CN108250344A - 一种低膨胀速度纳米级吸水微球及其制备方法 - Google Patents
一种低膨胀速度纳米级吸水微球及其制备方法 Download PDFInfo
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- CN108250344A CN108250344A CN201711440702.1A CN201711440702A CN108250344A CN 108250344 A CN108250344 A CN 108250344A CN 201711440702 A CN201711440702 A CN 201711440702A CN 108250344 A CN108250344 A CN 108250344A
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- 125000001400 nonyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 1
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Classifications
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/04—Acids; Metal salts or ammonium salts thereof
- C08F220/06—Acrylic acid; Methacrylic acid; Metal salts or ammonium salts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B82—NANOTECHNOLOGY
- B82Y—SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- B82Y40/00—Manufacture or treatment of nanostructures
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
- C09K8/506—Compositions based on water or polar solvents containing organic compounds
- C09K8/508—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/5083—Compositions based on water or polar solvents containing organic compounds macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
- C09K8/506—Compositions based on water or polar solvents containing organic compounds
- C09K8/508—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/5086—Compositions based on water or polar solvents containing organic compounds macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/504—Compositions based on water or polar solvents
- C09K8/506—Compositions based on water or polar solvents containing organic compounds
- C09K8/508—Compositions based on water or polar solvents containing organic compounds macromolecular compounds
- C09K8/512—Compositions based on water or polar solvents containing organic compounds macromolecular compounds containing cross-linking agents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K8/00—Compositions for drilling of boreholes or wells; Compositions for treating boreholes or wells, e.g. for completion or for remedial operations
- C09K8/50—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls
- C09K8/516—Compositions for plastering borehole walls, i.e. compositions for temporary consolidation of borehole walls characterised by their form or by the form of their components, e.g. encapsulated material
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Nanotechnology (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Manufacturing & Machinery (AREA)
- Crystallography & Structural Chemistry (AREA)
- Medicinal Chemistry (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Polymerisation Methods In General (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201711440702.1A CN108250344B (zh) | 2017-12-27 | 2017-12-27 | 一种低膨胀速度纳米级吸水微球及其制备方法 |
Applications Claiming Priority (1)
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CN201711440702.1A CN108250344B (zh) | 2017-12-27 | 2017-12-27 | 一种低膨胀速度纳米级吸水微球及其制备方法 |
Publications (2)
Publication Number | Publication Date |
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CN108250344A true CN108250344A (zh) | 2018-07-06 |
CN108250344B CN108250344B (zh) | 2020-11-13 |
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CN201711440702.1A Active CN108250344B (zh) | 2017-12-27 | 2017-12-27 | 一种低膨胀速度纳米级吸水微球及其制备方法 |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109265896A (zh) * | 2018-09-15 | 2019-01-25 | 张青美 | 一种防水型吸水膨胀橡胶的制备方法 |
CN110204641A (zh) * | 2019-07-11 | 2019-09-06 | 西南石油大学 | 一种调剖用交联聚合物微球及其制备方法 |
CN110372818A (zh) * | 2019-07-17 | 2019-10-25 | 中国石油大学(北京) | 一种Poly(AM-BA)共聚微球及其制备方法和应用 |
CN110963744A (zh) * | 2019-12-16 | 2020-04-07 | 湖北工业大学 | 一种逐级膨胀的液体膨胀剂及其制备方法 |
CN114195135A (zh) * | 2021-12-31 | 2022-03-18 | 苏州知益微球科技有限公司 | 一种石墨烯微球的制备方法及应用 |
CN115322760A (zh) * | 2022-10-11 | 2022-11-11 | 山东诺尔生物科技有限公司 | 一种两性离子型堵水调剖剂及其制备方法 |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277175A (zh) * | 2013-07-09 | 2015-01-14 | 中国石油化工股份有限公司 | 聚丙烯酰胺反相微乳液调驱体系 |
CN105315403A (zh) * | 2014-07-24 | 2016-02-10 | 中国石油化工股份有限公司 | 耐温抗盐活性微球及其制备方法和应用 |
CN106866880A (zh) * | 2015-12-14 | 2017-06-20 | 中国石油化工股份有限公司 | 多分散聚丙烯酰胺微球体系及其制备方法 |
-
2017
- 2017-12-27 CN CN201711440702.1A patent/CN108250344B/zh active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104277175A (zh) * | 2013-07-09 | 2015-01-14 | 中国石油化工股份有限公司 | 聚丙烯酰胺反相微乳液调驱体系 |
CN105315403A (zh) * | 2014-07-24 | 2016-02-10 | 中国石油化工股份有限公司 | 耐温抗盐活性微球及其制备方法和应用 |
CN106866880A (zh) * | 2015-12-14 | 2017-06-20 | 中国石油化工股份有限公司 | 多分散聚丙烯酰胺微球体系及其制备方法 |
Non-Patent Citations (1)
Title |
---|
雷光伦: "《孔喉尺度弹性微球深部调驱新技术》", 31 May 2011, 中国石油大学出版社 * |
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CN109265896A (zh) * | 2018-09-15 | 2019-01-25 | 张青美 | 一种防水型吸水膨胀橡胶的制备方法 |
CN109265896B (zh) * | 2018-09-15 | 2020-12-11 | 嘉兴华维新能源有限公司 | 一种防水型吸水膨胀橡胶的制备方法 |
CN110204641A (zh) * | 2019-07-11 | 2019-09-06 | 西南石油大学 | 一种调剖用交联聚合物微球及其制备方法 |
CN110204641B (zh) * | 2019-07-11 | 2021-07-23 | 西南石油大学 | 一种调剖用交联聚合物微球及其制备方法 |
CN110372818A (zh) * | 2019-07-17 | 2019-10-25 | 中国石油大学(北京) | 一种Poly(AM-BA)共聚微球及其制备方法和应用 |
CN110963744A (zh) * | 2019-12-16 | 2020-04-07 | 湖北工业大学 | 一种逐级膨胀的液体膨胀剂及其制备方法 |
CN110963744B (zh) * | 2019-12-16 | 2021-09-03 | 湖北工业大学 | 一种逐级膨胀的液体膨胀剂及其制备方法 |
CN114195135A (zh) * | 2021-12-31 | 2022-03-18 | 苏州知益微球科技有限公司 | 一种石墨烯微球的制备方法及应用 |
CN115322760A (zh) * | 2022-10-11 | 2022-11-11 | 山东诺尔生物科技有限公司 | 一种两性离子型堵水调剖剂及其制备方法 |
CN115322760B (zh) * | 2022-10-11 | 2022-12-20 | 山东诺尔生物科技有限公司 | 一种两性离子型堵水调剖剂及其制备方法 |
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