CN109651971A - 一种耐磨亚光触感胶粘膜及其制备方法 - Google Patents

一种耐磨亚光触感胶粘膜及其制备方法 Download PDF

Info

Publication number
CN109651971A
CN109651971A CN201910088440.XA CN201910088440A CN109651971A CN 109651971 A CN109651971 A CN 109651971A CN 201910088440 A CN201910088440 A CN 201910088440A CN 109651971 A CN109651971 A CN 109651971A
Authority
CN
China
Prior art keywords
sense
wear
resisting
touch
matt
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201910088440.XA
Other languages
English (en)
Other versions
CN109651971B (zh
Inventor
罗吉尔
王微
杨军
列永潮
陈启龙
李晓鹏
吴海波
陈伟
陈婉蓉
吴妮
王建华
卢金水
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
KAIPING QIYU ADHESIVE PRODUCTS TECHNOLOGY Co Ltd
Original Assignee
KAIPING QIYU ADHESIVE PRODUCTS TECHNOLOGY Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by KAIPING QIYU ADHESIVE PRODUCTS TECHNOLOGY Co Ltd filed Critical KAIPING QIYU ADHESIVE PRODUCTS TECHNOLOGY Co Ltd
Priority to CN201910088440.XA priority Critical patent/CN109651971B/zh
Publication of CN109651971A publication Critical patent/CN109651971A/zh
Application granted granted Critical
Publication of CN109651971B publication Critical patent/CN109651971B/zh
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00—Adhesives in the form of films or foils
    • C09J7/20—Adhesives in the form of films or foils characterised by their carriers
    • C09J7/22—Plastics; Metallised plastics
    • C09J7/24—Plastics; Metallised plastics based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/241—Polyolefin, e.g.rubber
    • C09J7/243—Ethylene or propylene polymers
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/08—Processes
    • C08G18/0804—Manufacture of polymers containing ionic or ionogenic groups
    • C08G18/0819—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups
    • C08G18/0823—Manufacture of polymers containing ionic or ionogenic groups containing anionic or anionogenic groups containing carboxylate salt groups or groups forming them
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/30—Low-molecular-weight compounds
    • C08G18/32—Polyhydroxy compounds; Polyamines; Hydroxyamines
    • C08G18/3203—Polyhydroxy compounds
    • C08G18/3206—Polyhydroxy compounds aliphatic
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/40—High-molecular-weight compounds
    • C08G18/48—Polyethers
    • C08G18/4833—Polyethers containing oxyethylene units
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/671—Unsaturated compounds having only one group containing active hydrogen
    • C08G18/672—Esters of acrylic or alkyl acrylic acid having only one group containing active hydrogen
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G18/00—Polymeric products of isocyanates or isothiocyanates
    • C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
    • C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
    • C08G18/67—Unsaturated compounds having active hydrogen
    • C08G18/675—Low-molecular-weight compounds
    • C08G18/6755—Unsaturated carboxylic acids
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/04—Coating
    • C08J7/0427—Coating with only one layer of a composition containing a polymer binder
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J7/00—Chemical treatment or coating of shaped articles made of macromolecular substances
    • C08J7/12—Chemical modification
    • C08J7/123—Treatment by wave energy or particle radiation
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
    • C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
    • C08J2323/10—Homopolymers or copolymers of propene
    • C08J2323/12—Polypropene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2475/00—Characterised by the use of polyureas or polyurethanes; Derivatives of such polymers
    • C08J2475/04—Polyurethanes
    • C08J2475/08—Polyurethanes from polyethers
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/10—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/122—Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/302—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00—Additional features of adhesives in the form of films or foils
    • C09J2301/30—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier
    • C09J2301/312—Additional features of adhesives in the form of films or foils characterized by the chemical, physicochemical or physical properties of the adhesive or the carrier parameters being the characterizing feature
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2423/00—Presence of polyolefin
    • C09J2423/10—Presence of homo or copolymers of propene
    • C09J2423/106—Presence of homo or copolymers of propene in the substrate

Landscapes

  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Wood Science & Technology (AREA)
  • General Chemical & Material Sciences (AREA)
  • Manufacturing & Machinery (AREA)
  • Adhesives Or Adhesive Processes (AREA)

