CN107922806A - 层压用粘接剂、多层膜和使用了其的二次电池 - Google Patents
层压用粘接剂、多层膜和使用了其的二次电池 Download PDFInfo
- Publication number
- CN107922806A CN107922806A CN201680049429.7A CN201680049429A CN107922806A CN 107922806 A CN107922806 A CN 107922806A CN 201680049429 A CN201680049429 A CN 201680049429A CN 107922806 A CN107922806 A CN 107922806A
- Authority
- CN
- China
- Prior art keywords
- film
- bonding agent
- secondary cell
- resin
- mentioned
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000007767 bonding agent Substances 0.000 title claims abstract description 46
- 238000003475 lamination Methods 0.000 title claims abstract description 31
- PPBRXRYQALVLMV-UHFFFAOYSA-N Styrene Chemical compound C=CC1=CC=CC=C1 PPBRXRYQALVLMV-UHFFFAOYSA-N 0.000 claims abstract description 59
- 229920005989 resin Polymers 0.000 claims abstract description 39
- 239000011347 resin Substances 0.000 claims abstract description 39
- 230000002378 acidificating effect Effects 0.000 claims abstract description 33
- 229920005672 polyolefin resin Polymers 0.000 claims abstract description 30
- 150000008064 anhydrides Chemical group 0.000 claims abstract description 29
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- 229920000098 polyolefin Polymers 0.000 claims abstract description 27
- 229910052751 metal Inorganic materials 0.000 claims abstract description 26
- 239000002184 metal Substances 0.000 claims abstract description 26
- 238000002156 mixing Methods 0.000 claims abstract description 6
- -1 carboxylic acids acid anhydride Chemical class 0.000 claims description 42
- 230000001070 adhesive effect Effects 0.000 claims description 31
- 229920001577 copolymer Polymers 0.000 claims description 31
- 239000000853 adhesive Substances 0.000 claims description 30
- 239000000463 material Substances 0.000 claims description 27
- 239000000178 monomer Substances 0.000 claims description 24
- 239000002904 solvent Substances 0.000 claims description 21
- 239000008151 electrolyte solution Substances 0.000 claims description 18
- 239000003960 organic solvent Substances 0.000 claims description 16
- 150000001336 alkenes Chemical class 0.000 claims description 14
- 150000001735 carboxylic acids Chemical class 0.000 claims description 13
- 238000007789 sealing Methods 0.000 claims description 12
- 238000012986 modification Methods 0.000 claims description 10
- 230000004048 modification Effects 0.000 claims description 10
- 239000012046 mixed solvent Substances 0.000 claims description 9
- 229910052799 carbon Inorganic materials 0.000 claims description 8
- 150000001875 compounds Chemical class 0.000 claims description 8
- 238000007493 shaping process Methods 0.000 claims description 8
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 7
- 229920001519 homopolymer Polymers 0.000 claims description 7
- 238000004806 packaging method and process Methods 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- 125000002723 alicyclic group Chemical group 0.000 claims description 6
- 150000002148 esters Chemical class 0.000 claims description 5
- 150000001298 alcohols Chemical class 0.000 claims description 4
- 125000001931 aliphatic group Chemical group 0.000 claims description 4
- XYLMUPLGERFSHI-UHFFFAOYSA-N alpha-Methylstyrene Chemical compound CC(=C)C1=CC=CC=C1 XYLMUPLGERFSHI-UHFFFAOYSA-N 0.000 claims description 4
- 125000003118 aryl group Chemical group 0.000 claims description 4
- 239000012530 fluid Substances 0.000 claims description 4
- 239000004593 Epoxy Substances 0.000 claims description 2
- 230000015572 biosynthetic process Effects 0.000 claims description 2
- 229920006267 polyester film Polymers 0.000 claims description 2
- 229920002554 vinyl polymer Polymers 0.000 claims description 2
- 150000001408 amides Chemical class 0.000 claims 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims 1
- 239000010931 gold Substances 0.000 claims 1
- 229910052737 gold Inorganic materials 0.000 claims 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 claims 1
- 239000003792 electrolyte Substances 0.000 description 17
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 16
- QQONPFPTGQHPMA-UHFFFAOYSA-N Propene Chemical group CC=C QQONPFPTGQHPMA-UHFFFAOYSA-N 0.000 description 16
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 description 15
- 239000003822 epoxy resin Substances 0.000 description 13
- 229920000647 polyepoxide Polymers 0.000 description 13
- KFZMGEQAYNKOFK-UHFFFAOYSA-N Isopropanol Chemical compound CC(C)O KFZMGEQAYNKOFK-UHFFFAOYSA-N 0.000 description 12
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- IISBACLAFKSPIT-UHFFFAOYSA-N bisphenol A Chemical class C=1C=C(O)C=CC=1C(C)(C)C1=CC=C(O)C=C1 IISBACLAFKSPIT-UHFFFAOYSA-N 0.000 description 11
- 238000006243 chemical reaction Methods 0.000 description 11
- 238000000576 coating method Methods 0.000 description 11
- 150000002924 oxiranes Chemical class 0.000 description 11
- RTZKZFJDLAIYFH-UHFFFAOYSA-N Diethyl ether Chemical compound CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 description 10
- 238000000034 method Methods 0.000 description 10
- VLKZOEOYAKHREP-UHFFFAOYSA-N n-Hexane Chemical compound CCCCCC VLKZOEOYAKHREP-UHFFFAOYSA-N 0.000 description 10
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 9
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 9
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 9
- HBBGRARXTFLTSG-UHFFFAOYSA-N Lithium ion Chemical compound [Li+] HBBGRARXTFLTSG-UHFFFAOYSA-N 0.000 description 9
- 239000011248 coating agent Substances 0.000 description 9
- 229960002050 hydrofluoric acid Drugs 0.000 description 9
- 239000000126 substance Substances 0.000 description 9
- 239000002131 composite material Substances 0.000 description 8
- 239000012948 isocyanate Substances 0.000 description 8
- CIHOLLKRGTVIJN-UHFFFAOYSA-N tert‐butyl hydroperoxide Chemical compound CC(C)(C)OO CIHOLLKRGTVIJN-UHFFFAOYSA-N 0.000 description 8
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 8
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Natural products CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 7
- FPYJFEHAWHCUMM-UHFFFAOYSA-N maleic anhydride Chemical compound O=C1OC(=O)C=C1 FPYJFEHAWHCUMM-UHFFFAOYSA-N 0.000 description 7
- 238000004519 manufacturing process Methods 0.000 description 7
- UAEPNZWRGJTJPN-UHFFFAOYSA-N methylcyclohexane Chemical compound CC1CCCCC1 UAEPNZWRGJTJPN-UHFFFAOYSA-N 0.000 description 7
- 239000000203 mixture Substances 0.000 description 7
- 238000003860 storage Methods 0.000 description 7
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 6
- 239000005977 Ethylene Substances 0.000 description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 description 6
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 description 6
- 229910001416 lithium ion Inorganic materials 0.000 description 6
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 5
- 239000012790 adhesive layer Substances 0.000 description 5
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 5
- 239000010410 layer Substances 0.000 description 5
- OFOBLEOULBTSOW-UHFFFAOYSA-N Propanedioic acid Natural products OC(=O)CC(O)=O OFOBLEOULBTSOW-UHFFFAOYSA-N 0.000 description 4
- 125000002619 bicyclic group Chemical group 0.000 description 4
- 229940106691 bisphenol a Drugs 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 238000007334 copolymerization reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 238000004049 embossing Methods 0.000 description 4
