CN104707619A - 一种石墨烯/Cu-Mn-Ti复合催化剂及其制备方法和应用 - Google Patents
一种石墨烯/Cu-Mn-Ti复合催化剂及其制备方法和应用 Download PDFInfo
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- CN104707619A CN104707619A CN201510057844.4A CN201510057844A CN104707619A CN 104707619 A CN104707619 A CN 104707619A CN 201510057844 A CN201510057844 A CN 201510057844A CN 104707619 A CN104707619 A CN 104707619A
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- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 title claims abstract description 57
- 239000003054 catalyst Substances 0.000 title claims abstract description 51
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- 239000010949 copper Substances 0.000 claims abstract description 10
- 239000012286 potassium permanganate Substances 0.000 claims abstract description 10
- 238000001914 filtration Methods 0.000 claims abstract description 9
- 239000011572 manganese Substances 0.000 claims abstract description 9
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- XTVVROIMIGLXTD-UHFFFAOYSA-N copper(II) nitrate Chemical compound [Cu+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O XTVVROIMIGLXTD-UHFFFAOYSA-N 0.000 claims abstract description 8
- MIVBAHRSNUNMPP-UHFFFAOYSA-N manganese(2+);dinitrate Chemical compound [Mn+2].[O-][N+]([O-])=O.[O-][N+]([O-])=O MIVBAHRSNUNMPP-UHFFFAOYSA-N 0.000 claims abstract description 8
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- 238000001035 drying Methods 0.000 claims abstract description 6
- 239000002253 acid Substances 0.000 claims abstract description 4
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- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 description 42
- 239000010936 titanium Substances 0.000 description 30
- HEMHJVSKTPXQMS-UHFFFAOYSA-M sodium hydroxide Inorganic materials [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 11
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 10
- 239000008247 solid mixture Substances 0.000 description 7
- 230000003197 catalytic effect Effects 0.000 description 6
- 239000012153 distilled water Substances 0.000 description 6
- 239000008367 deionised water Substances 0.000 description 5
- 229910021641 deionized water Inorganic materials 0.000 description 5
- 229910052748 manganese Inorganic materials 0.000 description 5
- 229910052761 rare earth metal Inorganic materials 0.000 description 5
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 description 4
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical group [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 4
- PWHULOQIROXLJO-UHFFFAOYSA-N Manganese Chemical group [Mn] PWHULOQIROXLJO-UHFFFAOYSA-N 0.000 description 4
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 4
- VWDWKYIASSYTQR-UHFFFAOYSA-N sodium nitrate Chemical compound [Na+].[O-][N+]([O-])=O VWDWKYIASSYTQR-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical group [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 3
- 239000003708 ampul Substances 0.000 description 3
- 238000005516 engineering process Methods 0.000 description 3
- 239000000463 material Substances 0.000 description 3
- 229910052719 titanium Inorganic materials 0.000 description 3
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- 238000007084 catalytic combustion reaction Methods 0.000 description 2
- 229910052802 copper Inorganic materials 0.000 description 2
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 description 2
- 229910052622 kaolinite Inorganic materials 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
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- 229910000510 noble metal Inorganic materials 0.000 description 2
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- 239000004317 sodium nitrate Substances 0.000 description 2
- 235000010344 sodium nitrate Nutrition 0.000 description 2
- 229910001220 stainless steel Inorganic materials 0.000 description 2
- 239000010935 stainless steel Substances 0.000 description 2
