CN1176157C - Soft superhigh gravity composite materials for acoustic insulation and noise elimination - Google Patents
Soft superhigh gravity composite materials for acoustic insulation and noise elimination Download PDFInfo
- Publication number
- CN1176157C CN1176157C CNB021577854A CN02157785A CN1176157C CN 1176157 C CN1176157 C CN 1176157C CN B021577854 A CNB021577854 A CN B021577854A CN 02157785 A CN02157785 A CN 02157785A CN 1176157 C CN1176157 C CN 1176157C
- Authority
- CN
- China
- Prior art keywords
- soft
- sound insulation
- noise elimination
- superelevation
- acoustic insulation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/08—Metals
- C08K2003/0887—Tungsten
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to a soft super-high gravity composite material for acoustic insulation and noise elimination, which belongs to the technical field of high molecular materials. Each component of the prevent invention has respective weight percentage content of 5 to 30% of high molecular polymer, 10 to 90% of tungsten, 3 to 10% of plasticiser, 1 to 5% of stabilizing agent and 1 to 10% of coupling agent, wherein the grain size of the tungsten is 100 nanometer to 2 micron. Besides good sound insulation and mechanical properties, the present invention also has the characteristics of flame resistance, anti-chemical medium, corrosion prevention, no poison, application property, etc. The defects of massiness and not easy processing of conventional sound insulation materials are overcome by the soft characteristic of the soft super-high gravity composite material for acoustic insulation and noise elimination. Thus larger space is provided for the application of the soft super-high gravity composite material for acoustic insulation and noise elimination. The present invention is suitable to be used as a sound insulation material for city aerial conveyer transportation, aviation and harbors and can be used for the vibration isolation treatment of light wall board sandwiches of building industry. The soft super-high gravity composite material for acoustic insulation and noise elimination has the advantages of effective noise reduction and working and living environment improvement.
Description
Technical field
What the present invention relates to is a kind of matrix material, particularly can be used for the soft superelevation proportion matrix material of sound insulation and noise reducing, belongs to polymeric material field.
Background technology
About the development of soundproof material and the history of using existing decades, but all there are some shortcomings in normally used in the market soundproof material, as the product cost height, mostly be mechanically resistant material and be difficult for secondary processing and the difficult sound insulation processing that is applied to irregularly shaped object etc.Its range of application is therefore limited.As everyone knows, the oise insulation factor of material is observed mass law: TL=20lgm+20lgf-43dB, in the formula: the oise insulation factor under the TL-sound wave vertical incidence condition, dB; The area density of m-material, kg/m
2F-incident acoustic wave frequency, Hz.When the material mass area ratio doubles, then acoustic transmission loss increases 6dB.As seen the high specific gravity characteristic can make material have high areal density, under the very little situation of thickness, can have higher sound insulation property.According to " mass law ", traditional picture brick wall, cement wall or the big material of mass area ratios such as Plate Steel, stereotype, though defening effect is all relatively good, because more thick and heavy, but processing and application property are poor, and the sound insulation that is not applied to irregularly shaped object is handled.
By literature search, Japanese Patent JP56059857, name is called: SOUND-INSULATING COMPOSITION (sound insulation composite material) discloses a kind of technology of preparing of soft soundproof material.Inorganic metals such as this patent employing lead powder are raw material, make the soft material with certain sound insulation property.But plumbous harmful to environment, and defening effect is also not enough.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, a kind of soft superelevation proportion matrix material that is used for sound insulation and noise reducing is provided, make it effectively reduce noise, do not endanger environment.The present invention is achieved by the following technical solutions, each component of the present invention and weight percent content thereof are: high molecular polymer: 5%~30%, particle diameter is the tungsten powder of 100 nanometers~2 micron: 10%~90%, softening agent: 3%~10%, stablizer: 1%~5%, coupling agent: 1%~10%; By mixing after injection moulding, mold pressing or calendering and moulding.
Wherein high molecular polymer can be rubber, thermoplastics or both mixtures, wherein rubber can be butadiene-acrylonitrile rubber, neoprene latex, natural rubber, thermoplastics is the chain macromolecular structure, for example polyethylene, polystyrene, polypropylene, polyvinyl chloride, softening agent comprises one or more in the following softening agent: dibutyl phthalate, dioctyl phthalate (DOP), diethyl phthalate.Coupling agent adopts one or more in the titante coupling agent.
