EP0955568A2 - Toner für die Entwicklung elektrostatischer Bilder - Google Patents
Toner für die Entwicklung elektrostatischer Bilder Download PDFInfo
- Publication number
- EP0955568A2 EP0955568A2 EP99202424A EP99202424A EP0955568A2 EP 0955568 A2 EP0955568 A2 EP 0955568A2 EP 99202424 A EP99202424 A EP 99202424A EP 99202424 A EP99202424 A EP 99202424A EP 0955568 A2 EP0955568 A2 EP 0955568A2
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- EP
- European Patent Office
- Prior art keywords
- long
- chain alkyl
- toner
- acid
- toner according
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08775—Natural macromolecular compounds or derivatives thereof
- G03G9/08782—Waxes
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/087—Binders for toner particles
- G03G9/08742—Binders for toner particles comprising macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- G03G9/08755—Polyesters
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- G—PHYSICS
- G03—PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
- G03G—ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY
- G03G9/00—Developers
- G03G9/08—Developers with toner particles
- G03G9/097—Plasticisers; Charge controlling agents
- G03G9/09733—Organic compounds
Definitions
- the present invention relates to a toner for developing electrostatic images used in image forming methods, such as electrophotography, electrostatic recording or electrostatic printing.
- a sheet carrying a toner image to be fixed (hereinafter called “fixation sheet”) is passed through hot rollers, while a surface of a hot roller having a releasability with the toner is caused to contact the toner image surface of the fixation sheet under pressure, to fix the toner image.
- fixation sheet a sheet carrying a toner image to be fixed
- a surface of a hot roller having a releasability with the toner is caused to contact the toner image surface of the fixation sheet under pressure, to fix the toner image.
- the fixing step a hot roller surface and a toner image contact each other in a melted state and under a pressure, so that a part of the toner is transferred and attached to the fixing roller surface and then re-transferred to a subsequent fixation sheet to soil the fixation sheet.
- This is called an offset phenomenon and is remarkably affected by the fixing speed and temperature.
- the fixing roller surface temperature is set to be low in case of a slow fixing speed and set to be high in case of a fast fixing speed. This is because a constant heat quantity is supplied to the toner image for fixation thereof regardless of a difference in fixing speed.
- the toner on a fixation sheet is deposited in several layers, so that there is liable to occur a large temperature difference between a toner layer contacting the heating roller and a lowermost toner layer particularly in a hot-fixation system using a high heating roller temperature.
- a topmost toner layer is liable to cause an offset phenomenon in case of a high heating roller temperature, while a low-temperature offset is liable to occur because of insufficient melting of the lowermost toner layer in case of a low heating roller temperature.
- the heating roller temperature can be somewhat lowered and it is possible to obviate a high-temperature offset phenomenon of an uppermost toner layer.
- a very high shearing force is applied to the toner layer, there are liable to be caused several difficulties, such as a winding offset that the fixation sheet winds about the fixing roller, the appearance of a trace in the fixed image of a separating member for separating the fixation sheet from the fixing roller, and inferior copied images, such as resolution failure of line images and toner scattering, due to a high pressure.
- a toner having a lower melt viscosity is generally used than in the case of low speed fixation, so as to lower the heating roller temperature and fixing pressure, thereby effecting the fixation while obviating the high-temperature offset and winding offset.
- an offset phenomenon is liable to be caused because of the low viscosity.
- JP-A Japanese Laid-Open Patent Applications
- JP-A 63-225244, 63-225245 and 63-225246
- JP-A Japanese Laid-Open Patent Applications
- 63-225244, 63-225245 and 63-225246 have disclosed a toner containing two types of non-linear polyester in order to provide improved low-temperature fixability, high-temperature anti-offset characteristic and anti-blocking characteristic.
- JP-A Japanese Laid-Open Patent Applications
- a characteristic curve (e.g., a solid curve representing a case of providing a maximum intensity of 1.4) becomes downwardly convex at a low developing potential and upwardly convex at a high developing potential. Accordingly, in a halftone region, a slight change in developing potential leads to a remarkable change in image density. This provides a complexity in obtaining a satisfactory density gradation characteristic.
- copied images appear clearer because of an edge effect so that clear line images can be retained in case where a maximum density of ca. 1.30 is attained at a solid image part which is less affected by the edge effect.
- the density gradation characteristic is liable to be remarkably affected by the saturation charge and the charging speed of a developer used.
- the saturation charge is appropriate for the developing conditions
- a developer showing a slow charging speed provides a low maximum image density, thus generally thin and blurred images in the initial stage of copying.
- the maximum image density is ca. 1.3, as described above, thus being able to obviate an adverse effect of the slow chargeability.
- the initial copy image density is increased if the saturation charge is increased.
- the charge of the developer is gradually increased to finally exceed an appropriate charge for development, thereby resulting in a lower copy image density.
- no problem occurs in line images if the maximum image density is ca. 1.3.
- a smaller particle size toner is liable to impair the fixability of a halftone image. This is particularly noticeable in high-speed fixation. This is because the toner coverage in a halftone part is little and a portion of toner transferred to a concavity of a fixation sheet receives only a small quantity of heat and the pressure applied thereto is also suppressed because of the convexity of the fixation sheet. A portion of toner transferred onto the convexity of the fixation sheet in a halftone part receives a much larger shearing force per toner particle because of a small toner layer thickness compared with that in a solid image part, thus being liable to cause offset or result in copy images of a lower image quality.
- Fog is another problem. If the toner particle size is reduced, the surface area of a unit weight of toner is increased, so that the charge distribution thereof is liable to be broadened to cause fog. As the toner surface area is increased per unit weight thereof, the toner chargeability is liable to be affected by a change in environmental conditions.
- the dispersion state of a charge control agent and a colorant is liable to affect the toner chargeability.
- JP-A 62-78569 has proposed a toner containing a polyester having a saturated or unsaturated hydrocarbon group with 3 - 22 carbon atoms in its side chain.
- JP-A 63-225244 has proposed a toner containing two types of polyester as a binder resin.
- JP-A 2-129653 and JP-A 3-46668 have proposed the use of a polyester resin treaetd with an acid or an alcohol as a binder resin.
- Such toners are actually effective in providing an increased fixability and a stable triboelectric chargeability but are liable to result in dispersion failure of polyolefin wax because the mono-alcohol used has an alkyl group containing a number of carbon atoms of as small as 10. This can lead to occurrence of cleaning failure and inferior anti-offset characteristic when used in a higher-speed apparatus, and the fixability in a low-temperature environment and the developing performance in a low-humidity environment cannot be said to be fully satisfactory.
- JP-A 59-129863 and JP-A 3-50561 have proposed the use of a polyester resin and an acid-modified polyolefin.
- maleic anhydride is added to polyolefin which has been synthesized in advance.
- the polarity obtained thereby is very weak, so that it is difficult to break an association of polymer OH groups.
- the charging speed is fast to provide a high charge because of association of polymer carboxylic groups.
- the toner quantity used for development is large to provide high image density copies.
- the saturation charge is gradually reduced so that the copy image density is gradually lowered correspondingly.
- maleic anhydride used in the above proposals reacts with water to open its ring but, even in such a case, the associatability of the resultant carboxylic group is lowered because of an adjacent carboxylic group.
- maleic acid is not always attached to molecular chain terminals. Accordingly, when maleic acid is attached to a middle of a molecular chain, this is identical to branching of the molecule chain.
- JP-A 56-87051 has disclosed a method of producing a binder resin by polymerization in the presence of a higher fatty acid or a higher alcohol.
- the fatty acids and alcohols specifically disclosed therein have only a small number of carbon atoms, so that the resultant toner is caused to have low storage stability and low environmental stability.
- JP-A 2-173038 and JP-A 3-46668 disclose reaction of a polyester resin with a monocarboxylic acid but the monocarboxylic acid used therein has a methylene group containing only less than 20 carbon atoms, and the resultant toner has left a room for improvement against problems, such as cleaning failure.
- a generic object of the present invention is to provide a toner for developing electrostatic images having solved the above-mentioned problems.
- a more specific object of the present invention is to provide a toner for developing electrostatic images showing excellent anti-offset characteristic and cleaning performance without impairing the fixability for a low-speed to a high-speed copying or printing apparatus.
- Another object of the present invention is to provide a toner for developing electrostatic images, even in a small particle size, capable of showing a good fixability at a halftone part and providing copy images of good image quality for a low-speed to a high-speed copying or printing apparatus.
- Another object of the present invention is to provide a tone for developing electrostatic images capable of providing high-density copy images free from fog for a low-speed to a high-speed copying or printing apparatus.
- Another object of the present invention is to provide a toner for developing electrostatic images capable of providing good images in a low-humidity environment and also in a high-humidity environment without being affected by a change in environmental conditions.
- Another object of the present invention is to provide a toner for developing electrostatic images capable of stably providing good images in a high-speed apparatus and thus applicable to wide variety of models of image forming apparatus.
- Another object of the present invention is to provide a toner for developing electrostatic images having excellent durability and capable of providing copy or print images having a high image density and free from fog on white background even in a long period of continuous image formation on a large number of sheets.
