CN1110682A - 杂环化合物的亚磺酰化方法 - Google Patents
杂环化合物的亚磺酰化方法 Download PDFInfo
- Publication number
- CN1110682A CN1110682A CN95100789A CN95100789A CN1110682A CN 1110682 A CN1110682 A CN 1110682A CN 95100789 A CN95100789 A CN 95100789A CN 95100789 A CN95100789 A CN 95100789A CN 1110682 A CN1110682 A CN 1110682A
- Authority
- CN
- China
- Prior art keywords
- compound
- alkyl
- halogen atom
- het
- amino
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/18—One oxygen or sulfur atom
- C07D231/20—One oxygen atom attached in position 3 or 5
- C07D231/22—One oxygen atom attached in position 3 or 5 with aryl radicals attached to ring nitrogen atoms
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D233/00—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings
- C07D233/54—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members
- C07D233/66—Heterocyclic compounds containing 1,3-diazole or hydrogenated 1,3-diazole rings, not condensed with other rings having two double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D233/88—Nitrogen atoms, e.g. allantoin
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/38—Nitrogen atoms
- C07D231/40—Acylated on said nitrogen atom
-
- C—CHEMISTRY; METALLURGY
- C07—ORGANIC CHEMISTRY
- C07D—HETEROCYCLIC COMPOUNDS
- C07D231/00—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings
- C07D231/02—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings
- C07D231/10—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members
- C07D231/14—Heterocyclic compounds containing 1,2-diazole or hydrogenated 1,2-diazole rings not condensed with other rings having two or three double bonds between ring members or between ring members and non-ring members with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
- C07D231/44—Oxygen and nitrogen or sulfur and nitrogen atoms
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plural Heterocyclic Compounds (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
- Pyrrole Compounds (AREA)
- Heterocyclic Carbon Compounds Containing A Hetero Ring Having Nitrogen And Oxygen As The Only Ring Hetero Atoms (AREA)
- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Low-Molecular Organic Synthesis Reactions Using Catalysts (AREA)
- Coloring (AREA)
- Cephalosporin Compounds (AREA)
Abstract
Description
Claims (16)
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
FR9402222 | 1904-02-22 | ||
FR9402222A FR2716453B1 (fr) | 1994-02-22 | 1994-02-22 | Procédé de sulfinylation de composés hétérocycliques. |
Publications (2)
Publication Number | Publication Date |
---|---|
CN1110682A true CN1110682A (zh) | 1995-10-25 |
CN1056833C CN1056833C (zh) | 2000-09-27 |
Family
ID=9460460
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN95100789A Expired - Lifetime CN1056833C (zh) | 1994-02-22 | 1995-02-22 | 杂环化合物的亚磺酰化方法 |
Country Status (24)
Country | Link |
---|---|
US (1) | US5618945A (zh) |