The present invention has substantive distinguishing features and marked improvement, the present invention is except that having good sound insulation and mechanical property, but also have characteristics such as fire-retardant, anti-chemical medium, protection against corrosion, nontoxic application property, soundproof material is thick and heavy and its softish characteristics have overcome in the past, the shortcoming that is difficult for processing, bigger space is provided for application of the present invention, is suitable for doing the soundproof material at city aerial conveyor traffic, aviation and harbour, and the sound insulation of building trade Light trabs interlayer is handled.Use this kind matrix material can reduce noise, improvement work and living environment effectively.
Embodiment
Further provide following examples in conjunction with content of the present invention:
Embodiment one
Each component is with following proportioning uniform mixing, and mixing in mill, make 1 millimeter soft thin slice, its mean transmission loss is about 21.6 decibels, and hardness is 86 (Shao Shi).
High molecular polymer: 30% (polystyrene: 15%, paracril: 15%), tungsten powder (0.1 micron): 55%, monoalkoxy three (dioctylphosphato) titanic acid ester: 5%, dibutyl phthalate: 8%, barium stearate: 1%, lead sulfate tribasic: 1%.
Embodiment two
Each component is with following proportioning uniform mixing, and mixing in mill, make 1 millimeter soft thin slice, (100 ~ 1600Hz), hardness is 88 (Shao Shi) to its oise insulation factor between 18 ~ 27 decibels.
PVC:15%, tungsten powder (60 microns): 80%, sec.-propyl three carboxyl titanic acid ester: 1%, dibutyl phthalate: 3%, barium stearate: 0.5%, lead sulfate tribasic: 0.5%.
Embodiment three
Each component is with following proportioning uniform mixing, and mixing in mill, make 1 millimeter soft thin slice, its mean transmission loss has good resistance of aging about 22 decibels.
High molecular polymer: 30% (polyethylene: 21%, paracril: 9%), tungsten powder (2 microns): 55%, monoalkoxy three (dioctylphosphato) titanic acid ester: 5%, dibutyl phthalate: 8%, barium stearate: 1%, lead sulfate tribasic: 1%.
Embodiment four
Each component is with following proportioning uniform mixing, and mixing in mill, make 1 millimeter soft thin slice, its mean transmission loss has good resistance of aging about 22 decibels.
Get PVC:5%, tungsten powder (1.8 microns): 90%, sec.-propyl three carboxyl titanic acid ester 1%, dibutyl phthalate: 3%, barium stearate: 0.5%, lead sulfate tribasic: 0.5% mix processing after, the density of being surveyed is 3.54g/cm
3, hardness is 92 (Shao Shi).
Claims (6)
1, a kind of soft superelevation proportion matrix material that is used for sound insulation and noise reducing, it is characterized in that: each component and weight percent content thereof are: high molecular polymer: 5%~30%, particle diameter is 100 nanometers~2 micron tungsten powder 55%-90%, softening agent: 3%-8%, stablizer: 1%-2%, coupling agent: 1%-5%.
2, this soft superelevation proportion matrix material that is used for sound insulation and noise reducing according to claim 1 is characterized in that described high molecular polymer is a kind of of rubber, thermoplastics or both mixtures.
3, the soft superelevation proportion matrix material that is used for sound insulation and noise reducing according to claim 2 is characterized in that rubber is a kind of of butadiene-acrylonitrile rubber, neoprene latex, natural rubber.
4, the soft superelevation proportion matrix material that is used for sound insulation and noise reducing according to claim 2 is characterized in that thermoplastics is the chain macromolecular structure, is a kind of of polyethylene, polystyrene, polypropylene, polyvinyl chloride.
5, the soft superelevation proportion matrix material that is used for sound insulation and noise reducing according to claim 1, it is characterized in that described softening agent, comprise in the following softening agent one or more: dibutyl phthalate, dioctyl phthalate (DOP), diethyl phthalate.
6, the soft superelevation proportion matrix material that is used for sound insulation and noise reducing according to claim 1 is characterized in that described coupling agent, and it adopts in the titante coupling agent one or more.
