CN115192477A - UV (ultraviolet) moisture dual-curing nail polish gel and preparation method thereof - Google Patents
UV (ultraviolet) moisture dual-curing nail polish gel and preparation method thereof Download PDFInfo
- Publication number
- CN115192477A CN115192477A CN202210955166.3A CN202210955166A CN115192477A CN 115192477 A CN115192477 A CN 115192477A CN 202210955166 A CN202210955166 A CN 202210955166A CN 115192477 A CN115192477 A CN 115192477A
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- Prior art keywords
- nail polish
- moisture dual
- curing
- parts
- moisture
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- 238000002360 preparation method Methods 0.000 title abstract description 9
- 238000001879 gelation Methods 0.000 title description 2
- NIXOWILDQLNWCW-UHFFFAOYSA-M Acrylate Chemical compound [O-]C(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-M 0.000 claims abstract description 21
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 18
- 239000003085 diluting agent Substances 0.000 claims abstract description 14
- 239000012752 auxiliary agent Substances 0.000 claims abstract description 12
- 239000011347 resin Substances 0.000 claims abstract description 12
- 229920005989 resin Polymers 0.000 claims abstract description 12
- 239000003292 glue Substances 0.000 claims abstract description 6
- 239000000126 substance Substances 0.000 claims description 15
- 239000000203 mixture Substances 0.000 claims description 11
- 239000004814 polyurethane Substances 0.000 claims description 8
- 229920002635 polyurethane Polymers 0.000 claims description 8
- 239000003795 chemical substances by application Substances 0.000 claims description 5
- 239000013078 crystal Substances 0.000 claims description 5
- 230000009977 dual effect Effects 0.000 claims description 5
- 238000010438 heat treatment Methods 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 238000003756 stirring Methods 0.000 claims description 5
- 239000002518 antifoaming agent Substances 0.000 claims description 2
- 239000002270 dispersing agent Substances 0.000 claims description 2
- 239000003112 inhibitor Substances 0.000 claims description 2
- 238000006116 polymerization reaction Methods 0.000 claims description 2
- 238000009736 wetting Methods 0.000 claims description 2
- 239000003999 initiator Substances 0.000 claims 3
- 238000000034 method Methods 0.000 claims 2
- -1 acyl phosphine oxide Chemical compound 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 abstract description 4
- 238000002834 transmittance Methods 0.000 abstract description 4
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 abstract description 4
- UHESRSKEBRADOO-UHFFFAOYSA-N ethyl carbamate;prop-2-enoic acid Chemical compound OC(=O)C=C.CCOC(N)=O UHESRSKEBRADOO-UHFFFAOYSA-N 0.000 abstract description 2
- 238000001723 curing Methods 0.000 description 32
- 239000000463 material Substances 0.000 description 6
- 230000000052 comparative effect Effects 0.000 description 4
- 239000002904 solvent Substances 0.000 description 4
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 description 3
- 239000000853 adhesive Substances 0.000 description 3
- 230000001070 adhesive effect Effects 0.000 description 3
- 239000011521 glass Substances 0.000 description 3
- 239000004925 Acrylic resin Substances 0.000 description 2
- 229920000178 Acrylic resin Polymers 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 238000013008 moisture curing Methods 0.000 description 2
- 239000000049 pigment Substances 0.000 description 2
- 238000005406 washing Methods 0.000 description 2
- DKPFZGUDAPQIHT-UHFFFAOYSA-N Butyl acetate Natural products CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- IUHFWCGCSVTMPG-UHFFFAOYSA-N [C].[C] Chemical class [C].[C] IUHFWCGCSVTMPG-UHFFFAOYSA-N 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 238000003287 bathing Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000003086 colorant Substances 0.000 description 1
- 238000010411 cooking Methods 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 230000008030 elimination Effects 0.000 description 1
- 238000003379 elimination reaction Methods 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- IQPQWNKOIGAROB-UHFFFAOYSA-N isocyanate group Chemical group [N-]=C=O IQPQWNKOIGAROB-UHFFFAOYSA-N 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 229920001220 nitrocellulos Polymers 0.000 description 1
