EA016496B9 - Способ получения смеси синтез-газа - Google Patents

Способ получения смеси синтез-газа

Info

Publication number
EA016496B9
EA016496B9 EA201000055A EA201000055A EA016496B9 EA 016496 B9 EA016496 B9 EA 016496B9 EA 201000055 A EA201000055 A EA 201000055A EA 201000055 A EA201000055 A EA 201000055A EA 016496 B9 EA016496 B9 EA 016496B9
Authority
EA
Eurasian Patent Office
Prior art keywords
making
carbon dioxide
catalyst
mixture containing
syngas mixture
Prior art date
Application number
EA201000055A
Other languages
English (en)
Other versions
EA201000055A1 (ru
EA016496B1 (ru
Inventor
Агаддин М.Х. Мамедов
Абдулазиз М. Ал-Джодай
Original Assignee
Сауди Бейсик Индастриз Корпорейшн
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Сауди Бейсик Индастриз Корпорейшн filed Critical Сауди Бейсик Индастриз Корпорейшн
Publication of EA201000055A1 publication Critical patent/EA201000055A1/ru
Publication of EA016496B1 publication Critical patent/EA016496B1/ru
Publication of EA016496B9 publication Critical patent/EA016496B9/ru

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C01—INORGANIC CHEMISTRY
    • C01B—NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00—Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C—CHEMISTRY; METALLURGY
    • C07—ORGANIC CHEMISTRY
    • C07C—ACYCLIC OR CARBOCYCLIC COMPOUNDS
    • C07C29/00—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
    • C07C29/15—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively
    • C07C29/151—Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring by reduction of oxides of carbon exclusively with hydrogen or hydrogen-containing gases
    • C07C29/1516—Multisteps
    • C07C29/1518—Multisteps one step being the formation of initial mixture of carbon oxides and hydrogen for synthesis
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J21/00—Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
    • B01J21/02—Boron or aluminium; Oxides or hydroxides thereof
    • B01J21/04—Alumina
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
    • B01J23/16—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
    • B01J23/24—Chromium, molybdenum or tungsten
    • B01J23/26—Chromium
    • B01J35/613—
    • B01J35/647—
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30—Hydrogen technology
    • Y02E60/32—Hydrogen storage
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/141—Feedstock
    • Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00—Technologies relating to chemical industry
    • Y02P20/50—Improvements relating to the production of bulk chemicals
    • Y02P20/52—Improvements relating to the production of bulk chemicals using catalysts, e.g. selective catalysts

Abstract

Изобретение относится к способу получения смеси синтез-газа, содержащей водород, монооксид углерода и диоксид углерода, включающему стадию приведения в контакт газообразной смеси сырья, содержащей диоксид углерода и водород, с катализатором, в котором катализатор состоит, по существу, из оксида хрома/оксида алюминия. Этот способ позволяет гидрировать диоксид углерода в монооксид углерода с высокой селективностью и хорошей стабильностью катализатора во времени и при изменении рабочих условий. Способ может быть применён отдельно, но также может быть объединён с другими способами, например, выше по потоку от синтеза продуктов, подобных алифатическим оксигенатам, олефинам или ароматическим соединениям.
EA201000055A 2007-06-25 2008-06-24 Способ получения смеси синтез-газа EA016496B9 (ru)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
EP07075510 2007-06-25
PCT/EP2008/005069 WO2009000494A2 (en) 2007-06-25 2008-06-24 Catalytic hydrogenation of carbon dioxide into syngas mixture

Publications (3)

Publication Number Publication Date
EA201000055A1 EA201000055A1 (ru) 2010-04-30
EA016496B1 EA016496B1 (ru) 2012-05-30
EA016496B9 true EA016496B9 (ru) 2012-07-30

Family

ID=39256933

Family Applications (1)

Application Number Title Priority Date Filing Date
EA201000055A EA016496B9 (ru) 2007-06-25 2008-06-24 Способ получения смеси синтез-газа

