KR930016525A - 가솔린의 벤젠 함량을 감소시키는 방법 - Google Patents

가솔린의 벤젠 함량을 감소시키는 방법 Download PDF

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Publication number
KR930016525A
KR930016525A KR1019930000407A KR930000407A KR930016525A KR 930016525 A KR930016525 A KR 930016525A KR 1019930000407 A KR1019930000407 A KR 1019930000407A KR 930000407 A KR930000407 A KR 930000407A KR 930016525 A KR930016525 A KR 930016525A
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KR
South Korea
Prior art keywords
charge
weight
isomerizing
benzene content
group viii
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KR1019930000407A
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English (en)
Inventor
크리스띤 뜨라버스
빠뜨릭 사라젱
장-마리 데브
크리스띠앙 마르실리
필립 뜨라버스
Original Assignee
프랑소와 앙드레프
앵스띠뛰 프랑세 뒤 뻬뜨롤
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Application filed by 프랑소와 앙드레프, 앵스띠뛰 프랑세 뒤 뻬뜨롤 filed Critical 프랑소와 앙드레프
Publication of KR930016525A publication Critical patent/KR930016525A/ko

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G45/00—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
    • C10G45/58—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins
    • C10G45/60—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used
    • C10G45/64—Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds to change the structural skeleton of some of the hydrocarbon content without cracking the other hydrocarbons present, e.g. lowering pour point; Selective hydrocracking of normal paraffins characterised by the catalyst used containing crystalline alumino-silicates, e.g. molecular sieves
    • C—CHEMISTRY; METALLURGY
    • C10—PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10G—CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
    • C10G2400/00—Products obtained by processes covered by groups C10G9/00 - C10G69/14
    • C10G2400/02—Gasoline

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
  • Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
  • Catalysts (AREA)

Abstract

본 발명은 (a)40내지 80중량%의 파라핀, 0.5내지 7중량%의 나프텐 및 6내지 45중량%의 방향족 탄화수소의 범위내의 중량 조성과 70내지 90℃의 최대 증류 온도를 특징으로 장입물 및 (b)C5-C6증류 분류물의 혼합물을 이성화 촉매의 존재하에 이성화시키는 벤젠 함량을 감소시키는 방법 및 파라핀을 이성화시키는 방법에 관한 것이다.

Description

가솔린의 벤젠 함량을 감소시키는 방법
본 내용은 요부공개 건이므로 전문내용을 수록하지 않았음

Claims (6)

  1. (a)40내지 80중량%의 파라핀, 0.5내지 7중량%의 나프텐 및 6내지 45중량%의 방향족 탄화수소의 범위내의 중량 조성과 70내지 90℃의 최대 증류 온도를 특징으로 장입물 및 (b)C5-C6분류물의 혼합물을 이성화 촉매의 존재하에 이성화시키는 벤젠 함량을 감소시키는 방법 및 파라핀을 이성화시키는 방법.
  2. 제1항에 있어서, 상가 혼합물이 20내지 80%의 상기 장입물을 포함하는 방법.
  3. 제1항 및 제2항에 있어서, 상기 이성화 촉매가 5내지 50의 Si/Al의 비를 갖는 모르데나이트 및 VⅢ족 금속중 적어도 하나의 금속을 포함하는 방법.
  4. 제3항에 있어서, 상기 VⅢ족 금속이 백금, 팔라듐 및 니켈중에서 선택되는 방법.
  5. 제1항 내지 제4항 중 어느 한 항에 있어서, 150내지 300℃의 온도, 대기압 내지 70bar의 수소 분압, 촉매 1ℓ당 1시간당 0.2내지 10ℓ의 장입물의 액체 시간당 공간 속도 및 0.5내지 10의 수소 대 장입물의 몰비의 실시 조건하에서 상기 이성화 반응을 실시하는 방법.
  6. 제1항 내지 제5항 중 어느 한 항에 있어서, 상기 분류물이 증류로 직접 생성된 C5-C6분류물인 방법.
    ※ 참고사항 : 최초출원 내용에 의하여 공개하는 것임.
KR1019930000407A 1992-01-15 1993-01-14 가솔린의 벤젠 함량을 감소시키는 방법 KR930016525A (ko)

Applications Claiming Priority (2)

Application Number Priority Date Filing Date Title
FR92004360 1992-01-15
FR9200436A FR2686095B1 (fr) 1992-01-15 1992-01-15 Production de base pour carburant exempt de benzene, presentant un indice d'octane eleve.