- 238000000016 photochemical curing Methods 0.000 description 1
- 229920000728 polyester Polymers 0.000 description 1
- 229920000642 polymer Polymers 0.000 description 1
- 230000002035 prolonged effect Effects 0.000 description 1
- KCTAWXVAICEBSD-UHFFFAOYSA-N prop-2-enoyloxy prop-2-eneperoxoate Chemical compound C=CC(=O)OOOC(=O)C=C KCTAWXVAICEBSD-UHFFFAOYSA-N 0.000 description 1
- 125000005373 siloxane group Chemical group [SiH2](O*)* 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 239000002352 surface water Substances 0.000 description 1
- 239000002562 thickening agent Substances 0.000 description 1
- 239000002966 varnish Substances 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/72—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds
- A61K8/84—Cosmetics or similar toiletry preparations characterised by the composition containing organic macromolecular compounds obtained by reactions otherwise than those involving only carbon-carbon unsaturated bonds
- A61K8/87—Polyurethanes
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q3/00—Manicure or pedicure preparations
- A61Q3/02—Nail coatings
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/95—Involves in-situ formation or cross-linking of polymers
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- Animal Behavior & Ethology (AREA)
- General Health & Medical Sciences (AREA)
- Public Health (AREA)
- Veterinary Medicine (AREA)
- Birds (AREA)
- Epidemiology (AREA)
- Cosmetics (AREA)
Abstract
The invention relates to UV (ultraviolet) moisture dual-curing methyl oil glue and a preparation method thereof, wherein the UV moisture dual-curing methyl oil glue is prepared from the following components in parts by mass 5-20 parts of UV moisture dual-curing resin, 50-70 parts of urethane acrylate, 10-20 parts of acrylate reactive diluent, 3-8 parts of photoinitiator and 3-8 parts of auxiliary agent. The nail polish gel can be cured qualitatively after being irradiated by UV light, can be cured continuously by moisture at the part irradiated by an insufficient UV light source or some color parts with poor light transmittance, and cannot be cured more fully after contacting water due to incomplete primary curing of UV irradiation, so that the performance of the nail polish is maximized.
Description
Technical Field
The invention relates to a UV moisture dual-curing nail polish gel and a preparation method thereof.
Background
Nail polish is a coating for beautifying and temporarily protecting nails, and pigments, pigments and some glittering materials are fixed on the nails through film-forming substances to achieve the effects of decoration and beautification. There are three types of nail polish currently marketed: the first type is a solvent type nail polish, which takes ethyl acetate and butyl acetate as main solvents and film-forming substances such as nitrocellulose, acrylic resin and the like as main basic connecting materials; the solidification mechanism is that the film forming substance is continuously accumulated to form a film through solvent volatilization; but has strong volatility, strong smell, flammability and explosiveness, has great production and transportation risks, and is the edge of domestic elimination. The second type is the domestic emerging water-based nail polish, which takes water-soluble polyurethane or water-soluble acrylic resin as a main film forming substance, and takes additives such as a hardening agent, a thickening agent, a wetting agent and the like as basic base materials, the curing mechanism is that polymer ions are aggregated and fused to form a film through volatilization of water, but the greatest defect at present is that the adhesive force and the temperature water resistance on the nail are not ideal. The third type is UV light-cured nail polish, which is a basic base material formed by using unsaturated carbon-carbon double-bond oligomer, such as acrylate, polyurethane acrylate, epoxy acrylate, polyester and the like as a main film forming substance, and matching with an active diluent and a photoinitiator; the curing mechanism is that the photoinitiator is initiated by the energy of ultraviolet light to generate free radicals or cations to initiate chemical reactions between unsaturated oligomers. The UV light-cured nail polish well overcomes the defects of strong smell, flammability, adhesive force on the nail and temperature and water resistance.