- Another object of the present invention is to provide copies of a photographic image with characters including clear character images and photographic images having a density gradation characteristic faithful to the original.
- a toner for developing an electrostatic image comprising a resin composition and a colorant, wherein said resin composition comprising a high-softening point polyester resin (I) having a softening point of 120 - 180 °C, a low-softening point polyester resin (II) having a softening point of 80 °C - 120 °C (exclusive), and a long-chain alkyl compound selected from the group consisting of a long-chain alkyl alcohol principally comprising long-chain alkyl alcohol components having long-chain alkyl groups of 23 to 252 carbon atoms and a long-chain alkyl carboxylic acid principally comprising long-chain alkyl carboxylic acid compounds having long-chain alkyl groups of 22 to 251 carbon atoms.
- a long-chain alkyl compound selected from the group consisting of a long-chain alkyl alcohol principally comprising long-chain alkyl alcohol components having long-chain alkyl groups of 23 to 252 carbon atoms and a long
- a toner for developing an electrostatic image comprising a resin composition and a colorant; said resin composition comprising a polyester resin, and a long-chain alkyl compound selected from the group consisting of a long-chain alkyl alcohol principally comprising long-chain alkyl alcohol components having long-chain alkyl groups of 23 to 252 carbon atoms and a long-chain alkyl carboxylic acid principally comprising long-chain alkyl carboxylic acid components having long-chain alkyl groups of 22 to 251 carbon atoms, and a colorant; wherein said resin composition includes a tetrahydrofuran (THF)-soluble content providing a gel permeation chromatogram showing a weight-average molecular weight (Mw) of at least 10 5 , a ratio of Mw to number-average molecular weight (Mn) of at least 35 and an areal percentage of at least 5 % of a region of molecular weight of at least 2x10 5
- THF tetrahydrofuran
- the toner for developing an electrostatic image according to the present invention contains a low-softening point polyester resin, a high-softening point polyester resin and a long-chain alkyl compound having a terminal hydroxyl or carboxyl group.
- a carboxyl group is a functional group having a very strong polarity so that carboxyl groups can associate with each other to provide a state where polymer chains extend outwardly from the side of association.
- the state of association may be represented as follows: and the structure is considered to be stable and exhibit a strong orientation.
- a long-chain alkyl carboxylic acid forms an association by itself. Accordingly, a long-chain alkyl carboxylic acid forms an association of carboxyl groups to contribute to an increase in toner charging speed.
- An OH group is susceptible of an external attack as described above, so that a -COOH group in a long-chain alkyl carboxylic acid has a function of collapsing an association of OH groups in a polyester polymer.
- a -COOH group of a long-chain alkyl carboxylic acid in a polymer matrix affects an environment surrounding a COOH association to rather increase the toner charging speed.
- a long-chain alkyl alcohol also affects a COOH association in a polymer matrix to increase the toner charging velocity similarly as the long-chain alkyl carboxylic acid.
- a long-chain alkyl alcohol also affects OH groups in a polymer matrix, thereby functioning to reduce the localization of charge density as a whole. Accordingly, the resin is less susceptible of an external attack, particularly with water, thereby increasing the saturation charge of the toner.
- a carboxylic acid having a branched structure instead of a long-chain alkyl group causes a steric hindrance because of the branching, thereby lowering the associatability.
- the associatability of carboxylic groups is also lowered in case where plural carboxylic groups are present in one molecular chain.
- the resultant toner is provided with a lower charging speed and an inferior environmental stability.
- the alcohol In case of an alcohol having a branched structure instead of a long-chain alkyl group, the alcohol causes a steric hindrance because of the branching, so that it does not act on an OH group of the polymer, so that the resin is liable to be affected by moisture, thereby lowering the saturation charge.
- the resin is also liable to be affected with moisture.
- polyester resin used in the present invention may be prepared by appropriately selecting the following components.
- the high-softening point polyester resin (I) used in the present invention may preferably comprise a non-linear polyester resin having a crosslinked or branched structure.
- the low-softening point polyester resin (II) may comprise either a linear polyester resin or a non-linear polyester resin but may preferably comprise a non-linear polyester resin.
- Such a non-linear polyester resin may be synthesized by using a polycarboxylic acid having three or more carboxyl groups or a polyol having three or more alcohol groups together with a dicarboxylic acid and a diol.
- the polyester resin used in the present invention may preferably comprise 45 - 55 mol. % of alcohol component and 55 - 45 mol. % of acid component.
- diol component may include: diols, such as ethylene glycol, propylene glycol, 1,3-butanediol, 1,4-butanediol, 2,3-butanediol, diethylene glycol, triethylene glycol, 1,5-pentanediol, 1,6-hexanediol, neopentyl glycol, 2-ethyl-1,3-hexanediol, hydrogenated bisphenol A, bisphenols derivatives represented by the following formula (A): wherein R denotes an ethylene or propylene group, x and y are independently 0 or a positive integer with the proviso that the average of x+y is in the range of 0 - 10; and diols represented by the following formula (B): wherein R' denotes -CH 2 CH 2 -,
- Examples of the dibasic carboxylic acid constituting at least 50 mol. % of the total acid may include benzenedicarboxylic acids, such as phthalic acid, terephthalic acid, isophthalic acid, diphenyl-p,p'-dicarboxylic acid, naphthalene-2,7-dicarboxylic acid, naphthalene-2,6-dicarboxylic acid, diphenylmethane-p,p'-dicarboxylic acid, benzophenone-4,4'-dicarboxylic acid and 1,2-diphenoxyethane-p,p'-dicarboxylic acid, and their anhydrides; alkyldicarboxylic acids, such as succinic acid, adipic acid, sebacic acid, azelaic acid, glutaric acid and cyclohexanedicarboxylic acid, and their anhydrides; C 6 - C 18 alkyl or alkenyl-substituted succinic acids
- An especially preferred class of alcohol components constituting the polyester resin is a bisphenol derivative represented by the above formula (A), and preferred examples of acid components may include dicarboxylic acids inclusive of phthalic acid, terephthalic acid, isophthalic acid and their anhydrides; succinic acid, n-dodecenylsuccinic acid, and their anhydrides, fumaric acid, maleic acid, and maleic anhydride.
- polycarboxylic acid having three or more carboxylic groups may include: trimellitic acid, pyromellitic acid, cyclohexanetricarboxylic acids, 2,5,7-naphthalenetricarboxylic acid, 1,2,5-naphthalenetricarboxylic acid, 1,2,4-butanetricarboxylic acid, 1,2,5-hexanetricarboxylic acid, 1,3-dicarboxyl-2-methylenecarboxylpropane, 1,3-dicarboxyl-2-methyl-methylenecarboxylpropane, tetra(methylenecarboxyl)methane, ,2,7,8-octanetetracarboxylic acid, and their anhydrides.
- polyols having three or more hydroxyl groups may include: sorbitol, 1,2,3,6-hexanetetraol, 1,4-sorbitan, pentaerythritol, dipentaerythritol, tripentaerythritol, sucrose, 1,2,4-butanetriol, glycerin, 2-methylpropanetriol, trimethylolethane, trimethylolpropane, and 1,3,5-trihydroxymethylbenzene.
- the polyester resin (I) obtained from the above components may have a softening point of 120 - 180 °C, preferably 125 - 175 °C, and may preferably be non-linear by crosslinking.
- the polyester resin (II) obtained also from the above components may have a softening point of 80 °C - 120 °C (not inclusive) , preferably 85 - 115 °C.
- a polyester resin (I) having a softening point below 120 °C provides a worse anti-offset characteristic at high temperatures, and a softening point exceeding 180 °C causes a poor fixability and poor mixing with the polyester resin (II), leading to poor electrophotographic performances and poor pulberizability during toner production.
- a polyester resin (II) having a softening point below 80 °C results in a lower anti-blocking characteristic, and a softening point of 120 °C or higher leads to a worse fixability.
- the polyester resins (I) and (II) may preferably be both non-linear and have a difference in softening point of at least 10 °C, more preferably at least 120 °C, therebetween.
- the polyester resin composition including the above-mentioned two types of polyester resins may preferably have a glass transition temperature (Tg) of 40 - 90 °C, more preferably 45 - 85 °C.
- the polyester resin composition may preferably have a number-average molecular weight (Mn) of 1,000 - 50,000, more preferably 1,500 - 20,000, particularly 2,500 - 10,000, and a weight-average molecular weight (Mw) of 3x10 3 - 3x10 6 , more preferably 1x10 4 - 2.5x10 6 , further preferably 4.0x10 4 - 2.0x10 6 .
- Mn number-average molecular weight
- Mw weight-average molecular weight
- the polyester resin composition may preferably have an acid value of 2.5 - 80 mgKOH/g, more preferably 5 - 60 mgKOH/g, further preferably 10 - 50 mgKOH/g, and an OH value of at most 80 mgKOH/g, more preferably at most 70 mgKOH/g, further preferably at most 60 mgKOH/g.
