FR2928094B1 - Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur - Google Patents

Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur

Info

Publication number
FR2928094B1
FR2928094B1 FR0801156A FR0801156A FR2928094B1 FR 2928094 B1 FR2928094 B1 FR 2928094B1 FR 0801156 A FR0801156 A FR 0801156A FR 0801156 A FR0801156 A FR 0801156A FR 2928094 B1 FR2928094 B1 FR 2928094B1
Authority
FR
France
Prior art keywords
titanium oxide
zirconium
oxide
catalyst
preparation
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Expired - Fee Related
Application number
FR0801156A
Other languages
English (en)
Other versions
FR2928094A1 (fr
Inventor
Stephan Verdier
Guillaume Criniere
Simon Ifrah
Rui Marques
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Rhodia Operations SAS
Original Assignee
Rhodia Operations SAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Priority to FR0801156A priority Critical patent/FR2928094B1/fr
Application filed by Rhodia Operations SAS filed Critical Rhodia Operations SAS
Priority to CN200980107506.XA priority patent/CN101959800B/zh
Priority to RU2010140393/05A priority patent/RU2448908C1/ru
Priority to PCT/EP2009/052126 priority patent/WO2009112355A1/fr
Priority to EP09719637A priority patent/EP2262735A1/fr
Priority to RU2012103968/05A priority patent/RU2531306C2/ru
Priority to JP2010549088A priority patent/JP5628049B2/ja
Priority to CA2716556A priority patent/CA2716556A1/fr
Priority to US12/920,394 priority patent/US8563462B2/en
Priority to KR1020107019581A priority patent/KR101215678B1/ko
Publication of FR2928094A1 publication Critical patent/FR2928094A1/fr
Application granted granted Critical
Publication of FR2928094B1 publication Critical patent/FR2928094B1/fr
Expired - Fee Related legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/86—Catalytic processes
    • B01D53/8621—Removing nitrogen compounds
    • B01D53/8625—Nitrogen oxides
    • B01D53/8628—Processes characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34—Chemical or biological purification of waste gases
    • B01D53/92—Chemical or biological purification of waste gases of engine exhaust gases
    • B01D53/94—Chemical or biological purification of waste gases of engine exhaust gases by catalytic processes
    • B01D53/9445—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC]
    • B01D53/945—Simultaneously removing carbon monoxide, hydrocarbons or nitrogen oxides making use of three-way catalysts [TWC] or four-way-catalysts [FWC] characterised by a specific catalyst
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/063—Titanium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/06—Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
    • B01J21/066—Zirconium or hafnium; Oxides or hydroxides thereof
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0201—Impregnation
    • B01J37/0211—Impregnation using a colloidal suspension
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/02—Impregnation, coating or precipitation
    • B01J37/0215—Coating
    • B01J37/0221—Coating of particles
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J37/00—Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
    • B01J37/08—Heat treatment
    • B01J37/10—Heat treatment in the presence of water, e.g. steam
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B82—NANOTECHNOLOGY
    • B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
    • B82Y30/00—Nanotechnology for materials or surface science, e.g. nanocomposites
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C01G23/047—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G23/00—Compounds of titanium
    • C01G23/04—Oxides; Hydroxides
    • C01G23/047—Titanium dioxide
    • C01G23/08—Drying; Calcining ; After treatment of titanium oxide
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/006—Compounds containing, besides zirconium, two or more other elements, with the exception of oxygen or hydrogen
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
    • C01G25/00—Compounds of zirconium
    • C01G25/02—Oxides
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2251/00—Reactants
    • B01D2251/20—Reductants
    • B01D2251/206—Ammonium compounds
    • B01D2251/2067—Urea
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20707—Titanium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/20—Metals or compounds thereof
    • B01D2255/207—Transition metals
    • B01D2255/20715—Zirconium
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01D—SEPARATION
    • B01D2255/00—Catalysts
    • B01D2255/30—Silica
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/613—10-100 m2/g
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J35/00—Catalysts, in general, characterised by their form or physical properties
    • B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
    • B01J35/61—Surface area
    • B01J35/615—100-500 m2/g
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2002/00—Crystal-structural characteristics
    • C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
    • C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2004/00—Particle morphology
    • C01P2004/60—Particles characterised by their size
    • C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
    • C01P2006/00—Physical properties of inorganic compounds
    • C01P2006/12—Surface area
    • C01P2006/13—Surface area thermal stability thereof at high temperatures
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02T—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION
    • Y02T10/00—Road transport of goods or passengers
    • Y02T10/10—Internal combustion engine [ICE] based vehicles
    • Y02T10/12—Improving ICE efficiencies