The most desirable combination of properties is currently available on the market as UV nail varnish. However, the application of the UV light source is limited because it requires an additional UV light source for curing, and if the UV light source is sufficiently irradiated, it cannot be used anywhere and anytime as in solvent-based nail polish and water-based nail polish. Secondly, for some darker or low transmittance colors, the curing may be incomplete, which may affect the adhesion and water resistance on the nails, however, in life, the fingers of the person's hands are not "clasped, scratched, knocked" for various activities (e.g. cooking dishes, washing clothes, washing hair and bathing, striking keyboards) and, at the same time, the person's hands are in contact with water for a very long period of time. If the curing is incomplete, prolonged exposure to water can affect the properties of the product.
Disclosure of Invention
The nail polish gel can be cured qualitatively quickly after being irradiated by UV light, and can be cured continuously by moisture at the part irradiated by an insufficient UV light source or some color parts with poor light transmittance, so that the performance of the nail polish is not deteriorated but cured more fully after contacting water due to incomplete primary curing of UV irradiation, and the performance of the nail polish is maximized.
The invention is realized by the following technical scheme:
the UV moisture dual-curing nail polish gel is prepared from the following components in parts by mass
Preferably, the UV photoinitiator is one of α -hydroxyketone derivatives, α -aminoketone derivatives or acylphosphine oxides.
Preferably, the auxiliary agent is one or any combination of more than two of a wetting dispersant, a leveling agent, an anti-settling agent, a defoaming agent, a polymerization inhibitor and an abrasion-resistant auxiliary agent.
The preparation method of the UV moisture dual-curing nail polish glue comprises the following steps: (1) Heating and mixing the photoinitiator and half of the acrylate reactive diluent in a water bath at 75-85 ℃ until the mixture is transparent and has no crystal;
(2) Adding UV moisture dual-curing resin, polyurethane acrylate, the other half of acrylate reactive diluent and an auxiliary agent into a container, and stirring the mixture uniformly at the rotating speed of 800-1200 r/min;
(3) Slowly adding the mixed substance in the step (1) into the uniformly mixed substance in the step (2), uniformly dispersing at 2200-2800r/min, standing and defoaming to obtain the UV moisture dual-curing methyl gum.
The UV resin can be UV resin of Basff, sadorma and Taiwan Changxing.
The UV moisture dual-curing resin can adopt Bayer and Basff UV moisture dual-curing resin.
The polyurethane acrylate can be polyurethane acrylate of Basfu, sadorma and Taiwan Yongxing.
The acrylate reactive diluent can adopt acrylate reactive diluents of Wanhua chemistry, saedoma and Taiwan Xinlimei.
The photoinitiator can be a photoinitiator of Tianjin Jiu, nippondi Italy and Beijing Yingli.
The auxiliary agent can adopt DIGAO, bike, effka and a moderate auxiliary agent.
The UV black paste (with 20 percent of color content) can be UV black paste of Endochidi and Nameixin materials
The principle of the scheme of the invention is as follows: UV moisture dual cure refers to the presence of both a photo-curing group and a moisture-curing group in the system, wherein the moisture-curing groups, including both siloxane groups and isocyanate groups, are reactive with water to cure.
Compared with the prior art, the invention has the following beneficial effects: the nail polish gel disclosed by the invention can be cured qualitatively quickly after UV irradiation, and can be cured continuously by moisture at the part irradiated insufficiently by a UV light source or at some color parts with poor light transmittance, so that the performance of the nail polish gel is not deteriorated but cured more fully after the nail polish gel is contacted with water due to incomplete primary curing of UV irradiation, and the performance of the nail polish is maximized.