Abstract

本发明公开了一种耐摩擦亚光触感胶粘膜，其自上而下由耐磨触感油层、BOPP亚光基膜层和水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数≤36达因。本发明利用润湿指数≤36达因的耐磨触感油层与水性压敏胶粘层可直接收卷解卷的特性，无需使用离型纸或离型膜，且具有触感效果良好、初粘力和持粘力适中、无残胶、环保的优点。本发明还公开了该耐摩擦亚光触感胶粘膜的制备方法，其操作过程可控性强，有利于大规模工业化生产，制备得的耐磨亚光触感胶粘膜可直接进行标签覆膜。

Description

一种耐磨亚光触感胶粘膜及其制备方法
技术领域
本发明涉及胶粘膜领域，特别涉及一种触感胶粘膜。
背景技术
触感膜是上光膜中国的一种新品种，其具有增加标签表面和纸盒表面的质感的功能。触感膜用手抚之有绒面感，是高档包装盒或标签的表面复合材料。近年来，国内外已研究出有触感效果的膜材，但应用上存在障碍，主要是不方便使用。现有的触感油涂层与胶黏剂的结合力大，所以不能直接收卷，要衬一层离型纸或离型膜再收卷，使用时去掉离型材料。行业中大部分用户嫌除去离型纸或离型膜麻烦而又浪费(成本高)，所以直接购买未涂胶粘剂的触感膜进行现场临时涂胶覆膜，而这种方式往往存在效率低、灵活性低、能耗高、使用溶剂胶造成环境污染等弊端。
发明内容
本发明的目的在于针对上述现有技术的不足，提供一种耐磨亚光触感胶粘膜，同时提供该触感胶粘膜的制备方法。
本发明所采取的技术方案是：一种耐摩擦亚光触感胶粘膜，其自上而下由耐磨触感油层、BOPP亚光基膜层和水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数≤36达因。
作为上述方案的进一步改进，所述BOPP亚光基膜层为经双面电晕处理的BOPP亚光基膜层。
作为上述方案的进一步改进，所述耐磨触感油的制备方法如下：
1)将聚乙二醇加入到密封容器中，加热至105～115℃进行真空预脱水，冷却至50℃并开启冷凝回流，在体系中滴加二异氰酸酯甲苯、丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比为6:6:2配制的混合物，搅拌；
2)待体系经升温后降温至50℃时，滴加丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比1:1配制的混合物，控制体系温度在78～82℃范围内，控制滴加时间为2h；
3)待体系温度为60℃时，滴加体系总质量2％的1,4-丁二醇进行交联反应，降温至60℃，加入摩尔量与9,10-烯基二十二正羧酸相同的丁二胺进行中和，后加入含有5％的乳化剂的去离子水进行乳化，搅拌，得耐磨触感油。
具体地，本发明中触感油的触感效果是由聚乙二醇与二异氰酸酯甲苯进行缩合反应形成的高聚物提供的，其柔软而富触感效果，但却不耐磨。引入较为耐磨的聚合物吸附于其分子链可有效提高微观方面的耐磨性而不影响宏观感觉的柔软性，因此引入耐磨聚合物——不饱和单体9,10-烯基二十二正羧酸，其经丁二胺中和羧基达到理想的微观硬度，然而该耐磨聚合物与柔软聚合物链不相容。本发明通过引入中间体——丙烯酸羟乙酯，利用其酯基与柔软聚合物分子有一定的亲和力，而其烯基为不饱和键，经过加热并加入过氧化苯甲酰引发聚合反应，再加少量二丁基锡二月桂酸酯作为催化剂，可以在较低的温度如78～82℃下聚合，即可打开烯键进行聚合，这样方才能如愿将耐磨物质吸附到柔软聚合物分子链中，从而达到增加触感油耐磨度的目的。
作为上述方案的进一步改进，步骤2)中所述丙烯酸羟乙酯和9,10-烯基二十二正羧酸的混合物中含有占混合物总重量1％的氧化苯甲酰和0.1％的二丁基锡二月桂酸酯。
作为上述方案的进一步改进，步骤3)中所述的乳化剂为OP-10。
作为上述方案的进一步改进，步骤3)中所述的离子水的添加量为中和后体系中重量的2倍。
作为上述方案的进一步改进，所述耐磨触感油层的厚度为1～5μm。具体地，对耐磨触感油层厚度的限定有利于降低水性压敏粘胶层的附着力，从而使该耐磨亚光触感胶粘膜进行解卷时减少变形量。
作为上述方案的进一步改进，所述BOPP亚光基膜层的厚度为18～20μm。
作为上述方案的进一步改进，所述水性压敏胶粘层的厚度为4～8μm。