- VZCYOOQTPOCHFL-UPHRSURJSA-N maleic acid Chemical compound OC(=O)\C=C/C(O)=O VZCYOOQTPOCHFL-UPHRSURJSA-N 0.000 description 4
- 239000011976 maleic acid Substances 0.000 description 4
- 210000004379 membrane Anatomy 0.000 description 4
- 239000012528 membrane Substances 0.000 description 4
- 229910052757 nitrogen Inorganic materials 0.000 description 4
- 229920005862 polyol Polymers 0.000 description 4
- 229910000077 silane Inorganic materials 0.000 description 4
- 229920002725 thermoplastic elastomer Polymers 0.000 description 4
- VZCYOOQTPOCHFL-UHFFFAOYSA-N trans-butenedioic acid Natural products OC(=O)C=CC(O)=O VZCYOOQTPOCHFL-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- ZWEHNKRNPOVVGH-UHFFFAOYSA-N 2-Butanone Chemical compound CCC(C)=O ZWEHNKRNPOVVGH-UHFFFAOYSA-N 0.000 description 3
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 3
- CERQOIWHTDAKMF-UHFFFAOYSA-N Methacrylic acid Chemical compound CC(=C)C(O)=O CERQOIWHTDAKMF-UHFFFAOYSA-N 0.000 description 3
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 3
- 239000004698 Polyethylene Substances 0.000 description 3
- 239000004793 Polystyrene Substances 0.000 description 3
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 3
- ZJCCRDAZUWHFQH-UHFFFAOYSA-N Trimethylolpropane Chemical compound CCC(CO)(CO)CO ZJCCRDAZUWHFQH-UHFFFAOYSA-N 0.000 description 3
- 239000002253 acid Substances 0.000 description 3
- 150000008065 acid anhydrides Chemical class 0.000 description 3
- 229910052782 aluminium Inorganic materials 0.000 description 3
- 239000005030 aluminium foil Substances 0.000 description 3
- 125000003178 carboxy group Chemical group [H]OC(*)=O 0.000 description 3
- 230000009194 climbing Effects 0.000 description 3
- 125000005442 diisocyanate group Chemical group 0.000 description 3
- 238000007598 dipping method Methods 0.000 description 3
- 238000001035 drying Methods 0.000 description 3
- 229920001971 elastomer Polymers 0.000 description 3
- 239000000806 elastomer Substances 0.000 description 3
- VXNZUUAINFGPBY-UHFFFAOYSA-N ethyl ethylene Natural products CCC=C VXNZUUAINFGPBY-UHFFFAOYSA-N 0.000 description 3
- WGCNASOHLSPBMP-UHFFFAOYSA-N hydroxyacetaldehyde Natural products OCC=O WGCNASOHLSPBMP-UHFFFAOYSA-N 0.000 description 3
- 150000002460 imidazoles Chemical class 0.000 description 3
- 229920001684 low density polyethylene Polymers 0.000 description 3
- 239000004702 low-density polyethylene Substances 0.000 description 3
- 229910052698 phosphorus Inorganic materials 0.000 description 3
- 239000011574 phosphorus Substances 0.000 description 3
- 229920000573 polyethylene Polymers 0.000 description 3
- 229920002223 polystyrene Polymers 0.000 description 3
- 230000008569 process Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000007870 radical polymerization initiator Substances 0.000 description 3
- 230000009257 reactivity Effects 0.000 description 3
- 230000009467 reduction Effects 0.000 description 3
- 150000003839 salts Chemical class 0.000 description 3
- 229920003048 styrene butadiene rubber Polymers 0.000 description 3
- OZAIFHULBGXAKX-UHFFFAOYSA-N 2-(2-cyanopropan-2-yldiazenyl)-2-methylpropanenitrile Chemical compound N#CC(C)(C)N=NC(C)(C)C#N OZAIFHULBGXAKX-UHFFFAOYSA-N 0.000 description 2
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 description 2
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- JAHNSTQSQJOJLO-UHFFFAOYSA-N 2-(3-fluorophenyl)-1h-imidazole Chemical compound FC1=CC=CC(C=2NC=CN=2)=C1 JAHNSTQSQJOJLO-UHFFFAOYSA-N 0.000 description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 description 2
- SVTBMSDMJJWYQN-UHFFFAOYSA-N 2-methylpentane-2,4-diol Chemical compound CC(O)CC(C)(C)O SVTBMSDMJJWYQN-UHFFFAOYSA-N 0.000 description 2
- WSSSPWUEQFSQQG-UHFFFAOYSA-N 4-methyl-1-pentene Chemical class CC(C)CC=C WSSSPWUEQFSQQG-UHFFFAOYSA-N 0.000 description 2
- FVCSARBUZVPSQF-UHFFFAOYSA-N 5-(2,4-dioxooxolan-3-yl)-7-methyl-3a,4,5,7a-tetrahydro-2-benzofuran-1,3-dione Chemical compound C1C(C(OC2=O)=O)C2C(C)=CC1C1C(=O)COC1=O FVCSARBUZVPSQF-UHFFFAOYSA-N 0.000 description 2
- KNDQHSIWLOJIGP-UHFFFAOYSA-N 826-62-0 Chemical class C1C2C3C(=O)OC(=O)C3C1C=C2 KNDQHSIWLOJIGP-UHFFFAOYSA-N 0.000 description 2
- 229930185605 Bisphenol Natural products 0.000 description 2
- KAKZBPTYRLMSJV-UHFFFAOYSA-N Butadiene Chemical compound C=CC=C KAKZBPTYRLMSJV-UHFFFAOYSA-N 0.000 description 2
- VYZAMTAEIAYCRO-UHFFFAOYSA-N Chromium Chemical compound [Cr] VYZAMTAEIAYCRO-UHFFFAOYSA-N 0.000 description 2
- NIQCNGHVCWTJSM-UHFFFAOYSA-N Dimethyl phthalate Chemical compound COC(=O)C1=CC=CC=C1C(=O)OC NIQCNGHVCWTJSM-UHFFFAOYSA-N 0.000 description 2
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 description 2
- VQTUBCCKSQIDNK-UHFFFAOYSA-N Isobutene Chemical compound CC(C)=C VQTUBCCKSQIDNK-UHFFFAOYSA-N 0.000 description 2
- 229910013872 LiPF Inorganic materials 0.000 description 2
- 101150058243 Lipf gene Proteins 0.000 description 2
- NTIZESTWPVYFNL-UHFFFAOYSA-N Methyl isobutyl ketone Chemical compound CC(C)CC(C)=O NTIZESTWPVYFNL-UHFFFAOYSA-N 0.000 description 2
- UIHCLUNTQKBZGK-UHFFFAOYSA-N Methyl isobutyl ketone Natural products CCC(C)C(C)=O UIHCLUNTQKBZGK-UHFFFAOYSA-N 0.000 description 2
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 description 2
- 229910019142 PO4 Inorganic materials 0.000 description 2
- 239000004743 Polypropylene Substances 0.000 description 2
- 239000006087 Silane Coupling Agent Substances 0.000 description 2
- XTXRWKRVRITETP-UHFFFAOYSA-N Vinyl acetate Chemical compound CC(=O)OC=C XTXRWKRVRITETP-UHFFFAOYSA-N 0.000 description 2
- 230000006978 adaptation Effects 0.000 description 2
- 239000004411 aluminium Substances 0.000 description 2
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 2
- PXKLMJQFEQBVLD-UHFFFAOYSA-N bisphenol F Chemical compound C1=CC(O)=CC=C1CC1=CC=C(O)C=C1 PXKLMJQFEQBVLD-UHFFFAOYSA-N 0.000 description 2
- 229910052804 chromium Inorganic materials 0.000 description 2
- 239000011651 chromium Substances 0.000 description 2
- JHIVVAPYMSGYDF-UHFFFAOYSA-N cyclohexanone Chemical compound O=C1CCCCC1 JHIVVAPYMSGYDF-UHFFFAOYSA-N 0.000 description 2
- LSXWFXONGKSEMY-UHFFFAOYSA-N di-tert-butyl peroxide Chemical compound CC(C)(C)OOC(C)(C)C LSXWFXONGKSEMY-UHFFFAOYSA-N 0.000 description 2
- IEJIGPNLZYLLBP-UHFFFAOYSA-N dimethyl carbonate Chemical compound COC(=O)OC IEJIGPNLZYLLBP-UHFFFAOYSA-N 0.000 description 2
- 238000009820 dry lamination Methods 0.000 description 2
- BXKDSDJJOVIHMX-UHFFFAOYSA-N edrophonium chloride Chemical compound [Cl-].CC[N+](C)(C)C1=CC=CC(O)=C1 BXKDSDJJOVIHMX-UHFFFAOYSA-N 0.000 description 2
- 230000005611 electricity Effects 0.000 description 2
- 230000007613 environmental effect Effects 0.000 description 2
- 125000003700 epoxy group Chemical group 0.000 description 2
- 230000003628 erosive effect Effects 0.000 description 2
- JBTWLSYIZRCDFO-UHFFFAOYSA-N ethyl methyl carbonate Chemical compound CCOC(=O)OC JBTWLSYIZRCDFO-UHFFFAOYSA-N 0.000 description 2
- FKRCODPIKNYEAC-UHFFFAOYSA-N ethyl propionate Chemical compound CCOC(=O)CC FKRCODPIKNYEAC-UHFFFAOYSA-N 0.000 description 2
- XLLIQLLCWZCATF-UHFFFAOYSA-N ethylene glycol monomethyl ether acetate Natural products COCCOC(C)=O XLLIQLLCWZCATF-UHFFFAOYSA-N 0.000 description 2
- 239000011888 foil Substances 0.000 description 2
- 125000000524 functional group Chemical group 0.000 description 2
- 239000000499 gel Substances 0.000 description 2
- LNEPOXFFQSENCJ-UHFFFAOYSA-N haloperidol Chemical compound C1CC(O)(C=2C=CC(Cl)=CC=2)CCN1CCCC(=O)C1=CC=C(F)C=C1 LNEPOXFFQSENCJ-UHFFFAOYSA-N 0.000 description 2
