DE69302287T2 - Erniedrigung des Benzolgehaltes von Benzinen durch Isomerisierung - Google Patents

Erniedrigung des Benzolgehaltes von Benzinen durch Isomerisierung

Info

Publication number: DE69302287T2
Authority: DE; Germany
Prior art keywords: isomerization; inclusive; fraction; catalyst; benzene
Prior art date: 1992-01-15
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

DE69302287T

Other languages

German (de)

English (en)

Other versions

DE69302287D1 (de

Inventor

Jean-Marie Deves

Christian Marcilly

Patrick Sarrazin

Christine Travers

Philippe Travers

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

IFP Energies Nouvelles IFPEN

Original Assignee

IFP Energies Nouvelles IFPEN

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1992-01-15

Filing date

1993-01-07

Publication date

1996-09-12

1993-01-07 Application filed by IFP Energies Nouvelles IFPEN filed Critical IFP Energies Nouvelles IFPEN

1996-05-30 Publication of DE69302287D1 publication Critical patent/DE69302287D1/de

1996-09-12 Application granted granted Critical

1996-09-12 Publication of DE69302287T2 publication Critical patent/DE69302287T2/de

2013-01-08 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 title claims description 57
238000006317 isomerization reaction Methods 0.000 title claims description 33
238000000034 method Methods 0.000 claims description 20
239000003054 catalyst Substances 0.000 claims description 14
238000004821 distillation Methods 0.000 claims description 13
BASFCYQUMIYNBI-UHFFFAOYSA-N platinum Chemical compound [Pt] BASFCYQUMIYNBI-UHFFFAOYSA-N 0.000 claims description 12
239000000203 mixture Substances 0.000 claims description 11
PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 claims description 6
KDLHZDBZIXYQEI-UHFFFAOYSA-N Palladium Chemical compound [Pd] KDLHZDBZIXYQEI-UHFFFAOYSA-N 0.000 claims description 6
229910052680 mordenite Inorganic materials 0.000 claims description 6
229910052697 platinum Inorganic materials 0.000 claims description 6
UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 5
229910052739 hydrogen Inorganic materials 0.000 claims description 5
239000001257 hydrogen Substances 0.000 claims description 5
229910052751 metal Inorganic materials 0.000 claims description 5
239000002184 metal Substances 0.000 claims description 5
229910052759 nickel Inorganic materials 0.000 claims description 3
229910052763 palladium Inorganic materials 0.000 claims description 3
TVMXDCGIABBOFY-UHFFFAOYSA-N octane Chemical compound CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 13
238000002407 reforming Methods 0.000 description 10
229930195733 hydrocarbon Natural products 0.000 description 6
150000002430 hydrocarbons Chemical class 0.000 description 6
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 5
239000010457 zeolite Substances 0.000 description 5
229910021536 Zeolite Inorganic materials 0.000 description 4
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 4
239000004215 Carbon black (E152) Substances 0.000 description 3
238000001833 catalytic reforming Methods 0.000 description 3
238000007142 ring opening reaction Methods 0.000 description 3
230000006641 stabilisation Effects 0.000 description 3
238000011105 stabilization Methods 0.000 description 3
ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 2
UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
239000000460 chlorine Substances 0.000 description 2
229910052801 chlorine Inorganic materials 0.000 description 2
239000010779 crude oil Substances 0.000 description 2
238000005984 hydrogenation reaction Methods 0.000 description 2
239000005995 Aluminium silicate Substances 0.000 description 1
DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
-1 Pentane Dimethylpentane Methylpentane Hexane Heptane Cyclopentane Methylcyclopentane Cyclohexane Chemical compound 0.000 description 1
238000010521 absorption reaction Methods 0.000 description 1
239000002253 acid Substances 0.000 description 1
235000012211 aluminium silicate Nutrition 0.000 description 1
238000005349 anion exchange Methods 0.000 description 1
150000001491 aromatic compounds Chemical class 0.000 description 1
VBEKGXAPCZTFJW-UHFFFAOYSA-N benzene;octane Chemical compound C1=CC=CC=C1.CCCCCCCC VBEKGXAPCZTFJW-UHFFFAOYSA-N 0.000 description 1
230000015572 biosynthetic process Effects 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
238000005341 cation exchange Methods 0.000 description 1
238000006243 chemical reaction Methods 0.000 description 1
150000001875 compounds Chemical class 0.000 description 1
125000000753 cycloalkyl group Chemical group 0.000 description 1
230000006378 damage Effects 0.000 description 1
238000006356 dehydrogenation reaction Methods 0.000 description 1
239000008298 dragée Substances 0.000 description 1
230000000694 effects Effects 0.000 description 1
230000007613 environmental effect Effects 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 1
239000007788 liquid Substances 0.000 description 1
239000011159 matrix material Substances 0.000 description 1
PIBWKRNGBLPSSY-UHFFFAOYSA-L palladium(II) chloride Chemical compound Cl[Pd]Cl PIBWKRNGBLPSSY-UHFFFAOYSA-L 0.000 description 1
239000012188 paraffin wax Substances 0.000 description 1
238000005453 pelletization Methods 0.000 description 1
230000008707 rearrangement Effects 0.000 description 1
238000000926 separation method Methods 0.000 description 1
229910052708 sodium Inorganic materials 0.000 description 1
239000011734 sodium Substances 0.000 description 1
239000007787 solid Substances 0.000 description 1
AGGKEGLBGGJEBZ-UHFFFAOYSA-N tetramethylenedisulfotetramine Chemical compound C1N(S2(=O)=O)CN3S(=O)(=O)N1CN2C3 AGGKEGLBGGJEBZ-UHFFFAOYSA-N 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
- C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
- C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
- C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
- C—CHEMISTRY; METALLURGY
- C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
- C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
- C10G2400/02—Gasoline

