CN101735530A - Flame-retardant sound insulation composite material and sound insulation component - Google Patents
Flame-retardant sound insulation composite material and sound insulation component Download PDFInfo
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- CN101735530A CN101735530A CN200910189266A CN200910189266A CN101735530A CN 101735530 A CN101735530 A CN 101735530A CN 200910189266 A CN200910189266 A CN 200910189266A CN 200910189266 A CN200910189266 A CN 200910189266A CN 101735530 A CN101735530 A CN 101735530A
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Abstract
The invention relates to a flame-retardant sound insulation composite material. The flame-retardant sound insulation composite material comprises the following components in percentage by weight: 5 to 30 percent of PVC, 5 to 30 percent of chlorinated polyethylene, 15 to 80 percent of iron powder of which the grain diameter is 10 to 100 microns, 0.5 to 2 percent of coupling agent and 9.5 to 23 percent of aid. The invention provides the flame-retardant sound insulation composite material, which is prepared from the PVC, the chlorinated polyethylene, the iron powder with the grain diameter of 10 to 100 microns, the coupling agent and the aid, has good flame-retardant sound insulation effect, and also has the characteristics of flame retardancy, innocuity, no lead, high strength, good construction property and low cost. Because the chlorinated polyethylene is particularly introduced into the material components of the flame-retardant sound insulation composite material, the using amount of a plasticizer of the material is reduced, and the composite material has better softness and can be widely applied to sound insulation treatment in the construction industry, decoration field and the like; and the sound insulation composite material can effectively reduce the noise, and the sound insulation index of the material can reach 25 to 32 decibels.
Description
Technical field
The present invention relates to a kind of matrix material and sound proof member, relate in particular to a kind of flame-proof sound insulation matrix material and use the sound proof member of described flame-proof sound insulation matrix material.
Background technology
Along with the industrialization development of society, also seem more and more outstanding as the three big sound pollution problems of one of polluting.Noise can endanger people's auditory system, if for a long time under noise circumstance, can make the people tired, deaf, even jeopardize people's life.Simultaneously noise also can quicken to build, machine construction aging and damaging, influence the service precision of equipment and instrument and life-span etc.Therefore, the control of noise has become one of important topic that needs to be resolved hurrily now with control.
The control of noise should be taken into account the sound system of being made up of sound source, route of transmission and three links of recipient with control.Because first and the 3rd link belongs to outwardness, old friends mainly focus on and propagate control.At present, the method for Chang Yong control noise is sound absorption and sound insulation.So-called sound absorption promptly takes sound-absorbing material, sound absorption structure to reduce the reverberant sound that reflection causes, thereby reaches the purpose of control noise; Sound insulation promptly utilizes soundproof material or sound insulating structure to isolate or stop the propagation of acoustic energy, and noise and other environment are kept apart control and control to reach noise.Though the principle of the two is not quite similar, the former is for same environment, is by the internal friction that the loss of the VISCOUS FLOW of sound wave and intermolecular relative movement cause acoustic energy to be changed into heat energy dissipation to fall, and material mostly is porous loose structure; The latter then be another environmental facies for noise circumstance, material mostly is fine and close abundant structure.But sound insulation also comprises the sound absorption part, i.e. also help sound insulation in the time of sound absorption.
The defening effect of soundproof material characterizes with oise insulation factor.Theoretical analysis and experimental study show, partiting sound member for the individual layer homogeneous, its sound insulation property mainly is to change along with the area density harmony wave frequency difference of member, its defening effect is obeyed mass law: R=18 * lg ρ+12 * lgf-25, in the formula, R (dB) is the oise insulation factor under a certain frequency, ρ (kg/m
2) be the area density of material, f (Hz) is the incident sound wave frequency.From on can find out that the defening effect that improves material can realize by the mass area ratio that improves material.
About the existing lot of experiments in aspects such as sound-absorbing material and dependency structure thereof, and develop many widely used novel materials and new technology.Though and last for a long time about the development and the application of soundproof material, but all there are some either-or shortcomings in general soundproof material at present, such as the cost height, contain Toxic matter, mostly be that mechanically resistant material is difficult for secondary processing and the difficult sound insulation that is applied to irregularly shaped object is handled, thereby make its application limited.Find by literature search, China Patent No. is: 02157782.X, patent name is: hyperbaric sound insulation composite material, announced a kind of high-density sound insulation composite material, this patent the tungsten powder combination of PVC and diameter 2-60 micron, is made better, the nontoxic soundproof material of a kind of defening effect by coupling agent.Its material composition is tungsten powder and PVC and coupling agent, by injection moulding, compression molding, be used to do the soundproof material at city aerial conveyor traffic, aviation and harbour, and the sound insulation of building trade Light trabs interlayer processing, use this kind sound insulation composite material can reduce noise effectively.But this material is owing to adopted plumbiferous stablizer, and tungsten powder is on the high side, thereby has limited the use range of material.