- 125000004836 hexamethylene group Chemical group [H]C([H])([*:2])C([H])([H])C([H])([H])C([H])([H])C([H])([H])C([H])([H])[*:1] 0.000 description 2
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 description 2
- 229910052739 hydrogen Inorganic materials 0.000 description 2
- 239000001257 hydrogen Substances 0.000 description 2
- 238000005984 hydrogenation reaction Methods 0.000 description 2
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 2
- 150000002513 isocyanates Chemical class 0.000 description 2
- 229910003002 lithium salt Inorganic materials 0.000 description 2
- 159000000002 lithium salts Chemical class 0.000 description 2
- FEPCMSPFPMPWJK-OLPJDRRASA-N maleopimaric acid Chemical compound C([C@]12C=C([C@H](C[C@@H]11)[C@H]3C(OC(=O)[C@@H]23)=O)C(C)C)C[C@@H]2[C@]1(C)CCC[C@@]2(C)C(O)=O FEPCMSPFPMPWJK-OLPJDRRASA-N 0.000 description 2
- 238000005259 measurement Methods 0.000 description 2
- HNEGQIOMVPPMNR-NSCUHMNNSA-N mesaconic acid Chemical compound OC(=O)C(/C)=C/C(O)=O HNEGQIOMVPPMNR-NSCUHMNNSA-N 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- 229940043265 methyl isobutyl ketone Drugs 0.000 description 2
- LVHBHZANLOWSRM-UHFFFAOYSA-N methylenebutanedioic acid Natural products OC(=O)CC(=C)C(O)=O LVHBHZANLOWSRM-UHFFFAOYSA-N 0.000 description 2
- HNEGQIOMVPPMNR-UHFFFAOYSA-N methylfumaric acid Natural products OC(=O)C(C)=CC(O)=O HNEGQIOMVPPMNR-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 description 2
- 239000010452 phosphate Substances 0.000 description 2
- 239000004014 plasticizer Substances 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 150000003077 polyols Chemical class 0.000 description 2
- 229920001155 polypropylene Polymers 0.000 description 2
- BDERNNFJNOPAEC-UHFFFAOYSA-N propan-1-ol Chemical compound CCCO BDERNNFJNOPAEC-UHFFFAOYSA-N 0.000 description 2
- 125000004805 propylene group Chemical group [H]C([H])([H])C([H])([*:1])C([H])([H])[*:2] 0.000 description 2
- 238000010526 radical polymerization reaction Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 150000005846 sugar alcohols Polymers 0.000 description 2
- 238000004381 surface treatment Methods 0.000 description 2
- 229920001897 terpolymer Polymers 0.000 description 2
- YLQBMQCUIZJEEH-UHFFFAOYSA-N tetrahydrofuran Natural products C=1C=COC=1 YLQBMQCUIZJEEH-UHFFFAOYSA-N 0.000 description 2
- 229920005992 thermoplastic resin Polymers 0.000 description 2
- VAYTZRYEBVHVLE-UHFFFAOYSA-N 1,3-dioxol-2-one Chemical class O=C1OC=CO1 VAYTZRYEBVHVLE-UHFFFAOYSA-N 0.000 description 1
- SBJCUZQNHOLYMD-UHFFFAOYSA-N 1,5-Naphthalene diisocyanate Chemical compound C1=CC=C2C(N=C=O)=CC=CC2=C1N=C=O SBJCUZQNHOLYMD-UHFFFAOYSA-N 0.000 description 1
- LIKMAJRDDDTEIG-UHFFFAOYSA-N 1-hexene Chemical compound CCCCC=C LIKMAJRDDDTEIG-UHFFFAOYSA-N 0.000 description 1
- ARXJGSRGQADJSQ-UHFFFAOYSA-N 1-methoxypropan-2-ol Chemical compound COCC(C)O ARXJGSRGQADJSQ-UHFFFAOYSA-N 0.000 description 1
- OAYXUHPQHDHDDZ-UHFFFAOYSA-N 2-(2-butoxyethoxy)ethanol Chemical compound CCCCOCCOCCO OAYXUHPQHDHDDZ-UHFFFAOYSA-N 0.000 description 1
- SBASXUCJHJRPEV-UHFFFAOYSA-N 2-(2-methoxyethoxy)ethanol Chemical compound COCCOCCO SBASXUCJHJRPEV-UHFFFAOYSA-N 0.000 description 1
- OZDGMOYKSFPLSE-UHFFFAOYSA-N 2-Methylaziridine Chemical class CC1CN1 OZDGMOYKSFPLSE-UHFFFAOYSA-N 0.000 description 1
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 1
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 description 1
- BKOOMYPCSUNDGP-UHFFFAOYSA-N 2-methylbut-2-ene Chemical group CC=C(C)C BKOOMYPCSUNDGP-UHFFFAOYSA-N 0.000 description 1
- QTWJRLJHJPIABL-UHFFFAOYSA-N 2-methylphenol;3-methylphenol;4-methylphenol Chemical compound CC1=CC=C(O)C=C1.CC1=CC=CC(O)=C1.CC1=CC=CC=C1O QTWJRLJHJPIABL-UHFFFAOYSA-N 0.000 description 1
- CAMBAGZYTIDFBK-UHFFFAOYSA-N 3-tert-butylperoxy-2-methylpropan-1-ol Chemical compound CC(CO)COOC(C)(C)C CAMBAGZYTIDFBK-UHFFFAOYSA-N 0.000 description 1
- VPWNQTHUCYMVMZ-UHFFFAOYSA-N 4,4'-sulfonyldiphenol Chemical compound C1=CC(O)=CC=C1S(=O)(=O)C1=CC=C(O)C=C1 VPWNQTHUCYMVMZ-UHFFFAOYSA-N 0.000 description 1
- RSWGJHLUYNHPMX-UHFFFAOYSA-N Abietic-Saeure Natural products C12CCC(C(C)C)=CC2=CCC2C1(C)CCCC2(C)C(O)=O RSWGJHLUYNHPMX-UHFFFAOYSA-N 0.000 description 1
- NOWKCMXCCJGMRR-UHFFFAOYSA-N Aziridine Chemical compound C1CN1 NOWKCMXCCJGMRR-UHFFFAOYSA-N 0.000 description 1
- 239000004342 Benzoyl peroxide Substances 0.000 description 1
- OMPJBNCRMGITSC-UHFFFAOYSA-N Benzoylperoxide Chemical compound C=1C=CC=CC=1C(=O)OOC(=O)C1=CC=CC=C1 OMPJBNCRMGITSC-UHFFFAOYSA-N 0.000 description 1
- WWZKQHOCKIZLMA-UHFFFAOYSA-N Caprylic acid Natural products CCCCCCCC(O)=O WWZKQHOCKIZLMA-UHFFFAOYSA-N 0.000 description 1
- KXDHJXZQYSOELW-UHFFFAOYSA-N Carbamic acid Chemical compound NC(O)=O KXDHJXZQYSOELW-UHFFFAOYSA-N 0.000 description 1
- 244000248349 Citrus limon Species 0.000 description 1
- 235000005979 Citrus limon Nutrition 0.000 description 1
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- 229920000089 Cyclic olefin copolymer Polymers 0.000 description 1
- FBPFZTCFMRRESA-JGWLITMVSA-N D-glucitol Chemical compound OC[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO FBPFZTCFMRRESA-JGWLITMVSA-N 0.000 description 1
- 244000147058 Derris elliptica Species 0.000 description 1
- OIFBSDVPJOWBCH-UHFFFAOYSA-N Diethyl carbonate Chemical compound CCOC(=O)OCC OIFBSDVPJOWBCH-UHFFFAOYSA-N 0.000 description 1
- ZAFNJMIOTHYJRJ-UHFFFAOYSA-N Diisopropyl ether Chemical compound CC(C)OC(C)C ZAFNJMIOTHYJRJ-UHFFFAOYSA-N 0.000 description 1
- IAYPIBMASNFSPL-UHFFFAOYSA-N Ethylene oxide Chemical compound C1CO1 IAYPIBMASNFSPL-UHFFFAOYSA-N 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- CTKINSOISVBQLD-UHFFFAOYSA-N Glycidol Chemical compound OCC1CO1 CTKINSOISVBQLD-UHFFFAOYSA-N 0.000 description 1
- 239000005057 Hexamethylene diisocyanate Substances 0.000 description 1
- 239000005058 Isophorone diisocyanate Substances 0.000 description 1
- YIVJZNGAASQVEM-UHFFFAOYSA-N Lauroyl peroxide Chemical compound CCCCCCCCCCCC(=O)OOC(=O)CCCCCCCCCCC YIVJZNGAASQVEM-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Chemical class 0.000 description 1
- 229910001290 LiPF6 Inorganic materials 0.000 description 1
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- XYFCBTPGUUZFHI-UHFFFAOYSA-N Phosphine Natural products P XYFCBTPGUUZFHI-UHFFFAOYSA-N 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000002202 Polyethylene glycol Substances 0.000 description 1
- 239000004721 Polyphenylene oxide Substances 0.000 description 1
- GOOHAUXETOMSMM-UHFFFAOYSA-N Propylene oxide Chemical compound CC1CO1 GOOHAUXETOMSMM-UHFFFAOYSA-N 0.000 description 1
- KHPCPRHQVVSZAH-HUOMCSJISA-N Rosin Natural products O(C/C=C/c1ccccc1)[C@H]1[C@H](O)[C@@H](O)[C@@H](O)[C@@H](CO)O1 KHPCPRHQVVSZAH-HUOMCSJISA-N 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- MCEBKLYUUDGVMD-UHFFFAOYSA-N [SiH3]S(=O)=O Chemical compound [SiH3]S(=O)=O MCEBKLYUUDGVMD-UHFFFAOYSA-N 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 150000001343 alkyl silanes Chemical class 0.000 description 1
- OBETXYAYXDNJHR-UHFFFAOYSA-N alpha-ethylcaproic acid Natural products CCCCC(CC)C(O)=O OBETXYAYXDNJHR-UHFFFAOYSA-N 0.000 description 1
- 150000001412 amines Chemical class 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000013556 antirust agent Substances 0.000 description 1
- 230000008901 benefit Effects 0.000 description 1
- KPTLPIAOSCGETM-UHFFFAOYSA-N benzene 1,2-diisocyanatoethane Chemical compound O=C=NCCN=C=O.c1ccccc1 KPTLPIAOSCGETM-UHFFFAOYSA-N 0.000 description 1
