EA039462B9 - Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов - Google Patents
Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диеновInfo
- Publication number
- EA039462B9 EA039462B9 EA201990858A EA201990858A EA039462B9 EA 039462 B9 EA039462 B9 EA 039462B9 EA 201990858 A EA201990858 A EA 201990858A EA 201990858 A EA201990858 A EA 201990858A EA 039462 B9 EA039462 B9 EA 039462B9
- Authority
- EA
- Eurasian Patent Office
- Prior art keywords
- oxo
- iron complex
- nitrogenated iron
- polymerization
- nitrogenated
- Prior art date
Links
- 150000004698 iron complex Chemical class 0.000 title abstract 4
- 230000003197 catalytic effect Effects 0.000 title abstract 2
- 150000001993 dienes Chemical class 0.000 title abstract 2
- 238000006116 polymerization reaction Methods 0.000 title abstract 2
- 238000000034 method Methods 0.000 title 1
- 125000003837 (C1-C20) alkyl group Chemical group 0.000 abstract 2
- ZCYVEMRRCGMTRW-UHFFFAOYSA-N 7553-56-2 Chemical compound [I] ZCYVEMRRCGMTRW-UHFFFAOYSA-N 0.000 abstract 1
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 abstract 1
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 abstract 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 abstract 1
- 229910052794 bromium Inorganic materials 0.000 abstract 1
- 229910052801 chlorine Inorganic materials 0.000 abstract 1
- 239000000460 chlorine Substances 0.000 abstract 1
- 125000005843 halogen group Chemical group 0.000 abstract 1
- 229910052740 iodine Inorganic materials 0.000 abstract 1
- 239000011630 iodine Substances 0.000 abstract 1
- 125000001997 phenyl group Chemical group [H]C1=C([H])C([H])=C(*)C([H])=C1[H] 0.000 abstract 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F15/00—Compounds containing elements of Groups 8, 9, 10 or 18 of the Periodic Table
- C07F15/02—Iron compounds
- C07F15/025—Iron compounds without a metal-carbon linkage
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C249/00—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C249/02—Preparation of compounds containing nitrogen atoms doubly-bound to a carbon skeleton of compounds containing imino groups
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C251/00—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton
- C07C251/02—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups
- C07C251/04—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms
- C07C251/06—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton
- C07C251/08—Compounds containing nitrogen atoms doubly-bound to a carbon skeleton containing imino groups having carbon atoms of imino groups bound to hydrogen atoms or to acyclic carbon atoms to carbon atoms of a saturated carbon skeleton being acyclic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/06—Butadiene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F136/00—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F136/02—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F136/04—Homopolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F136/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/08—Isoprene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F4/00—Polymerisation catalysts
- C08F4/42—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
- C08F4/44—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
- C08F4/60—Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides together with refractory metals, iron group metals, platinum group metals, manganese, rhenium technetium or compounds thereof
- C08F4/70—Iron group metals, platinum group metals or compounds thereof
- C08F4/7001—Iron group metals, platinum group metals or compounds thereof the metallic compound containing a multidentate ligand, i.e. a ligand capable of donating two or more pairs of electrons to form a coordinate or ionic bond
- C08F4/7003—Bidentate ligand
- C08F4/7004—Neutral ligand
- C08F4/7008—NO
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
- C07C2601/00—Systems containing only non-condensed rings
- C07C2601/12—Systems containing only non-condensed rings with a six-membered ring
- C07C2601/16—Systems containing only non-condensed rings with a six-membered ring the ring being unsaturated
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F36/00—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds
- C08F36/02—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds
- C08F36/04—Homopolymers and copolymers of compounds having one or more unsaturated aliphatic radicals, at least one having two or more carbon-to-carbon double bonds the radical having only two carbon-to-carbon double bonds conjugated
- C08F36/06—Butadiene
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerization Catalysts (AREA)
Abstract
Оксо-азотсодержащий комплекс железа, имеющий общую формулу (I)где R1 и R2, одинаковые или разные, выбраны из линейных или разветвленных C1-C20 алкильных групп; R3 представляет собой фенильные группы, необязательно замещенные одной или более линейных или разветвленных C1-C20 алкильных групп; X, будучи одинаковым, представляет собой атом галогена, выбранный из хлора, брома, йода; n равно 2 или 3. Указанный оксо-азотсодержащий комплекс железа, имеющий общую формулу (I), можно преимущественно использовать в каталитической системе для (со)полимеризации сопряженных диенов.
