CN1115403C - 流化床造粒 - Google Patents

流化床造粒 Download PDF

Info

Publication number: CN1115403C
Authority: CN; China
Prior art keywords: acid; aforementioned; fine particle; neutralizing agent; detergent
Prior art date: 1994-08-05
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.): Expired - Fee Related

Application number

CN95194514A

Other languages

English (en)

Chinese (zh)

Other versions

CN1155297A (zh

Inventor

S·V·达利维狄卡

V·R·达纽卡

N·D·密斯切

F·E·帕夏

Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)

Unilever NV

Original Assignee

Unilever NV

Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)

1994-08-05

Filing date

1995-07-24

Publication date

2003-07-23

1995-07-24 Application filed by Unilever NV filed Critical Unilever NV

1997-07-23 Publication of CN1155297A publication Critical patent/CN1155297A/zh

2003-07-23 Application granted granted Critical

2003-07-23 Publication of CN1115403C publication Critical patent/CN1115403C/zh

2015-07-24 Anticipated expiration legal-status Critical

Status Expired - Fee Related legal-status Critical Current

Links

238000005469 granulation Methods 0.000 title description 2
230000003179 granulation Effects 0.000 title description 2
238000000034 method Methods 0.000 claims abstract description 39
239000002253 acid Substances 0.000 claims abstract description 34
239000003599 detergent Substances 0.000 claims abstract description 34
239000000463 material Substances 0.000 claims abstract description 26
239000003795 chemical substances by application Substances 0.000 claims abstract description 23
239000000843 powder Substances 0.000 claims abstract description 22
230000003472 neutralizing effect Effects 0.000 claims abstract description 19
239000000203 mixture Substances 0.000 claims description 32
238000005406 washing Methods 0.000 claims description 19
239000002245 particle Substances 0.000 claims description 13
238000005243 fluidization Methods 0.000 claims description 12
239000010419 fine particle Substances 0.000 claims description 10
VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 8
239000003945 anionic surfactant Substances 0.000 claims description 8
229910021532 Calcite Inorganic materials 0.000 claims description 6
238000009826 distribution Methods 0.000 claims description 6
150000001875 compounds Chemical class 0.000 claims description 4
239000008187 granular material Substances 0.000 claims description 4
239000007788 liquid Substances 0.000 claims description 4
-1 alkylbenzene sulfonate Chemical class 0.000 claims description 3
230000007935 neutral effect Effects 0.000 claims description 3
239000000377 silicon dioxide Substances 0.000 claims description 3
229960001866 silicon dioxide Drugs 0.000 claims description 3
235000012239 silicon dioxide Nutrition 0.000 claims description 3
BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 2
229910052910 alkali metal silicate Inorganic materials 0.000 claims description 2
229910010272 inorganic material Inorganic materials 0.000 claims description 2
239000011147 inorganic material Substances 0.000 claims description 2
150000007513 acids Chemical class 0.000 claims 1
238000006386 neutralization reaction Methods 0.000 abstract description 11
230000000694 effects Effects 0.000 abstract description 6
238000004519 manufacturing process Methods 0.000 abstract description 4
239000012530 fluid Substances 0.000 abstract 1
239000011236 particulate material Substances 0.000 abstract 1
CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 description 17
235000019832 sodium triphosphate Nutrition 0.000 description 15
101710194948 Protein phosphatase PhpP Proteins 0.000 description 13
HWGNBUXHKFFFIH-UHFFFAOYSA-I pentasodium;[oxido(phosphonatooxy)phosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O HWGNBUXHKFFFIH-UHFFFAOYSA-I 0.000 description 13
239000013543 active substance Substances 0.000 description 6
238000002156 mixing Methods 0.000 description 6
150000003839 salts Chemical class 0.000 description 6
XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 6
239000004094 surface-active agent Substances 0.000 description 5
238000002360 preparation method Methods 0.000 description 4
239000002994 raw material Substances 0.000 description 4
239000011734 sodium Substances 0.000 description 4