- IZJDCINIYIMFGX-UHFFFAOYSA-N benzo[f][2]benzofuran-1,3-dione Chemical compound C1=CC=C2C=C3C(=O)OC(=O)C3=CC2=C1 IZJDCINIYIMFGX-UHFFFAOYSA-N 0.000 description 1
- 235000019400 benzoyl peroxide Nutrition 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical group NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 238000005422 blasting Methods 0.000 description 1
- 229920001400 block copolymer Polymers 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- NPAXBRSUVYCZGM-UHFFFAOYSA-N carbonic acid;propane-1,2-diol Chemical compound OC(O)=O.CC(O)CO NPAXBRSUVYCZGM-UHFFFAOYSA-N 0.000 description 1
- 150000001732 carboxylic acid derivatives Chemical class 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- HNEGQIOMVPPMNR-IHWYPQMZSA-N citraconic acid Chemical compound OC(=O)C(/C)=C\C(O)=O HNEGQIOMVPPMNR-IHWYPQMZSA-N 0.000 description 1
- 229940018557 citraconic acid Drugs 0.000 description 1
- 238000004891 communication Methods 0.000 description 1
- 238000013329 compounding Methods 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229930003836 cresol Natural products 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000006731 degradation reaction Methods 0.000 description 1
- 238000006356 dehydrogenation reaction Methods 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- GPLRAVKSCUXZTP-UHFFFAOYSA-N diglycerol Chemical compound OCC(O)COCC(O)CO GPLRAVKSCUXZTP-UHFFFAOYSA-N 0.000 description 1
- FBSAITBEAPNWJG-UHFFFAOYSA-N dimethyl phthalate Natural products CC(=O)OC1=CC=CC=C1OC(C)=O FBSAITBEAPNWJG-UHFFFAOYSA-N 0.000 description 1
- 229960001826 dimethylphthalate Drugs 0.000 description 1
- 150000002012 dioxanes Chemical class 0.000 description 1
- CZZYITDELCSZES-UHFFFAOYSA-N diphenylmethane Chemical class C=1C=CC=CC=1CC1=CC=CC=C1 CZZYITDELCSZES-UHFFFAOYSA-N 0.000 description 1
- 238000005868 electrolysis reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- WSTZPWUPYWHZRR-UHFFFAOYSA-N ethene;2-ethyl-2-(hydroxymethyl)propane-1,3-diol Chemical group C=C.CCC(CO)(CO)CO WSTZPWUPYWHZRR-UHFFFAOYSA-N 0.000 description 1
- LDLDYFCCDKENPD-UHFFFAOYSA-N ethenylcyclohexane Chemical compound C=CC1CCCCC1 LDLDYFCCDKENPD-UHFFFAOYSA-N 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- XYIBRDXRRQCHLP-UHFFFAOYSA-N ethyl acetoacetate Chemical compound CCOC(=O)CC(C)=O XYIBRDXRRQCHLP-UHFFFAOYSA-N 0.000 description 1
- 238000011156 evaluation Methods 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 150000002240 furans Chemical class 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 238000001879 gelation Methods 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 150000002314 glycerols Chemical class 0.000 description 1
- 238000007756 gravure coating Methods 0.000 description 1
- 230000036541 health Effects 0.000 description 1
- 238000010438 heat treatment Methods 0.000 description 1
- RRAMGCGOFNQTLD-UHFFFAOYSA-N hexamethylene diisocyanate Chemical compound O=C=NCCCCCCN=C=O RRAMGCGOFNQTLD-UHFFFAOYSA-N 0.000 description 1
- 229940051250 hexylene glycol Drugs 0.000 description 1
- 230000007062 hydrolysis Effects 0.000 description 1
- 238000006460 hydrolysis reaction Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 229910003480 inorganic solid Inorganic materials 0.000 description 1
- 238000011835 investigation Methods 0.000 description 1
- ZFSLODLOARCGLH-UHFFFAOYSA-N isocyanuric acid Natural products OC1=NC(O)=NC(O)=N1 ZFSLODLOARCGLH-UHFFFAOYSA-N 0.000 description 1
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 239000012939 laminating adhesive Substances 0.000 description 1
- 150000007517 lewis acids Chemical class 0.000 description 1
- 229910001496 lithium tetrafluoroborate Inorganic materials 0.000 description 1
- 230000007774 longterm Effects 0.000 description 1
- 230000014759 maintenance of location Effects 0.000 description 1
- 210000000713 mesentery Anatomy 0.000 description 1
- 238000001465 metallisation Methods 0.000 description 1
- KNRCVAANTQNTPT-UHFFFAOYSA-N methyl-5-norbornene-2,3-dicarboxylic anhydride Chemical compound O=C1OC(=O)C2C1C1(C)C=CC2C1 KNRCVAANTQNTPT-UHFFFAOYSA-N 0.000 description 1
- 238000006011 modification reaction Methods 0.000 description 1
- SLCVBVWXLSEKPL-UHFFFAOYSA-N neopentyl glycol Chemical compound OCC(C)(C)CO SLCVBVWXLSEKPL-UHFFFAOYSA-N 0.000 description 1
- 229910052759 nickel Inorganic materials 0.000 description 1
- 229920003986 novolac Polymers 0.000 description 1
- 125000005473 octanoic acid group Chemical group 0.000 description 1
- 239000008601 oleoresin Substances 0.000 description 1
- 150000007524 organic acids Chemical class 0.000 description 1
- 235000005985 organic acids Nutrition 0.000 description 1
- 150000001451 organic peroxides Chemical group 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- WXZMFSXDPGVJKK-UHFFFAOYSA-N pentaerythritol Chemical compound OCC(CO)(CO)CO WXZMFSXDPGVJKK-UHFFFAOYSA-N 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 239000003208 petroleum Substances 0.000 description 1
- 229920001568 phenolic resin Polymers 0.000 description 1
- 239000005011 phenolic resin Substances 0.000 description 1
- 229910000073 phosphorus hydride Inorganic materials 0.000 description 1
- IUGYQRQAERSCNH-UHFFFAOYSA-N pivalic acid Chemical compound CC(C)(C)C(O)=O IUGYQRQAERSCNH-UHFFFAOYSA-N 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001083 polybutene Polymers 0.000 description 1
- 229920000570 polyether Polymers 0.000 description 1
- 229920001223 polyethylene glycol Polymers 0.000 description 1
- 229920001195 polyisoprene Polymers 0.000 description 1
- 229920006124 polyolefin elastomer Polymers 0.000 description 1
- 229920002742 polystyrene-block-poly(ethylene/propylene) -block-polystyrene Polymers 0.000 description 1
- 150000003097 polyterpenes Chemical class 0.000 description 1
- 238000010248 power generation Methods 0.000 description 1
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 description 1
- LLHKCFNBLRBOGN-UHFFFAOYSA-N propylene glycol methyl ether acetate Chemical compound COCC(C)OC(C)=O LLHKCFNBLRBOGN-UHFFFAOYSA-N 0.000 description 1
- 229920001384 propylene homopolymer Polymers 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000013557 residual solvent Substances 0.000 description 1
- 229920003987 resole Polymers 0.000 description 1
- 238000005096 rolling process Methods 0.000 description 1
- 229920006395 saturated elastomer Polymers 0.000 description 1
- FZHAPNGMFPVSLP-UHFFFAOYSA-N silanamine Chemical compound [SiH3]N FZHAPNGMFPVSLP-UHFFFAOYSA-N 0.000 description 1
- IYMSIPPWHNIMGE-UHFFFAOYSA-N silylurea Chemical compound NC(=O)N[SiH3] IYMSIPPWHNIMGE-UHFFFAOYSA-N 0.000 description 1
- 239000007784 solid electrolyte Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 229920006132 styrene block copolymer Polymers 0.000 description 1
- QROFQHQXTMKORN-UHFFFAOYSA-N tert-butyl 2-phenylacetate Chemical compound CC(C)(C)OC(=O)CC1=CC=CC=C1 QROFQHQXTMKORN-UHFFFAOYSA-N 0.000 description 1
- SWAXTRYEYUTSAP-UHFFFAOYSA-N tert-butyl ethaneperoxoate Chemical compound CC(=O)OOC(C)(C)C SWAXTRYEYUTSAP-UHFFFAOYSA-N 0.000 description 1
- FQFILJKFZCVHNH-UHFFFAOYSA-N tert-butyl n-[3-[(5-bromo-2-chloropyrimidin-4-yl)amino]propyl]carbamate Chemical compound CC(C)(C)OC(=O)NCCCNC1=NC(Cl)=NC=C1Br FQFILJKFZCVHNH-UHFFFAOYSA-N 0.000 description 1
- 150000003512 tertiary amines Chemical class 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- KHPCPRHQVVSZAH-UHFFFAOYSA-N trans-cinnamyl beta-D-glucopyranoside Natural products OC1C(O)C(O)C(CO)OC1OCC=CC1=CC=CC=C1 KHPCPRHQVVSZAH-UHFFFAOYSA-N 0.000 description 1