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
IT102017000006307A IT201700006307A1 (it) | 2017-01-20 | 2017-01-20 | Complesso osso-azotato di ferro, sistema catalitico comprendente detto complesso osso-azotato di ferro e procedimento per la (co)polimerizzazione di dieni coniugati |
PCT/IB2018/050308 WO2018134757A1 (en) | 2017-01-20 | 2018-01-18 | Oxo-nitrogenated iron complex, catalytic system comprising said oxo-nitrogenated iron complex and process for the (co)polymerization of conjugated dienes |
Publications (3)
Publication Number | Publication Date |
---|---|
EA201990858A1 EA201990858A1 (ru) | 2019-12-30 |
EA039462B1 EA039462B1 (ru) | 2022-01-28 |
EA039462B9 true EA039462B9 (ru) | 2022-02-21 |
Family
ID=58737747
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
EA201990858A EA039462B9 (ru) | 2017-01-20 | 2018-01-18 | Оксо-азотсодержащий комплекс железа, каталитическая система, включающая указанный оксо-азотсодержащий комплекс железа, и способ (со)полимеризации сопряженных диенов |
Country Status (19)
Country | Link |
---|---|
US (1) | US11518776B2 (ru) |
EP (1) | EP3571210B1 (ru) |
KR (1) | KR102575575B1 (ru) |
CN (1) | CN110167949B (ru) |
BR (1) | BR112019014988B1 (ru) |
CA (1) | CA3041883A1 (ru) |
DK (1) | DK3571210T3 (ru) |
EA (1) | EA039462B9 (ru) |
ES (1) | ES2917890T3 (ru) |
HR (1) | HRP20220778T1 (ru) |
HU (1) | HUE058821T2 (ru) |
IT (1) | IT201700006307A1 (ru) |
PL (1) | PL3571210T3 (ru) |
PT (1) | PT3571210T (ru) |
RS (1) | RS63308B1 (ru) |
SA (1) | SA519401767B1 (ru) |
SI (1) | SI3571210T1 (ru) |
WO (1) | WO2018134757A1 (ru) |
ZA (1) | ZA201902695B (ru) |
Families Citing this family (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110483586B (zh) * | 2019-08-27 | 2021-07-09 | 中国科学技术大学 | 大位阻酮亚胺镍催化剂及其配体化合物、制备方法和应用 |
Family Cites Families (16)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3151047A (en) * | 1960-09-12 | 1964-09-29 | Phillips Petroleum Co | Separation of organic compounds by fractional distillation and phase separation |
US3373177A (en) * | 1963-05-20 | 1968-03-12 | Union Oil Co | Preparation of metal chelates of beta-iminocarbonyls |
US6545108B1 (en) * | 1999-02-22 | 2003-04-08 | Eastman Chemical Company | Catalysts containing N-pyrrolyl substituted nitrogen donors |
CN101311182A (zh) | 2000-05-31 | 2008-11-26 | 纳幕尔杜邦公司 | 烯烃的聚合 |
CN100369940C (zh) * | 2000-05-31 | 2008-02-20 | 纳幕尔杜邦公司 | 烯烃聚合催化剂 |
BR0111338A (pt) | 2000-05-31 | 2003-06-17 | Du Pont | Complexo de metal de transição, processo para a polimerização de olefinas, processo para a produção de um copolìmero polar |
JP2004517933A (ja) * | 2001-01-26 | 2004-06-17 | イー・アイ・デユポン・ドウ・ヌムール・アンド・カンパニー | オレフィン系化合物の重合 |
US6710007B2 (en) | 2001-01-26 | 2004-03-23 | E. I. Du Pont De Nemours And Company | Polymerization of olefinic compounds |
US7199255B2 (en) * | 2001-12-18 | 2007-04-03 | Univation Technologies, Llc | Imino-amide catalysts for olefin polymerization |
JP2005200305A (ja) * | 2004-01-13 | 2005-07-28 | Nippon Synthetic Chem Ind Co Ltd:The | イミダゾール類の製造方法 |
ITMI20111652A1 (it) * | 2011-09-14 | 2013-03-15 | Polimeri Europa Spa | Complesso oss-azotato di lantanidi, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