Summary of the invention
The technical problem that the present invention solves is: a kind of flame-proof sound insulation matrix material is provided, overcomes in the soundproof material of prior art and contain the technical problem that the tungsten powder material causes cost significantly to raise.The present invention also overcomes in the stablizer in the prior art soundproof material leaded, and the plumbous technical problem that human body is had harm.
Technical scheme of the present invention is: a kind of flame-proof sound insulation matrix material is provided, the component of described flame-proof sound insulation matrix material and weight percent content thereof are: polyvinyl chloride: 5%-30%, chlorinatedpolyethylene: 5%-30%, particle diameter is the iron powder of 10-100 micron: 15%-80%, silane coupling agent: 0.5%-2%, auxiliary agent: 9.5%-23%.
Further technical scheme of the present invention is: described polyvinyl chloride is the flexible PVC powder of polymerization degree 1000-2000.
Further technical scheme of the present invention is: described chlorinatedpolyethylene is that cl content is the chlorinatedpolyethylene powder of 30%-45%.
Further technical scheme of the present invention is: the usage ratio of described polyvinyl chloride and chlorinatedpolyethylene is 1: 1~1: 6.
Further technical scheme of the present invention is: described coupling agent is one or more in the silane coupling agent.
Further technical scheme of the present invention is: described auxiliary agent is one or more in stablizer, softening agent, fire retardant and the antiaging agent.
Technical scheme of the present invention is: a kind of sound proof member that adopts the described flame-proof sound insulation matrix material of above-mentioned arbitrary claim to make is provided.
Technique effect of the present invention is: a kind of flame-proof sound insulation matrix material is provided, adopting polyvinyl chloride, chlorinatedpolyethylene, particle diameter is iron powder, coupling agent and the auxiliary agent of 10-100 micron, the fire-retardant defening effect of flame-proof sound insulation matrix material that these components are made is good, but also has characteristics fire-retardant, nontoxic, unleaded, that the high application property of intensity is good and cost is low.Flame-proof sound insulation matrix material of the present invention has particularly been introduced chlorinatedpolyethylene in material composition, make the plasticizer consumption minimizing of material and have flexibility preferably, the sound insulation that can be widely used in building trade, decoration field etc. is handled, use that this kind soundproof material is compound can to reduce noise effectively, the sound reduction index of material reaches the 25-32 decibel.
Embodiment
Below in conjunction with specific embodiment, technical solution of the present invention is further specified.
The specific embodiment of the present invention is as follows: the invention provides a kind of flame-proof sound insulation matrix material, the component of described flame-proof sound insulation matrix material and weight percent content thereof are: polyvinyl chloride: 5%-30%, chlorinatedpolyethylene: 5%-30%, particle diameter is the iron powder of 10-100 micron: 15%-80%, silane coupling agent: 0.5%-2%, auxiliary agent: 9.5%-23%.The invention provides a kind of flame-proof sound insulation matrix material, adopting PVC, chlorinatedpolyethylene, particle diameter is iron powder, silane coupling agent and the auxiliary agent of 10-100 micron, the fire-retardant defening effect of flame-proof sound insulation matrix material that these components are made is good, but also have fire-retardant, nontoxic, unleaded, the good characteristics of the high application property of intensity, and cost is low.Flame-proof sound insulation matrix material of the present invention has particularly been introduced CPE in material composition, make the plasticizer consumption minimizing of material and have flexibility preferably, the sound insulation that can be widely used in building trade, decoration field etc. is handled, use that this kind soundproof material is compound can to reduce noise effectively, the sound reduction index of material reaches the 20-25 decibel.The preferred embodiment of the present invention is: described polyvinyl chloride is the flexible PVC powder of polymerization degree 1000-2000, described chlorinatedpolyethylene is that cl content is the chlorinatedpolyethylene powder of 30%-45%, described coupling agent is one or more in the silane coupling agent, and described auxiliary agent is one or more in stablizer, softening agent, fire retardant and the antiaging agent.