Country Status (6)

Country Link
US (1) US8288446B2 (ru)
EP (1) EP2175986A2 (ru)
JP (1) JP5411133B2 (ru)
CN (2) CN104192794A (ru)
EA (1) EA016496B9 (ru)
WO (1) WO2009000494A2 (ru)

Families Citing this family (40)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EA020700B1 (ru) 2008-12-17 2015-01-30 Сауди Бейсик Индастриз Корпорейшн Способ увеличения содержания монооксида углерода в синтез-газе
CA2763818A1 (en) * 2009-05-26 2010-12-02 University Of The Witwatersrand, Johannesburg A carbon absorbing system used in the production of synthesis gas
WO2012153762A1 (ja) * 2011-05-11 2012-11-15 株式会社村田製作所 逆シフト反応用触媒、およびそれを用いた合成ガスの製造方法
FR2982272B1 (fr) * 2011-11-04 2014-03-07 Commissariat Energie Atomique Procede de conversion thermochimique d'une charge carbonee en gaz de synthese contenant majoritairement h2 et co
US8962702B2 (en) * 2011-12-08 2015-02-24 Saudi Basic Industries Corporation Mixed oxide based catalyst for the conversion of carbon dioxide to syngas and method of preparation and use
WO2013135662A1 (de) 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxidkatalysatoren
WO2013135663A1 (de) 2012-03-13 2013-09-19 Bayer Intellectual Property Gmbh Verfahren zur reduktion von kohlendioxid bei hohen temperaturen an mischmetalloxid-katalysatoren umfassend edelmetalle
AU2013231342A1 (en) 2012-03-13 2014-10-16 Bayer Intellectual Property Gmbh Method for producing CO and/or H2 in an alternating operation between two operating modes
WO2013190500A2 (en) 2012-06-21 2013-12-27 Saudi Basic Industries Corporation Process for producing a synthesis gas mixture
US8551434B1 (en) 2012-06-29 2013-10-08 Saudi Basic Industries Corporation Method of forming a syngas mixture
EP2890496B1 (en) * 2012-08-28 2021-04-28 Dow Global Technologies LLC Catalyst composition and reactivation process useful for alkane dehydrogenations
CN104919023B (zh) 2013-01-04 2016-08-24 沙特***石油公司 利用太阳辐射通过合成气制备单元将二氧化碳转化为烃类燃料
CN105683141A (zh) 2013-10-29 2016-06-15 沙特基础工业公司 合成气的二氧化碳加氢方法及该过程与合成气转化过程的结合
EP3080037A1 (en) 2013-11-11 2016-10-19 Saudi Basic Industries Corporation Method for hydrogenation of co2 in adiabatic metal reactors
CN106133118B (zh) 2014-04-03 2018-03-23 沙特基础工业公司 使用co2转化甲烷蒸汽重整合成气的方法
WO2015193817A1 (en) 2014-06-19 2015-12-23 Sabic Global Technologies B.V. Methods for determining the amount of steam required for regeneration of catalysts
WO2016027219A1 (en) 2014-08-21 2016-02-25 Sabic Global Technologies B.V. Systems and methods for dehydrogenation of alkanes
CN105622344A (zh) * 2014-11-03 2016-06-01 中国石油化工股份有限公司 一种二氧化碳加氢合成甲醇的工艺方法
FR3029533B1 (fr) 2014-12-08 2017-05-12 Commissariat Energie Atomique Procede de gazeification de charge de matiere carbonee a rendement matiere et cout de production optimises
WO2017003014A1 (ko) * 2015-06-30 2017-01-05 한국화학연구원 환원가스 전처리 후 연속 반응-재생 및 유동식 올레핀 제조방법
WO2017074843A1 (en) * 2015-10-30 2017-05-04 Sabic Global Technologies B.V. Low temperature methods for hydrogenation of co2 for production of syngas compositions with low h2/co ratios