- IUCJMVBFZDHPDX-UHFFFAOYSA-N tretamine Chemical compound C1CN1C1=NC(N2CC2)=NC(N2CC2)=N1 IUCJMVBFZDHPDX-UHFFFAOYSA-N 0.000 description 1
- JLGLQAWTXXGVEM-UHFFFAOYSA-N triethylene glycol monomethyl ether Chemical compound COCCOCCOCCO JLGLQAWTXXGVEM-UHFFFAOYSA-N 0.000 description 1
- MEYZYGMYMLNUHJ-UHFFFAOYSA-N tunicamycin Natural products CC(C)CCCCCCCCCC=CC(=O)NC1C(O)C(O)C(CC(O)C2OC(C(O)C2O)N3C=CC(=O)NC3=O)OC1OC4OC(CO)C(O)C(O)C4NC(=O)C MEYZYGMYMLNUHJ-UHFFFAOYSA-N 0.000 description 1
- AVWRKZWQTYIKIY-UHFFFAOYSA-N urea-1-carboxylic acid Chemical compound NC(=O)NC(O)=O AVWRKZWQTYIKIY-UHFFFAOYSA-N 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- UKRDPEFKFJNXQM-UHFFFAOYSA-N vinylsilane Chemical class [SiH3]C=C UKRDPEFKFJNXQM-UHFFFAOYSA-N 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
- 239000004711 α-olefin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J123/00—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers
- C09J123/26—Adhesives based on homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Adhesives based on derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/08—Macromolecular additives
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/085—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/088—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/04—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material
- B32B15/08—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin
- B32B15/09—Layered products comprising a layer of metal comprising metal as the main or only constituent of a layer, which is next to another layer of the same or of a different material of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/18—Layered products comprising a layer of metal comprising iron or steel
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B15/00—Layered products comprising a layer of metal
- B32B15/20—Layered products comprising a layer of metal comprising aluminium or copper
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/06—Layered products comprising a layer of synthetic resin as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/32—Layered products comprising a layer of synthetic resin comprising polyolefins
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/34—Layered products comprising a layer of synthetic resin comprising polyamides
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B27/00—Layered products comprising a layer of synthetic resin
- B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J5/00—Manufacture of articles or shaped materials containing macromolecular substances
- C08J5/12—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives
- C08J5/124—Bonding of a preformed macromolecular material to the same or other solid material such as metal, glass, leather, e.g. using adhesives using adhesives based on a macromolecular component
- C08J5/128—Adhesives without diluent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L25/00—Compositions of, homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Compositions of derivatives of such polymers
- C08L25/02—Homopolymers or copolymers of hydrocarbons
- C08L25/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L51/00—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
- C08L51/06—Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J125/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Adhesives based on derivatives of such polymers
- C09J125/02—Homopolymers or copolymers of hydrocarbons
- C09J125/04—Homopolymers or copolymers of styrene
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J151/00—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers
- C09J151/06—Adhesives based on graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Adhesives based on derivatives of such polymers grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/04—Construction or manufacture in general
- H01M10/0436—Small-sized flat cells or batteries for portable equipment
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/052—Li-accumulators
- H01M10/0525—Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/056—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes
- H01M10/0564—Accumulators with non-aqueous electrolyte characterised by the materials used as electrolytes, e.g. mixed inorganic/organic electrolytes the electrolyte being constituted of organic materials only
- H01M10/0566—Liquid materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M10/00—Secondary cells; Manufacture thereof
- H01M10/05—Accumulators with non-aqueous electrolyte
- H01M10/058—Construction or manufacture
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/117—Inorganic material
- H01M50/119—Metals
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/121—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/122—Composite material consisting of a mixture of organic and inorganic materials
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/116—Primary casings; Jackets or wrappings characterised by the material
- H01M50/124—Primary casings; Jackets or wrappings characterised by the material having a layered structure
- H01M50/126—Primary casings; Jackets or wrappings characterised by the material having a layered structure comprising three or more layers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/131—Primary casings; Jackets or wrappings characterised by physical properties, e.g. gas permeability, size or heat resistance
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/186—Sealing members characterised by the disposition of the sealing members
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/10—Primary casings; Jackets or wrappings
- H01M50/183—Sealing members
- H01M50/19—Sealing members characterised by the material
- H01M50/193—Organic material
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/531—Electrode connections inside a battery casing
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/547—Terminals characterised by the disposition of the terminals on the cells
- H01M50/55—Terminals characterised by the disposition of the terminals on the cells on the same side of the cell
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M50/00—Constructional details or processes of manufacture of the non-active parts of electrochemical cells other than fuel cells, e.g. hybrid cells
- H01M50/50—Current conducting connections for cells or batteries
- H01M50/543—Terminals
- H01M50/552—Terminals characterised by their shape
- H01M50/553—Terminals adapted for prismatic, pouch or rectangular cells
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/03—3 layers
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2250/00—Layers arrangement
- B32B2250/40—Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/06—Coating on the layer surface on metal layer
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2255/00—Coating on the layer surface
- B32B2255/26—Polymeric coating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/30—Properties of the layers or laminate having particular thermal properties
- B32B2307/31—Heat sealable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/50—Properties of the layers or laminate having particular mechanical properties
- B32B2307/514—Oriented
- B32B2307/518—Oriented bi-axially