229910000029 sodium carbonate Inorganic materials 0.000 description 4
235000017550 sodium carbonate Nutrition 0.000 description 4
238000004090 dissolution Methods 0.000 description 3
239000000344 soap Substances 0.000 description 3
238000001694 spray drying Methods 0.000 description 3
108090000790 Enzymes Proteins 0.000 description 2
102000004190 Enzymes Human genes 0.000 description 2
235000012204 lemonade/lime carbonate Nutrition 0.000 description 2
230000003287 optical effect Effects 0.000 description 2
229910052708 sodium Inorganic materials 0.000 description 2
239000011343 solid material Substances 0.000 description 2
UNXRWKVEANCORM-UHFFFAOYSA-I triphosphate(5-) Chemical compound [O-]P([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O UNXRWKVEANCORM-UHFFFAOYSA-I 0.000 description 2
LSNNMFCWUKXFEE-UHFFFAOYSA-M Bisulfite Chemical compound OS([O-])=O LSNNMFCWUKXFEE-UHFFFAOYSA-M 0.000 description 1
BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 description 1
PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 description 1
229910021536 Zeolite Inorganic materials 0.000 description 1
DPDMMXDBJGCCQC-UHFFFAOYSA-N [Na].[Cl] Chemical compound [Na].[Cl] DPDMMXDBJGCCQC-UHFFFAOYSA-N 0.000 description 1
239000000654 additive Substances 0.000 description 1
230000000996 additive effect Effects 0.000 description 1
239000003513 alkali Substances 0.000 description 1
150000001447 alkali salts Chemical class 0.000 description 1
150000004996 alkyl benzenes Chemical class 0.000 description 1
150000001450 anions Chemical class 0.000 description 1
239000007864 aqueous solution Substances 0.000 description 1
230000009286 beneficial effect Effects 0.000 description 1
229910052799 carbon Inorganic materials 0.000 description 1
125000004432 carbon atom Chemical group C* 0.000 description 1
230000015556 catabolic process Effects 0.000 description 1
238000010924 continuous production Methods 0.000 description 1
238000006731 degradation reaction Methods 0.000 description 1
HNPSIPDUKPIQMN-UHFFFAOYSA-N dioxosilane;oxo(oxoalumanyloxy)alumane Chemical compound O=[Si]=O.O=[Al]O[Al]=O HNPSIPDUKPIQMN-UHFFFAOYSA-N 0.000 description 1
238000001035 drying Methods 0.000 description 1
239000000975 dye Substances 0.000 description 1
230000005611 electricity Effects 0.000 description 1
238000005265 energy consumption Methods 0.000 description 1
230000002349 favourable effect Effects 0.000 description 1
239000004615 ingredient Substances 0.000 description 1
229910017053 inorganic salt Inorganic materials 0.000 description 1
150000002500 ions Chemical class 0.000 description 1
238000011017 operating method Methods 0.000 description 1
239000004482 other powder Substances 0.000 description 1
239000010451 perlite Substances 0.000 description 1
235000019362 perlite Nutrition 0.000 description 1
235000020030 perry Nutrition 0.000 description 1
229920006395 saturated elastomer Polymers 0.000 description 1
239000001509 sodium citrate Substances 0.000 description 1
159000000000 sodium salts Chemical class 0.000 description 1
229910052938 sodium sulfate Inorganic materials 0.000 description 1
235000011152 sodium sulphate Nutrition 0.000 description 1
239000000243 solution Substances 0.000 description 1
235000013599 spices Nutrition 0.000 description 1
238000003756 stirring Methods 0.000 description 1
HRXKRNGNAMMEHJ-UHFFFAOYSA-K trisodium citrate Chemical compound [Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O HRXKRNGNAMMEHJ-UHFFFAOYSA-K 0.000 description 1
229940038773 trisodium citrate Drugs 0.000 description 1
235000021122 unsaturated fatty acids Nutrition 0.000 description 1
150000004670 unsaturated fatty acids Chemical class 0.000 description 1
239000010457 zeolite Substances 0.000 description 1

Classifications

- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D17/00—Detergent materials or soaps characterised by their shape or physical properties
- C11D17/06—Powder; Flakes; Free-flowing mixtures; Sheets
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D11/00—Special methods for preparing compositions containing mixtures of detergents
- C11D11/04—Special methods for preparing compositions containing mixtures of detergents by chemical means, e.g. by sulfonating in the presence of other compounding ingredients followed by neutralising