WO2017072649A1 (en) 2015-10-30 2017-05-04 Sabic Global Technologies B.V. Methods and systems for producing syngas from carbon dioxide and hydrogen
WO2017077421A1 (en) 2015-11-03 2017-05-11 Sabic Global Technologies B.V. Process and system for producing syngas from carbon dioxide and hydrogen
WO2017085593A2 (en) * 2015-11-16 2017-05-26 Sabic Global Technologies B.V. High temperature methods for hydrogenation of co2 to syngas for production of olefins
WO2017089937A2 (en) * 2015-11-24 2017-06-01 Sabic Global Technologies B.V. Systems and methods for producing c2 hydrocarbons and steam from the oxidative coupling of methane
WO2017141143A1 (en) * 2016-02-16 2017-08-24 Sabic Global Technologies B.V. Conversion of methane steam reforming gas composition with co2 for the production of syngas composition for oxosynthesis
WO2017141138A1 (en) * 2016-02-16 2017-08-24 Sabic Global Technologies B.V. Conversion of adjusted methane steam reforming gas composition with co2 for the production of syngas composition for oxo-synthesis
WO2018015829A1 (en) * 2016-07-18 2018-01-25 Sabic Global Technologies B.V. Process for high-pressure hydrogenation of carbon dioxide to syngas applicable for methanol synthesis
WO2018015828A1 (en) * 2016-07-18 2018-01-25 Sabic Global Technologies B.V. Process for high-pressure hydrogenation of carbon dioxide to syngas in the presence of used chromium oxide supported catalysts
WO2018015824A1 (en) * 2016-07-18 2018-01-25 Sabic Global Technologies B.V. Process for high-pressure hydrogenation of carbon dioxide to syngas in the presence of a copper/zinc/zirconium mixed metal oxide catalyst
WO2018020345A1 (en) * 2016-07-25 2018-02-01 Sabic Global Technologies B.V. Process for producing oxo-synthesis syngas composition by high-pressure hydrogenation of c02 over spent chromium oxide/aluminum catalyst
WO2018020343A1 (en) * 2016-07-25 2018-02-01 Sabic Global Technologies B.V. Process for producing an oxo-synthesis syngas composition by high-pressure hydrogenation over a chromium oxide/aluminum supported catalyst
KR20200142544A (ko) * 2018-04-13 2020-12-22 할도르 토프쉐 에이/에스 하이드로포밀화 반응에서 사용하기 위한 합성 가스의 생성 방법
CN108794298B (zh) * 2018-06-29 2020-12-25 厦门大学 一种低温合成甲醇的方法
SE542646C2 (en) 2018-08-16 2020-06-23 Rise Res Institutes Of Sweden Ab Concept for the production of food with reduced environmental impact
EP3770145A1 (en) 2019-07-24 2021-01-27 Basf Se A process for the continuous production of either acrolein or acrylic acid as the target product from propene
AU2020353700A1 (en) 2019-09-27 2022-03-31 Oxy Low Carbon Ventures, Llc Process for the conversion of carbon dioxide
US11591226B1 (en) 2020-08-25 2023-02-28 Advanced Energy Materials, Llc Plasma assisted distributed chemical production
CN115231520B (zh) * 2021-04-25 2023-07-28 中国石油大学(北京) 一种钢铁冶炼方法
US20220348472A1 (en) * 2021-05-03 2022-11-03 Infinium Technology, Llc Catalytic reactor system and catalyst for conversion of captured c02 and renewable h2 into low-carbon syngas

Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6833013B1 (en) * 2000-01-13 2004-12-21 Snamprogetti S.P.A. Process for the production of synthesis gas

