DE69503309T2 - Formkörper mit einer Markierung auf einem thermoplastischen Substrat und Verfahren zum Herstellen der Formkörper - Google Patents
Formkörper mit einer Markierung auf einem thermoplastischen Substrat und Verfahren zum Herstellen der FormkörperInfo
- Publication number
- DE69503309T2 DE69503309T2 DE69503309T DE69503309T DE69503309T2 DE 69503309 T2 DE69503309 T2 DE 69503309T2 DE 69503309 T DE69503309 T DE 69503309T DE 69503309 T DE69503309 T DE 69503309T DE 69503309 T2 DE69503309 T2 DE 69503309T2
- Authority
- DE
- Germany
- Prior art keywords
- weight
- parts
- synthetic material
- thermoplastic synthetic
- agent
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
- 229920001169 thermoplastic Polymers 0.000 title claims abstract description 46
- 239000004416 thermosoftening plastic Substances 0.000 title claims abstract description 45
- 239000000758 substrate Substances 0.000 title claims abstract description 9
- 238000004519 manufacturing process Methods 0.000 title description 2
- 229920002994 synthetic fiber Polymers 0.000 claims abstract description 34
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 26
- 238000004132 cross linking Methods 0.000 claims abstract description 9
- 238000005187 foaming Methods 0.000 claims abstract description 9
- XECAHXYUAAWDEL-UHFFFAOYSA-N acrylonitrile butadiene styrene Chemical compound C=CC=C.C=CC#N.C=CC1=CC=CC=C1 XECAHXYUAAWDEL-UHFFFAOYSA-N 0.000 claims description 14
- 229920000122 acrylonitrile butadiene styrene Polymers 0.000 claims description 14
- 239000004676 acrylonitrile butadiene styrene Substances 0.000 claims description 14
- 229920000642 polymer Polymers 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 7
- 229920001451 polypropylene glycol Polymers 0.000 claims description 7
- -1 tetrazole compounds Chemical class 0.000 claims description 7
- 229920000877 Melamine resin Polymers 0.000 claims description 6
- JDSHMPZPIAZGSV-UHFFFAOYSA-N melamine Chemical group NC1=NC(N)=NC(N)=N1 JDSHMPZPIAZGSV-UHFFFAOYSA-N 0.000 claims description 5
- PAPBSGBWRJIAAV-UHFFFAOYSA-N ε-Caprolactone Chemical compound O=C1CCCCCO1 PAPBSGBWRJIAAV-UHFFFAOYSA-N 0.000 claims description 4
- HGTUJZTUQFXBIH-UHFFFAOYSA-N (2,3-dimethyl-3-phenylbutan-2-yl)benzene Chemical group C=1C=CC=CC=1C(C)(C)C(C)(C)C1=CC=CC=C1 HGTUJZTUQFXBIH-UHFFFAOYSA-N 0.000 claims description 2
- 125000000751 azo group Chemical group [*]N=N[*] 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 238000000354 decomposition reaction Methods 0.000 claims description 2
- 150000002832 nitroso derivatives Chemical class 0.000 claims description 2
- 239000002245 particle Substances 0.000 claims description 2
- 125000000472 sulfonyl group Chemical group *S(*)(=O)=O 0.000 claims description 2
- 238000005299 abrasion Methods 0.000 abstract description 12
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 8
- 239000000203 mixture Substances 0.000 description 8
- 239000000126 substance Substances 0.000 description 6
- 238000012360 testing method Methods 0.000 description 5
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 229920001971 elastomer Polymers 0.000 description 4
- 239000008187 granular material Substances 0.000 description 4
- 239000005060 rubber Substances 0.000 description 4
- 239000004114 Ammonium polyphosphate Substances 0.000 description 3
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- 235000019826 ammonium polyphosphate Nutrition 0.000 description 3
- 229920001276 ammonium polyphosphate Polymers 0.000 description 3
- 229920000578 graft copolymer Polymers 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 230000005855 radiation Effects 0.000 description 3
- 229920002554 vinyl polymer Polymers 0.000 description 3
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- 239000004952 Polyamide Substances 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- 239000006229 carbon black Substances 0.000 description 2
- 238000000576 coating method Methods 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229920001577 copolymer Polymers 0.000 description 2
- 238000012936 correction and preventive action Methods 0.000 description 2
- 239000006260 foam Substances 0.000 description 2
- 238000001746 injection moulding Methods 0.000 description 2
- 239000000463 material Substances 0.000 description 2
- 229920002647 polyamide Polymers 0.000 description 2
- 229920002857 polybutadiene Polymers 0.000 description 2
- 229920000515 polycarbonate Polymers 0.000 description 2
- 239000004417 polycarbonate Substances 0.000 description 2
- 150000003254 radicals Chemical group 0.000 description 2
- 239000004408 titanium dioxide Substances 0.000 description 2
- JLBJTVDPSNHSKJ-UHFFFAOYSA-N 4-Methylstyrene Chemical compound CC1=CC=C(C=C)C=C1 JLBJTVDPSNHSKJ-UHFFFAOYSA-N 0.000 description 1
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 description 1
- NLHHRLWOUZZQLW-UHFFFAOYSA-N Acrylonitrile Chemical compound C=CC#N NLHHRLWOUZZQLW-UHFFFAOYSA-N 0.000 description 1
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 1
- 229920000459 Nitrile rubber Polymers 0.000 description 1