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Materials Engineering (AREA)
  • Environmental & Geological Engineering (AREA)
  • Inorganic Chemistry (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Geology (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Physics & Mathematics (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Chemical & Material Sciences (AREA)
  • Nanotechnology (AREA)
  • Analytical Chemistry (AREA)
  • Biomedical Technology (AREA)
  • Condensed Matter Physics & Semiconductors (AREA)
  • Combustion & Propulsion (AREA)
  • Composite Materials (AREA)
  • Thermal Sciences (AREA)
  • General Physics & Mathematics (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Catalysts (AREA)
  • Exhaust Gas Treatment By Means Of Catalyst (AREA)
FR0801156A 2008-03-03 2008-03-03 Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur Expired - Fee Related FR2928094B1 (fr)

Priority Applications (10)

Application Number Priority Date Filing Date Title
FR0801156A FR2928094B1 (fr) 2008-03-03 2008-03-03 Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur
US12/920,394 US8563462B2 (en) 2008-03-03 2009-02-23 Catalyst compositions based on nanoparticles of a zirconium oxide, a titanium oxide or a mixed zirconium/titanium oxide deposited onto a silica support therefor
PCT/EP2009/052126 WO2009112355A1 (fr) 2008-03-03 2009-02-23 Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur
EP09719637A EP2262735A1 (fr) 2008-03-03 2009-02-23 Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur
RU2012103968/05A RU2531306C2 (ru) 2008-03-03 2009-02-23 Композиция на основе оксида циркония, оксида титана или смешанного оксида циркония и титана, нанесенная на носитель из оксида кремния, способы ее получения и ее применение в качестве катализатора
JP2010549088A JP5628049B2 (ja) 2008-03-03 2009-02-23 シリカ担体上の酸化ジルコニウム、酸化チタン、または混合ジルコニウムチタン酸化物をベースとする組成物、調製方法、および触媒としての使用
CN200980107506.XA CN101959800B (zh) 2008-03-03 2009-02-23 基于二氧化硅载体上的氧化锆、氧化钛或锆和钛的混合氧化物的组合物、制备方法以及作为催化剂的用途
RU2010140393/05A RU2448908C1 (ru) 2008-03-03 2009-02-23 Композиция на основе оксида циркония, оксида титана или смешанного оксида циркония и титана, нанесенная на носитель из оксида кремния, способы ее получения и ее применение в качестве катализатора
KR1020107019581A KR101215678B1 (ko) 2008-03-03 2009-02-23 실리카 지지체 상의 산화 지르코늄, 산화 티타늄 또는 혼합된 산화 지르코늄 티타늄 기재 조성물, 제조 방법 및 촉매로서의 용도
CA2716556A CA2716556A1 (fr) 2008-03-03 2009-02-23 Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
FR0801156A FR2928094B1 (fr) 2008-03-03 2008-03-03 Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur

Publications (2)

Publication Number Publication Date
FR2928094A1 FR2928094A1 (fr) 2009-09-04
FR2928094B1 true FR2928094B1 (fr) 2014-07-11

Family

ID=39689002

Family Applications (1)