本发明所采取的另一个技术方案是：一种如上项所述的耐磨亚光触感胶粘膜的制备方法，其包括如下工艺步骤：对BOPP亚光基膜进行双面电晕处理，得BOPP亚光基膜层，在所述BOPP亚光基膜层的上表面涂覆耐磨触感油，烘干固化，形成耐磨触感油层，在所述BOPP亚光基膜层的下表面涂覆水性压敏胶粘剂，烘干固化，形成水性压敏胶粘剂层，直接收卷得成品。
本发明的有益效果是：
本发明利用润湿指数≤36达因的耐磨触感油层与水性压敏胶粘层可直接收卷解卷的特性，无需使用离型纸或离型膜，且具有触感效果良好、初粘力和持粘力适中、无残胶、环保的优点。
本发明通过对耐磨触感油的优化，使得该耐磨亚光触感胶粘膜具有180度剥离力≥4N/24mm、初粘力≤10cm、持粘力≥30min的综合性能。
本发明的制备方法操作过程可控性强，有利于大规模工业化生产，其制备得的耐磨亚光触感胶粘膜可直接进行标签覆膜。
具体实施方式
下面结合实施例对本发明进行具体描述，以便于所属技术领域的人员对本发明的理解。有必要在此特别指出的是，实施例只是用于对本发明做进一步说明，不能理解为对本发明保护范围的限制，所属领域技术熟练人员，根据上述发明内容对本发明作出的非本质性的改进和调整，应仍属于本发明的保护范围。同时下述所提及的原料未详细说明的，均为市售产品；未详细提及的工艺步骤或制备方法为均为本领域技术人员所知晓的工艺步骤或制备方法。
实施例1
一种耐摩擦亚光触感胶粘膜，其自上而下由厚度为1μm的耐磨触感油层、厚度为20μm的BOPP亚光基膜层和厚度为4μm的水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数为36达因。
制备方法：
1)对BOPP亚光基膜进行双面电晕处理，得BOPP亚光基膜层；
2)在所述BOPP亚光基膜层的上表面涂覆耐磨触感油，烘干固化，形成耐磨触感油层；
3)在所述BOPP亚光基膜层的下表面涂覆水性压敏胶粘剂，烘干固化，形成水性压敏胶粘剂层，直接收卷得实施例1成品。
本实施例中所述耐磨触感油、BOPP亚光基膜和水性压敏胶黏剂均为市售产品。将实施例1成品进行标签覆膜，其180度剥离力为4N/24mm、初粘力为10cm、持粘力为30min。
实施例2
一种耐摩擦亚光触感胶粘膜，其自上而下由厚度为5μm的耐磨触感油层、厚度为18μm的BOPP亚光基膜层和厚度为8μm的水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数为35达因。
制备方法：
1)对BOPP亚光基膜进行双面电晕处理，得BOPP亚光基膜层；
2)在所述BOPP亚光基膜层的上表面涂覆耐磨触感油，烘干固化，形成耐磨触感油层；
3)在所述BOPP亚光基膜层的下表面涂覆水性压敏胶粘剂，烘干固化，形成水性压敏胶粘剂层，直接收卷得实施例2成品。
本实施例中所述耐磨触感油、BOPP亚光基膜和水性压敏胶黏剂均为市售产品。将实施例2成品进行标签覆膜，其180度剥离力为4N/24mm、初粘力为10cm、持粘力为30min。
实施例3
一种耐摩擦亚光触感胶粘膜，其自上而下由厚度为1μm的耐磨触感油层、厚度为20μm的BOPP亚光基膜层和厚度为4μm的水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数为32达因。
制备方法：
1)对BOPP亚光基膜进行双面电晕处理，得BOPP亚光基膜层；
2)在所述BOPP亚光基膜层的上表面涂覆耐磨触感油，烘干固化，形成耐磨触感油层；
3)在所述BOPP亚光基膜层的下表面涂覆水性压敏胶粘剂，烘干固化，形成水性压敏胶粘剂层，直接收卷得实施例3成品。
本实施例中所述BOPP亚光基膜和水性压敏胶黏剂均为市售产品。所述耐磨触感油由以下制备方法获得：
1)将聚乙二醇加入到密封容器中，加热至105℃进行真空预脱水1h，冷却至50℃并开启冷凝回流，在体系中滴加二异氰酸酯甲苯、丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比为6:6:2配制的混合物，所述丙烯酸羟乙酯和9,10-烯基二十二正羧酸的混合物中含有占混合物总重量1％的氧化苯甲酰和0.1％的二丁基锡二月桂酸酯，搅拌；
2)待体系经升温后降温至50℃时，滴加丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比1:1配制的混合物，控制体系温度在78～82℃范围内，控制滴加时间为2h；