The making processes of flame-proof sound insulation matrix material of the present invention is as follows: the component and the weight percent content thereof of described flame-proof sound insulation matrix material are pressed PVC:5%-30%, chlorinatedpolyethylene: 5%-30%, particle diameter is the iron powder of 10-100 micron: 15%-80%, silane coupling agent: 0.5%-2%, the ratio uniform mixing of auxiliary agent: 9.5%-23%, then with mixed raw material mixing in mill (processing temperature is 140~190 ℃, and mixing time is 10~20 minutes).Flame-proof sound insulation matrix material after mixing promptly can be made into finished product and comes into operation.In the specific embodiment of the present invention,, use sheet material to carry out flame-proof sound insulation then and use the sheet material of laminating of the flame-proof sound insulation matrix material after mixing.
Specific embodiments of the invention are as follows:
Comparative Examples
Commodity sound-proof felt, thickness are 2 millimeters soft sample.
Embodiment one
Each component is with following proportioning uniform mixing, and mixing in mill, and 2 millimeters soft thin slice is made in mold pressing.PVC (polymerization degree 1300): 25.5%, particle diameter is 38 microns a iron powder: 51.1%, γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.5%, stearic acid: 0.1%, calcium-zinc composite stabilizing agent: 1%, dioctyl phthalate (DOP): 5.1%, triphenyl phosphite: 12.8%, zinc borate: 1.5%, molybdic oxide: 1.3%, antimonous oxide: 1.5%.
Embodiment two
Each component is with following proportioning uniform mixing, and mixing in mill, and 2 millimeters soft thin slice is made in mold pressing; PVC (polymerization degree 1300): 13.4%, chlorinatedpolyethylene (cl content 40%): 13.4%, particle diameter is 38 microns a iron powder: 53.4%, and γ-(2,3-epoxy third oxygen) propyl trimethoxy silicane: 0.5%, stearic acid: 0.1%, calcium-zinc composite stabilizing agent: 1.1%, triphenyl phosphite: 13.4%, zinc borate: 1.6%, molybdic oxide: 1.3%, antimonous oxide: 1.6%.
Table 1 is the comparing result of Comparative Examples and embodiment one and embodiment two:
Table 1
Performance index | Comparative Examples one | Embodiment one | Embodiment two |
Sound insulation index (dB) | ??26.3 | ??30.5 | ??31.7 |
Flame retardant resistance (LOI, %) | ??26 | ??33 | ??34 |
Area density (kg/m 2) | ??3.57 | ??4.98 | ??5.22 |
Hardness (Shao Shi A) | ??64 | ??90 | ??85 |
The present invention also provides a kind of sound proof member, and described sound proof member adopts above-mentioned flame-proof sound insulation matrix material to be made.The present invention is the sheet material of laminating of the flame-proof sound insulation matrix material after mixing, uses board making to become the sound proof member use of insulating against sound then.The invention provides and be suitable for significantly weakening the vibration that produces in various goods, device, structure or the equipment and the sound proof member of noise.As interval, exterior wall, soundproof room and spaced walls etc. movably.
Above content be in conjunction with concrete preferred implementation to further describing that the present invention did, can not assert that concrete enforcement of the present invention is confined to these explanations.For the general technical staff of the technical field of the invention, without departing from the inventive concept of the premise, can also make some simple deduction or replace, all should be considered as belonging to protection scope of the present invention.
Claims (7)
1. flame-proof sound insulation matrix material, it is characterized in that: the component of described flame-proof sound insulation matrix material and weight percent content thereof are: PVC:5%-30%, chlorinatedpolyethylene: 5%-30%, particle diameter is the iron powder of 10-100 micron: 15%-80%, coupling agent: 0.5%-2%, auxiliary agent: 9.5%-23%.
2. according to the described flame-proof sound insulation matrix material of claim 1, it is characterized in that described PVC is the flexible PVC powder of polymerization degree 1000-2000.
3. according to the described flame-proof sound insulation matrix material of claim 1, it is characterized in that described chlorinatedpolyethylene is that cl content is the chlorinatedpolyethylene powder of 30%-45%.
4. according to the described flame-proof sound insulation matrix material of claim 1, it is characterized in that the usage ratio of described polyvinyl chloride and chlorinatedpolyethylene is 1: 1~1: 6.
5. according to the described flame-proof sound insulation matrix material of claim 1, it is characterized in that described coupling agent is one or more in the silane coupling agent.
6. according to the described flame-proof sound insulation matrix material of claim 1, it is characterized in that described auxiliary agent is one or more in stablizer, softening agent, fire retardant and the antiaging agent.
7. use the described flame-proof sound insulation matrix material of above-mentioned arbitrary claim sound proof member for one kind, it is characterized in that, described sound proof member adopts the described flame-proof sound insulation matrix material of above-mentioned arbitrary claim to make.