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/732—Dimensional properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/752—Corrosion inhibitor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2439/00—Containers; Receptacles
- B32B2439/40—Closed containers
- B32B2439/46—Bags
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2457/00—Electrical equipment
- B32B2457/10—Batteries
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2553/00—Packaging equipment or accessories not otherwise provided for
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2323/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2323/02—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers not modified by chemical after treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2423/00—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers
- C08J2423/26—Characterised by the use of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Derivatives of such polymers modified by chemical after-treatment
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
- C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
- C08J2425/02—Homopolymers or copolymers of hydrocarbons
- C08J2425/04—Homopolymers or copolymers of styrene
- C08J2425/06—Polystyrene
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/10—Energy storage using batteries
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
Landscapes
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Electrochemistry (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Health & Medical Sciences (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- General Physics & Mathematics (AREA)
- Composite Materials (AREA)
- Laminated Bodies (AREA)
- Sealing Battery Cases Or Jackets (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
一种层压用粘接剂,其是以具有酸基或酸酐基的烯烃树脂(A)、固化剂(B)和苯乙烯树脂(C)作为必须成分的层压用粘接剂,其中,上述苯乙烯树脂(C)的配合比例相对于上述烯烃树脂(A)100质量份为0.01~1.5质量份的范围;一种多层膜,其以借助上述层压用粘接剂将未拉伸聚烯烃膜与金属膜粘接而得到的层叠体作为必须的膜构成;以及使用了上述多层膜的二次电池。
Description
技术领域
本发明涉及用于密封二次电池所使用的电解质的层压用粘接剂、使用了其的层叠体和二次电池。
背景技术
锂离子电池因能量密度高这一优点而被广泛用作信息通信设备/家电设备、尤其是便携电源,此外,最近从替代石油或环境低负荷等观点出发,作为混合动力汽车、电动汽车等的驱动用电源,进而作为太阳能发电、风力发电等可再生能源***中的蓄电用电池,利用范围正在扩大。
作为所述锂离子电池的外观形态,至今为止广泛使用着金属制的壳的圆筒形状或方形形状的电池,但是近年来,使用作为树脂膜与铝箔的复合材的层压膜作为电池用外装材而得到的袋型锂离子电池、或者将上述层压膜密封于通过深拉深成形或鼓凸成形而形成有凹部的容器而得到的压花状锂离子电池与具有金属制的壳的电池相比,成形的自由度高、质量轻,因此受到关注。
在此,作为构成锂离子电池的要素之一的电解质使用了非水电解液、凝胶聚合物系电解质、有机/无机固体电解质等,这些之中,从稳定性和离子电导率高的方面出发,现今将六氟化磷的锂离子盐(LiPF6)混合至碳酸酯系有机溶剂而得到的非水电解液成为主流。然而,在该非水电解液中混入水的情况下,由于非水电解液中的上述六氟化磷的锂离子盐与水的反应而生成氢氟酸,其透过构成电池外装材的树脂膜,进而侵入存在于树脂膜与铝箔之间的粘接剂层,导致粘接强度的降低。
从这种状况出发,例如作为对电解质溶液的耐性得以提高的层压膜用粘接剂,已知下述粘接剂组合物,其是包含具有羧基的非结晶性聚烯烃树脂、赋粘剂以及含氮丙啶的化合物的粘接剂,其中,相对于具有羧基的非结晶性聚烯烃树脂与赋粘剂的合计100质量份,以达到20~90质量份的比例使用上述具有羧基的非结晶性聚烯烃树脂,并以达到10~80质量份的比例使用上述赋粘剂(下述专利文献1)。然而,所述粘接剂组合物为了提高粘接性能而配合了大量的赋粘剂,通过这样的配合量而能够获得高凝聚力,另一方面,由于赋粘剂自身对烯烃系膜的粘接性低,因此还是得不到充分的粘接性能。
现有技术文献
专利文献
专利文献1:日本特开2013-112697号公报
发明内容
发明所要解决的课题
本发明所要解决的课题在于,提供耐电解质溶液浸渍后的粘接强度优异的层压用粘接剂、以及使用其制成的复合膜、将该复合膜用作外装材的耐电解质溶液性优异的二次电池。
用于解决课题的方法
本发明人等为了解决上述课题而反复进行了深入研究,结果发现:通过向以含有酸基的聚烯烃作为主剂的粘接剂中添加少量苯乙烯树脂,从而即使在电解质溶液中产生氢氟酸的情况下,粘接强度也不会降低,此外能够保持适度的储存期,从而完成了本发明。
即,本发明涉及一种层压用粘接剂,其特征在于,其以具有酸基或酸酐基的烯烃树脂(A)、固化剂(B)和苯乙烯树脂(C)作为必须成分,上述苯乙烯树脂(C)的配合比例相对于上述烯烃树脂(A)100质量份为0.01~1.5质量份的范围。
本发明还涉及一种多层膜,其以借助上述粘接剂将未拉伸聚烯烃膜与金属膜粘接而得到的层叠体作为必须的膜构成。
本发明还涉及一种二次电池,其以二次电池主体、分别与该二次电池的正极和负极接合的极耳、电解质溶液、以及以上述极耳露出至二次电池外部的方式将上述二次电池主体和电解质溶液封入的外装材作为必须的构成要素,其中,上述外装材是将上述多层膜以上述未拉伸聚烯烃膜侧形成热封部的方式构成袋状的包装袋而得到的。
本发明还涉及一种二次电池,其具有下述结构:上述多层膜具有通过深拉深成形或鼓凸成形而以未拉伸聚烯烃膜侧构成密封面的方式被赋形为压花状的形状,使两个该多层膜的密封面彼此贴合,且在通过该贴合而形成的内部空隙配设二次电池主体和电极端子并使该电极端子露出至电池外部,且在该内部空隙液密性地填充有电解质溶液。
发明的效果
根据本发明,能够提供耐电解质溶液浸渍后的粘接强度优异的层压用粘接剂、使用其制成的复合膜、将该复合膜用作外装材的耐电解质溶液性优异的二次电池。
附图说明
图1是本发明的多层膜的截面图。
图2是使用了本发明多层膜的袋状的二次电池的俯视图。
图3是将本发明的多层膜通过深拉深成形或鼓凸成形进行成形而得到的二次电池的立体图。
具体实施方式
如上所示,本发明的层压用粘接剂的特征在于,其以具有酸基或酸酐基的烯烃树脂(A)、固化剂(B)和苯乙烯树脂(C)作为必须成分,其中,上述苯乙烯树脂(C)的配合比例相对于上述烯烃树脂(A)100质量份为0.01~1.5质量份的范围。本发明中,通过这样地将较少量的苯乙烯树脂(C)配合至具有酸基或酸酐基的烯烃树脂(A)中,从而尤其是能够有效地防止通过六氟化磷的锂离子盐与水的反应而生成的氢氟酸对粘接剂层与金属层的界面所造成的侵蚀,能够有效地防止高温高湿环境下的粘接性劣化。
(具有酸基或酸酐基的烯烃树脂(A))
接下来,本发明的层压用粘接剂中使用的具有酸基或酸酐基的烯烃树脂(A)可列举出烯烃系单体与烯属不饱和羧酸或烯属不饱和羧酸酐的共聚物、或者向聚烯烃接枝改性烯属不饱和羧酸或烯属不饱和羧酸酐而得到的树脂。
作为前者的烯烃系单体与烯属不饱和羧酸或烯属不饱和羧酸酐的共聚物中使用的烯烃系单体,可列举出碳原子数为2~8的烯烃、例如乙烯、1-丙烯、异丁烯、1-丁烯、4-甲基戊烯、己烯、乙烯基环己烷等。这些之中,尤其是从粘接强度良好的观点出发,优选碳原子数为3~8的烯烃,尤其是1-丙烯和1-丁烯对溶剂的耐性优异、粘接强度优异,从这一点出发是优选的。
此外,作为与烯烃系单体的共聚中使用的烯属不饱和羧酸或烯属不饱和羧酸酐,接下来,作为与上述烯烃系单体的共聚物中使用或者与聚烯烃的接枝改性中使用的烯属不饱和羧酸或烯属不饱和羧酸酐,可列举出例如丙烯酸、甲基丙烯酸、马来酸、衣康酸、柠康酸、中康酸、马来酸酐、4-甲基环己-4-烯-1,2-二羧酸酐、双环[2.2.2]辛-5-烯-2,3-二羧酸酐、1,2,3,4,5,8,9,10-八氢萘-2,3-二羧酸酐、2-辛-1,3-二酮螺[4.4]壬-7-烯、双环[2.2.1]庚-5-烯-2,3-二羧酸酐、马来海松酸、四氢邻苯二甲酸酐、甲基-双环[2.2.1]庚-5-烯-2,3-二羧酸酐、甲基-5-降冰片烯-2,3-二羧酸酐、5-降冰片烯-2,3-二羧酸酐等。这些之中,尤其是从与烯烃系单体的反应性、共聚后的酸酐的反应性优异,并且因该化合物自身的分子量小而使得制成共聚物时的官能团浓度变高的观点出发,优选为马来酸酐。它们可以单独使用或者组合使用两种以上。
此外,对于上述共聚物来说,在上述的各种单体成分的基础上,可以组合使用其它的具有烯属不饱和基团的化合物。作为所述化合物,可列举出苯乙烯、丁二烯、异戊二烯等。
另一方面,作为接枝改性中使用的聚烯烃,可列举出碳原子数为2~8的烯烃的均聚物或共聚物、碳原子数为2~8的烯烃与其它单体的共聚物等,具体而言,可列举出例如高密度聚乙烯(HDPE)、低密度聚乙烯(LDPE)、线状低密度聚乙烯树脂等聚乙烯、聚丙烯、聚异丁烯、聚(1-丁烯)、聚4-甲基戊烯、聚乙烯基环己烷、乙烯/丙烯嵌段共聚物、乙烯/丙烯无规共聚物、乙烯/丁烯-1共聚物、乙烯/4-甲基-1-戊烯共聚物、乙烯/己烯共聚物等α-烯烃共聚物、乙烯/乙酸乙烯酯共聚物、乙烯/甲基丙烯酸甲酯共聚物、乙烯/乙酸乙烯酯/甲基丙烯酸甲酯共聚物、丙烯/1-丁烯共聚物等。这些之中,尤其是从粘接强度良好的观点出发,优选碳原子数为3~8的烯烃的均聚物、碳原子数为3~8的烯烃的两种以上的共聚物,尤其是丙烯的均聚物或者丙烯/1-丁烯共聚物对溶剂的耐性优异且粘接强度优异,从这一点出发是优选的。
接下来,作为与聚烯烃的接枝改性中使用的烯属不饱和羧酸或烯属不饱和羧酸酐,可列举出例如丙烯酸、甲基丙烯酸、马来酸、衣康酸、柠康酸、中康酸、马来酸酐、4-甲基环己-4-烯-1,2-二羧酸酐、双环[2.2.2]辛-5-烯-2,3-二羧酸酐、1,2,3,4,5,8,9,10-八氢萘-2,3-二羧酸酐、2-辛-1,3-二酮螺[4.4]壬-7-烯、双环[2.2.1]庚-5-烯-2,3-二羧酸酐、马来海松酸、四氢邻苯二甲酸酐、甲基-双环[2.2.1]庚-5-烯-2,3-二羧酸酐、甲基-5-降冰片烯-2,3-二羧酸酐、5-降冰片烯-2,3-二羧酸酐等。这些之中,尤其是从接枝改性后的官能团的反应性变高,并且经接枝改性后的聚烯烃的官能团浓度变高的观点出发,优选为马来酸酐。它们可以单独使用或者组合使用两种以上。
为了通过接枝改性而使聚烯烃与上述烯属不饱和羧酸或烯属不饱和羧酸酐发生反应,具体而言,可列举出下述方法等:将上述聚烯烃熔融,向其中添加烯属不饱和羧酸或烯属不饱和羧酸酐(接枝单体),使其发生接枝反应的方法;将聚烯烃树脂溶解于溶剂而制成溶液,向其中添加烯属不饱和羧酸或烯属不饱和羧酸酐,使其发生接枝反应的方法;将溶解于有机溶剂中的聚烯烃树脂与上述烯属不饱和羧酸或烯属不饱和羧酸酐混合,在上述聚烯烃树脂的软化温度或熔点以上的温度下进行加热,在熔融状态下同时进行自由基聚合和脱氢反应的方法。
为了在任意情况下均使上述接枝单体高效地进行接枝共聚,优选在自由基聚合引发剂的存在下实施接枝反应。接枝反应通常在60~350℃的条件下进行。自由基聚合引发剂的使用比例相对于改性前的聚烯烃树脂100重量份通常为0.001~1重量份的范围。
作为自由基聚合引发剂,优选为有机过氧化物,可列举出例如过氧化苯甲酰、过氧化二氯苯甲酰、过氧化二异丙苯、二叔丁基过氧化物、2,5-二甲基-2,5-二(过氧化苯甲酸酯)己炔-3、1,4-双(叔丁基过氧化异丙基)苯、过氧化月桂酰、过乙酸叔丁酯、2,5-二甲基-2,5-二(叔丁基过氧化)己炔-3、2,5-二甲基-2,5-二(叔丁基过氧化)己烷、过苯甲酸叔丁酯、过苯基乙酸叔丁酯、过异丁酸叔丁酯、过仲辛酸叔丁酯、过特戊酸叔丁酯、过特戊酸异丙苯酯和过二乙基乙酸叔丁酯等。也可以使用其它偶氮化合物、例如偶氮双异丁腈、偶氮异丁酸二甲酯等。
上述自由基聚合引发剂根据接枝反应的工艺来选择最佳的引发剂即可,通常优选使用过氧化二异丙苯、二叔丁基过氧化物、2,5-二甲基-2,5-二(叔丁基过氧化)己炔-3、2,5-二甲基-2,5-二(叔丁基过氧化)己烷、1,4-双(叔丁基过氧化异丙基)苯等二烷基过氧化物。
对于上述具有酸基或酸酐基的烯烃树脂(A)来说,从金属层的密合性进一步提高,耐电解质性优异的方面出发,更优选为具有1~200mgKOH/g的酸值的烯烃树脂(A)。
本发明中,较之烯烃系单体与烯属不饱和羧酸或烯属不饱和羧酸酐的共聚物,将烯属不饱和羧酸或烯属不饱和羧酸酐向聚烯烃进行接枝改性而得到的树脂从粘接强度更优异这一点出发是优选的。
作为所述具有酸基或酸酐基的烯烃树脂(A),尤其是马来酸酐改性聚丙烯、丙烯/1-丁烯共聚物的马来酸酐改性体,从粘接强度、特别是高温环境下的粘接强度优异的方面出发,是优选的。
从耐电解液性优异的观点出发,以上详述的具有酸基或酸酐基的烯烃树脂(A)的熔点优选为65℃~85℃的范围,进而,从耐电解液性优异的观点出发,基于DSC(差示扫描量热分析)的结晶化峰温度优选为28℃以上。
(固化剂(B))
接下来,固化剂(B)是与具有酸基或酸酐基的烯烃树脂(A)发生反应而与其交联,从而使粘接剂自身固化的成分,可列举出多官能异氰酸酯化合物、含氮丙啶基的化合物、以及环氧化合物、三聚氰胺树脂等。
此处,作为多官能异氰酸酯化合物,可列举出例如2,4-甲苯二异氰酸酯、2,6-甲苯二异氰酸酯、苯二亚甲基二异氰酸酯、二苯基甲烷二异氰酸酯、异佛尔酮二异氰酸酯、1,5-萘二异氰酸酯、六亚甲基二异氰酸酯、双(4-异氰酸酯环己基)甲烷、或者氢化二苯基甲烷二异氰酸酯等二异氰酸酯以及由它们衍生出的化合物、即上述二异氰酸酯的异氰脲酸酯体、加合体、缩二脲型、脲二酮体、脲基甲酸酯体、具有异氰酸酯残基的预聚物(由二异氰酸酯和多元醇得到的低聚物)、或者它们的复合体等。
将上述多官能异氰酸酯化合物用作固化剂(B)时,从固化性、粘接强度的观点出发,优选异氰酸酯基相对于具有酸基或酸酐基的烯烃树脂(A)中的酸基(酸酐基设为2当量)的当量比[NCO/酸基]为达到0.05~0.6的比例。
作为上述含氮丙啶基的化合物,可列举出例如N,N’-六亚甲基-1,6-双(1-氮丙啶羧基酰胺)、N,N’-二苯基甲烷-4,4’-双(1-氮丙啶羧基酰胺)、三羟甲基丙烷-三-β-吖丙啶基丙酸酯)、N,N’-甲苯-2,4-双(1-氮丙啶羧基酰胺)、三乙烯三聚氰胺、三羟甲基丙烷-三-β(2-甲基氮丙啶)丙酸酯、双间苯二甲酰-1-2-甲基氮丙啶、三-1-吖丙啶基氧化膦、三-1-2-甲基氮丙啶氧化膦等。
将上述含氮丙啶基的化合物用作固化剂(B)时,从固化性、粘接强度的观点出发,优选氮丙啶基相对于具有酸基或酸酐基的烯烃树脂(A)中的酸基(酸酐基设为2当量)的当量比[氮丙啶基/酸基]为达到0.3~10的比例。
作为上述环氧化合物,可列举出乙二醇、丙二醇、己二醇、新戊二醇、三羟甲基乙烷、三羟甲基丙烷、季戊四醇、甘油、双甘油、山梨糖醇、螺二醇或氢化双酚A等脂肪族多元醇的聚缩水甘油醚型环氧树脂;双酚A型环氧树脂、双酚F型环氧树脂、双酚S型环氧树脂、双酚AD型环氧树脂等双酚型环氧树脂;作为苯酚酚醛清漆树脂、甲酚酚醛清漆树脂的缩水甘油醚的酚醛清漆型环氧树脂等芳香族环氧树脂;作为双酚A、双酚F、双酚S、双酚AD等芳香族系多羟基化合物的环氧乙烷或环氧丙烷加成物的多元醇的聚缩水甘油醚;聚乙二醇、聚丙二醇或聚四亚甲基二醇等聚醚多元醇的聚缩水甘油醚型环氧树脂;双(3,4-环氧环己基甲基)己二酸酯、3,4-环氧环己基甲基-3’,4’-环氧环己基羧酸酯等环状脂肪族型聚环氧树脂。