Landscapes

Chemical & Material Sciences (AREA)
Oil, Petroleum & Natural Gas (AREA)
Crystallography & Structural Chemistry (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
General Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Catalysts (AREA)
Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)

DE69302287T 1992-01-15 1993-01-07 Erniedrigung des Benzolgehaltes von Benzinen durch Isomerisierung Expired - Fee Related DE69302287T2 (de)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
FR9200436A FR2686095B1 (fr)	1992-01-15	1992-01-15	Production de base pour carburant exempt de benzene, presentant un indice d'octane eleve.

Publications (2)

Publication Number	Publication Date
DE69302287D1 DE69302287D1 (de)	1996-05-30
DE69302287T2 true DE69302287T2 (de)	1996-09-12

Family

ID=9425704

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
DE69302287T Expired - Fee Related DE69302287T2 (de)	1992-01-15	1993-01-07	Erniedrigung des Benzolgehaltes von Benzinen durch Isomerisierung

Country Status (9)

Country	Link
EP (1)	EP0552069B1 (zh)
KR (1)	KR930016525A (zh)
CA (1)	CA2087384A1 (zh)
DE (1)	DE69302287T2 (zh)
ES (1)	ES2089739T3 (zh)
FR (1)	FR2686095B1 (zh)
MY (1)	MY109121A (zh)
RU (1)	RU2091441C1 (zh)
TW (1)	TW238298B (zh)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
FR2714305B1 (fr) *	1993-12-29	1996-02-02	Inst Francais Du Petrole	Catalyseur pour la réduction de la teneur en benzène dans les essences.
FR2743079B1 (fr) *	1995-12-27	1998-02-06	Inst Francais Du Petrole	Procede et dispositif d'hydrogenation selective par distillation catalytique comportant une zone reactionnelle a co-courant ascendant liquide-gaz
FR2743080B1 (fr) *	1995-12-27	1998-02-06	Inst Francais Du Petrole	Procede de reduction selective de la teneur en benzene et en composes insatures legers d'une coupe d'hydrocarbures
US5830345A (en) *	1996-02-28	1998-11-03	Chinese Petroleum Corporation	Process of producing a debenzenated and isomerized gasoline blending stock by using a dual functional catalyst
FR2948380B1 (fr) *	2009-07-21	2011-08-12	Inst Francais Du Petrole	Procede de reduction selective de la teneur en benzene et en composes insatures legers de differentes coupes hydrocarbures
EP2277980B1 (fr) *	2009-07-21	2018-08-08	IFP Energies nouvelles	Procédé de réduction sélective de la teneur en benzène et en composés insatures legers de differentes coupes hydrocarbures
US8808533B2 (en) *	2010-04-23	2014-08-19	IFP Energies Nouvelles	Process for selective reduction of the contents of benzene and light unsaturated compounds of different hydrocarbon fractions
CN103464210B (zh) *	2013-09-27	2015-07-22	凯瑞环保科技股份有限公司	一种轻烃异构化催化剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
CA975384A (en) *	1971-04-19	1975-09-30	Graham K. Hilder	Isomerisation of paraffin hydrocarbons
US4457832A (en) *	1983-01-19	1984-07-03	Chevron Research Company	Combination catalytic reforming-isomerization process for upgrading naphtha
FR2579906B1 (zh) *	1985-04-05	1987-05-15	Inst Francais Du Petrole
US5003118A (en) *	1989-12-29	1991-03-26	Uop	Isomerization of benzene-containing feedstocks

