with a basic solution, for example an ammonia solution or an acidic solution, a nitric acid solution, for example.
• the method comprises a ripening.
• This ripening is generally carried out on a suspension obtained after returning to the water of the precipitate, especially after washing.
• the ripening is done by heating again this suspension.
• the temperature at which the suspension is heated is at least 40 ° C., more particularly at least 60 ° C. and even more particularly at least 100 ° C. Generally, this temperature is at most 200 ° C., more particularly at most 150 ° C.
• the medium is thus maintained at a constant temperature for a period of time which is usually at least 30 minutes and more particularly at least 1 hour.
• the ripening can be done at atmospheric pressure or possibly at a higher pressure.
• the last stage of calcination of this second process can be carried out in the same way as for the first process and thus what has been described above for this calcination applies likewise here.
• compositions of the invention may also be prepared by a third method which will now be described. This process comprises the following steps:
• a base is brought into contact with the preceding mixture so as to form a precipitate
• the first step of this third method is similar to the first one of the second method and what has been described above on this subject applies likewise here.
• the second step consists in obtaining a precipitate by reacting the mixture formed in the preceding stage with a base.
• Hydroxide, carbonate or hydroxycarbonate products can be used as the base, for example.
• Mention may be made of alkali or alkaline earth hydroxides, secondary, tertiary or quaternary amines. However, amines and ammonia may be preferred in that they reduce the risk of pollution by alkaline or alkaline earth cations. We can also mention urea.
• the placing in the presence or in contact can be done in any order in a liquid medium.
• the contact with the base leads to the formation of a precipitate suspended in the reaction liquid medium. More particularly, the addition of the base is carried out until a pH of the reaction medium of at least 7 is obtained.
• this process may comprise an optional additional step which consists in subjecting the suspension resulting from the preceding step to maturing.
• the ripening is done by heating the suspension to a temperature of at least 60 ° C., more particularly at least 80 ° C. Generally this temperature is at most 200 ° C., more particularly at most 150 ° C.
• the medium is thus maintained at a constant temperature for a period of time which is usually at least 30 minutes and more particularly at least 1 hour.
• the ripening can be done at atmospheric pressure or possibly at a higher pressure.
• compositions of the invention as described above or as obtained by the methods described above are in the form of powders but they may optionally be shaped to be in the form of granules, beads, cylinders or nests. bee of variable dimensions.
• compositions of the invention can be used as catalysts.
• the invention also relates to catalytic systems comprising the compositions of the invention.
• These systems comprise a coating (wash coat) with catalytic properties based on these compositions and a binder of known type, on a substrate of the type for example metallic monolith or ceramic. This coating is obtained by mixing the composition with the binder so as to form a suspension which can then be deposited on the substrate.
• catalytic systems and more particularly the compositions of the invention can find very many applications. They are thus particularly well adapted to, and therefore usable in the catalysis of various reactions such as, for example, dehydration, hydrosulfuration, hydrodenitrification, desulfurization, hydrodesulphurization, dehydrohalogenation, reforming, reforming.
• the catalytic systems and compositions of the invention may finally be used as a catalyst for the selective reduction of NOx by reduction reaction of these NOx by any hydrocarbon reducing agent or else by ammonia or urea and, in this case as a catalyst for the hydrolysis or decomposition reaction of urea to ammonia (SCR process).
• the compositions of the invention can be used in combination with precious metals or transition metals in oxide, sulfide or other form and thus play the role of support for these metals.
• the nature of these metals and the techniques for incorporating them into the support compositions are well known to those skilled in the art.
• the metals can be gold, silver, platinum, rhodium, palladium or iridium, molybdenum, tungsten, nickel, cobalt, manganese or vanadium; they may be used alone or in combination and they may in particular be incorporated into the compositions by impregnation.
• This example relates to the preparation according to the first method of the invention of a composition based on zirconium oxide dispersed on a silica support in the respective proportions by weight of oxide of 30% and 70%.
• a colloidal solution of ZrO 2 is first carried out.
• a concentrated solution of ZrO (NO 3 ) 2 with deionized water is diluted to obtain 600 ml of a solution of ZrO (NO 3 ) 2 at 80 g / l eq. ZrO 2 having a pH of 2.
• An NH 3 solution of 28% is added instantaneously so that the final pH reaches 10 and the formation of a precipitate is observed.
• the precipitate is filtered and then washed with 6L of deionized water.
• EXAMPLE 2 This example relates to the preparation according to the third method of the invention of a composition based on zirconium oxide on a silica support in the respective proportions by mass of oxide of 10% and 90%.
• the silica used is Tixosil 68® whose solids content at 900 ° C. is 90%
• the zirconium source is a solution of ZrO (NO 3 ) 2 whose solids content at 900 ° C. is 19.1%.