3)待体系温度为60℃时，滴加体系总质量2％的1,4-丁二醇进行交联反应，降温至60℃，加入摩尔量与9,10-烯基二十二正羧酸相同的丁二胺进行中和，后加入含有5％的OP-10的去离子水进行乳化，离子水的添加量为中和后体系中重量的2倍，搅拌，得本实施例耐磨触感油。
将上述实施例3成品进行标签覆膜，其180度剥离力为4.4N/24mm、初粘力为8cm、持粘力为38min。
实施例4
一种耐摩擦亚光触感胶粘膜，其自上而下由厚度为5μm的耐磨触感油层、厚度为18μm的BOPP亚光基膜层和厚度为8μm的水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数为33达因。
制备方法：
1)对BOPP亚光基膜进行双面电晕处理，得BOPP亚光基膜层；
2)在所述BOPP亚光基膜层的上表面涂覆耐磨触感油，烘干固化，形成耐磨触感油层；
3)在所述BOPP亚光基膜层的下表面涂覆水性压敏胶粘剂，烘干固化，形成水性压敏胶粘剂层，直接收卷得实施例4成品。
本实施例中所述BOPP亚光基膜和水性压敏胶黏剂均为市售产品。所述耐磨触感油由以下制备方法获得：
1)将聚乙二醇加入到密封容器中，加热至115℃进行真空预脱水1h，冷却至50℃并开启冷凝回流，在体系中滴加二异氰酸酯甲苯、丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比为6:6:2配制的混合物，所述丙烯酸羟乙酯和9,10-烯基二十二正羧酸的混合物中含有占混合物总重量1％的氧化苯甲酰和0.1％的二丁基锡二月桂酸酯，搅拌；
2)待体系经升温后降温至50℃时，滴加丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比1:1配制的混合物，控制体系温度在78～82℃范围内，控制滴加时间为2h；
3)待体系温度为60℃时，滴加体系总质量2％的1,4-丁二醇进行交联反应，降温至60℃，加入摩尔量与9,10-烯基二十二正羧酸相同的丁二胺进行中和，后加入含有5％的OP-10的去离子水进行乳化，离子水的添加量为中和后体系中重量的2倍，搅拌，得本实施例耐磨触感油。
将上述实施例4成品进行标签覆膜，其180度剥离力为4.2N/24mm、初粘力为8.5cm、持粘力为35min。
实施例5
一种耐摩擦亚光触感胶粘膜，其自上而下由厚度为3μm的耐磨触感油层、厚度为19μm的BOPP亚光基膜层和厚度为6μm的水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数为30达因。
制备方法：
1)对BOPP亚光基膜进行双面电晕处理，得BOPP亚光基膜层；
2)在所述BOPP亚光基膜层的上表面涂覆耐磨触感油，烘干固化，形成耐磨触感油层；
3)在所述BOPP亚光基膜层的下表面涂覆水性压敏胶粘剂，烘干固化，形成水性压敏胶粘剂层，直接收卷得实施例5成品。
本实施例中所述BOPP亚光基膜和水性压敏胶黏剂均为市售产品。所述耐磨触感油由以下制备方法获得：
1)将聚乙二醇加入到密封容器中，加热至110℃进行真空预脱水1h，冷却至50℃并开启冷凝回流，在体系中滴加二异氰酸酯甲苯、丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比为6:6:2配制的混合物，所述丙烯酸羟乙酯和9,10-烯基二十二正羧酸的混合物中含有占混合物总重量1％的氧化苯甲酰和0.1％的二丁基锡二月桂酸酯，搅拌；
2)待体系经升温后降温至50℃时，滴加丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比1:1配制的混合物，控制体系温度在78～82℃范围内，控制滴加时间为2h；
3)待体系温度为60℃时，滴加体系总质量2％的1,4-丁二醇进行交联反应，降温至60℃，加入摩尔量与9,10-烯基二十二正羧酸相同的丁二胺进行中和，后加入含有5％的OP-10的去离子水进行乳化，离子水的添加量为中和后体系中重量的2倍，搅拌，得本实施例耐磨触感油。
将上述实施例5成品进行标签覆膜，其180度剥离力为4.3N/24mm、初粘力为9cm、持粘力为33min。
上述实施例为本发明的优选实施例，凡与本发明类似的工艺及所作的等效变化，均应属于本发明的保护范畴。