- the polyester resin composition has an acid value of below 2.5 mgKOH/g, few carboxylic group association assemblies of the binder resin are formed, thus being liable to result in a slow charging speed. If the polyester resin has an acid value exceeding 80 mgKOH/g, there remain many carboxyl groups not forming association assemblies in the polyester resin, thus being susceptible of attack with moisture and resulting in an inferior environmental stability. If the polyester resin has an OH value exceeding 80 mgKOH/g, many associates of OH groups are formed so that the polyester resin is susceptible of attack with moisture to result in a lower environmental stability.
- the polyester resins (I) and (II) may be amply mixed with each other ordinarily by (i) adding the high-softening point polyester resin (I) into the low-softening point polyester resin in a molten state at an elevated temperature under stirring or (ii) blending them by a mixer such as a Henschel mixer or a ball mill.
- polyester resin composition including the polyester resins (I) and (II).
- the long-chain alkyl alcohol used in the present invention may be represented by the following formula (1): CH 3 (CH 2 ) x CH 2 OH (1), wherein x denotes an average value in the range of 21 - 250, preferably 21 - 100.
- the long-chain alkyl alcohol may for example be produced as follows. Ethylene is polymerized in the presence of a Ziegler catalyst and, after the polymerization, oxidized to provide an alkoxide of the catalyst metal and polyethylene, which is then hydrolyzed to provide an objective long-chain alkyl alcohol.
- the thus prepared long-chain alkyl alcohol has little branching and a sharp molecular weight distribution and is suitably used in the present invention.
- the long-chain alkyl carboxylic acid used in the present invention may be represented by the following formula (2): CH 3 (CH 2 ) y COOH (2), wherein y denotes an average value in the range of 21 - 250, preferably 21 - 100.
- the long-chain alkyl carboxylic acid may be produced by oxidizing the long-chain alkyl alcohol of the above formula (1).
- the content (wt. %) of each long-chain alkyl alcohol component can be measured by the GC-MS analysis.
- a GC-MS analyzer ("VG TR10-1", available from VG Organic Co.) and a column of "DB-1" or "DB-5" (available from J & W Co.).
- VG TR10-1 available from VG Organic Co.
- DB-1 column of "DB-5"
- J & W Co. it is preferred to silicate the long-chain alkyl alcohol components in advance of the GC-MS analysis.
- the content (wt. %) of each long-chain alkyl carboxylic acid can also be measured similarly.
- the parameters x and y in the formulae (1) and (2) are respectively an average value.
- the parameters x and y as an average value may be 21 - 250, preferably 21 - 200. If x or y is below 21, the resultant toner is liable to cause a melt sticking onto the photosensitive member surface and show a lower storage stability. In case where the parameter x or y exceeds 250, the above-mentioned effect contributing to the toner chargeability is little.
- the long-chain alkyl alcohol components having long-chain alkyl groups of 23 to 252 carbon atoms may preferably occupy at least 60 wt. %, more preferably at least 70 wt. %, of the total long-chain alkyl alcohol.
- the long-chain alkyl carboxylic acid components having long-chain alkyl groups of 22 to 251 carbon atoms may preferably occupy at least 60 wt. %, more preferably at least 70 wt. %, of the total long-chain alkyl carboxylic acid.
- the long-chain alkyl alcohol contains at least 50 wt. % of a long-chain alkyl alcohol component having at least 37 carbon atoms based on the total alkyl alcohol components.
- the long-chain alkyl carboxylic acid contains at least 50 wt. % of a long-chain alkyl carboxylic acid component having at least 38 carbon atoms based on the total alkyl carboxylic acid components. Unless these conditions are satisfied, the resultant toner is liable to cause a melt-sticking onto the photosensitive member surface and exhibit a lower storage stability.
- the long-chain alkyl alcohol or long-chain alkyl carboxylic acid used in the present invention may preferably have a melting point of at least 91 °C. If the melting point is below 91 °C, the long-chain alkyl alcohol or long-chain alkyl carboxylic acid is liable to be separated by melting during the melt-kneading step for toner production, and show an inferior dispersibility in toner particles. The resultant toner is liable to cause a melt-sticking onto the photosensitive member surface and show a lower storage stability. Further, because of a difference in flowability among toner particles, the toner is liable to have ununiform chargeability, cause fog and provide rough images.
- the long-chain alkyl alcohol or long-chain alkyl carboxylic acid may preferably have a weight-average molecular weight (Mw) of 500 - 10,000, more preferably 600 - 8,000, and a Mw/Mn ratio of at most 3, more preferably at most 2.5, so as to suppress the toner melt-sticking onto the photosensitive member and provide an improved storage stability of the toner.
- Mw weight-average molecular weight
- the long-chain alkyl alcohol used in the present invention may preferably have an OH value of 10 - 120 mgKOH/g, further preferably 20 - 100 mgKOH/g. If the long-chain alkyl alcohol has an OH value below 10 mgKOH/g, the effect thereof on the carboxyl group and OH group of the binder resin (polyester resin), and the dispersibility thereof in the binder resin is lowered to result in ununiform toner chargeability leading to a density decrease, fog, and inferior image quality in copy images.
- the long-chain alkyl alcohol is caused to contain a large amount of low-molecular weight molecules so that the resultant toner is liable to cause a melt-sticking onto the photosensitive member and lower the storage stability.
- the long-chain alkyl carboxylic acid used in the present invention may preferably have an acid value of 5 - 120 mgKOH/g, further preferably 10 - 100 mgKOH/g. If the long-chain alkyl carboxylic acid has an acid value below 5 mgKOH/g, the effect thereof onto the OH groups in the binder resin becomes small and the dispersion thereof in the binder resin is also worse, thereby resulting in inferior image qualities of copy images, similarly as in the case of the long-chain alkyl alcohol. Further, as the carboxyl groups do not sufficiently associate each other, the environmental characteristic is liable to be impaired. Further, the resultant toner is liable to show a low charging velocity, to result in a lower density at the initial stage of copying.
- the acid value of the long-chain alkyl carboxylic acid exceeds 120 mgKOH/g, it contains a large amount of low-molecular weight molecules, the resultant toner is liable to cause melt-sticking onto the photosensitive member and lower the storage stability, similarly as in the case of the long-chain alkyl alcohol.
- the long-chain alkyl alcohol and/or the long-chain alkyl carboxylic acid may preferably be contained in an amount of 0.1 - 30 wt. parts, particularly 0.5 - 20 wt. parts, per 100 wt. parts of the binder resin. Below 0.1 wt. part, the above-mentioned effect cannot be exhibited sufficiently. Above 30 wt. parts, the anti-blocking characteristic of the resultant toner is lowered and the pulverizability in toner production becomes inferior.
- the polyester resin composition further contains a polyeser resin (III), at least a portion of which has been modified with a long-chain alkyl compound having a long-chain alkyl group of 23 - 102 carbon atoms and a terminal hydroxyl or carboxyl group.
- a polyeser resin (III) at least a portion of which has been modified with a long-chain alkyl compound having a long-chain alkyl group of 23 - 102 carbon atoms and a terminal hydroxyl or carboxyl group.
- the binder resin composition contains such a polyester resin (III) having introduced a long-chain alkyl group of 23 - 102 carbon atoms
- the resultant toner is provided with further improved low-temperature fixability and releasability, is less liable to cause a dispersion failure of a long-chain alkyl compound, such as polyolefin wax, in the resin composition even when such a long-chain alkyl compound is contained, and is less liable to cause cleaning failure.
- fine powder fraction produced during toner production can be re-used for toner production without causing a lower performance in developability or fixability in the resultant toner.
- the modified polyester resin (III) shows good compatibility with the polyester resins (I) and (II)
- the modified polyester resin (III) promotes the uniform dispersion of a charge control agent and a colorant, such as a magnetic material
- the molecular chain severance during the melt-kneading during toner production including re-cycled fine powder fraction and the other materials occurs seldom in the state where the modified polyester resin (III) is uniformly dispersed.
- the modified polyester resin (III) used in the present invention may be produced by using a long-chain alkyl alcohol of the following formula (1') as a modifier compound: CH 3 (CH 2 ) x CH 2 OH (1'), wherein x denotes an average value in the range of 21 - 100.
- the long-chain alkyl alcohol of the formula (1') may have a low melting point of 70 - 140 °C, and provides an effect of providing a lower fixing temperature by connection thereof to an intermediate yet-unreacted carboxyl group to provide a branched structure or connection to a terminal of the polyester main chain.
- the modification further provides an improved mutual solubility between the polyester resin composition and a long-chain alkyl compound, such as polyolefin wax, to prevent a dispersion failure of the long-chain alkyl compound in the polyester resin composition.
- a long-chain alkyl compound such as polyolefin wax
- the addition of the long-chain alkyl group may further provide an improved releasability from the fixing roller and an improved anti-offset characteristic.
- the polyester resin (III) modified with the long-chain alkyl alcohol of the formula (1') may prevent successive chargeability and provide a stable chargeability.