• a dilute solution of 10% ammonia is prepared by adding a volume of 28% NH 3 with two volumes of water.
• a stock is formed in the reactor by introducing 59.80 g of silica (ie 54 g of SiO 2) diluted with 771 ml of deionized water (70 g / l eq SiO 2), then 68% HNO 3 is added. in order to obtain a dispersion at pH 2.
• 31.41 g of ZrO (NO 3 ) 2 solution ie 6 g of ZrO 2 eq.
• 86 ml with deionized water 70 g / l eq ZrO 2
• the ammonia solution is then added at 10 ml / min until a pH of 9 is obtained (added mass: 32 g).
• the whole is transferred into an autoclave and brought under agitation to
• the cooled mixture is then filtered off and isovolume washed with water at room temperature.
• the cake is then calcined in air at 700 ° C. for 4 hours.
• This example relates to the preparation according to the third method of the invention of a composition based on zirconium oxide on a silica support in the respective proportions by weight of oxide of 30% and 70%.
• the same silica, the same source of zirconium and the same ammonia solution as in Example 2 are used.
• a stock is formed in the reactor by introducing 46.51 g of silica (ie 42 g of SiO 2 ) diluted with 60OmL of deionized water (70 g / L eq SiO 2 ), followed by HNO 3 68% in order to obtain a dispersion at pH 2.
• 94.24 g of ZrO (NO 3 ) 2 solution ie 18 g of ZrO 2 eq.
• diluted to 257 ml with deionized water (70 g / L eq ZrO 2 ) are introduced into the bottom of the tank, the ammonia solution is then added at 10 ml / min until a pH of 9 is obtained (added mass: 73 g).
• the treatment is then carried out by autoclaving, washing and calcining in the same manner as in Example 2.
• EXAMPLE 4 This example relates to the preparation according to the third method of the invention of a composition based on titanium oxide on a silica support in the respective proportions by mass of oxide of 10% and 90%.
• Tixosil 68® silica powder 200 g are dispersed in 570 ml of water in which HNO 3 has been added to obtain a pH of 0.5. 26.8 g of TiOCI 2 (21% equivalent weight of TiO 2) are then added to the medium obtained. 10% NH 4 OH is then added to achieve a pH of 7.
• Example 2 The treatment is then carried out by autoclaving, washing and calcining in the same manner as in Example 2.
• This example relates to the preparation according to the third method of the invention of a composition based on titanium oxide on a silica support in the respective proportions by mass of oxide of 30% and 70%.
• Example 2 The treatment is then carried out by autoclaving, washing and calcining in the same manner as in Example 2.
• This example relates to the preparation according to the third method of the invention of a composition based on oxides of titanium and zirconium on a silica support in the respective proportions by weight of oxide of 30% for ZrTiO 4 and 70% for SiO2.
• Example 2 The treatment is then carried out by autoclaving, washing and calcining in the same manner as in Example 2.
• the XRD analysis only shows the presence of the ZrTiO 4 phase.
• the following examples are comparative examples implementing the known technique of impregnation.
• This example relates to the preparation of a composition based on titanium oxide on a silica support in the respective proportions by mass of oxide of 10% and 90%.
• a composition containing 90% of SiO 2 and 10% of TiO 2 is prepared by dry impregnation of 16.09 g of silica according to Example 2 with 6.64 g of a 25.1% by weight TiOCI solution. 2 previously diluted in 23.5 ml of H 2 O.
• the powder is then calcined under air at 700 ° C. for 4 hours. It is verified by XRD that only the anatase phase is present between 700 and 900 ° C.
• This example relates to the preparation of a composition based on titanium oxide on a silica support in the respective proportions by weight of oxide of 30% and 70%.
• a mixture containing 70% of SiO 2 and 30% of TiO 2 is produced by dry impregnation of 12.88 g of silica according to Example 2 with 20.49 g of a 25.1% by weight TiOCI solution. 2 previously diluted in 9 ml of H 2 O. The powder is then calcined in air at 700 ° C for 4 hours.
• This example relates to the preparation of a composition based on titanium oxide on a silica support in the respective proportions by weight of oxide of 30% and 70%.
• a mixture containing 70% of SiO 2 and 30% of TiO 2 is produced by dry impregnation of 22.5 g of silica according to Example 2 with 15.45 g of a 25.1% by weight TiOCI solution. 2 previously diluted in 14.3 ml of H 2 O.
• the powder is then calcined under air at 700 ° C. for 4 hours. It is verified by XRD that only the ZrTiO 4 phase is present between 700 and 1000 ° C.
• compositions according to the invention have supported oxides whose size is significantly smaller than those of the oxides of the compositions obtained by the known impregnation technique.

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