Family Cites Families (10)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
GB335632A (en) * 1929-07-02 1930-10-02 British Celanese Improvements in or relating to the treatment of mixtures containing carbon dioxide and hydrogen for the purpose of reducing or eliminating hydrogen content, and to the formation of carbon monoxide therefrom
US4098809A (en) * 1972-12-20 1978-07-04 Snamprogetti S.P.A. Process for the production of dimethyl ether
GB2168718B (en) 1984-10-29 1988-06-29 Humphreys & Glasgow Ltd Process for the production of synthesis gas and its utilisation
US4581339A (en) * 1985-03-18 1986-04-08 Air Products And Chemicals, Inc. Catalytic dehydrogenation reactor cycle
JP2847018B2 (ja) 1993-06-25 1999-01-13 株式会社コスモ総合研究所 二酸化炭素還元反応触媒
KR0138587B1 (ko) 1994-08-19 1998-05-01 김은영 새로운 메탄올 합성방법
JPH10273452A (ja) * 1997-03-31 1998-10-13 Idemitsu Petrochem Co Ltd アルキル芳香族炭化水素の脱水素反応用触媒およびその製造方法ならびにこれを用いたビニル芳香族炭化水素の製造方法
JP2000037629A (ja) * 1998-07-24 2000-02-08 Chiyoda Corp 脱水素触媒
FR2806073B1 (fr) * 2000-03-07 2002-06-07 Air Liquide Procede de production de monoxyde de carbone par retroconversion inverse avec un catalyseur adapte
KR100555294B1 (ko) * 2003-09-17 2006-03-03 한국과학기술연구원 역수성가스 반응을 이용한 디메틸에테르의 제조방법

Patent Citations (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US6833013B1 (en) * 2000-01-13 2004-12-21 Snamprogetti S.P.A. Process for the production of synthesis gas

Non-Patent Citations (4)

* Cited by examiner, † Cited by third party
Title
AILING SUN ET AL.: "ETHYLBENZENE DEHYDROGENATION IN THE PRESENCE OF CARBON DIOXIDE OVER ALUMINA SUPPORTED CATALYSTS" CATALYSIS TODAY, 1 September 2004 (2004-09-01), pages 273-279, XP002532686 see page 273, right column, lines 1-7, see page 276, left column, lines 3-5. see page 279, right column, lines 3-6 *
BADSTUBE T. ET AL.: "SCREENING OF CATALYSTS IN THE OXIDATIVE DEHYDROGENATION OF ETHYLBENZENE WITH CARBON DIOXIDE" APPLIED CATALYSIS A: GENERAL, vol. 204, 1 June 2000 (2000-06-01), pages 153-165, XP002532687 see page 154, left column, last 16 lines, see page 154, right column, entire point 2.1, see point 3.1 at page 155, lines 1-9, see figure 1(a), see page 161, right column, lines 3-6 *
HOWARD. F. RASE: "HANDBOOK OF COMMERCIAL CATALYSTS HETEROGENEOUS CATALYSTS" 1998, XP002532689, see entire point 19.2.2 at pages 405 and 406, see in particular page 406 "shift reaction" *
YOSHIHIRO SAKURAI: "DEHYDROGENATION OF ETHYLBENZENE WITH AN ACTIVATED CARBON-SUPPORTED VANADIUM CATALYST" APPLIED CATALYSTIS A: GENERAL, vol. 192, 1 June 2000 (2000-06-01), pages 281-288, XP002532688, see table 1, see page 284, left column, lines 7-9 *

Also Published As

Publication number Publication date
EA201000055A1 (ru) 2010-04-30
WO2009000494A3 (en) 2009-10-01
EP2175986A2 (en) 2010-04-21
US8288446B2 (en) 2012-10-16
EA016496B1 (ru) 2012-05-30
WO2009000494A2 (en) 2008-12-31
US20100105962A1 (en) 2010-04-29
JP5411133B2 (ja) 2014-02-12
JP2010531221A (ja) 2010-09-24
CN101687633A (zh) 2010-03-31
CN104192794A (zh) 2014-12-10

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