- the average value x in the formula (1') for the modifier long-chain alkyl alcohol may be in the range of 21 - 100. If x is below 21, the effect of lowering the toner fixation temperature is scarce and the addition in a large amount for the purpose of lowering the fixation temperature is liable to provide a poor storage stability. Further, little slippage-imparting effect against the photosensitive member is attained to result in a difficulty, such as cleaning failure. If x is larger than 100, the modified polyester resin (III) is caused to have a large melting point, thus providing little effect of lowering the fixation temperature.
- Such long-chain alkyl alcohols may be produced the processes disclosed, e.g., in U.S. Patents Nos. 2,892,858; 2,781,419; 2,787,626 and 2,835,689; and U.K. Patent No. 808,055.
- such a long-chain alkyl alcohol may for example be produced as follows. Ethylene is polymerized in the presence of a Ziegler catalyst and, after the polymerization, oxidized to provide an alkoxide of the catalyst metal and polyethylene, which is then hydrolyzed to provide an objective long-chain alkyl alcohol.
- the thus prepared long-chain alkyl alcohol has little branching and a sharp molecular weight distribution and is suitably used in the present invention.
- the modifier long-chain alkyl alcohol may have a number-average molecular weight (Mn) of 150 - 4,000, preferably 250 - 2,500, and a weight-average molecular weight (Mw) of 250 - 10,000, preferably 400 - 8,000.
- the modifier long-chain alkyl alcohol may have an OH value of 5 - 150 mgKOH/g, preferably 10 - 120 mgKOH/g. If the OH value of the long chain alkyl alcohol is below 5 mgKOH/g, the dispersibility in the binder resin is lowered to provide also low dispersibility of the charge control agent and colorant. As a result, the toner chargeability is liable to be ununiform, leading to difficulties, such as a lowering in density of copy or print images and fog causing inferior image quality. If the OH value is above 150 mgKOH/g, long-chain alkyl alcohol components of low molecular weight are contained in a substantial quantity to result in a lower storage stability.
- the modified polyester resin (III) may also be produced by using a long-chain alkyl carboxylic acid of the following formula (2') as a modifier compound: CH 3 (CH 2 ) y COOH (2'), wherein y denotes an average value in the range of 21 - 100.
- the long-chain alkyl carboxylic acid of the formula (2') may be produced by oxidizing the long-chain alkyl alcohol of the formula (1').
- the long-chain alkyl carboxylic acid of the formula (2') may have a low melting point of 70 - 140 °C, and provides an effect of providing a lower fixing temperature by connection thereof to an intermediate yet-unreacted hydroxyl group to provide a branched structure or connection to a terminal hydroxyl group of the polyester main chain.
- the long-chain alkyl carboxylic acid modifier of the formula (2') provides an excellent releasability, thus providing a good high-temperature anti-offset characteristic. Further, by reaction of the long-chain alkyl carboxylic acid of the formula (2') with yet-unreacted hydroxyl groups at the terminal or within the polymer chain, the total number of hydroxyl groups in the polyester resin can be reduced, thus providing a good environmental stability.
- the average value y in the formula (2') for the modifier long-chain alkyl carboxylic acid may be in the range of 21 - 100. If y is below 21, the effect of lowering the toner fixation temperature is scarce and the addition in a large amount for the purpose of lowering the fixation temperature is liable to provide a poor storage stability. Further, little slippage-imparting effect against the photosensitive member is attained to result in a difficulty, such as cleaning failure. If y is larger than 100, the modified polyester resin (III) is caused to have a large melting point, thus providing little effect of lowering the fixation temperature.
- the modifier long-chain alkyl carboxylic acid may have a number-average molecular weight (Mn) of 150 - 4,000, preferably 250 - 2,500, and a weight-average molecular weight (Mw) of 250 - 10,000, preferably 400 - 8,000.
- the modifier long-chain alkyl carboxylic acid may have an acid value of 5 - 150 mgKOH/g, preferably 10 - 120 mgKOH/g. If the acid value of the long chain alkyl carboxylic acid is below 5 mgKOH/g, the dispersibility in the binder resin is lowered to provide images of inferior qualities similarly as in the case of the long-chain alkyl alcohol. If the acid value is above 150 mgKOH/g, long-chain alkyl carboxylic acid components of low molecular weight are contained in a substantial quantity to result in a lower storage stability, similarly as in the case of the long-chain alkyl alcohol.
- the modified polyester resin (III) may be produced by modifying a polyester resin with such a modifier compound having a long-chain alkyl of 23 to 102 carbon atoms, and a terminal hydroxyl or carboxyl group, i.e., the long-chain alkyl alcohol of the formula (1') or the long-chain alkyl carboxylic acid of the formula (2'), e.g., in the following manners.
- the method (i) of effecting the modification simultaneously with the synthesis of a polyester resin to be modified is preferred. This is because the modification simultaneous with the polyester resin synthesis allows a faster reaction, an easier molecular weight control and a higher modification rate.
- the modified polyester resin (III) produced by this method is caused to have a matrix-domain structure wherein the polyester portion constitutes a matrix (or domains) and the modifier compound portion constitutes domains (or a matrix), providing very minute uniformly dispersed domains.
- the long-chain alkyl alcohol or carboxylic acid for providing the modified polyester resin (III) occupies 0.05 - 30 wt. %, more preferably 0.1 - 25 wt. %, of the total binder resin.
- the content of the modifier compound is below 0.05 wt. %, the dispersibility of the non-reacted long-chain alkyl alcohol, long-chain alkyl carboxylic acid, release agent, charge control agent and colorant is lowered, thus being liable to cause an ununiform toner chargeability leading to image quality degradation. Further, when classified fine powder is recycled during toner production, the resultant toner is liable to provide further lower image qualities.
- the content of the long-chain alkyl alcohol or long-chain alkyl carboxylic acid in the modified polyester resin (III) exceeds 30 wt. % of the total binder resin, the dispersibility of the charge control agent, etc., is good but the toner chargeability is rather lowered because the modifying alkyl portion in the polyester resin shows a weak chargeability, thus being liable to provide lower image qualities. Further, in this case, the pulverizability during toner production becomes worse, so that it becomes difficult to provide fine particles of the toner.
- the non-linear polyester resin composition in the toner may preferably have a number-average molecular weight (Mn) of 1,000 - 50,000, more preferably 1,500 - 20,000 and a weight-average molecular weight (Mw) of 3x10 3 - 2x10 6 , more preferably 4x10 4 - 1.5x10 6 .
- the non-linear polyester resin composition may preferably show a glass transition point (Tg) of 40 - 80 °C, more preferably 45 - 70 °C.
- the above formula represents a preferred condition so that a substantial amount of carboxyl group is present in the polyester resin effective for suppressing the function of OH groups in the polymer to provide an accelerated chargeability of the toner.
- the coefficient of 1/4 preceding the OH value is attributable to a weak dissociation of the OH group. In other words, this is attributable to the fact that all of the OH groups do not associate because of little localization in electron density as described above.
- the polyester resin composition constituting the binder resin of the toner according to the present invention may contain a tetrahydrofuran (THF)-soluble content providing a gel-permeation chromatogram showing a weight-average molecular weight (Mw) of at least 10 5 , preferably at least 1.5x10 5 , a ratio (Mw/Mn) of weight-average molecular weight (Mw) to number-average molecular weight (Mn) of at least 35, more preferably at least 45, and an areal percentage for a molecular weight region of at least 2x10 5 of at least 5 %, more preferably at least 7 %, so as to provide better low temperature-fixability and anti-offset characteristic.
- THF tetrahydrofuran
- the toner for developing electrostatic images it is possible to add a charge control agent, as desired, in order to further stabilize the chargeability thereof.
- the charge control agent may be used in 0.1 - 10 wt. parts, preferably 0.1 - 5 wt. parts, per 100 wt. parts of the binder resin.
- Examples of the charge control agents may include the following.
- negative charge control agents may include: organometal complexes and chelate compounds, inclusive of mono-azo metal complexes; acetylacetone metal complexes; aromatic hydroxycarboxylic acid metal complexes or metal salts and aromatic dicarboxylic acid metal complexes or metal salts.
- organometal complexes and chelate compounds inclusive of mono-azo metal complexes; acetylacetone metal complexes; aromatic hydroxycarboxylic acid metal complexes or metal salts and aromatic dicarboxylic acid metal complexes or metal salts.
- Other examples may include: aromatic mono- and poly-carboxylic acids, metal salts, anhydrides and esters of these acids, and phenol derivatives of bisphenols.
- Examples of the positive charge control agents may include: nigrosine and products of modification thereof with aliphatic acid metal salts, etc.; onium salts inclusive of quaternary ammonium salts, such as tributylbenzylammonium-1-hydroxy-4-naphthosulfonate and tetrabutylammonium tetrafluoroborate, and their homologues, such as phosphonium salts, and lake pigments thereof; triphenylmethane dyes and lake pigments thereof (the laking agents including phosphotungstic acid, phosphomolybdic acid, phosphomolybdic-tungstic acid, tannic acid, lauric acid, gallic acid, ferricyanic acid, ferrocyanic acid, ferrocyane compounds, etc.); metal salts of higher fatty acids; diorganotin oxides, such as dibutyltin oxide, dioctyltin oxide and dicyclohexyltin oxide; and diorganotin bor
- the toner for developing electrostatic image according to the present invention may be either a magnetic toner or a non-magnetic toner.