EP (1) | EP0668269B1 (zh) |
JP (3) | JP3963965B2 (zh) |
KR (1) | KR100370990B1 (zh) |
CN (1) | CN1056833C (zh) |
AT (1) | ATE218127T1 (zh) |
AU (1) | AU678876B2 (zh) |
BR (1) | BR9500858A (zh) |
CA (1) | CA2143135C (zh) |
CZ (1) | CZ294640B6 (zh) |
DE (1) | DE69526815T2 (zh) |
DK (1) | DK0668269T3 (zh) |
ES (1) | ES2173932T3 (zh) |
FI (1) | FI113764B (zh) |
FR (1) | FR2716453B1 (zh) |
HU (1) | HU214283B (zh) |
IL (1) | IL112708A (zh) |
PL (1) | PL183151B1 (zh) |
PT (1) | PT668269E (zh) |
RO (1) | RO113639B1 (zh) |
RU (1) | RU2136665C1 (zh) |
SK (1) | SK282510B6 (zh) |
UA (1) | UA44226C2 (zh) |
ZA (1) | ZA951468B (zh) |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104557713A (zh) * | 2013-10-22 | 2015-04-29 | 江苏托球农化有限公司 | 高纯度氟虫腈制备方法 |
CN102171182B (zh) * | 2008-10-02 | 2015-07-22 | 巴斯夫欧洲公司 | 生产和提纯三氟甲烷亚磺酸的方法 |
CN113149873A (zh) * | 2021-03-10 | 2021-07-23 | 浙江埃森化学有限公司 | 一种三氟甲基亚磺酰氯的制备方法 |
CN113825743A (zh) * | 2019-03-19 | 2021-12-21 | 格哈达化工有限公司 | 氟虫腈的合成方法 |
CN115353490A (zh) * | 2022-09-26 | 2022-11-18 | 安徽美诺华药物化学有限公司 | 一种氟虫腈的纯化工艺 |
CN115650919A (zh) * | 2022-04-13 | 2023-01-31 | 华东理工大学 | 一种自三氯甲基亚磺酰氯制备氟虫腈的方法 |
Families Citing this family (25)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
AU6523398A (en) * | 1997-04-07 | 1998-10-30 | Mitsubishi Corporation | Pyrazole derivatives, process for preparing the same, intermediates, and pest control agent containing the same as active ingredient |
FR2784101B1 (fr) * | 1998-09-14 | 2000-11-17 | Rhodia Chimie Sa | Procede de condensation de derive(s) aromatique(s) et d'un derive sulfinique dont la chaine carbonee est attachee a la fonction sulfinique par un atome de carbone perhalogene |
GB9907458D0 (en) * | 1999-03-31 | 1999-05-26 | Rhone Poulenc Agrochimie | Processes for preparing pesticidal intermediates |
MXPA01013211A (es) | 1999-06-29 | 2002-08-12 | Mitsubishi Chem Corp | Derivados de pirazol y procedimiento para producir los mismos, pesticidas que contienen los mismos como el ingrediente activo. |
BR9917518B1 (pt) * | 1999-10-22 | 2009-08-11 | processos para a preparação de pesticidas 1-arilpirazóis e seus intermediários. | |
EP1331222A1 (en) * | 2002-01-28 | 2003-07-30 | Virbac S.A. | Environment friendly reagents and process for halogenoalkylsulfinylation of organic compounds |
AU2004234057A1 (en) * | 2003-04-29 | 2004-11-11 | Akzo Nobel N.V. | Antisolvent solidification process |
US7687533B2 (en) * | 2004-03-18 | 2010-03-30 | Pfizer Inc. | N-(1-arylpyrazol-4l) sulfonamides and their use as parasiticides |
EP1968578A4 (en) | 2005-12-14 | 2011-02-23 | Makhteshim Chem Works Ltd | POLYMORPHIC AND AMORPHOUS FORMS OF 5-AMINO-L- [2,6-DICHLORO-4- (TRIFLUOROMETHYL) PHENYL] -4- [(TRIFLUOROMETHYL) SULFINYL] -IH-PYRAZOLE-3-CARBONITRIL |
CN101168529B (zh) * | 2006-10-24 | 2011-03-23 | 温州大学 | 氟虫腈、乙虫腈及其衍生物的合成方法 |
CA2667559A1 (en) * | 2006-11-10 | 2008-05-15 | Basf Se | Process for the sulfinylation of a pyrazole derivative |
