CS378589A3 - Process for preparing mixture of linear and cyclic alkyl aluminooxanes - Google Patents

Process for preparing mixture of linear and cyclic alkyl aluminooxanes Download PDF

Info

Publication number: CS378589A3
Authority: CS; Czechoslovakia
Prior art keywords: aluminum; reaction; added; alumoxane; solution
Prior art date: 1988-06-22

Application number

CS893785A

Other languages

Czech (cs)

English (en)

Inventor

Howard Curtis Welborn Jr

Original Assignee

Exxon Chemical Patents Inc

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1988-06-22

Filing date

1989-06-22

Publication date

1992-11-18

1988-06-23 Priority claimed from US07/210,881 external-priority patent/USH1510H/en

1989-06-22 Application filed by Exxon Chemical Patents Inc filed Critical Exxon Chemical Patents Inc

1992-11-18 Publication of CS378589A3 publication Critical patent/CS378589A3/cs

Links

239000000203 mixture Substances 0.000 title claims description 8
238000004519 manufacturing process Methods 0.000 title description 12
YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 47
238000000034 method Methods 0.000 claims description 27
230000008569 process Effects 0.000 claims description 22
-1 allyl aluminum Chemical compound 0.000 claims description 16
125000005234 alkyl aluminium group Chemical group 0.000 claims description 12
150000001875 compounds Chemical class 0.000 claims description 10
QVRPRGWIJQKENN-UHFFFAOYSA-N 2,4,6-triethyl-1,3,5,2,4,6-trioxatriborinane Chemical compound CCB1OB(CC)OB(CC)O1 QVRPRGWIJQKENN-UHFFFAOYSA-N 0.000 claims description 9
BRTALTYTFFNPAC-UHFFFAOYSA-N boroxin Chemical compound B1OBOBO1 BRTALTYTFFNPAC-UHFFFAOYSA-N 0.000 claims description 9
JLTRXTDYQLMHGR-UHFFFAOYSA-N trimethylaluminium Chemical group C[Al](C)C JLTRXTDYQLMHGR-UHFFFAOYSA-N 0.000 claims description 9
229910052782 aluminium Inorganic materials 0.000 claims description 8
229930195733 hydrocarbon Natural products 0.000 claims description 7
150000002430 hydrocarbons Chemical class 0.000 claims description 7
238000002360 preparation method Methods 0.000 claims description 7
239000004215 Carbon black (E152) Substances 0.000 claims description 6
IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 6
XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 6
VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 claims description 6
239000002904 solvent Substances 0.000 claims description 5
239000011541 reaction mixture Substances 0.000 claims description 4
GBBSAMQTQCPOBF-UHFFFAOYSA-N 2,4,6-trimethyl-1,3,5,2,4,6-trioxatriborinane Chemical group CB1OB(C)OB(C)O1 GBBSAMQTQCPOBF-UHFFFAOYSA-N 0.000 claims 1
VRAIHTAYLFXSJJ-UHFFFAOYSA-N alumane Chemical compound [AlH3].[AlH3] VRAIHTAYLFXSJJ-UHFFFAOYSA-N 0.000 claims 1
125000003944 tolyl group Chemical group 0.000 claims 1
238000006243 chemical reaction Methods 0.000 description 24
239000000243 solution Substances 0.000 description 17
IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 16
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 15
239000003054 catalyst Substances 0.000 description 13
JKWMSGQKBLHBQQ-UHFFFAOYSA-N diboron trioxide Chemical compound O=BOB=O JKWMSGQKBLHBQQ-UHFFFAOYSA-N 0.000 description 11
239000000047 product Substances 0.000 description 11
UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 9
229910052757 nitrogen Inorganic materials 0.000 description 8
229910052810 boron oxide Inorganic materials 0.000 description 7
VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 6