Landscapes

Chemical & Material Sciences (AREA)
Life Sciences & Earth Sciences (AREA)
Engineering & Computer Science (AREA)
Chemical Kinetics & Catalysis (AREA)
Oil, Petroleum & Natural Gas (AREA)
Wood Science & Technology (AREA)
Organic Chemistry (AREA)
Detergent Compositions (AREA)

CN95194514A 1994-08-05 1995-07-24 流化床造粒 Expired - Fee Related CN1115403C (zh)

Applications Claiming Priority (2)

Application Number	Priority Date	Filing Date	Title
GB9415904A GB9415904D0 (en)	1994-08-05	1994-08-05	Process for the production of detergent composition
GB9415904.3		1994-08-05

Publications (2)

Publication Number	Publication Date
CN1155297A CN1155297A (zh)	1997-07-23
CN1115403C true CN1115403C (zh)	2003-07-23

Family

ID=10759488

Family Applications (1)

Application Number	Title	Priority Date	Filing Date
CN95194514A Expired - Fee Related CN1115403C (zh)	1994-08-05	1995-07-24	流化床造粒

Country Status (13)

Country	Link
EP (1)	EP0775193A1 (cs)
CN (1)	CN1115403C (cs)
AU (1)	AU702808B2 (cs)
BR (1)	BR9508505A (cs)
CA (1)	CA2195313A1 (cs)
CZ (1)	CZ289884B6 (cs)
GB (1)	GB9415904D0 (cs)
HU (1)	HU222907B1 (cs)
PL (1)	PL181161B1 (cs)
SK (1)	SK282576B6 (cs)
TW (1)	TW380161B (cs)
WO (1)	WO1996004359A1 (cs)
ZA (1)	ZA956415B (cs)

Families Citing this family (29)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB9526097D0 (en) *	1995-12-20	1996-02-21	Unilever Plc	Process
TW397862B (en) *	1996-09-06	2000-07-11	Kao Corp	Detergent granules and method for producing the same, and high-bulk density detergent composition
US6143711A (en) *	1996-10-04	2000-11-07	The Procter & Gamble Company	Process for making a detergent composition by non-tower process
US6172034B1 (en)	1996-10-04	2001-01-09	The Procter & Gamble	Process for making a detergent composition by non-tower process
US6211137B1 (en)	1996-10-04	2001-04-03	The Procter & Gamble Company	Process for making a detergent composition by non-tower process
US6150323A (en) *	1996-10-04	2000-11-21	The Procter & Gamble Company	Process for making a detergent composition by non-tower process
US6136777A (en) *	1996-10-04	2000-10-24	The Procter & Gamble Company	Process for making a detergent composition by non-tower process
US6211138B1 (en)	1996-10-04	2001-04-03	The Procter & Gamble Company	Process for making a detergent composition by non-tower process
US6121229A (en) *	1996-10-04	2000-09-19	The Procter & Gamble Company	Process for making a detergent composition by non-tower process
US6391844B1 (en)	1996-10-04	2002-05-21	The Procter & Gamble Company	Process for making a detergent composition by non-tower process
GB9712580D0 (en) *	1997-06-16	1997-08-20	Unilever Plc	Production of detergent granulates
GB9712587D0 (en) *	1997-06-16	1997-08-20	Unilever Plc	Production of detergent granulates
GB9712583D0 (en) *	1997-06-16	1997-08-20	Unilever Plc	Production of detergent granulates
GB9713748D0 (en) *	1997-06-27	1997-09-03	Unilever Plc	Production of detergent granulates
ES2293684T3 (es) *	1997-07-14	2008-03-16	THE PROCTER & GAMBLE COMPANY	Procedimiento para fabricar una composicion detergente de baja densidad mediante aglomeracion controlada en un secador de lecho fluido.
JP2002507629A (ja) *	1997-07-14	2002-03-12	ザ、プロクター、エンド、ギャンブル、カンパニー	粒子サイズによって塊状化を制御することによる低密度の洗剤組成物の作製方法
US6423679B1 (en)	1997-07-15	2002-07-23	The Procter & Gamble Company	Process for making high-active detergent agglomerates by multi-stage surfactant paste injection
US6440342B1 (en)	1998-07-08	2002-08-27	The Procter & Gamble Company	Process for making a low density detergent composition by controlling nozzle height in a fluid bed dryer
CN1094383C (zh) *	1998-09-11	2002-11-20	自贡市化工研究设计院	沉淀水合二氧化硅的喷雾—流化床造粒方法
WO2000024863A1 (en)	1998-10-26	2000-05-04	The Procter & Gamble Company	Processes for making granular detergent composition having improved appearance and solubility
GB9825563D0 (en)	1998-11-20	1999-01-13	Unilever Plc	Particulate laundry detergent compositions containing anionic surfactant granules
DE19855380A1 (de) *	1998-12-01	2000-06-08	Henkel Kgaa	Granulationsverfahren
DE19859778A1 (de)	1998-12-23	2000-06-29	Henkel Kgaa	Mehrphasiges Reinigungsmittel mit Naphthalinsulfonsäure-Formaldehyd-Kondensat
TR200102761T2 (tr)	1999-03-30	2002-03-21	Unilever N. V.	Deterjan tozu bileçimi.
GB9927653D0 (en)	1999-11-22	2000-01-19	Unilever Plc	Process for preparing granular detergent compositions
GB0119708D0 (en) *	2001-08-13	2001-10-03	Unilever Plc	Process for the production of detergent granules
GB0119711D0 (en) *	2001-08-13	2001-10-03	Unilever Plc	Process for the production of detergent granules
DE102005005499A1 (de) *	2005-02-04	2006-08-17	Henkel Kgaa	Verfahren zur Herstellung von Wasch- oder Reinigungsmitteln
EP2123742A1 (en)	2008-05-14	2009-11-25	The Procter and Gamble Company	A solid laundry detergent composition comprising light density silicate salt

Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1404317A (en) *	1971-10-23	1975-08-28	Bell Chemicals Pty Ltd	Manufacture of detergent powders
EP0353976A1 (en) *	1988-08-05	1990-02-07	Cussons (International) Limited	Detergents
CN1087945A (zh) *	1992-09-30	1994-06-15	亨克尔两合股份公司	表面活性剂粒状产物的制备方法

Family Cites Families (5)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
US3425948A (en) *	1966-01-03	1969-02-04	Wyandotte Chemicals Corp	Composition and process for light-weight surfactant products
ZA72295B (en) *	1971-02-01	1973-09-26	Colgate Palmolive Co	Method for neutralization of detergent acid
DD140987B1 (de) *	1979-01-05	1982-06-30	Manfred Mittelstrass	Kontinuierliches herstellungsverfahren granulierter wasch-und reinigungsmittel in wirbelschichtapparaten
RO88903A2 (ro) *	1983-11-04	1986-06-30	Intreprinderea De Detergenti"Dero",Ro	Procedeu pentru fabricarea detergentilor granulati si instalatie pentru aplicarea acestuia
US4734224A (en) *	1986-09-15	1988-03-29	The Dial Corporation	Dry neutralization process for detergent slurries

1994
- 1994-08-05 GB GB9415904A patent/GB9415904D0/en active Pending
1995
- 1995-07-24 CN CN95194514A patent/CN1115403C/zh not_active Expired - Fee Related
- 1995-07-24 SK SK145-97A patent/SK282576B6/sk unknown
- 1995-07-24 BR BR9508505A patent/BR9508505A/pt not_active IP Right Cessation
- 1995-07-24 CZ CZ1997305A patent/CZ289884B6/cs not_active IP Right Cessation
- 1995-07-24 EP EP95927721A patent/EP0775193A1/en not_active Withdrawn
- 1995-07-24 AU AU31656/95A patent/AU702808B2/en not_active Ceased
- 1995-07-24 HU HU9700357A patent/HU222907B1/hu not_active IP Right Cessation
- 1995-07-24 PL PL95318548A patent/PL181161B1/pl not_active IP Right Cessation
- 1995-07-24 WO PCT/EP1995/002935 patent/WO1996004359A1/en active IP Right Grant
- 1995-07-24 CA CA002195313A patent/CA2195313A1/en not_active Abandoned
- 1995-08-01 ZA ZA9506415A patent/ZA956415B/xx unknown
- 1995-08-09 TW TW084108296A patent/TW380161B/zh not_active IP Right Cessation

