Quick-setting strippable property nail polish glue and preparation method thereof
Technical field
The invention belongs to polymeric material field, relate to a kind of nail polish glue, a kind of quick-setting strippable property nail polish glue and preparation method thereof.
Background technology
Manicure is liked coming from one and is had deep love for by Ms.Nail polish glue is applied to nail with instrument when using, and crosslinks polymerisation after common UV light source light source treatment with irradiation, the nail polish adhesive curing thing of generation beautiful in colour, glittering and translucent full, change irregularly infinite, be the favorite of ladies.Compared with mode light source curing with common UV, UV-LED light source has the plurality of advantages such as luminous efficiency height, life-span length, reaction speed is fast, heat release is few, energy-saving and environmental protection, the most gradually substitutes common UV light source.Along with the abundant of city life and the quickening of rhythm of life conversion, ladies have liked the nail of allegro conversion oneself.Peelable nail polish glue is easy to use, peels off without cleaner just whole of energy when needing to take off, and easily, is particularly suitable for child and uses.But current peelable nail polish glue typically with the addition of peelable component in the formula of nail polish glue, production and use to nail polish glue are made troubles.
Based on background above, need to develop a kind of can rapid curing, have from peel off component, there is decorative effect simultaneously, strippable property nail polish glue that peeling effect is good and preparation method thereof.
Summary of the invention
For above-mentioned technical problem of the prior art, the invention provides a kind of quick-setting strippable property nail polish glue and preparation method thereof, described this quick-setting strippable property nail polish glue and preparation method thereof to solve to the addition of peelable component in nail polish glue formula of the prior art, the technical problem made troubles to production and the use of nail polish glue.
The invention provides a kind of quick-setting strippable property nail polish glue, calculate by weight, its raw material composition and content are as follows:
Wherein, the chemical constitution of described UV solidification Resin A is as follows:
Wherein: m is the integer in the range of 1-30;N is the integer in the range of 1-30;
The preparation method of described UV solidification Resin A is as follows:
1) calculate by weight and weigh following each component:
2) methyl and phenyl hydrogen-containing silicon oil and the tetramethylol methane tetraacrylate of above-mentioned gained are joined in a reaction vessel; add polymerization inhibitor; it is passed through protective gas; stir and heat, being warming up to 60~80 DEG C, adding catalyst; the lower constant temperature 3~5h of stirring; stop heating, treat that temperature drops to room temperature, obtain UV and solidify Resin A;
Described UV solidification resin B is that hyperbranched UV solidifies resin;
nullDescribed reactive diluent is double pentaerythritol methacrylate、Diethylene glycol diacrylate、Oxolane acrylate、Tetramethylol methane tetraacrylate、Ethoxylated bisphenol A dimethylacrylate、Two-trimethylolpropane tetra-acrylate、Three (2-ethoxy) isocyanuric acid triacrylate、Tetramethylol methane tetraacrylate、Ethoxyquin trimethylolpropane trimethacrylate、Third oxidation trimethylolpropane trimethacrylate、Ethoxyquin tetramethylol methane tetraacrylate、Isobornyl acrylate、Tricyclodecane Dimethanol diacrylate、Third oxidation neopentylglycol diacrylate、Ethoxyquin trimethylolpropane trimethacrylate、Hyperbranched polyester acrylic ester、Alkoxy acrylic ester、Carbonic acid mono acrylic ester、Imidazole radicals mono acrylic ester、Cyclic carbonate ester mono acrylic ester、Epoxy silicone monomer、Silicone acrylate、Or any one or the two or more mixture in vinyl ethers monomer;
Described levelling agent is enlightening height Tego Glide 410, any one or two or more mixture in Germany BYK Bi Ke BYK-UV3510, BYK-341, BYK-344, BYK-345, BYK-346, BYK-347 or BYK-348;
One or both mixtures in the described NP-100 that UV wetting agent is LG-DOW company or Germany's BYK 333 levelling agent;
Described defoamer is any one or two or more mixture in Germany BYK Bi Ke BYK-024, BYK-025, BYK-035, BYK-037, BYK-038, BYK-044 or BYK-038;
Described light trigger A is any one or two or more mixture in BASF Irgacure1173, Irgacure 184D, Irgacure TPO, Irgacure 369, Irgacure 651, Irgacure 379, Irgacure 819, Irgacure 907 or macromolecular photoinitiator Esacure KIP 150;
Described photoinitiator b is any one or two or more mixture in BASF BASF light trigger Irgacure 2959, IRGACURE500 or IRGACURE819DW;
Further, described mill base is the temperature sensing color changing mill base of a kind of changeable colour.
Further, the one quick-setting strippable property nail polish glue of the present invention, calculate by weight, its raw material composition and content are as follows:
The preparation method of wherein said UV solidification Resin A is:
Above-mentioned 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of tetramethylol methane tetraacrylates are joined in a reaction vessel, adds the polymerization inhibitor of 0.005 part, be passed through protective gas, stir and heat, be warming up to 60 DEG C, add catalyst, stirring
Lower constant temperature 3h, stops heating, treats that temperature drops to room temperature, obtains UV and solidifies Resin A;
Described reactive diluent is oxolane acrylate, tetramethylol methane tetraacrylate and the mixture of ethoxylated bisphenol A dimethylacrylate 1:1:1 in mass ratio composition;
Described levelling agent is enlightening height Tego Glide 410;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the mixture of Germany BYK-035, BYK-037 1:1 in mass ratio;
Described mill base is the temperature sensing color changing mill base of a kind of changeable colour;
Described light trigger A is the mixture of BASF Irgacure1173, Irgacure 184D, Irgacure TPO 1:1:1 in mass ratio composition;
Described photoinitiator b is the mixture of BASF BASF light trigger Irgacure 2959, IRGACURE500 1:1 in mass ratio composition.
Further, the one quick-setting strippable property nail polish glue of the present invention, calculate by weight, its raw material composition and content are as follows:
The preparation method of wherein said UV solidification Resin A is as follows:
Above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of tetramethylol methane tetraacrylates are joined in a reaction vessel; add the polymerization inhibitor of 0.01 part; it is passed through protective gas; stir and heat, being warming up to 80 DEG C, adding 0.05 part of catalyst; the lower constant temperature 5h of stirring; stop heating, treat that temperature drops to room temperature, obtain UV and solidify Resin A;
Described reactive diluent is oxolane acrylate, tetramethylol methane tetraacrylate and the mixture of ethoxylated bisphenol A dimethylacrylate 2:1:1 in mass ratio composition;
Described levelling agent is the mixture of Germany's BYK-345, BYK-346 1:1 in mass ratio composition;
Described wetting agent is Germany BYK 333;
Described defoamer is the mixture of Germany's BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition;
Described mill base is the temperature sensing color changing mill base of a kind of changeable colour;
Described light trigger A is BASF Irgacure 184D, Irgacure TPO, many kinds of mixtures of Irgacure 369 1:1:1 in mass ratio;
Described photoinitiator b is the mixture of BASF BASF light trigger Irgacure 2959, IRGACURE500 2:1 in mass ratio composition.
Present invention also offers the preparation method of above-mentioned a kind of quick-setting strippable property nail polish glue, comprise the steps:
1) UV solidification Resin A, UV solidification resin B, reactive diluent, levelling agent, wetting agent, defoamer, mill base, light trigger A and photoinitiator b are weighed according to parts by weight;
2) in the high speed dispersor controlling rotating speed 300-400r/min, wetting agent, levelling agent, defoamer and mill base are added, after disperseing 15-20min under 600-800r/min rotating speed, rotating speed is down to 300r/min, add UV solidification Resin A, UV solidification resin B, UV solidification resin C and light trigger A, photoinitiator b, continue dispersion 5-10min, mix, i.e. obtain strippable property nail polish glue.
The reaction equation of above-mentioned UV solidification Resin A is as follows:
Due to the fact that have employed UV solidification Resin A molecular structure in containing several functional group propenoic acid esters make it have at 385nmUV-LED, lamp source irradiate under rapid capability.Precoat the surface of the slide of strippable property nail polish glue through UV nail polish light irradiation after the strippable property nail polish glue film of gained of the present invention, according to the fingers-touch method (surface of the strippable property nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, shortest time used when being fully cured with strippable property nail polish glue characterizes), after testing, the hardening time of the quick-drying strippable property nail polish glue of the present invention is 1-7s.It is organosilicon structures that the UV as main film forming substance of the present invention solidifies Resin A molecular structure, having the lowest surface can, reduce the interaction between film and base material, it is allowed to embody preferable rippability, peel strength uses Shenzhen newly to think carefully, and the CMT5104 electronic tension tester of company is at room temperature carried out the stripping test of 180 °, draw speed 50mm/min by GB/T2790-1995 standard " 180 ° of peeling strength test methods of adhesive ";Recording peel strength is 0.21~0.25kN/m;The chameleon pigment that the present invention adds brings Protean color to strippable property nail polish glue, and the toughening effect UV that has of interpolation solidifies resin C, makes strippable property nail polish glue have certain toughness.
The present invention compares with prior art, and its technological progress is significant.A kind of strippable property nail polish glue of present invention quick setting capabilities under 385nmUV-LED lamp source is irradiated, has the bright feature such as changeable of convenient and swift, the color of covering with paint, has high glaze simultaneously, just has good peelable effect without remover.There is after its film is cured the features such as higher toughness, preferable strippable property.And its preparation method due to technique simple, easy to control, therefore have technology maturation, quickly, the feature such as efficiently, the technical field such as manicure of various people can be widely used, be suitable to industrialized production.
Detailed description of the invention
Below by embodiment, the present invention is described in further detail, but be not limiting as the present invention.
In raw material used by various embodiments of the present invention in addition to the special producer shown and specification, other raw materials are commercially available, and specification is chemical pure.
The model of the various equipment used by the present invention and the information of manufacturer are as follows:
GFJ-0.4 type high speed dispersor, Shanghai Xin Nuo instrument and equipment Co., Ltd produces.
Embodiment 1
A kind of strippable property nail polish glue, calculates by weight, and its raw material composition and content are as follows:
Wherein said UV solidification Resin A calculates by weight, and its composition and content are as follows:
Described UV solidification Resin A is prepared as follows:
Above-mentioned 20 parts of methyl and phenyl hydrogen-containing silicon oils and 10 parts of tetramethylol methane tetraacrylates are joined in the there-necked flask of 500ml; add the polymerization inhibitor of 0.005 part; it is passed through protective gas; stir and heat, being warming up to 60 DEG C, adding catalyst; the lower constant temperature 3h of stirring; stop heating, treat that flask temperature drops to room temperature, obtain UV and solidify Resin A.
Described reactive diluent is oxolane acrylate, tetramethylol methane tetraacrylate, (2) ethoxylated bisphenol A dimethylacrylate, the mixture of the composition of 1:1:1 in mass ratio;
Described levelling agent is enlightening height Tego Glide 410;
Described wetting agent is the NP-100 of LG-DOW company;
Described defoamer is the mixture of Germany BYK-035, BYK-037 1:1 in mass ratio;
Described mill base is the temperature sensing color changing mill base of a kind of changeable colour;
Described light trigger A be BASF Irgacure1173, Irgacure 184D, Irgacure TPO in mass ratio
The mixture of 1:1:1 composition;
Described photoinitiator b is the mixture of BASF BASF light trigger Irgacure 2959, IRGACURE500 1:1 in mass ratio composition;
The preparation method of above-mentioned a kind of strippable property nail polish glue, specifically includes following steps:
(1), the preparation of strippable property nail polish glue
According to formula, 1 part of wetting agent, 0.05 part of levelling agent, 0.2 part of defoamer and 1 part of mill base is added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo instrument and equipment Co., Ltd) controlling rotating speed 300r/min, after disperseing 15min under 600r/min rotating speed, rotating speed is down to 300r/min, add 50 parts of UV solidification Resin A, 50 parts of UV solidification resin B, 50 portions of reactive diluents, 3 parts of light trigger A and 3 parts of photoinitiator bs, continue dispersion 10min, mix, i.e. obtain strippable property nail polish glue.
After the strippable property nail polish glue film of gained of the present invention, UV-LED light irradiation through 385nm precoats the surface of slide of strippable property nail polish glue, according to the fingers-touch method (surface of the strippable property nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, shortest time used when being fully cured with strippable property nail polish glue characterizes), after testing, the hardening time of the quick-drying strippable property nail polish glue of the present invention is 1s.
Further, a kind of strippable property nail polish glue of the present invention, UV solidification Resin A molecular structure as main film forming substance is organosilicon structures, having the lowest surface can, reduce the interaction between film and base material, being allowed to embody preferable rippability, the stripping that peel strength uses Shenzhen newly to think carefully that the CMT5104 electronic tension tester of company at room temperature carries out 180 ° by GB/T2790-1995 standard " 180 ° of peeling strength test methods of adhesive " is tested, draw speed 50mm/min;Recording peel strength is 0.25kN/m;Therefore, curing rate higher after the strippable property nail polish glue film of described gained of the present invention, it is easily peeled.
Embodiment 2
A kind of strippable property nail polish glue, calculates by weight, and its raw material composition and content are as follows:
Wherein said UV solidification Resin A calculates by weight, and its composition and content are as follows:
Described UV solidification Resin A is prepared as follows:
Above-mentioned 60 parts of methyl and phenyl hydrogen-containing silicon oils and 20 parts of tetramethylol methane tetraacrylates are joined in the there-necked flask of 500ml; add the polymerization inhibitor of 0.01 part; it is passed through protective gas; stir and heat, being warming up to 80 DEG C, adding 0.05 part of catalyst; the lower constant temperature 5h of stirring; stop heating, treat that flask temperature drops to room temperature, obtain UV and solidify Resin A.
Described reactive diluent is oxolane acrylate, tetramethylol methane tetraacrylate, (2) ethoxylated bisphenol A dimethylacrylate, the mixture of the composition of 2:1:1 in mass ratio;
Described levelling agent is the mixture of Germany's BYK-345, BYK-346 1:1 in mass ratio composition;
Described wetting agent is Germany BYK 333;
Described defoamer is the mixture of Germany's BYK Bi Ke BYK-024, BYK-025 1:1 in mass ratio composition;
Described mill base is the temperature sensing color changing mill base of a kind of changeable colour;
Described light trigger A is BASF Irgacure 184D, Irgacure TPO, many kinds of mixtures of Irgacure 369, in mass ratio 1:1:1;
Described photoinitiator b is BASF BASF light trigger Irgacure 2959, the mixture of IRGACURE500, in mass ratio 2:1 composition;
The preparation method of above-mentioned a kind of strippable property nail polish glue, specifically includes following steps:
According to formula, 10 parts of wetting agents, 0.1 part of levelling agent, 1 part of defoamer and 10 parts of mill bases are added in the GFJ-0.4 type high speed dispersor (Shanghai Xin Nuo instrument and equipment Co., Ltd) controlling rotating speed 400r/min, after disperseing 20min under 800r/min rotating speed, rotating speed is down to 300r/min, add 80 parts of UV solidification Resin A, 80 parts of UV solidification resin B, 80 portions of reactive diluents, 5 parts of light trigger A and 5 parts of photoinitiator bs, continue dispersion 10min, mix, i.e. obtain strippable property nail polish glue.
After the strippable property nail polish glue film of gained of the present invention, UV-LED light irradiation through 385nm precoats the surface of slide of strippable property nail polish glue, according to the fingers-touch method (surface of the strippable property nail polish glue of the cured a period of time that press...withes one's finger, using tack-free as completely crued standard, shortest time used when being fully cured with strippable property nail polish glue characterizes), after testing, the hardening time of the quick-drying strippable property nail polish glue of the present invention is 7s.
Peel strength uses Shenzhen newly to think carefully, and the CMT5104 electronic tension tester of company is at room temperature carried out the stripping test of 180 °, draw speed 50mm/min by GB/T2790-1995 standard " 180 ° of peeling strength test methods of adhesive ";Recording peel strength is 0.21kN/m;Therefore, curing rate higher after the strippable property nail polish glue film of described gained of the present invention, it is easily peeled.
In sum, the strippable property nail polish glue of the present invention uses UV curing formula, and the high speed curable of UV improves its curing rate, only 1~7s;The toughening effect UV that has added solidifies resin C, makes strippable property nail polish glue have certain toughness.UV solidification Resin A molecular structure as main film forming substance is organosilicon structures, has the lowest surface energy, reduces the interaction between film and base material, be allowed to embody preferable rippability, and peel strength is 0.21~0.25kN/m.
Described content is only the basic explanation under present inventive concept, and according to any equivalent transformation that technical scheme is made, all should belong to protection scope of the present invention.