上述环氧化合物的环氧当量在100~300g/eq.的范围时,从能够确保较长的储存期,并且交联密度高,粘接强度更良好的观点出发,是优选的,尤其是脂肪族多元醇的聚缩水甘油醚型环氧树脂从粘接强度优异这一点出发是优选的。
此外,将环氧化合物用作固化剂(B)时,环氧基相对于具有酸基或酸酐基的烯烃树脂(A)中的酸基(酸酐基设为2当量)的当量比[环氧基/酸基]优选为达到0.1~10的比例,其中,为达到0.1~3的比例时从固化性、粘接强度的观点出发是优选的。此外,本发明中,优选与上述环氧化合物一起并用固化促进剂。
此处可使用的固化促进剂可列举出例如磷系化合物、叔胺、咪唑、有机酸金属盐、路易斯酸、胺络合盐等。这些之中,从固化促进效果优异的观点出发,优选咪唑。
上述的各种固化剂(B)之中,尤其是从储存期性优异且粘接强度也良好的观点出发,优选环氧化合物。即,在作为固化剂(B)而使用例如多官能异氰酸酯化合物时,虽然其与作为主剂的具有酸基或酸酐基的烯烃树脂(A)的反应性高,固化性良好,然而在其相反的方面储存期变短、容易导致凝胶化,但是环氧化合物在确保长期储存期的同时,还兼具优异的粘接强度。
接下来,本发明中使用的苯乙烯树脂(C)可列举出苯乙烯的均聚物、α-甲基苯乙烯的均聚物等苯乙烯系单体的均聚物;苯乙烯与α-甲基苯乙烯的共聚物;苯乙烯和α-甲基苯乙烯等苯乙烯系单体与聚合性脂肪族单体的共聚物;苯乙烯和α-甲基苯乙烯等苯乙烯系单体与聚合性芳香族单体的共聚物等。
(苯乙烯树脂(C))
此外,上述苯乙烯树脂(C)的熔点在80~140℃的范围时,从耐电解液性优异的观点出发是优选的。此外,其重均分子量在800~3,000的范围时,从对金属膜的润湿性得到改善,氢氟酸的阻挡效果更优异的观点出发是优选的。需要说明的是,此处,重均分子量是通过下述条件测定的值。
测定装置:东曹株式会社制HLC-8220GPC
柱:东曹株式会社制TSK-GUARDCOLUMN SuperHZ-L
+东曹株式会社制T SK-GEL SuperHZM-M×4
检测器:RI(差示折射计)
数据处理:东曹株式会社制Multi Station GPC-8020model II
测定条件:柱温 40C
溶剂 四氢呋喃
流速 0.35ml/分钟
标准:单分散聚苯乙烯
试样:将以树脂固体成分换算为0.2质量%的四氢呋喃溶液用微过滤器过滤得到的物质(100μl)
如上所示,苯乙烯树脂(C)的配合量相对于上述烯烃树脂(A)100质量份为0.01~1.5质量份的范围。在该配合量低于0.01质量份时,无法充分表现出通过配合该苯乙烯树脂(C)而带来的阻挡氢氟酸的效果,另一方面,在该配合量超过1.5质量份时,导致粘接强度的降低,难以防止氢氟酸对粘接剂层与金属层的界面造成的侵蚀。
本发明的层压粘接剂中,通过在上述各成分的基础上进一步配合有机溶剂,从而能够确保流动性,表现出适当的涂布性。作为所述有机溶剂,只要是通过涂布粘接剂时的干燥工序中的加热而能够使其挥发去除的溶剂,就没有特别限定,可列举出例如甲苯、二甲苯等芳香族系有机溶剂;正己烷、正庚烷等脂肪族系有机溶剂;环己烷、甲基环己烷等脂环族系有机溶剂;甲乙酮、甲基异丁基酮、环己酮等酮系溶剂;乙酸乙酯、乙酸丁酯等酯系溶剂;乙醇、甲醇、正丙醇、2-丙醇(异丙醇)、丁醇、己醇等醇系溶剂;二异丙醚、丁基溶纤剂、四氢呋喃、二噁烷、丁基卡必醇等醚系溶剂;二乙二醇单甲醚、三乙二醇单甲醚、丙二醇单甲醚等二醇醚系溶剂;乙二醇单甲醚乙酸酯、丙二醇单甲醚乙酸酯、二乙二醇单***乙酸酯等二醇酯系溶剂等,它们可以单独使用,也可以组合使用2种以上。
然而,本发明中使用的上述具有酸基或酸酐基的烯烃树脂(A)是非氯系的烯烃树脂,通常对有机溶剂的溶解性差。因而,作为对上述具有酸基或酸酐基的烯烃树脂(A)显示出良好溶解性的有机溶剂,期望以脂环族系有机溶剂与酯系溶剂与醇系溶剂的混合溶剂的形式来使用。
作为脂环族系有机溶剂,优选为环己烷、甲基环己烷等,作为酯系溶剂,优选为乙酸乙酯、乙酸丁酯等,作为醇系溶剂,优选为乙醇、甲醇、正丙醇、2-丙醇(异丙醇)、丁醇、己醇等,其中,优选为丁醇、异丙醇。配合比率没有特别限定,如果脂环族系有机溶剂为相对于混合溶剂总量占据50%的量,则溶解性更优异,故而优选。
优选为例如甲基环己烷/乙酸丁酯/丁醇、甲基环己烷与乙酸乙酯与异丙醇的组合。
上述混合溶剂通常难以溶解苯乙烯系树脂的其他的热塑性树脂,但是本发明中使用的苯乙烯树脂(C)虽然是热塑性树脂,却仍然良好地溶解于该混合溶剂。因此,使用上述混合溶剂时,粘接剂的涂布性、对金属膜的润湿性变得良好,阻挡氢氟酸的效果变得更良好。
此处,作为上述有机溶剂的用量,相对于上述具有酸基或酸酐基的烯烃树脂(A)与该有机溶剂的总质量,上述具有酸基或酸酐基的烯烃树脂(A)的比例是达到10~30质量%的比例时,从作为粘接剂的涂布性、对金属膜的润湿性优异的观点出发,是优选的。
本发明的层压用粘接剂可进一步根据需要而使用赋粘剂、增塑剂、热塑性弹性体、磷酸化合物、硅烷偶联剂或反应性弹性体。这些添加剂的含量在不损害本发明粘接剂的功能的范围内可以适当调整来使用。
作为此处可使用的赋粘剂,可列举出聚萜烯树脂、松香系树脂、脂肪族系石油树脂、脂环族系石油树脂、共聚系石油树脂和氢化石油树脂等。
此外,作为增塑剂,可列举出聚异戊二烯、聚丁烯、操作油等,作为热塑性弹性体,可列举出苯乙烯/丁二烯共聚物(SBS)、苯乙烯/丁二烯共聚物的加氢物(SEBS)、SBBS、苯乙烯/异戊二烯共聚物的加氢物(SEPS)、苯乙烯嵌段共聚物(TPS)、烯烃系弹性体(TPO)等,反应性弹性体可列举出将这些弹性体进行酸改性而得到的产物。此外,作为硅烷偶联剂,可列举出氨基硅烷、巯基硅烷、乙烯基硅烷、环氧硅烷、甲基丙烯酸类硅烷、脲基硅烷、烷基硅烷、苯乙烯基硅烷、硫化物硅烷、异氰酸酯硅烷。
通过将以上详述的各成分进行混合,从而能够制备出本发明的层压用粘接剂。此时,可以同时配合各成分并混合而制成粘接剂,但是从粘接剂的稳定性、作业性优异的观点出发,优选:将除了固化剂(B)之外的成分预先混合而预先制造出主剂的预混物,在使用粘接剂时制成将固化剂(B)混合的双组份型粘接剂。
(多层膜)
通过使用本发明的层压用粘接剂,使未拉伸聚烯烃膜与金属膜进行贴合,从而能够得到本发明的多层膜。
作为此处使用的金属膜,可列举出金属箔、贴合有各种膜的金属箔、金属蒸镀膜等,作为其原材料,可列举出例如铝、铜、镍、不锈钢等。可以对这些金属膜实施喷砂处理、研磨处理、脱脂处理、蚀刻处理、基于防锈剂浸渍或喷雾的表面处理、三价铬化成处理、磷酸盐化成处理、硫化物化成处理、阳极氧化被膜形成、氟树脂涂布等表面处理。这些之中,实施了三价铬化成处理后的金属膜从密合性保持性能(耐环境劣化性)、防腐蚀性优异的观点出发是优选的。此外,从防止腐蚀的观点出发,该金属膜的厚度优选为10~100μm的范围。
另一方面,作为未拉伸聚烯烃膜,可列举出聚乙烯、聚丙烯等的未拉伸膜。此外,未拉伸聚烯烃膜的厚度为10~100μm的范围时,从能够实现包装袋的薄膜化且包装袋自身的强度优异的观点出发是优选的。
作为制造多层膜的具体方法,通过使用上述有机溶剂将本发明的层压用粘接剂调整至适当的粘度后,使用辊涂法、凹版涂布法、棒涂法等公知的涂布方法,将其涂布至上述金属膜并干燥,从而形成粘接层。此时,本发明的层压用粘接剂组合物的干燥涂布重量优选在达到0.5~20.0g/m2的范围内。若低于0.5g/m2,则连续均匀涂布性容易降低,另一方面,若超过20.0g/m2,则涂布后的溶剂脱离性也降低,容易发生作业性降低、残留溶剂的问题。
接着,通过在金属膜的涂布有本发明层压用粘接剂的面上重叠未拉伸聚烯烃膜并进行干式层压(干式层叠法)来进行贴合,从而能够得到作为目标的本发明的多层膜。此处,优选在层压辊的温度为25~120℃、压力为3~300kg/cm2的条件下实施。
此外,从能够提高粘接强度的观点出发,优选进行干式层压后再进行熟化。熟化条件优选为25~100℃、12~240小时。
从赋形性的观点出发,优选:上述本发明的多层膜在上述金属膜的借助上述粘接剂进行粘接的一侧的相反侧进一步隔着粘接层层压有基材膜。此处,构成粘接层的粘接剂可以是公知通用的层压用粘接剂,但从粘接强度的观点出发,期望为本发明的层压用粘接剂。
作为此处可使用的基材膜,可列举出双轴拉伸聚酯膜或双轴拉伸聚酰胺膜。该基材膜位于用作二次电池的外装材时的最外层。此外,基材膜的厚度通常可列举出15~30μm的范围。
图1是这样操作而得到的本发明的多层膜的截面图,金属膜C与未拉伸聚烯烃膜A隔着本发明的粘接剂B被层压,进而,隔着粘接剂层D(期望为本发明的粘接剂)进一步层压了基材膜E。此处,将所述多层膜形成为二次电池的外装材时,以未拉伸聚烯烃膜A侧接触电解质溶液的方式来使用,最终通过相对的未拉伸聚烯烃膜A被热封来形成外装材。
(二次电池)
接下来,使用本发明的多层膜来制造二次电池时,作为该二次电池的形态,可列举出:将多层膜成形为袋状而制成二次电池的形态、或者通过深拉深成形或鼓凸成形使多层膜形成外装材而制成二次电池的形态。
在此,具体而言,袋状的二次电池以二次电池主体、分别与该二次电池的正极和负极接合的构成端子的极耳、电解质溶液、以及以上述极耳露出至二次电池外部的方式将上述二次电池主体和电解质溶液封入的外装材作为必须的构成要素,其中,上述外装材可列举出:将本发明的多层膜以上述未拉伸聚烯烃膜侧相对地形成热封部的方式重合或折叠,并进行热封,从而构成袋状包装袋的外装材。作为具体的袋状包装袋,有三向密封袋、四向密封袋和枕型等袋形式,例如在四向密封袋的情况下,如图2的俯视图所示,可列举出具有下述结构:以内包电池主体的方式由多层膜b形成包装袋,在与二次电池主体的正极和负极接合的极耳a露出至外部且在内部液密性地填充有电解质溶液的状态下,通过四向的热封部c密闭。
另一方面,关于通过多层膜的深拉深成形或鼓凸成形而得到的二次电池,具体可列举出具有下述结构:通过对本发明的多层膜进行深拉深成形或鼓凸成形,从而以未拉伸聚烯烃膜侧构成密封面的方式形成被赋形为压花状的成形体,使两个成形体(多层膜的密封面彼此)贴合,且在通过该贴合而形成的内部空隙配设二次电池主体和电极端子并使该电极端子露出至电池外部,且在该内部空隙液密性地填充有电解质溶液。具体而言,例如如图3的立体图所示,可列举出:被赋形为压花状的电池容器e以内包二次电池且填充有电解质溶液的方式进行贴合并具备电极端子d的结构。需要说明的是,被赋形为压花状的成形体的密封面彼此通过热封而形成的轮缘部可以如图3所示那样地被切掉。
在此,上述二次电池期望被用作锂离子电池,此时的电解质溶液由碳酸丙二醇酯、碳酸乙二醇酯、碳酸二甲酯、碳酸二乙酯、碳酸甲乙酯等非质子性溶剂与电解质构成。此处,作为作为电解质的锂盐,可以使用LiPF6、LiBF4等盐。
如上所述,这些锂盐通过与水分的水解反应而生成氢氟酸,有时导致金属面的腐蚀、多层膜的各层之间的层压强度的降低,但是,在本发明中能够有效地从金属面阻挡该氢氟酸。
实施例
以下,通过实施例来具体说明本发明。表记“份”表示质量份。
需要说明的是,各实施例和比较例中使用的苯乙烯树脂的重均分子量(Mw)是通过下述条件测定的值。
测定装置:东曹株式会社制HLC-8220GPC
柱:东曹株式会社制TSK-GUARDCOLUMN SuperHZ-L
+东曹株式会社制TSK-GEL SuperHZM-M×4
检测器:RI(差示折射计)
数据处理:东曹株式会社制Multi Station GPC-8020modelII
测定条件:柱温 40℃
溶剂 四氢呋喃
流速 0.35ml/分钟
标准:单分散聚苯乙烯
试样:将以树脂固体成分换算为0.2质量%的四氢呋喃溶液利用微过滤器过滤得到的物质(100μl)
(实施例1~4和比较例1~6)
将作为具有酸基或酸酐基的烯烃树脂(A)的、将马来酸酐接枝改性于包含1-丙烯和1-丁烯的共聚物而得到的含酸基的烯烃树脂20质量份溶解于80质量份混合溶剂(甲基环己烷/乙酸丁酯/丁醇=72/7/1(质量比)),将由此所得的树脂溶液(不挥发成分为20质量%、东洋纺株式会社制造的“HARDLEN NS-2002”)100质量份用作主剂,混合表1或表2所示的除了环氧化合物之外的成分,并充分搅拌,制造出主剂的预混物。接下来,将表1或表2所示的环氧化合物以表1或表2中的配合量配合至上述预混物中而制备出粘接剂后,用棒涂机以5g/m2的涂布量(dry)涂布至未表面处理铝箔(东洋铝株式会社制造的铝箔“1N30H”:膜厚为30μm),以80℃干燥1分钟后,在100℃使其与未拉伸聚烯烃膜(东丽膜加工株式会社制造的“ZK-93KM”、膜厚:70μm)粘贴,从而制作出层叠体。
其后,以60℃熟化5天后,测定初始粘接强度。
(实施例5)
将作为具有酸基或酸酐基的烯烃树脂(A)的、将马来酸接枝改性于包含1-丙烯和1-丁烯的共聚物而得到的含酸基的烯烃树脂(GMP7550E)20质量份溶解于80质量份混合溶剂(甲基环己烷/乙酸乙酯/异丙醇=72/7/1的混合溶剂),将由此所得的树脂溶液(不挥发成分为20质量%)100质量份用作主剂,除此之外,与实施例4同样制备粘接剂,使用该粘接剂来制作层叠体。
对于各例中得到的层叠体,评价了粘接性能和耐电解液性,将其结果示于表1。需要说明的是,各性能试验的条件如下所示。
(初始粘接强度的测定)
在A&D株式会社制造的TENSILON试验仪中,将上述涂布物切割成15mm宽,测定180°剥离强度。
(耐电解液性)
将层叠体以85℃在电解液“碳酸乙二醇酯∶碳酸甲乙酯∶碳酸二甲酯=1∶1∶1(wt%)+LiPF6为1mol+碳酸亚乙烯酯为1质量%”中浸渍7天,由浸渍前后的粘接强度的保持率如下所示地实施评价。
○:80%以上
△:60%以上且低于80%
×:低于60%
(储存期性)
按照表1和表2的配合,配合主剂、固化剂和溶剂,充分搅拌并脱泡后,利用B型粘度计来测定粘度。紧紧地密闭样品瓶的瓶盖,并放入40℃的恒温槽中,在2小时后、4小时后、6小时后测定各自的粘度,按照下述基准来评价粘度的推移。
○:相对于初始的粘度上升率低于30%
△:相对于初始的粘度上升率为30%以上且低于50%
×:相对于初始的粘度上升率为50%以上
(高温强度试验)
在A&D株式会社制造的TENSILON试验仪中,将上述涂布物切割成15mm宽,在80℃的恒温槽内测定剥离强度。
[表1]
[表2]
HARDLEN NS-2002:使将马来酸酐接枝改性于包含1-丙烯和1-丁烯的共聚物而得到的含酸基的烯烃树脂溶解于混合溶剂(甲基环己烷/乙酸丁酯/丁醇=72/7/1(质量比))而得到的树脂溶液(不挥发成分为20质量%)
GMP7550E:将马来酸接枝改性于包含1-丙烯和1-丁烯的共聚物而得到的含酸基的烯烃树脂(不挥发成分为100质量%)
CUREZOL 2E4MZ:咪唑(四国化成工业株式会社制,“CUREZOL 2E4MZ”、不挥发成分为100%)
Denacol EX-321:环氧树脂(三羟甲基丙烷聚缩水甘油醚、Nagase ChemteXCorporation制,“Denacol EX-321”、不挥发成分为100质量%)
FTR6100:苯乙烯系单体与聚合性脂肪族单体的共聚物(三井化学公司制,苯乙烯系树脂“FTR6100”、重均分子量为1100、不挥发成分为100质量%)
FTR2140:苯乙烯与α-甲基苯乙烯的共聚物(三井化学公司制,“FTR2140”、重均分子量为3200、不挥发成分为100质量%)
FMR0150:苯乙烯系单体与聚合性芳香族单体的共聚物(三井化学公司制,“FMR0150”、重均分子量为2000、不挥发成分为100质量%)
FTR8120:苯乙烯系单体的均聚物(三井化学公司制,“FTR8120”、重均分子量为1500、不挥发成分为100质量%)
EPICLON 860:双酚A型环氧树脂(DIC株式会社制,“EPICLON 860”、环氧当量为240g/eq.、不挥发成分为100质量%)
其结果,使用了实施例1~5的层压用粘接剂的层叠体的初始粘接强度高,且耐电解液性优异。比较例1~4是未加入苯乙烯树脂的例子,耐电解液性差。此外,比较例5~6是苯乙烯树脂超过1.5质量份的例子,初始粘接强度差。
符号说明
A:未拉伸聚烯烃膜
B:本发明的层压用粘接剂
C:金属膜
D:粘接剂层
E:基材膜
a:极耳
b:多层膜
c:热封部
d:电极端子
e:成形体
Claims (12)
1.一种层压用粘接剂,其特征在于,其是以具有酸基或酸酐基的烯烃树脂(A)、固化剂(B)和苯乙烯树脂(C)作为必须成分的层压用粘接剂,其中,所述苯乙烯树脂(C)的配合比例相对于所述烯烃树脂(A)100质量份为0.01~1.5质量份的范围。
2.根据权利要求1所述的层压用粘接剂,其中,所述苯乙烯树脂(C)的熔点在80~140℃的范围。
3.根据权利要求1或2所述的层压用粘接剂,其中,所述苯乙烯系树脂(C)的重均分子量在800~3,000的范围。
4.根据权利要求1~3中任一项所述的层压用粘接剂,其中,所述苯乙烯系树脂(C)为苯乙烯系单体的均聚物、苯乙烯与α-甲基苯乙烯的共聚物、苯乙烯系单体与聚合性脂肪族单体的共聚物、或者苯乙烯系单体与聚合性芳香族单体的共聚物。
5.根据权利要求1~4中任一项所述的层压用粘接剂,其中,所述固化剂(B)为环氧化合物。
6.根据权利要求1~5中任一项所述的层压用粘接剂,其中,所述具有酸基或酸酐基的烯烃树脂(A)是将烯属不饱和羧酸或烯属不饱和羧酸酐接枝改性于碳原子数为3~8的烯烃的均聚物或2种以上碳原子数为3~8的烯烃的共聚物而得到的。