Claims (10)

1.一种耐磨亚光触感胶粘膜，其特征在于：自上而下由耐磨触感油层、BOPP亚光基膜层和水性压敏胶粘层组成，所述耐磨触感油层的上表面的润湿指数≤36达因。
2.根据权利要求1所述的一种耐磨亚光触感胶粘膜，其特征在于：所述BOPP亚光基膜层为经双面电晕处理的BOPP亚光基膜层。
3.根据权利要求1所述的一种耐磨亚光触感胶粘膜，其特征在于：所述耐磨触感油的制备方法如下：
1)将聚乙二醇加入到密封容器中，加热至105～115℃进行真空预脱水，冷却至50℃并开启冷凝回流，在体系中滴加二异氰酸酯甲苯、丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比为6:6:2配制的混合物，搅拌；
2)待体系经升温后降温至50℃时，滴加丙烯酸羟乙酯和9,10-烯基二十二正羧酸按重量比1:1配制的混合物，控制体系温度在78～82℃范围内，控制滴加时间为2h；
3)待体系温度为60℃时，滴加体系总质量2％的1,4-丁二醇进行交联反应，降温至60℃，加入摩尔量与9,10-烯基二十二正羧酸相同的丁二胺进行中和，后加入含有5％的乳化剂的去离子水进行乳化，搅拌，得耐磨触感油。
4.根据权利要求3所述的一种耐磨亚光触感胶粘膜，其特征在于：步骤2)中所述丙烯酸羟乙酯和9,10-烯基二十二正羧酸的混合物中含有占混合物总重量1％的氧化苯甲酰和0.1％的二丁基锡二月桂酸酯。
5.根据权利要求3所述的一种耐磨亚光触感胶粘膜，其特征在于：步骤3)中所述的乳化剂为OP-10。
6.根据权利要求3所述的一种耐磨亚光触感胶粘膜，其特征在于：步骤3)中所述的离子水的添加量为中和后体系中重量的2倍。
7.根据权利要求1所述的一种耐磨亚光触感胶粘膜，其特征在于：所述耐磨触感油层的厚度为1～5μm。
8.根据权利要求1所述的一种耐磨亚光触感胶粘膜，其特征在于：所述BOPP亚光基膜层的厚度为18～20μm。
9.根据权利要求1所述的一种耐磨亚光触感胶粘膜，其特征在于：所述水性压敏胶粘层的厚度为4～8μm。
10.一种如权利要求1～9任一项所述的耐磨亚光触感胶粘膜的制备方法，其特征在于包括如下工艺步骤：对BOPP亚光基膜进行双面电晕处理，得BOPP亚光基膜层，在所述BOPP亚光基膜层的上表面涂覆耐磨触感油，烘干固化，形成耐磨触感油层，在所述BOPP亚光基膜层的下表面涂覆水性压敏胶粘剂，烘干固化，形成水性压敏胶粘剂层，直接收卷得成品。
CN201910088440.XA 2019-01-31 2019-01-31 一种耐磨亚光触感胶粘膜及其制备方法 Active CN109651971B (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201910088440.XA CN109651971B (zh) 2019-01-31 2019-01-31 一种耐磨亚光触感胶粘膜及其制备方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201910088440.XA CN109651971B (zh) 2019-01-31 2019-01-31 一种耐磨亚光触感胶粘膜及其制备方法

Publications (2)

Publication Number Publication Date
CN109651971A true CN109651971A (zh) 2019-04-19
CN109651971B CN109651971B (zh) 2023-04-18

Family

ID=66122494

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201910088440.XA Active CN109651971B (zh) 2019-01-31 2019-01-31 一种耐磨亚光触感胶粘膜及其制备方法

Country Status (1)

Country Link
CN (1) CN109651971B (zh)

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110564314A (zh) * 2019-08-01 2019-12-13 联冠(开平)胶粘制品有限公司 一种适用碳带打印的裱膜胶带及其生产工艺
CN117645843A (zh) * 2023-10-18 2024-03-05 皇冠新材料科技股份有限公司 一种保护膜胶粘带及其制备方法