- 229910017566 Cu-Mn Inorganic materials 0.000 description 1
- 229910017871 Cu—Mn Inorganic materials 0.000 description 1
- UCKMPCXJQFINFW-UHFFFAOYSA-N Sulphide Chemical compound [S-2] UCKMPCXJQFINFW-UHFFFAOYSA-N 0.000 description 1
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- -1 aromatic hydrocarbons organic compound Chemical class 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
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- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
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- 229910044991 metal oxide Inorganic materials 0.000 description 1
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- Catalysts (AREA)
Abstract
Description
比表面积 | 总孔容 | 孔径 | |
GS-Ti/Cu/Mn(1:1:1) | 15.895m3/g | 0.5842cm3/g | 90.95nm |
Claims (8)
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CN201510057844.4A CN104707619B (zh) | 2015-02-04 | 2015-02-04 | 一种石墨烯/Cu‑Mn‑Ti复合催化剂及其制备方法和应用 |
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CN201510057844.4A CN104707619B (zh) | 2015-02-04 | 2015-02-04 | 一种石墨烯/Cu‑Mn‑Ti复合催化剂及其制备方法和应用 |
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105597775A (zh) * | 2015-11-02 | 2016-05-25 | 浙江工商大学 | 一种石墨烯/Cu-Mn-Ce复合催化剂以及制备方法和应用 |
CN106238065A (zh) * | 2016-07-08 | 2016-12-21 | 宁波钛安新材料科技有限公司 | 一种催化甲醛分解的复合催化剂及其制备方法 |
CN106607056A (zh) * | 2016-12-30 | 2017-05-03 | 北京化工大学常州先进材料研究院 | 一种石墨烯负载贵金属复合氧化物VOCs催化剂及制备方法 |
CN108914085A (zh) * | 2018-07-17 | 2018-11-30 | 华南理工大学 | 一种多孔微纤负载石墨烯薄膜及其制备方法 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
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CN103331159A (zh) * | 2013-07-10 | 2013-10-02 | 中南大学 | 一种Cu2O-TiO2/还原石墨烯三元复合物及其制备方法和应用 |
WO2014005598A1 (en) * | 2012-07-06 | 2014-01-09 | Teknologisk Institut | Method of preparing a catalytic structure |
CN103721510A (zh) * | 2013-12-13 | 2014-04-16 | 江苏中科睿赛污染控制工程有限公司 | 一种VOCs高效处理方法 |
CN104190409A (zh) * | 2014-08-19 | 2014-12-10 | 南京师范大学 | 石墨烯负载钛基核壳结构的低温scr抗硫催化剂及制备方法 |
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2015
- 2015-02-04 CN CN201510057844.4A patent/CN104707619B/zh not_active Expired - Fee Related
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2014005598A1 (en) * | 2012-07-06 | 2014-01-09 | Teknologisk Institut | Method of preparing a catalytic structure |
CN103331159A (zh) * | 2013-07-10 | 2013-10-02 | 中南大学 | 一种Cu2O-TiO2/还原石墨烯三元复合物及其制备方法和应用 |
CN103721510A (zh) * | 2013-12-13 | 2014-04-16 | 江苏中科睿赛污染控制工程有限公司 | 一种VOCs高效处理方法 |
CN104190409A (zh) * | 2014-08-19 | 2014-12-10 | 南京师范大学 | 石墨烯负载钛基核壳结构的低温scr抗硫催化剂及制备方法 |
Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105597775A (zh) * | 2015-11-02 | 2016-05-25 | 浙江工商大学 | 一种石墨烯/Cu-Mn-Ce复合催化剂以及制备方法和应用 |
CN106238065A (zh) * | 2016-07-08 | 2016-12-21 | 宁波钛安新材料科技有限公司 | 一种催化甲醛分解的复合催化剂及其制备方法 |
CN106238065B (zh) * | 2016-07-08 | 2018-10-16 | 宁波钛安新材料科技有限公司 | 一种催化甲醛分解的复合催化剂及其制备方法 |
CN106607056A (zh) * | 2016-12-30 | 2017-05-03 | 北京化工大学常州先进材料研究院 | 一种石墨烯负载贵金属复合氧化物VOCs催化剂及制备方法 |
CN108914085A (zh) * | 2018-07-17 | 2018-11-30 | 华南理工大学 | 一种多孔微纤负载石墨烯薄膜及其制备方法 |
CN108914085B (zh) * | 2018-07-17 | 2020-12-22 | 华南理工大学 | 一种多孔微纤负载石墨烯薄膜及其制备方法 |
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Effective date of registration: 20210423 Address after: 226300 Century Avenue, Nantong high tech Zone, Jiangsu, China, No. 266, No. Patentee after: NANTONG WOTE OPTOELECTRONICS TECHNOLOGY Co.,Ltd. Address before: Hangzhou City, Zhejiang province 310018 Xiasha Higher Education Park is 18 street. Patentee before: ZHEJIANG GONGSHANG University Effective date of registration: 20210423 Address after: No. 516, South Road, Haian Town, Haian City, Nantong City, Jiangsu Province Patentee after: JIANGSU JIAYU SPECIAL EQUIPMENT Co.,Ltd. Address before: 226300 Century Avenue, Nantong high tech Zone, Jiangsu, China, No. 266, No. Patentee before: NANTONG WOTE OPTOELECTRONICS TECHNOLOGY Co.,Ltd. |
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