Application Number Title Priority Date Filing Date
FR0801156A Expired - Fee Related FR2928094B1 (fr) 2008-03-03 2008-03-03 Composition a base d'un oxyde de zirconium, d'un oxyde de titane ou d'un oxyde mixte de zirconium et de titane sur un support en silice, procedes de preparation et utilisation comme catalyseur

Country Status (9)

Country Link
US (1) US8563462B2 (fr)
EP (1) EP2262735A1 (fr)
JP (1) JP5628049B2 (fr)
KR (1) KR101215678B1 (fr)
CN (1) CN101959800B (fr)
CA (1) CA2716556A1 (fr)
FR (1) FR2928094B1 (fr)
RU (2) RU2531306C2 (fr)
WO (1) WO2009112355A1 (fr)

Families Citing this family (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
KR20170047378A (ko) * 2014-09-05 2017-05-04 바스프 코포레이션 연소 엔진 배기물 스트림의 처리를 위한 촉매의 백금족 금속 지지체로서의 티타니아-도핑된 지르코니아

Family Cites Families (13)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH0732875B2 (ja) * 1988-06-29 1995-04-12 川崎製鉄株式会社 ｏ−キシレンの気相接触酸化用流動触媒の製造方法
US6162530A (en) * 1996-11-18 2000-12-19 University Of Connecticut Nanostructured oxides and hydroxides and methods of synthesis therefor
RU2129989C1 (ru) * 1997-12-09 1999-05-10 Институт катализа им.Г.К.Борескова СО РАН Материал на основе диоксида циркония и способ его приготовления
JP2002047032A (ja) * 2000-08-01 2002-02-12 Nippon Sheet Glass Co Ltd 光触媒膜付き基板及びその製造方法
JP2004305947A (ja) * 2003-04-08 2004-11-04 Shinto V-Cerax Ltd アナターゼ形酸化チタン光触媒担持シリカゲル及びその製法
CN1264606C (zh) * 2003-12-12 2006-07-19 天津化工研究设计院 一种铈基稀土复合氧化物材料的制法及用途
CN100417589C (zh) * 2003-12-25 2008-09-10 千代田化工建设株式会社 层合多孔氧化钛及其制造方法和采用它的催化剂
US7125536B2 (en) * 2004-02-06 2006-10-24 Millennium Inorganic Chemicals, Inc. Nano-structured particles with high thermal stability
FR2887469B1 (fr) * 2005-06-27 2008-01-04 Rhodia Chimie Sa Procede de traitement de gaz pour l'oxydation catalytique du monoxyde de carbone et des hydrocarbures utilisant une composition a base d'un metal et d'une zircone comprenant de la silice
CN101069856A (zh) * 2006-05-12 2007-11-14 崔建光 柴油引擎尾气污染物氧化催化剂
FR2905371B1 (fr) * 2006-08-31 2010-11-05 Rhodia Recherches & Tech Composition a reductibilite elevee a base d'un oxyde de cerium nanometrique sur un support, procede de preparation et utilisation comme catalyseur
US20080206562A1 (en) * 2007-01-12 2008-08-28 The Regents Of The University Of California Methods of generating supported nanocatalysts and compositions thereof
JP4092714B1 (ja) * 2007-03-26 2008-05-28 Ｔｏｔｏ株式会社 光触媒塗装体およびそのための光触媒コーティング液

Also Published As

Publication number Publication date
CN101959800A (zh) 2011-01-26
US8563462B2 (en) 2013-10-22
KR20100120190A (ko) 2010-11-12
KR101215678B1 (ko) 2012-12-27
JP5628049B2 (ja) 2014-11-19
RU2448908C1 (ru) 2012-04-27
RU2012103968A (ru) 2013-08-20
CA2716556A1 (fr) 2009-09-17
WO2009112355A1 (fr) 2009-09-17
CN101959800B (zh) 2015-03-11
EP2262735A1 (fr) 2010-12-22
RU2531306C2 (ru) 2014-10-20
FR2928094A1 (fr) 2009-09-04
JP2011513054A (ja) 2011-04-28
US20110045967A1 (en) 2011-02-24

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