Detailed Description
The invention will be further illustrated with reference to the following specific embodiments
Example 1
The UV moisture dual-curing nail polish gel comprises the following components in parts by mass
The preparation method of the UV moisture dual-curing nail polish gel comprises the following steps: (1) Heating and uniformly mixing a photoinitiator and half of acrylate reactive diluent in a water bath at 75 ℃ until the mixture is transparent and has no crystal;
(2) Adding UV moisture dual-curing resin, polyurethane acrylate, the other half of acrylate reactive diluent and an auxiliary agent into a container, and stirring the mixture to be uniform at the rotating speed of 800 r/min;
(3) And (3) slowly adding the mixed substance in the step (1) into the uniformly mixed substance in the step (2), then uniformly dispersing at 2200r/min, standing and defoaming to obtain the UV moisture dual-curing nail polish gel.
Example 2
The UV moisture dual-curing nail polish gel comprises the following components in parts by mass
The preparation method of the UV moisture dual-curing nail polish gel comprises the following steps: (1) Heating and uniformly mixing a photoinitiator and half of acrylate reactive diluent in a water bath at 80 ℃ until the mixture is transparent and has no crystal;
(2) Adding UV moisture dual-curing resin, urethane acrylate, the other half of acrylate reactive diluent and an auxiliary agent into a container, and stirring the mixture to be uniform at the rotating speed of 1000 r/min;
(3) And (3) slowly adding the mixed substance in the step (1) into the uniformly mixed substance in the step (2), uniformly dispersing at 2500r/min, standing and defoaming to obtain the UV moisture dual-curing nail polish gel.
Example 3
The nail polish gel comprises the following components in parts by mass:
the preparation method of the UV moisture dual-curing nail polish gel comprises the following steps: (1) Heating and uniformly mixing a photoinitiator and half of acrylate reactive diluent in a water bath at 85 ℃ until the mixture is transparent and has no crystal;
(2) Adding UV moisture dual-curing resin, polyurethane acrylate, the other half of acrylate reactive diluent and an auxiliary agent into a container, and stirring the mixture to be uniform at the rotating speed of 1200 r/min;
(3) And (3) slowly adding the mixed substance in the step (1) into the uniformly mixed substance in the step (2), uniformly dispersing at 2800r/min, standing and defoaming to obtain the UV moisture dual-curing methyl gum.
In order to observe the performance of each embodiment conveniently, 3 parts of UV black paste (20% color content) is added into the UV moisture dual-curing nail polish glue prepared in each embodiment, and when the nail polish glue is used specifically, other different color pastes can be added into the formula according to the requirements of users.
The preparation method operations of the above embodiments are carried out under the condition of avoiding light and UV ultraviolet light.
Comparative example 1
This comparative example differs from example 1 in that: 10 parts of UV moisture dual-curing resin is replaced by UV
And 10 parts of resin.
The cured nail polish gel of each example and each comparative example is placed in a constant temperature and humidity cabinet for about 5 hours, taken out, wiped to dry surface water vapor, placed on white A4 paper to slightly rub back and forth until the A4 paper is rubbed to certain extent to observe whether black residues exist or not.
Adhesion force: after the film was formed and cured on glass, the glass was placed in a constant temperature and humidity chamber for about 5 hours, and the adhesion was measured with reference to QB/T2287-2011.
Curing equipment: nail-beautifying UV lamp with power of 24W.
A constant temperature box: the temperature is 30 ℃ and the humidity is 50%
Base material: PVC nail sheet and glass plate
Curing time: 30 seconds
Film making equipment: wet film making device
Note: +: in general, a + +: good, + + +: is excellent in
In conclusion, compared with the comparative example, the UV moisture dual-curing nail polish gel provided by the invention has the advantages that the curing degree is higher, other properties are kept good, the adhesive force is good, the glossiness is high, the flexibility is good, the heat release performance is low, and the shrinkage resistance is good.
The present invention is not limited to the above-described embodiments, and all simple alternatives made according to the principles of the present invention are within the scope of the present invention.