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102002190A (en) * | 2010-09-28 | 2011-04-06 | 南京乐金熊猫电器有限公司 | Polypropylene modified sound isolation material and preparation method thereof |
CN103937137A (en) * | 2014-04-18 | 2014-07-23 | 安徽省中日农业环保科技有限公司 | Wear-resistant and flame-retardant composite sound-absorbing board material added with additive and preparation method of material |
CN106088966A (en) * | 2016-08-01 | 2016-11-09 | 陆坤 | A kind of titanium alloy soundproof door |
CN106088967A (en) * | 2016-08-01 | 2016-11-09 | 陆坤 | A kind of steel soundproof door |
CN106193958A (en) * | 2016-08-01 | 2016-12-07 | 陆坤 | A kind of preparation method of aluminum alloy sound insulation door |
CN106193933A (en) * | 2016-08-01 | 2016-12-07 | 陆坤 | A kind of preparation method of titanium alloy soundproof door |
CN106193932A (en) * | 2016-08-01 | 2016-12-07 | 陆坤 | A kind of aluminum alloy sound insulation door |
CN106285349A (en) * | 2016-08-01 | 2017-01-04 | 陆坤 | A kind of preparation method of steel soundproof door |
CN107956400A (en) * | 2017-11-29 | 2018-04-24 | 国网湖南省电力有限公司 | A kind of substation's light sound-insulation folding door |
CN108093614A (en) * | 2017-12-13 | 2018-05-29 | 江西伟普科技有限公司 | A kind of preparation method that there is sound insulation to inhale ripple heat-insulating environment-protection type composite material |
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Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102002190A (en) * | 2010-09-28 | 2011-04-06 | 南京乐金熊猫电器有限公司 | Polypropylene modified sound isolation material and preparation method thereof |
CN102002190B (en) * | 2010-09-28 | 2012-07-25 | 南京乐金熊猫电器有限公司 | Polypropylene modified sound isolation material and preparation method thereof |
CN103937137A (en) * | 2014-04-18 | 2014-07-23 | 安徽省中日农业环保科技有限公司 | Wear-resistant and flame-retardant composite sound-absorbing board material added with additive and preparation method of material |
CN103937137B (en) * | 2014-04-18 | 2016-01-20 | 安徽省中日农业环保科技有限公司 | A kind of abrasion resistant fire blocking composite sound-absorbing panel material adding auxiliary agent and preparation method thereof |
CN106193958A (en) * | 2016-08-01 | 2016-12-07 | 陆坤 | A kind of preparation method of aluminum alloy sound insulation door |
CN106088967A (en) * | 2016-08-01 | 2016-11-09 | 陆坤 | A kind of steel soundproof door |
CN106088966A (en) * | 2016-08-01 | 2016-11-09 | 陆坤 | A kind of titanium alloy soundproof door |
CN106193933A (en) * | 2016-08-01 | 2016-12-07 | 陆坤 | A kind of preparation method of titanium alloy soundproof door |
CN106193932A (en) * | 2016-08-01 | 2016-12-07 | 陆坤 | A kind of aluminum alloy sound insulation door |
CN106285349A (en) * | 2016-08-01 | 2017-01-04 | 陆坤 | A kind of preparation method of steel soundproof door |
CN107956400A (en) * | 2017-11-29 | 2018-04-24 | 国网湖南省电力有限公司 | A kind of substation's light sound-insulation folding door |
CN107956400B (en) * | 2017-11-29 | 2023-09-19 | 国网湖南省电力有限公司 | Light sound insulation folding door of transformer substation |
CN108093614A (en) * | 2017-12-13 | 2018-05-29 | 江西伟普科技有限公司 | A kind of preparation method that there is sound insulation to inhale ripple heat-insulating environment-protection type composite material |
CN108093614B (en) * | 2017-12-13 | 2019-11-05 | 江西伟普科技有限公司 | The preparation method of wave heat-insulating environment-protection type composite material is inhaled in a kind of sound insulation |
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Address after: Room 402, Building B3, East Industrial Zone, No. 8, Wenchang South Street, Xiangshan Street Community, Shahe Street, Nanshan District, Shenzhen, Guangdong 518000 Patentee after: SHENZHEN CLOCELL ACOUSTICS TECHNOLOGY Co.,Ltd. Address before: 518000 301, 302, 303a, 303b, 303C, 304, 305 (office address) of Shenzhen Overseas Students (Longgang) Pioneer Park No.1, Qinglin West Road, Longgang District, Shenzhen City, Guangdong Province Patentee before: SHENZHEN CLOCELL ACOUSTICS TECHNOLOGY Co.,Ltd. |