EP2083627A1 (en) | 2006-11-10 | 2009-08-05 | Basf Se | Crystalline modification of fipronil |
UA110598C2 (uk) | 2006-11-10 | 2016-01-25 | Басф Се | Спосіб одержання кристалічної модифікації фіпронілу |
WO2008055883A1 (en) | 2006-11-10 | 2008-05-15 | Basf Se | Crystalline modification of fipronil |
JP5450079B2 (ja) * | 2006-11-10 | 2014-03-26 | ビーエーエスエフ ソシエタス・ヨーロピア | ピラゾール誘導体のスルフィニル化の方法 |
EA018047B1 (ru) * | 2006-11-10 | 2013-05-30 | Басф Се | Способ сульфинилирования производной пиразола |
JP5877624B2 (ja) | 2006-11-10 | 2016-03-08 | ビーエーエスエフ ソシエタス・ヨーロピアBasf Se | フィプロニルの結晶変態 |
US7378547B1 (en) | 2006-11-28 | 2008-05-27 | E.I. Du Pont De Nemours And Company | Process for the synthesis of hydroxy aromatic acids |
FR2925493B1 (fr) * | 2007-12-19 | 2011-09-30 | Vetoquinol | Procede de preparation du fipronil et d'analogues de celui-ci. |
CN103313604B (zh) | 2011-01-14 | 2016-03-02 | K·H·伽达 | [5-氨基-1-(2,6-二氯-4-三氟甲苯基)-3-腈-4-三氟甲基亚磺酰基吡唑]中的多晶体 |
CN102093295A (zh) * | 2011-03-10 | 2011-06-15 | 江苏长青农化股份有限公司 | 一种农药杀虫剂氟虫腈的合成方法 |
TWI579274B (zh) | 2012-04-20 | 2017-04-21 | 龍馬躍公司 | 製備1-芳基-5-烷基吡唑化合物的改良方法 |
US8993613B2 (en) | 2013-04-17 | 2015-03-31 | The Hartz Mountain Corporation | Ectoparasiticidal formulations |
EP3412659A1 (en) * | 2017-06-09 | 2018-12-12 | Solvay Sa | Processes for the manufacture of sulfur-substituted pyrazole derivatives |
CN107963993A (zh) * | 2018-01-06 | 2018-04-27 | 江苏托球农化股份有限公司 | 一种高纯度氟虫腈的制备方法 |
Family Cites Families (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US5187185A (en) * | 1988-12-09 | 1993-02-16 | Rhone-Poulenc Ag Company | Pesticidal 1-arylpyrroles |
JPS55157570A (en) * | 1979-05-26 | 1980-12-08 | Nissan Chem Ind Ltd | Sulfamylimidazole derivative, and agricultural and horticultural fungicide |
US5232940A (en) * | 1985-12-20 | 1993-08-03 | Hatton Leslie R | Derivatives of N-phenylpyrazoles |
GB8713768D0 (en) * | 1987-06-12 | 1987-07-15 | May & Baker Ltd | Compositions of matter |
DE3820190A1 (de) * | 1988-06-14 | 1989-12-21 | Cassella Ag | Pyrrolderivate, ihre herstellung und ihre verwendung als pharmazeutische wirkstoffe |
CA2004776C (fr) * | 1988-12-13 | 2000-04-25 | Claude Wakselman | Procede de preparation de perfluoroalkylthioethers |
US5223525A (en) * | 1989-05-05 | 1993-06-29 | Rhone-Poulenc Ag Company | Pesticidal 1-arylimidazoles |
GB9120641D0 (en) * | 1991-09-27 | 1991-11-06 | Ici Plc | Heterocyclic compounds |
-
1994
- 1994-02-22 FR FR9402222A patent/FR2716453B1/fr not_active Expired - Lifetime
-
1995
- 1995-02-16 UA UA95028159A patent/UA44226C2/uk unknown
- 1995-02-17 EP EP95102219A patent/EP0668269B1/fr not_active Expired - Lifetime
- 1995-02-17 PT PT95102219T patent/PT668269E/pt unknown
- 1995-02-17 AT AT95102219T patent/ATE218127T1/de active
- 1995-02-17 DE DE69526815T patent/DE69526815T2/de not_active Expired - Lifetime
- 1995-02-17 DK DK95102219T patent/DK0668269T3/da active