- the magnetic toner it is preferred to use a magnetic material as shown below for providing uniform chargeability, flowability, copy or print image density, etc.
- Examples of such a magnetic material also functioning as a colorant may include: iron oxide, such as magnetite, hematite, and ferrite; iron oxides containing another metal oxide; metals, such as Fe, Co and Ni, and alloys of these metals with other metals, such as Al, Co, Cu, Pb, Mg, Ni, Sn, Zn, Sb, Be, Bi, Cd, Ca, Mn, Se, Ti, W and V; and mixtures of the above.
- the magnetic material may include: triiron tetroxide (Fe 3 O 4 ), diiron trioxide ( ⁇ -Fe 2 O 3 ), zinc iron oxide (ZnFe 2 O 4 ), yttrium iron oxide (Y 3 Fe 5 O 12 ), cadmium iron oxide (CdFe 2 O 4 ), gadolinium iron oxide (Gd 3 Fe 5 O 12 ), copper iron oxide (CuFe 2 O 4 ), lead iron oxide (PbFe 12 O 19 ), nickel iron oxide (NiFe 2 O 4 ), neodymium iron oxide (NdFe 2 O 3 ), barium iron oxide (BaFe 12 O 19 ), magnesium iron oxide (MgFe 2 O 4 ), manganese iron oxide (MnFe 2 O 4 ), lanthanum iron oxide (LaFeO 3 ), powdery iron (Fe), powdery cobalt (Co), and powdery nickel (Ni).
- the above magnetic materials may be used singly or in mixture of two or more species. Particularly
- the magnetic material may have an average particle size (Dav.) of 0.1 - 2 ⁇ m, preferably 0.1 - 0.5 ⁇ m.
- the magnetic material may preferably show magnetic properties when measured by application of 10 kilo-Oersted, inclusive of: a coercive force (Hc) of 20 - 200 Oersted, more preferably 20 - 150 Oersted, a saturation magnetization ( ⁇ s) of 50 - 200 emu/g, particularly 50 - 100 emu/g, and a residual magnetization ( ⁇ r) of 2 - 25 emu/g, particularly 2 - 20 emu/g.
- Hc coercive force
- ⁇ s saturation magnetization
- ⁇ r residual magnetization
- the magnetic material may be contained in the toner in a proportion of 10 - 200 wt. parts, preferably 20 - 150 wt. parts, per 100 wt. parts of the binder resin.
- the toner according to the present invention may contain appropriate dye or pigment as a non-magnetic colorant, particularly for providing a non-magnetic toner.
- Examples of the dye may include: C.I. Direct Red 1, C.I. Direct Red 4, C.I. Acid Red 1, C.I. Basic Red 1, C.I. Mordant Red 30, C.I. Direct Blue 1, C.I. Direct Blue 2, C.I. Acid Blue 9, C.I. Acid Blue 15, C.I. Basic Blue 3, C.I. Basic Blue 5, C.I. Mordant Blue 7, C.I. Direct Green 6, C.I. Basic Green 4, and C.I. Basic Green 6.
- the pigment may include: Chrome Yellow, Cadmium Yellow, Mineral Fast Yellow, Navel Yellow, Naphthol Yellow S, Hansa Yellow G, Permanent Yellow NCG, Tartrazine Lake, Orange Chrome Yellow, Molybdenum Orange, Permanent Orange GTR, Pyrazolone Orange, Benzidine Orange G, Cadmium Red, Permanent Red 4R, Watching Red Ca salt, eosine lake; Brilliant Carmine 3B; Manganese Violet, Fast Violet B, Methyl Violet Lake, Ultramarine, Cobalt BLue, Alkali Blue Lake, Victoria Blue Lake, Phthalocyanine Blue, Fast Sky Blue, Indanthrene Blue BC, Chrome Green, chromium oxide, Pigment Green B, Malachite Green Lake, and Final Yellow Green G.
- the toner may contain appropriate pigment or dye as described below.
- magenta pigment examples include: C.I. Pigment Red 1, 2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12, 13, 14, 15, 16, 17, 18, 19, 21, 22, 23, 30, 31, 32, 37, 38, 39, 40, 41, 48, 49, 50, 51, 52, 53, 54, 55, 57, 58, 60, 63, 64, 68, 81, 83, 87, 88, 89, 90, 112, 114, 122, 123, 163, 202, 206, 207, 209; C.I. Pigment Violet 19; and C.I. Violet 1, 2, 10, 13, 15, 23, 29, 35.
- magenta pigments may be used alone but can also be used in combination with a dye so as to increase the clarity for providing a color toner for full color image formation.
- magenta dyes may include: oil-soluble dyes, such as C.I. Solvent Red 1, 3, 8, 23, 24, 25, 27, 30, 49, 81, 82, 83, 84, 100, 109, 121; C.I. Disperse Red 9; C.I. Solvent Violet 8, 13, 14, 21, 27; C.I. Disperse Violet 1; and basic dyes, such as C.I. Basic Red 1, 2, 9, 12, 13, 14, 15, 17, 18, 22, 23, 24, 27, 29, 32, 34, 35, 36, 37, 38, 39, 40; C.I. Basic Violet 1, 3, 7, 10, 14, 15, 21, 25, 26, 27, 28.
- yellow pigment may include: C.I. Pigment Yellow 1, 2, 3, 4, 5, 6, 7, 10, 11, 12, 13, 14, 15, 16, 17, 23, 65, 73, 83; C.I. Vat Yellow 1, 13, 20.
- Such a non-magnetic colorant may be added in an amount of 0.1 - 60 wt. parts, preferably 0.5 - 50 wt. parts, per 100 wt. parts of the binder resin.
- Examples of the release agent may include: aliphatic hydrocarbon waxes, such as low-molecular weight polyethylene, low-molecular weight polypropylene, microcrystalline wax, and paraffin wax, oxidation products of aliphatic hydrocarbon waxes, such as oxidized polyethylene wax, and block copolymers of these; waxes containing aliphatic esters as principal constituents, such as carnauba wax, montanic acid ester wax, and partially or totally deacidified aliphatic esters, such as deacidified carnauba wax.
- aliphatic hydrocarbon waxes such as low-molecular weight polyethylene, low-molecular weight polypropylene, microcrystalline wax, and paraffin wax, oxidation products of aliphatic hydrocarbon waxes, such as oxidized polyethylene wax, and block copolymers of these
- waxes containing aliphatic esters as principal constituents such as carnauba wax, montanic acid ester wax, and partially or totally dea
- the release agent may include: saturated linear aliphatic acids, such as palmitic acid, stearic acid, and montanic acid; unsaturated aliphatic acids, such as brassidic acid, eleostearic acid and parinaric acid; saturated alcohols, such as stearyl alcohol, behenyl alcohol, ceryl alcohol, and melissyl alcohol; polyhydric alcohols, such as sorbitol; aliphatic acid amides, such as linoleylamide, oleylamide, and laurylamide; saturated aliphatic acid bisamides, methylene-bisstearylamide, ethylene-biscaprylamide, and ethylene-biscaprylamide; unsaturated aliphatic acid amides, such as ethylene-bisolerylamide, hexamethylene-bisoleylamide, N,N'-dioleyladipoylamide, and N,N'-dioleylsebacoylamide, aromatic bisamides, such
- the particularly preferred class of release agent (wax) in the present invention may include aliphatic hydrocarbon waxes because of good dispersibility within the resin.
- Specific examples of the wax preferably used in the present invention may include e.g., a low-molecular weight alkylene polymer obtained through polymerization of an alkylene by radical polymerization under a high pressure or in the presence of a Ziegler catalyst under a low pressure; an alkylene polymer obtained by thermal decomposition of an alkylene polymer of a high molecular weight; and a polymethylene hydrocarbon wax obtained by subjecting a mixture gas containing carbon monoxide and hydrogen to the Arge process to form a hydrocarbon mixture and distilling the hydrocarbon mixture to recover a residue.
- Fractionation of wax may preferably be performed by the press sweating method, the solvent method, vacuum distillation or fractionating crystallization.
- a metal oxide catalyst generally a composite of two or more species
- the Synthol process e.g., by the Synthol process, the Hydrocol process (using a fluidized catalyst bed), and the Arge process (using a fixed catalyst bed) providing a product rich in waxy hydrocarbon, and hydrocarbons obtained by polymerizing an alkylene, such as ethylene, in the presence of a Ziegler catalyst, as they are rich in saturated long-chain linear hydrocarbons and accompanied with few branches.
- polymethylene hydrocarbon waxes synthesized without polymerization because of their structure and molecular weight distribution suitable for easy fractionation.
- the release agent shows a peak in a molecular weight region of 400 - 2400, further 450 - 2000, particularly 500 - 1600.
- the resultant toner is provided with preferable thermal characteristics.
- the release agent when used, may preferably be used in an amount of 0.1 - 20 wt. parts, particularly 0.5 - 10 wt. parts, per 100 wt. parts of the binder resin.