Publications (1)

Publication Number Publication Date
KR930016525A true KR930016525A (ko) 1993-08-26

Family

ID=9425704

Family Applications (1)

Application Number Title Priority Date Filing Date
KR1019930000407A KR930016525A (ko) 1992-01-15 1993-01-14 가솔린의 벤젠 함량을 감소시키는 방법

Country Status (9)

Country Link
EP (1) EP0552069B1 (ko)
KR (1) KR930016525A (ko)
CA (1) CA2087384A1 (ko)
DE (1) DE69302287T2 (ko)
ES (1) ES2089739T3 (ko)
FR (1) FR2686095B1 (ko)
MY (1) MY109121A (ko)
RU (1) RU2091441C1 (ko)
TW (1) TW238298B (ko)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
FR2714305B1 (fr) * 1993-12-29 1996-02-02 Inst Francais Du Petrole Catalyseur pour la réduction de la teneur en benzène dans les essences.
FR2743079B1 (fr) * 1995-12-27 1998-02-06 Inst Francais Du Petrole Procede et dispositif d'hydrogenation selective par distillation catalytique comportant une zone reactionnelle a co-courant ascendant liquide-gaz
FR2743080B1 (fr) * 1995-12-27 1998-02-06 Inst Francais Du Petrole Procede de reduction selective de la teneur en benzene et en composes insatures legers d'une coupe d'hydrocarbures
US5830345A (en) * 1996-02-28 1998-11-03 Chinese Petroleum Corporation Process of producing a debenzenated and isomerized gasoline blending stock by using a dual functional catalyst
US8808533B2 (en) * 2010-04-23 2014-08-19 IFP Energies Nouvelles Process for selective reduction of the contents of benzene and light unsaturated compounds of different hydrocarbon fractions
EP2277980B1 (fr) * 2009-07-21 2018-08-08 IFP Energies nouvelles Procédé de réduction sélective de la teneur en benzène et en composés insatures legers de differentes coupes hydrocarbures
FR2948380B1 (fr) * 2009-07-21 2011-08-12 Inst Francais Du Petrole Procede de reduction selective de la teneur en benzene et en composes insatures legers de differentes coupes hydrocarbures
CN103464210B (zh) * 2013-09-27 2015-07-22 凯瑞环保科技股份有限公司 一种轻烃异构化催化剂及其制备方法

Family Cites Families (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CA975384A (en) * 1971-04-19 1975-09-30 Graham K. Hilder Isomerisation of paraffin hydrocarbons
US4457832A (en) * 1983-01-19 1984-07-03 Chevron Research Company Combination catalytic reforming-isomerization process for upgrading naphtha
FR2579906B1 (ko) * 1985-04-05 1987-05-15 Inst Francais Du Petrole
US5003118A (en) * 1989-12-29 1991-03-26 Uop Isomerization of benzene-containing feedstocks

Also Published As

Publication number Publication date
TW238298B (ko) 1995-01-11
CA2087384A1 (fr) 1993-07-16
ES2089739T3 (es) 1996-10-01
DE69302287D1 (de) 1996-05-30
RU2091441C1 (ru) 1997-09-27
EP0552069B1 (fr) 1996-04-24
FR2686095A1 (fr) 1993-07-16
EP0552069A1 (fr) 1993-07-21
DE69302287T2 (de) 1996-09-12
MY109121A (en) 1996-12-31
FR2686095B1 (fr) 1994-04-29

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