1992
- 1992-01-15 FR FR9200436A patent/FR2686095B1/fr not_active Expired - Fee Related
1993
- 1993-01-07 ES ES93400020T patent/ES2089739T3/es not_active Expired - Lifetime
- 1993-01-07 EP EP93400020A patent/EP0552069B1/fr not_active Expired - Lifetime
- 1993-01-07 DE DE69302287T patent/DE69302287T2/de not_active Expired - Fee Related
- 1993-01-14 MY MYPI93000060A patent/MY109121A/en unknown
- 1993-01-14 KR KR1019930000407A patent/KR930016525A/ko active IP Right Grant
- 1993-01-14 RU RU9393004431A patent/RU2091441C1/ru active
- 1993-01-15 CA CA002087384A patent/CA2087384A1/fr not_active Abandoned
- 1993-01-18 TW TW082100291A patent/TW238298B/zh active

Also Published As

Publication number	Publication date
RU2091441C1 (ru)	1997-09-27
FR2686095A1 (fr)	1993-07-16
DE69302287D1 (de)	1996-05-30
EP0552069B1 (fr)	1996-04-24
TW238298B (zh)	1995-01-11
FR2686095B1 (fr)	1994-04-29
MY109121A (en)	1996-12-31
KR930016525A (ko)	1993-08-26
EP0552069A1 (fr)	1993-07-21
CA2087384A1 (fr)	1993-07-16
ES2089739T3 (es)	1996-10-01

Legal Events

Date	Code	Title	Description
1997-05-22	8364	No opposition during term of opposition
2004-01-29	8328	Change in the person/name/address of the agent	Representative=s name: VONNEMANN, KLOIBER & KOLLEGEN, 80796 MUENCHEN
2004-11-11	8339	Ceased/non-payment of the annual fee

Publication	Publication Date	Title
DE2526887C2 (de)	1986-09-18	Verfahren zur Herstellung von aromatischen Kohlenwasserstoffen
DE69423881T2 (de)	2000-12-07	Benzolreduktion in benzin durch alkylierung mit höheren olefinen
DE68909819T2 (de)	1994-02-24	Verfahren zur Reformierung einer Kohlenwasserstofffraktion mit limitiertem C9+-Gehalt.
DE69128241T2 (de)	1998-03-12	Kombinationsverfahren zur Hydrierung und Isomerierung von Benzol und Paraffinen enthaltenden Einsätzen
DE69218616T2 (de)	1997-07-03	Kombiniertes paraffinisomerisierungs-/ringöffnungs-verfahren
DD281968A5 (de)	1990-08-29	Katalysatorzusammensetzung fuer die umwandlung von kohlenwasserstoffen
DE2320223C2 (de)	1982-04-22	Verfahren zur Isomerisierung von aliphatischen Kohlenwasserstoffen
DE2526888A1 (de)	1976-03-18	Verfahren zur gleichzeitigen herstellung von benzin und aromatischen verbindungen chemischer reinheit mit 8 oder weniger kohlenstoffatomen
DE1234902B (de)	1967-02-23	Kontinuierliches Kohlenwasserstoffumwandlungsverfahren
DE2934460A1 (de)	1980-03-20	Verfahren zur herstellung von kohlenwasserstoffen mit einer motoroktanzahl von ueber etwa 78
DE3781528T2 (de)	1993-04-15	Verfahren zur oktanzahlsteigerung und zur verringerung des schwefelgehaltes von olefinischen benzinen.
DE2162442A1 (de)	1972-07-27	Katalytisches Reformierverfahren
DE2148121A1 (de)	1972-04-06	Verfahren zum katalytischen Cracken von Naphtha
DE69419240T2 (de)	1999-10-21	Katalysator zur Erniedrigung des Benzolgehaltes von Benzinen
DE2326834A1 (de)	1973-12-06	Verfahren zur verarbeitung von kohlenwasserstoffnaphtha zu einem fluessigen produkt mit einem hohen aromatengehalt
DE69302287T2 (de)	1996-09-12	Erniedrigung des Benzolgehaltes von Benzinen durch Isomerisierung
DE69326030T2 (de)	2000-01-05	Erniedrigung des Benzolgehaltes von Benzinen
DE69417607T2 (de)	1999-10-14	Verfahren zur Herstellung von Benzin mit hoher Oktanzahl
DE69424028T2 (de)	2000-09-14	Katalysator zur Erniedrigung des Benzolgehaltes von Benzinen
DE69117936T2 (de)	1996-08-08	Katalysator auf basis von chloriertem eta-aluminiumoxid und dessen verwendung zur isomerisierung von c4-c6 n-paraffinen
DE69204206T2 (de)	1996-02-01	Hydrodeziklierungsverfahren.
DE1770019A1 (de)	1971-09-16	Verfahren zur Hydrierung von Aromaten
DE69837351T2 (de)	2008-04-10	Dehydrocyklizierungsverfahren mit abwärts strömender entfernung von dimethylbutan
DE69309729T2 (de)	1997-09-18	Verfahren zur Aufarbeitung eines Kohlenwasserstoffeinsatzes
DE2239282B2 (de)	1975-01-16	Verfahren zur gleichzeitigen Herstellung eines Aromatenkonzentrates und eines Isobutankonzentrates