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160229156A1 (en) * 2013-04-09 2016-08-11 Jiangsu Kangdexin Composite Material Co., Ltd. Matte thermal laminating film and preparing method thereof
CN205498184U (zh) * 2016-01-28 2016-08-24 广东普莱斯新材料科技有限公司 一种耐刮触感包装膜
CN106833424A (zh) * 2017-03-22 2017-06-13 北京康得新功能材料有限公司 外涂型抗静电型预涂膜及其生产方法
CN106945351A (zh) * 2017-04-13 2017-07-14 北京康得新功能材料有限公司 一种环保型表面触感预涂膜及其制备方法
CN206692592U (zh) * 2017-03-22 2017-12-01 北京康得新功能材料有限公司 一种包装用抗静电型预涂膜
CN107815265A (zh) * 2017-11-21 2018-03-20 江门新时代包装材料有限公司 一种超透明压敏胶粘带的制备方法及配方

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20160229156A1 (en) * 2013-04-09 2016-08-11 Jiangsu Kangdexin Composite Material Co., Ltd. Matte thermal laminating film and preparing method thereof
CN205498184U (zh) * 2016-01-28 2016-08-24 广东普莱斯新材料科技有限公司 一种耐刮触感包装膜
CN106833424A (zh) * 2017-03-22 2017-06-13 北京康得新功能材料有限公司 外涂型抗静电型预涂膜及其生产方法
CN206692592U (zh) * 2017-03-22 2017-12-01 北京康得新功能材料有限公司 一种包装用抗静电型预涂膜
CN106945351A (zh) * 2017-04-13 2017-07-14 北京康得新功能材料有限公司 一种环保型表面触感预涂膜及其制备方法
CN107815265A (zh) * 2017-11-21 2018-03-20 江门新时代包装材料有限公司 一种超透明压敏胶粘带的制备方法及配方

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110564314A (zh) * 2019-08-01 2019-12-13 联冠(开平)胶粘制品有限公司 一种适用碳带打印的裱膜胶带及其生产工艺
CN117645843A (zh) * 2023-10-18 2024-03-05 皇冠新材料科技股份有限公司 一种保护膜胶粘带及其制备方法

Also Published As

Publication number Publication date
CN109651971B (zh) 2023-04-18

Similar Documents

Publication Publication Date Title
CN102732174B (zh) 预涂膜及该预涂膜的制备方法
CN100588690C (zh) 用于金属的阻燃型紫外光固化涂料
CN109651971A (zh) 一种耐磨亚光触感胶粘膜及其制备方法
CN102199241B (zh) 一种水性含氟丙烯酸酯乳液的制备方法及其应用
CN105068288B (zh) 一种智能调光膜及其制备方法
CN101497730A (zh) 一种含氟离型剂及基于该离型剂形成的离型涂层的离型纸
CN104371508A (zh) 一种耐候涂层组合膜
CN102516446B (zh) 一种水性丙烯酸树脂及其制备方法和应用
CN107253383A (zh) 一种热弯膜及其制备方法
CN106833449A (zh) 一种可生物降解的改性聚乳酸胶带及其制备方法
CN104962161B (zh) 一种水性可剥离涂料
CN108586657A (zh) 水性涂料用的丙烯酸乳液
CN1355267A (zh) 具有“核－壳”结构的互穿网络水性聚氨酯胶乳粘合剂
CN108795166A (zh) 一种高耐磨环保水性光油及其制备方法
CN109056350A (zh) 一种有机硅合成革的制备方法
CN110066360B (zh) 一种抗回黏水性丙烯酸乳液及其制备方法和应用
CN109796894A (zh) 一种泡棉胶带及其制备方法
CN202847030U (zh) 预涂膜
CN101205450A (zh) 水性复膜胶及其制作方法
CN108707245B (zh) 一种聚乙烯片材表面的在线亲水性处理方法
CN106753012A (zh) 一种亲水性防雾膜及其制备方法
CN110041859A (zh) 无底纸cpp冷裱膜用水性压敏胶及其制备方法和冷裱膜
CN110003807A (zh) 一种水性乳胶异种接枝材料及其制备方法、以及其在软质pvc薄膜压敏胶带中的应用
CN206406558U (zh) 一种亲水性防雾膜
CN109796917A (zh) 一种uv固化聚氨酯丙烯酸酯粘合剂的制备方法

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant