CN105887515A - 一种锦纶56纤维/棉混纺面料的印花方法 - Google Patents

一种锦纶56纤维/棉混纺面料的印花方法 Download PDF

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CN105887515A
CN105887515A CN201610428281.XA CN201610428281A CN105887515A CN 105887515 A CN105887515 A CN 105887515A CN 201610428281 A CN201610428281 A CN 201610428281A CN 105887515 A CN105887515 A CN 105887515A
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chinlon
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cotton
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郝新敏
鞠景堂
赵鹏程
严欣宁
倪成涛
仇凯
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Liaoning Sunichem Co Ltd
Best Fiber Technology (dandong) Co Ltd
Quartermaster Research Institute of General Logistics Department of CPLA
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Best Fiber Technology (dandong) Co Ltd
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Abstract

本发明公开了一种锦纶56纤维/棉混纺面料的印花方法。该印花方法包括如下步骤：采用活性染料对所述锦纶56纤维/棉混纺面料进行印花；所述锦纶56纤维/棉混纺面料为锦纶56纤维与棉纤维的混纺面料。本发明锦纶56纤维/棉混纺面料的印花方法，具有如下优点：本发明锦纶56纤维与棉混纺织物一步法印花采用同浆印花的方式，具有节约能源、环保的优点，本发明印花方法工艺简单，由于锦纶56纤维的特殊性，同浆印花可以达到两种纤维得色一致的效果。

Description

一种锦纶56纤维/棉混纺面料的印花方法
技术领域
本发明涉及一种锦纶56纤维/棉混纺面料的印花方法。
背景技术
锦纶纤维是世界上出现的第一种合成纤维，锦纶一般常用的品种有锦纶-6为聚己内酰胺，锦纶-66为己二胺与己二酸聚合而成，锦纶56是一种新型的聚酰胺纤维，与锦纶66使用石油原料不同，它使用的原料是生物原料，通过生物工程方法从各类淀粉和秸秆纤维素中发酵制备戊二胺，由于批量大、低成本，故可以代替己二胺。生物基纤维具有绿色、环境友好、原料可再生以及生物降解等优良特性，有助于解决当前全球经济社会发展所面临的严重的资源和能源短缺，以及环境污染等问题。
锦纶56具有许多优异的特性，强度接近锦纶66，高于涤纶，密度低于涤纶；吸湿性高，抗静电性好；柔软度接近羊毛；玻璃化温度低于锦纶66，锦纶56结晶度相对低于锦纶-66，锦纶56玻璃化温度为46℃，远低于涤纶，可保证寒冷条件下耐低温性；柔软，耐磨性好等。
各种纤维，不论是天然纤维、还是人造纤维和合成纤维都各自的优点和缺点。一般天然纤维如棉花、羊毛吸湿性都比较好，穿着舒适，合成纤维一般耐磨性好，强力高，但吸湿性差，透气性不好。把各种纤维，如天然的纤维、人造的纤维和合成的纤维进行不同比例混纺，就可以充分运用各种纤维的特点，取长补短，增强织物的服用性能，锦纶56纤维/棉纯混纺面料的印花方法未见相关技术的公开。
发明内容
本发明的目的是提供一种锦纶56纤维/棉混纺面料的印花方法，本发明的印花方法采用同浆印花的方式，遵循节约能源、环保以及工艺简单的原则。
本发明所提供的一种锦纶56纤维/棉混纺面料的印花方法，包括如下步骤：
采用活性染料对所述锦纶56纤维/棉混纺面料进行印花；
所述锦纶56纤维/棉混纺面料为锦纶56纤维与棉纤维的混纺面料。
上述的印花方法中，所述印花包括如下步骤：
(1)配制印花浆，每100质量份的所述印花浆的组成如下：
增稠剂5份，尿素5份，防染盐1份，碳酸氢钠2份，和余量的水；
所述防染盐为间硝基对甲苯磺酸钠；
(2)向所述印花浆中加入所述活性染料，搅拌均匀后对所述锦纶56纤维/棉混纺面料进行印花，然后依次经烘干和蒸化即实现印花过程。
上述的印花方法中，所述增稠剂可选择增稠剂FS-80E，可由辽宁恒星精细化工有限公司提供，为多羧基高分子聚合物，具有匀染性好、抱水性好，不背渗的特点，使印制的图案轮廓更加精细、同时具有退浆容易、手感柔软等特点。
上述的印花方法中，所述活性染料的选择至关重要，因为活性染料固色是在碱性条件下进行的，所以选择用双活性基活性染料如B型活性染料或P型活性染料，有利于活性染料在低碱条件下与棉纤维及锦纶56纤维发生键合反应，所述P型活性染料具体可为P-6B红活性染料。
上述的印花方法中，所述活性染料的加入量可为所述印花浆质量的0.1％～8％，具体可为4％。
上述的印花方法中，所述烘干的温度可为100℃～110℃，所述烘干的时间可为2分钟～4分钟，具体可在110℃的条件下烘干3分钟；
所述蒸化的温度可为102℃～105℃，所述蒸化的时间可为8～20分钟，具体可在105℃的条件下蒸化15分钟。
本发明锦纶56纤维/棉混纺面料的印花方法，具有如下优点：本发明锦纶56纤维与棉混纺织物一步法印花采用同浆印花的方式，具有节约能源、环保的优点，本发明印花方法工艺简单，由于锦纶56纤维的特殊性，同浆印花可以达到两种纤维得色一致的效果。
具体实施方式
下述实施例中所使用的实验方法如无特殊说明，均为常规方法。
下述实施例中所用的材料、试剂等，如无特殊说明，均可从商业途径得到。
下述实施例中所使用的增稠剂FS-80购自辽宁恒星精细化工有限公司。
下述实施例中所用的P-6B红活性染料购自亨斯曼公司。
实施例1、锦纶56纤维与棉纤维混纺织物活性染料同浆印花
(1)配制印花浆，质量组成如下：
增稠剂FS-80：5％，尿素：5％，防染盐S(间硝基对甲苯磺酸钠)：1％，碳酸氢钠2％和水：87％。
(2)将P-6B红活性染料加入至上述配制的印花浆中，其中，P-6B红活性染料的加入量为印花浆质量的4％，然后搅拌均匀对锦纶56纤维与棉纤维混纺织物进行同浆印花，然后经烘干(110℃×3分钟)、蒸化(105℃×15分钟)和水洗后处理即可。
本实施例混纺织物的印花各项色牢度指标如表1中所示。
由表1中数据可以看出，印花后各项牢度达到要求。
表1实施例锦纶56纤维与棉混纺织物印花各项色牢度指标比
品名项目 实施例1
干摩擦色牢度 3.5
湿摩擦色牢度 3.5
耐水浸色牢度 5
耐氯色牢度 3.5
耐海水色牢度 3.5
耐碱汗渍色牢度 3.5
耐日晒色牢度 5.5
耐皂洗色牢度 3.5
表1中各指标的测定方法如下：
1、皂洗牢度按国标GB/T3921.4-1997测试。
2、干湿摩擦牢度按GB/3920执行。
3、耐(碱)汗渍色牢度按ISO105－E04：2008执行。
4、耐氯漂色牢度按ISO105E03：2010执行。
5、耐海水色牢度按AATCC106－2002执行。
6、耐水浸色牢度按JIS(37±2)℃×4h。
7、耐日晒色牢度按ISO105B02－1994执行。

Claims (7)

1.一种锦纶56纤维/棉混纺面料的印花方法，包括如下步骤：
采用活性染料对所述锦纶56纤维/棉混纺面料进行印花；
所述锦纶56纤维/棉混纺面料为锦纶56纤维与棉纤维的混纺面料。
2.根据权利要求1所述的印花方法，其特征在于：所述印花包括如下步骤：
(1)配制印花浆，每100质量份的所述印花浆的组成如下：
增稠剂5份，尿素5份，防染盐1份，碳酸氢钠2份，和余量的水；
所述防染盐为间硝基对甲苯磺酸钠；
(2)向所述印花浆中加入所述活性染料，搅拌均匀后对所述锦纶56纤维/棉混纺面料进行印花，然后依次经烘干和蒸化即实现印花过程。
3.根据权利要求1或2所述的印花方法，其特征在于：所述增稠剂为增稠剂FS-80E。
4.根据权利要求1-3中任一项所述的印花方法，其特征在于：所述活性染料为B型活性染料或P型活性染料。
5.根据权利要求1-4中任一项所述的印花方法，其特征在于：所述活性染料的加入量为所述印花浆质量的0.1％～8％。
6.根据权利要求1-5中任一项所述的印花方法，其特征在于：所述烘干的温度为100℃～110℃，所述烘干的时间为2分钟～4分钟。
7.根据权利要求1-6中任一项所述的印花方法，其特征在于：所述蒸化的温度为102℃～105℃，所述蒸化的时间为8～20分钟。
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CN111172785A (zh) * 2020-02-04 2020-05-19 军事科学院***工程研究院军需工程技术研究所 一种锦纶56与纤维素纤维混纺织物的碱性印花方法
CN111235911A (zh) * 2020-02-07 2020-06-05 军事科学院***工程研究院军需工程技术研究所 一种锦纶56纤维及织物的碱性快速印花方法
CN111778736A (zh) * 2020-01-09 2020-10-16 军事科学院***工程研究院军需工程技术研究所 一种锦纶56织物或无纺布的酸性低温快速印花方法
CN111826977A (zh) * 2020-01-22 2020-10-27 军事科学院***工程研究院军需工程技术研究所 一种锦纶56与蛋白质纤维混纺织物的酸性印花方法
CN112011868A (zh) * 2019-05-28 2020-12-01 上海凯赛生物技术股份有限公司 一种聚酰胺纤维与棉的混纺纱线及其制备方法和应用

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CN112011868A (zh) * 2019-05-28 2020-12-01 上海凯赛生物技术股份有限公司 一种聚酰胺纤维与棉的混纺纱线及其制备方法和应用
CN111778736A (zh) * 2020-01-09 2020-10-16 军事科学院***工程研究院军需工程技术研究所 一种锦纶56织物或无纺布的酸性低温快速印花方法
CN111826977A (zh) * 2020-01-22 2020-10-27 军事科学院***工程研究院军需工程技术研究所 一种锦纶56与蛋白质纤维混纺织物的酸性印花方法
CN111172785A (zh) * 2020-02-04 2020-05-19 军事科学院***工程研究院军需工程技术研究所 一种锦纶56与纤维素纤维混纺织物的碱性印花方法
CN111235911A (zh) * 2020-02-07 2020-06-05 军事科学院***工程研究院军需工程技术研究所 一种锦纶56纤维及织物的碱性快速印花方法

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