- the release agent may be uniformly dispersed in the binder resin by a method of mixing the release agent in a solution of the resin at an elevated temperature under stirring or melt-kneading the binder resin together with the release agent.
- a flowability-improving agent may be blended with the toner to improve the flowability of the toner.
- examples thereof may include: powder of fluorine-containing resin, such as polyvinylidene fluoride fine powder and polytetrafluoroethylene fine powder; and fine powdery silica such as wet-process silica and dry-process silica, and treated silica obtained by surface-treating (hydrophobizing) such fine powdery silica with silane coupling agent, titanium coupling agent, silicone oil, etc. It is also preferred to use titanium oxide fine powder, aluminum oxide fine powder, and surface-treated products of such fine powders.
- a preferred class of the flowability-improving agent includes dry process silica or fumed silica obtained by vapor-phase oxidation of a silicon halide.
- silica powder can be produced according to the method utilizing pyrolytic oxidation of gaseous silicon tetrachloride in oxygen-hydrogen flame, and the basic reaction scheme may be represented as follows: SiCl 4 + 2H 2 + O 2 ⁇ SiO 2 + 4HCl.
- Fine silica powder formed by vapor phase oxidation of a silicon halide to be used in the present invention include those sold under the trade names as shown below.
- AEROSIL Natural Aerosil Co. 130 200 300 380 OX 50 TT 600 MOX 80 COK 84 Cab-O-Sil (Cabot Co.) M-5 MS-7 MS-75 HS-5 EH-5 Wacker HDK (WACKER-CHEMIE GMBH) N 20 V 15 N 20E T 30 T 40 D-C Fine Silica (Dow Corning Co.) Fransol (Fransil Co.)
- treated silica fine powder obtained by subjecting the silica fine powder formed by vapor-phase oxidation of a silicon halide to a hydrophobicity-imparting treatment. It is particularly preferred to use treated silica fine powder having a hydrophobicity of 30 - 80 as measured by the methanol titration test.
- Silica fine powder may be imparted with a hydrophobicity by chemically treating the powder with an organosilicon compound, etc., reactive with or physically adsorbed by the silica fine powder.
- Example of such an organosilicon compound may include: hexamethyldisilazane, trimethylsilane, trimethylchlorosilane, trimethylethoxysilane, dimethyldichlorosilane, methyltrichlorosilane, allyldimethylchlorosilane, allylphenyldichlorosilane, benzyldimethylcholrosilane, bromomethyldimethylchlorosilane, ⁇ -chloroethyltrichlorosilane, ⁇ -chloroethyltrichlorosilane, chloromethyldimethylchlorosilane, triorganosilylmercaptans such as trimethylsilylmercaptan, triorganosilyl acrylates, vinyldimethylacetoxysilane, dimethylethoxysilane, dimethyldimethoxysilane, diphenyldiethoxysilane, hexamethyldisiloxane
- the flowability-improving agent may have a specific surface area of at least 30 m 2 /g, preferably 50 m 2 /g, as measured by the BET method according to nitrogen adsorption.
- the flowability-improving agent may be used in an amount of 0.01 - 8 wt. parts, preferably 0.1 - 4 wt. parts, per 100 wt. parts of the toner.
- the toner according to the present invention may be used as a mono-component type developer or a toner for a two-component type developer composed of such a toner and a carrier.
- the carrier plays an important role for having the toner fully exhibit its performances.
- the carrier may comprise, for example, surface-oxidized or unoxidized powder of metals, such as iron, nickel, copper, zinc, cobalt, manganese, chromium, and rare earth metals, alloys and oxides of these, and ferrites.
- the carrier may be produced through various processes without particular restriction.
- Coated carriers obtained by coating the above-mentioned carrier material with a solid coating material, such as a resin are particularly preferred.
- a solid coating material such as a resin
- Various known coating methods may be adopted, inclusive of application of a solution or suspension liquid of a solid coating material, such as a resin, in a solvent, and blending in a powder form.
- solid carrier-coating material may include: polytetrafluoroethylene, monochlorotrifluoroethylene, polyvinylidene fluoride, silicone resin, polyester resin, styrene resin, acrylic resin, polyamide, polyvinyl butyral, and amino-acrylate resin. These coating materials may be used singly or in mixture of two or more species.
- the coating rate may preferably be 0.1 - 30 wt. %, more preferably 0.5 - 20 wt. %, of the total carrier.
- the carrier may preferably have an average particle size of 10 - 100 ⁇ m, more preferably 20 - 70 ⁇ m.
- the carrier may comprise magnetic ferrite particles, surface coated with 0.01 - 5 wt. %, preferably 0.1 - 1 wt. %, of fluorine-containing resin, silicone resin, styrene resin, acrylic resin, etc., and having a particle size distribution including at least 70 wt. % of particles of 250 mesh-pass and 400 mesh-on so as to provide the above-mentioned average particle size.
- Such coated ferrite carrier particles have a sharp particle size distribution and provide a preferable triboelectric charge and thus improved electrophotographic performances to the toner according to the present invention.
- a two-component type developer may be prepared by blending the toner and carrier in such a mixing ratio as to provide a toner concentration in the developer of preferably 2 - 15 wt. %, more preferably 4 - 13 wt. %, which generally provides good performances.
- the toner according to the present invention may be prepared by sufficiently blending the binder resin, the long-chain alkyl compound, a magnetic or non-magnetic colorant, and a charge control agent or other additives, as desired, by a blender such as a Henschel mixer or a ball mill, followed by melt-kneading for mutual dissolution of the resins of the blend, cooling for solidification of the kneaded product, pulverization and classification to recover a toner product.
- a blender such as a Henschel mixer or a ball mill
- the toner may be further sufficiently blended with an external additive such as a flowability-improving agent having a chargeability to a polarity identical to that of the toner by a blender such as a Henschel mixer to obtain a toner according to the present invention, wherein the external additive is carried on the surface of the toner particles.
- an external additive such as a flowability-improving agent having a chargeability to a polarity identical to that of the toner by a blender such as a Henschel mixer to obtain a toner according to the present invention, wherein the external additive is carried on the surface of the toner particles.
- the height H on the softening S-character curve corresponds to the total flow-out amount, and a temperature T 0 corresponding to the point C (a height of H/2) provides a softening point of the sample.
- Measurement may be performed in the following manner by using a differential scanning calorimeter ("DSC-7", available from Perkin-Elmer Corp.) according to ASTM D3418-82.
- DSC-7 differential scanning calorimeter
- the sample is placed on an aluminum pan and subjected to measurement in a temperature range of 30 - 200 °C at a temperature-raising rate of 10 °C/min in parallel with a blank aluminum pan as a reference.
- an absorption peak attributable to a principal binder resin component generally appears in the temperature region of 40 - 80 °C
- an absorption peak attributable to a long-chain alkyl alcohol or carboxylic acid generally appears in the temperature region of 70 - 140 °C.
- the glass transition temperature is determined as a temperature of an intersection of a DSC curve and an intermediate line pressing between the base lines obtained before and after the appearance of the absorption peak (i.e., a temperature of a mid point on the DSC curve).
- An example of a heat absorption cube is shown in Figure 5.
- the sample may be a starting material thereof or a (non-reacted) long-chain alkyl alcohol or long-chain alkyl carboxylic acid recovered from a toner in a manner described in (9) (A) appearing hereinafter.
- the sample is subjected to a DSC analysis similarly as the measurement of the glass transition temperature and generally provides a heat absorption peak in the range of 70 - 140 °C, of which the temperature is taken as a melting point (m.p.).
- a sample material is accurately weighed and dissolved in a mixture solvent, and water is added thereto.
- the resultant liquid is titrated with 0.1N-NaOH by potentiometric titration using glass electrodes (according to JIS K1557-1970).
- the titration is performed in a state of dissolution under heating.
- a fraction thereof recovered by using a fraction collector during the molecular weight distribution measurement is used as a sample after drying and subjected to measurement in the above-described manner.
- a sample is accurately weighed into a 100 ml-eggplant-shaped flask, and 5 ml of an acetylating agent is accurately added thereto. Then, the system is heated by dipping into a bath of 100 °C ⁇ 5 °C. After 1 - 2 hours, the flask is taken out of the bath and allowed to cool by standing, and water is added thereto, followed by shaking to decompose acetic anhydride. In order to complete the decomposition, the flask is again heated for more than 10 min. by dipping into the bath. After cooling, the flask wall is sufficiently washed with an organic solvent.
- the resultant liquid is titrated with a N/2-potassium hydroxide solution in ethyl alcohol by potentiometric titration using glass electrodes (according to JIS K0070-1966).
- the OH value of a long-chain alkyl alcohol may be measured according to ASTM E-222, TEST METHOD B.
- the molecular weight (distribution) of a binder resin or resin component may be measured based on a chromatogram obtained by GPC (gel permeation chromatography).
- a column is stabilized in a heat chamber at 40 °C, tetrahydrofuran (THF) solvent is caused to flow through the column at that temperature at a rate of 1 ml/mm., and 50 - 200 ⁇ l of a GPC sample solution adjusted at a concentration of 0.05 - 0.6 wt. % is injected.