239000005977 Ethylene Substances 0.000 description 6
238000006384 oligomerization reaction Methods 0.000 description 6
238000006116 polymerization reaction Methods 0.000 description 6
125000004432 carbon atom Chemical group C* 0.000 description 5
125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 5
150000003839 salts Chemical class 0.000 description 5
239000004698 Polyethylene Substances 0.000 description 4
UORVGPXVDQYIDP-UHFFFAOYSA-N borane Chemical compound B UORVGPXVDQYIDP-UHFFFAOYSA-N 0.000 description 4
229920000573 polyethylene Polymers 0.000 description 4
229920000642 polymer Polymers 0.000 description 4
238000010992 reflux Methods 0.000 description 4
AQZWEFBJYQSQEH-UHFFFAOYSA-N 2-methyloxaluminane Chemical compound C[Al]1CCCCO1 AQZWEFBJYQSQEH-UHFFFAOYSA-N 0.000 description 3
MWUXSHHQAYIFBG-UHFFFAOYSA-N Nitric oxide Chemical compound O=[N] MWUXSHHQAYIFBG-UHFFFAOYSA-N 0.000 description 3
QCWXUUIWCKQGHC-UHFFFAOYSA-N Zirconium Chemical compound [Zr] QCWXUUIWCKQGHC-UHFFFAOYSA-N 0.000 description 3
239000012298 atmosphere Substances 0.000 description 3
230000015572 biosynthetic process Effects 0.000 description 3
ARUVKPQLZAKDPS-UHFFFAOYSA-L copper(II) sulfate Chemical compound [Cu+2].[O-][S+2]([O-])([O-])[O-] ARUVKPQLZAKDPS-UHFFFAOYSA-L 0.000 description 3
125000004122 cyclic group Chemical group 0.000 description 3
238000004880 explosion Methods 0.000 description 3
239000007788 liquid Substances 0.000 description 3
239000012299 nitrogen atmosphere Substances 0.000 description 3
238000003756 stirring Methods 0.000 description 3
229910052726 zirconium Inorganic materials 0.000 description 3
VXNZUUAINFGPBY-UHFFFAOYSA-N 1-Butene Chemical compound CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 2
LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 2
KWKAKUADMBZCLK-UHFFFAOYSA-N 1-octene Chemical compound CCCCCCC=C KWKAKUADMBZCLK-UHFFFAOYSA-N 0.000 description 2
YVSMQHYREUQGRX-UHFFFAOYSA-N 2-ethyloxaluminane Chemical compound CC[Al]1CCCCO1 YVSMQHYREUQGRX-UHFFFAOYSA-N 0.000 description 2
RSPAIISXQHXRKX-UHFFFAOYSA-L 5-butylcyclopenta-1,3-diene;zirconium(4+);dichloride Chemical compound Cl[Zr+2]Cl.CCCCC1=CC=C[CH-]1.CCCCC1=CC=C[CH-]1 RSPAIISXQHXRKX-UHFFFAOYSA-L 0.000 description 2
RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
238000004566 IR spectroscopy Methods 0.000 description 2
229910000085 borane Inorganic materials 0.000 description 2
KGBXLFKZBHKPEV-UHFFFAOYSA-N boric acid Chemical class OB(O)O KGBXLFKZBHKPEV-UHFFFAOYSA-N 0.000 description 2
229910052802 copper Inorganic materials 0.000 description 2
239000010949 copper Substances 0.000 description 2
229910000365 copper sulfate Inorganic materials 0.000 description 2
DIOQZVSQGTUSAI-UHFFFAOYSA-N decane Chemical compound CCCCCCCCCC DIOQZVSQGTUSAI-UHFFFAOYSA-N 0.000 description 2
238000004821 distillation Methods 0.000 description 2
ZSWFCLXCOIISFI-UHFFFAOYSA-N endo-cyclopentadiene Natural products C1C=CC=C1 ZSWFCLXCOIISFI-UHFFFAOYSA-N 0.000 description 2
125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 2
238000005227 gel permeation chromatography Methods 0.000 description 2
230000007062 hydrolysis Effects 0.000 description 2
238000006460 hydrolysis reaction Methods 0.000 description 2
239000000463 material Substances 0.000 description 2
229910052751 metal Inorganic materials 0.000 description 2
239000002184 metal Substances 0.000 description 2
VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 2
239000003960 organic solvent Substances 0.000 description 2
230000035484 reaction time Effects 0.000 description 2