ITMI20122199A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso bis-imminico di cobalto |
ITMI20122201A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Complesso osso-azotato di cobalto, sistema catalitico comprendente detto complesso osso-azotato e procedimento per la (co)polimerizzazione di dieni coniugati |
ITMI20122203A1 (it) | 2012-12-20 | 2014-06-21 | Versalis Spa | Procedimento per la preparazione di (co)polimeri di dieni coniugati in presenza di un sistema catalitico comprendente un complesso osso-azotato di cobalto |
ITMI20131830A1 (it) * | 2013-11-05 | 2015-05-06 | Versalis Spa | Polibutadieni di-blocco stereoregolari a struttura 1,4-cis/1,2 sindiotattica da polimerizzazione stereospecifica |
PL3237463T3 (pl) * | 2014-12-23 | 2020-06-29 | Versalis S.P.A. | Okso-nitrowany kompleks wanadowy, układ katalityczny zawierający ten okso-nitrowany kompleks wanadowy i sposób (co)polimeryzacji sprzężonych dienów |
-
2017
- 2017-01-20 IT IT102017000006307A patent/IT201700006307A1/it unknown
-
2018
- 2018-01-18 HU HUE18702336A patent/HUE058821T2/hu unknown
- 2018-01-18 US US16/345,015 patent/US11518776B2/en active Active
- 2018-01-18 CA CA3041883A patent/CA3041883A1/en active Pending
- 2018-01-18 HR HRP20220778TT patent/HRP20220778T1/hr unknown
- 2018-01-18 RS RS20220576A patent/RS63308B1/sr unknown
- 2018-01-18 SI SI201830671T patent/SI3571210T1/sl unknown
- 2018-01-18 DK DK18702336.1T patent/DK3571210T3/da active
- 2018-01-18 ES ES18702336T patent/ES2917890T3/es active Active
- 2018-01-18 KR KR1020197015214A patent/KR102575575B1/ko active IP Right Grant
- 2018-01-18 BR BR112019014988-0A patent/BR112019014988B1/pt active IP Right Grant
- 2018-01-18 EP EP18702336.1A patent/EP3571210B1/en active Active
- 2018-01-18 CN CN201880004927.9A patent/CN110167949B/zh active Active
- 2018-01-18 PT PT187023361T patent/PT3571210T/pt unknown
- 2018-01-18 PL PL18702336.1T patent/PL3571210T3/pl unknown
- 2018-01-18 WO PCT/IB2018/050308 patent/WO2018134757A1/en unknown
- 2018-01-18 EA EA201990858A patent/EA039462B9/ru unknown
-
2019
- 2019-04-29 ZA ZA2019/02695A patent/ZA201902695B/en unknown
- 2019-05-12 SA SA519401767A patent/SA519401767B1/ar unknown
Also Published As
Publication number | Publication date |
---|---|
PT3571210T (pt) | 2022-05-27 |
EA201990858A1 (ru) | 2019-12-30 |
KR20190101962A (ko) | 2019-09-02 |
WO2018134757A1 (en) | 2018-07-26 |
KR102575575B1 (ko) | 2023-09-05 |
SI3571210T1 (sl) | 2022-07-29 |
CA3041883A1 (en) | 2018-07-26 |
IT201700006307A1 (it) | 2018-07-20 |
BR112019014988B1 (pt) | 2022-12-20 |
CN110167949B (zh) | 2022-08-23 |
DK3571210T3 (da) | 2022-06-07 |
SA519401767B1 (ar) | 2023-02-19 |
US20210292354A1 (en) | 2021-09-23 |
EA039462B1 (ru) | 2022-01-28 |
HRP20220778T1 (hr) | 2022-09-16 |
EP3571210B1 (en) | 2022-04-13 |
BR112019014988A2 (pt) | 2020-04-28 |
US11518776B2 (en) | 2022-12-06 |
ZA201902695B (en) | 2022-09-28 |
CN110167949A (zh) | 2019-08-23 |
HUE058821T2 (hu) | 2022-09-28 |
RS63308B1 (sr) | 2022-07-29 |
ES2917890T3 (es) | 2022-07-12 |
EP3571210A1 (en) | 2019-11-27 |
PL3571210T3 (pl) | 2022-08-08 |
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TH4A | Publication of the corrected specification to eurasian patent |