- THF tetrahydrofuran
- the identification of sample molecular weight and its molecular weight distribution is performed based on a calibration curve obtained by using several monodisperse polystyrene samples and having a logarithmic scale of molecular weight versus count number.
- the standard polystyrene samples for preparation of a calibration curve may be available from, e.g., Pressure Chemical Co.
- the detector may be an RI (refractive index) detector.
- RI reffractive index
- a preferred example thereof may be a combination of ⁇ -styragel 500, 10 3 , 10 4 and 10 5 available from Waters Co.; or a combination of Shodex KA-801, 802, 803, 804 and 805 available from Showa Denko K.K.;
- the molecular weight (distribution) of a long-chain alkyl alcohol or a long-chain alkyl carboxylic acid may be measured by GPC under the following conditions:
- the molecular weight distribution of a sample is obtained once based on a calibration curve prepared by monodisperse polystyrene standard samples, and recalculated into a distribution corresponding to that of polyethylene using a conversion formula based on the Mark-Houwink viscosity formula.
- a developer sampled from a layer on a developer carrying member is weighed and placed in an apparatus as shown in Figure 2, more specifically in a metal-made measuring container 2 equipped with an electroconductive screen of 500 mesh (capable of being changed into another size so as not to allow passage of magnetic carrier particles) at the bottom and covered with a metal lid 4.
- the total weight of the container 2 is weighed and denoted by W 1 (g).
- an aspirator 1 composed of an insulating material at least with respect to a part contacting the container 2 is operated to suck the toner through a suction port 7 to set a pressure at a vacuum gauge 5 at 250 mmAg while adjusting an aspiration control valve 6. In this state, the aspiration is performed sufficiently (for ca.
- T ( ⁇ C/g) (C x V)/(W 1 - W 2 ).
- sample toner containing a principal resin component, a modified polyester resin, and a non-reacted long-chain alkyl alcohol or a long-chain alkyl carboxylic acid is weighed and placed in a cylindrical filter paper (e.g., "No. 86R" having a size of 28 mm x 100 mm, available from Toyo Roshi K.K.), and at least 500 ml of xylene heated to 120 °C or higher is dripped thereon. After the dripping, the xylene in the filtrate (solution of resinous matters including waxes, alcohols and carboxylic acid) is evaporated off, followed by drying under vacuum.
- a cylindrical filter paper e.g., "No. 86R" having a size of 28 mm x 100 mm, available from Toyo Roshi K.K.
- the thus-dried sample is weighed and placed again in a cylindrical filter paper to be placed on a Soxhlet's extractor ( Figure 3) and then subjected to extraction with 200 ml of solvent THF (tetrahydrofuran) in a Soxhlet's extractor.
- THF tetrahydrofuran
- the extraction is performed for 6 hours. At this time, the reflux rate is controlled so that each THF extraction cycle takes about 4 - 5 minutes.
- the cylindrical filter paper is taken out and dried to recover the long-chain alkyl alcohol or carboxylic acid.
- the filtrate liquid is dried to recover the principal resin and the modified polyester resin in mixture.
- THF 32 contained in a vessel 31 is vaporized under heating by a heater 28, and the vaporized THF is caused to pass through a pipe 37 and guided to a cooler 35 which is always cooled with cooling water 36.
- the THF cooled in the cooler 35 is liquefied and stored in a reservoir part containing a cylindrical filter paper 33.
- the THF is discharged from the reservoir part to the vessel 31 through the pipe 34.
- the toner or resin in the cylindrical filter paper is subjected to extraction with the thus circulating THF.
- the measurement is performed according to ASTM D3418-42. Each sample is once subjected to temperature-raising to remove its thermal history and then subjected to the DSC analysis by effecting temperature raising and cooling in a temperature range of 0 - 200 °C at a temperature-changing rate of 10 °C/min. The area of a heat-absorption peak of each sample is divided by the sample weight to obtain ⁇ H (J/kg).
- a sample recovered in (9)(A) is used. Each sample is weighed and dissolved in a solvent, and water is added thereto. The resultant liquid is titrated with 0.1N-NaOH by potentiometric titration using glass electrodes (according to JIS K1557-1970). In the case of a long-chain alkyl carboxylic acid, the titration is performed in a dissolved state under heating.
- a sample recovered in (9)(A) above is used for the measurement. Each sample is accurately weighed into a 100 ml-eggplant-shaped flask and 50 ml of xylene is added thereto, followed by heating on an oil bath at 120 °C. Another eggplant-shaped flask containing 5 ml of xylene as a blank is equally subjected to the following operation.
- Polyesters were prepared while monitoring the progress of the reaction by measuring the acid value and the reaction was terminated when a prescribed acid value was reached, followed by cooling to room temperature to recover the polyesters.
- Polyester resins D - V were prepared by subjecting monomers respectively shown in Table 1 to polycondensation similarly as in Polyester Production Example 1, and the softening points of the resultants polyester resins are also shown in Table 1 below.
- Table 1 Polyester resin Monomer composition *3 (acids//alcohols) Softening point (°C) Type *1 Name L A IPA/AA//PO-BPA/EO-BPA 93 L D *2 AA/DSA//PO-BPA/EO-BPA 71 L E *2 TPA//PO-BPA/EO-BPA 75 NL B TPA/FA/TMA//PO-BPA/EO-BPA 99 NL F *2 AA/SA/TMA//PO-BPA/EO-BPA 78 NL G IPA/TMA//PO-BPA/EO-BPA 122 NL C IPA/TPA/TMA//PO-BPA/EO-BPA 130 NL H TPA/TMA/PO-BPA/EO-B
- Resin compositions (iii) to (xx) shown in Table 2 were prepared in the same manner as above.
- the above ingredients were pre-mixed by a Henschel mixer and melt-kneaded through a twin-screw extruder at 130 °C. After cooling, the melt-kneaded product was coarsely crushed by a cutter mill and finely pulverized by a jet stream pulverizer, followed by classification by a pneumatic classifier to obtain a magnetic toner having a weight-average particle size of 6.3 ⁇ m.
- the magnetic toner was charged into a digital copying machine ("GP-55", mfd. by Canon K.K.) to be evaluated with respect image characteristics, whereby results as shown in Table 6 appearing hereinafter were obtained. Further, a fixing test was performed by taking out the fixing apparatus of the copying machine so as to use it as an externally driven fixing apparatus equipped with a temperature controller at various fixing speeds, whereby good results also as shown in Table 6 were obtained.
- the density gradation characteristic was good because of a fast charging speed and a stable saturation charge.
- an undesirable phenomenon of selective development that a developer fraction of a small particle size is selectively consumed could be obviated.
- the halftone images were free from change in image quality from the initial stage, free from density irregularity, smooth and good.
- the resultant toner showed a developing potential - copy image density characteristic as represented by a dot and dash line in Figure 1.
- Magnetic toners were prepared and evaluated in the same manner as in Example 1 except that the polyester resin composition, long-chain alkyl alcohol and long-chain alkyl carboxylic acid were changed as shown in Tables 4 - 5, whereby results as shown in Table 6 were obtained.
- Table 6 shows the results of evaluation performed according to the following manner and standards. (1) Each item was evaluated at 5 levels as follows:
- Magnetic toners having characteristics shown in Tables 8 and 9 were prepared in the same manner as in Example 1 except for replacing the polyester resin composition, the long-chain alkyl alcohol and the long-chain alkyl carboxylic acid with those shown in Table 7. The resultant magnetic toners were evaluated in the same manner as in Example 1, whereby results shown in Table 10 were obtained.
- Table 8 Example Polyester resin composition in toner Mw Mn Mw/Mn Contest of M.W.
- Modified polyester resins H-2 to L2 and N-2 shown in Table 12 were prepared by polycondensation and modification in the same manner as in Production Example 26 except for using long-chain alkyl alcohols ⁇ -10 to ⁇ -14 and long-chain alkyl carboxylic acid ⁇ -1 instead of the long-chain alkyl alcohol ⁇ -1.
- Resin compositions (xxiii) to (xxxi) shown in Table 13 were prepared in the same manner as above.
- BET specific surface area (S BET ) 300 m 2 /g
- the magnetic toner was charged into a digital copying machine ("GP-55", mfd. by Canon K.K.) to be evaluated with respect image characteristics, whereby good results as shown in Table 15 appearing hereinafter were obtained. Further, a fixing test was performed by taking out the fixing apparatus of the copying machine so as to use it as an externally driven fixing apparatus equipped with a temperature controller at various fixing speeds, whereby good results also as shown in Table 15 were obtained.
- Magnetic toners were prepared and evaluated in the same manner as in Example 25 except that the polyester resin compositions (xxii) - (xxxi) were used instead of the resin composition (xxi), whereby results as shown in Table 15 were obtained.
- a magnetic toner was prepared in the same manner as in Example 25 except for using 30 wt. parts of the classified fine powder fraction in addition to 100 wt. parts of the polyester resin composition (xxi), 90 wt. parts of the magnetic iron oxide and 2 wt. parts of the mono-ago metal complex.