Claims (4)
- UV moisture dual cure first oil glue, its characterized in that: the composition is prepared from the following components in parts by mass:
- 2. the UV moisture dual cure nail polish gel of claim 1, characterized in that: the UV photoinitiator is one of alpha-hydroxy ketone derivative initiators, alpha-amino ketone derivative initiators or acyl phosphine oxide initiators.
- 3. The UV moisture dual cure nail polish gel of claim 1, characterized in that: the auxiliary agent is one or any combination of more than two of a wetting dispersant, a flatting agent, an anti-settling agent, a defoaming agent, a polymerization inhibitor or a wear-resistant auxiliary agent.
- 4. A method of preparing a UV moisture dual cure nail polish gel as claimed in any one of claims 1 to 3, characterized in that: the method comprises the following steps:(1) Heating and mixing the photoinitiator and half of the acrylate reactive diluent in a water bath at 75-85 ℃ until the mixture is transparent and has no crystal;(2) Adding UV moisture dual-curing resin, polyurethane acrylate, the other half of acrylate reactive diluent and an auxiliary agent into a container, and stirring the mixture uniformly at the rotating speed of 800-1200 r/min;(3) And (3) slowly adding the mixed substance in the step (1) into the uniformly mixed substance in the step (2), uniformly dispersing at the rotating speed of 2200-2800r/min, standing and defoaming to obtain the UV moisture dual-curing nail polish gel.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210955166.3A CN115192477A (en) | 2022-08-10 | 2022-08-10 | UV (ultraviolet) moisture dual-curing nail polish gel and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202210955166.3A CN115192477A (en) | 2022-08-10 | 2022-08-10 | UV (ultraviolet) moisture dual-curing nail polish gel and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN115192477A true CN115192477A (en) | 2022-10-18 |
Family
ID=83585595
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202210955166.3A Pending CN115192477A (en) | 2022-08-10 | 2022-08-10 | UV (ultraviolet) moisture dual-curing nail polish gel and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN115192477A (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
| CN105748317A (en) * | 2016-02-23 | 2016-07-13 | 上海应用技术学院 | Quickly-curing strippable nail polish gel and preparation method thereof |
| CN109735224A (en) * | 2018-12-29 | 2019-05-10 | 天津久源新材料技术有限公司 | A kind of spectacle-frame coating of UV/ moisture dual cure and preparation method thereof |
| EP3712190A1 (en) * | 2019-03-18 | 2020-09-23 | ALLNEX AUSTRIA GmbH | Binder for an aqueous coating composition |
| CN114042015A (en) * | 2021-12-06 | 2022-02-15 | 河源然生新材料有限公司 | One-stroke colored high-solid-chroma nail polish gel and preparation method thereof |
| CN215837554U (en) * | 2021-06-18 | 2022-02-18 | 深圳市赫裕技术有限公司 | Three layer construction's novel beautiful first subsides |
-
2022
- 2022-08-10 CN CN202210955166.3A patent/CN115192477A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105213221A (en) * | 2015-10-08 | 2016-01-06 | 上海应用技术学院 | A kind of quick-drying nail polish glue and preparation method thereof |
| CN105748317A (en) * | 2016-02-23 | 2016-07-13 | 上海应用技术学院 | Quickly-curing strippable nail polish gel and preparation method thereof |
| CN109735224A (en) * | 2018-12-29 | 2019-05-10 | 天津久源新材料技术有限公司 | A kind of spectacle-frame coating of UV/ moisture dual cure and preparation method thereof |
| EP3712190A1 (en) * | 2019-03-18 | 2020-09-23 | ALLNEX AUSTRIA GmbH | Binder for an aqueous coating composition |
| CN215837554U (en) * | 2021-06-18 | 2022-02-18 | 深圳市赫裕技术有限公司 | Three layer construction's novel beautiful first subsides |
| CN114042015A (en) * | 2021-12-06 | 2022-02-15 | 河源然生新材料有限公司 | One-stroke colored high-solid-chroma nail polish gel and preparation method thereof |
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Application publication date: 20221018 |