7.根据权利要求1~6中任一项所述的层压用粘接剂,其含有脂环族系有机溶剂与酯系溶剂与醇系溶剂的混合溶剂。
8.一种多层膜,其以借助权利要求1~7中任一项所述的粘接剂将未拉伸聚烯烃膜与金属膜粘接而得到的层叠体作为必须的膜构成。
9.根据权利要求8所述的多层膜,其中,在所述金属膜的借助所述粘接剂粘接的一侧的相反侧,进一步隔着粘接层而层压有基材膜。
10.根据权利要求9所述的多层膜,其中,所述基材膜为双轴拉伸聚酯膜或双轴拉伸聚酰胺膜。
11.一种二次电池,其特征在于,其是以二次电池主体、分别与该二次电池的正极和负极接合的极耳、电解质溶液、以及以所述极耳露出至二次电池外部的方式将所述二次电池主体和电解质溶液封入的外装材作为必须的构成要素的二次电池,其中,
所述外装材是通过将权利要求8~10中任一项所述的多层膜以所述未拉伸聚烯烃膜侧形成热封部的方式构成袋状的包装袋而得到的。
12.一种二次电池,其特征在于,其具有下述结构:权利要求8~10中任一项所述的多层膜具有通过深拉深成形或鼓凸成形而以未拉伸聚烯烃膜侧构成密封面的方式被赋形为压花状的形状,使两个该多层膜的密封面彼此贴合,且在通过该贴合而形成的内部空隙配设二次电池主体和电极端子并使该电极端子露出至电池外部,且在该内部空隙液密性地填充有电解质溶液。
Applications Claiming Priority (3)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2015169103 | 2015-08-28 | ||
JP2015-169103 | 2015-08-28 | ||
PCT/JP2016/074798 WO2017038615A1 (ja) | 2015-08-28 | 2016-08-25 | ラミネート用接着剤、多層フィルム、及びこれを用いた二次電池 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN107922806A true CN107922806A (zh) | 2018-04-17 |
CN107922806B CN107922806B (zh) | 2020-06-26 |
Family
ID=58187424
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201680049429.7A Expired - Fee Related CN107922806B (zh) | 2015-08-28 | 2016-08-25 | 层压用粘接剂、多层膜和使用了其的二次电池 |
Country Status (7)
Country | Link |
---|---|
US (1) | US20180248156A1 (zh) |
EP (1) | EP3342838A4 (zh) |
JP (1) | JP6143147B1 (zh) |
KR (1) | KR20180037215A (zh) |
CN (1) | CN107922806B (zh) |
TW (1) | TWI711676B (zh) |
WO (1) | WO2017038615A1 (zh) |
Cited By (7)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108884367A (zh) * | 2016-05-10 | 2018-11-23 | Dic株式会社 | 层压用粘接剂、使用该粘接剂的层叠体以及二次电池 |
CN110607141A (zh) * | 2018-06-15 | 2019-12-24 | Dic株式会社 | 接着剂、层叠体、电池用包装材、电池用容器及电池 |
CN113025127A (zh) * | 2019-12-25 | 2021-06-25 | Dic株式会社 | 涂布剂、层叠体、成型体及包装材料 |
CN114096628A (zh) * | 2019-07-10 | 2022-02-25 | 大日本印刷株式会社 | 金属端子用粘接性膜、带有金属端子用粘接性膜的金属端子、使用了该金属端子用粘接性膜的蓄电器件和蓄电器件的制造方法 |
CN114207068A (zh) * | 2019-09-06 | 2022-03-18 | 东洋纺株式会社 | 聚烯烃系粘接剂组合物 |
CN114341301A (zh) * | 2019-10-08 | 2022-04-12 | 东洋纺株式会社 | 聚烯烃系粘合剂组合物 |
CN114787311A (zh) * | 2019-12-25 | 2022-07-22 | Dic株式会社 | 粘接剂、层叠体、包装材、电池用包装材、电池 |
Families Citing this family (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR102468900B1 (ko) * | 2017-05-31 | 2022-11-18 | 린텍 가부시키가이샤 | 시트상 접착제, 가스 배리어성 적층체, 및 봉지체 |
JP6911635B2 (ja) * | 2017-08-24 | 2021-07-28 | 東洋インキScホールディングス株式会社 | 接着剤組成物および積層体 |
TWI785173B (zh) * | 2017-12-26 | 2022-12-01 | 日商迪愛生股份有限公司 | 接著劑、積層體、電池用包裝材料及電池 |
WO2019171709A1 (ja) * | 2018-03-06 | 2019-09-12 | 東洋紡株式会社 | ポリオレフィン系接着剤組成物 |
WO2019172109A1 (ja) * | 2018-03-07 | 2019-09-12 | 東亞合成株式会社 | 接着剤組成物及びこれを用いた接着剤層付き積層体 |
CN111918944A (zh) * | 2018-03-30 | 2020-11-10 | 东洋纺株式会社 | 聚烯烃类粘接剂组合物 |
CN111971360B (zh) * | 2018-03-30 | 2022-07-08 | 东洋纺株式会社 | 聚烯烃系粘接剂组合物 |
KR102030603B1 (ko) * | 2019-01-23 | 2019-10-10 | 주식회사 케이엠지 | 파우치형 리튬이차전지용 접착제 및 이를 이용한 파우치형 리튬이차 전지 |
US11075407B2 (en) * | 2019-03-15 | 2021-07-27 | Robert Bosch Gmbh | Grafted polyesters as electrolytes for lithium ion batteries |
WO2021251221A1 (ja) * | 2020-06-12 | 2021-12-16 | 東洋紡株式会社 | ポリオレフィン系接着剤組成物および積層体 |
WO2024059996A1 (zh) * | 2022-09-20 | 2024-03-28 | 宁德时代新能源科技股份有限公司 | 复合膜及其制备方法、电池模块、电池包和用电装置 |
Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104662114A (zh) * | 2012-09-25 | 2015-05-27 | Dic株式会社 | 层压用粘接剂、使用了该粘接剂的层叠体以及二次电池 |
Family Cites Families (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS59149943A (ja) * | 1983-02-16 | 1984-08-28 | Sumitomo Chem Co Ltd | 接着性樹脂組成物 |
JPS6114272A (ja) * | 1984-06-29 | 1986-01-22 | Ube Ind Ltd | 接着性ポリエチレン組成物及びその金属積層体 |
JP3184725B2 (ja) * | 1995-01-19 | 2001-07-09 | 昭和電工株式会社 | 接着性樹脂組成物ならびにその積層体およびその製造方法 |
JP3669105B2 (ja) * | 1997-03-26 | 2005-07-06 | 三菱化学株式会社 | 多層延伸成形体 |
TWI511351B (zh) * | 2010-10-14 | 2015-12-01 | Toppan Printing Co Ltd | 鋰離子電池用外裝材料 |
JP5670803B2 (ja) * | 2011-03-31 | 2015-02-18 | ユニチカ株式会社 | 電池用外装体及びその製造方法並びに電池 |
JP6426895B2 (ja) * | 2013-05-31 | 2018-11-21 | 昭和電工パッケージング株式会社 | 電池用外装材及び電池 |
JP5954283B2 (ja) * | 2013-09-20 | 2016-07-20 | Dic株式会社 | ラミネート積層体用接着剤組成物、これを使用した積層体、および二次電池 |
JP5700166B1 (ja) * | 2014-08-01 | 2015-04-15 | 東洋インキScホールディングス株式会社 | 接着剤組成物、積層体、蓄電デバイス用包装材、蓄電デバイス用容器および蓄電デバイス |
-
2016
- 2016-08-25 KR KR1020187005547A patent/KR20180037215A/ko not_active Application Discontinuation
- 2016-08-25 WO PCT/JP2016/074798 patent/WO2017038615A1/ja active Application Filing
- 2016-08-25 JP JP2017508693A patent/JP6143147B1/ja active Active
- 2016-08-25 EP EP16841647.7A patent/EP3342838A4/en not_active Withdrawn
- 2016-08-25 CN CN201680049429.7A patent/CN107922806B/zh not_active Expired - Fee Related
- 2016-08-25 US US15/755,194 patent/US20180248156A1/en not_active Abandoned
- 2016-08-26 TW TW105127358A patent/TWI711676B/zh active
Patent Citations (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104662114A (zh) * | 2012-09-25 | 2015-05-27 | Dic株式会社 | 层压用粘接剂、使用了该粘接剂的层叠体以及二次电池 |
Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108884367A (zh) * | 2016-05-10 | 2018-11-23 | Dic株式会社 | 层压用粘接剂、使用该粘接剂的层叠体以及二次电池 |
CN108884367B (zh) * | 2016-05-10 | 2021-03-12 | Dic株式会社 | 层压用粘接剂、使用该粘接剂的层叠体以及二次电池 |
CN110607141A (zh) * | 2018-06-15 | 2019-12-24 | Dic株式会社 | 接着剂、层叠体、电池用包装材、电池用容器及电池 |
CN114096628A (zh) * | 2019-07-10 | 2022-02-25 | 大日本印刷株式会社 | 金属端子用粘接性膜、带有金属端子用粘接性膜的金属端子、使用了该金属端子用粘接性膜的蓄电器件和蓄电器件的制造方法 |
CN114207068A (zh) * | 2019-09-06 | 2022-03-18 | 东洋纺株式会社 | 聚烯烃系粘接剂组合物 |
CN114207068B (zh) * | 2019-09-06 | 2024-04-02 | 东洋纺Mc株式会社 | 聚烯烃系粘接剂组合物 |
CN114341301A (zh) * | 2019-10-08 | 2022-04-12 | 东洋纺株式会社 | 聚烯烃系粘合剂组合物 |
CN114341301B (zh) * | 2019-10-08 | 2023-09-29 | 东洋纺Mc株式会社 | 聚烯烃系粘合剂组合物 |
CN113025127A (zh) * | 2019-12-25 | 2021-06-25 | Dic株式会社 | 涂布剂、层叠体、成型体及包装材料 |
CN114787311A (zh) * | 2019-12-25 | 2022-07-22 | Dic株式会社 | 粘接剂、层叠体、包装材、电池用包装材、电池 |
CN114787311B (zh) * | 2019-12-25 | 2023-05-09 | Dic株式会社 | 粘接剂、层叠体、包装材、电池用包装材、电池 |
Also Published As
Publication number | Publication date |
---|---|
KR20180037215A (ko) | 2018-04-11 |
TW201715003A (zh) | 2017-05-01 |
CN107922806B (zh) | 2020-06-26 |
WO2017038615A1 (ja) | 2017-03-09 |
JP6143147B1 (ja) | 2017-06-07 |
US20180248156A1 (en) | 2018-08-30 |
EP3342838A1 (en) | 2018-07-04 |
EP3342838A4 (en) | 2019-03-13 |
TWI711676B (zh) | 2020-12-01 |
JPWO2017038615A1 (ja) | 2017-08-31 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN107922806A (zh) | 层压用粘接剂、多层膜和使用了其的二次电池 | |
CN105658753B (zh) | 层压用胶粘剂、使用了该胶粘剂的层叠体、以及二次电池 | |
KR101899265B1 (ko) | 폴리올레핀계 접착제 조성물 | |
TWI579358B (zh) | 積層用黏著劑、使用其之積層體及二次電池 | |
JP6020438B2 (ja) | 非水電解質二次電池容器用積層体、及びその製造方法、並びに非水電解質二次電池、及び接着剤組成物 | |
CN103931013A (zh) | 电化学电池用包装材料 | |
JP6065570B2 (ja) | 非水電解質二次電池容器用積層体、及びその製造方法、並びに非水電解質二次電池、及び接着剤組成物 | |
CN107310232B (zh) | 电池外包装用层叠体、电池外包装体、电池外包装体的制备方法及电池 | |
CN108473836A (zh) | 层压用粘接剂组合物、层叠体和二次电池 | |
JP7215091B2 (ja) | ポリオレフィン系接着剤組成物 | |
KR101379490B1 (ko) | 전지용 포장재 및 그의 제조 방법 | |
CN106876614A (zh) | 电池包装用层叠体、电池包装体以及电池 | |
JPWO2019188284A1 (ja) | ポリオレフィン系接着剤組成物 | |
JP5589897B2 (ja) | 接着剤組成物、及びそれを用いた積層体、並びに二次電池 | |
JPWO2017030024A1 (ja) | リチウムイオン電池用包装材料 | |
EP3778819B1 (en) | Polyolefin-based adhesive composition | |
JPWO2016075975A1 (ja) | ラミネート用接着剤、それを用いた積層体、及び二次電池 | |
JP2012056974A (ja) | 接着剤組成物、及びそれを用いた積層体、並びに二次電池 | |
CN108884367A (zh) | 层压用粘接剂、使用该粘接剂的层叠体以及二次电池 | |
JP5527143B2 (ja) | 接着剤組成物、及びそれを用いた積層体、並びに二次電池 | |
KR20190035748A (ko) | 폴리올레핀계 접착제 조성물 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
GR01 | Patent grant | ||
GR01 | Patent grant | ||
CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20200626 Termination date: 20210825 |
|
CF01 | Termination of patent right due to non-payment of annual fee |