- the magnetic toner was evaluated in the same manner as in Example 25, whereby results shown in Table 15 were obtained.
- Table 14 Example Polyester resin composition in toner Mw Mn Mw/Mn Content of M.W.
Landscapes
- Physics & Mathematics (AREA)
- General Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Developing Agents For Electrophotography (AREA)
Applications Claiming Priority (5)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP31607394 | 1994-11-28 | ||
JP31607394 | 1994-11-28 | ||
JP33770494 | 1994-12-28 | ||
JP33770494 | 1994-12-28 | ||
EP95308507A EP0716351B1 (de) | 1994-11-28 | 1995-11-27 | Toner für die Entwicklung elektrostatischer Bilder |
Related Parent Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95308507A Division EP0716351B1 (de) | 1994-11-28 | 1995-11-27 | Toner für die Entwicklung elektrostatischer Bilder |
EP95308507.3 Division | 1995-11-27 |
Publications (3)
Publication Number | Publication Date |
---|---|
EP0955568A2 true EP0955568A2 (de) | 1999-11-10 |
EP0955568A3 EP0955568A3 (de) | 2000-01-26 |
EP0955568B1 EP0955568B1 (de) | 2005-07-06 |
Family
ID=26568523
Family Applications (2)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95308507A Expired - Lifetime EP0716351B1 (de) | 1994-11-28 | 1995-11-27 | Toner für die Entwicklung elektrostatischer Bilder |
EP99202424A Expired - Lifetime EP0955568B1 (de) | 1994-11-28 | 1995-11-27 | Toner für die Entwicklung elektrostatischer Bilder |
Family Applications Before (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EP95308507A Expired - Lifetime EP0716351B1 (de) | 1994-11-28 | 1995-11-27 | Toner für die Entwicklung elektrostatischer Bilder |
Country Status (6)
Country | Link |
---|---|
US (1) | US5660963A (de) |
EP (2) | EP0716351B1 (de) |
KR (1) | KR0163821B1 (de) |
CN (2) | CN1107886C (de) |
DE (2) | DE69534302T2 (de) |
HK (1) | HK1012059A1 (de) |
Cited By (1)
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EP1283111A3 (de) * | 2001-07-31 | 2003-05-02 | Ricoh Company, Ltd. | Bildaufzeichnungsmaterial, Verfahren und Gerät zum Entfernen von Bildern, und Bildaufzeichungsverfahren und Gerät |
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US5875379A (en) * | 1996-08-23 | 1999-02-23 | Minolta Co., Ltd. | Developing device capable of preventing cracking of developer due to pressing of a developer layer controlling member |
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EP0913735B1 (de) * | 1997-10-31 | 2005-09-14 | Xeikon International N.V. | Tonerteilchen, die eine Mischung aus einem modifizierten linearen Polymer, einem vernetzten Polymer und einem Wachs enthalten |
US6071664A (en) * | 1997-10-31 | 2000-06-06 | Agfa-Gevaert, N.V. | Toner particles containing a mixture of a modified linear polymer, a cross-linked polymer and a wax |
US6238836B1 (en) * | 1998-09-25 | 2001-05-29 | Dainippon Ink Chemicals, Inc. | Toner composition and developer for electrostatic image development |
US6248493B1 (en) | 1998-09-25 | 2001-06-19 | Dainippon Ink And Chemicals, Inc. | Toner for non-magnetic single component development |
US6194116B1 (en) * | 1998-12-15 | 2001-02-27 | Minolta Co., Ltd. | Toner containing specific alkyl carboxylic acid with fine particles externally added |
JP3638227B2 (ja) | 1999-06-03 | 2005-04-13 | コニカミノルタビジネステクノロジーズ株式会社 | 静電荷像現像用カラートナー |
JP2001051450A (ja) | 1999-06-03 | 2001-02-23 | Minolta Co Ltd | 静電荷像現像用カラートナー |
JP4002039B2 (ja) * | 1999-09-27 | 2007-10-31 | 花王株式会社 | 非接触定着用トナー |
EP1271255B1 (de) * | 2000-03-13 | 2010-09-22 | Sanyo Chemical Industries, Ltd. | Toner und herstellungsverfahren |
ES2236094T3 (es) | 2000-07-10 | 2005-07-16 | Canon Kabushiki Kaisha | Toner. |
JP5073888B2 (ja) | 2001-03-28 | 2012-11-14 | 花王株式会社 | 静電荷像現像用トナー |
US6924075B2 (en) | 2002-02-22 | 2005-08-02 | Xeikon International N.V. | Dry toner composition |
US6887639B2 (en) | 2002-02-22 | 2005-05-03 | Xeikon International N.V. | Liquid toner composition |
US6881527B2 (en) * | 2002-03-26 | 2005-04-19 | Canon Kabushiki Kaisha | Toner, and process cartridge |
JP3693330B2 (ja) * | 2002-10-18 | 2005-09-07 | 花王株式会社 | 樹脂組成物 |
JP2005062797A (ja) * | 2003-07-30 | 2005-03-10 | Canon Inc | 磁性トナー |
JP4343709B2 (ja) * | 2004-01-06 | 2009-10-14 | 花王株式会社 | 電子写真用トナーの製造方法 |
US7862973B2 (en) | 2006-11-22 | 2011-01-04 | Ricoh Company, Ltd. | Toner and developer, and image forming apparatus, image forming method and process cartridge |
US7824832B2 (en) * | 2006-06-02 | 2010-11-02 | Kao Corporation | Toner for electrophotography |
JP4749238B2 (ja) * | 2006-06-02 | 2011-08-17 | 花王株式会社 | 電子写真用トナー |
JP4749939B2 (ja) * | 2006-06-02 | 2011-08-17 | 株式会社リコー | 画像形成装置、画像形成方法、及びプロセスカートリッジ |
JP5054443B2 (ja) * | 2007-06-20 | 2012-10-24 | 株式会社リコー | 画像形成装置、画像形成方法、及びプロセスカートリッジ |
CN101788773B (zh) * | 2009-11-13 | 2011-11-02 | 无锡佳腾磁性粉有限公司 | 彩色激光打印机蓝色耐久性防伪显影剂及其制备方法 |
US8741523B2 (en) * | 2010-04-16 | 2014-06-03 | Konica Minolta Business Technologies, Inc. | Toner for developing electrostatic image and manufacturing method thereof |
JP5828742B2 (ja) * | 2011-11-02 | 2015-12-09 | キヤノン株式会社 | トナー |
US9158217B2 (en) * | 2013-06-26 | 2015-10-13 | Canon Kabushiki Kaisha | Toner |
US20160139522A1 (en) | 2014-11-18 | 2016-05-19 | Canon Kabushiki Kaisha | Toner |
US9989869B2 (en) * | 2015-01-05 | 2018-06-05 | Ricoh Company, Ltd. | Toner, toner stored unit, and image forming apparatus |
WO2017067812A1 (en) * | 2015-10-23 | 2017-04-27 | Hewlett-Packard Indigo B.V. | Electrophotographic composition |
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- 1995-11-27 EP EP95308507A patent/EP0716351B1/de not_active Expired - Lifetime
- 1995-11-27 DE DE69521189T patent/DE69521189T2/de not_active Expired - Lifetime
- 1995-11-27 EP EP99202424A patent/EP0955568B1/de not_active Expired - Lifetime
- 1995-11-28 US US08/563,290 patent/US5660963A/en not_active Expired - Lifetime
- 1995-11-28 KR KR1019950044154A patent/KR0163821B1/ko not_active IP Right Cessation
- 1995-11-28 CN CN95120261A patent/CN1107886C/zh not_active Expired - Fee Related
-
1998
- 1998-12-10 HK HK98113105A patent/HK1012059A1/xx not_active IP Right Cessation
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Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP1283111A3 (de) * | 2001-07-31 | 2003-05-02 | Ricoh Company, Ltd. | Bildaufzeichnungsmaterial, Verfahren und Gerät zum Entfernen von Bildern, und Bildaufzeichungsverfahren und Gerät |
US6913860B2 (en) | 2001-07-31 | 2005-07-05 | Ricoh Company, Ltd. | Image forming material, method and device for removing images, and image forming process and apparatus |
Also Published As
Publication number | Publication date |
---|---|
DE69534302D1 (de) | 2005-08-11 |
EP0716351A3 (de) | 1997-10-08 |
EP0955568A3 (de) | 2000-01-26 |
EP0955568B1 (de) | 2005-07-06 |
CN1150661A (zh) | 1997-05-28 |
EP0716351B1 (de) | 2001-06-06 |
US5660963A (en) | 1997-08-26 |
EP0716351A2 (de) | 1996-06-12 |
HK1012059A1 (en) | 1999-07-23 |
DE69521189D1 (de) | 2001-07-12 |
DE69534302T2 (de) | 2006-04-27 |
DE69521189T2 (de) | 2001-10-31 |
CN1107886C (zh) | 2003-05-07 |
KR960018776A (ko) | 1996-06-17 |
CN1388415A (zh) | 2003-01-01 |
KR0163821B1 (ko) | 1999-03-20 |
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