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number	Priority date	Publication date	Assignee	Title
GB1404317A (en) *	1971-10-23	1975-08-28	Bell Chemicals Pty Ltd	Manufacture of detergent powders
EP0353976A1 (en) *	1988-08-05	1990-02-07	Cussons (International) Limited	Detergents
CN1087945A (zh) *	1992-09-30	1994-06-15	亨克尔两合股份公司	表面活性剂粒状产物的制备方法

Also Published As

Publication number	Publication date
CN1155297A (zh)	1997-07-23
BR9508505A (pt)	1998-05-26
CA2195313A1 (en)	1996-02-15
AU3165695A (en)	1996-03-04
CZ289884B6 (cs)	2002-04-17
SK282576B6 (sk)	2002-10-08
HUT77715A (hu)	1998-07-28
MX9700863A (es)	1997-09-30
PL318548A1 (en)	1997-06-23
WO1996004359A1 (en)	1996-02-15
GB9415904D0 (en)	1994-09-28
HU222907B1 (hu)	2003-12-29
PL181161B1 (pl)	2001-06-29
ZA956415B (en)	1997-02-03
AU702808B2 (en)	1999-03-04
TW380161B (en)	2000-01-21
SK14597A3 (en)	1997-07-09
CZ30597A3 (en)	1997-09-17
EP0775193A1 (en)	1997-05-28

Legal Events

Date	Code	Title
1997-07-23	C06	Publication
1997-07-23	PB01	Publication
1997-11-19	C10	Entry into substantive examination
1997-11-19	SE01	Entry into force of request for substantive examination
2003-07-23	C14	Grant of patent or utility model
2003-07-23	GR01	Patent grant
2005-09-21	C19	Lapse of patent right due to non-payment of the annual fee
2005-09-21	CF01	Termination of patent right due to non-payment of annual fee

Publication	Publication Date	Title
CN1115403C (zh)	2003-07-23	流化床造粒
CN1111595C (zh)	2003-06-18	使用无机复盐通过附聚制备低密度洗涤剂组合物的方法
EP0402111B1 (en)	1995-02-01	Formation of detergent granules by deagglomeration of detergent dough
JPH0747757B2 (ja)	1995-05-24	洗剤組成物
US5629275A (en)	1997-05-13	Process for the production of surfactant-containing granules
PL184656B1 (pl)	2002-11-29	Sposób wytwarzania kompozycji detergentowej lub jej komponentu
CN1170917C (zh)	2004-10-13	洗涤剂颗粒的制备
KR960001021B1 (ko)	1996-01-17	세제 조성물 및 그 제조 방법
CN1214730A (zh)	1999-04-21	用无机复盐附聚制造低密度洗涤剂组合物的方法
CN1054631C (zh)	2000-07-19	制备高活性颗粒状洗涤剂的方法
AU751566B2 (en)	2002-08-22	Detergent powder composition
CN1343250A (zh)	2002-04-03	制备有涂层的洗涤剂颗粒的方法
CN1120229C (zh)	2003-09-03	含二氧化硅的低密度洗涤剂附聚物的制备
CN1433462A (zh)	2003-07-30	制备粒状洗涤剂组合物的方法
CN1568362A (zh)	2005-01-19	洗涤剂颗粒的制备方法
PL187377B1 (pl)	2004-06-30	Sposób wytwarzania kompozycji detergentowej lub jej komponentu
CN1116402C (zh)	2003-07-30	含二氧化硅的低密度洗涤剂附聚物的制备
CN1188145A (zh)	1998-07-22	改良油脂清除能力的颗粒洗涤剂
MXPA97000863A (en)	1998-07-03	Granulation in a fluidized bed
MXPA97002347A (en)	1998-07-03	Compositions highly active granular detergents and processing for elaboration