Priority Applications (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021577854A CN1176157C (en) | 2002-12-26 | 2002-12-26 | Soft superhigh gravity composite materials for acoustic insulation and noise elimination |
PCT/CN2003/001102 WO2004058867A1 (en) | 2002-12-26 | 2003-12-22 | Flexible composite with super-high specific gravity used in sound insulation and noise reduction |
AU2003292865A AU2003292865A1 (en) | 2002-12-26 | 2003-12-22 | Flexible composite with super-high specific gravity used in sound insulation and noise reduction |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CNB021577854A CN1176157C (en) | 2002-12-26 | 2002-12-26 | Soft superhigh gravity composite materials for acoustic insulation and noise elimination |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1424347A CN1424347A (en) | 2003-06-18 |
CN1176157C true CN1176157C (en) | 2004-11-17 |
Family
ID=4753000
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CNB021577854A Expired - Fee Related CN1176157C (en) | 2002-12-26 | 2002-12-26 | Soft superhigh gravity composite materials for acoustic insulation and noise elimination |
Country Status (3)
Country | Link |
---|---|
CN (1) | CN1176157C (en) |
AU (1) | AU2003292865A1 (en) |
WO (1) | WO2004058867A1 (en) |
Families Citing this family (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN1741127B (en) * | 2005-08-25 | 2010-05-12 | 上海交通大学 | Reciprocating vibration energy-dissipation acoustic structure |
CN101497768B (en) * | 2009-03-04 | 2011-08-31 | 三友(天津)高分子技术有限公司 | Silencing film for automobile |
CN102585330A (en) * | 2012-01-18 | 2012-07-18 | 厦门虹鹭钨钼工业有限公司 | Tungsten-polymer composite material and preparation method thereof |
CN102991094B (en) * | 2012-12-03 | 2016-02-10 | 太仓苏易信息科技有限公司 | A kind of preparation method of Novel sound-proof curtain fabric |
CN105986627A (en) * | 2015-02-07 | 2016-10-05 | 马明 | Preparation method of powder metal composite sound insulation coiled material |
CN106084338B (en) * | 2016-06-02 | 2020-11-10 | 上海交通大学 | Soft high-specific-gravity rubber-plastic foam material for sound insulation and noise reduction |
CN106050093B (en) * | 2016-08-03 | 2017-12-26 | 安徽卡塔门窗有限公司 | A kind of soundproof window |
CN107760006A (en) * | 2017-09-29 | 2018-03-06 | 镇江市星耀智能装备有限公司 | A kind of acoustical panel |
CN107793742A (en) * | 2017-10-02 | 2018-03-13 | 镇江市星耀智能装备有限公司 | A kind of sheet material quieter material |
CN114346236B (en) * | 2021-12-08 | 2023-12-15 | 广州市华司特合金制品有限公司 | Tungsten resin composite material and preparation method thereof |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
SU127226A1 (en) * | 1959-06-11 | 1959-11-30 | М.Г. Вальцифер | Method for multiple drawing of tungsten wire |
US4326418A (en) * | 1980-04-07 | 1982-04-27 | North American Philips Corporation | Acoustic impedance matching device |
US4382201A (en) * | 1981-04-27 | 1983-05-03 | General Electric Company | Ultrasonic transducer and process to obtain high acoustic attenuation in the backing |
JPS61196299A (en) * | 1985-02-27 | 1986-08-30 | 株式会社 日立メデイコ | Ultrasonic sound absorbing material |
JPH0772836B2 (en) * | 1985-11-14 | 1995-08-02 | 富士通株式会社 | Method for manufacturing acoustic wave absorber |
JPH04168162A (en) * | 1990-10-31 | 1992-06-16 | Tatsuta Electric Wire & Cable Co Ltd | Sound-absorbable coating |
JP2749488B2 (en) * | 1992-10-02 | 1998-05-13 | オリンパス光学工業株式会社 | Ultrasonic probe manufacturing method |
JP3113215B2 (en) * | 1997-04-11 | 2000-11-27 | ティーディーケイ株式会社 | Cartridge for magnetic recording media |
JP2000163861A (en) * | 1998-11-26 | 2000-06-16 | Mitsubishi Materials Corp | Balancer of magnetic recording device and its production |
-
2002
- 2002-12-26 CN CNB021577854A patent/CN1176157C/en not_active Expired - Fee Related
-
2003
- 2003-12-22 AU AU2003292865A patent/AU2003292865A1/en not_active Abandoned
- 2003-12-22 WO PCT/CN2003/001102 patent/WO2004058867A1/en not_active Application Discontinuation
Also Published As
Publication number | Publication date |
---|---|
WO2004058867A1 (en) | 2004-07-15 |
CN1424347A (en) | 2003-06-18 |
AU2003292865A1 (en) | 2004-07-22 |
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