239000007787 solid Substances 0.000 description 2
239000010935 stainless steel Substances 0.000 description 2
229910001220 stainless steel Inorganic materials 0.000 description 2
239000000126 substance Substances 0.000 description 2
230000001052 transient effect Effects 0.000 description 2
VOITXYVAKOUIBA-UHFFFAOYSA-N triethylaluminium Chemical compound CC[Al](CC)CC VOITXYVAKOUIBA-UHFFFAOYSA-N 0.000 description 2
DQEOZNPKBKCSPK-UHFFFAOYSA-N 2,4,6-tributyl-1,3,5,2,4,6-trioxatriborinane Chemical compound CCCCB1OB(CCCC)OB(CCCC)O1 DQEOZNPKBKCSPK-UHFFFAOYSA-N 0.000 description 1
PXSCEAJMCLQOBY-UHFFFAOYSA-N 2,6,6-trimethyloxaluminane Chemical compound C[Al]1CCCC(C)(C)O1 PXSCEAJMCLQOBY-UHFFFAOYSA-N 0.000 description 1
QYBTUFPDFJBKQW-UHFFFAOYSA-N 2-methyl-1,3,5,2,4$l^{2},6$l^{2}-trioxatriborinane Chemical compound CB1O[B]O[B]O1 QYBTUFPDFJBKQW-UHFFFAOYSA-N 0.000 description 1
229910000838 Al alloy Inorganic materials 0.000 description 1
229910018516 Al—O Inorganic materials 0.000 description 1
OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 description 1
NHTMVDHEPJAVLT-UHFFFAOYSA-N Isooctane Chemical compound CC(C)CC(C)(C)C NHTMVDHEPJAVLT-UHFFFAOYSA-N 0.000 description 1
229920010126 Linear Low Density Polyethylene (LLDPE) Polymers 0.000 description 1
WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 1
230000009471 action Effects 0.000 description 1
230000002411 adverse Effects 0.000 description 1
125000001931 aliphatic group Chemical group 0.000 description 1
150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001336 alkenes Chemical class 0.000 description 1
PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
238000004458 analytical method Methods 0.000 description 1
239000003849 aromatic solvent Substances 0.000 description 1
150000005840 aryl radicals Chemical class 0.000 description 1
125000004429 atom Chemical group 0.000 description 1
230000008901 benefit Effects 0.000 description 1
238000009835 boiling Methods 0.000 description 1
239000004327 boric acid Substances 0.000 description 1
125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
229910052791 calcium Inorganic materials 0.000 description 1
239000011575 calcium Substances 0.000 description 1
150000001719 carbohydrate derivatives Chemical class 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
238000009750 centrifugal casting Methods 0.000 description 1
239000007795 chemical reaction product Substances 0.000 description 1
238000001816 cooling Methods 0.000 description 1
JZCCFEFSEZPSOG-UHFFFAOYSA-L copper(II) sulfate pentahydrate Chemical compound O.O.O.O.O.[Cu+2].[O-]S([O-])(=O)=O JZCCFEFSEZPSOG-UHFFFAOYSA-L 0.000 description 1
150000001923 cyclic compounds Chemical class 0.000 description 1
230000007423 decrease Effects 0.000 description 1
230000007812 deficiency Effects 0.000 description 1
YNLAOSYQHBDIKW-UHFFFAOYSA-M diethylaluminium chloride Chemical compound CC[Al](Cl)CC YNLAOSYQHBDIKW-UHFFFAOYSA-M 0.000 description 1
JVSWJIKNEAIKJW-UHFFFAOYSA-N dimethyl-hexane Natural products CCCCCC(C)C JVSWJIKNEAIKJW-UHFFFAOYSA-N 0.000 description 1
JGHYBJVUQGTEEB-UHFFFAOYSA-M dimethylalumanylium;chloride Chemical compound C[Al](C)Cl JGHYBJVUQGTEEB-UHFFFAOYSA-M 0.000 description 1
238000004090 dissolution Methods 0.000 description 1
230000000694 effects Effects 0.000 description 1
238000005485 electric heating Methods 0.000 description 1
239000002360 explosive Substances 0.000 description 1
238000001125 extrusion Methods 0.000 description 1