- 1995-02-17 ES ES95102219T patent/ES2173932T3/es not_active Expired - Lifetime
- 1995-02-20 SK SK234-95A patent/SK282510B6/sk not_active IP Right Cessation
- 1995-02-20 IL IL11270895A patent/IL112708A/xx not_active IP Right Cessation
- 1995-02-21 RU RU95102481A patent/RU2136665C1/ru active
- 1995-02-21 HU HU9500522A patent/HU214283B/hu unknown
- 1995-02-21 CZ CZ1995461A patent/CZ294640B6/cs not_active IP Right Cessation
- 1995-02-21 FI FI950800A patent/FI113764B/fi not_active IP Right Cessation
- 1995-02-21 PL PL95307393A patent/PL183151B1/pl unknown
- 1995-02-21 BR BR9500858A patent/BR9500858A/pt active IP Right Grant
- 1995-02-22 US US08/392,243 patent/US5618945A/en not_active Expired - Lifetime
- 1995-02-22 CA CA002143135A patent/CA2143135C/fr not_active Expired - Lifetime
- 1995-02-22 KR KR1019950003467A patent/KR100370990B1/ko not_active IP Right Cessation
- 1995-02-22 ZA ZA951468A patent/ZA951468B/xx unknown
- 1995-02-22 AU AU12383/95A patent/AU678876B2/en not_active Expired
- 1995-02-22 JP JP03385695A patent/JP3963965B2/ja not_active Expired - Lifetime
- 1995-02-22 RO RO95-00361A patent/RO113639B1/ro unknown
- 1995-02-22 CN CN95100789A patent/CN1056833C/zh not_active Expired - Lifetime
-
2005
- 2005-01-26 JP JP2005017759A patent/JP4447478B2/ja not_active Expired - Lifetime
-
2007
- 2007-02-07 JP JP2007027926A patent/JP4731503B2/ja not_active Expired - Lifetime
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102171182B (zh) * | 2008-10-02 | 2015-07-22 | 巴斯夫欧洲公司 | 生产和提纯三氟甲烷亚磺酸的方法 |
CN104557713A (zh) * | 2013-10-22 | 2015-04-29 | 江苏托球农化有限公司 | 高纯度氟虫腈制备方法 |
CN104557713B (zh) * | 2013-10-22 | 2018-08-21 | 江苏托球农化股份有限公司 | 高纯度氟虫腈制备方法 |
CN113825743A (zh) * | 2019-03-19 | 2021-12-21 | 格哈达化工有限公司 | 氟虫腈的合成方法 |
CN113149873A (zh) * | 2021-03-10 | 2021-07-23 | 浙江埃森化学有限公司 | 一种三氟甲基亚磺酰氯的制备方法 |
CN115650919A (zh) * | 2022-04-13 | 2023-01-31 | 华东理工大学 | 一种自三氯甲基亚磺酰氯制备氟虫腈的方法 |
CN115353490A (zh) * | 2022-09-26 | 2022-11-18 | 安徽美诺华药物化学有限公司 | 一种氟虫腈的纯化工艺 |
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Owner name: BAYER CROPSCIENCE SA Free format text: FORMER OWNER: AFANGDI AGRICULTURAL SCIENCE S.A. Effective date: 20030425 |
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Owner name: AFANGDI AGRICULTURAL SCIENCE S.A. Free format text: FORMER NAME OR ADDRESS: RHONE-POULENC AGROCH-IMIE Owner name: RHONE-POULENC AGROCH-IMIE Free format text: FORMER NAME OR ADDRESS: RHONE-POULENC AGROCH-IMIE (AGROCHIMIE) |
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Assignee: Bayer Crop Science (China) Co.,Ltd. Assignor: BAYER CROPSCIENCE S.A. Contract fulfillment period: 2009.8.31 to 2015.2.21 Contract record no.: 2009990001195 Denomination of invention: Process for the sulphinylation of heterocyclic compounds Granted publication date: 20000518 License type: Exclusive license Record date: 20091028 |
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