- 239000005062 Polybutadiene Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 125000005250 alkyl acrylate group Chemical group 0.000 description 1
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 description 1
- 150000001723 carbon free-radicals Chemical class 0.000 description 1
- 229910010293 ceramic material Inorganic materials 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 239000003431 cross linking reagent Substances 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000009863 impact test Methods 0.000 description 1
- 238000002347 injection Methods 0.000 description 1
- 239000007924 injection Substances 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Chemical compound OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- 238000010330 laser marking Methods 0.000 description 1
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 1
- 239000000155 melt Substances 0.000 description 1
- 229910052751 metal Inorganic materials 0.000 description 1
- 239000002184 metal Substances 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 238000006116 polymerization reaction Methods 0.000 description 1
- 230000000379 polymerizing effect Effects 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 230000000717 retained effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000007655 standard test method Methods 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 150000003440 styrenes Chemical class 0.000 description 1
- 229920002725 thermoplastic elastomer Polymers 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B41—PRINTING; LINING MACHINES; TYPEWRITERS; STAMPS
- B41M—PRINTING, DUPLICATING, MARKING, OR COPYING PROCESSES; COLOUR PRINTING
- B41M5/00—Duplicating or marking methods; Sheet materials for use therein
- B41M5/26—Thermography ; Marking by high energetic means, e.g. laser otherwise than by burning, and characterised by the material used
- B41M5/267—Marking of plastic artifacts, e.g. with laser
Landscapes
- Physics & Mathematics (AREA)
- Optics & Photonics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Vehicle Interior And Exterior Ornaments, Soundproofing, And Insulation (AREA)
- Treatments Of Macromolecular Shaped Articles (AREA)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
BE9400464A BE1008341A3 (nl) | 1994-05-04 | 1994-05-04 | Vormdeel met een markering op een ondergrond van een thermoplastische kunststof en een werkwijze voor de bereiding van het vormdeel. |
Publications (2)
Publication Number | Publication Date |
---|---|
DE69503309D1 DE69503309D1 (de) | 1998-08-13 |
DE69503309T2 true DE69503309T2 (de) | 1999-04-15 |
Family
ID=3888141
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
DE69503309T Expired - Fee Related DE69503309T2 (de) | 1994-05-04 | 1995-05-03 | Formkörper mit einer Markierung auf einem thermoplastischen Substrat und Verfahren zum Herstellen der Formkörper |
Country Status (4)
Country | Link |
---|---|
EP (1) | EP0680831B1 (fr) |
AT (1) | ATE168074T1 (fr) |
BE (1) | BE1008341A3 (fr) |
DE (1) | DE69503309T2 (fr) |
Families Citing this family (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5977514A (en) * | 1997-06-13 | 1999-11-02 | M.A. Hannacolor | Controlled color laser marking of plastics |
US5976411A (en) * | 1997-12-16 | 1999-11-02 | M.A. Hannacolor | Laser marking of phosphorescent plastic articles |
AU2003219936A1 (en) * | 2002-03-01 | 2003-09-16 | Markem Corporation | Marking substrates |
EP2110260A1 (fr) * | 2008-04-15 | 2009-10-21 | Gemalto SA | Support personnalisable comprenant des moyens d'antifalsification et procédé de fabrication d'un tel support. |
JP6897642B2 (ja) * | 2018-08-31 | 2021-07-07 | カシオ計算機株式会社 | 熱膨張性シート、熱膨張性シートの製造方法、造形物及び造形物の製造方法 |
Family Cites Families (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS60206845A (ja) * | 1984-03-30 | 1985-10-18 | Kanegafuchi Chem Ind Co Ltd | 発泡性熱可塑性共重合体粒子 |
JPH03167246A (ja) * | 1989-11-29 | 1991-07-19 | Nippon Oil Co Ltd | 樹脂組成物 |
JPH0489285A (ja) * | 1990-07-31 | 1992-03-23 | Sony Corp | 合成樹脂成形体への印字方法 |
JP3102818B2 (ja) * | 1992-04-16 | 2000-10-23 | 日本ジーイープラスチックス株式会社 | レーザーマーキング用樹脂組成物 |
NL9202096A (nl) * | 1992-12-02 | 1993-04-01 | Dsm Nv | Polymeersamenstelling, bevattende een polymeer en tenminste een stralingsgevoelig bestanddeel. |
-
1994
- 1994-05-04 BE BE9400464A patent/BE1008341A3/nl not_active IP Right Cessation
-
1995
- 1995-05-03 EP EP95201142A patent/EP0680831B1/fr not_active Expired - Lifetime
- 1995-05-03 AT AT95201142T patent/ATE168074T1/de not_active IP Right Cessation
- 1995-05-03 DE DE69503309T patent/DE69503309T2/de not_active Expired - Fee Related
Also Published As
Publication number | Publication date |
---|---|
BE1008341A3 (nl) | 1996-04-02 |
EP0680831B1 (fr) | 1998-07-08 |
ATE168074T1 (de) | 1998-07-15 |
DE69503309D1 (de) | 1998-08-13 |
EP0680831A1 (fr) | 1995-11-08 |
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Legal Events
Date | Code | Title | Description |
---|---|---|---|
8364 | No opposition during term of opposition | ||
8327 | Change in the person/name/address of the patent owner |
Owner name: DSM IP ASSETS B.V., HEERLEN, NL |
|
8339 | Ceased/non-payment of the annual fee |