239000012467 final product Substances 0.000 description 1
125000000524 functional group Chemical group 0.000 description 1
239000007789 gas Substances 0.000 description 1
238000002309 gasification Methods 0.000 description 1
239000008241 heterogeneous mixture Substances 0.000 description 1
229920001903 high density polyethylene Polymers 0.000 description 1
239000004700 high-density polyethylene Substances 0.000 description 1
239000012456 homogeneous solution Substances 0.000 description 1
229920001519 homopolymer Polymers 0.000 description 1
239000012535 impurity Substances 0.000 description 1
239000012442 inert solvent Substances 0.000 description 1
238000001746 injection moulding Methods 0.000 description 1
125000000959 isobutyl group Chemical group [H]C([H])([H])C([H])(C([H])([H])[H])C([H])([H])* 0.000 description 1
229910000464 lead oxide Inorganic materials 0.000 description 1
229910052744 lithium Inorganic materials 0.000 description 1
GYNNXHKOJHMOHS-UHFFFAOYSA-N methyl-cycloheptane Natural products CC1CCCCCC1 GYNNXHKOJHMOHS-UHFFFAOYSA-N 0.000 description 1
238000002156 mixing Methods 0.000 description 1
230000004048 modification Effects 0.000 description 1
238000012986 modification Methods 0.000 description 1
TVMXDCGIABBOFY-UHFFFAOYSA-N n-Octanol Natural products CCCCCCCC TVMXDCGIABBOFY-UHFFFAOYSA-N 0.000 description 1
238000000655 nuclear magnetic resonance spectrum Methods 0.000 description 1
150000002902 organometallic compounds Chemical class 0.000 description 1
YEXPOXQUZXUXJW-UHFFFAOYSA-N oxolead Chemical compound [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 1
125000001147 pentyl group Chemical group C(CCCC)* 0.000 description 1
239000002685 polymerization catalyst Substances 0.000 description 1
239000002244 precipitate Substances 0.000 description 1
125000001436 propyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
230000009467 reduction Effects 0.000 description 1
239000007858 starting material Substances 0.000 description 1
QAOWNCQODCNURD-UHFFFAOYSA-L sulfate group Chemical group S(=O)(=O)([O-])[O-] QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
238000003786 synthesis reaction Methods 0.000 description 1
150000003609 titanium compounds Chemical class 0.000 description 1
229910052723 transition metal Inorganic materials 0.000 description 1
LALRXNPLTWZJIJ-UHFFFAOYSA-N triethylborane Chemical compound CCB(CC)CC LALRXNPLTWZJIJ-UHFFFAOYSA-N 0.000 description 1
239000004711 α-olefin Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G79/00—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule
- C08G79/10—Macromolecular compounds obtained by reactions forming a linkage containing atoms other than silicon, sulfur, nitrogen, oxygen, and carbon with or without the latter elements in the main chain of the macromolecule a linkage containing aluminium
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07F—ACYCLIC, CARBOCYCLIC OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
- C07F5/00—Compounds containing elements of Groups 3 or 13 of the Periodic Table
- C07F5/06—Aluminium compounds
- C07F5/061—Aluminium compounds with C-aluminium linkage
- C07F5/066—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage)
- C07F5/068—Aluminium compounds with C-aluminium linkage compounds with Al linked to an element other than Al, C, H or halogen (this includes Al-cyanide linkage) preparation of alum(in)oxanes
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F10/00—Homopolymers and copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond

Landscapes

Chemical & Material Sciences (AREA)
Organic Chemistry (AREA)
Health & Medical Sciences (AREA)
Chemical Kinetics & Catalysis (AREA)
Medicinal Chemistry (AREA)
Polymers & Plastics (AREA)
Toxicology (AREA)
Transition And Organic Metals Composition Catalysts For Addition Polymerization (AREA)

CS893785A 1988-06-22 1989-06-22 Process for preparing mixture of linear and cyclic alkyl aluminooxanes CS378589A3 (en)

Applications Claiming Priority (1)

Application Number	Priority Date	Filing Date	Title
US07/210,881 USH1510H (en)	1988-06-23	1988-06-23	Continuous process for crystallizing nitroguanidine

Publications (1)

Publication Number	Publication Date
CS378589A3 true CS378589A3 (en)	1992-11-18

Family

ID=22784665

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CS893785A CS378589A3 (en)	1988-06-22	1989-06-22	Process for preparing mixture of linear and cyclic alkyl aluminooxanes

Country Status (19)

Country	Link
EP (1)	EP0348126B1 (de)
JP (1)	JPH02256686A (de)
KR (1)	KR910000756A (de)
AR (1)	AR243552A1 (de)
AT (1)	ATE85617T1 (de)
AU (1)	AU620106B2 (de)
BR (1)	BR8903011A (de)
CA (1)	CA1327366C (de)
CS (1)	CS378589A3 (de)
DE (1)	DE68904825T2 (de)
DK (1)	DK309789A (de)
ES (1)	ES2053993T3 (de)
FI (1)	FI893057A (de)
HU (1)	HU207090B (de)
IL (1)	IL90623A0 (de)
NO (1)	NO892565L (de)
PL (1)	PL280119A1 (de)
PT (1)	PT90924B (de)
YU (1)	YU124289A (de)

Families Citing this family (8)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US5001244A (en) *	1988-06-22	1991-03-19	Exxon Chemical Patents Inc.	Metallocene, hydrocarbylaluminum and hydrocarbylboroxine olefin polymerization catalyst
US5411925A (en) *	1993-02-12	1995-05-02	Phillips Petroleum Company	Organo-aluminoxy product and use
DE4203753A1 (de) *	1992-02-10	1993-08-12	Basf Ag	Katalysatorsysteme zur polymerisation von c(pfeil abwaerts)2(pfeil abwaerts)-bis c(pfeil abwaerts)1(pfeil abwaerts)(pfeil abwaerts)0(pfeil abwaerts)-alkenen
US5354721A (en) *	1993-06-22	1994-10-11	Phillips Petroleum Company	Organo-aluminoxy product and use
US5414180A (en) *	1993-07-14	1995-05-09	Phillips Petroleum Company	Organo-aluminoxy product and use
US5496781A (en) *	1994-05-16	1996-03-05	Phillips Petroleum Company	Metallocene catalyst systems, preparation, and use
US6046347A (en) *	1998-09-24	2000-04-04	Akzo Nobel Nv	Aluminoxane synthesis employing reduced amount of trialkylaluminum compound
EP1201683A1 (de) *	2000-10-30	2002-05-02	SOLVAY POLYOLEFINS EUROPE - BELGIUM (Société Anonyme)	Verfahren zur Polymerisation von Alpha-Olefinen

1989
- 1989-06-14 CA CA000602777A patent/CA1327366C/en not_active Expired - Fee Related
- 1989-06-15 IL IL90623A patent/IL90623A0/xx unknown
- 1989-06-19 EP EP89306177A patent/EP0348126B1/de not_active Expired - Lifetime
- 1989-06-19 AT AT89306177T patent/ATE85617T1/de not_active IP Right Cessation
- 1989-06-19 DE DE8989306177T patent/DE68904825T2/de not_active Expired - Fee Related
- 1989-06-19 YU YU01242/89A patent/YU124289A/xx unknown
- 1989-06-19 ES ES89306177T patent/ES2053993T3/es not_active Expired - Lifetime
- 1989-06-20 PL PL28011989A patent/PL280119A1/xx unknown
- 1989-06-20 JP JP1156958A patent/JPH02256686A/ja active Pending
- 1989-06-21 NO NO89892565A patent/NO892565L/no unknown
- 1989-06-21 FI FI893057A patent/FI893057A/fi not_active Application Discontinuation
- 1989-06-21 PT PT90924A patent/PT90924B/pt not_active IP Right Cessation
- 1989-06-21 AU AU36655/89A patent/AU620106B2/en not_active Ceased
- 1989-06-21 KR KR1019890008555A patent/KR910000756A/ko not_active Application Discontinuation
- 1989-06-21 BR BR898903011A patent/BR8903011A/pt not_active Application Discontinuation
- 1989-06-21 HU HU893172A patent/HU207090B/hu not_active IP Right Cessation
- 1989-06-22 DK DK309789A patent/DK309789A/da not_active Application Discontinuation
- 1989-06-22 CS CS893785A patent/CS378589A3/cs unknown
- 1989-06-22 AR AR89314226A patent/AR243552A1/es active

Also Published As

Publication number	Publication date
FI893057A0 (fi)	1989-06-21
IL90623A0 (en)	1990-01-18
ATE85617T1 (de)	1993-02-15
YU124289A (en)	1990-10-31
DE68904825T2 (de)	1993-05-27
DK309789A (da)	1989-12-23
PT90924B (pt)	1994-11-30
FI893057A (fi)	1989-12-23
JPH02256686A (ja)	1990-10-17
DK309789D0 (da)	1989-06-22
BR8903011A (pt)	1990-02-06
EP0348126A2 (de)	1989-12-27
HUT50840A (en)	1990-03-28
KR910000756A (ko)	1991-01-30
NO892565L (no)	1989-12-27
EP0348126A3 (en)	1990-03-14
DE68904825D1 (de)	1993-03-25
PL280119A1 (en)	1990-01-22
NO892565D0 (no)	1989-06-21
HU207090B (en)	1993-03-01
AR243552A1 (es)	1993-08-31
ES2053993T3 (es)	1994-08-01
EP0348126B1 (de)	1993-02-10
AU3665589A (en)	1990-01-04
AU620106B2 (en)	1992-02-13
CA1327366C (en)	1994-03-01
PT90924A (pt)	1989-12-29

Publication	Publication Date	Title
EP0372617B2 (de)	2002-12-18	Synthese von Methylaluminoxanen
US5041584A (en)	1991-08-20	Modified methylaluminoxane
US5086024A (en)	1992-02-04	Catalyst system for polymerization of olefins
US5041583A (en)	1991-08-20	Preparation of aluminoxanes
US5550305A (en)	1996-08-27	Ethylene trimerization
EP0539876B1 (de)	1996-01-10	Katalytisches Verfahren für Kettenverlängerung
JP2001517714A (ja)	2001-10-09	変性アルミノキサン触媒活性化剤
US5371260A (en)	1994-12-06	Amino-aluminoxane compositions
EP0638593A1 (de)	1995-02-15	Katalysatorzusammensetzungen
EP0574854A2 (de)	1993-12-22	Durch Aktinide katalysiertes Verfahren zur Kettenverlängerung
EP0622347A1 (de)	1994-11-02	Trimerisierung von Ethylen und Katalysatoren dafür
JPH07173172A (ja)	1995-07-11	第三級アミノ−アルミノキサンハロゲン化物
CA2337346C (en)	2009-11-24	Activator composition comprising aluminum compound mixture
US4952714A (en)	1990-08-28	Non-aqueous process for the preparation of alumoxanes
EP0645393B1 (de)	2000-01-05	Aluminoxanen mit einer erhöhten katalytischen Aktivität
US6228794B1 (en)	2001-05-08	Cationic group 13 complexes incorporating bidentate ligands as polymerization catalysts
CS378589A3 (en)	1992-11-18	Process for preparing mixture of linear and cyclic alkyl aluminooxanes
CA2336793C (en)	2010-01-26	Three coordinate aluminum catalyst activator composition
CA2063520A1 (en)	1992-10-16	Preparation of aluminoxanes
EP0283958A2 (de)	1988-09-28	Olefinpolymere und Verfahren zu deren Herstellung
JP4480891B2 (ja)	2010-06-16	２核フルオロアリールアルミニウムアルキル錯体
JPH0730091B2 (ja)	1995-04-05	アルミノキサン類の製造方法
CA2015549C (en)	1998-10-27	Synthesis of methylaluminoxanes
JPS62148491A (ja)	1987-07-02	アルミノオキサン類の製造方法